TW201144390A - Coloring composition for use in color filter and color filter - Google Patents

Abstract

A coloring composition for use in a color filter of the present invention includes a coloring agent, a resin binder and an organic solvent. The coloring agent includes a halogenide obtained by reacting a resin with a side-chain containing a cation group with an anion dye.

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a coloring composition for a color filter used for manufacturing a color filter for a color liquid crystal display device, a color image sensor device, or the like. And a color filter having a filter segment formed using the same. [0002]

[Prior Art] In recent years, liquid crystal display devices have been highly evaluated for their thinness, space saving, light weight, or power saving, and the recent popularization of television applications has progressed rapidly. When it is applied to television applications, it is required to improve the brightness or contrast performance. For the color filters constituting the components of the color liquid crystal display device, it is also expected to improve the penetration of the near one and the height of the contrast. The method for producing a color filter is known to include: a method of dyeing a pattern by freshly forming a pattern; a transparent electrode in which a specific pattern is formed in advance; a resin containing a pigment dissolved and dispersed in a solvent by voltage application An electrodeposition method in which a pattern is formed by ionization; a printing method using, for example, offset printing using an ink containing a thermosetting resin or an ultraviolet curing resin; and a method in which a photoresist material is dispersed in a coloring agent such as a pigment A pigment dispersion method of a color resist material or the like. Recently, the pigment dispersion method has become the mainstream. However, the color filter using the pigment as a coloring agent causes the degree of polarization controlled by the liquid crystal to be disordered due to light scattering or the like caused by the pigment particles, and as a result, there is a problem that the brightness or contrast of the color liquid crystal display device is lowered. As a technique for solving this problem, a dye-containing color resist material has been proposed as a colorant. However, for dyes used in color filters, heat resistance and light resistance are required, as well as the form number of the resin constituting the color filter, A0101, page 3, page 72, 1003232411-0, 201144390, phase and grain, and for dissolving Solubility of the organic solvent of the resin. For example, Japanese Patent Laid-Open No. Hei 6-75375 discloses a color resist material in which a curable resin composition is formulated with a dye. However, since the color resist material can be baked after exposure at a low temperature, a dye having low heat resistance can be used, but the heat resistance of the dye itself is not improved. Therefore, in order to increase solubility and improve heat resistance and light resistance, a color filter using a salt of an anionic dye and a cationic compound as a coloring agent has been proposed. For example, in 曰本特开平 5_3332〇7, a toothed dye obtained by forming an anionic dye into a salt with an alkylammonium, an alkanolammonium or a cyclohexammonium is disclosed in Japanese Patent Laid-Open No. 2〇〇4_3〇7391, A halogenated dye obtained by forming an anionic dye with a naphthyl ammonium salt is disclosed. However, these halogenated dyes are also inferior in compatibility with the resin binder for the solvent used in the production of the color filter, and thus it is difficult to impart long-term storage stability for the coloring composition for color filters. And the strong adhesion between the coating film and a transparent substrate such as glass. Further, a crystalline water-based coloring material obtained by forming a cationic dye into a salt by a cationic polymer is disclosed in Japanese Laid-Open Patent Publication No. Hei. No. Hei. However, the crystalline aqueous coloring material is used for the purpose of use in a particulate state, and the use of a color filter which is required to be used in a dissolved state has not been examined in detail. Further, for example, Japanese Laid-Open Patent Publication No. 2000-352819 proposes a colored resin composition which is obtained by copolymerizing a monomer having an amine oxime structure and an anionic dye. This is achieved by the action of the amine oxime structure as a dyeing point with the anionic dye to stabilize the dye of 1003232411-0 in the coating film and to improve the tolerance. However, the method disclosed herein is 100113563. Form No. A0101 Page 4 of 72 201144390 It is a mixed solvent and an anionic dye in an organic solvent, so that a dye having a high polarity is not sufficiently dissolved, and a problem of foreign matter occurs. SUMMARY OF THE INVENTION [0003] ❹

(Problems to be Solved by the Invention) An object of the present invention is to provide a coloring composition for a color filter which is excellent in stability, and a color which is free from foreign matter and has a strong adhesion to a transparent substrate such as glass. Filter. (Means for Solving the Problem) The inventors of the present invention have earnestly accumulated research in order to achieve the above object, and as a result, have found that a resin obtained by reacting a resin having a cationic group in a side chain with a salt of an anionic dye (halogenation) The colored filter for a color filter of the product) has high storage stability, and no foreign matter is generated in the coating film, and the adhesion is good, and the present invention has been completed in accordance with this discretion. That is, a coloring composition for a color filter according to the present invention is characterized in that it contains a coloring agent, a resin binder, and an organic solvent; the coloring agent contains a toothed product, and the side of the body A resin having a cationic group in a chain is obtained by reacting with an anionic dye. In one or more aspects of the present invention, the resin-based vinyl resin having a cationic group in the side chain includes a structural unit represented by the following general formula (1); 100113563 Form No. A0101 Page 5 of 72 page 1003232411-0 201144390

Ordinary formula (1) or substituted or unsubstituted (in general formula (1), \ represents a hydrogen atom, a burnt group. w stands for a hydrogen atom, a substituted or unsubstituted burnt group, a substituted or a non-substituted base Or the aryl group of the substituted or unsubstituted aryl group W may be bonded to each other to form a ring. The taste is a sub-alkyl group, an arylene group, _cR5l_r ", which means a sub-alkyl group. Y- represents an inorganic or organic anion". Further, in one or more aspects of the present invention, the (four) valence of the vinyl-based resin containing the structural unit represented by the general formula (1) is from 1 〇 to 200 mgKOH/g. Further, in the present invention One or more of the above-mentioned subtractive substances are in an aqueous solution 'mixed with a resin having a cationic group in the side chain and an anionic dye, and the anti-anion and the anion (4) opposite to the side chain having a cationic group are removed. Further, in the case of one or more of the present invention, the organic solvent contains one selected from the group consisting of ethylene glycol vinegar (6) ycoi Acetate, aromatic alcohols and ketones. The above organic solvent. 1 or more aspects of the invention, the colorant further into a 100113563 Form No. A0101 Page 6 / Total 72 Page 1003232411-0 201144390 Ο [0004] Ο 100113563 The step contains a pigment. One or more of the present invention In the aspect, the coloring composition for a color calender sheet further contains a photopolymerizable monomer and/or a photopolymerization initiator. Further, if the color filter is provided in accordance with another aspect of the present invention, The color filter of the color filter of the present invention is formed by the coloring composition. (Effect of the Invention) In the present invention, color filter using a resin having a cationic group in a side chain and a toothed product of an anionic dye is used. The coloring composition for sheet can be used to obtain a color filter having high storage stability and having no foreign matter generated when the coating is applied, and having good adhesion. [Embodiment] Hereinafter, the present invention will be described in detail. The coloring composition for a sheet is used in a coloring agent carrier containing a resin binder and an organic solvent, and comprises a halogenated product of a resin having a cationic group in a side chain and an anionic dye. The resin having a cationic group in the side chain is used to obtain a resin having a cationic group in the side chain of the toothed product of the present invention, and is not particularly limited as long as it has at least one ammonium salt group in the side chain. However, as a suitable rust salt, if it is considered from the viewpoint of difficulty in obtaining, it is preferably an ammonium salt, an iodide salt, a sulfur salt, a diazonium salt or a scale salt. If storage stability (thermal stability) is considered, it is preferably an ammonium salt. Iodine salt and scaly salt. Further suitable is a salt. In order to prepare a coloring composition for a color filter containing the halogenated product of the present invention, it is visualized as a color filter, and is formed in a side chain form. No. 0101 Page 7 of 72 1003232411-0 201144390 The resin of the cationic group preferably has the same resin skeleton (the portion excluding the cationic group of the side chain) of the resin binder constituting the coloring composition for a color filter. In the present invention, the acrylic resin is preferably used as the resin binder, and therefore it is preferably a vinyl resin, and particularly preferably an acrylic resin. The vinyl-based resin having a cationic group in the side chain is preferably a vinyl-based resin containing a structural unit represented by the following general formula (1), and an acrylic resin is particularly preferably used.

In the general formula (1), R represents a hydrogen atom 'or a substituted or unsubstituted base. The alkyl group shown by \ is, for example, a mercapto group, an ethyl group, a propyl group, a η-fluorenyl group, an i-butyl group, a t-butyl group, an η-hexyl group or a cyclohexyl group. The alkyl group is preferably an alkyl group having 1 to 12 carbon atoms, more preferably an alkyl group having 1 to 8 carbon atoms, and a carbon group having a carbon number of 丨 4 is particularly suitable. When the alkyl group has a substituent group, the substituent group may, for example, be a trans group or an alkoxy group. \It is most preferably a hydrogen atom or a methyl group. In the general formula (1), 'R2 to R4 each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, or a substitution or no 100113563. Form No. A0101 Page 8 of 72 page 1003232411- 0 201144390 ❹ ο Replacement of aryl. Here, the alkyl group represented by R2 to R4 may, for example, be a linear alkyl group (methyl, ethyl, n-propyl, n-butyl, n-pentyl, n-octyl, n-dodeyl, n-tetradecyl). Base, n-hexadecyl and n-octadecyl, etc., branched alkyl (isopropyl, isobutyl, secondary butyl, tert-butyl, isopentyl, neopentyl, tertiary pentyl, dissident Base, 2-ethylhexyl and 1,1,3,3-tetradecylbutyl, etc., cycloalkyl (cyclopropyl, cyclobutyl, cyclopentyl and cyclohexyl, etc.), and bridged cyclic alkane Base (norbornyl, adamantyl and fluorenyl). The alkyl group is preferably an alkyl group having 1 to 18 carbon atoms, and more preferably an alkyl group having 1 to 8 carbon atoms. The dilute group represented by R2 to R4 may, for example, be a linear or branched alkenyl group (vinyl group, allyl group, 1-propanyl group, 2-propenyl group, 1-butylenyl group, 2-butene group). Base, 3-butenyl, 1-methyl-1-propenyl, methyl-2-propenyl, 2-methyl-1-propenyl and 2-methyl-2-propenyl, etc., cycloalkenyl (2-cyclohexenyl and 3-cyclohexenyl, etc.). The alkenyl group is preferably an alkyl group having 2 to 18 carbon atoms, and is preferably an alkyl group having 2 to 8 carbon atoms. Examples of the aryl group represented by r2 to r4 include a monocyclic aryl group (phenyl group, etc.), a condensed polycyclic aryl group (naphthyl group, anthryl group, phenanthryl group, anthracene quinolinyl group, anthracenyl group, and naphthylquinoline). And the like, and an aromatic heterocyclic hydrocarbon group (thienyl group (a group derived from thiophene)), a furyl group (a group derived from furan), a pipenyl group (a group derived from a piper group). More than a bite group (base derived from a pyridine), a 9-carbonyl oxime group (a base derived from oxime), and a 9-carbonyl thioxanthyl group (a group derived from thioxanthene, etc.). With respect to r2 to r4, when the above alkyl group, alkenyl group or aryl group has a substituent group, the substituent group may, for example, be a halogen atom, a hydroxyl group, an alkoxy group, an aryloxy group, an alkenyl group, a decyl group or an alkoxycarbonyl group. a selected substituent such as a carbonyl group or a phenyl group. The substituent group is preferably an atom of an atom, a hydroxyl group, an alkoxy group or a phenyl group. 100113563 Form No. A0101 Page 9 of 72 1003232411-0 201144390 From the viewpoint of stability, r2 to r4 should be substituted or unsubstituted alkyl, and more preferably a non-substituted base. Also, R. ~R, two of them are combined to form a ring. In the general formula (1), the Q group linking the vinyl group and the ammonium salt group means an alkylene group, an arylene group, -CONH-R9- or -C00-R9-, and R5 represents an alkylene group. Among them, from the viewpoint of the polymerizability of the monomer containing the vinyl-based resin having the structural unit represented by the general formula (1-2), and the difficulty of obtaining it, 0 is preferably -C0NH-R9- or -C00-R9-. Further, R5 is more preferably a methyl group, an ethane group, a propane group or a butylene group, and particularly preferably an ethane group. The oxime (reverse anion) in the general formula (1) may be an inorganic or organic anion. The counter anion may be any conventional one, and specifically, a halide ion such as a hydroxide ion, a vapor ion, a bromide ion or an iodide ion; a carboxylate ion such as a formate ion or an acetate ion; a carbonate ion; a mineral acid ion such as a hydrogencarbonate ion, a nitrate ion, a sulfate ion, a sulfite ion, a chromate ion, a potassium dichromate ion, a phosphate ion or a permanganate ion; a cyanide ion; and further, such as iron hexacyanoferrate (III) ) Complex ions such as acid ions. From the viewpoint of synthetic suitability or stability, it is preferably a halide ion and a carboxylate ion, and is most preferably a halide ion. When the counter anion is an organic acid ion such as a carboxylic acid ion, the organic acid ion is organically bonded to the resin skeleton, and the organic acid ion may form a cationic group or an intramolecular salt of the side chain. The ethylenic resin containing the structural unit represented by the general formula (1) is generally a copolymer resin. In order to obtain such a copolymer resin, not only a method of copolymerizing an ethylenically unsaturated monomer having an amine group with an oligomer but also copolymerizing an ethylenically unsaturated monomer having an amine group with an oligomer can be obtained. The method for obtaining a copolymerized resin having an amine group and reacting with a hydrazine chlorinating agent and vaporizing ammonium is 100113563, Form No. A010] Page 10 of 72, 1003232411-0 201144390. The following shows an ethylenically unsaturated monomer which can be used to obtain a vinyl resin containing a structural unit represented by the general formula (1). In addition, in the case of "one or both of the acryl group and the methacryl group", it is described as "(meth)acryl group". Similarly, when one or both of "propylene hydride and/or methacryl oxime" is indicated, it may be described as a plant (mercapto) acrylamide. The ethylenically unsaturated monomer having a 4-stage ammonium salt group may, for example, be: (Kemi)

Propylene oxime oxyethyl trimethylated ammonium hydride, (meth) propylene oxiranyl triethyl transpiration, (meth) propylene oxiranyl oxymethyl dimethylation, (meth) propylene Alkyl (meth) acrylate such as ammonium morpholine morpholine is a fourth-order salt, (meth) acrylamide propyl tridecyl vaporized, (meth) acrylamide Ethyl diethylammonium hydride, (mercapto) acrylamide ethyl dimethyl sulfhydryl group gasification money! Base (methyl) acrylamide amine grade 4 money salt; Dilyl propyl sulphate; and trimethyl ethyl phenyl chlorinated. The ethylenically unsaturated monomer having an amine group may, for example, be a dimercaptoamine ethyl group (

Methyl) acrylic acid vinegar, monoethylamine ethyl (methyl) propyl ketone, dipropylamine ethyl (meth) acrylate, diisopropylamine ethyl (methyl) propyl Dilute ester, dibutylamine ethyl (mercapto) acrylate, diisobutylamine ethyl (meth) acrylate vinegar, a 'secondary butyl amine ethyl (mercapto) propylene Dilute acid, dimethylaminopropyl (mercapto) acrylate, diethylamine ethyl (mercapto) acrylate, diethylaminopropyl (mercapto) acrylamide, dipropylamine Propyl (meth) acrylamide, diisopropylamine propyl (meth) acrylamide, dibutylamine propyl (meth) acrylamide, diisobutylaminopropyl (decyl) a (meth) acrylate or (meth) acrylamide having a dialkylamine 100113563 group, such as acrylamide, di-tertiary-butylaminopropyl (decyl) acrylamide, etc.; Form No. A0101 Page 11 of 72 1003 201144390 Styrenes with dialkylamine groups such as methylamine styrene and dimethylamine methyl styrene; diene such as diene methylamine and dienamine Amine compound; N_ Xi groups. An aromatic vinyl-based monomer containing an amine group such as pirone, N-vinylpyrrolidone or N-vinylcarbazole. Examples of the gasification agent include a sulfonic acid ester such as dimethylsulfuric acid, diethylsulfonic acid or dipropylsulfuric acid; a sulfonic acid ester such as a methyl sulfonate or a sulfonic acid sulfonate; An alkyl bromide such as brominated ethane, propane bromide or octyl bromide; or benzyl or benzyl bromide. The reaction of the ethylenically unsaturated monomer having an amine group with the hydrazine chlorinating agent can generally be carried out by dropping an ethylenically unsaturated monomer solution having an amine group and dropping the oxime gasifying agent below the molar amount with respect to the amine group. get on. The temperature at the time of the ammonium gasification reaction was 90. (Below the degree, especially when the vinyl monomer is subjected to ammonium gasification, it is preferably about 3 Torr or less, and the reaction time is about 1 to 4 hours. Further, 'alkoxycarbonyl alkyl toothing can also be used as the hydrazine gas. The carbonyl carbonyl halide can be represented by the following general formula (2): Z-R6-C00R7 is generally the formula (2) (in the general formula (2), z is a halogen such as chloro! Bromine; r6 is a calcined group having 1 to 6 carbon atoms, preferably 1 to 5, more preferably 1 to 3; R 7 is a lower alkyl group having 1 to 6 carbon atoms, preferably 1 to 3 carbon atoms. The reaction between the ethylenically unsaturated monomer and the alkoxycarbonylalkyl group can be carried out by the same procedure as the above-mentioned rust gasifying agent by calcining the oxycarbonyl group of the oxycarbonyl group with respect to the amine group. After the reaction, C00R is hydrolyzed to a carboxylate ion (-C00-), whereby an ethylenically unsaturated monomer having a carbonyl betaine structure and having an ammonium salt group can be obtained. Further, as described above, A copolymerized resin obtained by copolymerizing an ethylenically unsaturated monomer having an amine group with another ethylenically unsaturated monomer, and the above-mentioned form number A01 01 Page 2 of 2 / Total 72 pages 1003232411-0 201144390 In the same manner, a copolymer resin having a 4-stage ammonium salt group can be obtained by reacting with a sulfonium salt gasifying agent. The above comonomer can utilize an ethylenically unsaturated monomer. The ethylenically unsaturated monomer is preferably, for example, a (meth) acrylate, a crotonate, a vinyl ester, a maleic acid diester, a fumaric acid diester, an itaconate diester. Classes, (meth) acrylamides, vinyl ethers, vinyl alcohol esters, styrenes, (meth) acrylonitrile, etc. «Special examples of the mysterious vinyl group (comonomer) For example, the following compounds are mentioned.

Examples of the (mercapto) acrylates include methyl (meth) acrylate, ethyl (meth) acrylate, n-propyl (meth) acrylate, and isopropyl (decyl) propyl acrylate. Base, n-butyl (meth)acrylate, isobutyl (meth)acrylate, tert-butyl (meth)acrylate, n-hexyl (meth)acrylate, cyclohexyl (meth)acrylate, (methyl) ) Tertiary butylcyclohexyl acrylate, 2-ethylhexyl (meth) acrylate, trioctyl (meth) acrylate, dodecyl (decyl) acrylate, octadecyl (decyl) acrylate, (A) Ethyl ethoxide ethyl acrylate, (mercapto) acrylic acid, 2-hydroxyethyl (meth)propionate, 2-methoxyethyl (meth) acrylate, (methyl) 2-ethoxyethyl acrylate, 2-(2-methoxyethoxy)ethyl (decyl) acrylate, 3-phenoxy-2-hydroxypropyl (meth) acrylate, (methyl) Benzyl acrylate, (meth)acrylic acid diethylidene monodecyl ether, (mercapto)acrylic acid diethylene glycol monoethyl ether, (meth)acrylic acid triethylene glycol monoterpene Ether, (dimercapto)acrylic acid diethylene glycol monoethyl mystery, (mercapto)acrylic acid polyethylene glycol monomethyl hydrazine, (fluorenyl) acrylic acid polyethylene glycol monoethyl ether, (meth)acrylic acid Phenoxyethoxyethyl, nonylphenoxy polyethylene glycol (meth)acrylate, dicyclopentenyloxyethyl (meth)acrylate, trifluoroethyl (meth)acrylate, (100113563 form No. A0101 Page 13 of 72 1003232411-0 201144390 Mercapto) octyl fluoride acrylate, perfluorooctyl (meth) acrylate, dicyclopentyl (meth) acrylate, (meth) acrylate Bromophenyl, (fluorenyl) tribromophenoxyethyl acrylate, and the like. Examples of the crotonic acid vinegar include exemplified by 0 vinyl esters such as crotonic acid butyl group and crotonyl hexyl group, and examples thereof include vinyl ethyl ester, ethylene propyl ester, ethylene butyl ester, ethylene oxime ethyl ester, and benzoic acid ethylene. . Examples of the maleic acid diesters include dimethyl maleic acid, diethyl maleate, and dibutyl butyl bromide. Examples of the fumaric acid diesters include dimethyl fumarate, diethyl fumarate, and dibutyl fumarate. Examples of the itaconic acid diesters include diamyl itaconate, diethyl itaconate, and dibutyl itaconate. Examples of the (mercapto) acrylamides include (fluorenyl) acrylamide, N-methyl (meth) acrylamide, N-ethyl (meth) acrylamide, and N-propyl ( Mercapto) acrylamide, N-isopropyl (meth) acrylamide, N-n-butyl (meth) acrylamide, N-tert-butyl (meth) acrylamide, N-ring Hexyl (meth) acrylamide, N-(2-methoxyethyl) (meth) acrylamide, N,N-dimercapto (meth) acrylamide, N,N-diethyl ( Methyl) acrylamide, N-phenyl(fluorenyl) acrylamide, N-benzyl (meth) acrylamide, (fluorenyl) propylene hydrazino, diacetone acrylamide, and the like. Examples of the vinyl ethers include mercapto vinyl ether, butyl vinyl ether, hexyl vinyl ether, and methoxyethyl vinyl ether. Examples of the styrenes include stupid ethylene, methyl stearrene, dimercaptostyrene, trimethylstyrene, ethylstyrene, isopropylstyrene, butylstyrene, hydroxystyrene, and oxime. Styrene, butoxy-oxyethylene, ethoxylated styrene, fluorostyrene 100113563 Form No. A0101 Page 14 of 72 1003232411-0 201144390, fluoroethylene, bromostyrene, fluoromethylstyrene, The base styrene, the ethylene benzoic acid methyl group, and the α-methyl styrene which are protected by the acid J·biomass removal protecting group (for example, tertiary B 〇c, etc.). Further, the ethylenically unsaturated monomer as a comonomer may have an acid group. Examples of the ethylenically unsaturated monomer having an acid group include unsaturated monocarboxylic acids such as acrylic acid, methacrylic acid, crotonic acid, gaseous acrylic acid, and cinnamic acid; maleic acid and maleic anhydride 'fubutene Unsaturated dicarboxylic acid or anhydride thereof such as diacid, itaconic acid, itaconic anhydride, citraconic acid, tococanic anhydride, mesaconic acid; unsaturated polyvalent carboxylic acid or anhydride thereof having a valence of 3 or more; succinic acid Mono(2-propenyloxyethyl), succinic acid mono(2-mercaptopropenyloxyethyl), phthalic acid mono(2-propenyloxyethyl), phthalic acid mono (2_A) Mono-[(methyl) propylene oxide oxyalkyl] vinegar of valence carboxylic acid having a valence of more than 2 valences; ω-rebel-polycaprolactone monoacrylic acid ester, ω- a mono(indenyl) acrylate having a terminal carboxyl group such as a carboxy-polycaprolactone monomethacrylate or the like. A method for obtaining an ethylene-based resin having a structural unit represented by the general formula (1) as suitable for the present invention can be carried out by anionic polymerization, living anionic polymerization, cationic polymerization, living cationic polymerization, radical polymerization, and living radical polymerization. Methods. Among them, radical polymerization or living radical polymerization is preferred. In the case of living radical polymerization, a polymerization initiator is preferably used. As the polymerization initiator, an azo compound and an organic peroxide can be used. Examples of the azo compound include 2,2'-azobisisobutyronitrile, 2,2'-azobis(2-mercaptobutyronitrile), and 1,1'-azobis(cyclohexane). 1 -carboxonitrile), 2,2 '-azobis(2,4-dimethylvaleronitrile), 2,2'-azobis(2,4-dimethyl-4-methoxyvaleronitrile) , dimethyl 2,2'-azo double (2 100113563 Form No. 101 0101 Page 15 / Total 72 Page 1003232411-0 201144390 - Methyl propionate), 4,4' ~ Azobis (4-cyano) Valeric acid), 2,2-azobis(2-hydroxymethylvaleronitrile) and 2,2'-azobis[2_(2-imidazolin-2-yl)propane]. Examples of the organic peroxide include benzoquinone peroxide, tertiary hydrogen peroxide butadiene, diisopropyl peroxycarbonate, di-n-propyl peroxycarbonate, and di(2-ethoxyethyl). Peroxycarbonate, tertiary butyl peroxy neoacetate, (3,5,5 tridecyl hexanyl) peroxide, dipropyl decyl peroxide, and diethyl hydrazine peroxide. These polymerization initiators may be used singly or in combination of two or more. The polymerization temperature is preferably from 4 Torr to 150 ° C, more preferably from 50 to Π 0 ° C, and the polymerization reaction time is preferably from 3 to 30 hours, more preferably from 5 to 20 hours. The living radical polymerization method suppresses the side reaction which occurs in general radical polymerization, and further increases the polymerization growth, so that the block polymer or the resin having the same molecular weight can be easily synthesized. Among them, the atomic mobile radical polymerization method using an organic halide or a halogenated compound as a starting agent and a transition metal complex as a catalyst can be adapted to a wide range of monomers. It is more suitable in terms of the polymerization temperature of the equipment. The atomic mobile radical polymerization can be carried out by the methods described in the following References 1 to 8. (Reference l) Fukuda et al.

Prog.Polym' Sci.20 04, 29, 329 (Reference 2) ^^1;7』&326\¥51^ et al., (:1^111.1^¥2〇〇1, 101, 2921 (Reference Document 3) Matyjaszewski et al., J. Am. Chem. Soc. 1995, 117, 5614 (Reference 4) Macromolecules 1 995, 28, 7901,

Science , 1996 , 272 , 866 100113563 Form No. A0101 Page 16 / Total 72 Page 1003232411-0 201144390 (Reference 5) W096/030421 (Reference 6) W097/018247 (Reference 7) 曰本特开平 9-208616 Japanese Laid-Open Patent Publication No. Hei 8-41117. The organic solvent is preferably used in the above polymerization, and the organic solvent is not particularly limited.

However, for example, ethyl acetate, n-butyl acetate, isobutyl acetate, toluene, xylene, propylene, ketone, methyl ethyl ketone, cyclohexanone, propylene glycol monomethyl ether ethyl ester, dipropylene glycol monomethyl can be used. Ethyl ether ethyl ester, ethylene glycol monoethyl ether ethyl ester, ethylene glycol monobutyl ether ethyl ester, diethylene glycol monoethyl ether ethyl ester or ethylene glycol monobutyl ether ethyl ester. These polymerization solvents may be used in combination of two or more kinds. The amount of the ammonium salt group which is suitably present in the vinyl-based resin containing the structural unit represented by the general formula (1) is not particularly limited, but the ammonium salt of the resin is preferably 10 to 200 mgKOH/g, more preferably 20~13〇mgK〇H/g

. When the ammonium salt value is less than 1 〇 mg K 〇 H / g, the ratio of the anionic dye of the reaction becomes small, so the coloring power is lowered, and more halogenated product is required in the resist material. Therefore, the resin binder or the curable resin or the like which is originally added to the resist material is reduced, and the glass adhesion of the resist film may be deteriorated or the coating film resistance of the resist film may be deteriorated. On the other hand, when it is more than 200 mgKOH/g, the solvent solubility of the self-chemical product deteriorates as a foreign matter and precipitates in the anti-surname material. In addition, the ammonium salt group valence is equivalent to the so-called full salt base price, and the salt group (cationic group) existing in the vinyl resin containing the structural unit represented by the general formula (1) has only an ammonium salt group. Therefore, an ammonium salt group is used in the present specification. In the present invention, the ammonium salt valence is used to neutralize the total ammonium salt group of 1 gram of the vinyl resin containing the structural unit represented by the general formula (1) 100113563. Form No. A0101 Page 17 / Total 72 Page 1003232411 -0 201144390 The desired number of milligrams of potassium hydroxide (K OH) equivalent to silver nitrate. The molecular weight of the vinyl-based resin containing the structural unit represented by the general formula (1) used in the present invention is not particularly limited, but the converted weight average molecular weight measured by a gel permeation chromatography (GPC) is preferably 1,000. ~500,000, more preferably 3,000~150,000. Further, the vinyl-based resin containing the structural unit represented by the general formula (1) which is suitable for the present invention preferably has a property of being dissolved in a solvent which is widely used for a coloring composition for a color filter. Thereby, a coating film which does not generate foreign matter can be obtained. It is especially preferred to dissolve in propylene glycol monomethyl ether ethyl ester. In the resin having a cationic group in the side chain, the total content of the structural unit represented by the above general formula (1-2) is not particularly limited, but the total structural unit contained in the resin having a cationic group in the side chain. When it is 100% by mass, the total content of the structural unit represented by the above general formula (1-2) is preferably 5% by mass or more, more preferably from the viewpoint of solvent solubility and coloring power of the halogenated product. 10 to 50% by mass. Anionic dye The anionic dye which obtains the halogenated product of the present invention may be a color-developing compound which is ion-bonded (forms a salt) to a resin having a cationic group in the side chain. The compound is not particularly limited as long as it has a carboxylic acid group, a sulfonic acid group, a phenolic hydroxyl group, a phosphoric acid group or a metal salt thereof in the molecule, and the solubility in an organic solvent or a developer can be considered. The salt forming property, the absorbance, the interaction with other components of the composition, light resistance, heat resistance and the like are appropriately selected. Examples of the anionic dye include an anthraquinone anionic dye, a monoazo anionic dye, a disazo anionic dye, a dioxazine anionic dye, an amine ketone anionic dye, and a xanthene anionic property. Dyeing 100113563 Form No. A0101 Page 18 of 72 1003232411-0 201144390 Quinoline-based anionic dyes, triphenylmethane-based anionic dyes, etc. The following 'color index numbers indicate the anionic properties that can be used to synthesize halogenated products. dye. The red dyes may be small 3, 4, 5, 6, 7, 8 9 , 1 , 11, 12, 13, 14 '15, 16, 17, 18, 19, 20 22 ' 23, 24, 25, 25 : 1, 26, 26 : 1, 26 : 2, 27, 29, 30, 31, 32, 33, 34, 35, 36, 37, 39, 40, 41, 42, 43, 44, 45, 47, 50, 52, 53, 54, 55, 56, 57, 59, 60, 62, 64, 65, 66, 67, 68, 70, 71, 73, 74, 76, 76: 1, 80, 81, 82, 83, 85, 86, 87, 88, 89, 91, 92, 93, 97, 99, 102, 104, 106, 107, 108, 11〇, iii, 113, 114, 115, 116, 12〇, 123, 125, 127, 128, 131, 132, 133, 134, 135, 137, 138, 141, 142, 143, 144, 148, 150, 151, 152, 154, 155, 157, 158, 160' 161, 163, 164, 167, Π0, 171, 172, 173, 175, 176, 177, 181, 229, 231, 237, 239, 240, 241, 242, 249, 252, 253, 255, 257, 260, 263, 264, 266, 267, 274, 276, 280, 286, 289, 299, 306, 309, 311, 323, 333, 324, 325, 326, 334, 335, 336, 337, 340, 343, 344, 347, 348, 350, 351, 353, 354, 356 , 388, etc. and c. I. Direct red 1, 2, 2: 1, 4, 5, 6, 7, 8, 10, 10: 1, 13, 14, 15, 16, 17, 18, 21, 22, 23, 24, 26, 26: 1, 28, 29, 31, 33, 33: 1, 34, 35, 36, 37, 39, 42, 43: 1, 44, 46, 49, 52, 53, 54, 55, 56 100113563 Form No. A0101 Page 19 of 72 1003232411-0 201144390 ' 57 ' 58 ' 59 ' 60 ' 61 ' 62 ' 67 ' 67 : 1 ' 68 ' 72 ' 72 : 1 ' 73 ' 74 ' 75 ' 77 ' 78 ' 79 ' 81 ' 81 : 1 ' 85 ' 86 , 88 , 89 , 90 , 97 , 100 , 101 , 101 : 1, 107 , 108 , 110 , 114 , 116 , 1 , 120 , 121 , 122, 122: 1, 124, 125, 127, 127: 1, 127: 2, 128, 129, 130, 132, 134 ' 135, 136, 137, 138, 140, 141, 148, 149, 150 ' 152 , 153 ' 154, 155 ' 156 ' 169, 171, 172, 173, 174, 175, 176, 177, 179, 180, 181, 182, 185, 186, 189, 204, 211, 213, 214, 217, 222 224, 225, 226, 227, 228, 232, 236, 237, 238, etc. can also be used as a red dye. The yellow dyes include CI acid yellow 2, 3, 4, 5, 6, 7, 8, 9, 9: 1, 10, 11, η: 1, 12' 13, 14, 15, 16, 17, 17 : 1, 18, 20, 21, 22, 23, 25, 26, 27, 29, 30, 31, 33, 34, 36, 38, 39, 40, 40: 1, 41, 42, 42: 1, 43 , 44, 46, 48 ' 51 ' 53 ' 55 ' 56 ' 60 ' 63 ' 65 ' 66, 67, 68, 69, 72, 76, 82, 83, 84, 86, 87, 90, 94, 105, 115 , 117, 122, 127, 131, 132, 136' 141, 142, 143, 144, 145, 146, 149, 153, 159, 166, 168, 169, 172, 174, 175, 178, 180, 183, 187 , 188, 189, 190, 191, 199, etc. Also, CI is directly yellow 1, 2, 4, 5, 12, 13, 15, 20, 24, 25, 26, 32, 33, 34, 35, 41, 42, 44, 44: 1 '45, 46, 48 , 49, 50, 51, 61, 66, 67, 69, 70, 71, 72, 73, 74, 81, 84, 86, 90, 91, 92, 95, 107, 110, 117, 118, 119, 120 , 121, 126, 127, 129, 132 100113563 Form No. A0101 Page 20 / Total 72 Page 1003232411-0 201144390, 133, 134, etc. can also be used as a yellow dye. The orange dyes include C. I. Acidic orange 1, 1, 1, 4, 5, 6, 7, 8, 9, 10, 12, 14, 16, 17, 18, 19, 20, 20:1. 22, 23, 24, 24: 1, 25, 27, 28, 28: 1, 30, 31, 33, 35, 36, 37, 38, 41, 45, 49, 50, 51, 54, 55, 56, 59, 79, 83, 94, 95, 102, 106, 116, 117, 119, 128, 131, 132, 134, 136, 138, and the like. Also, CI direct orange 1, 2, 3, 4, 5, 6, 7, 8, 10, 13, 17, 19, 20, 21, 24 '25, 26, 29, 29: 1, 30, 31, 32, 33 '43, 49, 51, 56, 59, 69, 72, 73, 74, 75, 76, 79, 80, 83 '84, 85, 87, 90, 91, 92, 95, 96, 97, 98, 1〇1, 1〇2, 102: 1, 104, 108, 112, 114, etc. can also be used as an orange dye. The blue dyes include CI acid blue 1, 2, 3, 4, 5, 6, 7, 8, 9, 11, 13 ' 14, 15, 17, 19, 21, 22, 23, 24, 25 26, 27, 29, 34, 35, 37, 40, 41, 41: 1, 43, 44, 45, 46, 47, 48, 49, 50, 51, 52, 53, 54, 55, 56, 57, 58, 62, 62 : 1, 63, 64, 65, 68, 69, 70, 73, 75, 78, 79 '80, 81, 83, 84, 85, 86, 88, 89 ' 90 ' 90 : 1 ' 91 ' 92, 93 ' 95 ' 96 ' 99 ' 100 ' 103 ' 104, 108, 109, 110, 111, 112, 113, 114, 116, 117, 118, 119, 120, 123, 124, 127, 127: 1, 128, 129, 135, 137, 138, 143, 145, 147, 150, 155, 159, 169, 174, 175, 176, 183, 198, 203, 204, 205, 206, 208, 213, 227, 230, 231, 232, 233, 235, 239, 245, 247, 253, 255, 257, 258, 260 100113563 Form number A0101 Page 21 of 72 page 1003232411-0 201144390, 261, 262, 264, 266, 269 , 271, 272, 273, 274, 277 '278, 280, etc. Also, CI direct blue 1, 2, 3, 4, 5'6, 7, 8, 8:1, 9, 10, 12, 14, 15, 16, 19, 20, 21, 21: 1, 22, 23 , 25, 27 ' 29, 31 ' 35, 36, 37 ' 40 ' 42, 45 ' 48, 49, 50 ' 53 ' 54, 55, 58 ' 60, 61 ' 64, 65, 67, 79, 96, 97 , 98:1, 1〇1'1〇6, 107, 108, 109, 111, 116, 122, 123, 124, 128, 129, 130, 130: 1, 132, 136, 138, 140, 145, 146 , 149, 152, 153, 154, 156, 158, 158: 1, 164, 165, 166, 167, 168, 169, 170 '174, 177, 181, 184, 185, 188, 190, 192, 193, 206 207, 209, 213, 215, 225, 226, 229, 230, 231, 242, 243, 244, 253, 254, 260, 263, etc. can also be used as a blue dye. The purple dye may be C. I·Acid Violet 1, 2, 3, 4, 5, 5: 1, 6, 7, 7: 1, 9, 11, 12, 13, 14, 15, 16, 17, 19 , 20, 21, 23, 24, 25, 27, 29, 30, 31, 33, 34, 36, 38, 39, 41, 42, 43, 47, 49, 51, 63, 67, 72, 76, 96 , 97, 102, 1〇3, log, etc. Also, CI Direct Violet 12, 13, 14, 16, 17, 18, 21, 22, 25, 26, 27, 28, 29, 30, 31, 32, 34, 35, 36, 37, 38, 39, 40 , 41, 42 , 43 , 45 , 51 , 52 , 54 , 57 , 58 , 61 , 62 , 63 , 64 , 71 , 72 , 77 , 78 , 79 , 80 , 81 , 82 , 83 , 85 , 86 87 88 '93 '97 and so on can also be used as a blue dye. The green dye can be citrate green 2, 3, 5, 6, 7, 8, 9, 10 100113563 Form No. A0101 « 99 Le μ Bei / Total 72 Page 1003232411-0 201144390 , 11, 13, 14, 15, 16 '17, 18, 19, 20, 22, 25, 25: 1 ' 27 ' 34 ' 36 ' 38 ' 40 ' 41 ' 42 ' 44 &gt; 54 ' 55 ' 59, 66, 69, 70, 71, 81, 84, 94, 95, etc. Also, CI direct green 11 ' 13, 14, 24, 30, 34, 38, 42, 49, 55, 56, 57, 60, 78, 79, 80, etc. can also be used as green dye To use. Salt formation The halogenated product of the present invention may be obtained by stirring or vibrating an aqueous solution of a resin having a cationic group and a cationic dye in a side chain, or by mixing an aqueous solution of a resin having a cationic group in a side chain under stirring or vibration. An aqueous solution of an anionic dye is easily obtained. In the aqueous solution, the cationic group of the resin and the anionic group of the dye are ionized, and the ions are combined to form a salt which is insoluble in water and thus can be removed by washing or the like. The side chain to be used has a cationic group-based resin and an anionic dye, and each of them may be a single type or a plurality of types having different structures. As the aqueous solution used for forming the salt, a resin having a cationic group in the side chain and an anionic dye are dissolved. Therefore, a mixed solution of water and a water-soluble organic solvent can also be used. The water-soluble organic solvent may, for example, be decyl alcohol, ethanol, n-propanol, isopropanol, 1-nonoxy-2-propanol, 1-ethoxy-2-propanol, n-butanol, isobutanol or 2- (methoxy methoxy) ethanol, 2-butenylethanol, 2-(isopropoxy)ethanol, 2-(hexyloxy)ethanol, 2-(hexyloxy)ethanol, diethylene glycol, diethylene Alcohol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, triethylene glycol, triethylene glycol monomethyl ether, polyethylene glycol, glycerin, tetraethylene glycol, Dipropylene glycol, propylene-, di-propanol, aniline, σ ratio bite, ethyl acetate, acetate propyl, 100113563 Form No. 1010101 Page 23 / Total 72 Page 1003232411-0 201144390 Methyl ethyl _, N, N- Dimethyl ketoamine, dimethyl sub-sector, four gas squeaking (THF), m ylang, 2 _ methyl ylang, methyl-2-indolizan, L2_hexanediol, 2, 4,6-hexanetrioltetrafuran methanol, 4-methoxy-4pentane 1 and other water-soluble solvent solutions are based on the total weight of the aqueous solution, preferably used in a ratio of 5 to 5 G% by weight. Use a ratio of ~20% by weight. The ratio of the resin having a cationic group to the anionic dye in the side chain, if the total cationic structural unit of the resin and the molar ratio of the total anionic group of the anionic dye are in the range of 1 Å/1 to 1/4, The halogenated product of the present invention is suitably prepared, and the molar ratio is preferably in the range of 2/1 to 1/2. <Pigment> The coloring composition for a color filter of the present invention may further contain a pigment. The pigment may be used alone or in combination of two or more organic or inorganic pigments. The pigment is preferably a pigment having high color rendering properties and high heat resistance, and particularly preferably a pigment which is resistant to thermal decomposition. Hereinafter, a specific example of an organic pigment which can be used for a coloring composition for a color filter will be described by a color index number. For the red coloring composition for forming the red filter and the light sheet section, for example, Pigment Red 7, 9, 14, 41, 48: 1, 48: 2, 48: 3, 48: 4 '57 may be used: 1, 81, 81: 1, 81: 2, 81: 3, 81: 4, 97, 122, 123, 146, 149, 166, 168, 169, 176, 177, 178, 180, 184, 185, 187, 192, 200, 202, 208 '209, 210, 215, 216, 217, 220, 223, 224, 226 '227, 228, 240, 242, 246, 254, 255, 264, 270, 272, 273, 276, 277, 278, 279, 280, 281, 282, 283, 284, 285, 286, and 287, etc. Red 100100563 Form No. A0101 Page 24 / Total 72 Page 1003232411-0 201144390 Material. Further, it is possible to simultaneously use orange pigments such as C. I. pigment oranges 36, 38, 43, 71 and 73 and/or Pigment Yellow 1, 2, 3, 4, 5, 6, 10, 12, 13, 14'15, 16, 17, 18, 20, 24, 31, 32, 34, 35, 35: 1, 36, 36: 1 '37, 37: 1, 40 '42, 43, 53, 55' 60 ' 61, 62 ' 63, 65, 73, 74, 77 ' 81 ' 83, 86 ' 93 ' 94 ' 95, 97, 98, 100 '101, 104, 106, 108, 109, 110, 113, 114, 115, 116, 117, 118, 119, 120, 123, 125, 126, 127, 128, 129, 137, 138, 139, 147, 148, 150, 151, 152, 153, 154, 155, 156, 161, 162, 164, 166, 167, 168, 169, 170, 171, 172, 173, 174, 175, 176, 177, 179, 180, 181, 182, 185, 187, 188, 193, 194, 198, 199, Yellow pigment such as 213, 214, 218, 219, 220 or 2 21 . The green coloring composition for forming the green filter segment may use, for example, a green pigment such as C.I. Pigment Green 7, 10, 36, 37, 58 or the like. Further, CI pigment yellows 1, 2, 3, 4, 5, 6, 10, 12, 13, 14, 15, 16, 17, 18, 24, 31, 32, 34, 35 can be used simultaneously in the green coloring composition. 35: 1, 36, 36: 1, 37, 37: 1, 40, 42, 43, 53, 55, 60, 61, 62, 63, 65, 73, 74, 77, 81, 83, 93, 95 , 97, 98, 100, 101, 104, 106, 108, 109, 110, 113, 114, 115, 116, 117, 118, 119, 120, 123, 126, 127, 128, 129, 138, 147, 150 , 151, 152, 153, 154, 155, 156, 161, 162, 164, 166, 167, 168, 169, 170, 171, 172, 173, 174, 175, 176, 177, 179, 180, 181, 100113563 Form No. A0101 Page 25 of 72 1003232411-0 201144390 Yellow pigment such as 182, 185, 187, 188, 193, 194, 198, 199, 213, 214, 218, 219, 22 0 or 221. For the blue coloring composition for forming the blue filter segment, for example, Pigment Blue 1, 1: 2, 1: 3, 2, 2: 1, 2: 2, 3, 8, 9, 10, 10: 1, 11, 12, 15, 15:1, 15: 2, 15: 3, 15: 4, 15: 6, 16, 18, 19, 22, 24, 24: 1, 53, 56 ' 56 : 1, 57, 58, 59, 60, 61, 62, 64 and other blue pigments. Further, a purple pigment such as C. I. Pigment Violet 1, 19, 23, 27, 29, 30, 32, 37, 40, 42, 50 may be used simultaneously in the blue coloring composition. The cyan coloring composition for forming the cyan filter section may be used alone or in combination, for example, CI Pigment Blue 15 : 1, 15, 2:15:4, 15:3, 15 = 6, 16, 81, etc. . The magenta colored composition for forming the magenta filter segment may be used alone or in combination to give (iv), for example, c, I. pigment purpura, 19, G. quinone pigment red 144, 146, m, 169, 81, etc. Pigments and red pigments. The yellow coloring composition can simultaneously use a yellow pigment. Further, examples of the inorganic pigment include titanium oxide, barium sulfate, zinc white, lead sulfate, yellow wrong, zinc yellow, and purple red paint (red iron oxide (1) (1), recorded red, ultramarine blue, sweet green, chrome oxide green, _, pulse, In order to obtain a balance between saturation and brightness, (4) to ensure good coatability, sensitivity, developability, etc., organic pigments are used in combination with organic pigments. When pigments are used in the present invention, from brightness and ampoules Opinion considerations, relative to the weight of the moo, the deuterated product should be in the range of _ 8_. Pigment refinement 100113563 Form bat number A0101 Page 26 / Total 72 page 1003232411-0 201144390 Pigment system added to the color composition of the present invention In order to correspond to high penetration and high contrast, it is preferable to refine by salt grinding treatment, etc. From the viewpoint of good dispersion in the colorant carrier, the primary particle diameter of the pigment is preferably 10 nm or more. Considering the high filter section, the primary particle size of the pigment should be 80 nm or less. A particularly suitable range is 20 to 60 nm. The salt milling treatment refers to the use of a kneader, a 2-roll mill, a 3-roll mill, and a ball. a mixing machine such as a grinder, an attritor, or a sand mill, while heating a mixture of a pigment, a water-soluble inorganic salt, and a water-soluble organic solvent, mechanically mixing and stirring, and removing water-soluble inorganic salts and water-soluble by washing with water. Treatment with an organic solvent. The water-soluble inorganic salt functions as a pulverization aid. In the case of salt milling, the pigment is pulverized by the high hardness of the inorganic salt. The conditions obtained by salt-milling the pigment are optimized. A pigment with a very fine particle size or a narrow distribution range and a clear particle size distribution. The water-soluble inorganic salt may use sodium chloride, barium chloride, gasification or sodium sulfate, but from the price point of view, gasification should be used. Sodium (salt salt). From the viewpoints of treatment efficiency and production efficiency, the water-soluble inorganic salt is preferably used in a ratio of 50 to 2000 parts for the 100 parts by weight of the pigment, and is preferably used in a ratio of 300 to 1000 parts. The organic solvent functions as a wet pigment and a water-soluble inorganic salt, and if it is dissolved (mixed) in water and substantially insoluble in the inorganic salt used, it is not particularly useful. However, in the case of salt milling, the temperature rises and the solvent becomes in a state of easy evaporation. Therefore, from the viewpoint of safety, it is preferably a high boiling point solvent having a boiling point of 120 ° C or higher. For example, 2-(anthraceneoxyoxy) can be used. Ethane, 2-butoxyethane, 2-(isopropoxy)ethane, 2-(hexyloxy 100113563 Form No. A0101, page 27/72, 1003232411-0, 201144390) ethane, 2-( Hexyloxy)ethane, diethylene glycol, diethylene glycol monodecyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, triethylene glycol, triethylene glycol monomethyl Ether, liquid polyethylene glycol, 1-methoxy-2-propane, 1-ethoxy-2-propane, dipropylene glycol, dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether or liquid Polypropylene glycol and the like. The water-soluble organic solvent is preferably used in a ratio of 5 to 100 parts by weight of the pigment 100 parts by weight, and is most preferably used in a ratio of 50 to 500 parts by weight. When the pigment is subjected to salt milling, the resin may be added as needed. The type of the resin to be used is not particularly limited, and a natural resin, a modified natural resin, a synthetic resin or a synthetic resin modified from a natural resin can be used. The resin to be used is preferably solid at room temperature, insoluble in water, and partially soluble in the above organic solvent. The amount of the resin used is preferably a ratio of 5 to 200 parts by weight for the 100 parts by weight of the pigment. <Resin Adhesive> The resin binder is a disperse coloring agent, particularly a substance which disperses a halogenated product and a pigment, or which dyes and permeates a halogenated product, and contains a thermoplastic resin. The resin binder is preferably in a wavelength range of 400 to 700 nm in the visible light region, and has a spectral transmittance of 80% or more, more preferably 95% or more. Further, in the case of the alkali-developing type coloring resist, an alkali-soluble vinyl-based resin obtained by copolymerizing an ethylenically unsaturated monomer containing an acidic group is preferably used. Further, in order to further enhance the light sensitivity, an active energy ray-curable resin having an ethylene-unsaturated double bond may also be used. Thermoplastic Resin The thermoplastic resin used as the resin binder may, for example, be a propionate resin, a butyral resin, a styrene-maleic acid copolymer, or a vaporized poly 100113563. Form No. A0101 Page 28 / Total 72 Page 1003232411 -0 201144390 Ethylene, gasified polypropylene, polyvinyl chloride, ethylene-vinyl acetate copolymer, polyvinyl acetate, polyurethane resin, polyester resin, vinyl resin, alkyd resin, polystyrene resin, polyamide Resin, rubber tree, smashed rubber, cellulose, polyethylene (HDpE, LI) pE), polybutylene and polyimide resin. Alkali soluble vinyl resin

The vinyl-based alkali-soluble resin obtained by copolymerizing an ethylenically unsaturated monomer having an acidic group may, for example, be a resin having an acid group such as a carboxyl group or a sulfo group. Specifically, the alkali-soluble resin may, for example, be an acrylic resin having an acidic group, an olefin-(anhydride) maleic acid copolymer, a stupid ethylene-styrenesulfonic acid copolymer, or a stupid ethylene-(meth)acrylic acid copolymer. Or an isobutylene-(anhydride) maleic acid copolymer or the like. Among them, at least one resin selected from the group consisting of an acrylic resin having an acidic group and a styrene/styrenesulfonic acid copolymer, particularly an acrylic resin having an acidic group, has high heat resistance and high transparency, and therefore is suitably used.

The active energy ray-curable resin having a double bond of ethylenic unsaturation is used as a polymer having a reactive substituent such as a hydroxyl group, a carboxyl group or an amine group, and has a reactive substitution such as an isocyanate group, an aldehyde group or an epoxy group. A resin obtained by reacting a (meth)acrylic acid compound or cinnamic acid with a light bridging group such as a (meth)acryl fluorenyl group or a styryl group. Further, by containing a (meth)acrylic acid compound having a hydroxyl group such as a hydroxyalkyl (meth) acrylate, a styrene-maleic anhydride copolymer or an α-olefin carboxylic acid-maleic anhydride is contained. A linear polymer of an acid anhydride such as a copolymer is subjected to a half esterification. A material having both an alkali-soluble energy and an energy ray-hardening property as a thermoplastic resin is also suitable as a coloring composition for a color filter. 100113563 Form No. 1010101 Page 29 of 72 5 1003232411-0 201144390 The molecular weight of the resin binder used in the present invention is not particularly limited, and the converted weight average molecular weight determined by gel permeation chromatography (GPC) is preferably 5, 000~1 00, 000, more preferably 7, 00 0~50, 0 00 ° The conversion weight average molecular weight of the resin binder is 5,000 to 10,000, which is less likely to cause film reduction during development. Moreover, at the time of development, the permeability of the non-pixel portion tends to be good, which is suitable. The resin binder is considered to have a good film formability and various kinds of resistance. The total amount of the colorant is preferably 10 parts by weight or more, and the colorant is high in concentration. The viewpoint of color characteristics should be used in an amount of 500 parts by weight or less. <Thermosetting compound> In the present invention, it is preferable to further contain a thermosetting compound in combination with a thermoplastic resin as a resin binder. When the color filter is produced by using the coloring composition of the color filter of the present invention, by containing a thermosetting compound, it reacts when the filter segment is fired, thereby increasing the bridging density of the coating film, and the filter region. The heat resistance of the segment is thus increased, and the pigment condensation at the time of firing of the filter segment is suppressed, and the effect of increasing the contrast ratio is obtained. Examples of the thermosetting compound include an epoxy compound and/or a resin, a benzoamine compound and/or a resin, a rosin-modified maleic acid compound and/or a resin, a rosin-modified fumaric acid compound, and/or Or a resin, a melamine compound and/or a resin, a urea compound and/or a resin, a phenol compound, and/or a resin, but the invention is not limited thereto. It is preferred to use an epoxy compound and/or a resin for the coloring composition for a color filter of the present invention. The epoxy compound is a low molecular compound or a high molecular weight compound such as a resin. Examples of such an epoxy resin include bisphenols (bisphenol A, bisphenol F, bisphenol 100113563, Form No. A0101, page 30/72) 1003232411-0 201144390 s double, double 酴 AD, etc.), stupid test (benzene, burn-based replacement benzene, aromatic replacement materials, miscellaneous, hydrazine-substituted naphthalene H-benzene, burn-based replacement via stupid, 4 base Naphthalene, etc., each lion (gas secret, B (four), burnt base 'secret, burning base replacement sulfhydryl, hetero, croton, cinnamon, etc.) polycondensate, stupid and various dilute compounds (two rings Pentylene dilute, (four), ethylene disulfide, norbornne dilute, ethylene dilute ice thin, tetrahydrogen, diethylene, stupid, diethylene, diisopropyl, diisopropyl , Ding Er suspected, s丄, ^, 戍, a woman, etc.) polymer, benzene

Polycondensate with ugly (propene, methyl ethyl steel, methyl isobutyl amide, acetophenone, etc.), benzene and aromatic dimethanol (benzene dimethanol, α, αα ', α, - benzene Dimethanol, stupid dimethanol 'f,, α, - double-methanol, methanol, etc.' 'Stupid class and aromatic dihaloquinones (α, α' - di-xylene, dichloromethyl Poly condensate, bisphenols and hybrids, alcohol «(4) glycidylation

The glycerin _ epoxy resin, alicyclic epoxy resin, glycidylamine epoxy resin, glycidol _ epoxy resin, etc., may be used in the case of an epoxy compound which is generally used, and is not limited thereto. These may be used alone or in combination of two or more. Commercial products can be cited, for example, £1 (:0 八丁807, £1 (:0 八?815, £?1-

COAT825, EPICOAT827, EPICOAT828, EPICOAT190P, EPIC0AT191P (above, trade name, oiled Shell Epoxy Co., Ltd.), EPICOAT1 004, EPIC0AT1 256C or higher, trade name, Japan Epoxy Resins Co., Ltd., TECHMORE VG3101L (product name, Mitsui Chemicals Co., Ltd.), EPPN-501H, 502H (trade name, manufactured by Nippon Kayaku Co., Ltd.), JER 1032H60C product name, Japan Epoxy 100113563 Form No. A0101 Page 31 of 72 page 1003232411-0 201144390

Resins Co., Ltd.), JER 157S65, 157S70 (product name, manufactured by Japan Epoxy Resins Co., Ltd.), JER152, JER154 (above, the product name, manufactured by Japan Epoxy 1^3 11^ Co., Ltd.), £0 (^ -1023, £001^-1038, EOCN-104S, EOCN1020C or higher are trade names, manufactured by Nippon Kayaku Co., Ltd.), CELLOXIDE 2021, EHPE-3150 (above, trade name, manufactured by Daicel Chemical Industry Co., Ltd.), DENAC0L EX -810 &gt; EX-830 ' EX-851 ' EX-512 ' EX-421 ' EX-313, EX-210, EX-111 (the above are trade names, manufactured by Nagase ChemteX Co., Ltd.), etc., but not limited to These are the same. The compounding amount of the epoxy compound is preferably from 5% to 300 parts by weight, more preferably from 1.0 to 50 parts by weight, based on the weight of the coloring agent. If it is less than 〇.5 by weight, the heat resistance improvement effect is small, and if it is more than 3 〇 〇 weight portion, 瑕疵 may occur when the filter segment is formed by photolithography. Further, in order to assist the hardening of the thermosetting resin, the colored calender coloring composition of the present invention may contain a curing agent, a curing accelerator, and the like. The effective curing agent is an amine compound, an acid anhydride, an active ester, a carboxylic acid compound, a sulfonic acid compound, etc., but is not particularly limited thereto, and any hardener may be used if it reacts with the thermosetting resin. can. The hardening accelerator may, for example, be an amine compound (for example, dicyandiamide, benzyldimethylamine, 4-(dimethylamine)-N,N-dimethylbenzylamine, 4-methoxyl group_ N'N-dimercaptobenzylamine and 4-methyl-n,n-didecylbenzylamine, etc.; 4th ammonium compound (for example, a blocked isocyanate compound such as triethylbenzylammonium hydride ( For example, dimethylamine, etc.); imidazolyl derivative bicyclic oxime compounds and salts thereof (eg imidazolyl, 2-methylimidazolyl, 2-ethylimidazolyl 100113563, 2-ethyl-4-methylimidazole) Base, 2-styl imidazolyl form number A0101 Page 32 / Total 72 pages 4 - Phenyl hydrazine 1003232411-0 201144390 Base, cyanoethyl-2-phenylthiol and 1-(2-cyanide Base ethyl)_2_ethyl-4-methylimidazolyl, etc.; phosphorus compounds (such as triphenylphosphine, etc.); guanamine compounds (such as melamine, guanamine, acetamide, benzoguanamine, etc.); And S-triazine derivatives (for example, 2,4-diamine-6-methylpropenyl oxime oxime, 2-vinyl-2,4-diamine-6-trisole, 2-ethene base_

100113563 4,6-Diamine-S-triazine·isocyanate acid addenda and 2,4-diamine-6-methylpropyl styrene oxyethyl-S-triazine•isocyanate acid addenda, etc.). These may be used alone or in combination of two or more. The content of the hardening accelerator is preferably 0.01 to 15 parts by weight based on the weight of the thermosetting compound. <Organic solvent> The coloring composition of the present invention contains an organic solvent so that the coloring agent is sufficiently dispersed and permeated in the coloring agent carrier, and is applied to a substrate such as a glass substrate to have a dry film thickness of 〇·2 to 5#. A filter segment is formed. Examples of the organic solvent include ethyl lactate, benzyl alcohol, hydrazine, 2,3-tripropane, 1,3-butanediol, 1,3-butanediol, and 1,3-butanediol diacetate. 1,4-dioxin, 2-heptanone, 2-methyl-1,3-propanediol, 3,3,5-trimethyl-2-cyclohexene-butanone, 3,5,5-dimethyl Base ring I, 3-ethoxypropionic acid ethyl, 3-methoxy-3-butyl butyl acetate, 3-methoxybutanol, butyl 3-methoxyacetate, 4-heptanone , m-diphenyl, m-diethylbenzene, m-benzene, N,N-dimethylethenamine, n-butylbenzene, n-propyl acetate, N_D pyrrolidone, o-xylene, o-toluene, O-diethylbenzene, o-diphenylbenzene, p-benzoic acid, p-diethylbenzene, dibutylbenzene, tertiary butylbenzene, isophora, ethylene glycol diethyl ether, ethylene glycol dibutyl ether, ethylene glycol Monoethyl ether acetate, ethylene glycol monobutyl ether, ethylene glycol monobutyl ether acetate, ethylene glycol monopropyl ether, diisobutyl ketone, ring form number A0101, page 33 / total 72 pages 1003232411-0 201144390 Hexanol acetate, dipropylene glycol dimethyl ether, dipropylene glycol methyl ether acetate, dipropylene glycol monobutyl ether, diacetone , propylene glycol diacetate, propylene glycol phenyl ether, propylene glycol monoethyl ether, propylene glycol monopropyl ether, propylene glycol monomethyl ether, propylene glycol monoterpene ether acetate, propylene glycol monoterpene ether propionate, phenyl alcohol, methyl isobutyl ketone, Methylcyclohexanol, n-aminoacetate, n-butyl acetate, isoamyl acetate, isobutyl acetate, propyl acetate, divalent acid ester, and the like. Among them, from the viewpoint of dispersing and dissolving the pigment and the halogenated product of the present invention, it is preferred to use ethyl lactate, propylene glycol monodecyl ether acetate, propylene glycol monoethyl ether acetate, and ethylene glycol monomethyl ether acetate. An alcohol such as an ester or an ethylene glycol monoethyl ether acetate; an aromatic alcohol such as a benzyl alcohol; or a ketone such as cyclohexanone. In particular, from the viewpoint of safety and hygiene and low viscosity, it is more preferably propylene glycol monomethyl ether acetate. These solvents may be used alone or in combination of two or more. When two or more kinds of mixed solvents are used, the above-mentioned suitable solvent preferably contains 6 5 to 9 5 % by weight. Further, since the organic solvent can adjust the coloring composition to an appropriate viscosity to form a filter segment having a uniform film thickness, the total weight of the coloring agent is preferably 100 to 4000 parts by weight. . <Dispersion> The coloring composition of the present invention can be formed by a coloring agent carrier composed of the above-mentioned i-forming product, the above-mentioned resin binder and a solvent, and further preferably, together with a dispersing aid such as a pigment derivative, in the case of containing a pigment. It is finely dispersed and produced by various dispersing mechanisms such as a 3-roll mill, a 2-roll mill, a sand mill, a kneader or an attritor. Further, the colored composition of the present invention may be obtained by separately dispersing a pigment, a halogenated product, and other coloring agents in a colorant carrier and mixing them. 100113563 Form No. A0101 Page 34 of 72 1003232411-0 201144390 Dispersing Aid When the coloring agent is dispersed in the coloring agent carrier, a dispersing aid such as a pigment derivative, a resin type pigment dispersing agent or a surfactant may be suitably used. . The dispersing aid has a good ability to disperse the coloring agent, and the effect of preventing the re-coagulation of the dispersing coloring agent is very large, and the spectroscopic effect can be obtained when the coloring agent is dispersed in the coloring agent carrier. A color filter with high penetration. In the present invention, the role of the de-activating agent is to be subtracted.

The pigment derivative may be an organic pigment, a ruthenium roll, an acridone or a triazine, and a compound having a basic substituent, an acidic substituent or an o-benzidine imine methyl group which may have a substituent group may be mentioned. For example, Japanese Patent Publication No. Sho 63-305173, Japanese Patent Publication No. Sho 57-01562, Japanese Patent Publication No. Sho 59-40172, Japanese Patent Publication No. SHO 63-171 No. 2, Japanese Patent Publication No. 5-9469 And the like, these may be used alone or in combination of two or more.

调 攸 , , 色素 色素 色素 色素 色素 色素 色素 色素 色素 色素 色素 色素 色素 色素 色素 色素 色素 色素 色素 色素 色素 色素 色素 色素 色素 色素 色素 色素 色素 色素 色素 色素 色素 色素 色素 色素 色素 色素 色素 色素 色素 色素 色素 色素 色素 色素 色素 色素The ratio. In addition, the blending amount of the pigment derivative is preferably a weight portion or less, and more preferably a ratio of 35 parts by weight or less, based on the total weight of the added pigment. The azure type a dispersant has a pigment affinity site having a property of adsorbing to a pigment and a site compatible with a pigment carrier, and has a function of adsorbing to a colorant to stabilize the dispersion of the colorant with respect to the pigment carrier. For the specific resin type dispersant, a polycarboxylate such as polyurethane or polyacrylate can be used. 100113563 Form No. A0101 Page 35 / Total 72 Page 1003232411-0 201144390 'Unsaturated Polyamide, Polycarboxylic Acid, Polydecanoic Acid (Partial) An amine salt, a polycarboxylate ammonium salt, a polycarboxylic acid alkylamine salt, a polyoxyalkylene oxide, a long-chain polyamine guanamine phosphate, a hydrocarbon-containing polycarboxylate or a modified substance thereof, by having a polymerization An oily dispersant such as a guanamine or a salt thereof formed by reacting a polyester having a lower carboxyl group and a free carboxyl group, (meth)acrylic acid-(meth)acrylate copolymer, styrene-butylene Water-soluble resin such as acid copolymer, polyvinyl alcohol or polyvinylpyrrolidone or water-soluble polymer compound, polyester-based dispersant, modified polyacrylate-based dispersant, ethylene oxide/propylene oxide addition compound, tannic acid An ester-based dispersant or the like may be used singly or in combination of two or more kinds, but it is not necessarily limited thereto. Commercially available resin-based dispersants include 0丨5-perbyk-101, 103, 107' 108, 110, 111, 116, 130, 140, 154, 161, 162, 163, 164 manufactured by BYK-Chemie. 165, 166, 170, 171, 174, 180, 181, 182, 183, 184, 185, 190, 2000, 2001, 2020, 2090, 2091, 2164 or 2163, Anti-Terra-U, 203 and 204, BYK - P104, P104S, 220S and 6919, Lactimon, Lactimom-WS and Bykumen, SOLSPERSE 3000, 9000, 13240, 13650, 13940 '17000, 18000, 20000, 21000, 24000, 26000, 27000, 28000, 31845 by Lubrizol, Japan 32000, 32500, 32600, 34750, 36600, 38500, 41000, 41090, 53095, 55000 and 76500, EFKA-46, 47, 48, 452, LP4008, 4009, LP4010, LP4050, LP4055, 400, manufactured by Chiba Corporation, Japan. 401, 402, 403, 450 ' 451 ' 453 , 4540 ' 4550 , 4560 , 4800 ' 5010 , 5065 , 5066 ' 5070 ' 7500 ' 7554 , 1101 ' 120 , 150 ' 100113563 Form No . A0101 Page 36 / Total 72 Page 1003232411 -0 201144390 1501, 1 502 and 1 5 03. AJISPER-PA111, PB711, PB821, PB822, PB824, etc. manufactured by Ajinomoto Fine-Techno Co., Ltd.

The surfactant may, for example, be a polyethylene oxide rough sulphate sodium sulfonate, a styrene-acrylic acid copolymer acrylate, an alkyl naphthalene acid sodium, a hospital based bismuth dimercapto sodium, a lauryl sulfate. Anionic interfacial activity of ethanolamine, lauryl sulfate diethanolamine, lauryl sulfate, stearic acid ethanolamine, ammonium stearate, sodium lauryl sulfate, styrene-acrylic acid copolymer ethanolamine, polyethylene oxide ether phosphate Agent; polyethylene oxide (four), polyethylene oxide lauryl ether, polyepoxyethylene sulfonyl benzene shout, polyepoxy Ethylene squash acid vinegar, polyepoxyethylene sorbitol liver glycerol stearic acid, etc. a cationic surfactant; a bioactive dry-hybrid surfactant such as a ketone 4-grade salt or the like; an oxime dimethylamine acetic acid quaternary acid (4) a quaternary citrate inner salt; Or a surfactant, which may be used alone or in combination of two or more types. Use but not

A resin type dispersant and an interface meter-weight portion are added, and it is preferable that the ratio of the i pigment is 〇·1 to 55 parts by weight, and further, the ratio of the parts. Resin type dispersant, interface activity adjustment; 45 Addition of Yankee total (10) Weight part is small (4) Add 1 pair to add effect, shop. When it is smashed, it is difficult to obtain a fruit, and the amount of the preparation is more than 55 parts by weight, which may ring the silk. Excessive dispersion <photopolymerizable monomer> 100113563::::r product, step- or light=: want to contain =? heat (four)... into transparent tree 1003232411 201144390 fat monomer or merging, these can be separate Or use two or more types together. The amount of the monomer to be added is preferably from 5 to 400 parts by weight based on 100 parts by weight of the total amount of the coloring agent, and is more preferably from 1 to 300 parts by weight from the viewpoint of photocurability and developability. Examples of the monomer or oligomer which forms a transparent resin by curing by ultraviolet rays or heat include methyl (meth) acrylate, ethyl (meth) acrylate, and 2- phenylethyl (methyl) Acrylate, propyl propyl (meth) acrylate, cyclohexyl (meth) acrylate, b-carboxy (meth) acrylate, polyethylene glycol mono (meth) acrylate, j, 6-hexane di(di)(meth)acrylate, triethylene glycol di(meth)acrylate, tripropylene glycol di(meth)acrylate, trihydroxydecylpropane (meth)acrylate, neopentyl Tetraol (meth) acrylate, neopentyl alcohol tetrakis(meth) acrylate, dipentaerythritol penta (meth) acrylate, dipentaerythritol hexa(meth) acrylate, 1,6 - various propionic acid esters and methyl acrylates such as butanediol diglycidyl ether, bisphenol octahydroglycidyl ether, neopentyl glycol glyceryl ether, methylolated melamine, etc. )Acrylic acid, styrene, vinyl acetate, vinyl ethyl ethane, ethylene glycol diethyl sulphide, neopentyl alcohol triethylene _ (fluorenyl) acrylamide, N-methylmethyl (meth) acrylamide, N-vinylformamide, acrylonitrile, etc., but not necessarily limited to such <photopolymerization initiator> 100113563 In the coloring composition for color filter and light sheet of the invention, the composition is cured by ultraviolet irradiation. When a filter segment is formed by photolithography, a photopolymerization initiator or the like can be added. The form of the development type coloring resist material is adjusted. When the photopolymerization initiator is used, the amount is preferably 5 to 2% by weight based on the total amount of the coloring agent. 1003232411-0 Form No. A0101 Page 38 of 72 201144390 Ο

100113563 From the viewpoint of photohardenability and developability, it is more preferably ίο~150% by weight. The photopolymerization initiator can be used as a 4-phenyloxy di-acetophenone or a 4-tert-butyl-one gas. , diethoxyacetophenone, 1-(4-isopropylphenyl)2-perylene-2-methylpropan-1-ylidene, cyclohexylbenzoquinone, 2_&gt; Amine-1 -(4-morphinylphenyl)-butadiene- 1 _ net and other benzene-based compounds; benzo, benzo-bond, benzoethyl ether, benzoisopropyl ether, benzyl dimethyl condensate Benzene compound; dioxin, benzoquinone benzoic acid, benzoquinone benzoic acid methyl, 4 phenyl benzophenone, hydroxybenzhydryl, propylene benzophenone, 4-benzene a benzophenone compound such as 醯-4'-methyldiphenyl sulfide, 3,3',4,4,-tetrakis(t-butylperoxycarboxy)benzophenone; thioxanthone, 2 a thioxanthone compound such as chlorothioxanthone, 2-methylthioxanthone, isopropylthioxanthone or 2,4-diisopropylthiopyrene 2,4-diethylthioxanthene; 2,4,6-tris-orthotriazine, 2-styl _4,6_bis(trimethylmethyl)-o-triazine, 2-(p-methoxybenzene) Base)_4,6_bis(trichloromethyl)-o-triazine, 2-(p-tolyl)-4, bis(trichloroindenyl)-o-triazine, 2-piperidin-4,6-double ( Tris-methyl)-orthotriazine, 2,4_bis(trimethylmethyl)-6-phenylethendyl-o-triazine, 2-(naphtho- 1 -yl)-4,6-double (three Gas methyl)-orthotriazine, 2_(4-methoxynaphthalenyl) 4,6-bis(dimethylmethyl)-o-trimethylene, 2,4-tris-methyl-(piperidinyl) a triazine-based compound such as -6-triazine, 2,4-tris-methyl (4'-decyloxystyryl)-6-triazine; hydrazine, 2 _octanedione, 1 - [4 - ( Phenylthio)-,2(0-benzopyrene)], 〇_(acetamidine)-1'}-(1-styl-2-reoxa-2-(4,-methoxy-naphthyl) An oxime ester compound such as ethylene)hydroxylamine; a phosphine compound such as bis(2,4,6-trimercaptobenzo)phosphonium phosphine or 2' 4,6-dimethyl cumene oxide phenylphosphine 39 pages / a total of 72 pages, form number A0101 1003232411-0 201144390; 9, 10 - quinone compounds such as phenanthrenequinone, camphorquinone, ethyl hydrazine; boric acid S-based compounds; oxazole compounds; or imidazole compounds. These photopolymerization initiators may be used alone or in combination of two or more kinds in any ratio as needed. The photopolymerization initiator is a total weight of the coloring agent in the coloring composition for a color filter, preferably a ratio of 5 to 200 parts by weight, from the viewpoints of photocurability and developability. More preferably, it is a ratio of 10 to 150 parts by weight. <Sensitizer> The coloring composition for a color filter of the present invention may further contain a sensitizer. Examples of the sensitizer include unsaturated ketones represented by flavonoid derivatives or dibenzylideneacetone, 1,2-dione derivatives represented by benzyl or camphorquinone, benzo derivatives, and hydrazine derivatives. , naphthoquinone derivatives, anthracene derivatives, oxime derivatives, thiopurine derivatives, oxime derivatives, thio. Polymethine pigments, acridine derivatives, azabenzene derivatives, etc., such as xanthene derivatives, coumarin derivatives, coumarin derivatives, cyanine derivatives, merocyanine derivatives, and cyanine derivatives , diene terpene derivative, oxazine derivative, porphyrin derivative, imprinted derivative, rust salt derivative 'squaraine rust salt derivative, porphyrin derivative, tetraphenylporphyrin derivative 'Sanfang a decane derivative, a tetrabenzopyroline derivative, a tetrapyrazine porphyrin derivative, a phthalocyanine derivative, a tetrazoporphyrin derivative, a tetraquinoxaline porphyrin derivative, naphthalene 100113563 phthalocyanine, Subphthalocyanine derivative, pyridinium salt derivative thiopyrazole salt charm, four. Bulun organism, ceramide, snail derivative, snail derivative, thio-spiroside derivative &amp; metal arsenic complex, organic ruthenium complex, Mie _ derivative, α _ Orbital base, brewed base hydride, tolyl (IV), benzyl-9, 10-phenanthrene and form number Α0101 Page 40 / Total 72 pages 1003232411-0 201144390 Durene, camphor, ethyl蒽醌, 4,4, _diethyl hydrazide, 3,3' or 4,4'-tetrakis(tert-butylperoxy decyl)benzophenone, 4,4 '-dimethylamine Anthrone and the like. Specifically, 'the color of the pigments manual (1 986, Kodansha), Dahe Yuanxin, etc., "Chemistry of Functional Pigments" (1981, CMC) and Chisam Sang Sanlang, etc. The sensation agent described in "Special Functional Materials" (me year, CMC) compiled by the person is not limited to these. Further, the "other" may contain a sensitizer which exhibits absorption of light from the material to the near-infrared region. It is also possible to use two or more sensitizers at any ratio as needed. When the sensitizer is used, the amount of the photopolymerization initiator contained in the coloring composition is 1 part by weight, which is preferably a ratio of 3 to 6 parts by weight, from photocurability and developability. The viewpoint of consideration is more preferably a ratio of 5 to 5 parts by weight. <Amine compound> The coloring composition for a color filter of the present invention may contain an amine compound having a function of reducing dissolved oxygen. The amine-based compound may, for example, be triethanolamine, mercaptodiethanolamine, triisopropanolamine, 4-dimethylamine benzoic acid methyl, 4-didecylamine benzoic acid ethyl, 4-dimethylamine. Benzoic acid 2-ethylhexyl and N,N-dimethyl-p-toluidine and the like. <Leveling Agent> A leveling agent is preferably added to the coloring composition of the present invention in order to improve the leveling property of the composition on the transparent substrate. The leveling agent is preferably dimethyloxoxime which has a polyether structure or a polyester structure in the main chain. Specific examples of the dimercaptooxyl having a polyether structure in the main chain include, for example, T〇RAY·D〇w 100113563, Form No. A0101, Page 41/72, 1003232411-0, 201144390 匸〇1^ The company's ^-2122 and 6-generation company system 奵 _ _ 333. Specific examples of the dimethyl decane having a polyacetate structure in the main chain include BYK-310 and ΒΥΐ (_37〇#) manufactured by BYK Co., Ltd., and can also be used in the main chain having a poly-structure. Methyl decane and dimethyl methoxy olefin having a polyester structure in the main chain. The content of the leveling agent is generally based on the total weight of the coloring composition, 〇. 〇〇3~〇 [% by weight. A particularly suitable leveling agent is a compound having a hydrophobic group and a hydrophilic group in the molecule, which has a hydrophilicity and a low solubility in water, and is added to the coloring composition. When the material has a characteristic of low surface tension reducing ability, and even if the surface tension reducing ability is low, it is useful for a material having good lubricity of a glass plate, and it is preferable to use a coating amount which is caused by no foaming. Internally, the chargeable substance can be sufficiently suppressed. The leveling agent having the appropriate characteristics of the shaft should preferably use a fluorene unit having a polycyclic ring unit. The polycyclic unit includes a polyethylene oxide unit and a polyepoxy unit. '·Dimethyl 7 oxygen hospital can also have Both the polyethylene oxide unit and the polyepoxy propylene unit. The combination of the oxidized oxygen unit and the dimethyl (tetra) oxygen chamber can be any of the following types: the conversion unit is in the repeat unit of the dimethyl money institute. Pendant type; polyepoxy burning unit combined with dimethyl ketone burning end ^ end known modified type; and polyepoxy burning unit and dimethyl oxime oxy-alonge repeated recombination of linear block copolymer Types of dimethyl sulphate units with polyepoxy firing units are commercially available from T〇RAY.D〇wc〇rning/A\: for example, FZ-211〇, F7 r, mi22, FZ-2130, FZ-2l66, F7_, FZ-22G3, FZ-22Q7, but not limited to these. 100113563 Uniform dye can also be added to the _ sub-, cationic form number side 1 " _721 non-201144390 sub- Or an amphoteric surfactant. It is also possible to use a surfactant in a mixture of two or more. The anionic surfactant which is auxiliaryly added to the leveling agent may be a polyethylene oxide ether sulfate or a dodecyl group. Sodium benzene sulfonate, styrene-acrylic acid copolymer acrylate, alkyl naphthalene sulfonate, alkyl diphenyl ether disulfonate, laurel Ethylamine sulfate, triethanolamine lauryl sulfate, ammonium lauryl sulfate, ethanolamine stearate, ammonium stearate, sodium lauryl sulfate, monoethanolamine of styrene-acrylic acid copolymer, and poly(ethylene oxide ether) phosphate. The cationic surfactant of the auxiliary leveling agent may, for example, be an alkyl 4-grade ammonium salt or the like, and an epoxy-containing ethigen addition. The non-ionic surfactant which is auxiliaryly added to the leveling agent may be a polycyclic ring. Oxyethylene ether ether, polyethylene oxide lauryl ether, polyethylene oxide nonylphenyl ether, polyethylene oxide ether phosphate, polyethylene oxide sorbitan glyceryl stearic acid, polyethylene glycol single laurel An amphoteric surfactant such as an alkyl quaternary ammonium carboxylate inner salt such as an ester or an alkyl dimethylamine acetic acid quaternary ammonium carboxylate inner salt; or a fluorine-based or sulfhydryl-based surfactant. <Other additive components> In the coloring composition of the present invention, a storage stabilizer may be contained in order to stabilize the viscosity of the composition over time. Further, in order to improve the adhesion to the transparent substrate, a adhesion promoter such as a decane coupling agent may be contained. Examples of the storage stabilizer include four-stage ammonium vapors such as τ-based trimethyl chloride and dimethylhydroxylamine; organic acids such as lactic acid and oxalic acid, and ethyl ether; tertiary butyl pyrocatechol; Organic phosphines such as phosphines and tetraphenylphosphines; and phosphites. The storage stabilizer is used in an amount of from 0.1 to 1 part by weight based on 100 parts by weight of the total amount of the coloring agent. 100113563 Form No. A0101 Page 43 of 72 1003232411-0 201144390 The adhesion promoter can be exemplified by the following decane coupling agents: ethylene tris(yS-methoxy with oxy) decane, ethylene ethoxy decane and ethylene trimethoxy Ethylene decanes such as decane; T-methyl propylene oxy propylene tridecyl decane (decyl) decyl acrylate; yS - (3, 4-epoxycycloalkyl) ethyl trimethoxy decane, Lu -(3,4-epoxycycloalkyl)decyltrimethoxy decane, s-(3,4-epoxycycloalkyl)ethyltriethoxydecane, yS-(3,4-epoxy Epoxy decanes such as cycloalkyl)methyltriethoxydecane, 7-glycidoxypropyltrimethoxydecane, T-glycidoxypropyltriethoxydecane; N - /5 (Amineethyl)r-Aminopropyltrimethoxydecane, N-/?(Aminoethyl)7-Aminopropyltriethoxydecane, N-/3 (Amineethyl)r-Aminopropyl A Diethoxy decane, T-aminopropyl triethoxy decane, T-aminopropyl trimethoxy decane, N-phenyl-τ-aminopropyl trimethoxy sulphonate, N-phenyl- γ _ 丙基 propyl triethoxy dream burning and other amine stone smoldering; and Τ - A thiodecane such as mercaptopropyltrimethoxydecane or fluorenyl-mercaptopropyltrimethylethene. The adhesion enhancer is used in an amount of from 0.01 to 10 parts by weight, preferably from 0.05 to 5 parts by weight, based on 100 parts by weight of the coloring agent in the coloring composition. <Removal of coarse particles> The coloring composition of the present invention is preferably a coarse particle of 5/m or more by a mechanism such as a centrifugal separation, a sintered filter or a membrane filter, and more preferably a coarse particle of 1/zm or more, and further 0.5. / / m above the coarse particles and mixed with the removal of dust. Thus, the colored composition is preferably substantially free of particles of 0.5 #m or more. More preferably 〇.3#πι below. <Color Filter> Next, a color filter relating to the present invention will be described. The color filter of the present invention is provided with a filter section formed by the coloring composition for a color filter of the present invention, 100113563 Form No. Α0101, 44/72, 1003232411-0, 201144390. The color filter may be a device having a red filter segment, a green filter segment, and a blue filter segment, or a magenta filter segment, a cyan filter segment, and a yellow color. The material of the filter section Ο As the transparent substrate, a soda lime glass, a low alkali borosilicate glass, a glass plate such as a non-exhaustive acid glass, or a polycarbonate, a polymethyl methacrylate methyl group, and the like may be used. A resin plate such as polyethylene glycol. Further, on the surface of the glass plate or the resin plate, a transparent electrode composed of indium oxide, tin oxide or the like may be formed in order to drive the liquid crystal molecules after the formation of the panel. Method of Manufacturing Color Filter The color filter of the present invention can be produced by a printing method or photolithography. When the filter segment is formed by the printing method, only the printing and drying of the coloring composition prepared by the printing ink are repeated, and the patterning can be completed. Therefore, the method of manufacturing the color filter is low in cost and quantity. Good productivity. Further, by the development of printing technology, it is possible to perform printing with a fine pattern having high dimensional accuracy and smoothness. When printing, it is preferable that the ink does not dry and solidify on the printing plate or on the felt cloth. Moreover, the control of the fluidity of the ink on the printing press is also important, and the viscosity of the ink can be adjusted by a dispersing agent or a body pigment. When the filter segment is formed by the photolithography method, the solvent development type or the alkali development type coloring resistance is applied to the transparent substrate by a coating method such as spray coating or spin coating, slit coating, or roll coating. The colored composition prepared by the etchant material is applied to a film having a dry film thickness of 〇2 to 5, which is dried as needed, and is provided with a special pattern by contact or non-contact with the film. UV exposure. Thereafter, 100113563 is immersed in a solvent or an alkali developer, or sprayed by a sprayer such as Form No. A0101, page 45/72, to spray the developer 1003232411-0 201144390 to remove the uncured portion to form a desired pattern. After that, the same operation is repeated for other colors, and a color filter is manufactured. In order to promote

The polymerization of the colored anti-surname material can also be applied as needed. ^I By the photolithography method, it is possible to manufacture a color light film having a higher precision than the above printing method. When developing, 'as an alkali developing solution, an aqueous solution such as sodium carbonate and sodium hydroxide can be used, and a diterpene base group can also be used. Organic tests such as amines and triethanolamine. Further, an antifoaming agent or a surfactant may be added to the developer. Further, in order to improve the ultraviolet exposure sensitivity, after coating and drying the above-mentioned coloring resist, it is also possible to apply a dry water-soluble or alkali-soluble resin such as polyvinyl alcohol or a water-soluble acrylic resin to form a film which prevents oxygen from inhibiting polymerization. 'Performed UV exposure. In addition to the above methods, the color filter of the present invention can be produced by an electrodeposition method, a transfer method, an inkjet method, or the like, and the coloring composition of the present invention can be used in any method. Furthermore, the electrodeposition method is formed by using a transparent conductive film formed on a substrate, and performing electrophoretic deposition on each of the color filter segments on the transparent conductive film by electrophoresis of colloidal particles, thereby fabricating a color filter. method. Further, the transfer method is based on the surface of the peelable transfer substrate, and the filter segments are formed in advance, and the filter segments are transferred to the desired substrate to form respective color filters on the transparent substrate or the reflective substrate. A black matrix may be formed in advance before the slice segments. The black matrix is a multilayer film of chromium or chromium/chromium oxide, an inorganic film such as titanium nitride, or a resin film in which a light-shielding agent is dispersed, but is not limited thereto. Further, a thin film transistor (TFT) may be formed in advance on the transparent substrate or the reflective substrate, and then each color filter segment may be formed. Further, in the color filter of the present invention, a film can be formed as needed, and a conductive film can be formed by the surface of the film No. A101, page 46, page 72, 1003232411-0, 201144390. [Examples] Hereinafter, the present invention will be described based on examples, but the present invention is not limited thereto. In addition, as long as it is not specified, the "part" means "weight". First, the production of a resin binder, a finely divided pigment, a resin having a cationic group in a side chain, and a toothed product used in the examples and the comparative examples will be described. <Modulating Resin Adhesive>

The resin binder solution 1 was prepared in a four-part flask equipped with a thermometer, a cooling tube, a nitrogen gas introduction tube, a stirring device, and a dropping tube, and placed in a loop of 2 parts of cyclohexanone, and heated to 80 ° C. After the reaction vessel, the n-butyl decyl acrylate was removed by a dropping of 2 hours, the hexabutyl methacrylate 1,3-particulate, the hydroxyethyl methacrylate 4.6, the methacrylic acid 3.4, the butyl group Phenol oxirane modified acrylate ("AR0NIX M110" manufactured by Toagosei Co., Ltd.) 7.4, 2, 2'-azobisisobutyronitrile. A mixture of 4 parts. After the drop

Further reaction was continued for 3 hours to obtain a solution of an acrylic resin having a weight average molecular weight of 26,000. After cooling the solution to room temperature, 'the resin solution was sampled by about 2 g, heated at 18 ITC for 20 minutes to dry it, and the non-volatile component was measured. According to the measurement results, methoxypropyl acetate was added to the previously synthesized resin solution. The resin binder solution 1 was prepared by setting the nonvolatile component to 2% by weight. Here, the weight average molecular weight (Mw) of the resin binder is measured by a gel permeation chromatography (GPC) using polystyrene as a quasi-substance. <Manufacture of micronized pigments> 100113563 Blue micronized pigment (p_l) Form No. A0101 Page 47 of 72 1003232411-0 201144390 酞 Phthalocyanine blue pigment c·丨. Pigment Blue 15 : 6 (Toyo Ink Manufactured in the "Lionol Blue Es" manufactured by the company, Ltd., and the 800 parts of the crushed salt and the 1 part of the diethylene glycol were placed in a stainless steel kneading kneader (manufactured by Inoue Seisakusho Co., Ltd.) to γ 〇C. Mix and mix for 12 hours. The mixed search mixture is placed in the warm water 3 crucible, and heated to about 7 〇〇c, and the surface is stirred by a high-speed stirrer for about 1 hour to prepare a shape, and the mash and water are washed to remove the salt and the solvent. Thereafter, it was dried at 8 ° C for 24 hours to obtain 98 parts of blue fine pigment (P-1). The pigment obtained had an average primary particle diameter of 28.3 nm. Here, the average primary particle diameter of the pigment is measured by a transmission electron microscope ("JEM-1 200EX" manufactured by Sakamoto Electronics Co., Ltd.), and the primary particle diameter of all the pigment particles in the observation sample of 50,000 times is measured and used. average value. Further, when the particle shape is non-spherical, the long diameter and the short diameter are measured, and the value obtained by (long diameter + short diameter)/2 is used as the particle diameter. Purple fine pigment (p-2) 120 parts of dioxin-based purple pigment c. I. Pigment Violet 23 ("Fast Violet RL" by Clariant Co., Ltd.), crushed salt 16 及, and 乙二二The alcohol 1 crucible was placed in a stainless steel gallon kneader (manufactured by Inoue Co., Ltd.), and mixed and stirred at 90 ° C for 18 hours. The kneaded material was placed in 5000 parts of warm water, heated to about 7 〇t, and stirred in a high-speed stirrer for about 1 hour to form a slurry. The mixture was repeatedly filtered and washed with water to remove salt and solvent, and then 80°. C was dried for 24 hours to obtain 118 parts of purple fine pigment (P-2). The average primary particle diameter of the obtained pigment was 26 4 nm. Red fine pigment (P-3) Diketopyrrolopyrrole red pigment c. Pigment red 254 ("IRGAZIN RED 2030" manufactured by Chiba 100113563, Japan) 120 parts, crushed salt 1003232411 Form No. A0101 Page 48 / A total of 72 pages of 201144390 1 000 parts and 120 parts of ethylene glycol were placed in a stainless steel 1 gallon kneader (manufactured by Inoue Manufacturing Co., Ltd.) to 6 〇. (: Mixing and mixing for 1 hour. The mixed mixture is placed in warm water 2000, heated to about 8 (rc, and mixed with a high-speed spoiler for about 1 hour to form a slurry, and the filtration is repeated. After washing with water to remove salt and solvent, it was dried at 80 ° C for 24 hours to obtain 115 red fine pigments (P-3). The average primary particle diameter of the obtained pigment was 24. 8 (10) 〇 yellow fine pigment (P) -4) 》 Nickel complex yellow pigment c. 颜料. Pigment yellow 15 〇 (1 ^ £ ^ 公司 company "E-4GN") 100 parts, gasification sodium 7 〇〇 and diethylene glycol 18 The crotch portion was placed in a stainless steel 1 gallon kneader (manufactured by Inoue Seisakusho Co., Ltd.), and the mixture was stirred and mixed at 8 Torr for 6 hours. The kneaded mixture was placed in a warm water bath and heated to about 8 (TC). The surface was made into a slurry with a high-speed stirrer for about 丨 hours, and was repeatedly filtered in a slurry, washed with water to remove salt and solvent, and dried at 8 ° C for 24 hours to obtain 95 yellow fine pigments (P_4). The average primary particle diameter of the obtained pigment is 39. 2 nm. i Green fine pigment (P-5)) CI pigment green 36 of the hostile green pigment (Toyo 120 parts of "Lionol Green 6YK" manufactured by Water Manufacturing Co., Ltd., 16 parts of gasified sodium and 270 parts of ethylene glycol were placed in a non-recorded steel 1 life-mixing kneader (manufactured by Inoue Seisakusho Co., Ltd.) at 70 ° C. The mixture was stirred for 12 hours, and the mixed mixture was placed in 5000 parts of warm water, heated to about 70 ° C, and stirred in a high-speed stirrer for about 1 hour to form a slurry. The filtration and washing were repeated to remove salt and After the granules were dried at 80 ° C for 24 hours to obtain 117 green fine pigments (P-5). The average primary particle diameter of the obtained pigment was 32. 6 η πι. Modulations > 1003232411-0 100113563 Form Α Α 0101 Page 49 / Total 72 pages 201144390 Resin 1 with a cationic group in the side chain 1 In a separate flask equipped with a thermometer, a stirrer, a distillation tube, and a cooling 15 3 parts of methyl ethyl ketone, and the temperature was raised to 75 under a nitrogen stream. (:. Further, 3,0 parts of methyl methacrylate, 28.0 parts of n-butyl butyl acrylate, and methyl 2-ethylhexyl acrylate 28 were uniformly mixed. 〇, dimethylamine ethyl methacrylate 10. 0, 2, 2 _ azobis(2,4~dimethylvaleronitrile) 6.5 parts, and thioglycolide 25.1, the obtained mixture was placed in a dropping funnel, and the dropping funnel was attached to the above 4 The mixture was dropped over 2 hours, and after 2 hours from the end of the dropwise addition, the polymerization yield was confirmed to be 98% from the solid content, the weight average molecular weight (Mw) was 6,830, and cooled to 5 (TC. After the cooling. The reaction mixture was further added with a vaporized methyl group of 3.2 parts, and an ethanol of 22.0 parts of the mixture, which was reacted at 5 ° C for 2 hours, and then heated to 80 t over 1 hour, and further reacted for 2 hours. Thus, the resin 1 having 47% by weight of the resin component and having a cationic group in the side chain was obtained. The obtained ammonium salt value of the resin was 34 mgKOH/g. Here, the weight average molecular weight (Mw) of the resin having a cationic group is measured by a gel permeation chromatograph (GPC) which is a standard material. Further, the ammonium salt value of the resin having a cationic group in the % side chain is titrated with a 5% aqueous solution of chromic acid, and is determined as an indicator drug, and converted to potassium hydroxide by G. decalcified silver. After the amount of miscellaneous silver required for the base is corrected, the salt value of the cationic group is added to the side chain. In a separate flask equipped with a thermometer, a blender, and a 曰2 plant, you can put it into the sacred tube and the cooler, and put it into isopropanol 62 4a A. ^ ^ . 7 s •. Helium, the temperature was raised to 75T under a nitrogen stream. Further, ethyl propylene oc is uniformly mixed; 1JtIJ 曰 Du τ § 32·1, methyl n-propyl acrylate 25. Part 1, lauryl propylene stern 100113563 Form ΑΟΗΠ 〇 5〇^ ester 25. 1 , methacrylamide acetamidopropyl 72 I 1003232411-( 201144390 trimethylammonium vapor 17.7, 2, 2,-azobis(2,4-dimethylvaleronitrile) 5·7, and After the 15.6 parts of ethyl ethyl ketone, the obtained mixture was placed in a dropping funnel. The dropping funnel was attached to the above-mentioned four separate flasks, and the mixture was dropped over 2 hours. After the completion of the dropwise addition for 2 hours, the polymerization was confirmed from the solid content. The yield was 98%, the weight average molecular weight (Mw) was 7420, and it was cooled to 5 〇t. The cooled reaction mixture was added with 72 parts of isopropyl alcohol to obtain 40% by weight of the resin component and cationic in the side chain. Base resin 2. The obtained resin has a salt valence of 45 mg KOH/g. ^ Resin 3 having a cationic group in the side chain is placed in a separate flask equipped with a thermometer, a stirrer, a distillation tube, and a cooler. 3 parts of methyl ethyl ketone, heated to 75X under nitrogen flow. 5部,N,N-dimethylaminomethylstyrene 20. 0, propyl methacrylate 25.5, methyl benzyl acrylate 25.0, methyl 2-ethylhexyl acrylate. 2, 2,-azobis(2,4-dimethylvaleronitrile) 6. 7 and methyl ethyl ketone 25.1, placed in a dropping funnel, mounted in 4 separate flasks, after 2 After 2 hours from the end of the dropwise addition, q was confirmed to have a polymerization yield of 98% from the solid content, a weight average molecular weight (Mw) of 6,770, and cooled to 5 ° C. The cooled reaction mixture 'additional gasification benzyl 7 parts, 7 parts of ethanol, 2 parts, reacted at 5 ° C for 2 hours, and then heated to 8 (TC for 1 hour) over 1 hour. Thus obtained 50% by weight of resin component and cation in side chain Resin-based resin 3. The obtained ammonium salt of the resin has a valence of 60 mg KOH/g. The resin having a cationic group in the side chain 4 is placed in a separate flask equipped with a thermometer, a stirrer, a distillation tube, and a cooler. 62.4 parts of isopropanol, and the temperature was raised to 75 ° C under a nitrogen stream. Further, 5% methacrylate methacrylate was added, and the stearyl acrylate 100113563 was uniformly mixed. Form No. A0101 Page 51 / Total 72 Page 1003232411-0 201144390 2〇-〇, 2,100 parts of cyclohexyl methacrylate, ^1^^^£1??£90 (made by Nippon Oil Co., Ltd., diethylene glycol single Acetyl acrylate) 1 5. 0, N-vinyl oxime _20. 〇, 2, 2'-azobis(2,4-dimercapto valeronitrile) 4. 7 #, and isopropyl After the alcohol was 15.6, the obtained mixture was placed in a dropping funnel. The dropping funnel was attached to the above four separate flasks, and the mixture was dropped over 2 hours. Two hours after the end of the dropwise addition, the polymerization yield was confirmed to be 98% from the solid content, and the weight average molecular weight (Mw) was 7,550, and was cooled to 5 Torr. The cooled reaction mixture was further vaporized with methyl group 9. oxime and isopropanol 22. The oxime was reacted with 5ITC for 2 hours, and then heated to 8 ° C for 1 hour, and further reacted for 2 hours. Thereafter, 50 parts of isopropyl alcohol was added to obtain a resin 4 having a resin component of 44% by weight and a cationic group in the side chain. The obtained ammonium salt value of the resin was 92 mgKOH/g. The resin 5 having a cationic group in the side chain was placed in a separate flask of a thermometer, a stirrer, a distillation tube, and a cooler, and placed in a portion of methyl ether ketone 82.0, and heated to 75 t under a nitrogen stream. Further, a mixture of 5% ethyl methacrylate 23.5 parts, a tertiary butyl methacrylate 26.0 part, a decyl acrylate acrylate 25. 〇, KAYAMAR 21 (made by Nippon Kayaku Co., Ltd., ε-Hone vinegar 1 Moer-added 2-phosphate by thioethyl succinate) 10. 0, diethylaminopropyl methacrylate Π. 5, 2,2'-azobis (2,4- After 6.0 parts of dimethylvaleronitrile and 25.6 parts of mercaptoacetone, the obtained mixture was placed in a dropping funnel, and the dropping funnel was attached to the above-mentioned four separate flasks, and the mixture was dropped over 2 hours. Two hours after the end of the dropwise addition, the polymerization yield was confirmed to be 98% from the solid content, and the weight average molecular weight (Mw) was 7 〇 1 Torr, and was cooled to 5 Torr. (: The resin 5 having a resin component of 48% by weight and having a cationic group in the side chain was obtained in this manner. The obtained ammonium salt value of the resin was 49 mgKOH/g. 100113563 Form No. A0101 Page 52 of 72^03232411-0 201144390 Resin 6 with cationic group in side chain

4份。 The detached flask with a thermometer, a stirrer, a distillation tube, a cooler, the isopropyl alcohol was 62. 4 parts, the temperature was raised to 75 ° C ° under nitrogen flow, and the phthalate was further uniformly mixed 32. 1 , propyl methacrylate methacrylate 30. 1 part, methyl lauryl acrylate 32-1, mercapto acrylamide propylamine trimethylated ammonium hydride 5. 7 parts, 2, 2, - azo double (2 After 6 parts of 4-dimethylpentamidine and 25.0 parts of methyl ethyl ketone, the obtained mixture was placed in a dropping funnel, and the dropping funnel was attached to the above four separate flasks for 2 hours. The mixture was dropped. Two hours after the completion of the dropwise addition, the polymerization yield was confirmed to be 98% from the solid content, and the weight average molecular weight (Mw) was 7000 Å to 5 (TC). Thereafter, 65 parts of isopropyl alcohol was added to obtain a resin component of 40% by weight. Resin 6 having a cationic group in a side chain. The obtained resin has an ammonium salt value of 15 mgKOH/g. Resin having a cationic group in the side chain 7

4 parts of a separate flask equipped with a thermometer, a stirrer, a distillation tube, and a cooler were placed in 62.4 parts of isopropyl alcohol, and the temperature was raised to 75 ° C under an ammonia gas flow. 0之间。 2, 2, 2' - azobis (1, 2, 2'-azo double (1), 2, 2'-azo double (methyl methacrylate) After 6 parts of 2, 4-dimercapto valeronitrile and 25 parts of methyl ethyl ketone, the obtained mixture was placed in a dropping funnel, and the dropping funnel was attached to the above four separate flasks, and it was passed through 2 The mixture was dropped in an hour. Two hours after the end of the dropwise addition, the polymerization yield was confirmed to be 98% from the solid content, the weight average molecular weight (Mw) was 7050, and it was cooled to 5 (TC. 65 parts of isopropyl alcohol was added to the cooled reaction mixture to obtain a resin component. 40% by weight of resin 7 having a cationic group in the side chain. The obtained ammonium salt value of the resin is 138 mgKOH/g. 100113563 Form No. A0101 Page 53 of 72 1003232411-0 201144390 Here, in the side chain The amine valence of the resin of the cationic group is determined by the potentiometric titration method using a 0.1% aqueous solution of hydrochloric acid to determine the amount of hydrochloric acid required for neutralization, and is converted to the equivalent of potassium hydroxide. <Production of halogenated product> Halogenation (A-1) A halogenated product (A-1) composed of CI Acid Red 289 and a resin having a cationic group in a side chain was produced by the following procedure: The side chain of 51 parts of water 2000 was added. The resin 1 of the cationic group was sufficiently mixed and stirred, and the obtained resin solution was heated to 60 ° C. In the above resin solution, 10 aqueous solutions of CI Acid Red 289 were dissolved in 90 parts of water. dropping The mixture was stirred at 60 ° C for 120 minutes, and the reaction was sufficiently carried out. The end of the reaction was confirmed by dropping the reaction solution on the filter paper, and the end point was not bleed, and it was judged that the toothed product was obtained. The obtained reaction mixture was stirred while stirring. After allowing to cool to room temperature, suction filtration is carried out, and after washing with water, the halogenated product remaining on the filter paper is removed by a dryer and dried to obtain a halogenated product of CI acid red 289 and a resin having a cationic group in the side chain. (Al) 32. Halogenated product (A-2) A halogenated product (A-2) composed of CI acid blue 112 and a resin having a cationic group in a side chain was produced by the following procedure. To the 2,000 parts of the water, 51 resin having a cationic group in the side chain of 51 parts is added, and after sufficiently stirring and mixing, the obtained resin solution is heated to 60 ° C. In the above resin solution, 90 parts of water are successively dissolved. 10 parts of the aqueous solution of CI Acid Red 289. After dripping, it is stirred at 60 ° C for 120 minutes to fully carry out the reaction. The end of the reaction is confirmed by dropping the reaction solution on the filter paper, and it is the end point when it does not bleed. Obtain halogenation to generate 100113563 Form No. A0101 Page 54 / Total 72 Page 1003232411-0 201144390. Mix the obtained reaction mixture, and then let it cool down to room temperature and then suction and filter. After washing, the dryer will remain on the filter paper. Then, the product was removed by moisture removal, and 32 parts of the halogenated product (4-1) of the acid red 289 and the side and cationic group-containing resin 1 were obtained. The deuterated product (A-3) was obtained as follows. In the procedure, a halogenated product (A 3 ) composed of CI Acid Blue 93 and a resin 3 having a cationic group in a side chain was produced. Adding 47.6% of the N,N' dimethylformamide aqueous solution in 2000%

The resin 3 having a cationic group in the side bond is sufficiently heated and mixed (10) after mixing and mixing. In the solution of the sulphate, one of the 90 parts of the water was dissolved in the water of 90 parts, and the aqueous solution of the acid blue was dripped, and the reaction was carried out at 7 (TC for 120 minutes). The reaction was confirmed by the drop. When the reaction liquid does not bleed, it is the end point, and it can be judged that the toothed product is obtained. - The reaction mixture obtained by the surface mixing is cooled to room temperature, and then suction-filtered, and after washing, the residue is dried by a dryer. The product on the rail is dehydrated and dried to obtain a halogenated product (A-3) of CI acid blue 93 and a resin having a cationic group in the side chain. Halogenated product (A-4) The following procedure is employed. A subtractive product (Η) composed of an acid derivative of C. 丨. Pigment Yellow 138 and a resin 4 having a cationic group in a side chain was prepared. In the case of 100 parts of 1% 1% sulfuric acid, a CI of 1 part was added. Pigment yellow 138, heated to 60. (: (4) line consumption. Then, the reaction solution was poured into a large amount of 100113563 ice water, and the reaction product (two derivatives) was precipitated, and washed with a filter or the like. The water-soluble paste of the acid-reducing derivative is redispersed in water at 2000 °P Using the aqueous sodium hydroxide solution, adjust the pH to the weak form No. A0101, page 55 / page 72, 1003232411-0, 201144390. In the above aqueous solution of the adjusted pH sulfonic acid derivative, drop 190 parts of water in a row. An aqueous solution of 20.0 parts of a resin having a cationic group in a side chain was dissolved. After the dropwise addition, the reaction was sufficiently carried out by stirring at 6 ° C for 12 minutes. The end of the reaction was confirmed when the reaction solution was dropped without dropping the filter paper. At the end point, it is judged that the halogenated product is obtained. While the reaction mixture obtained by mixing is allowed to cool to room temperature, it is suction-filtered, and after washing with water, the product remaining on the filter paper is dried by a dryer to remove moisture. The halogenated product (A-4) of the acid derivative of c. I. pigment yellow 138 and the resin 4 having a cationic group in the side chain was obtained. The halogenated product (A-5) was produced by the following procedure. A halogenated product (A_5) consisting of CI acid red 249 and a resin having a cationic group in the side chain. &amp; 20% acetic acid 2 〇〇〇 part added 63. 2 parts of the side chain having a cationic group of resin 5 'Full stirring After the combination, the mixture is heated to 6 〇〇c to carry out the ammonium gasification of the amine group of the tertiary chain of the third chain. In the water of 90 parts, the aqueous solution of the C. I acid red 249 of 1 〇 is dissolved. The ammonium salted resin solution is dropped a little. After dripping, it is 60. (: stirring for 120 minutes, the reaction is sufficiently carried out. The confirmation of the end point of the reaction is the end point when the filter paper drops the reaction liquid, and it is the end point, and it can be judged that i is obtained. Thereafter, the obtained reaction mixture was stirred while being allowed to cool to room temperature, and then suction-filtered, and after washing with water, the toothed product remaining on the filter paper was removed by a drier and dried. The CI acid red 249 and the halogenated product (A-5) of the resin 5 having a cationic group of the side bond are 38 parts. Halogenated product (a to 6) 100113563 The following procedure was used to manufacture CI Direct Blue 86 and DisPerbyk-2® (byk Chemie Japan, modified acrylic block common form bat No. AQ101, page 56 / total 72 stomach 1003232411-0 201144390

A halogenated product (A-6) composed of a polymer and an ammonium salt having a valence of 61 mg K0H/g. Add 50.9 Disperbyk - 2000 to the water 2000, fully mix and mix. After sufficient mixing and mixing, the obtained resin solution is heated to 60. Hey. In the above resin solution, 10 parts of the aqueous solution of C.I. Direct Blue 86 was dissolved in the water of 9 parts. After the dropping, the mixture was stirred at 601 for 120 minutes to sufficiently carry out the reaction. The confirmation of the end point of the reaction is the end point of the filter liquid when the reaction liquid does not bleed, and it can be judged that the halogenated product is obtained. While stirring the obtained reaction mixture, the mixture was allowed to cool to room temperature, and then subjected to suction filtration. After washing with water, the toothed product remaining on the filter paper was removed by a dryer and dried to obtain C. 丨. Direct Blue 86 and

Part 31 of the Disperbyk-2000 product (A-6). Halogenated product (A-7) A halogenated product (a-7) consisting of C. I. Acid Blue 93 and a resin having a cationic group in a side chain was produced by the following procedure »

In a 2% aqueous solution of 10% N,N-dimethylformamide, 186.8 parts of a resin having a cationic group having a side chain added thereto, and fully stirred; after mixing and mixing, the obtained resin solution is heated. To 7 (TC), in the above resin solution, a portion of the water of 90 parts was dissolved in a portion of c. I. an aqueous solution of acid blue 93. After the dropwise addition, the mixture was stirred at 70 ° C for 120 minutes to sufficiently carry out the reaction. When the end point is broken, the reaction solution is dropped on the filter paper, and the end point is not oozing. It can be judged that the self-generated product is obtained. While stirring the obtained reaction mixture, the mixture is allowed to cool to room temperature, and then suction-filtered and washed. The i-product remaining on the filter paper was removed by a dryer and dried, and 75 parts of a halogenated product (A-7) of CI acid blue 93 and a resin having a cationic group in the side chain were obtained. 100113563 Halogenated product (A-8) Form No. A0101 Page 57 of 72 1003232411-0 201144390 A halogenated product (A_8) composed of CI Acid Blue 93 and a resin having a cationic group in a side chain was produced by the following procedure. 10% N,N-dimethylformamidine 2 parts of the amine aqueous solution were added, and the resin ruthenium having a cationic group was added to the side chain of 934. After sufficiently stirring and mixing, the obtained sapwood liquid was heated to a charge. c. In the above (4) solution, a few drops were made. The aqueous solution of the ci acid blue 93 in the (four) part is dissolved in the water of the crotch. After the dropping, the mixture is stirred at 7 ° C for 120 minutes to fully carry out the reaction. The reverse point is u, and the reaction liquid does not seep when the dropping is carried out. The end point 'can be judged to obtain the (four) chemical product... The reaction obtained by the surface Lin mixed H-(4) After being cooled to room temperature, it is subjected to suction filtration, and after washing with water, the raw silk is removed to remove moisture, and the CI acid blue 93 and the side bond are obtained. 48 parts of the functional product (A-8) of the cationic group resin 1. Halogenated product (A-9) was produced by the following procedure: "L·i. Acid blue 93 and a side chain having a cationic group T-9 is a tortoise-forming product U-9). ^^^-methylmethylamine amine aqueous solution 2000, adding 31. 1 side of the side bond with a cationic group of tree wax 4, fully searched After mixing, (4) it is difficult to dissolve in h耽. In the upper job fat solution, one by one drop in the water of 9G The reaction was carried out in the water of the CI Acid Blue 93 of the 1G part, and the reaction was confirmed. The confirmation of the end point of the reaction was carried out by dropping the reaction solution on the paper, and the end of the reaction was not obtained when it was not oozing. After the reaction mixture is allowed to cool to room temperature, it is subjected to suction filtration, and after washing with water, the toothed product remaining on the scorpion*&quot;, I is removed by a dryer to remove moisture and obtain 'C. I · Acid 铥qq 100113563 Form No. _93 and the resin of the resin group 4 having a cationic group on the side chain. Page 58 of 72 1003232411 201144390 Chemical product (A-9) 22 parts. ▼Natural product (Α-ι〇) ^The following procedure 'produces a southern chemical product (A-10) composed of a resin blue 7 and a resin having a cationic side chain. 'Ν' N - 2000 parts of a methyl guanamine aqueous solution, and 23 2 parts of a resin 7 having a cationic group in a side chain were added, and after sufficiently mixing and mixing, the resin solution obtained was heated to 赃. In the above resin solution, 1Q of the water of the sputum acid blue 93 is dissolved in the water of the ninth part of the ninth (9). After dropping, 'by 7G. (10) Mix for 12G minutes and fully react. The confirmation of the end point of the reaction is based on the dropping of the reaction liquid on the paper, and the end point is not bleed, and it can be judged that the obtained reaction mixture is obtained by mixing the obtained reaction product, and the mixture is cooled to room temperature, and then subjected to suction filtration and washing. After that, the halogenated product remaining on the filter paper is dried by a dryer to remove water, and 19 parts of a halogenated product (Al〇) of the resin 7 having a cationic acid group and a side chain having a cationic group are obtained. Halogenated product (C-1) Q The following procedure was employed to prepare a halogenated product (c-i) composed of c. I. Acid Red 289 and distearyl dimethylammonium hydride (Rose red D86P). To a portion of 10 parts of a 10% sodium hydroxide solution, 11.5 parts of rose red D86P was added, and after sufficiently mixing and mixing, the obtained resin solution was heated to 60 °C. In the above resin solution, 10 parts of an aqueous solution of C.I. Acid Red 289 was dissolved in 90 parts of water. After dripping, the mixture was stirred at 6 ITC for 120 minutes to fully carry out the reaction. The confirmation of the end point of the reaction is carried out by dropping the reaction solution on the paper, and the end point is not bleed, and it is judged that the toothed product is obtained. The obtained reaction mixture was stirred while being allowed to cool to room temperature, and then subjected to suction filtration. After washing with water, the dryer was left on the filter paper 100113563 Form No. A0101 Page 59 / Total 72 Page 1003232411-0 201144390 Halogenated product The water was removed and dried to obtain 17 halogenated products (Cl) of CI Acid Red 289 and Rose Bengal D86P. Halogenated product (C-2) A halogenated product (C-2) composed of C. I. Acid Blue 112 and monostearny uranyl ammonium hydride (Rose Red 24P) was produced by the following procedure. To a portion of the 7% sodium hydroxide solution, 8.1 parts of rose red 24P' was added, and after stirring and mixing, the obtained resin solution was heated to 50 °C. In the above resin solution, 10 parts of an aqueous solution of C. I. Acid Blue η 2 was dissolved in a water of 9 parts. After the dropwise addition, the mixture was stirred at 5 °t for 120 minutes to sufficiently carry out the reaction. The end point of the reaction was confirmed by dropping the reaction liquid on the filter paper, and the end point was not bleed, and it was judged that the chemical product was obtained. While stirring the obtained reaction mixture, the mixture was allowed to cool to room temperature, and then subjected to suction filtration. After washing with water, the halogenated product remaining on the filter paper was removed by a dryer and dried to obtain c.] [• Acid Blue 112 and There are 16 halogenated products (c-2) of rose red 24P. <Solvent Solubility Test Method> Solvent solubility was evaluated for the above-obtained southern product. The evaluation was carried out by observing the dissolved state of the _ product solution prepared at a concentration of 5 wt%. The solvent used was propylene glycol monoethyl ether ethyl ester (PGMAC). After each tooth-forming solution was prepared to have a concentration of 5 wt%, it was stirred with a stirrer and allowed to stand for 1 hour to prepare an evaluation solution. The following four stages were used to evaluate the dissolved bear 〇 ◎: completely dissolved; 〇: almost dissolved; △: - partially dissolved; x. insoluble * The results are shown in Table 1 below. 100113563 Form No. A0101 Page 60 of 72 1〇03232411-〇 201144390 Table 1:

Pigment dispersion 撖——___ Cyclohexanone PGMAC A-1 ◎ A-2 ◎ 〇A-3 ◎ 〇_ A—4 ◎ ◎ A-5 ◎ ◎ A'6 ◎ 〇A-7 ◎ 〇A-8 ◎ 〇 A-9 ◎ 〇A-1〇〇△ c-1 〇Δ C~2 Δ X Example 1: Preparation of coloring composition (DB-1) The components shown in the following Table 1 were stirred and mixed uniformly, and then used. Oxide beads of diameter 〇5mm, IGER grinding machine (Mini made by IGER Japan)

Model M-250 MKII") was dispersed for 5 hours, and then filtered through a 5.0 m filter to prepare a pigment dispersion (DB-1). Table A: Salty component tooth formation product (A-1) 4.0 parts of fine pigment (P-1) 7.0 part &quot;honing and bonding solution 1 · — ~~ 40.0 part &quot;Ϊ hexanone ~ 10.0$ PGMAC — ~~ 38_0 The tree is ground and dispersed _ ("KAKA43 00," manufactured by Chiba Corporation, Japan)

Examples 2 to 8, 17 to 20, and Comparative Examples 1 to 3: Production of the colored composition (db-2 to 15) except that the functionalized product and the finely divided pigment were changed to the compositions shown in Table 2, A colored composition was prepared in the same manner as in Example 1 (DB-2 to 100113563, Form No. A0101, Page 61/72, 1003232411-015). 201144390 <Evaluation of coloring composition> With respect to the obtained coloring composition (D B -1 to 15), the following method was carried out to test the stability and the coating foreign matter. The test results are shown in Table 2. 〇 Preservation stability test method The viscosity of the produced coloring composition at 25 ° C was measured at a rotation number of 20 rpm using an E-type viscometer (TUE-20L type manufactured by Toki Sangyo Co., Ltd.). The initial viscosity on the day of the coloring composition was prepared, and the viscosity was promoted after storage for 7 days in a thermostatic chamber at 40 ° C, and the viscosity change rate was calculated, and the stability was evaluated by the following criteria. ◎: less than 10%; 〇: 1% or more and less than 20%; Δ: 2% or more and less than 5%; and X: 55% or more. The results are shown in Table 2 below. Coating film foreign matter test method A test substrate was prepared from the newly prepared coloring composition, and the number of particles was counted and evaluated. First, a colored composition was applied to the transparent substrate so that the dried coating film was about 2.0/m, and the test substrate was obtained by heating at 230 ° C for 20 minutes in an oven. Thereafter, the surface observation (magnification: 500 times) was carried out using a metal microscope "BX60" manufactured by 01 ympus Systems, Inc., and the number of observable particles was calculated by penetrating at any five fields. The following baseline assessments were used. In the evaluation results, ◎ and 〇 are small and good in foreign matter, △ is a number of foreign matter, but the level of use is not a problem, and X is uneven due to foreign matter (spot), so it is equivalent to an unusable state. . ◎: less than 5 〇: 5 or more, less than 20 100113563 Form No. A0101 Page 62 / Total 72 Page 1003232411-0 201144390 △ : 20 or more, less than 100 X: 100 or more are shown in Table 2 below result. Table 2 :

Coloring composition #Chemical product Micronized pigment Preservation stability Coating film Foreign matter type Mixing amount Kinding amount Example 1 DB-1 Α-1 4 parts Ρ-1 7 parts ◎ Poor example 2 DB-2 Α-2 6 Part Ρ-1 5 parts~~〇~ 〇Example 3 DB-3 Α-3 8 parts Ρ-2 3 parts 〇© Implementation _ Example 4 DB-4 Α-4 4 parts Ρ-5 7 parts ◎ Example 5 DB-5 Α-5 3 parts. Ρ-3 8 parts ◎ ◎ Example 6 DB-6 Α-6 7 parts Ρ-4 4 parts Δ 〇 Example 7 DB-7 A-2 11 parts _ — △ 〇 Implementation tree 8 DB-8 Α-3 11 parts one Δ 〇 Example 17 DB-12 Α-7 10 parts Ρ-2 1 part 〇 ◎ Example 18 DB-13 Α-8 9 parts Ρ-2 2 parts 〇 ◎ Real cover example 19 DB-14 Α-9 7 parts Ρ-2 4 parts 〇〇Example 2〇DB-15 A—10 6 parts Ρ-2 5 parts 〇Δ Comparative example 1 DB - 9 C-2 3 Department Ρ-1 8 parts X 〇Comparative example 2 DB-10 C-2 5 parts Ρ-1 6 parts X △ Comparative example 3 DB-11 C-2 11 parts - - XX Resin containing cationic group in side chain The coloring composition of the hydrazine product (A4 to 10) generally has good storage stability, and as a result, almost no coating film foreign matter is produced. In addition, halogenation using a cation of an alkylamine-based cation is included. The coloring composition of the product (C-1, 2) is still within the allowable range in terms of the foreign matter of the coating film, but overall, the storage stability is not good, and it is difficult to form the coloring composition after storage. To make a film. Examples 9 to 16, 21 to 2 4. Comparative Examples 4 to 6 Example 9: Resist material (R-1) A mixture of the following Tables was uniformly mixed, and then a filter of 1 μm The alkali-developable resist material R-1 was obtained by filtration. 1003232411-0 100113563 Form No. Α0101 Page 63 of 72 201144390 Table B: Ύο.ο Part 71:0 Part 0.4 丨Dimethylpropane tripropylene acrylate chemical company Μ "NK ester ATMPTj", photopolymerization Initiator company decline "IRGACURE 907j increase--- 5.2 chemical company crab "ΕΑΒ - F ring eTi ---- 18.0 parts no 16, 21~24, comparative examples 4~6: resist material (R 2 ~ 15) p The coloring composition (10) was changed to the composition shown in Table 3, and all of them were prepared in the same manner as in Example 9 to produce an anti-reagent material ~ 15) 〇 &lt;Evaluation of the anti-money agent material> For the obtained resist material ~ i5), the following method was used to test the foreign matter of the coating, the foreign matter of the coating film, and the adhesion of the glass. The test method of the foreign matter of the coating film 1 on the transparent substrate of the thick coffee, the example 9 is called a comparative example. The anti-material obtained in 4~6 is spin-coated after the dry material becomes 2.5&quot; m rotation number, and the 'intermediate silver lamp' is used to calculate the amount of light after the width of the stripe 150mJ/cm2 'When the unexposed part is washed away with the ultra-South water sodium carbonate aqueous solution, the 4 external lines are exposed to 5% After the 'hot air oven, baking at 20 23〇〇c pure, reckoning in the substrate are to be

Mam's striped pattern is then used to observe the surface of the fabricated substrate (500 times) using a 01ympus system male metal microscope "BX60 100113563 Form No. A0101 Page 64 / Total 72 pages 1003232411-0 201144390". The number of observable particles is calculated through any five fields of view. The following benchmark assessments were used. In the evaluation results, ◎ and 〇 are small and good in foreign matter, △ is a number of foreign objects, but the level of use is not a problem, and X is uneven due to foreign matter (spots), so it is equivalent to an unusable state. . ◎: less than 5; 〇: 5 or more, less than 20; △: 20 or more, less than 100; X: 100 or more The results are shown in Table 3. Glass adhesion test method

In the test for the adhesion to the glass, a coating film was formed in the same procedure as the above-mentioned coating film foreign matter test, and the chemical resistance of the obtained coating film was confirmed and evaluated. The test method was carried out in a 5% aqueous sodium hydroxide solution, and immersed at 25 ° C for 30 minutes. By visual observation, the adhesion to the glass before and after the soaking was evaluated in the third stage. 〇: peeling was not confirmed at all; △: peeling was confirmed slightly; X: peeling was confirmed

The results are shown in Table 3. 100113563 Form No. A0101 Page 65 of 72 1003232411-0 201144390 Table 3:

Resist material coloring composition coating film foreign matter glass adhesion Example 9 DB-1 DB-1 ◎ 〇 - Example 10 DB-2 DB-2 〇〇 - t mask 11 DB-3 DB-3 ◎ 〇 - Example 12 DB-4 DB - 4 〇 Δ Example 13 DB-5 DB-5 ◎ 0 Example 14 DB-6 DB-6 〇〇 Example 15 DB-7 DB-7 〇〇 Example 16 DB- 8 DB-8 〇〇 Example 21 DB-12 DB-12 ◎ △ Example 22 DB-13 DB-13 ◎, 〇 Example 23 DB-14 DB-14 实施 Example 24 DB-15 DB-15 Δ 〇 Comparative Example 4 DB-9 DB-9 〇X - Comparative Example 5 DB-10 DB-10 Δ X Comparative Example 6 DB-11 DB-11 XX Resist materials of Examples 9 to 16, 21 to 24 ( The foreign matter of the coating film of R-1 to 15) is also used as a color light-receiving sheet, and the glass adhesion property is also a good result. In addition, the resist materials of the comparative examples 4 and 5 (R-9, 1〇) have poor glass adhesion. The resist material (RU) of Comparative Example 6 generates a lot of foreign matter, so that it is not as a color filter. The quality of use. Therefore, it is apparent that the coloring composition containing the chemical-derived product of the resin having a cationic group in the side chain can provide a color filter which is excellent in both a good coating state and glass adhesion. Example 2 5: Anti-surname material (R-16) The components shown in the following Table c were stirred and mixed uniformly, and then filtered through a filter of 1 〇//m to obtain a developer-resistant anti-surname material R _ 1 β. 100113563 Form No. 1010101 Page 66/72 Page 1003232411-0 201144390 Table c: Amount of coloring composition (DB-1) 60.0 Part of epoxy compound solution 1 (EHPE3150, 20% PGMAC solution manufactured by Daicel Chemical Industry Co., Ltd.) 11.0 Trimethylolpropane triacrylate ("NK ester ATMPT j" manufactured by Shin-Nakamura Chemical Co., Ltd.) 4.2 Photopolymerization start _ (R IRGACURE 907 manufactured by Sakamoto Chiba Co., Ltd.) 1.2 sensitizer (manufactured by Hodogaya Chemical Co., Ltd.) ΕΑΒ—F”) 0.4 parts of cyclohexanone 5.2 PGMAC 18.0

Example 26: Resist material (R-17) The epoxy compound solution 1 of Example 25 (alkali-developing resist material R-1) was changed to epoxy compound solution 2 ("Angase ChemteX" "EX" In the same manner as the resist material R-1 except for the "201% PGMAC solution of 20%), the developer-resistant anti-surname material (R-17) was obtained. Example 27: Resist material (R-18)

Except that the epoxy compound solution 1 of Example 25 (developing type anti-retaining agent material R-1) was changed to epoxy compound solution 3 ("EPIC0AT825" 20% PGMAC solution manufactured by Oiled Shell Epoxy Co., Ltd.) The alkali-developing resist material (18) was obtained in the same manner as the resist material R-1. <Evaluation of the contrast ratio> On the glass substrate, under the C light source, the resist material was applied so as to have a film thickness of x = 〇 150, y = 060. 060, and the substrate was heated at 230X for 20 minutes. The comparison of the obtained substrates was measured by the following method, and the results are shown in Table 4. Method for measuring the contrast ratio of the coating film 100113563 Between the first polarizing plate and the second polarizing plate, Form No. A0101 Page 67 / Total 72 pages Shuangshou with anti-money material 1003232411-0 201144390 'II, \, The glass substrate is irradiated with light by a backlight unit for a liquid crystal display device from the first polarizing plate side. The light from the backlight unit is polarized by the first polarizing plate, and then passes through the dried coating film of the anti-off material and the glass substrate to reach the second polarizing plate. When the polarization axes of the first polarizing plate and the second polarizing plate are parallel to each other, the county second neopolar polarizing plate, but the polarizing axes of the two polarizing plates are orthogonal to each other, the light is blocked by the second polarizing plate. However, when the light which is polarized by the first polarizing plate is coated with the anti-surname material, if the coloring agent is scattered by a knife, or the like, a part of the polarizing surface is deviated, when the two polarizing plates are parallel, the wearing is performed. When the amount of light passing through the second polarizing plate is small, a part of the light penetrates the second polarizing plate when the polarization axes of the two polarizing plates are orthogonal. The brightness of the transmitted light is measured by a luminance meter on the second polarizing plate, and the brightness of the polarizing plates of the two polarizing plates is parallel with respect to the brightness (orthogonal brightness) when the polarizing axes of the two polarizing plates are orthogonal (parallel time) The ratio of brightness is set to the contrast ratio. That is, the contrast ratio is calculated by the following formula. Contrast ratio = (brightness in parallel) / (brightness in quadrature) Therefore, if scattering occurs due to the toner particles in the resist coating film, the brightness is lowered in parallel, and the brightness is increased in the orthogonal direction, so the contrast ratio is reduce. In addition, a color luminance meter (rBM-5A manufactured by T〇pc〇ri Co., Ltd.) was used for the luminance meter, and a polarizing plate ("NpF_G1220DUN" manufactured by Minto Electric Co., Ltd.) was used as the polarizing plate. Further, in the measurement, in order to block the unnecessary light, a black mask having a hole of 1 cm square was aligned with the measurement portion. 100113563 Form No. A0101 Page 68/72 Page 1003232411-0 201144390 Table 4: Resist Material Coloring Composition Thermosetting Compound Contrast Example 9 DB-1 DB-1 - 9500 Example 25 DB-16 DB- 1 Epoxy compound solution i 10500 Example 26 DB-17 DB-1 Cyclopene compound solution 2 10200 Example 27 DB-18 DB-1 Epoxy compound solution 3 10300 Anti-residue material containing epoxy compound (R-16) ~18) With a high contrast ratio, it provides a better color filter. [Simple description of the drawing] [0005] [Explanation of main component symbols] [0006] 100113563 Form No. A0101 Page 69 of 72 1003232411-0

Claims (1)

201144390 VII. Patent application scope: 1 coloring composition for color filters, characterized by containing a coloring agent, a resin binder and an organic solvent; the coloring agent contains a halogenated product, which has a side chain having a cationic group A resin is obtained by reacting with an anionic dye. (2) The coloring composition for a color filter according to the first aspect of the invention, wherein the resin-based vinyl resin having a cationic group in the side chain includes a structure represented by the following general formula (1) Unit; / Η2 -~r -CC-^ ?+ General formula (1) F?2-N-R4 R3 Y_ (in the general formula (1), represents a hydrogen atom, or a substituted or unsubstituted alkyl group. r2 ～r4 each independently represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, or a substituted or unsubstituted aryl group, and two of Rg to I?4 may be bonded to each other to form a ring. Q represents an alkylene group, an arylene group, -CONH-R5- or -c〇〇-R5-, and % represents an alkylene group β γ- represents an inorganic or organic anion) 3 · Color as in the second item of the patent application The coloring composition for a filter, wherein the ammonium salt of the ethylene-based resin containing the structural unit represented by the general formula (1) has a valence of 10 to 300 mg KOH/g. 100113563 Form No. A0101 Page 70 of 72 page 1003232411 -0 201144390 4. Color filter used in any of the scope of the whistle patent range 】 to 3 a composition in which a dentate product is mixed in an aqueous solution and mixed with a side bond (4) ionic group and an anionic dye to remove a counter anion of a resin having a cationic group and a counter cation of an anionic dye. A coloring composition for a color light-passing sheet according to any one of the preceding claims, wherein the organic solvent contains ethylene glycol acetate (Glyc® Acetate), aromatic alcohol The coloring composition for a color filter according to any one of the above-mentioned items, wherein the coloring agent further contains a pigment. The coloring composition for a color filter of any one of the first to sixth aspects of the invention, further comprising a photopolymerizable monomer and/or a photopolymerization initiator 〇8, a color filter, which is The color filter used in any one of claims 1 to 7 is formed by a color composition. 100113563 Form No. A0101 Page 71 of 72 1003232411