TW201213450A - Colored resin composition - Google Patents

Abstract

Disclosed is a color filter which has clear and high-quality color properties having excellent contrast performance, and also has superior resistance including heat resistance to that of conventional color filters, and high reliability. Also disclosed is a colored resin composition for forming a color filter, which utilizes a specific dye-type coloring compound and can be produced by mixing the coloring compound with a binder resin, a solvent, a curing agent, specific curing agent, a curing-accelerating agent and others. A color filter produced using the resin composition has excellent color properties such as contrast performance and therefore has high quality, and also has excellent resistance including heat resistance and solvent resistance and high reliability.

Description

201213450 6. Technical Field of the Invention The present invention relates to a colored resin composition for forming a blue pixel, a color filter formed using the colored resin composition, and a color filter using the color filter. Electronic display device such as a liquid crystal display device, an imaging device (CCD (Charge-Coupled Device), CMOS (Complementary Metal Oxide Semiconductor)), or an organic EL (Electroluminese) display . [Prior Art] A liquid crystal display element such as a liquid crystal display (LCD) represented by a notebook computer, a liquid crystal television, or a mobile phone, or an image pickup element used as an input device of a digital camera, a color photocopying machine, or the like ( For colorization of CCD and CMOS), a color filter is required. As a method for producing a color filter used in such a liquid crystal display device or a solid-state image sensor, there are dyeing method, electric chain method, printing & pigment dispersion method, etc. In recent years, the pigment dispersion method has gradually become mainstream. The material patterning & is representative of the photolithography method. A mixture of a photosensitive resin composition and a pigment dispersion is used to form a color filter or a light sheet. Recently, the following method has also been carried out: a coloring ink is directly applied to a substrate by an ink jet printer without interposing a photomask: a color filter is formed. The improvement in color purity, chroma, and contrast required for color calendering is particularly important. By increasing the brightness, the amount of light can also reduce the power consumption, so it is also environmentally friendly = 155912.doc 201213450 technology. In order to improve the color purity of the color filter, it is necessary to increase the content of the coloring pigment or to select a pigment having a better spectral shape. On the other hand, in order to increase the brightness, it is necessary to increase the transmittance, so it is necessary to lower the pigment concentration or to make the film thickness thin. In order to coexist these opposite characteristics, a method of pulverizing the pigment is carried out, but the current state has a limit in terms of resistance or dispersion stability, and even if the brightness is improved, the coexistence of the resistance cannot be achieved. In order to solve such problems, research on the use of dyed ochre/lighting sheets is being promoted as another means. When a dye is used, there is an advantage that the purity and the degree of the color which cannot be achieved when the pigment is used are coexisted, or the contrast is also improved because the particles are not particles, so that the light can be suppressed from being scattered. However, in the case of a display body requiring long-term reliability such as a television, light resistance or heat resistance is particularly required, but the blue dye is significantly inferior to the pigment. For example, in Patent Documents 1 and 2, there is no significant difference in light resistance or heat resistance of a base-based compound which is related to a color filter using a triphenylsulfonium-based compound, and is light and practical. Further, in Patent Document 3, there is a description that the dibenzophenanthrene compound is excellent in terms of the degree of fit. However, there is no description about the resistance. Further, similarly to the pigment, due to light scattering, formation of a liquid crystal on the color filter to define dibenzopyran as a fluorescent dye causes a decrease in contrast. When the film is applied to the film, Ν·methyl is used. More than 0 each. A solvent having a high solubility such as a ketone is required as a solvent for the alignment film material, and it is desired that it does not elute even if it is impregnated with the solvent. There are no major problems with the pigments to date; 曰 dyes are more solvent-soluble than pigments, so solvent resistance is especially needed. In a color calender sheet which requires high reliability, (4) a colored resin composition containing a compound having excellent resistance to a colored material is required, but the current situation is practically not practically 155912.doc 201213450. Therefore, as the next generation, it is a high-quality color filter that is excellent in resistance. [PRIOR ART DOCUMENT] [Patent Document 1] Japanese Patent Laid-Open Publication No. Hei. No. Hei. No. Hei. No. Hei. 〇 32 999 999 999 999 999 999 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 Passing light film pixels. [Means for Solving the Problems] The inventors of the present invention have diligently studied to solve the above problems, and as a result, have found that by using a colored resin composition containing a specific dye-based coloring material compound in a color ray film pixel, The problem thus completed the present invention. In other words, the present invention relates to: (1) A colored resin composition for a color filter comprising a colored material compound represented by the following formula (1), a colored material compound represented by the formula (2), a binder resin, a solvent, and the like. Photopolymerization initiator, hardener and hardening accelerator, *55912.doc 201213450 [Chemical 1]

(In the formula (1), 'Rlb to R6b each independently represent a hydrogen atom, a halogen atom, an alkyl group of ci_ci2, an alkoxy group of a Cl-C12, a nitro group, a carboxyl group or an alkoxycarbonyl group; and Υι~γ4 independently represent a hydrogen atom, C1_C12 alkyl, aryl; χ丨~& independently represent a hydrogen atom, a C1-C12 alkyl group, a C1-C12 alkoxy group, a halogen atom, a phenyl group, a phenoxy group, a carboxyl group, an alkoxy group a carbonyl group, an amine sulfhydryl group, a sulfo group or an amine fluorenyl group; ζ· represents an alkylsulfonyl methide anion having a high-order alkyl group of cn_cio, an anthracene anion or an alkyl group ), [Chemical 2]

155912.doc 201213450 (In the formula (2), Rla~R6 are independently 砉- represent an anthracene atom, an alkyl group of C1-C30, a radical or a radical; R7a~R20a independently represent a hydrogen atom, a dentate atom, C1 -C6 alkyl; Z- represents the same illusion as in the formula (1); (7) The resin composition containing the compound of the colored material as in (1), and the enthalpy in the formula (1) and the formula (2) are independently three. a fluoromethyl (tetra) methide anion, a bis-three-methyl imine anion or a tri-sodium methyl sulphate, (3) a colored resin composition as in (1) or (2), which contains the following formula (7) Milk resin as a hardener, [Chemical 3]

(In the formula (3), Rlc to Rw each independently represent a hydrogen atom, an alkyl group of cici2, an alkoxy group of C1-C12, a dentate atom; further, 〇 represents a glycidyl group; (4) as in (1) to (3) A colored resin composition containing a metal phthalocyanine pigment; 155912.doc 201213450 (5) A colored hardening film for a color filter, which is used in any one of (1) to (4) a colored resin composition is patterned; (6) a color filter comprising a colored cured film for a color filter as (5); (7) a display device installed as in (6) A color light-passing film is produced; (8) - a kind of m-body imaging element 'which is a color filter of (6). [Effects of the Invention] The colored resin composition of the present invention can provide excellent color characteristics and excellent contrast characteristics, heat resistance and solvent resistance by using a colored resin composition containing a specific dye-based coloring material compound. High quality color filter pixels for color filters. [Embodiment] The colored resin composition of the present invention contains a binder resin, a solvent, a photopolymerization initiator, a hardener, a hardening accelerator, and a specific dye-based coloring material: if necessary, other pigments or dyes may be colored. The various additives such as the material compound, the interface active heat curing agent, the polymerization inhibitor, and the ultraviolet absorber are not limited thereto, and the components other than the specific dye-based coloring material compound can be used without particular limitation. The method of producing a pixel using the colored resin composition of the present invention is mainly a photosensitive resin composition excellent in developability using a photopolymerization initiator in the photolithography method and the inkjet former, and photopolymerization is not necessarily required in the latter. A thermosetting resin composition is used as a starting agent. The specific dye-based colored material represented by the above formula (1) used in the present invention is 155912.doc 8 201213450 The Rb to R0b of the compound independently represent a hydrogen atom, a halogen atom, an alkyl group of C1C12, an alkoxy group of C1-C12, and a nitro group. , a carboxyl group, an alkoxycarbonyl group. Υι~γ4 independently represent a hydrogen atom, an alkyl group of Cl_C12, and an aryl group. Χΐ~& can independently have a hydrogen atom, a C1-C12 alkyl group, a C1-C12 alkoxy group, a halogen atom, a nitro group, a phenoxy group, a carboxyl group, an alkoxycarbonyl group, an amine carbaryl group, a sulfo group. One or two or more kinds of sulfonamide groups, of which a carboxyl group or an alkoxycarbonyl group is preferred. The anion moiety Ζ- represents an alkylsulfonyl methide anion having a higher alkyl halide of Ci_C10, a sulfonyl imine anion or an alkylsulfonate. Examples of the alkyl group include a mercapto group, an ethyl group, a n-propyl group, an isopropyl group, an n-butyl group, a second butyl group, a third butyl group, an isobutyl group, a n-pentyl group, a n-hexyl group, and a n-octyl group. A C1_C12 alkyl group such as a 2-ethylhexyl group or a cyclohexyl group. The alkyl group may have a substituent. Examples of the alkyl group having a substituent include a hydroxyethyl group, a hydroxypropyl group, a hydroxybutyl group, a 2-sulfoethyl group, a carboxyethyl group, and a cyanoethyl group. Alkoxyethyl, ethoxyethyl, butoxyethyl, difluoromethyl, pentafluoroethyl, and the like. Further, the alkyl group may have a substituent including an aminomethyl group and a carboxyl group. The alkoxy group which has the same alkyl group of ci_c12 as the above alkyl group is exemplified as the above-mentioned alkoxycarbonyl group, and the alkoxycarbonyl group having the same C1-C12 alkyl group is also exemplified as the alkoxycarbonyl group. Examples of the aryl group include an aromatic hydrocarbon residue such as a phenyl group, a naphthyl group, an anthracenyl group, a phenanthryl group, a fluorenyl group or a benzoyl group; and a π-bite group. An aromatic heterocyclic residue such as a thiol group, a β-density group, a quinolyl group, an isoquinolyl group, a fluorenyl group, a fluorenyl group, an imidazolyl group, an oxazolyl group, a thienyl group or a furyl group. The aryl group may have a substituent at 155912.doc 201213450, and examples of the substituent include a group of alkoxy groups, an i atom, a sulfo group, a carboxyl group, an alkoxycarbonyl group, an amine methyl group, and a cyanogen group. Base $. Examples of the halogen atom in the formulae (1) and (2) include a fluorine atom, a gas atom, a bromine atom, and an iodine atom. The phenoxy group may have a substituent. Examples of the substituent include a linear or branched alkyl group of C1-C12, a halogen atom, an amine group, an alkylamine group, and a hydroxyl group. Examples of the alkoxycarbonyl group include a methoxycarbonyl group, an ethoxycarbonyl group, a propoxycarbonyl group, an isopropoxycarbonyl group, a butoxycarbonyl group, an isobutoxy group, a silk group, and a isose. (4), neopentyloxy, cyclopentyloxy (tetra), hexyloxy (tetra), cyclohexyloxy, heptyloxy, cycloheptyloxycarbonyl, octyloxycarbonyl, 2-ethylhexyloxy Carbocarbonyl, cyclooctyloxy, oxime, oxime, tricyclic oxime, methoxypropoxy, ethoxypropoxy, hexyloxypropoxy Substituted, 2-ethylhexyloxypropoxy M-group, f-oxyhexyloxy (tetra), oxy-oxyl group, and the like. The above amine fluorenyl group may have a substituent, and examples of the substituent include a linear or branched alkyl group of C1-CU, a strepyl group, a fluorenyl sulfonyl group, a pyrimidinyl group and the like. Further, as the above amine aryl group, a 2 (tetra) group bonded to nitrogen may form a C3-C12 cycloalkyl ring together with the nitrogen atom, or an aliphatic group having one or more hetero atoms such as nitrogen, oxygen, sulfur or the like. Heterocyclic. Examples of the above-mentioned continuation group include a methyl stellite base, an ethyl aryl group, a hexyl continuation group, and a fluorenyl group. Examples of the above amine sulfonyl group include an aminesulfonyl group, a methylamine sulfonate 155912.doc 201213450 fluorenyl group, an ethylamine sulfonyl group, a propylamine sulfonyl group, an isopropylamine sulfonyl group, and a butyl group. Amidoxime, isobutylamine sulfonyl, amylamine sulfonyl, isoamylamine sulfonyl, neopentylamine sulfonyl, cyclopentylamine sulfonyl, hexylamine sulfonyl Cyclohexylamine sulfonyl, heptylamine sulfonyl, cycloheptylamine sulfonyl, octylamine sulfonyl, 2-ethylhexylamine sulfonyl, 1,5-dimethylhexylamine sulfonate Sulfhydryl, cyclooctylamine sulfonyl, decylamine sulfonyl, decylamine sulfonyl, tricyclodecylamine sulfonyl, methoxypropylamine sulfonyl, ethoxypropylamine Synthetic base, propoxypropylamine hydrazino, isopropoxypropylamine hydrazino, hexyloxypropylamine continuation, 2-ethylhexyloxypropylamine thiol, A Oxyhexylamine sulfonyl, 3-phenyl-1-methylpropylamine sulfonyl and the like. The anion portion z- of the dye-based coloring material compound represented by the general formula (1) and the formula (2) contained in the colored resin composition of the present invention independently represents a crucible-human-calcining group having Cl C10. A thioglycolate anion, a sulfonyl sulfoximine anion or an alkyl sulfonate. Specific examples thereof include a tris-trifluoromethylsulfonyl methide anion, a bis-trifluoromethylsulfonimide anion, and a trifluoromethylsulfonate 'nonafluorobutylsulfonate. It is a tris-trifluoromethyl decyl methide anion. Specific examples of the above formula (1) are shown in the following Tables M to Table, but the present invention is not limited to these. [Table 1] 1559l2.doc 201213450 Table 1-1 Compound No. Chemical Formula 1 To t Et FjCOjS^.^SOjCF, Jn^COOH Wpj u 2 Protect Et ΕΚΝγ^γ°γίΝγ>Λ®Εί WiS'g/SChCFi dr° H 3 Jxxxyk D, CF, S〇P ^yCOOH 4 Η H ει, ΝνΓΎ°Τ^Τ^ H}C FjCOjS^SOjCF, Js^^COOEt S〇aCF3 5 ε^η'Υ\όύ^ϋ<^ ^cAAjAAch ,柳, p〇, CFl ^°°Et 6 a ψ Ε^Νγ,γ0γΓγΝ®Εί PjCOjS^g^^OjCF, Jx^OOEt S〇2CFj u 155912.doc -12- 8 201213450 Table 1-2 Compound No. Chemical Formula 7 FjCOjS+SOjCP, ^γ000» 8 Ε^Νν^γ°γ^γ^Ε! FjCOjS^^SOjCFj J^COOM· SOjCFj 9 ψ f Ε^Νγ^γΛν^Ν®Εΐ FaCOjSvI^OaCFj l.CONH^ W3 10 V *f Ε^Μγ"γ°γ^Ν®Ε1 FjCOjS^SOjCF, ^L^OOEt S〇2〇F3 u 11 ΕΚΝ,γγγ〇γί'γ^Εί FjCOaS^g^SOjCP, Q 8 〇2CF, 12 h^Y^YY^ch, HjC^^Y^S^ FjCOjS^^SOjCF, Js^^^OOEt S«V:F9 u -13- 155912.doc 201213450 Table 1-3 13 1 f* FjCOjS Let SO*CF, Jv.^COOEt SOzCFj 14 ff ^,ΝΥΎ°Υ^Ύ 咕Et FjCOiS^OjCF, ^KXONhV SOjCFj uc 15 FjCOjS^^SOjCFj Jv^COOMe N Cr 16 Φ ΐΝ^'ί#ί5ΐγ!? ΐΝ^ PaCOaS'^S C^CF* Cri "X) SO.CF, 17 0 PaC〇aS, ©/SO, CF3 u 〇H ^ 18 ΖΤΧ〇Η . W. Cl 155912.doc -14- 8 201213450

In the R1 a to R 6 a of the dye-based coloring material compound represented by the general formula (2) of the present invention, 'as a C 1 - C 3 0 calcining 1 group' can be listed, for example, methyl group, ethyl group, propyl group, Isopropyl, butyl, 1-mercaptopropyl (second butyl), isobutyl, pentyl, 1-ethylpropyl, 1-methylbutyl, cyclopentyl, hexyl, decyl Base, 1-ethylbutyl, cyclohexyl, hydroxypropyl, 2-sulfoethyl, carboxyethyl, cyanoethyl, decyloxyethyl, ethoxyethyl, butoxyethyl, Trifluoromethyl, pentafluoroethyl, 2-heptyl, heptyl, octyl, decyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecane Base, hexadecane, heptadecyl, octadecyl, nineteenth base, arachyl, eicosyl, eicosyl, behenyl, Thirteen alkyl, tetracosyl, dipentadecyl, dihexadecyl, heptacosyl, octadecyl, octadecyl, tridecyl, isoheptyl , isooctyl, isodecyl, isodecyl, isodecyl, isododecyl, iso 13155912.doc -15- 201213450 alkyl, isotetradecyl, isopentadecyl, isohexadecyl, isoheptadecyl, isooctadecanyl, isopropenyl, isoarachyl, iso Twenty yards (isoeicosyl), isoindole--Hyun, iso-teledioyl, iso-tris-trialkyl, iso-tetracosyl, iso-pentadecyl, iso-hexadecane , iso-heptadecyl, iso-octadecyl, iso-dodecyl, iso-t-octadecyl, 1-methylhexyl, 1-ethylheptyl, 1-decylheptyl, hydrazine Cyclohexylethyl, 1-heptyloctyl, 2-decylcyclohexyl, 3-decylcyclohexyl, 4·nonylcyclohexyl, 2,6-didecylcyclohexyl, 2,4-didecyl Cyclohexyl, 3,5-dimethylcyclohexyl, 2,5-didecylcyclohexyl, 2,3-dimethylcyclohexyl, 3,3,5-trimethylcyclohexyl, 4-third A cyclohexyl group, a 2-ethylhexyl group, a 1-adamantyl group, a 2-adamantyl group, and the like. Among them, more preferred are ethyl, isopropyl, isobutyl, isopentyl, isoheptyl and 2-nonylcyclohexyl. The alkyl group may have a substituent. The substituent is not particularly limited, and examples thereof include an alkoxy group such as a hydroxyl group, a sulfo group, a carboxyl group, a cyano group, a methoxy group or an ethoxy group, and a halogen. In the case of R a to R 0af of the formula (2), the phenyl group or the benzyl group may have a substituent, and examples of the substituent ' may include methyl group, ethyl group, propyl group, isopropyl group, butyl group and the like. (C1_C5) alkyl group such as butyl group, tert-butyl group or pentyl group, halogen atom such as fluorine atom, chlorine atom, bromine atom or male atom, acid group, methoxy group, ethoxy group, propoxy group, butoxy group Base, third butoxy, pentyloxy, etc. (ci_c6) alkoxy 'hydroxyethyl, hydroxypropyl and the like hydroxy (C1_C5) alkyl, methoxyethyl, ethoxyethyl, ethoxypropyl (1,1) alkoxy (C1-C5)alkyl, 2-hydroxyethoxy, etc. hydroxy (C1_C5) alkoxy, 2-methoxy ethoxy, 2-B Alkoxy (C1_C5) alkoxy such as oxyethoxy group, 2-sulfoethyl group, carboxyethyl group, cyanoethyl group, etc. 155912.doc -16· 201213450 R7a~R2Ga of the formula (2) In the above, the C1-C6 alkyl group may be unsubstituted or substituted. Examples of the C1-C6 alkyl group include a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, an isobutyl group, and a pentyl group. , cyclopentyl, hexyl, cyclohexyl, propylidene, 2-crossyl Ethyl, cyclohexylethyl, arylethyl, methoxyethyl, ethoxyethyl, butoxyethyl, trifluoromethyl, pentafluoroethyl, etc. as the heart of the formula (2) A wide range of 2^, preferably a hydrogen atom, a gas atom or an unsubstituted C1-C6 alkyl group. Specific examples shown by the formula (2) are shown in Table 2-1 and Table 2-2 below, but The present invention is not limited to these. [Table 2] Table 2-1 Compound No.; »Substituent R-- Anion r la 2a 3a 4a Sa 6a 7a 8a 9a 10a 11a 12a 13a 14a 15a 16a 17a 18a 19a 20a 2-1 Et Ht Et Et Et HHHHHHHHHHHHHHH α 2-2 Et Et Et Et Et H ——-HH —— HHHHHHHHHH IT HHH β 2-3 Et Et Et Et HHHHHHHHHHHH 2-4 Me Me Me Me Me HHHHH-HHHHHHHHH 2-5 n-Bu n-Bu n-Bu n-Bu Et HHHHHHHHHHH h" HHH — 2*6 i-Bu i*Bu i-Bu i-Bu Et HHHHHHHHHHHHHHH 2-7 Et Ht Et Et i -Pr HHHHHHHHHHHHHHHH 2·8 n-Bu n*Bu n-Bu n*Bu i-Pr HHHHHHHHHHHHHHH 2-9 Et Et Et Et CH HHHHHHHHHHHHH HH 2-10 Et Ht Et Et i-Pen HHHHHHHHHHHHHHH 2-11 CH Et CH Et CH HHHHHHHHHHHHHHH 2-12 Et Et Et Et i-Hep HHHHHHHHHHHHHH 2 2 Et Et Et Et MeCH HHHHHHHHHHHHHH 2-14 CH Et CH Et i -Pen HHHHHHHHHHHHHHH 2-15 CH Et CH Et Me Me HHHHHHHHHHHHHH 2-16 Et Et Et Et t-Bu HHHHHHHHHHHHHHH 2 2 Et Et Et a Ph HHHHHHHHHHHHHHH 2-18 Et Et Et Et i-Pen H Me HHH Me HHHHHH — HHH α 155912.doc -17· 201213450 Table 2·2 ___-------------- 17a 18a 19a 20a Ion moiety · 2-19 Et Et Et Et HHHHHHHHHHHHHHH α 2-20 Et Et Ht Ht HHHHHHHHHHHHHHH α 2-21 £t Et Et Et "chKCH»11 HHHHHHHHHHHHHHH α 2-22 Et Et Et B, HHHHHHHHHHHHHHH 2 2-23 Et Et E( Et HHHHHHHHHHHHHHH α 2-24 Et Et Et Ht HHHH Cl HHH Cl HH HHHH α 2-25 Et Ei Et Et HHHH a HHH CJ HHHHHH α 2-25 Et El Et Ht HHHH Me HHH Me HHHHHH α 2-27 Et Et Et Et ςν HHHH Me HHH Me HHHHHH α 2-28 Me Me Me Me HHHHHHHHHHHHHHHH α In the above Table 2-1 and Table 2-2, regarding the substituent r, Me represents a fluorenyl group, Et represents a non-ethyl 'n-Bu represents n-butyl group, i_Bu represents an isobutyl group, and EtC]s Cyanoethyl, EtCl represents a gaseous ethyl group 'Bz represents a benzyl group, ph represents a phenyl group, and CH represents a cyclohexyl group. NR2 represents an alkylamine group, and R is the same as the above alkyl group. Further, when Z- is α, it represents a tris-trifluoromethylsulfonyl sulfhydryl anion, and in the case of β, it represents a bis-trifluoromethylsulfonylimide anion, and in the case of γ, it represents three. Fluorinyl sulfonate. The dye-based coloring material compound of the formula (1) and the formula (7) used in the colored resin composition of the present invention can be used, for example, in "The Theory of Manufacturing Dyestuff Chemistry" (pp. 373-375) issued by Takubun Co., Ltd. According to the known synthesis method described, it is also possible to purchase an anion moiety, which is a commercial product of a gas anion, and to synthesize it by salt exchange by adding a corresponding salt or acid. When the dye-based colored material compound 155912.doc 201213450 of the present invention is synthesized by solitude, the target can be easily obtained, for example, by anionic portion z- of the general formulae (1) and (7). The colored material compound which is a chlorine anion is dissolved in the reaction solvent (for example, water or methanol, ethanol, isopropanol, acetone, N,N-dimethylformamide (hereinafter abbreviated as DMF), N_methyl-2) a water-soluble polar solvent such as pyrrolidone (hereinafter abbreviated as NMP), which may be used singly or in combination, _, adding a corresponding salt or bismuth 5~3 equivalents at a specific temperature (for example, 〇~l〇( The TC is stirred and the precipitated crystals are collected by filtration. The total solid content of the colored resin composition of the present invention (the total solid content of the compound containing a colored material, a binder resin, a hardener, etc., the same meaning below) The content of the compound of the colored material represented by the above formula (1) and formula (7) contained in the use of the compound (1) and the formula (7) is preferably a part by mass of the oxime, more preferably a mascara. When the content exceeds the range, precipitation or precipitation occurs. Condensed The problem is that the adhesion to the substrate is lowered due to insufficient hardening. On the other hand, when the content is small, there is a tendency that sufficient color purity as a color characteristic cannot be obtained. Further, regarding the above formula (1) The ratio of the formula (2) is good in any ratio within the above range, but in terms of contrast characteristics, it is preferable that the content of the formula (2) is more than the formula (1). For example, when considering the contrast When the content of the above formula is from 1 to 30 parts by mass, the formula (2) is preferably from 2 to 30 parts by mass. When the content of the above formula (1) exceeds 30 parts by mass, it is difficult to add an equivalent amount of the formula (7). It is preferable to use as much as possible in the above range. However, other characteristics such as brightness and resistance are not limited thereto, and when the content ratio of the above formula (1) is large, the characteristics are exhibited. When the solubility of the dye-based coloring material compound represented by the formula (2) in the 155912.doc -19-201213450 color resin composition is low, it may be the same as the pigment of any of the following components. Dispersing agent or dispersing aid, etc. The compound of the above-mentioned formula (1) and the formula (2) may be used in combination of two or more kinds, and may be used alone or in combination with other dyes or pigments. Since the present invention relates to blue pixels, it is preferable. It is mixed with a known blue dye or a purple dye, or a blue pigment or a violet pigment, etc. The binder resin used in the present invention means a dispersion function as a dispersing agent or a dispersing aid to achieve dispersion of a pigment dispersion. Stability, and in terms of the design of the photolithography method, it is desirable to be soluble in the developer solution used in the development processing step in the manufacture of the color light film. Since the fine pattern is self-preferable, it is preferable to have sufficient hardening characteristics with a photopolymerization initiator and a photopolymerizable cover to excite the ancient body. The pigment-dispersed resin composition obtained must have good compatibility with a constituent material such as a photopolymerization initiator, a photopolymerizable monomer, and a pigment dispersion liquid, and is stable without precipitation or agglomerates. In the case of the ink jet method, it is not particularly necessary to test the solubility, so that it is preferable to select another resin which is compatible with the colored material compound or the additive. As the binder resin, a known resin may be used, and more preferably an ethylenically unsaturated monomer having at least one carboxyl group or a vinyl group as exemplified below, or other copolymerizable aromatic smoke-based or aliphatic smoke. The copolymer of the ethylenically unsaturated monomer or the like is more desirable, and can also be used in the side chain or the terminal, such as an epoxy group, and an acrylate having an acrylate. These monomers and the like can be combined into two or more types. 155912.doc 201213450 The above-mentioned carboxyl group-containing unsaturated monomer which can be used in the present invention, for example, acrylic acid, methacrylic acid, crotonic acid , unsaturated acrylic acid, ethyl acrylate, cinnamic acid and other unsaturated monocarboxylic acids; maleic acid, maleic anhydride, fumaric acid, itaconic acid, itaconic anhydride, mercapto Unsaturated dicarboxylic acid (anhydride) such as butenedioic acid, methyl maleic anhydride or methyl fumaric acid; unsaturated polycarboxylic acid (anhydride) of 3 兀 or more; 2_(fluorenyl) Propylene oxyethylhexahydrophthalic acid, 2_mercaptopropene oxyethyl _2_ propyl propyl phthalate, 2- propylene methoxyethyl 2 hydroxyethyl o-dicarboxylate. The ethylenically unsaturated monomers having carboxyl groups may be used alone or in combination. The above-mentioned hydroxyl group-containing unsaturated monomer which can be used in the present invention is, for example, 2-(meth)acrylic acid 2-ethylidene vinegar or (meth)acrylic acid 2-propyl propyl ester , (mercapto)acrylic acid 3-glycolyl, (mercapto)acrylic acid butyl acetonate, (meth)acrylic acid 3- butyl vinegar '(meth) acrylate 5 _ base 戍Vinegar, (meth)acrylic acid 4-pivalyl vinegar, (mercapto) acrylic acid 3_yl pentyl vinegar, (m-hexyl hexanoate, (meth) acrylate 5 · hexyl vinegar , (meth)acrylic acid 4 · hexyl vinegar, (f-) acrylic acid 5 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ (Methyl)acrylic acid 2_(2_ mercaptoethoxy) ethyl vinegar, glycerol monomethacrylic acid vinegar, polyethylene glycol mono(methyl)propionate-polypropylene glycol mono(sub)acrylic vinegar , poly(ethylene glycol-propylene glycol) mono- acrylate, etc. The terminal is a polyglycol diol mono(methyl) acrylate vinegar, etc. These ethyl (tetra) unsaturated monomers having a trans group may be used alone or in combination of two or more. Further, as the unsaturated monomer other than the above, For example, styrene, 155912.doc -21 · 201213450 α-mercaptostyrene, o-vinyl f benzene, m-vinyl toluene, p-vinyl fluorene, o-chlorostyrene, m-styrene, An aromatic vinyl compound such as p-chlorostyrene or p-methoxystyrene; methyl (meth) acrylate, (methyl;) ethyl acrylate, n-propyl (meth) acrylate, (meth) acrylate Propyl ester, n-butyl (meth)acrylate, isobutyl (meth)acrylate, second butyl (meth)acrylate, tert-butyl (meth)acrylate, 2-hydroxyl (meth)acrylate Vinegar, benzyl (mercapto) acrylate, p-cumylphenoxyethylene (fluorenyl) acrylate, 2-hydroxy-3-phenoxypropyl (meth) acrylate, o-phenyl phenyl hydrazine Glycidyl ether (mercapto) acrylate, o-phenylphenol (meth) acrylate via ethylate, (Unsaturated carboxylic acid esters such as phenoxyethyl acrylate; cyclopentyl acrylate), cyclohexyl (meth) acrylate, dinonylcyclohexyl (decyl) acrylate, (A) (meth)acrylic acid-lowering ester, (meth)acrylic acid-lowering methyl hydrazine, (fluorenyl) propyl phenyl phenyl thioglycolate, (mercapto) cyano cyanohydrazide, (a Isodecyl acrylate, stilbene (mercapto) acrylate, decyl acrylate, decyl (meth) acrylate, adamantyl (mercapto) acrylate, (fluorenyl) acrylate Dimethyl hydroxycarbonate, tricyclo[5.sup.2,6,6] fluorenyl-8-yl (meth) acrylate, tricyclo[5 2 〇 6 2 6] - an alicyclic skeleton such as decyl ester, cyclomethacrylate (meth) acrylate, 2_(indenyl) propylene oxiranyl ethyl hexahydrophthalic acid, or butyl cyclohexyl acrylate; Hydroxyl-terminated polyalkylene glycol mono(indenyl) such as ethylene glycol mono(meth)acrylic acid vinegar, polypropylene glycol mono(methyl) acrylate, poly(ethylene glycol-propylene glycol) monomethacrylate Acrylic acid S; methoxy polyethylene glycol monomethacrylic acid, lauryloxy polyethylene glycol mono (meth) acrylate, octyloxy polyethylene glycol polypropylene glycol mono (meth) acrylate, Nonylphenoxy polyethylene glycol monoacrylic acid vinegar, 155912.doc 8 *22· 201213450 Nonylphenoxypolypropylene glycol monoacrylate, allyloxy polyethylene glycol_polypropylene glycol mono(methyl) Alkyl-terminated polyalkylene glycol mono(meth)acrylic acid vinegar such as acrylate, 2-aminoethyl acrylate S|, 2-aminoethyl methacrylate, 2-aminopropyl acrylate Aminoalkyl acrylates such as 2-aminopropyl methacrylate, % aminopropyl acrylate, 3-aminopropyl methacrylate, etc.; glycidyl acrylate, glycidyl methacrylate , (3)-butylene butyl (meth)acrylate, (meth)acrylic acid, 4_epoxycyclohexyl)methyl ester, (meth)acrylic acid 4-hydroxybutyl ester glycidyl ether and other unsaturated carboxylic acid shrinkage Glycerides; vinyl acetates such as vinyl acetate, vinyl propionate, vinyl butyrate, vinyl benzoate; vinyl ether ether Unsaturated anthracenes such as vinyl ether, allyl glycidyl hydrazine, methyl propyl glycidyl ether; cyanoethylene compounds such as acrylonitrile, methacrylonitrile, α-chloroacrylonitrile, and dicyanoethylene; Amine, methacrylamide, α_aepine amide, Ν-phenyl maleimide, Ν-cyclohexyl maleimide, Ν_(fluorenyl) propylene phthalate Unsaturated guanamine or unsaturated subsulphate such as formazan, hydrazine-(2-hydroxyethyl) acrylamide, hydrazine-(2-hydroxyethyl) methacrylamide, maleimide or the like Amines; aliphatic conjugated dienes such as 1,3-butadiene, isoprene, gas butadiene; polystyrene, polyacrylic acid methacrylate, polymethyl methacrylate, polybutyl acrylate A polymonomer such as polybutyl methacrylate or polyfluorene ketone having a monopropenyl fluorenyl group or a monomethacryl fluorenyl group at the end of the polymer molecular chain. These unsaturated monomers may be used alone or in combination of two or more. Further, a polymer in which an unsaturated double bond is further introduced into a side chain of the copolymer is also useful. For example, a cis-sebacic acid needle of 155912.doc -23-201213450 polymer for maleic anhydride and copolymerizable styrene, vinyl phenol, acrylic acid, acrylate, acrylamide, etc. a compound which is subjected to a half esterification by reacting an acrylic acid acetoacetate having an alcoholic hydroxyl group such as hydroxyethyl acrylate or glycidyl methacrylate, which has an alcoholic hydroxyl group; and for acrylic acid or acrylic acid. A compound obtained by reacting a hydroxyl group of a copolymer of an acrylate having an alcoholic hydroxyl group such as an ethyl acrylate with an acrylic acid to cause an acrylic acid to react. Further, an amino phthalate resin, a polyamide, a polyimide resin, a polyester resin, a commercially available ACA-200M (manufactured by Daicel), 〇RGA-3060 (manufactured by Osaka Organic Chemicals), or AX3- may also be used. BNX02 (Japan Catalyst Manufacturing), UXE_3024 (Nippon Chemical Manufacturing), UXE-3000 (Nippon Chemical Manufacturing), ZGA-287H (Nippon Chemical Manufacturing), TCR-1338H (Nippon Chemical Manufacturing), zxr_1722h (Japanese) Pharmaceutical manufacturing), ZFR-1401 H (manufactured by Sakamoto Chemical Co., Ltd.), zCR-1642 (manufactured by Sakamoto Chemical Co., Ltd.). A dispersant or dispersing aid is usually used in dispersing the pigment. There are a dye-based dispersant, a resin-based dispersant, an surfactant, and the like which have good adsorptivity to a pigment. For example, as a dye-based dispersant, the following method is known as a known technique: a method of mixing a sulfonate of a pigment or a metal salt thereof with a pigment, or a mixed-substituted amino mercapto derivative, as in the above-mentioned Patent Document 4 Method and so on. The resin-based dispersant is also a non-polar non-ionic one. However, it is usually a polymer resin having an acid value and an amine value which impart good pigment adsorption properties, and examples thereof include an acrylic resin and a polyamino phthalate resin. , polycarboxylic acid, polyamide resin, polyester resin, and the like. Specific examples thereof include ED211 (manufactured by Nanben Chemical Co., Ltd.) and Ajisper pB821 (Ajin〇m〇t〇).

Manufactured by Fine-Techno), s〇lsperse 71000 (manufactured by Avecia). In the case of producing a binder resin (copolymer) used in the present invention, a polymerization initiator is used for 155912.doc 24 8 201213450. Here, specific examples of the polymerization initiator used in the synthesis of the copolymer include, for example, α,α,_azobis(isobutyronitrile), 2 2,_azobis(2-mercaptobutylene). Nitrile), butyl octanoate, tri-tert-butyl peroxide, benzoquinone peroxide, methyl ethyl hydrazine peroxide, and the like. The use ratio of the polymerization initiator is 0. (Η25 parts by mass) based on the total amount of all the monomers used in the synthesis of the copolymer. Further, in the case of synthesizing the copolymer, it is preferred to use the following The organic solvent is described, but it has to be sufficiently solvable for the monofunctional monomer or polymerization initiator used, etc. The reaction temperature for synthesizing the copolymer is preferably 5 〇 to 12 〇t, particularly preferably 8〇~1〇代。 Further, the reaction time is preferably the hour of Bu, more preferably 3~2〇小日寺. The preferred acid value of the copolymer is 10~3〇〇(mgK〇H/g), A preferred value of H) is 2 〇〇 (mgKOH/g). When the acid value or the value of the value is below the value, the visibility decreases. The weight average molecular weight (Mw) of the copolymer is preferably 2_~__, more preferably 3_~coffee (9). When the weight average molecular weight is 2,000 or less or 4 Å or more, the sensitivity and developability are lowered. In the present invention, the above-mentioned point resin may be used alone or in combination of two or more. The content of the binder resin of the present invention is usually 〇5 to 99 parts by mass, and 5 to 5 parts by mass, based on the total solid content (10) parts by mass of the colored resin composition. In this case, the content of the resin is not Up to 0.5 parts by mass' is a case where the developability is lowered or a problem such as a smear or a residual film in a region other than the portion where the pixel is formed is formed. Column: = 2: a hardener used, in the case of radical polymerization In the case of ion hardening, an epoxy tree may be mentioned. In the case, a trimeric amine hardener may be mentioned. Specific examples of these may be 155912.doc -25 - 201213450. (Methyl) 2-hydroxyethyl acrylate, 2-hydroxypropyl (meth) acrylate, 2-ethylhexyl (meth) acrylate, ethylene glycol di(decyl) acrylate, diethylene glycol di(methyl) Acrylate, triethylene glycol (mercapto) acrylate, tetraethylene glycol (meth) acrylate, trishydroxypropyl propane tri (meth) acrylate, pentaerythritol di (meth) acrylate, pentaerythritol three ( Methyl) acrylate, pentaerythritol tetrakis(fluorenyl) acrylate , dipentaerythritol hexa(meth) acrylate 'glycerol (meth) acrylate, bisphenol A type epoxy bis(indenyl) acrylate, bisphenol F type epoxy bis(indenyl) acrylate, bisphenol oxime Epoxy bis(meth)acrylate vinegar, ethoxylated trimethylolpropane tri(meth) acrylate, propoxylated trimethylol propyl tris(decyl) acrylate, ethoxylated glycerol tris(sulfonate) Acrylate, ethoxylated isocyanuric acid tris(meth) acrylate, bis(trihydroxymethyl propyl propyl) tetra(meth) acrylate, pentoxide tetraol tetrakis(meth) acrylate, 9, 9-bis[4-(2-propanyloxyethoxy)phenyl] hydrazine, Kayarad RP-1040 (manufactured by Nippon Kayaku Co., Ltd.), Kayarad DPCA-30 (manufactured by Sakamoto Chemical Co., Ltd.), UA-3 3H (New Nakamura Chemical Manufacturing), UA-53H (Naka Nakamura Chemical Manufacturing Co., Ltd.), M-8060 (manufactured by Toyo Chemical Co., Ltd.); TEMPIC (manufactured by Nippon Chemical Co., Ltd.), TMMP (manufactured by Nippon Chemical Co., Ltd.), PEMP (as a thiol-based polymerization monomer)堺Chemical manufacturing), DPMP (manufactured by 堺Chemicals); NC-6000, NC-6300, NC-3000, EOCN- as the Japanese chemical products for epoxy resins 1020, XD-1000, EPPN-501H, BREN-S, NC-7300L, Celloxide 2021P, EHPE3150 from Daicel Chemical Products Cyclomer M100, Epolead PB3600, Epikote 828, Epikote YX8000, Epikote YX4000, VG -3101L (manufactured by Printec), Sila-Ace S510 (manufactured by Chisso) 'TEPIC (manufactured by Nissan Chemical Industries) 155912.doc .26- 8 201213450 etc. 'Methylated trimeric amine or Mw_3〇 as a melamine hardener Sanwa Chemical Manufacturing) and so on. These may be used alone or in combination of two or more. The amount of the three components is from 1 to 80 parts by mass, preferably from 5 to 30 parts by mass, per part by mass of the total solid content of the colored resin composition. Among the above-mentioned curing agents, an epoxy resin represented by the following formula (3) having a glycidyl group G is particularly preferable in terms of improvement in solvent resistance. [Chemical 4]

G (3) In the formula (7), Rlc to Rl9c are each independently a hydrogen atom, a ci_ci2 alkyl group, a ci-c12 oxy group, a # atom atom 'the + is preferably a hydrogen atom, a methyl group, an ethyl group or an A group. Any of the oxy groups, particularly preferably, is a hydrogen atom and R19c is an F group. The epoxy tree gambling of the above formula (7) is, for example, by using (4)-based "methyl phenyl phenyl ketone" and (d) (unsubstituted or having (1) burnt soil, CI-C12 oxy, _ A reaction of a phenol resin obtained by substituting a phenol resin and an epihalohydrin (at least I55912.doc -27-201213450 selected from the group consisting of a gas alcohol and a performance alcohol) is produced as a main component. Examples of the product include VG-3101L manufactured by Printec, NC-6000 of Nippon Chemical Co., Ltd., NC-6300, etc. The content is 1 to 80 parts by mass based on 100 parts by mass of the total solid content of the colored resin composition. In the case of less than the above range, the effect of solvent resistance or the like is lowered, and when the amount is too large, the developability is lowered and development is impossible, which is not preferable. The epoxy resin is hardened, and it is preferable to use a hardening accelerator together. As the hardening accelerator used in the present invention, it is necessary to promote a reaction catalyst for ion hardening, and examples thereof include amines of the first to third grades or nitrogens such as imidazole. Heterocyclic compound, photoacid generator or acid produced by acid a raw material, a resin having an acid anhydride or a carboxylic acid, an acrylate monomer, a starter, etc. The resin, the monomer, and the like having a carboxylic acid are as described above, and the polymerization initiator will be described below. Specific examples of the amines include triethylamine, triethanolamine, Kayahard AA, Kayabond C-100, Kayabond C-200S, Kayabond C-300S, etc. as a specific example of sitting at 0 m. List: Curezol 2MZ-H, Curezol C11Z, Curezol C17Z, Curezol 1, 2DMZ, Curezol 2E4MZ, Curezol 2PZ, Curezol 2P4MZ, Curezol 1B2MZ, Curezol 1B2PZ, Curezol 2MZ-CN, Curezol Cl 1Z-CN, Curezol 2E4MZ-CN ' Curezol 2PZ-CN > Curezol C11Z-CNS ' Curezol 2PZCNS-PW, Curezol 2MZ-A, Curezol C11Z-A, Curezol 2E4MZ-A, Curezol 2MA-OK, Curezol 2PZ-OK, Curezol 2PHZ-PW , Curezol 2P4MHZ-PW, Curezol TBZ, Curezol 2PZL-T, Curezol VT, Curezol SFZ, etc. As an acid anhydride 155912.doc • 28 · 8 201213450 Specific examples _, can be cited · · maleic acid liver, station anhydride Ortho-benzene &qu Ot; by the needle, tetraphthalic anhydride, pyromellitic acid needle, biphenyl tetraacid, two needles, the heart of the chemical products. Hey. Among these, a hardening accelerator of imidazole is preferred, and Cu(10) is preferable in terms of reactivity! Mm, =reZ〇l 2PZ, CurezoI 1B2MZ, Curez〇l. The cerium is preferably 〜 〇 5 to 2 parts by mass with respect to the total solid content i 〇〇 by mass of the colored resin composition. In less cases, the hardening property is lowered, and in the case of too much, the storage stability is lowered. The pigment which can be used in combination in the colored resin composition of the present invention is preferably one having a spectral characteristic suitable for a color calendering sheet, and may be appropriately selected from dyes, organic pigments or inorganic pigments, and may be used singly or in combination as needed. The content of the above-mentioned lyophile or the like is 0 to 60 parts by mass, preferably 5 to 30 parts by mass, based on the total solid content of the colored resin composition. These various pigments and dyes are shown below. The organic pigment which can be used in combination in the present invention is not particularly limited, and examples thereof include a brewing system, a brewing phthalocyanine, a benzophenanthrene group, a quinacridone system, and an azo chelate. System, azo, isoporphyrin, isoindolinone, dermatone, indanthrene, pyrithion, dibromofluorenone, vaginal, lanthanide Pigments such as piperidone, quinophthalone, thioindigo, diterpene, quinacridone, and dibenzopyran; acid dyes, basic dyes, direct dyes, etc., using various precipitating agents Insoluble precipitated lake pigment, dyed lake pigment, etc. More specifically, 'the dye index can be exemplified by: pigment blue b 1:2, 9, 14, 15, 15:1, 15:2, 15.3, 15:4, 15:6, 16, 17, 19, 25, 27, 28, 29, 33, 35, 36, 155912.doc -29· 201213450 56Λ 60 . 61 . 61:1 ^ 62 > 63 ^ 66 > 67 ' 68 ' 71 > 72 > 73, 74, 75, 76, 78, 79; Pigment Purple Bu 1: Bu 2, 2: 2, 3, 3: 3, 5, 5: Bu 14, 15 , 16, 19, 23, 25, 27, 29 31 32, 37 39, 42, 44, 47, 49, 50; Violet 3 '4,27,39 like. Especially the pigment blue is 15.6 哎嚭 coarse sand, so it is better. 5_6, 枓 枓 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 , titanium oxide, barium sulfate, # & blue, oxidized, yellow, iron, ultramarine, iron and zinc, = white, iron black, ship Dan, sulfuric acid, tin yellow, money red, compound dicobalt, Metal oxides such as barium sulfate and magnesium carbonate, metal sulfides, sulfates, metal hydroxides, metal carbonates, and the like. As the towel of the present invention, it can be used in combination (4), and there are no (4) restrictions on acid dyes, alkaline materials, bismuth dyes, sulphur dyes, anthraquinone dyes, naphthalene plants, reactive dyes, disperse dyes, and the like. However, as long as the agent is the agent, the dye is insoluble in the organic solvent, and is suitably used as a dispersion.曰 Regarding the above-mentioned dyes insoluble in organic solvents, it is known as an acid compound (for example, n-propylamine, ethyl A A 吏 organic), for example, in the case of an acid dye or an artificial dye.

The amine is converted to an amine by a reaction such as: 4, or a dye which is modified by the reaction of the organic amine compound with the acid-reducing group and which has an amine group. These amine-modified dyes can also be used in the colored resin composition of the present invention. For example, Η乍 is a specific dye', and the dye index can be exemplified by solvent blue 2, 3, 4, 5, 6, 23, 35, 36, 37, 38, J559I2.doc 201213450 43, 48, 58, 59 , 67, 70, 78, 98, 102, 104; Basic Blue 7; Acid Blue 8〇, 83, 90; Solvent Violet 8, 9 as purple dye; Violet 4, 5, 14; Alkaline Violet 1 . The photopolymerization initiator to be added to the colored resin composition of the present invention used in the photolithography method is preferably one which is sufficiently sensitive to ultraviolet rays emitted from an ultrahigh pressure mercury lamp which is generally used as an exposure light source. A radically polymerizable photoradical initiator, an ionic hardening photoacid generator, a photobase generator, and the like can be given. In the photopolymerization, a component of a polymerization accelerator called a sensitizer which is hardened by a less exposure period can be used in combination. The photopolymerization initiator which can be used is not particularly limited, and specific examples thereof include: a streptoethylenedione, a benzoin mystery, a benzoin, a benzoin, a benzophenone, a 3,3'-dimethyl Esterified product of 4-methoxybenzophenone, benzoylbenzoic acid, benzhydrazinobenzoic acid, 4-phenylindoleyl-4,-methyldiphenyl sulfide, presently曱 缩 _, 2-butoxyethyl-4-mercapto phenyl phthalate ' chloro-9-oxopurine p star, fluorenyl-9-oxysulfur p mountain p star, ethyl _9 _Oxathiazepine, isopropyl-9-oxosulfur p-p-star, di-mercapto-9-oxopurine p-star, diethyl oxysulfonate P-star, diisopropyl-9-oxo-sulfur-u P-star, dimethylaminomethyl benzoate, 1-(4-dodecylphenyl)-2-hydroxy-2-mercaptopropan-1-one, 1-hydroxycyclohexyl phenyl ketone, 2- Hydroxy-2-mercapto-1-phenylpropan-1-one, 1-(4-isopropylphenyl)_2-hydroxy-2-mercaptopropyl-1-one, benzamidinecarboxylic acid 2-mercapto_ι_(4_曱thiophenyl)-2-zolinylpropan-1-one, 2-benzyl-2-didecylamino 4-(4-imidylphenyl) -butanone-1,2,4-bis(trichloroindenyl)-6-(4-methoxyphenyl)_ι,3,5 - three tillage, 2,4,6-tris(trichloroindenyl)-1,3,5_ three-plowed, 2,4-bis(tribromoindolyl)-6-(4'-decyloxy Phenyl)-1,3,5-all Mitsui, 2,4,6-three (three deserts 155912.doc -31 - 201213450 base)-1,3,5·all three tillage, 2,4-double ( Triseocarbyl)-6-(1,3-benzodioxolan-5-yl)-1,3,5-all three tillage, dibenzophenone, benzoquinonephthalic acid, 1- (4-phenylthiophenyl)butane-1,2-dione-2-mercapto-0-benzoate, 1-(4-methylthiophenyl)butane-1,2 -dione-2-indenyl-indole-acetate, 1-(4-mercaptothiophenyl)butan-1-one oxime-indole-acetate, 4,4'-double (diethyl Aminopheny)benzophenone, p-nonylaminophenylphosphonium isoamyl ester, p-dimethylaminobenzoic acid ethyl ester, 2,2'-bis(o-chlorophenyl)-4,4 ·, 5,5'-Tetraphenyl-1,2'-biimidazole, Diazoxan S-series initiator, and commercially available Kayacure DMBI, Kayacure BDMK 'Kayacure BP-100, Kayacure BMBI, Kayacure DETX- S, Kayacure EPA (all manufactured by Sakamoto Chemicals), Darocure 1173, Darocure 1116 (all manufactured by Merck Japan), Irgacure 907 (made by B ASF Japan), Irgacure 3 69 (manufactured by B ASF Japan), Irgacure 379EG (manufactured by BASF Japan), Irgacure OXE-01 (manufactured by BASF Japan), Irgacure OXE-02 (manufactured by BASF Japan), Irgacure PAG103 (manufactured by BASF Japan), TME-Triazine (Sanwa) Chemically produced), biimidazole (manufactured by Heijin Chemical Co., Ltd.), STR-110, STR-1 (all manufactured by Respe Chemical), and the like. In the case of a thermosetting resin composition used in an inkjet method or the like, a thermal polymerization initiator is usually used, and a photopolymerization initiator may be used in combination as needed. Examples of the thermal polymerization initiator include an azo compound or an organic peroxide. Examples thereof include 2,2'-azobisisobutyronitrile and 2,2'-azobis (2,4-di). Methyl valeronitrile), 2,2 匕 azobis(2-methylbutyronitrile), di-tert-butyl peroxide, benzoyl peroxide, cumene peroxy neodecanoate, and the like. These polymerization initiators may be used singly or in combination as needed to have a content of 155912.doc · 32· 8 201213450. The content of the above is 0.5 relative to the total solid content of the colored resin composition. 〜50 parts by mass, preferably 丨25 parts by mass. The organic solvent used in the present invention can be used as a binder resin, a photopolymerizable monomer, a photopolymerization initiator or the like as a constituent component of the colored resin composition, and is used for the synthesis of the binder resin. A single B energy monomer or a polymerization initiator or the like also has sufficient solvency. Further, in the case of producing a pigment dispersion, those which can ensure dispersion stability can also be used. The organic solvent to be used in the present invention is not particularly limited as long as it can be used, and specific examples thereof include benzenes such as benzene and toluene 'xylene; methyl cardia, ethyl cellosolve, and butyl cellosolve. Solvents such as agents; methyl ketone acetate vinegar, ethyl cellosolve acetate vinegar, butyl cellosolve acetate vinegar and other cellosolve acetate vinegar; propylene glycol monomethyl acetate vinegar, propylene glycol monoethyl acetate Propylene glycol, such as propylene glycol monobutyl acetate, etc. (4) acetic acid vinegar; methyl methoxypropionate, ethyl methoxypropionate, methyl ethoxypropionate, ethyl ethoxy propionate, etc. Esters; lactic acid vinegar such as methyl lactate, ethyl lactate, lactic acid butyl vinegar, etc., diethylene glycol monoterpene, diethylene glycol, monoethylidene and other di-ethyl alcohols [acidic g, acetic acid An ester such as ester or butyl acetate; an ether such as dioxane, diethyl ether, tetrahydrofuran or di-p-alkane; a ketone such as acetone, mercaptoethyl ketone 'methyl butyl ketone or cyclohexanone; methanol; Alcohols such as ethanol, butanol, isopropanol and benzyl alcohol. These may be used alone or in combination of two or more. Further, the amount of the organic solvent to be used is preferably from 40 to 10,000 parts by mass, more preferably from 100 to 1,000 parts by mass, per part by mass of the total solid content of the colored resin composition. The colored resin composition of the present invention is a toughening resin, a curing agent, a photopolymerization initiator, a specific dye-based coloring material compound, or the like by a dispersing mixer or a homogenizing 155912.doc •33·201213450 machine. It is produced by mixing and stirring an organic solvent. Further, other pigments or dyes may be added as needed, but in the case of a pigment or a dye having a low solubility, the dispersion is obtained by a coating machine using a suitable dispersing agent, and added to the coloring. The resin composition is mixed. Further, various additives such as a filler, a surfactant, a thermal polymerization inhibitor, a adhesion promoter, an antioxidant 'ultraviolet absorber, an anti-agglomerating agent, and the like can be further added to the colored resin composition of the present invention. Further, the colored resin composition of the present invention may be subjected to microfiltration or the like after the preparation thereof to remove impurities or the like. Next, a method of preparing a cured product from the colored resin composition of the present invention will be described. First, 'on a substrate such as a glass substrate or a tantalum substrate, a film thickness is 0 by using a spin coating method, a roll coating method, a slit and a spin method, a die coating method, a bar coating method, or the like. G 5~5 is applied in the manner of coating the colored resin composition of the present invention, if necessary, in a decompression chamber, with a drying bar of 23 to 150 C and a time of 1 to 6 minutes, more preferably 120C. The mixture was dried under reduced pressure for a period of time (7), and then subjected to a baking treatment by a hot plate or a clean baking (4) (4). Then, the radiation is irradiated through a specific reticle pattern by a usual photolithography method (for example, an electron beam or an ultraviolet ray, a wire, preferably ultraviolet ray), and an aqueous surfactant solution, an alkaline aqueous solution, or a surfactant and an alkali agent are used. A mixed aqueous solution is used for the shirt. In the development method, there may be any combination of the dipping method, the spraying method, the spraying method, the mixing method, the chopping U, and the like. After the removal of the day by the development: the shot, and rinsed with water, the post-baking treatment, the treatment;; 1559l2.doc • 34- 201213450, such as at a temperature of 13 〇 ~ 300t and time minutes, more preferably The temperature was 150 25 GC and the time was 1 to 3 Torr, and the pixel including the colored cured film of the present invention was obtained. As the above-mentioned "material surfactant", a polyoxyethylene compound base and a polyoxyalkylene base material can be used. Further, as a test, it is possible to use (iv) sodium, potassium carbonate, sodium hydroxide, potassium hydroxide, diethanolamine or tetramethyl hydroxide. In the present invention, it is preferred to use an aqueous solution containing both an alkali agent and a surfactant. The development is carried out at a treatment temperature of usually 10 to 5 (rc, preferably 2 to 4 Torr) at a treatment temperature of usually 30 to 600 seconds, preferably 30 to 12 seconds. The cured product of the resin composition is useful as a color filter suitable for a solid-state imaging device used in a liquid crystal display device, an organic EL display, a digital camera, or the like, the color filter having the present invention prepared in the above manner The patterned pixel of the cured product of the colored resin composition. In the display device of the present invention, the liquid crystal display device is, for example, sequentially laminated with a light source, a polarizing film, a display electrode, a liquid crystal, an alignment film, and a common electrode. The organic EL display is produced by forming the color filter of the present invention on the upper or lower surface of the multilayer organic light-emitting element. Further, the organic EL display is produced by forming a color filter such as a color light-emitting film or a polarizing film. The solid-state imaging device is produced by, for example, providing a color filter layer of the present invention on a wafer on which a transfer electrode and a photodiode are provided, and then laminating a microlens. [Example] The present invention will be described in more detail by the following examples, but the present invention is not limited by the examples. The spectrophotometer "Shimadzu Corporation" υν_315〇ϋ 155912.doc •35-201213450 measures the spectral transmittance characteristics and calculates In the chromaticity of the XYZ color system, the heat resistance and contrast of the colored body were evaluated. Synthesis Example 1 Rose red enamel (manufactured by Tokyo Chemical Industry Co., Ltd.) lg, water 20 g' in the following formula (101) was added to a 100 ml beaker. The mixture was dropped for 30 minutes at room temperature, and a solution of 1 g of a cerium salt dissolved in trifluoromethane (TFSM) in 1 g of DMF was added dropwise thereto for 3 hours. The precipitated dye was collected by filtration. The mixture was washed with water and dried to obtain TFSM salt of Rose Bengal B (Compound No. 1) 7.7 g. Maximum absorption wavelength: 56 〇 nm (cyclohexanone) [Chemical 5]

(101) Synthesis Example 2 Rose red B i g of the above formula (101) and water 2 g were added to a 100 ml beaker, and the mixture was stirred at room temperature for 30 minutes. A solution of 1 g of potassium salt of bis-difluorodecylsulfonimide (TFSI) dissolved in DMF j g was added thereto, and stirred for 3 hours.

Dry and obtain Rose Red B. Filter out the precipitated dye and wash it with water? 51 salt (compound) ^ 〇. 2) 0.7 §. Maximum absorption wavelength: 560 nm (cyclohexanone) Synthesis Example 3 155912.doc -36 - 8 201213450 Adding the above-mentioned formula (ιοί) to the 2000 ml beaker, adding 4 g of water (750 manufactured by Tokyo Chemical Industry Co., Ltd.), water 750 g , stir at room temperature for 3 minutes. A solution of lithium salt of fluoromethylsulfonic acid (5 g) dissolved in water 10 gt was added thereto, and the mixture was stirred for 3 hours. The precipitated dye was collected by filtration, washed with water, and dried to obtain 3.5 g of trifluorosulfonate (Compound N..) of Rose Bengal B. Maximum absorption wavelength: 560 nm (cyclohexanone) Synthesis Example 4 Basic Blue 7 of the following formula (100) (Basic Blue 7, manufactured by Tokyo Chemical Industry Co., Ltd., decomposition temperature: 217. 2 parts of the solution was dissolved in 150 g of water. Adding a solution of 3 _ 1 g of tris-trifluorosulfonylsulfonyl hydrazide dissolved in 30 g of acetonitrile while mixing. After 3 hours of mixing, the precipitated crystals were collected by filtration and washed with water. Dry to obtain a basic blue 7 TFSM salt (compound g. Maximum absorption wavelength: 610 nm (cyclohexanone) [Chem. 6]

Synthesis Example 5 7 parts of the basic blue of the above formula (100) was dissolved in water 15 § §, while stirring 155912.doc • 37·201213450, one side was added to the water, and the bis-trifluoromethane group was dissolved. After the mixture was stirred for 3 hours, the precipitated crystals were collected by filtration, washed with water and dried to obtain 0.7 g of TFSI salt (Compound No. 2-2) of Basic Blue 7. Maximum absorption wavelength: 61 0 nm (cyclohexanone) Synthesis Example 6 2 g of Basic Blue 7 (manufactured by Tokyo Chemical Industry Co., Ltd., decomposition temperature: 217 C) of the above formula (100) was dissolved in water i5 〇g, and stirred while stirring. In the water 1〇g, the solution of the solution of difluoroanthryl acid continued to be a salt solution of 8 g. After the mixture was stirred for 3 hours, the precipitated crystals were collected by filtration, washed with water and dried to obtain 0.8 g of a dichlorohexanoate (Compound No. 2-3) of m. Maximum absorption wavelength: 610 nm (cyclohexanone) Synthesis Example 7 [Chemical 7] + ^ (102) (1) 1-Cai Cai (10.0 g, 0 〇5 m〇1), 2-methylcyclohexylamine ( 6 〇g, 〇〇5 mol), sodium dibutylate (6 5 g, 〇〇7 m〇1), pd2(dba)3 (same 〇〇〇3 eq_), BINAP (same as 0·008 eq Dissolved in 12 Torr of toluene and stirred at 8 Torr for 3 hours. Thereafter, the reaction liquid was returned to room temperature, and the reaction liquid was subjected to column filtration, and the filtrate was distilled off under reduced pressure, whereby the above formula (1〇2) 1 〇 5 g (9 l%) was obtained. Synthesis Example 8 155912.doc 8 •38- 201213450

(2) The compound 102 (9·3 g, 0·04 m〇i) obtained in Synthesis Example 7 and 4,4··bis(diethylamino)benzol were dissolved in 50 ml of toluene. A mixed solution of a ketone (115 g, 0.04 mol) and a phosphonium gas (6 〇g, 〇〇4 m〇1) was reacted at 6 Torr for 3 hours. After returning to room temperature, water was added for liquid separation, and the organic layer was concentrated under reduced pressure, whereby 22.8 g (98%) of the above formula (3) was obtained. Synthesis Example 9 (3) The compound 1〇3 (3 〇g, 〇.〇〇5 m〇1) obtained in Synthesis Example 8 was dissolved in a mixed solution of 10 ml of water and 40 ml of decyl alcohol. A solution of 2.8 g of a tri-trifluoromethanesulfonylsulfonyl sulfonate salt was dissolved in a mixed solution of 3 ml of DMF and 20 ml of decyl alcohol. After heating and stirring at 60 ° C for 3 hours, the precipitated crystals were collected by filtration, washed with water, and dried to obtain a compound.

No.2-20 3.2 g. Maximum absorption wavelength: 602 nm (cyclohexanone) Synthesis Example 10 155912.doc •39· 201213450 [Chemical 9]

In a flask equipped with a stirrer, a reflux condenser, and a stirring device, a trifunctional phenol compound 104 (Tris P-PA manufactured by Honshu Chemical Industry Co., Ltd.) 141.5 g, a surface gas alcohol 463 g, and a diterpenoid hydrazine were added while purifying nitrogen gas. 95 g, dissolved under stirring, and warmed to 45 °C. Then, 41 g of scaly sodium hydroxide was added in portions over 90 minutes, and further to 45. The reaction was carried out for 5 hours under the arm, and the reaction was carried out at 60 ° C for 2 hours. After completion of the reaction, water was washed with 50 〇 g of water. The solvent such as excess surface alcohol was distilled off from the oil layer under reduced pressure using a rotary evaporator. To the residue was added hydrazine isobutyl ketone 5 〇〇 g and dissolved to raise the temperature to 70 °C. After adding 10 g of a 30% by mass aqueous sodium hydroxide solution under stirring, the reaction was carried out for 1 hour, and then washed with water until the washing water of the oil layer became neutral. 'A solution was obtained from the obtained solution under reduced pressure using a rotary evaporator. The isobutyl ketone or the like was distilled off, whereby an epoxy resin (1〇5) of 19 〇g was obtained. The obtained epoxy resin had an epoxy equivalent of 2〇1 g/eq and a softening point of 59β (: Synthesis Example 11 (Preparation of Adhesive Resin (Copolymer)) Methyl B was added to a 500 ml four-necked flask. Base _16 〇 g, 曱 丙烯酸 丙烯酸 曱 曱 曱 曱 曱 曱 33 33 33 33 33 33 33 33 33 33 33 33 33 33 33 33 33 33 33 , , , , , , , , , , , , , , , , The temperature was raised to 8 ° C, and the mixture was directly mixed for 4 hours at 80 to 85 C. After the reaction was completed, it was cooled to room temperature and 1559 l 2 .doc 8 -40 to 201213450 to obtain a colorless transparent and uniform copolymer solution. The mixture of propanol and water is precipitated and filtered, and the solid component is taken out and dried to obtain a copolymer (Α). The obtained copolymer (a) has a weight average molecular weight of 18,000 in terms of polystyrene. Acid value: 152» Example 1 As a photopolymerization initiator, a copolymer of 5·5 g as a binder resin and Kayarad DPHA (manufactured by Sakamoto Chemical Co., Ltd.) as a photopolymerizable monomer

Irgacure 907 (manufactured by BASF Japan) 1.5 g, Irgacure 〇XE-02 (BASF

Made in Japan) 0.3 g and Kayacure DETX-S (manufactured by Sakamoto Chemical Co., Ltd.) 0·6 g, Compound No. l of Synthesis Example 1 0.3 g, Compound of Synthesis Example 4 νο·2_ι 〇 3 g, as a solvent ring The ketone 20 g and propylene glycol monomethyl ether acetate 8 6 g were separately mixed to obtain the colored resin composition of the present invention. Example 2 A composition similar to that of Example 1 was set except that the compound No. 2-1 of Synthesis Example 4 was changed to the compound No. 2-2 of Synthesis Example 5 to obtain a colored resin composition. (Example 3) A composition similar to that of Example 1 was set except that the compound No. 2-1 of Synthesis Example 4 was changed to the compound No. 2-3 of Synthesis Example 6, and a colored resin composition was obtained. (Example 4) A composition similar to that of Example 1 was set except that the compound No. 1 of the synthesis example 1 was changed to the compound No. 2 of the synthesis example 2, and the colored resin composition was obtained. 155912.doc -41·201213450 Example 5 except that the compound of Synthesis Example 1 was changed to No. 1 and changed to the compound of Synthesis Example 3.

Other than No. 3, the composition was the same as that of the Example, and a colored resin composition was obtained. Example 6 Using CI Pigment Blue i5:6/Ajisper pB821/s〇lsperse 5〇〇〇/pGMEA (Propylene Glycol Methyl Ether Acetate, Propylene Glycol Monomethyl Ether Acetate) = 15.0/6.0/1·0/78.0 (Quality After mixing the composition ratio, 〇3 mm of cerium oxide beads 400 g' was added and treated with a paint shaker for 6 minutes and filtered, thereby obtaining a blue pigment dispersion 1 ^ 22 g of blue was added to Example i Color Pigment Dispersion 1 'The colored resin composition of the present invention was obtained. (Example 7) A colored resin composition was obtained except that the compound of Synthesis Example 4 was changed to the compound No. 2-2 of Synthesis Example 5, and the composition was the same as that of Example 6. (Example 8) A composition similar to that of Example 6 was set except that the compound No. 2-1 of Synthesis Example 4 was changed to the compound No. 2-3 of Synthesis Example 6, and a colored resin composition was obtained. (Example 9) A composition similar to that of Example 6 was prepared except that the compound No. 1 of Synthesis Example 1 was changed to the compound No. 3 of Synthesis Example 3, and a colored resin composition was obtained. Example 10 155912.doc •42·201213450 A composition similar to that of Example 6 was obtained except that the compound Νο·2-1 of Synthesis Example 4 was changed to the compound Ν〇·2-20 of Synthesis Example 9, and a colored resin was obtained. combination. Example 11 A setting was made except that the adhesive copolymer (Α) was set to 2.4 g, and 3.0 g of the epoxy resin 105 of Synthesis Example 10 was used as a curing agent, and 0.1 g of 1B2PZ (manufactured by Shikoku Chemicals Co., Ltd.) was used as a hardening accelerator. For the same composition as in Example 6, a colored resin composition was obtained. Example 12 The adhesive copolymer (A) was set to 2.4 g, and 3.0 g of the epoxy resin 105 of Synthesis Example 1 was used as a hardener, and 1 g of 1B2PZ (manufactured by Shikoku Chemical Industries Co., Ltd.) was used as a hardening accelerator. The composition similar to that of Example 1 was set except that the colored resin composition was obtained. Comparative Example 1 The same composition as in Example 1 was obtained except that the compound No. 2-1 of Synthesis Example 4 described in Example 1 was not used, and the compound No. 1 of Synthesis Example 1 was set to 0.6 g. A colored resin composition. Comparative Example 2 except that the compound No. 1 of Synthesis Example 1 was changed to the compound of Synthesis Example 2.

Other than No. 2, the composition was the same as that of Comparative Example 1, and a colored resin composition was obtained. Comparative Example 3 A composition similar to that of Comparative Example 设定 was prepared except that the compound No. 1 of Synthesis Example 1 was changed to the compound of Comparative Example 3, ,ο·3, to obtain a colored resin group 155912.doc • 43-201213450. Comparative Example 4 A colored resin composition was obtained in the same manner as in Comparative Example 1, except that the compound No. 1 of Synthesis Example 1 was changed to Rose Red b. Comparative Example 5 A composition similar to that of Comparative Example 1 was set except that the compound No. 1 of Synthesis Example 1 was changed to Basic Blue 7, and a colored resin composition was obtained. Comparative Example 6 The compound of Compound No. 1 and Synthesis Example 4 of Synthesis Example 1 was used.

Other than No. 2-1, the composition was the same as that of Example 6, and a colored resin composition was obtained. Comparative Example 7 A composition similar to that of Example 6 was set except that the compound No. 1 of Synthesis Example 1 and the compound N〇 2_1 of Synthesis Example 4 were changed to 0.6 g of Basic Blue 7, and a colored resin composition was obtained. The colored resin composition obtained above (the embodiment was applied to the above substrate, and 8 was used after the pre-baking under conditions of TC x 100 seconds, after the photomask was hardened by exposure, and the surfactant was used. The aqueous solution is subjected to development 'and rinsed with water' to add & at 2 generations to obtain a colored pattern. The obtained pattern has 5 (four) square resolution in the line and the gap, and is not confirmed ~ to the residue / check For example, it is also applicable to the use of high-resolution color filters for solid-state imaging devices. Evaluation of heat resistance, contrast, and solvent resistance. The substrate was applied to the glass I55912.doc -44 - 201213450 substrate in the same manner as described above, and the entire surface was exposed and dried at 200 ° C for 5 minutes, and then baked. Color filter substrate having color characteristics. Then, each evaluation was performed as follows: "The heat resistance is measured by measuring the spectral transmittance of the substrate before and after the treatment for 120 minutes at 200 ° C." The color difference (AEab) before and after the heat treatment was evaluated. The contrast was obtained by using the above-mentioned evaluation substrate, and the contrast value (CT-1 manufactured by Kesaka Electric Co., Ltd.) was based on the brightness value (cd/cm2) of the two polarizing plates in parallel. The ratio of the luminance value (cd/cm2) in the orthogonal direction (the luminance value in parallel/the luminance value in the orthogonal direction) is calculated. The 杂 钱 溃 (4) is used as the aligning film material = Ν-methylpyrrolidone In the middle, it was confirmed that there were changes in the helmet, and the knives were changed, and the spectral transmittance of the above-mentioned evaluation substrate was measured, and the spectroscopy was performed after 3 sec, 1 minute, and 3 minutes after being immersed in the Ν_ Τ base ratio. The transmittance was compared with the dry phase, and the visual enthalpy was evaluated by the spectroscopic chromatic aberration. Hereinafter, the results of the heat resistance of the spleen stalks under the spleen w 4 are shown in Table 3. The results of the solvent resistance are shown in Table 4. [Table 3] ° Table 3 Evaluation results of heat resistance △ Eab Example 1 5.0 Example 2 5.9 Example 3 6.1 - Example 4 6.4 Greedy Example 5 7.1 - Example 6 4.7 - Example 7 4.9 Example 8 5.0 - Example 9 6.3 Example 10 3.6 Example 11 2.6 - Example 12 4.6 ~ Comparative Example 4 Comparative Example 5 58.7 155912.doc -45· 201213450 In Comparative Example 4, the coloration of the pigment was observed in the hardening baking (5 minutes at 200 ° C) before the heat-resistant treatment, and the result was significantly poorer in the heat. Therefore, color difference evaluation cannot be performed. [Table 4] Table 4 Contrast Evaluation Results Contrast Example 1 10100 Example 2 10200 Example 3 13000 Example 4 9700 Example 5 10700 Example 6 10200 Example 7 10200 Example 8 10400 Implementation Example 9 10000 Example 10 10200 Example 11 11000 Comparative Example 1 400 Comparative Example 2 400 Comparative Example 3 400 Comparative Example 4 300 Comparative Example 5 300 Comparative Example 6 8500 [Table 5] Table 5 Evaluation results of solvent resistance AEab after 30 seconds After 1 minute, 3 minutes later, Example 11 0.1 0.1 0.2 Example 12 0.1 0.5 3.2 Comparative Example 5 - - Comparative Example 7 3.3 - - In Comparative Examples 5 and 7, the dye was completely dissolved in N-decylpyrrolidone, Since the colored film was completely peeled off, the spectral transmittance could not be measured. From the evaluation results of Table 3, it is understood that Examples 1 to 12 of the present invention show significantly good results as compared with Comparative Example 4 or 5 which is a dye of the previous 155912.doc-46-201213450, and the inventive colored material compound The patience has been greatly improved. In the case of the mixing of the pigments, in the case of mixing the pigments, even if it is mixed with the pigment, the state is also excellent in that the components are not particularly insoluble in the insoluble matter, and it is suggested that the dyes of the present invention are widely applicable to the coloring material compounds. . From the evaluation of the contrast of Table 4, it was found that the results showed significantly good results as compared with the dye of Comparative Example 5 or the pigment of 6. Further, in the evaluation of the solvent resistance of Table 5, the examples containing the resin and the comparative examples 5 and 7 not containing the epoxy resin of the present invention were remarkably excellent in solvent resistance. Although it was suggested that the conventional dye-based colored resin composition was not practical in terms of solvent resistance, it was confirmed from the above results that the colored resin composition of the present invention has color filter suitability. According to the above, the colored resin composition of the present invention using a specific dye-based colored material compound has vivid color characteristics and is excellent in resistance, and can obtain a high-quality and highly reliable color-removing filter which cannot be obtained by the prior product. It is also known that the pigments can be mixed and used depending on the application, showing a wide range of applicability, and thus the industrial value is high. 155912.doc •47·

Claims (1)

201213450 VII. Patent application range: A colored resin composition for color light-based sheets containing a compound of the following formula, a compound of a colored material, a compound of a colored material represented by the formula (7), and a polymerization of each of Starting agent, hardener and hardening accelerator, [Chemical 1] (In the formula (1), R1b to Reb each independently represent a hydrogen atom, a halogen atom, an alkyl group of C1-C12, an alkoxy group of C1_C12, a nitro group, a carboxyl group, an alkoxycarbonyl group, and ΥγΥ4 independently represent a hydrogen atom, C1_C12, respectively. The alkyl group and the aryl group; Χι to X5 each independently represent a hydrogen atom, a C1-C12 alkyl group, a C1-C12 alkoxy group, a halogen atom, a nitro group, a phenoxy group, a carboxyl group, an alkoxycarbonyl group, or a sulfo group. , amidyl or sulfonyl; z- represents a alkyl thiol amide anion, alkyl sulfoximine anion or alkyl sulfonate having a higher alkyl halide; 155912.doc 201213450 [Chemical 2] (In the formula (2), Rla to R6a are independently coated with a non-deuterium atom, a C1-C30 alkyl group, a base group or a nodal group; and R"7a~R_2〇a are independently 矣_〆司立表非氢 atoms, The dentate atom, the alkyl group of cn-C6', and the same meaning as in the formula (1). 2. The colored resin composition containing the compound of the colored material as claimed in the present invention, the Z-in the formula (1) and the formula (7) Separately for the three-three-methyl methyl continuous/methide anion, bis-trifluoromethane rolling 1r sulfonyl imide anion sulfonate. X ~ fluoromethyl 3. If request 1 or 2 The epoxy resin of the colored resin composition is used as a hardener, which contains the following formula (3): 155912.doc 201213450 [Chemical 3] (Ric-R!9 in the formula (3). Each independently represents a hydrogen atom, a ci_ci2 alkyl group, a C1-C12 alkoxy group, a halogen atom; and, G represents a glycidyl group. 4. As claimed in claim 1 A colored resin composition according to any one of the preceding claims, which comprises a metal phthalocyanine pigment. 5. A coloring cured film for color filter, which is patterned using the colored resin composition according to any one of the claims 6. A color filter comprising the colored hardening film for a color filter according to claim 5, wherein the device is mounted with the color filter of claim 6 8. A solid-state imaging device's system is installed with the color stencil of claim 6. 155912.doc 201213450 IV. Designated representative map: (1) The representative representative of the case is: (none) b) A brief description of the symbol of the representative figure: 5. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: 155912.doc 8