201202752 六、發明說明： 【發明所屬之技術領域】 [0001] 本發明係有關一種抗眩膜，尤指一種不同内外霧度 之抗眩膜及其製作方法。 【先前技術】201202752 VI. Description of the Invention: [Technical Field] [0001] The present invention relates to an anti-glare film, and more particularly to an anti-glare film having different internal and external haze and a method for fabricating the same. [Prior Art]
〇 隨著光電科技的進步，抗反射光學薄膜之研究成為 重要發展之技術。抗反射光學薄膜之研究在光學領域中 應用非常廣泛’在光學元件表面鑛上抗反射膜，可以增 進光學儀器整體之表現。近年來，液晶顯示器（LCD)被廣 泛應用於各項現代電子化產品’知個人電腦、筆記型電 :: .-- 腦、數位相機、行動電話、PDA及液晶電視（LCD TV) 等。由於外在光線在照射顯示器表面之玻璃或塑膠基材 的表面時約會有4〜5%的反射，因此液晶顧示器在使用 時，容易受外界光線干擾，影響畫面視覺效果，對於大 尺寸面板，特別是大於2 〇吋以上之液晶電視而言，其螢 幕表面外在光反射影響更為明顯v為了解決外在光線的 干擾’抗眩膜因敢果明顯及成本較低等因素，廣泛應用 於筆記型電腦、電腦之液晶顯示螢幕上。 [0003] 圖1係一習知技術之抗眩膜結構示意圖，抗眩膜是藉 由抗眩粒子的添加以達到抗眩之效果，如圖所示：該抗 眩膜結構包含有一基材1、一設置於該基材1之上的抗眩 膜塗層2 ’該抗眩膜塗層2包含有一樹脂3及一光散射粒子 4 ’其製作方法為；將一抗眩膜塗液塗佈於該基材1上， 經過供箱將該抗眩膜塗液中所含之溶劑蒸發，再經過紫 外燈照射或焕箱後使該抗眩膜塗液中之樹脂3產生硬化反 099122070 表單編號A0101 第3頁/共19頁 0992038860-0 201202752 應，形成該抗眩膜塗層2。該抗眩膜塗層2内之光散射粒 子4在該抗眩膜塗液剛塗佈在該基材1上時，均勻分散在 該抗眩膜塗液中，當該抗眩膜塗液中之溶劑蒸發後，該 樹脂3和該光散射粒子4逐漸沉降，形成該抗眩膜塗層2。 由於該抗眩膜塗液之溶劑蒸發時，溶劑與該樹脂3、溶劑 與该光散射粒子4以及該樹脂3與該光散射粒子4之間的作 用力複雜’使得該光散射粒子4在乾燥後隨機分佈於該抗 眩膜塗層2中。但上述之技術無法控制該光散射粒子4在 該抗眩膜塗層2中之分佈狀況，無法有效控制抗眩膜之霧 度。 [0004] 而如美國專利公告第5998013號之” Anti-glare hard coat film and process for producing the film” 、美國專利公告第6217176號之” Antiglare film and use thereof” 、美國專利公告第 6613426B2號之 Very fine apti-glare hard coat film” '美國專利公告第669614时2號之一 Anti_glare film and process for producing same thereof ”、美國專利公告第6896960號之，’ Anti-glare hard coat film” 、美國專利公告第7〇33638B2號之” Anti_ glare film and process for producing the same”中所揭示之内容’其係揭露了各種不同製作抗眩 膜之方法或材料’其主要是利用光散射粒子之大小和數 量以及樹脂層之厚度來控制抗眩膜之霧度。此外，如中 華民國專利公告第557363號之，’抗眩膜”、中華民國專 利公告第590886號之，，形成抗眩抗反射膜的方法”及中 099122070 表單編號A0101 第4頁/共19頁 0992038860-0 201202752 [0005] 華民國專利公告第” Μ252022，’號+，， 现之光學抗眩薄膜，’， 其係亦揭露了利用光散射粒子之夫， 小和數量以及樹脂層 之厚度來控制抗眩膜之霧度的方法及材料 但，由於塗佈設備之限制’對於塗佈製程調整不是 -件容易的事情。因此’若要製作不同霧度之抗眩膜， 抗眩膜塗液之配方須要重新設計，且因為濕膜厚度、光 學塗液枯度以及光散射粒子與樹脂之搭配性等因素考量 ，不容易製作出所設計之内外霧度值的抗眩膜。 0 [0006] Ο 如日本專利第2006-088643號之，，細 process of embossed roll” 及美國專利第 7008066B2 號” Antiglare film process f〇r producing the same, and display device using antiglare fiim”中所揭示之技術’真孫藉由壓花滾輪 使得塗膜表面形成凹凸微結構，以達到抗<眩或是抗反射 之效果。藉由上述之技術雖然可以製作不同霧度之抗眩 膜，然而對於不同霧度抗眩膜之製造必須搭配不同之廢 化滚輪’造成成::本上之增加。此外》上述之方法只能改 變外部霧度，無法有效調整内部霧度》 [0007] 【發明内容】 本發明之主要目的’在於解決習知技術無法有效分別 控制抗眩膜之内外霧度的問題。 本發明之另一目的，在於提供一種製備方式簡單且成 本低廉的抗眩膜。 099122070 為達上述目的，本發明提供一種不同内外霧度之抗眩 臈，其包含有一透明基板及一由一抗眩膜塗液塗佈於該 表單編號A0101 第5頁/共19百 貞 0992038860-0 201202752 透明基板上形成的抗眩膜塗層，其中該抗眩膜塗液包含 有-樹脂、一溶劑'一使該樹脂硬化的起始劑/硬化劑、 一親樹脂光散射粒子及-疏樹脂紐射粒子。 此外，本發明也提供—種不同内外霧度之抗眩膜的製 作方法，其包含有W-S5共五個步驟，如下所列： 51 :將一透明基板洗淨，烘乾備用； 52 :製備一光散射粒子； 53 :製備-反特性光散射粒子，藉由表面改質將步㈣ 所製備之絲射粒子改質成對樹賴疏躲相異之反特 性光散射粒子； 54 :製作-抗眩膜塗⑯，將步驟52和步驟幻所製備之該 光散射粒子及該反躲光散驗子明需比例置入於二 樹脂中而得該抗眩膜塗液；及 55 :將步驟S4所製備之抗眩膜塗液塗佈於步驟si之透明 基板上並娱乾，完成該抗眩膜之製作。 需特別說明較，步驟魏巾之雜雜子可以為親 樹脂光散射粒子或疏樹脂絲射粒子，並*限定必須先 製備親樹脂光散射粒子或先製備疏翁脂光散射粒子而 反特性光散射粒子係指與先製備之光散射粒子特性相異 的疏樹脂光散射粒子或親樹脂光散射粒子。 由上述說明可知，本發明藉由調整設置於該樹脂内的 親樹脂光散射粒子及疏樹脂光散射粒子的比例濃度分別 控制4几眩膜的内外霧度，藉此製造出符合不同需求的抗 眩膜，並且，該親樹脂光散射粒子及該疏樹脂光散射粒 子之内部材料相同，僅其表面官能基不同，具有製備容 易及低成本的優點。 099122070 表單編號A0101 第6頁/共19頁 0992038860-0 201202752 【實施方式】 闺 «本㈣之詳細㈣及技㈣容，現脑合圖式說 ' 明如下： 請參閱圖2所示’係本發明一較佳實施例之剖面結構 不意圖，如圖所示：本發明係為一種不同内外霧度之抗 眩膜，其包含有一透明基板1〇及一由一抗眩膜塗液塗佈 於該透明基板10上形成的抗眩膜塗層2〇a，其中該抗眩膜 塗液包含有一樹脂30、一溶劑、一使該樹脂3〇硬化的起 始劑/硬化劑、一親樹脂光散射粒子4〇8及一疏樹脂光散 0 射粒子50a。 進一步的說明，該透明基故1〇係遠自於由玻璃、壓克 力（polyacrylate)、聚碳:酸:醋（.p.〇iycarb〇nate) 、聚乙烯（polyethylene)、聚對苯二甲酸乙二醇酯（ polyethylene terephthalate)及三醋酸纖維素（ triacetyl cellulose)所組成之群组或其組合。該樹 月曰3 0係選自於由光硬化樹脂及熱硬化樹脂_所組成之群組 ，其中該光硬化樹脂係選自於單體及寡聚物之任一種， s玄早體係選自於由-異丁基丙稀薇S旨isobuty 1 ac-rylate)、2-乙基己基丙烯酸酯（2-ethylhexyl ac-rylate) 、1，6_ 己—酵,一丙稀酸醋（1，6-hexanediol diacrylate)、三丙二醇二丙稀酸醋（tripropylene glycol diacrylate)、三烴曱基丙烧二丙稀酸酯 (trimethylolpropane diacrylate)、二季戊四醇五 丙烯酸醋（dipentaerythritol pentaacrylate)、 季戊四醇三丙稀酸酯（pentaerythritol triac-rylate)及二季戊四醇六丙稀酸酯（dipentaeryth- 099122070 表單編號A0101 第7頁/共19頁 0992038860-0 201202752 ritol hexaacrylate) ’該寡聚物係選自於由聚氨酯（ 甲基）丙稀酸S曰养聚體（urethane (meth)acrylate oligomer)、聚醋丙烤酸醋低聚物（p〇iyester (meth)acrylate oligomer)、環氧丙烯酸酯低聚物（ epoxy (meth)acrylate oligomer)所組成之群組； 該熱硬化樹脂係為無機樹脂及有機樹脂之任一種或其混 合’該無機樹脂包含有曱氧基之四曱氧基石夕烧（Tetra- methyloxysilane)、四乙氧基矽烷（Tetraethyl-oxysilane，TE0S)及聚矽酸乙酯（p〇iy(ethyl silicate))，該有機樹脂係為壓克力樹脂及環氧樹脂 之任一種。 而该起始劑係選自於由二苯甲網（benzophenone ) 、I-氫乳-環己院-苯基-嗣（1-hydroxy-cyclohexyl -phenyl-ketone)、2-羥基-2-曱基-1 -苯基-1 -丙酮 (2-hydroxy-2-methyl -l-phenyl-1-propanone) '苯甲醯甲酸甲酯（methyUenzoylformate)及三芳 基硫型六氟鱗鹽（triaryls:u'fo.nuiura hexafl uoro-antimonate salts)所蠢成之群組。 該硬化劑係選自於由氣化氫、硝酸、氨、偶氮二異丁 晴（2-2-Azobis(isobutyronitrile)， AIBN)、偶 氮二異庚晴（2,2’-〇 With the advancement of optoelectronic technology, the research of anti-reflective optical films has become an important development technology. The study of anti-reflective optical films is very widely used in the field of optics. Anti-reflection films on the surface of optical components can enhance the overall performance of optical instruments. In recent years, liquid crystal displays (LCDs) have been widely used in various modern electronic products, such as personal computers, notebook computers, digital cameras, mobile phones, PDAs, and liquid crystal televisions (LCD TVs). Since the external light is about 4 to 5% reflective when it illuminates the surface of the glass or plastic substrate on the surface of the display, the liquid crystal display is easily interfered by external light when it is used, which affects the visual effect of the screen. Especially for LCD TVs larger than 2 inches, the effect of external light reflection on the surface of the screen is more obvious. v. In order to solve the interference of external light, the anti-glare film is widely used due to obvious factors such as dare and low cost. On the LCD screen of the notebook computer and computer. 1 is a schematic view showing the structure of an anti-glare film according to a conventional technique. The anti-glare film is added by anti-glare particles to achieve an anti-glare effect, as shown in the figure: the anti-glare film structure comprises a substrate 1 An anti-glare film coating 2 disposed on the substrate 1 'the anti-glare film coating 2 comprises a resin 3 and a light-scattering particle 4', which is prepared by coating an anti-glare film coating solution On the substrate 1, the solvent contained in the anti-glare coating liquid is evaporated through a box, and then the resin 3 in the anti-glare coating liquid is hardened by ultraviolet light irradiation or a soft box. 099122070 Form No. A0101 Page 3 of 19 0992038860-0 201202752 The anti-glare film coating 2 should be formed. The light-scattering particles 4 in the anti-glare film coating layer 2 are uniformly dispersed in the anti-glare film coating liquid when the anti-glare film coating liquid is just coated on the substrate 1, when the anti-glare film coating liquid is used After the solvent is evaporated, the resin 3 and the light-scattering particles 4 gradually settle to form the anti-glare film coating 2. Since the solvent of the anti-glare film coating liquid evaporates, the force between the solvent and the resin 3, the solvent and the light-scattering particles 4, and the resin 3 and the light-scattering particles 4 is complicated, so that the light-scattering particles 4 are dried. It is then randomly distributed in the anti-glare film coating 2. However, the above technique cannot control the distribution of the light-scattering particles 4 in the anti-glare film coating 2, and the haze of the anti-glare film cannot be effectively controlled. [0004] For example, "Anti-glare hard coat film and process for producing the film", U.S. Patent Publication No. 6217176, "Antiglare film and use thereof", and US Patent Publication No. 6613426B2, Veryy Fine apti-glare hard coat film" 'Anti-glare film and process for producing same thereof", US Patent Publication No. 6,896,960, 'Anti-glare hard coat film', US Patent Publication No. The contents disclosed in "Anti_ glare film and process for producing the same" of 7 〇 33638 B2, which disclose various methods or materials for producing anti-glare films, which mainly utilize the size and number of light-scattering particles and resin The thickness of the layer is used to control the haze of the anti-glare film. In addition, as in the Republic of China Patent Publication No. 557363, the 'anti-glare film', the Republic of China Patent Publication No. 590886, the method of forming an anti-glare anti-reflection film"中099122070 Form No. A0101 Page 4 of 19 Page 0992038860-0 201202752 [0005] China National Patent Announcement No. Μ252022, 'No.+,, now optical anti-glare film,', which also discloses methods and materials for controlling the haze of the anti-glare film by using the light scattering particles, the small amount and the thickness of the resin layer. Due to the limitations of the coating equipment, it is not easy to adjust the coating process. Therefore, if an anti-glare film with different haze is to be produced, the formulation of the anti-glare coating liquid needs to be redesigned, and it is not easy to consider due to factors such as wet film thickness, optical coating liquid dryness, and the compatibility of light-scattering particles and resin. An anti-glare film with a designed haze value inside and outside is produced. 0 [0006] Ο as disclosed in Japanese Patent No. 2006-088643, the process of embossed roll" and the US Patent No. 7008066B2 "Antiglare film process f〇r producing the same, and display device using antiglare fiim" The technology 'true sun makes the surface of the coating film form a concave-convex microstructure by embossing roller to achieve anti-glare or anti-reflection effect. Although the above technology can produce anti-glare film with different haze, however, for different The manufacture of haze anti-glare film must be combined with different scraping rollers to cause:: the increase in the original. In addition, the above method can only change the external haze, and can not effectively adjust the internal haze. [0007] [Summary] The main object of the present invention is to solve the problem that the conventional technique cannot effectively control the inside and outside haze of the anti-glare film separately. Another object of the present invention is to provide an anti-glare film which is simple in preparation and low in cost. The present invention provides an anti-glare device with different internal and external haze, comprising a transparent substrate and a coating solution coated with an anti-glare film. Form No. A0101 Page 5 / 19 贞 0992038860-0 201202752 An anti-glare coating formed on a transparent substrate, wherein the anti-glare coating liquid contains a resin, a solvent, and an initiator which hardens the resin. / hardener, a resin light scattering particle and - resin resin particles. In addition, the present invention also provides a method for producing an anti-glare film with different internal and external haze, comprising five steps of W-S5, as follows Listed: 51: Wash a transparent substrate, dry for use; 52: Prepare a light-scattering particle; 53: Prepare-anti-ductive light-scattering particles, modify the silk particles prepared by step (4) by surface modification Paired tree stalking and opposite characteristic light scattering particles; 54: Fabrication - anti-glare film coating 16, the light scattering particles prepared in step 52 and step illusion and the anti-hiding scatter test The anti-glare coating liquid is obtained by adding the anti-glare coating liquid prepared in the step S4; and the anti-glare coating liquid prepared in the step S4 is applied to the transparent substrate of the step si and being dried to complete the production of the anti-glare film. In particular, the hybrids of the step Wei towel may be pro-resin light scattering particles or Resin silk particles, and * must first prepare the resin light scattering particles or first prepare the light scattering particles and the inverse characteristic light scattering particles refer to the resin light scattering particles which are different from the characteristics of the light scattering particles prepared first or According to the above description, the present invention can be manufactured by adjusting the ratios of the inner and outer hazes of four glare films by adjusting the ratios of the resin-light-scattering particles and the resin-based light-scattering particles provided in the resin. An anti-glare film conforming to different requirements is provided, and the inner material of the resin-light-scattering particle and the resin-transparent light-scattering particle are the same, and only the surface functional groups are different, which has the advantages of easy preparation and low cost. 099122070 Form No. A0101 Page 6 / Total 19 Page 0992038860-0 201202752 [Embodiment] 闺«本(四)的详细(四)和技术(四)容,即脑图式说' Ming as follows: Please refer to Figure 2 The cross-sectional structure of a preferred embodiment of the invention is not intended to be as shown. The present invention is an anti-glare film having different inner and outer haze, comprising a transparent substrate 1 and an anti-glare coating solution. An anti-glare coating layer 2〇a formed on the transparent substrate 10, wherein the anti-glare coating solution comprises a resin 30, a solvent, an initiator/hardener for hardening the resin, and a resin light. The scattering particles 4〇8 and a sparse resin light-scattering particle 50a. Further, the transparent substrate is far from glass, polyacrylate, polycarbon: acid: vinegar (.p. 〇iycarb〇nate), polyethylene (polyethylene), poly-p-phenylene A group consisting of polyethylene terephthalate and triacetyl cellulose or a combination thereof. The tree 曰 30 is selected from the group consisting of a photocurable resin and a thermosetting resin, wherein the photocurable resin is selected from any one of a monomer and an oligomer, and the smectite system is selected from the group consisting of a monomer and an oligomer. Isobuty 1 ac-rylate, 2-ethylhexyl ac-rylate, 1,6_hex-enzyme, acrylic acid vinegar (1,6) -hexanediol diacrylate), tripropylene glycol diacrylate, trimethylolpropane diacrylate, dipentaerythritol pentaacrylate, pentaerythritol triacrylate (pentaerythritol triac-rylate) and dipentaerythritol hexaacrylate (dipentaeryth- 099122070 Form No. A0101 Page 7 / 19 pages 0992038860-0 201202752 ritol hexaacrylate) 'The oligomer is selected from polyurethane (methyl) Urethane (meth)acrylate oligomer, p〇iyester (meth)acrylate oligomer, epoxy (meth)acrylate Oligomer The thermosetting resin is any one of an inorganic resin and an organic resin or a mixture thereof. The inorganic resin contains a tetramethoxy methoxy group and a tetraethoxy decane (Tetraethyl). -oxysilane, TEOS) and p〇iy (ethyl silicate), which is either an acrylic resin or an epoxy resin. The initiator is selected from the group consisting of benzophenone, 1-hydroxy-cyclohexyl-phenyl-ketone, 2-hydroxy-2-indole 2-hydroxy-2-methyl-l-phenyl-1-propanone 'methy Uenzoylformate and triarylsulfur hexafluoroscale salt (triaryls:u 'fo.nuiura hexafl uoro-antimonate salts) is a group that is stupid. The hardener is selected from the group consisting of hydrogenated hydrogen, nitric acid, ammonia, 2-2-Azobis (isobutyronitrile, AIBN), and azobisisoheptyl (2,2'-
Azobis(2,4-dimethylvaLeronitrile)， ADVN)、過 氧化苯甲醯（Benzoyl peroxide, ΒΡ0) '曱基四氫鄰 笨二曱酸肝（Methyl tetrahydro phthalic anhydride) 、 二乙浠三胺 （Diethyltriamine) 及雙氰胺 (Dicyandiamide)所組成之群組。 099122070 表單編號A0101 第8頁/共19頁 0992038860-0 201202752 再者’該親樹脂光散射粒子40a和疏樹脂光散射粒子 50a係為有機粒子及無機粒子之任一種，該無機粒子係選 自於由氧化石夕（silicon oxide)、氧化铭（aluminum oxide)、摻綈二氧化錫（antimony-doped tin oxide) 、 氧化錫 （tin oxide) 、 錄化鋅 （zinc antimon-ite)、五氧化錄（antimony pentoxide)、氧化銦錫 (indium tin oxide)及摻銘氧化辞（aluminum-doped zinc oxide, zinc antimonate) 所組成之群 組’該有機粒子可以為聚甲基丙烯酸甲酯（PMMA)、聚Azobis (2,4-dimethylvaLeronitrile), ADVN), Benzoyl peroxide (ΒΡ0) 'Methyl tetrahydro phthalic anhydride, Diethyltriamine and A group consisting of dicyandiamide. 099122070 Form No. A0101 Page 8/19 pages 0992038860-0 201202752 Further, the pro-resin light-scattering particles 40a and the resin-repellent light-scattering particles 50a are any one of organic particles and inorganic particles, and the inorganic particles are selected from From silicon oxide, aluminum oxide, antimony-doped tin oxide, tin oxide, zinc antimon-ite, and pentoxide Antimony pentoxide), a group of indium tin oxide and aluminum-doped zinc oxide (zinc antimonate). The organic particles may be polymethyl methacrylate (PMMA), poly
苯乙烯（polystyrene)及苯代三聚氰胺（benzo- ... guanamine)所組成之群組。 而溶劑之材料係選自於由異丙醇（IPA)、曱乙酮 (MEK)、甲基異丁酮（MIBK)、醋酸乙g|(EAC)、醋酸丁 S旨（BAC)、甲苯（toluene)、環己酮（cyclohexanone) 、甲醇（methanol)及丙二醇甲醚醋酸_(propylene glycol monoethyl ether acetate，PGMEA)所組成 之群組。A group consisting of polystyrene and benzo- guanamine. The solvent material is selected from the group consisting of isopropanol (IPA), acetophenone (MEK), methyl isobutyl ketone (MIBK), ethyl acetate g (EAC), butyl acetate (BAC), toluene (BAC). Toluene), a group consisting of cyclohexanone, methanol, and propylene glycol monoethyl ether acetate (PGMEA).
由上述所製成之該親樹脂先散射粒子4〇a具有與該疏 樹脂光散射粒子50a不同之表面官能基，而在本實施例中 該疏樹脂光散射粒子5〇a為該親樹脂光散射粒子4〇a表 面改質之結果。該親樹脂光散射粒子4〇a和疏樹脂光散射 粒子50a之大小介於0.5-10 um之間，更常見者為 5um，由於該親樹脂光散射粒子4〇a不會排斥該樹脂3〇， 因而沉浸在抗眩膜塗層2〇a内部，而相對的，該疏樹脂光 散射粒子50a因為較為排斥該樹脂3〇，因而分散在抗眩膜 塗層20a表層，藉由調整該親樹脂光散射粒子4〇a及該疏 099122070 表單編號A0101 第9頁/共19頁 0992038860-0 201202752 樹脂光散射粒子50a的濃度分別控制内霧度及外霧度。 請再參閱圖3所示，其係為本發明另一較佳實施例之 剖面結構示意圖，與圖2中較為不同的地方是，該疏樹脂 光散射粒子50b相互間具有聚集引力，會相互聚集形成一 較大的聚集體於該抗眩膜塗層20b中，且該聚集體突出於 該抗眩膜塗層20b的表面上，使該抗眩膜塗層20b的表面 凹凸不平，藉此控制外霧度。 本發明亦提供了一種不同内外霧度之抗眩膜的製作方 法，請參閱圖4所示，其係本發明一較佳實施例之步驟流 程示意圖，該製作方法包含有S1〜S5共五個步驟，如下 所列： 51 :將一透明基板洗淨，烘乾備用； 52 :製備一光散射粒子； 53 :製備一反特性光散射粒子，藉由表面改質將步驟S2 所製備之光散射粒子改質成對樹脂親疏特性相異之反特 性光散射粒子； 54 :製作一抗眩膜塗液，將步驟S2和步驟S3所製備之該 光散射粒子及該反特性光散射粒子以所需比例置入於一 樹脂中而得該抗眩膜塗液；及 55 :將步驟S4所製備之抗眩膜塗液塗佈於步驟S1之透明 基板上並烘乾，完成該抗眩膜之製作。 需特別說明的是，步驟說明中之光散射粒子可以為親 樹脂光散射粒子（40a、40b)或疏樹脂光散射粒子（ 50a、50b)，並不限定必須先製備親樹脂光散射粒子（ 40a、40b)或先製備疏樹脂光散射粒子（50a、50b)， 而反特性光散射粒子係指與先製備之光散射粒子特性相 099122070 表單編號A0101 第10頁/共19頁 0992038860-0 201202752 異的疏樹脂光散射粒子（50a、50b)或親樹脂光散射粒 子（40a、40b )。The pre-resinant scattering particles 4〇a produced by the above have surface functional groups different from the resin-transparent light-scattering particles 50a, and in the present embodiment, the resin-transparent light-scattering particles 5〇a are the pro-resin light. The result of surface modification of the scattering particles 4〇a. The size of the pro-resin light-scattering particles 4〇a and the resin-repellent light-scattering particles 50a is between 0.5 and 10 μm, more commonly 5 μm, since the pro-resin light-scattering particles 4〇a do not repel the resin. So, immersed in the interior of the anti-glare film coating 2〇a, and in contrast, the resin-repellent light-scattering particles 50a are dispersed in the surface layer of the anti-glare film coating 20a by repelling the resin 3〇, by adjusting the pro-resin The light scattering particles 4〇a and the thinning 099122070 Form No. A0101 Page 9/19 pages 0992038860-0 201202752 The concentrations of the resin light scattering particles 50a control the internal haze and the external haze, respectively. Please refer to FIG. 3 again, which is a schematic cross-sectional view of another preferred embodiment of the present invention. The difference between FIG. 2 and the second embodiment is that the resin-repellent light-scattering particles 50b have a concentrated attraction force and gather with each other. Forming a larger aggregate in the anti-glare film coating 20b, and the aggregate protrudes from the surface of the anti-glare film coating 20b, so that the surface of the anti-glare film coating 20b is uneven, thereby controlling Outside haze. The present invention also provides a method for fabricating an anti-glare film with different internal and external haze. Referring to FIG. 4, it is a schematic flow chart of a preferred embodiment of the present invention. The manufacturing method includes five S1~S5. The steps are as follows: 51: Washing a transparent substrate and drying it for use; 52: preparing a light scattering particle; 53: preparing a reverse characteristic light scattering particle, and scattering the light prepared in step S2 by surface modification The particles are modified into inverse-reflecting light-scattering particles having different affinity characteristics to the resin; 54: preparing an anti-glare coating liquid, and the light-scattering particles prepared in steps S2 and S3 and the inverse- characteristic light-scattering particles are required The anti-glare coating liquid is prepared by applying the ratio to a resin; and 55: applying the anti-glare coating liquid prepared in step S4 to the transparent substrate of step S1 and drying to complete the production of the anti-glare film. . It should be particularly noted that the light scattering particles in the step description may be pro-resin light scattering particles (40a, 40b) or resin light scattering particles (50a, 50b), and it is not necessary to prepare the resin light scattering particles (40a). 40b) or firstly prepare resin light scattering particles (50a, 50b), and the inverse characteristic light scattering particles refer to the characteristics of the light scattering particles prepared previously. 099122070 Form No. A0101 Page 10 / 19 pages 0992038860-0 201202752 The resin light scattering particles (50a, 50b) or the resin light scattering particles (40a, 40b).
綜上所述’由於本發明藉由調整設置於該樹脂3 〇内的 該親樹脂光散射粒子（40a、40b)及該疏樹脂光散射粒 子（5 0 a、5 0 b )的比例》辰度分別控制抗眩膜的内外霧度 ，藉此製造出符合不同需求的抗眩膜，並且，該親樹脂 光散射粒子（40a、40b)及該疏樹脂光散射粒子（5〇a 、50b)之内部材料相同，僅其表面官能基不同，具有製 備容易及低成本的優點。因此本發明極具進步性及符合 申請發明專利之要件，爰依法提出申請，祈鈞局早曰賜 准專利，實感德便。 ；| 1; 本發明更可藉由下列之較佳實施例來加以說明： 基材前處理： 將一PET基材以乙醇洗淨後’再以去離子水清洗，烘乾備 用。 親樹脂光散射粒子及疏樹腊光散射粒子製作： ❹ 將0.86g PVP-40 (SIGMA-ALDRICH 公司製造）與 32ml乙醇混合1小時後，加入溶有lwt% AIBN (SHOWA 公司製造）之8ml Styrene (SIGMA-ALDRICH公司製造 )單體，並置入含有加熱回流裝置之三口圓底燒瓶，接著 通氮氣30分鐘以去除氧氣，最後將去除養氣候之物品放 置於恆溫水浴中均勻攪拌，恆溫水浴之反應溫度為70°C ，反應時間為24小時得一乳狀液體，將該乳狀液體以離 心方式清洗數次後烘乾，得到一白色粉末的親樹脂光散 射粒子。以金相顯微鏡（MICROTECH-835)量測其粒徑分 佈大致為3, 4-3. 6微米。 099122070 表單編號A0101 第11頁/共19頁 0992038860-0 201202752 取lg的親樹脂光散射粒子置於60ml樣品瓶内並加入 10ml的工業乙醇後以超音波震盪10分鐘，接著取硫酸約 2-2. 5ml緩慢滴加瓶内，直到瓶内之pH值等於0.25左右 ’再以超音波震盪1〇分鐘，最後把整杯溶液放置於7〇 °C的水浴中攪拌3小時’離心清洗並烘乾後可得疏親樹脂 光散射粒子。 以下列舉三個不同實施例以加強說明本發明之特徵： 例一： 取0. 6g之親樹脂光散射粒子加入4g異丁醇中，以超音 波振動分散。再將5g季戊四醇三丙烯酸醋樹脂（In summary, the ratio of the resin light scattering particles (40a, 40b) disposed in the resin 3 及 and the resin light scattering particles (50 a, 5 0 b ) is adjusted by the present invention. The inner and outer haze of the anti-glare film are separately controlled, thereby producing an anti-glare film that meets various requirements, and the pre-resin light-scattering particles (40a, 40b) and the resin-transparent light-scattering particles (5〇a, 50b) The internal materials are the same, and only the surface functional groups are different, which has the advantages of easy preparation and low cost. Therefore, the present invention is highly progressive and conforms to the requirements of the invention patent application, and the application is made according to the law, and the prayer bureau gives the patent as early as possible. The invention can be further illustrated by the following preferred embodiments: Pretreatment of the substrate: A PET substrate is washed with ethanol and then washed with deionized water and dried for use. Production of pre-resin light-scattering particles and light-scattering light-scattering particles: ❹ After mixing 0.86 g of PVP-40 (manufactured by SIGMA-ALDRICH) with 32 ml of ethanol for 1 hour, 8 ml of Styrene dissolved in 1 wt% AIBN (manufactured by SHOWA Co., Ltd.) was added. The monomer (manufactured by SIGMA-ALDRICH) was placed in a three-neck round bottom flask containing a heated reflux device, and then nitrogen gas was purged for 30 minutes to remove oxygen. Finally, the weather-removing articles were placed in a constant temperature water bath and uniformly stirred. The reaction temperature was 70 ° C, and the reaction time was 24 hours to obtain a milky liquid. The emulsion liquid was washed several times by centrifugation and then dried to obtain a white powder of resin-light scattering particles. 6微米。 The metallographic microscope (MICROTECH-835) measured particle size distribution is roughly 3, 4-3. 6 microns. 099122070 Form No. A0101 Page 11 of 19 0992038860-0 201202752 Take lg of pro-resin light scattering particles in a 60ml sample vial and add 10ml of industrial ethanol, then vortex for 10 minutes with ultrasonic wave, then take 2-2 of sulfuric acid. 5ml slowly drip into the bottle until the pH of the bottle is equal to about 0.25' and then oscillate with ultrasonic for 1 minute. Finally, place the whole cup of solution in a water bath of 7 °C for 3 hours. Centrifuge and dry. After that, the resin light scattering particles can be obtained. Three different examples are listed below to enhance the description of the features of the present invention: Example 1: 0.6 g of the resin light scattering particles were added to 4 g of isobutanol and dispersed by ultrasonic vibration. Then 5g pentaerythritol triacrylate vinegar resin (
Sartomer公司，製造）及〇.4g [rgacure 184 (Ciba-Geigy公司製造）加入，以超音波振動分散。所得 之塗液以RDS 5號塗佈棒塗佈於聚對笨二甲酸乙二醇醋（ PET)基材上，然後置於70°C烘箱烘烤3分鐘，接著以η型 水銀燈（劑量為500〜600mJ/cm2)照射硬化，形成抗眩膜 〇 例二： 取0.6g疏親樹脂光散射漱?¥加入4g異丁醇中，以超音 波振動分散。再將5g季戊四醇三丙烯酸酯樹脂（Sartomer, manufactured by S.4g [rgacure 184 (manufactured by Ciba-Geigy)), dispersed by ultrasonic vibration. The obtained coating liquid was coated on a polyethylene terephthalate (PET) substrate with a RDS No. 5 coating bar, and then baked in an oven at 70 ° C for 3 minutes, followed by an η-type mercury lamp (dose was 500~600mJ/cm2) Irradiation hardening to form an anti-glare film. Example 2: Take 0.6g of light-repellent resin light scattering 漱? ¥4g added to 4g isobutanol and disperse by ultrasonic vibration. 5 g of pentaerythritol triacrylate resin (
Sartomer公司製造）及0.4g Irgacure 184 (Ciba-Geigy公司製造）加入，以超音波振動分散。所得 之塗液以RDS 5號塗佈棒塗佈於聚對笨二甲酸乙二醇醋（ PET)基材上，然後置於70°C烘箱烘烤3分鐘，接著以η型 水銀燈（劑量為500~600mJ/cm2)照射硬化，形成抗眩膜 〇 例三： 099122070 表單編號A0101 第12頁/共19頁 0992038860-0 201202752 取0. 3g親樹脂光散射粒子和〇. 3g疏樹脂光散射粒子 加入4g異丁醇中，以超音波振動分散。再將5§季戊四醇 三丙烯酸酯樹脂（Sartomer公司製造）及〇 4g Irga_ cure 184 (Ciba-Geigy公司製造）加入，以超音波振動 分散。所得之塗液以RDS 5號塗佈棒塗佈於聚對苯二曱酸 乙二醇酯（PET)基材上，然後置於7(TC烘箱烘烤3分鐘 ’接著以Η型水銀燈（劑量為5〇〇〜600mJ/cm2)照射硬化 ’形成抗眩膜。 以霧度計NDH-5000W(廠牌為Nippon Denshoku)進行全 光穿透及總霧度與内、外部霧度之測量結果如表1所示： 表1 *霧度計量測結果; [0009] ---— 總霧度 全光穿透 内部霧度 ------ 外部霧度 例一 -------- 32. 4 91. 3 24. 6 —~ -—, 7. 8 例二 ------- 41. 0 88. 9 15. 6 25. 4 例三 L----- 36. 3 90. 2 20, 1 16. 2 由上表可知’藉由不同濃度設置之親樹脂光散射粒子 屮... ..:¾ .... t * ; 與疏樹脂光散射攀子，可以有效的調整抗眩膜之内外霧 度。 以上已將本發明做一詳細說明，惟以上所述者，僅爲 本發明之一較佳實施例而已，當不能限定本發明實施之 範圍。即凡依本發明申請範圍所作之均等變化與修飾等 ’皆應仍屬本發明之專利涵蓋範圍内。 【圖式簡單說明】 [0010] 圖1 ’係習知技術之抗眩膜結構示意圖。 [0011] 圖2 ’係本發明一較佳實施例之剖面結構示意圖。 099122070 * 衣单蝙號A0101 第13頁/共19頁 0992038860-0 201202752 [0012] 圖3，係本發明另一較佳實施例之剖面結構示意圖。 [0013] 圖4，係本發明一較佳實施例之步驟流程示意圖。 【主要元件符號說明】 [0014] 習知技術 [0015] 1 ： 基材 [0016] 2 ： 抗眩膜塗層 [0017] 3 ： 樹脂 [0018] 4 ： 光散射粒子 [0019] 本發明： 、 [0020] 10 :透明基板 [0021] 20a、20b :抗眩膜塗層 [0022] 30 :樹脂 [0023] 40a、40b :親樹脂光散射粒子 [0024] 50a、50b :疏樹脂光散射粒子 099122070 表單編號A0101 第14頁/共19頁 0992038860-0It was added by Sartomer and 0.4g Irgacure 184 (manufactured by Ciba-Geigy Co., Ltd.) and dispersed by ultrasonic vibration. The obtained coating liquid was coated on a polyethylene terephthalate (PET) substrate with a RDS No. 5 coating bar, and then baked in an oven at 70 ° C for 3 minutes, followed by an η-type mercury lamp (dose was 500~600mJ/cm2) Irradiation hardening to form anti-glare film Example 3: 099122070 Form No. A0101 Page 12 of 19 0992038860-0 201202752 Take 0. 3g of resin light scattering particles and 〇. 3g resin light scattering particles It was added to 4 g of isobutanol and dispersed by ultrasonic vibration. Further, 5 § pentaerythritol triacrylate resin (manufactured by Sartomer Co., Ltd.) and g 4 g Irga_ cure 184 (manufactured by Ciba-Geigy Co., Ltd.) were added, and dispersed by ultrasonic vibration. The resulting coating liquid was coated on a polyethylene terephthalate (PET) substrate with a RDS No. 5 coating bar, and then placed in a 7 (TC oven for 3 minutes) followed by a mercury-type lamp (dose). For 5〇〇~600mJ/cm2), it is hardened to form an anti-glare film. The haze meter NDH-5000W (labeled Nippon Denshoku) is used for total light penetration and total haze and internal and external haze measurements. Table 1 shows: Table 1 * Haze measurement results; [0009] ---- Total haze full light penetration internal haze ------ External haze example ------- - 32. 4 91. 3 24. 6 —~ -—, 7. 8 Case 2 ------- 41. 0 88. 9 15. 6 25. 4 Example 3 L----- 36. 3 90. 2 20, 1 16. 2 As can be seen from the above table, 'Resin light scattering particles 不同....::3⁄4 .... t * ; with different concentrations of light scattering can effectively Adjusting the inner and outer haze of the anti-glare film. The present invention has been described in detail above, but the above is only a preferred embodiment of the present invention, and the scope of the present invention is not limited. Equivalent changes and modifications, etc. of the scope of the application of the present invention should still belong to the present invention. BRIEF DESCRIPTION OF THE DRAWINGS [0010] FIG. 1 is a schematic view showing the structure of an anti-glare film according to a conventional technique. [0011] FIG. 2 is a schematic cross-sectional view showing a preferred embodiment of the present invention. 099122070 * Figure 3 is a cross-sectional view of another preferred embodiment of the present invention. [0013] Figure 4 is a schematic view of a preferred embodiment of the present invention. [0013] Figure 4 is a cross-sectional view of another preferred embodiment of the present invention. [Scheme of the main components] [0014] Conventional technology [0015] 1 : Substrate [0016] 2 : Anti-glare film coating [0017] 3 : Resin [0018] 4 : Light-scattering particles [0019] The present invention: [0020] 10: transparent substrate [0021] 20a, 20b: anti-glare film coating [0022] 30: resin [0023] 40a, 40b: pro-resin light-scattering particles [0024] 50a, 50b: resin Light Scattering Particles 099122070 Form No. A0101 Page 14 of 19 Page 0992038860-0