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TW201210479A - Harmful arthropods controlling composition and control method of harmful arthoropods - Google Patents

Harmful arthropods controlling composition and control method of harmful arthoropods Download PDF

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Publication number
TW201210479A
TW201210479A TW100127347A TW100127347A TW201210479A TW 201210479 A TW201210479 A TW 201210479A TW 100127347 A TW100127347 A TW 100127347A TW 100127347 A TW100127347 A TW 100127347A TW 201210479 A TW201210479 A TW 201210479A
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Taiwan
Prior art keywords
harmful
group
parts
sheath blight
harmful arthropod
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TW100127347A
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Chinese (zh)
Inventor
Atsushi Iwata
Emiko Sakamoto
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Sumitomo Chemical Co
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
    • A01N43/38—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings condensed with carbocyclic rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
    • A01N47/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing —O—CO—O— groups; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
    • A01N37/24—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides containing at least one oxygen or sulfur atom being directly attached to the same aromatic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
    • A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/32—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing >N—CO—N< or >N—CS—N< groups directly attached to a cycloaliphatic ring

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

Provided is a harmful arthropods controlling composition comprising spirotetramat and one or more sheath blight controlling compound selected from Group (A). Gropu (A): consisting of flutolanil, pencycuron, furametpyr and validarycin A.

Description

201210479 六、發明說明： 【發明所屬之技術領域】 本發明是關於有害生物防治用組成物及有害生物的防 治方法。 【先前技術】 以往’做為有害節肢動物防治組成物的有效成分，而 有許多化合物為人所知（例如參照The Pesticide201210479 6. Description of the Invention: [Technical Field of the Invention] The present invention relates to a composition for pest control and a method for preventing harmful organisms. [Prior Art] In the past, as an active ingredient of a harmful arthropod control composition, many compounds are known (for example, refer to The Pesticide).

Manua卜 15th edition (BCPC 出版；ISBN 978-1-901396-18 -8)。 【發明内容】 本發明之課題係提供對於有害節肢動物具有優異的防 治效力的有害節肢動物防治組成物。 亦即，本發明是關於以下[1]至[6]的内容。 [1 ] 一種有害節肢動物防治組成物，係含有賜派滅 (spirotetramat)與由群（A)所選的1種以上的紋枯病 防治化合物。 群（A):福多寧（f lutolani 1)、賓克隆（pencycuron)、 福拉比（furametpyr)及維利黴素A(validamycin A)所成之 群。 [2] 如[1]所述的有害節肢動物防治組成物，其紋枯病防治 化合物為福多寧（flutolani 1)或福拉比 (furametpyr) 〇 [3] 如[1]或[2]所述的有害節肢動物防治組成物，其中賜 派滅（sp i rotetramat)與紋枯病防治化合物之重量比 3 323369 201210479 為 10 : 1 至 1 : 100 。 [4] 一種有害節肢動物的防治方法，係包含將賜派滅 (spirotetramat)與群（a)中所選1種以上的紋枯病防 治化合物的有效量’對植物或植物的栽培地施用的步 驟。 群（A).福多寧（f lutolani 1)、賓克隆（penCyCur〇n)、 福拉比（iurametpyr)及維利黴素A(validamycin A)所成之 群。 [5] 如[4]所述的防治方法，其紋枯病防治化合物是福多寧 (flutolanil)或福拉比（furametpyr)。 [6] 如[4]或[5]所述的防治方法，其中賜派滅 (spirotetramat)與紋枯病防治化合物之重量比為 10 : 1 至 1 : 100 。 [7] 如[4]至[6]所述的防治方法，其有害節肢動物是屬於 飛蝨類的昆蟲。 [8] 如[4]至[6]任一項所述的防治方法，其有害節肢動物 是褐飛蝨、白背飛蝨或斑飛蝨。 【實施方式】 實施發明的形態 本發明的有害節肢動物防治組成物是含有賜派滅 (spirotetramat)與下述群（A)中所選的1種以上的紋枯病 防治化合物（以下’有時簡稱為本紋枯病防治化合物）。 群（A):福多寧（f lutolani 1)、賓克隆（pencycuron)、 福拉比（furametpyr)及維利黴素A(validamycin A)所成之 4 323369 201210479 群。 做為上述紋枯病防治化合物的典型例可舉福多寧 (flutolanil)及福拉比（furametpyr)。 賜派減（spirotetramat)是習知的化合物，例如可依曰 本專利特表2000-516918號公報所述的方法製造。 福多寧（flutolani 1)、賓克隆（pencycuron)、福拉比 (furametpyr)及維利黴素A(val idamycin A)都是習知的化 合物，例如「The Pesticide Manual-15th edition (BCPC 出版；ISBN 978-卜901396-18-8)的 559、871、580 及 1187 頁等之記述。這些化合物可由市售的製劑而得，或以習知 的方法製造。 在本發明的有害節肢動物防治組成物中的賜派滅與本 紋枯病防治化合物的含有比率並無特別的限定，但對賜派 滅1000重量份，本紋枯病防治化合物通常是10至1000000 重量份（即，賜派滅：紋枯病防治化合物（重量比）=100 : 1 至1 : 1000)，理想是100至100000重量份（賜派滅：紋枯 病防治化合物（重量比）= 100 : 1至1 : 100)，較理想是100 至10000重量份（賜派滅：紋枯病防治化合物（重量比）= 10 : 1 至 1 : 10) 〇 本發明的有害節肢動物防治組成物是，將賜派滅與本 紋枯病防治化合物單純混合也可以，將賜派滅及紋枯病防 治化合物與惰性承載物混合，視必要而添加界面活性劑或 其他製劑用補助劑而製劑化成為油劑、乳劑、可流動劑、 水合劑、顆粒水合劑、粉劑、粒劑等。 5 323369 201210479 又，前述的製劑化的有害 接使用或添加其他的惰性成分動物防治組成物，可直 有害節肢動物防治劑而使用。 砂、植物油等)而成為 本發明的有害節肢動物防 枯病防治化合物的合計量通常β、成物中的賜派滅及本紋 〇. 1至99請，理想是 圍。 在0· 5至70重量％的範 上述h性承載物而言，可 固體承栽物而言，例如載物、液體承載物。 (attapulgite)黏土、膨土 故 问嶺黏土、海泡石 工卿土石、蒙脫石 滑石、石夕漆土、方解石等礦物 酉U生白土錢石、 天然有機物、尿料麻未錄粉、胡桃殼粉等 合成含水氧切碳峡、硫酸錢等鹽類； #。 n機W所成的微粉末或粒狀物 等芳=物Γ，例如可舉二甲苯、燒基笨、甲基蔡 專方香族㈣，2—丙醇、乙二醇、丙二醇、 義 醚等醇類；丙嗣、環己銅、異佛爾綱等嗣類;大豆：乙= 籽油等植物油’石油系脂肪族烴類；酯類；二 腈及水等。 .’ 界面活性劑而言，例如可舉燒基硫酸醋，燒基芳基續 酸醋’二烧基確基琥賴鹽，聚氧伸乙基縣芳基_酸 酉旨鹽，木質素續酸鹽，蔡魏_ Μ聚縮合物等陰離子界 面活性劑1氧伸乙基絲芳_，聚氧伸乙基炫基聚氧 伸丙基嵌段共聚物，脂肪酸山梨糖醇酯等非離子界面活性 323369 6 201210479 劑；及烷基三曱基銨鹽等陽離子界面活性劑等。 其他的製劑用輔助劑而言，例如可舉聚乙烯醇、聚乙 烯吡咯酮等水溶性高分子；阿拉伯樹膠、海藻酸及其鹽； 竣曱基纖維素（CMC)、三仙膠等多糖類；紹鎂石夕酸鹽、氧化 鋁溶膠等無機物；防腐劑；著色劑及酸性磷酸異丙酯 (PAP)、BHT等安定化劑等。 本發明的有害節肢動物防治組成物，可用於保護植物 使其不受對植物攝食、吸汁等加害的有害節肢動物（例如有 害昆蟲及有害蟎的加害。 本發明的有害節肢動物防治組成物有防治效力的有害 節肢動物而言，例如可舉以下者。 半翅目害蟲：斑飛益（Laodelphax striatellus)、褐 飛蝨（Nilaparvata lugens)、白背飛蝨（Sogatella furcifera)等飛蝨類；黑尾葉蟬（Nephotettix cincticeps)、台灣黑尾葉蟬（Nephotettix virescens)) 荨葉_類，棉财（Aphis gossypii)、桃財（Myzus persicae)、菜财（Brevicoryne brassicae)、馬鈴薯網管 財（Macrosiphum euphorbiae)、馬龄薯财（Aulacorthum solani)、稻麥财（Rhopalosiphum padi)、大插对 (Toxoptera citricidus)等蚜蟲類；溫室粉蝨 (Trialeurodes vaporariorum)、煙草粉益（Bemisia tabaci)、銀葉粉蝨（Bemisiaargentifolii)等粉蝨類；橘 紅腎圓盾介殼蟲（Aonidiella aurantii)、聖荷西介殼蟲 (Comstockaspis perniciosa)、桂矢尖介殼蟲（Unaspis 7 323369 201210479 citri)、紅墩介殼蟲（Ceroplastesrubens)、吹綿介殼蟲 (Icerya purchase)等介殼蟲類；絨蟎目害蟲：二點葉蟎 (Tetranychus urticae)、柑抬葉蜗（Panonychus citri)、 小爪蜗屬（Oligonychus)的葉蜗等； 前述有害節肢動物中，較佳的例可舉斑飛蝨 (Laodelphax striatellus)、褐飛蝨（Nilaparvata lugens)、白背飛蟲(Sogatella furcifera)等飛兹類。 本發明的有害節肢動物防治組成物也可用於防治植物 病害的目的’例如可防治稻的紋枯病（Rh i zocton i a so 1 ani) 等。 本發明的有害節肢動物防治組成物，例如，在植物或 植物的栽培地施用’而用於防治有害節肢動物。對於植物 的施用部位而言，可舉植物的莖葉、植物的花、植物的果 實、植物的種子等。 本發明的有害節肢動物的防治方法，包含將賜派滅與 由上述群（A)所選的1種以上的紋枯病防治化合物的有效 量，對植物或植物的栽培地施用的步驟。在該防治方法中， 上述紋枯病防治化合物的典型例，與本發明的有害節肢動 物防治組成物相同。 本發明的有害節肢動物防治方法，例如，可將本發明 的有害節肢動物防治組成物對植物等施用而實施。 本發明的有害節肢動物防治組成物、賜派滅及上述紋 枯病防治化合物的施用例而言，可舉莖葉撒佈等對植物的 莖葉處理，土壤處理等對植物的栽培地的處理等。 323369 8 201210479 立將本發麵有害節肢動物防治組成物對植物或植物的 栽 包用時，其施用量是有效量即可，可隨施用的植物 ，類、防治對象的有害節肢動物種類及發生程度、製劑形 ^处理夺功、氣象條件等而改變，但將賜派滅與本紋枯 病^台化合物的合計量而言，對栽培該植物場所每 10000m2 吊也用1至5〇〇〇g，理想是10至500g。在本說明書中， =效里疋扎賜派滅及上述紋枯病防治化合物的合計施用 置’對於防治有害節肢動物上必要的施用量而言。 本鲞明的有害節肢動物防治組成物、賜派滅及上述紋 枯病防/α化合物是乳劑、水合劑、可流動劑時，通常以水 人，撒佈施用。這時’賜派滅與本紋枯病防治化合物的 σ °十1農度通常是〇. 0001至3重量％，理想是〇· 0005至1 量％本發明的有害節肢動物防治組成物、賜派滅及上述 、枯病防/α化合物是粉劑、粒劑等時，通常不稀釋而直接 施用。 ，本七月的有害節肢動物防治方法，可做為旱田、水田、 坪果W園等農耕地或非農耕地用而使用。 等，。本發明，在栽培以下所舉的「植物」等的農耕地 可為了防治在該農耕地的有害節肢動物之目的而使用。 農作物：多^ _ 木、稻、小麥、大麥、黑麥、燕麥、高梁、 棉 '大五、输5 气 足、菜豆、花生、蕎麥、甜菜、油菜、向曰 癸、甘蔗、煙草等。 蔬菜·加科蔬菜類（茄、番茄、甜椒、辣椒、 瓜科蔬菜（胡瓜、土 &amp; Λ 南瓜、節瓜、西瓜、香瓜、西葫蘆等）， 9 323369 201210479 ^字花科蔬菜（蘿蔔、_、山葵、大頭菜（隨剛）、白 菜、包心菜、芬菜、青花菜、花椰菜等），菊科蔬菜（牛旁、 筒蒿菜、朝鮮13、萬宣等），百合科蔬菜（葱、洋葱、大蒜、 虞U等），芽科蔬菜（紅蘿葡、歐芽、芽菜、歐洲防風草等）， 蘇科蔬菜（緩菜、寨菜等），唇形科蔬菜（紫蘇、薄荷、九層 塔等）’草莓，甘藷，山芋，芋等。 花卉（玫瑰、菊等）； 觀葉植物； 草皮； 果樹：仁果類（蘋果、西洋梨、曰本梨、花梨、棍梓等）， 核果類（桃、李、油桃、梅、櫻桃、杏、歐洲李等），柑橘 類（溫州柑、橙、擰檬、萊姆、葡萄柚等），堅果類（栗、胡 桃、榛果、杏仁、開心果、腰果、澳洲胡桃等），液果類（藍 «、蔓越每、黑華、覆盆子莓等），葡萄.，柿，撤禮，批把， 香蕉，咖啡，棗椰子，可可椰子等。 果樹以外的樹木：茶、桑，賞花植物類、行道樹（例如： 夏鵃、樺樹、花水木、桉樹、銀杏、紫丁香花、楓樹、機 樹、白揚樹、短毛紫莉花、楓香、法國梧桐、棒樹、曰本 香柏、日本冷杉、日本鐵杉、杜松、松、本州魚鱗雲杉、 曰本紅豆杉等）。 在上述植物中，較佳的例可舉玉米、小麥、稻等。更 較佳之例而言，可舉稻。 上述「植物」也可以是由基因重組技術或交配的育種 法而賦予耐性的植物。 323369 10 201210479 - 實施例 - 以下，將以製劑例及試驗例詳細說明本發明，但本發 明並不限定於只是下面的例。在以下的例中，如無特別註 明均表示重量份。 製劑例1 將賜派滅10份及福多寧（flutolanil)io份加於月桂 基硫酸鈉4份、木質素磺酸鈣2份、合成含水氧化矽微粉 末20份及矽藻土 54份的混合物中，充分攪拌混合而得水 合劑。 製劑例2 將賜派滅10份及賓克隆（pencycuron)lO份加於月桂 基硫酸鈉4份、木質素續酸約2份、合成含水氧化;ε夕微粉 末20份及矽藻土 54份的混合物中，充分攪拌混合而得水 合劑。 製劑例3 將賜派滅10份及福拉比（furametpyr)lO份加於月桂 基硫酸納4份、木質素橫酸辦2份、合成含水氧化&gt;ε夕微粉 末20份及矽藻土 54份的混合物中，充分攪拌混合而得水 合劑。 製劑例4 將賜派滅10份及維利黴素A(validamycin A)10份加 於月桂基硫酸納4份、木質素績酸辦2份、合成含水氧化 矽微粉末20份及矽藻土 54份的混合物中，充分攪拌混合 而得水合劑。 11 323369 201210479 製劑例5 將賜派滅2份及福多寧（f iut〇iani ι)ι份、高嶺黏土 87份及滑石10份充分粉碎混合而得粉劑。 製劑例6 將賜派滅2份及賓克隆（pencyCUr〇n)l份、高嶺黏土 87份及滑石10份充分粉碎混合而得粉劑。 製劑例7 將賜派滅2份及福拉比（furametpyr)l份、高嶺黏土 87份及滑石10份充分粉碎混合而得粉劑。 製劑例8 將賜派滅4份及維利黴素A(validamycin A)1份、高 嶺黏土 85份及滑石10份充分粉碎混合而得粉劑。 製劑例9 將賜派滅5份、福多寧（flutolanil)10份、含聚氧伸 乙基烷基醚硫酸銨鹽50份的白碳（=白碳：聚氧伸乙基烧基 醚硫酸銨鹽=1 : 1(重量比）的混合物）30份水55份混合， 以濕式粉碎法進行微粉碎而得可流動劑。 製造例10 將賜派滅5份、賓克隆（penCyCur〇n)l〇份、含聚氧伸 乙基烷基醚硫酸銨鹽50份的白碳（=白碳：聚氧伸乙基烷基 醚硫酸銨鹽=1 : 1(重量比）的混合物）3〇份及水55份混合， 以濕式粉碎法進行微粉碎而得可流動劑。 製造例11 將賜派滅5份、福拉比（furametpyr)l〇份、含聚氧伸 12 323369 201210479 乙基烷基醚硫酸銨鹽50份的白碳（=白碳：聚氧伸乙基烷基 醚硫酸銨鹽=1 : 1(重量比）的混合物）3〇份水55份混合， 以濕式粉碎法進行微粉碎而得可流動劑。 製造例12 將賜派滅5份、維利黴素A(validamycin A)l〇份、含 聚氧伸乙基烧基硫酸銨鹽50份的白碳（=白碳：聚氧伸乙 基烷基醚硫酸銨鹽=1 : 1(重量比）的混合物）3〇份及水55 份混合’以濕式粉碎法進行微粉碎而得可流動劑。 其次’將本發明的效果以試驗例表示。 試驗例1(對褐飛蝨的殺蟲活性試驗） 將依照日本專利特表2000-516918號公報所述的方法 製造的賜派滅原體、福多寧（flutolani 1)原體（和光純藥公 司製）、賓克隆（pencycuron)原體（和光純藥公司製）、及福 拉比（furametpyr)原體i〇mg，分別溶解於含有s〇igen TW-20 (第一工業製藥公司製）的丙酮（和光純藥工業公司製） lml後，以含有展著劑（商品名：代因（音譯）（註冊商標）， 住化武田園藝公司製）〇. 〇2容量％的水稀釋到規定的濃度。 將賜派滅的水稀釋液與福多寧（flut〇lanil)的水稀釋液、 賓克隆（pencycuron)的水稀釋液或福拉比（furametpyr)的 水稀釋液混合，而調製試驗用藥液。 在2. 5葉期的在紙盆種植的稻（〇ryZa satiVa，品種： 星之夢）幼苗每2株撒佈前述試驗用的藥液2〇lml。將此稻 幼苗風乾後，放入於裝水4. 8ml的玻璃製試管（直徑30賴、 鬲200mm)中。在此試管中每支放養褐飛蝨3齡幼蟲1〇隻， 13 323369 201210479 放在室内（25°C，濕度60%)。放養開始日起6日後觀察放 養的供試幼蟲的生死狀況。由觀察結果，依前述式υ算出 死蟲率，依前述式2)算出修正死蟲率。又，試驗是以2重 複實施。將其平均值示於第2表。 式1):死蟲率（％)=(供試蟲數—生存蟲數穴供試蟲數 X 100 式2);修正死蟲率（％) = {(處理區死蟲率—無處理區 死蟲率）/(100-無處理區死蟲率）} χ 1〇〇 第1表 供試化合物 濃度（卯m) 修正死蟲率[%] 賜派滅 ----- 0.4 __ 60 __^派滅+福多寧 0.4 + 0.04 80 賜派滅+福多寧 0.4 + 0.4 90 _賜派滅+福多寧 0.4 + 4 90 賜派滅+賓克隆 0.4 + 0. 〇4 85 賜派滅+賓克隆 0. 4 + 〇. 4 90 _____賜派滅+賓克隆 0.4 + 4 85 __賜派滅+福拉比 〇. 4 + 0. 4 l 85 賜派滅+福拉比 0· 4 + 4 90 (註）供試化合物有2種時的濃度是配合化合物記述 的順序而記述。 產業上利用的可能性 本發明的有害節肢動物防治組成物對於有害節肢動物 14 323369 201210479 可更有效率防治。 【圖式簡單說明】 無。 【主要元件符號說明】 無。 15 323369Manua Bu 15th edition (BCPC Publishing; ISBN 978-1-901396-18 -8). Disclosure of the Invention An object of the present invention is to provide a harmful arthropod control composition which has excellent anti-therapeutic efficacy against harmful arthropods. That is, the present invention relates to the following [1] to [6]. [1] A harmful arthropod control composition comprising a spirotetramat and one or more sheath blight control compounds selected by the group (A). Group (A): a group of f lutolani 1 , pencycuron, furametpyr and validamycin A. [2] The harmful arthropod control composition according to [1], wherein the sheath blight control compound is flutanin 1 or furametpyr 〇 [3] such as [1] or [2] The harmful arthropod control composition, wherein the weight ratio of sp i rotetramat to sheath blight control compound is 10:1 to 1:100 by weight ratio 3 323369 201210479. [4] A method for controlling harmful arthropods, which comprises administering an effective amount of a pest control compound of the selected one or more selected from the group consisting of spirotetramat and group (a) to a plant or plant cultivation site. step. Group (A). F lutolani 1 , penCyCur〇n, iurametpyr and validamycin A. [5] The control method according to [4], wherein the sheath blight control compound is flutolanil or furametpyr. [6] The method according to [4] or [5], wherein the weight ratio of the spirotetramat to the sheath blight control compound is from 10:1 to 1:100. [7] The control method according to [4] to [6], wherein the harmful arthropod is an insect belonging to the planthopper. [8] The control method according to any one of [4] to [6] wherein the harmful arthropod is brown planthopper, whitebacked planthopper or spotted planthopper. [Embodiment] The harmful arthropod control composition of the present invention is a sheath blight control compound selected from the group consisting of spirotetramat and the following group (A) (hereinafter "sometimes Referred to as the sheath blight prevention compound). Group (A): Group 4 323369 201210479 formed by F lutolani 1 , pencycuron, furametpyr and validamycin A. Typical examples of the above-mentioned sheath blight control compound include flutolanil and furametpyr. The spirotetramat is a conventional compound, and can be produced, for example, by the method described in JP-A-2000-516918. Flutolani 1 , pencycuron , furametpyr and val idamycin A are all known compounds, such as "The Pesticide Manual-15th edition (BCPC Publishing; The descriptions of 559, 871, 580, and 1187 pages of ISBN 978-Bu 901396-18-8. These compounds can be obtained from commercially available preparations or can be produced by a known method. The harmful arthropod control composition of the present invention There is no particular limitation on the ratio of the content of the smear and the control compound of the present stalk, but the stalk control compound is usually 10 to 1,000,000 parts by weight (i.e., sent out) : Sheath blight control compound (weight ratio) = 100 : 1 to 1: 1000), ideally 100 to 100,000 parts by weight (Give out: Sheath blight control compound (weight ratio) = 100 : 1 to 1: 100) More preferably, it is 100 to 10,000 parts by weight (Give it out: the sheath blight prevention compound (weight ratio) = 10:1 to 1: 10) 〇 The harmful arthropod control composition of the present invention is The sheath blight prevention compound can be mixed simply, and will be sent out. The sheath blight control compound is mixed with an inert carrier, and if necessary, a surfactant or other formulation auxiliary agent is added to prepare an oil agent, an emulsion, a flowable agent, a hydrating agent, a granule hydrating agent, a powder, a granule, and the like. 5 323369 201210479 In addition, the above-mentioned formulated harmful use or addition of other inert component animal control composition can be used directly as a harmful arthropod control agent. Sand, vegetable oil, etc.) is a harmful arthropod pest control of the present invention. The total amount of the control compound is usually β, the derivative of the product and the 〇 〇. 1 to 99, ideally the circumference. In the range of 0.5 to 70% by weight of the above-mentioned h-type carrier, the solid support For the plant, for example, the cargo, the liquid carrier, the attapulgite clay, the bentonite clay, the sepiolite, the montmorillonite talc, the stone lacquer, the calcite, etc. , natural organic matter, urinary material, unrecorded powder, walnut shell powder, etc., synthetic hydrous cut carbon gorge, sulfuric acid money and other salts; #. n machine W made of micro-powder or granules, etc., for example, Dimethyl , burning base stupid, methyl Cai special prescription Xiang (four), 2-propanol, ethylene glycol, propylene glycol, ether and other alcohols; acetamidine, cyclohexyl copper, isophora and other steroids; soybean: B = Vegetable oils such as seed oils are petroleum-based aliphatic hydrocarbons; esters; dinitrile and water, etc. 'For surfactants, for example, sulphur-based sulphuric acid vinegar, aryl aryl sulphuric acid vinegar' Aloe sulphate, polyoxy-extension ethyl aryl _ acid sulphate salt, lignin hydrochloride, Cai Wei _ Μ polycondensate and other anionic surfactants 1 oxygen extension ethyl silk fang _, polyoxyethyl ether Non-ionic interfacial activity such as sulfopolyoxyl propyl block copolymer, fatty acid sorbitol ester, etc. 323369 6 201210479; and cationic surfactant such as alkyl tridecyl ammonium salt. Examples of other preparation auxiliary agents include water-soluble polymers such as polyvinyl alcohol and polyvinylpyrrolidone; gum arabic, alginic acid and salts thereof; polysaccharides such as mercapto cellulose (CMC) and Sanxian gum. ; inorganic substances such as sulphate, alumina sol; preservative; coloring agent and acid isopropyl phosphate (PAP), BHT and other stabilizers. The harmful arthropod control composition of the present invention can be used for protecting plants from harmful arthropods (such as harmful insects and harmful cockroaches) which are harmful to plant feeding, sucking juice, etc. The harmful arthropod control composition of the present invention has prevention and treatment. For harmful arthropods, for example, the following: Hemiptera pests: Laodelphax striatellus, Nilaparvata lugens, Sogatella furcifera, etc. (Nephotettix cincticeps), Taiwanese Nephotettix virescens) Aphis gossypii, Myzus persicae, Brevicoryne brassicae, Macrosiphum euphorbiae, horse Aulacorthum solani, Rhopalosiphum padi, Toxoptera citricidus and other aphids; Trialeurodes vaporariorum, Bemisia tabaci, Bemisiaargentifolii Amaranthus; Aonidiella aurantii, San Jose scale insect (Comstockas) Pis perniciosa), Unaspis 7 323369 201210479 citri, Ceroplastesrubens, Icera purchase, etc.; ), Panonychus citri, the genus of Oligonychus, etc.; among the above-mentioned harmful arthropods, preferred examples are Laodelphax striatellus, Nilaparvata lugens, and white. Flygs such as Sogatella furcifera. The harmful arthropod control composition of the present invention can also be used for the purpose of controlling plant diseases, such as rice sheath blight (Rh i zocton i a so 1 ani). The harmful arthropod control composition of the present invention is applied, for example, in the cultivation of plants or plants, and is used for controlling harmful arthropods. The plant application site may include stems and leaves of plants, flowers of plants, fruits of plants, seeds of plants, and the like. The method for controlling a harmful arthropod of the present invention comprises the step of administering an effective amount of one or more kinds of sheath blight control compounds selected by the above group (A) to a plant or plant cultivation site. In the control method, the above-mentioned typical example of the sheath blight control compound is the same as the harmful arthropod control composition of the present invention. The harmful arthropod control method of the present invention can be carried out, for example, by applying the harmful arthropod control composition of the present invention to a plant or the like. In the application examples of the harmful arthropod control composition, the smear and the above-mentioned sheath blight control compound of the present invention, the stem and leaf treatment of the plant such as stem and leaf spreading, and the treatment of the plant cultivation site such as soil treatment may be mentioned. Wait. 323369 8 201210479 When applying the harmful arthropod control composition to the plant or plant, the application amount is an effective amount, which can be related to the plant, the class, the harmful arthropod species of the control object and the occurrence The degree, the shape of the preparation, the treatment, the meteorological conditions, etc., are changed, but in terms of the total amount of the compound of the stalk and the stalk, the 10,000 m2 hang for the plant site is also used for 1 to 5 〇〇〇. g, ideally 10 to 500 g. In the present specification, the total application of the above-mentioned control factors for the control of the sheath blight is carried out in terms of the amount of application necessary for the control of harmful arthropods. The harmful arthropod control composition of the present invention, the smear and the above-mentioned anti-α compound are emulsions, hydrating agents, and flowable agents, and are usually applied by water. At this time, the σ ° 10 1 agricultural degree of the control compound is usually 〇 0001 to 3% by weight, ideally 〇 0005 to 1% by weight of the harmful arthropod control composition of the present invention. When the above-mentioned, blight disease prevention/α compound is a powder, a granule, or the like, it is usually applied directly without dilution. The harmful arthropod control method in July can be used as agricultural land or non-agricultural land such as dry land, paddy field, and Pingguo W garden. Wait,. In the present invention, the cultivation of a "plant" such as the following can be used for the purpose of controlling harmful arthropods in the agricultural land. Crops: more ^ _ wood, rice, wheat, barley, rye, oats, sorghum, cotton 'big five, lose 5 gas foot, kidney beans, peanuts, buckwheat, sugar beets, rapeseed, sorghum, sugar cane, tobacco and so on. Vegetables · Jia Ke vegetables (egg, tomato, sweet pepper, pepper, melon vegetable (courgette, soil &amp; Λ pumpkin, zucchini, watermelon, melon, zucchini, etc.), 9 323369 201210479 ^ word flower vegetables (radish, _, wasabi, kohlrabi (with fresh), cabbage, cabbage, fennel, broccoli, broccoli, etc.), Asteraceae vegetables (Niubian, wormwood, North Korea 13, Wanxuan, etc.), Liliaceae vegetables (onions, onions) , garlic, 虞U, etc., buds vegetables (red stalks, buds, sprouts, parsnips, etc.), Suco vegetables (sweet vegetables, sauerkraut, etc.), Labiatae vegetables (perilla, mint, nine-story tower) Etc.) 'Strawberry, sweet potato, hawthorn, alfalfa, etc. Flower (rose, chrysanthemum, etc.); foliage plant; turf; fruit tree: pome fruit (apple, western pear, 曰本梨, pear, stick, etc.), stone fruit (peach, plum, nectarine, plum, cherry, apricot, European plum, etc.), citrus (Wenzhou mandarin, orange, lemon, lime, grapefruit, etc.), nuts (chestnut, walnut, hazelnut, almond, happy Fruit, cashew nuts, Australian walnuts, etc.), liquid fruit (blue « Cranberry, blackberry, raspberry, etc.), grape, persimmon, retreat, batch, banana, coffee, date palm, coconut palm, etc. Trees other than fruit trees: tea, mulberry, flower viewing plants, street trees (for example: summer 桦, birch, sapwood, eucalyptus, ginkgo, lilac, maple, eucalyptus, poplar, short-haired jasmine, sweet gum, sycamore, stick tree, sakamoto cedar, Japanese fir , Japanese hemlock, juniper, pine, Honshu Spruce, Sakamoto yew, etc.) Among the above plants, preferred examples are corn, wheat, rice, etc. More preferably, rice is exemplified. The above-mentioned "plant" may be a plant that confers tolerance by a genetic recombination technique or a mating breeding method. 323369 10 201210479 - Examples - Hereinafter, the present invention will be described in detail by way of formulation examples and test examples, but the present invention is not limited thereto. In the following examples, the parts are given by weight unless otherwise indicated. Formulation Example 1 10 parts of chlorhexidine and io parts of flutolanil are added to 4 parts of sodium lauryl sulfate, lignin. 2 parts of calcium sulfonate, synthetic aqueous oxidation A mixture of 20 parts of mash fine powder and 54 parts of diatomaceous earth was stirred and mixed to obtain a hydrating agent. Formulation Example 2 10 parts of chlorpyrifos and 10 parts of pencycuron were added to 4 parts of sodium lauryl sulfate, and wood A mixture of about 2 parts of acid and a synthetic aqueous oxidation; a mixture of 20 parts of ε 微 micro powder and 54 parts of diatomaceous earth, and thoroughly stirred and mixed to obtain a hydrating agent. Formulation Example 3 will give 10 parts of Furabi (furametpyr) 10 parts of a mixture of 4 parts of sodium lauryl sulfate, 2 parts of lignin acid, 2 parts of synthetic aqueous oxidation &gt; ε 微 fine powder and 54 parts of diatomaceous earth, and thoroughly stirred and mixed to obtain a hydrating agent. Example 4 10 parts of chlorpyrifos A (validamycin A) were added to 4 parts of sodium lauryl sulfate, 2 parts of lignin acid acid, 20 parts of synthetic aqueous cerium oxide powder and diatomaceous earth 54 The mixture was thoroughly stirred and mixed to obtain a hydrating agent. 11 323369 201210479 Formulation Example 5 A powder was obtained by thoroughly pulverizing and mixing 2 parts of Fouutinian ι, 1 part of kaolin clay, and 10 parts of talc. Formulation Example 6 2 parts of chlorpyrifos and 1 part of penmone (pencyCUr〇n), 87 parts of kaolin clay, and 10 parts of talc were thoroughly pulverized and mixed to obtain a powder. Formulation Example 7 Two parts of furnishing, one part of furametpyr, 87 parts of kaolin clay, and 10 parts of talc were thoroughly pulverized and mixed to obtain a powder. Formulation Example 8 4 parts of chlorpyrifos A, 1 part of validamycin A, 85 parts of kaolin clay, and 10 parts of talc were thoroughly pulverized and mixed to obtain a powder. Formulation Example 9 5 parts, flutolanil 10 parts, and 50 parts of polyoxyethylene ethyl ether sulfate ammonium sulfate (= white carbon: polyoxyalkylene ether sulphate) A mixture of ammonium salt = 1 : 1 (by weight) was mixed with 30 parts of water (55 parts), and finely pulverized by a wet pulverization method to obtain a flowable agent. Production Example 10 5 parts of penfenzol (penCyCur〇n), a white carbon containing 50 parts of polyoxyethylene ethyl ether sulfate ammonium sulfate (=white carbon: polyoxyalkylene ethyl group) A mixture of ammonium sulphate sulfate = 1 : 1 (by weight) was mixed with 3 parts of water and 55 parts of water, and finely pulverized by a wet pulverization method to obtain a flowable agent. Production Example 11 White carbon (=white carbon: polyoxy-extended ethyl group) of 5 parts, furametpyr, and polyoxygen extension 12 323369 201210479 ethyl alkyl ether sulfate ammonium salt A mixture of alkyl ether sulfate ammonium salt = 1 : 1 (by weight)) 3 parts by weight of water was mixed, and finely pulverized by a wet pulverization method to obtain a flowable agent. Production Example 12 5 parts of vallimycin A (validamycin A), white carbon containing 50 parts of polyoxyethylidene ammonium sulfate (= white carbon: polyoxyalkylene oxide) A mixture of ammonium ether sulfate ammonium salt = 1 : 1 (by weight)) 3 parts by weight and 55 parts of water were mixed and finely pulverized by a wet pulverization method to obtain a flowable agent. Next, the effects of the present invention are shown in a test example. Test Example 1 (Insecticide activity test against brown planthopper) The genus of flutolani 1 produced by the method described in Japanese Patent Publication No. 2000-516918 (manufactured by Wako Pure Chemical Industries, Ltd.) ), the clone (pencycuron) (manufactured by Wako Pure Chemical Co., Ltd.), and the furametpyr, i〇mg, were dissolved in acetone containing s〇igen TW-20 (manufactured by Daiichi Kogyo Co., Ltd.). (Wako Pure Chemical Industries, Ltd.) After lml, it is diluted to the specified concentration with water containing 2% by volume of a spreading agent (trade name: Daiyin (registered trademark), manufactured by Sugawara Takeda Horticulture Co., Ltd.) . The test solution is prepared by mixing the diluted water dilution with a water dilution of flut〇lanil, a water dilution of pencycuron or a water dilution of furamethyr. In the 2. 5 leaf stage, the rice seedlings (〇ryZa satiVa, variety: Star Dream) seedlings planted in the paper pot were spread 2 liters per second for the test solution. The rice seedlings were air-dried, and placed in a glass test tube (diameter 30 Å, 鬲 200 mm) containing 4. 8 ml of water. In this test tube, each of the 3rd instar larvae of the brown planthopper was stocked, and 13 323 369 201210479 was placed indoors (25 ° C, humidity 60%). The life and death status of the stocked larvae were observed after 6 days from the start of stocking. From the observation results, the mortality rate was calculated according to the above formula, and the corrected mortality rate was calculated according to the above formula 2). Also, the test was repeated in two. The average value is shown in the second table. Formula 1): Dead insect rate (%) = (number of test insects - number of living insects number of test insects X 100 type 2); revised dead insect rate (%) = {(treatment area dead insect rate - no treatment area Dead insect rate) / (100 - no treatment area dead insect rate)} χ 1〇〇 Table 1 test compound concentration (卯m) Modified dead insect rate [%] Give away ----- 0.4 __ 60 __ ^派灭+福多宁 0.4 + 0.04 80 派派灭+福多宁 0.4 + 0.4 90 _送派灭+福多宁 0.4 + 4 90 派派灭+宾克隆0.4 + 0. 〇4 85 +宾克隆0. 4 + 〇. 4 90 _____送派灭+宾克隆0.4 + 4 85 __送派灭+福拉比〇. 4 + 0. 4 l 85 派派灭+福拉比0· 4 + 4 90 (Note) The concentration of the test compound in two cases is described in the order in which the compound is described. Industrial Applicability The harmful arthropod control composition of the present invention can be more effectively prevented against harmful arthropods 14 323 369 201210479. [Simple description of the diagram] None. [Main component symbol description] None. 15 323369

Claims (1)

201210479 七、申請專利範圍： 1 · 一種有害節肢動物防治組成物，係含有賜派滅 (spirotetramat)與由群（A)所選的1種以上的紋枯病 防治化合物， 群（A):福多寧（flutolanil)、賓克隆 (pencycuron)、福拉比（furametpyr)及維利黴素 A(validamycin A)所成之群。 2.如申請專利範圍第1項所述的有害節肢動物防治組成 物，其中，紋枯病防治化合物為福多寧（flutolanil) 或福拉比（furametpyr)。 3·如申請專利範圍第1項或第2項所述的有害節肢動物防 治組成物，其中，賜派滅（spirotetramat)與紋枯病防 治化合物之重量比為10 : 1至1 : 1〇〇。 4· 一種有害節肢動物的防治方法，係包含將賜派滅 (spirotetraraat)與群（A)中所選1種以上的紋枯病防 治化合物的有效量，對植物或植物的栽培地施用的步 驟， 群（A) ·福多寧（fiut〇ianu)、賓克隆 (pencycuron)、福拉比（furametpyr)及維利黴素 A(validamycin A)所成之群。 5. 如申請專利範圍第4項所述的防治方法，其中，紋枯病 防治化合物是福多寧（flut〇lanil)或福拉比 (furametpyr) ° 6. 如申凊專利範圍第4項或第5項所述的防治方法，其 323369 1 201210479 中，賜派滅（spirotetramat)與紋枯病防治化合物之重 量比為10 : 1至1 : 100。 7. 如申請專利範圍第1項至第6項所述的防治方法，其 中，有害節肢動物是屬於飛蝨類的昆蟲。 8. 如申請專利範圍第4項至第6項任一項所述的防治方 法，其中，有害節肢動物是褐飛蝨、白背飛蝨或斑飛蝨。 2 323369 201210479 四、指定代表圖： (一) 本案指定代表圖為：本案無圖式。 (二) 本代表圖之元件符號簡單說明：無。 五、本案若有化學式時，請揭示最能顯示發明特徵的化學式： 本案無化學式。 323369201210479 VII. Patent application scope: 1 · A harmful arthropod control composition containing more than one species of sheath blight control compound selected by spirotetramat and group (A), group (A): Fu A group of flutolanil, pencycuron, furametpyr, and validamycin A. 2. The harmful arthropod control composition according to claim 1, wherein the sheath blight control compound is flutolanil or furametpyr. 3. The harmful arthropod control composition according to claim 1 or 2, wherein the weight ratio of the spirotetramat to the sheath blight control compound is 10:1 to 1:1〇〇 . 4. A method for controlling harmful arthropods, comprising the step of administering an effective amount of a sheath blight control compound selected from the group consisting of spirotetraraat and group (A) to a plant or plant cultivation site. , group (A) · group of fiut〇ianu, pencycuron, furametpyr and validamycin A. 5. The method of controlling according to item 4 of the patent application, wherein the sheath blight control compound is flut〇lanil or furametpyr 6. as claimed in claim 4 or In the control method according to Item 5, in the 323369 1 201210479, the weight ratio of the spirotetramat to the sheath blight control compound is 10:1 to 1:100. 7. The method of controlling according to items 1 to 6 of the patent application, wherein the harmful arthropod is an insect belonging to the planthopper. 8. The method according to any one of claims 4 to 6 wherein the harmful arthropod is brown planthopper, whitebacked planthopper or spotted planthopper. 2 323369 201210479 IV. Designated representative map: (1) The representative representative of the case is: The case has no schema. (2) A brief description of the symbol of the representative figure: None. 5. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: There is no chemical formula in this case. 323369
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