TW201138838A - Two-layer type powder cosmetic preparation - Google Patents

Abstract

Disclosed is a two-layer type powder cosmetic preparation containing (a) an antibacterial zeolite powder and (b) 50-90% by mass of ethanol that serves as a base agent, which is characterized by additionally containing (c) glutathione and/or L-cysteine and (d) zinc paraphenolsulfonate. The two-layer type powder cosmetic preparation exhibits excellent re-dispersibility and discoloration prevention of the antibacterial zeolite powder (a). The two-layer type powder cosmetic preparation contains ethanol as a main base agent and has an antibacterial zeolite powder, which is insoluble in ethanol, blended therein. The two-layer type powder cosmetic preparation exhibits extremely excellent re-dispersibility of the antibacterial zeolite powder (a), and is capable of preventing discoloration of the antibacterial zeolite powder (a) when the cosmetic preparation gets on clothes.

Description

201138838 VI. Description of the Invention: [Technical Field to Which the Invention Is Ascribed] The present invention relates to a two-layer type powder cosmetic. Specifically, it is a stomach; a kind of double-layer powder cosmetic in which an insoluble: bio-antibacterial zeolite powder is insoluble in an ethanol base, and redispersion of the antibacterial zeolite powder at the time of use It is extremely excellent, and I can surely prevent discoloration of the antimicrobial zeolite powder when it is attached to clothing. [Prior Art] The antibacterial zeolite which is used as a deodorant cosmetic may be discolored by adhesion to sweat and clothing. Further, when the two-layer type powder cosmetic containing the antibacterial zeolite powder is used, it is necessary to redisperse the antibacterial zeolite which is separated into two layers to be uniformly dispersed. Further, the two-layer type powder cosmetic means a liquid preparation in which a powder is formulated, and if it is left to stand still, the powder is sedimented and separated into two layers of a powder and a liquid, so that the powder is vibrated to uniformly disperse the powder ( The powder is redispersed and then used. Patent Document 1 describes an oil-based skin containing an antibacterial zeolite, glutathione, and/or L. cysteine (Lcysteine) and an oil component, and discloses an oil system. When the sweating cosmetic is attached to clothes, glutathione and/or L-cysteine exerts the following effects: by washing the strip, the discoloration of the antibacterial zeolite caused by sunlight is liable to fall or to alleviate the turbidity. degree. On the other hand, in the powder double-layer type cosmetic containing anti-H vermiculite powder containing insoluble powder, the cosmetic base as a solution for dispersing the powder becomes an important constituent element. The base agent used in Patent Document 1 is limited to 201138838. : Department' and there is no discussion about ethanol base. Further, in the patent document, although there are some components of the present invention, such as antibacterial zeolite, caspase and cysteine, the exclusive content does not have any opinion on the overall composition of the present invention. . Further, the present invention in which an antibacterial zeolite which is an insoluble powder is blended in an ethanol base can prevent sun exposure by blending the glutathione and/or L-cysteine described in Patent Document 1. The resulting discoloration is found in the invention of the present invention. Also 'patent literature! The effect of the glutinous and sulphate in the middle surface refers to the effect that the discoloration caused by the exposure of the antibacterial zeolite attached to the clothes is easily detached by washing (that is, the washing property lifting effect). The effect of preventing the discoloration of the antibacterial zeolite caused by sunlight exposure in the present invention is not the same in essence. This fact can be easily understood from the fact that the evaluations of the "staining adhesion (anti-tarnishing effect) after the exposure of the glaze are all "X" in the examples i to 12 of the patent document. In addition, glutathione and/or L-cysteine do not necessarily exhibit the same effect as Patent Document 1 in the cosmetic of the present invention which is a different base of the oil-based skin external preparation, that is, Patent Document 1. . On the other hand, in the two-layer type powder cosmetic in which an antibacterial zeolite which is an insoluble powder is blended in an ethanol base, even if only glutathione and/or L-cysteine are blended, an antibacterial zeolite is not obtained. The cosmetic material having excellent redispersibility is also found in the invention of the present invention. Patent Document 2 describes a discoloration preventing agent for a silver-based antibacterial agent. Patent Document 2 discloses an anti-tarnishing agent which is an anti-tarnishing agent for a silver-based antibacterial agent which is composed of a compound having a thiol group, so that the antibacterial activity of the silver-based antibacterial agent is not lowered, and In this case, the silver-based antibacterial agent and the antibacterial property-imparting object treated by the treatment are prevented from discoloring, and the compound 6 having a thiol group is loaded with L-cysteine, reduced-type unsweetened form, thioglycolic acid, or the like. . However, the object of the discoloration preventing agent of Patent Document 2 is not particularly limited to the prevention of discoloration of the sheet to which the antibacterial property is imparted, and the invention of the present invention which is not formulated with an antibacterial zeolite which is an insoluble powder in an alcohol base is not limited. Powder double-layer cosmetics have any insights. In the double-layer type powder cosmetic in which the m 'ethanol base is blended with the antibacterial zeolite which is insoluble, even if only glutathione and/or L-cysteine are blended, the antibacterial zeolite cannot be obtained. The cosmetic material having excellent dispersibility is described above. Patent Document 3 describes a two-layer type powder cosmetic in which an antibacterial zeolite powder having a surface treated with polyfluorene is used as a dispersing agent using a polyether modified polyfluorene having an HLB of 5 or less, thereby achieving better redispersion. The effect is further described as preferably containing a p-cyanosulfonate of the phenolsulfonate. However, Patent Document 3 does not disclose an effect of preventing discoloration of the antibacterial zeolite powder. There is also the problem that the redispersed antimicrobial zeolite powder is defined as a powder whose surface is hydrophobized by polyfluorene. Further, whether glutathione and/or L-cysteine described in Patent Document 1 exhibits a good anti-tarnishing effect in the present invention, which is common to those skilled in the art of the present invention. It is unpredictable, and as described above, in the cosmetic materials having different base materials, the glutathione and/or L-cysteine do not necessarily exhibit the same effects as those of Patent Document 1. On the other hand, general agents are conventional. However, in the invention of the present invention in which the metal soap is used as the powder in the dispersed ethanol base and the anti-201138838 bacteria are used as the insoluble powder, even if the divalent metal salt of the fatty acid is separately formulated as the dispersing agent, the antibacterial property cannot be obtained. The full re-polished nature of the zeolite powder was confirmed by the inventors of the present invention. Patent Document 1: Japanese Patent Laid-Open Publication No. Hei. No. Hei. No. Hei. No. Hei. No. 2, No. Hei. A two-layer type powder cosmetic of zeolite powder, which is a cosmetic which is not used to disperse the powder during use, and which will settle after use. Generally, when the powder accumulates in the system, it causes agglomeration. It is difficult to disperse the effect. Therefore, the design of the two-layer type powder cosmetic material is a technical matter that makes the powder which is agglomerated at the time of sedimentation and is easily dispersed even when used. On the other hand, 'the technique of preventing discoloration caused by the antibacterial zeolite powder adhering to clothes' is also an extremely important technical issue in the preparation of a two-layer type powdered cosmetic material having an antibacterial zeolite powder. In view of the above-mentioned point of view, the inventors of the present invention have made intensive studies on the redispersibility and discoloration prevention of the powder in the two-layer type powder cosmetic containing the antibacterial zeolite, and found that the main component is ethanol. And a two-layer type powder in which an insoluble antibacterial zeolite powder is formulated in an ethanol base, and glutathione and/or L-cysteine is used as an anti-tarnishing sword of the antibacterial zeolite powder, and By adjusting the zinc benzene (tetra) acid as a redispersibility enhancer for the antibacterial zeolite powder, it can prevent the discoloration of the antibacterial zeolite powder when it is attached to the clothes, and can be used to enhance the vibrating of the container by using the container 6 201138838 Antibacterial / Fu The redispersibility of the stone powder is greatly improved, and the present invention has been completed. Further, it was found that in addition to the combination of glutathione and/or L-cysteine and zinc phenol zinc sulphate, a metal salt of a divalent or higher valence of a fatty acid (for example, a metal soap such as calcium stearate or zinc stearate) is also formulated. Further, the redispersibility of the antibacterial zeolite powder is further improved. The long-term standing still exhibits good redispersibility, and the present invention has been completed. An object of the present invention is to achieve a redispersibility of an antibacterial Fossil powder and an anti-tarnishing effect when attached to clothes, in a powder double-layer type cosmetic in which an antibacterial zeolite which is an insoluble powder is blended in an ethanol base. . That is, the present invention is a two-layer type powder cosmetic characterized in that it contains (a) an antibacterial zeolite powder, (b) ethanol as a base, and a mass of 5% to 5%, and further contains (c) bran. Glutathione and/or L-cysteine, and (d) p-phenol sulfonate, wherein the antibacterial zeolite powder is excellent in redispersibility and discoloration resistance. Further, the present invention provides a The two-layer type powder cosmetic further contains (e) a metal salt of two or more valences of the fatty acid. Further, the present invention provides the above-described two-layer type powder cosmetic, which further contains (f) water. Further, the present invention provides A two-layer type powder cosmetic according to the above aspect, wherein the antibacterial zeolite of the component (a) is coated with an MQ resin represented by the following average formula: Ο) (R3Si〇i/2)2 · nSi〇2 ( In the formula, R is a monovalent hydrocarbon group, and η is a number of from 1 to 5. Further, the present invention provides a two-layer type powder cosmetic in which a metal salt of a divalent or higher valence of a fatty acid is a hard fat. Acid about. In the ethanol base, a two-layer powder cosmetic having an antibacterial zeolite which is an insoluble powder is blended, and the antibacterial zeolite powder is extremely excellent in redispersibility, and the discoloration of the antibacterial zeolite powder can be suppressed when it adheres to clothes. [Embodiment] <(a) Antibacterial zeolite powder> The antibacterial zeolite powder used in the present invention is a zeolite powder in which an antibacterial metal ion is retained in a portion of the zeolite which can be ion-exchanged. That is, a zeolite powder in which a part or all of the ion-exchangeable ions of the zeolite are substituted with a bacteriostatic metal. In the present invention, a budstone which is replaced by an antibacterial metal ion together with an ammonium ion is preferred. The zeolite may be either natural zeolite or synthetic zeolite. Zeolite, aluminosilicate having a two-dimensional framework structure, can be represented by the formula xM2/naAl2〇3.YSi〇2.ZH2〇. In the formula, m represents an ion capable of undergoing diion exchange, and is usually a metal ion of a valence. 4 (metal) The atomic price of the ion. X &amp; γ represents the number of metal oxides, and the number of non-crystalline waters, respectively. Specific examples of the zeolite include, for example, A-type zeolite, χ-type zeolite, γ-type buddha, Τ-type buddha, high-temperature cerium oxide, soda lime, mordenite, and analcite. (1) (4), chabazite, eri〇nite, and the like. The ion exchange capacity of the rock, the A-type zeolite is 7 meq/g, the χ_ type zeolite is 6 4 &, the heart type = 201138838, the stone is 5 meq/g, the T_ type is boiling, and the .^ . is 3.41^ Lime and lime are 11.5 meq/g, silk first zeolite is 2.6 m 4 8 2 6 meq/e ϋ 'Fo is 5 meq/g, clinoptilolite is 2: q/g € Buddha..., wool is antibacterial metal ion Or ammonium ion &quot; "There is a ground τι; 4 Ding eagle parent for a full capacity. / Ions can be ionized ^ ^ v ions, such as sodium, calcium, potassium, magnesium, iron The metal ion m is an antibacterial or indefinite ion which is replaced by the plasma, and is silver, tin, erbium, silk, chrome, and chrome. In the present invention, the ion of U is preferred, preferably silver. ^ 1 silver ion, (four) sub-substituted with ammonium ion, "Focus is also good." Antibacterial metal ions from the antibacterial 丨 眺 眺 眺 篁 篁 篁 篁 篁 篁 沸石 沸石 沸石 沸石 沸石 沸石 沸石 沸石 沸石 沸石 沸石 沸石 沸石 沸石 沸石 沸石 沸石 沸石 沸石In order to contain silver ions ι·ι~15 plasmonic acid or zinc ions..1~&quot;% of the amount of antibacterial zeolite 'ammonium ion' in the zeolite, -r Ά f, up to 20 mass% , From the effective anti-Ludan Α 乂 乂 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 c. The mass percentage of the zeolite in the dry basis. In the present invention, the antibacterial zeolite can be used as a commercial product. It is preferable to use, for example, an antibacterial silver ion instead of a zinc ion and an ion-recording zeolite (cellamedic). AJ 10N: shares of Guyang, + SINANEN ZEOMIC). The manufacture of antibacterial zeolites is prepared, for example, in the following manner. That is, the silver ions, 'illusion ions, zinc ions, etc., which are prepared in advance, are prepared. The mixed aqueous solution of the metal ions is contacted with the zeolite. The ions capable of ion exchange in the zeolite are replaced by the above ions. 201138838 Contact, may be 10~70t:, preferably 4〇~6 (rc, in batch or continuous The formula (for example, the column method) is carried out for 3 to 24 hours, preferably (7) to 24 hours. Further, the pH of the mixed aqueous solution is appropriately adjusted to 3 to 1 Torr (preferably 5 to 7). Adjustment prevents precipitation of silver oxide or the like to the surface of the zeolite or fine In the pores, it is better. In addition, the ions in the mixed aqueous solution are usually supplied in the form of a salt. Silver ions can make (four) silver acid, silver sulfate, gas, silver, silver acetate. Ammonia silver nitrate, diammonium silver sulfate, etc., copper ion 'can use copper nitrate (Π) 'peroxy acid copper, copper acetate, potassium tetracyanosilicate, sulfuric acid steel, etc., zinc ion, can be used nitric acid (11 ), zinc sulfate, zinc peroxy zinc, zinc thiocyanate, zinc acetate, etc., mercury ions, can use mercury vapor, mercury nitrate, mercury acetate, tin ions, tin sulfate, lead ions, can be used Sulfuric acid Lm, barium ion, can use gasification secret, touch chemical, etc., cadmium ion, can use cadmium permanate cadmium sulfate, cadmium nitrate, cadmium acetate, chromium ion, can use chromium perchlorate, chromium sulfate, sulfuric acid Ammonium chromium, chromium nitrate, etc., Ming ion can use the gas acid Ming 'sulphuric acid Ming, nitric acid Ming, acetic acid snake and so on. The content of the antibacterial metal ion in the zeolite can be appropriately controlled by adjusting the concentration of each ion (salt) of the above mixed aqueous solution. For example, when the antibacterial zeolite contains silver ions, an antibacterial zeolite having a suitable silver ion content of 〇. id% can be obtained by setting the silver ion concentration in the mixed aqueous solution to 0.002 Μ /1 to 0.15 Μ /1. Further, when the antibacterial zeolite further contains copper ions or zinc ions, the copper ion concentration in the mixed aqueous solution is 0.1 M/1 to 0.85 M/1, and the chroma ion concentration is 〇·15 M/1 to 1.2 ΜΛ ' An antibacterial zeolite having a suitable steel ion content of 〇·1 to 8% and a zinc ion content of 01 to 8 〇/〇 can be obtained. 10 201138838 In addition to the above mixed aqueous solution, the antibacterial zeolite can be ion-exchanged by using a separate water-containing material of each ion and allowing each aqueous solution to be successively mixed with a phosgene. The concentration of each ion in each aqueous solution can be determined depending on the concentration of each ion in the mixed aqueous solution. The ion-master was replaced with the finished zeolite, which was thoroughly washed and dried. Dry, at 105C~115C, or under reduced pressure ((a) hit (four)) to 7〇~9〇. It is better to do it. In addition, the ion of the water-soluble salt or the organic ion of the tin or the like may be replaced with an organic solvent such as ethanol or propylene to cause the insoluble salt to be precipitated without being precipitated. The average particle diameter of the antibacterial zeolite powder is preferably 1 〇 &quot; m or less. It is preferably 0_1~5# m. Further, when the average particle diameter is in this range, in the particle size distribution, it is preferably 2% by mole or less in the case where the particle diameter exceeds 15/im. The average particle diameter is measured by a usual method such as the number average diameter of the image analysis of the transmission electron microscope photograph. <MQ resin-coated antibacterial zeolite powder> An antibacterial zeolite powder coated with a ruthenium resin is preferred from the viewpoint of improving the usability of the local medium. The antibacterial zeolite powder is preferably a hydrophobized powder obtained by subjecting MQ resin to a surface treatment by a usual method. The resin used in the present invention means that it is composed of Si 〇 2 units (q units) and units (m units) jin. P-knife is cross-linked by the conventional organic polyoxo-oxygen resin (trimethylsiloxysilic aeid). It has a configuration shown by the average formula (1) and its M/Q molar ratio is 〇.7 〜1 〇. 201138838 0)

(R3SiO&quot;2)2 · nSiO (wherein R is a monovalent hydrocarbon group, and n is a number of 1 to 5.) The MQ resin has been used alone as a water repellent, such as a foundation, an eye cream, an emulsion, a cream, and a sunscreen lotion. Cosmetic raw materials, etc., are also used as surface treatment agents for powders for cosmetics (Japanese Patent No. 337859, etc.). The MQ resin used in the present invention is generally (CH3)3SiC1, (CHASiOSUCH3)3, (organic oxirane having M units such as CHASiOH, and water glass, ortho-alkyl phthalate). a phthalic acid ester such as an alkyl polyphthalate, which is obtained by adding water or an acid to an organic solvent to carry out hydrolysis and condensation, followed by washing, washing, solvent removal, etc. The MQ resin used in the present invention The M/Q molar ratio is 〇7~1〇. The reason is that 'if the M/Q molar ratio exceeds 1〇 or is less than 〇7, then a good coating may not be obtained. The molecular weight of the MQ resin used in the invention is not particularly limited, and is preferably between 500 and i 〇 _. The reason is that if the molecular weight is not sufficient, there is a disadvantage that the treated powder tends to aggregate. , thin = Q WI has a disadvantage that the solubility of the organic solvent is lowered and the surface of the powder cannot be uniformly coated. The surface of the sapphire is preferably the surface of the antibacterial smectite. The method of coating the MQ resin is not particularly limited. For example, it can be 姑 P-call-like, etc. - Search, one; two stone two Henschel mixer (Henschel grease, remove the solvent, the heart has been dissolved in the solvent called the tree mq tree m' L from this. The solvent used is volatile organic solvent For example, there are decamethylcyclopentasiloxane, decamethylcyclopentasiloxane, 2-propane, hexane, cyclohexane, etc. The amount of MQ resin coated on the antibacterial zeolite is relative to the antibacterial zeolite. The ratio is expressed as 0. 5 mass% or more' is preferably 0. from the viewpoint of usability. 5 to 10% by mass» is preferably from 1 to 3% by mass. <Preparation amount of antibacterial zeolite powder> The content of the antibacterial zeolite in the two-layer type powder cosmetic is from 0.1 to 50% by mass, preferably from 1 to 50% by mass based on the total amount of the two-layer type powder cosmetic. %, more preferably 3 to 7 mass%. The appropriate amount is appropriately determined and formulated according to the form of the product. <(b) Ethanol> The two-layer type powder cosmetic of the present invention contains (b) ethanol as a main base of the solution, and contains 5 〇 to 9 〇 mass ° / 相对 with respect to the total amount of the two-layer type powder cosmetic. More preferably, it is a two-layer type powder cosmetic containing a solution system of about 75 to 90% by mass of ethanol. When the content of the ethanol constituting the solution is as much as 75 to 9% by mass, the anti-tarnishing effect of the antibacterial zeolite powder may be excellent. Further, in the two-layer type powder cosmetic of the present invention, the other components constituting the solution for dispersing the antibacterial zeolite powder may be formulated, and the water may be formulated to have a mass % of 丨1. <(c) glutathione and/or L-cysteine> The glutathione and/or L-cysteine used in the invention contains (a) an antimicrobial zeolite powder and as a base (b) The effect of preventing discoloration of the antibacterial zeolite caused by sunlight exposure in the two-layer type powder cosmetic of 50 to 9% by mass of ethanol. That is, the makeup 13 201138838 of the present invention which is used as a deodorant can prevent the discoloration caused by sunlight exposure due to sweat or the like adhering to clothing and adhering to the clothing (4) antibacterial zeolite powder. Significant effect of surface cysteine and / or L-cysteine. This effect is the effect of cercosin and/or L-cysteine in the invention of the present invention, and the unexpected effect originally discovered by the inventors of the present invention is a remarkable effect unique to the present invention. Furthermore, the patent documents described in the prior art! The effect of the glutathione and/or L4 cystine is not to prevent the effect of discoloration caused by sweat and sunlight exposure. That is, in the invention of Patent Document 1, even glutathione and/or glutathione is formulated. L-cysteine also causes discoloration of the antibacterial zeolite (contamination of clothing) due to sweat and sunlight exposure, and the effect of easy discoloration by washing (washing improvement effect) is patent The effect of the glutathione and/or L-cysteine of the invention described in Document i is intrinsically different from the effect of the invention of preventing the discoloration of the antibacterial zeolite produced by sunlight exposure. In the invention of the present invention, the (a) antibacterial zeolite powder and the double-layer powder cosmetic of 50 to 90% by mass of ethanol as a base agent are formulated with glutathione and/or L-cysteine as essential components. The color-changing effect greatly contributes to the progressive effect of the invention. <(c) Content of glutathione and/or L-cysteine> Glutathione and/or L-cysteine in double The content of the layered powder cosmetic, compared to the double layer powder The total amount of makeup at the end is preferably 〇. 丨~5 mass%, more preferably 0·1~1. 5% by mass, and even better. 3 ~ 〇. 5 mass%. <(d) Pair of zinc phenolsulfonate> The zinc phenolate used in the invention of the present invention contributes to the following conditions: the essential component of 201138838: (c) glutathione and/or cysteamine in the formulation The acid is an essential component and contains (a) an antibacterial buddha powder and a (b) ethanol 5 〇 to 90% by mass of a two-layer type powder cosmetic as a base, and the container is vibrated by use to separate The redispersibility of the (a) antibacterial zeolite powder which is double-layered and settled is greatly improved. That is, (d) the effect of (a) the redispersibility of the antibacterial zeolite powder is exhibited by the fact that the benzene sulfonic acid is not alone. (c) glutathione and/or L-cysteine, which is capable of preventing discoloration of the above-mentioned antibacterial zeolite powder, is also a double-layer type powder (4) which is uniquely formulated as an essential component, 'that is, the bran which is essential ingredient In the presence of cystine and/or L-cysteine, (d) has a significant effect on zinc phenolsulfonate (a) redispersibility of the fungicidal zeolite powder, which was discovered by the inventors of the present invention. Further, in the meal layer type powder cosmetic containing ethanol as a main base, it is difficult to re-disperse the (4) antibacterial zeolite powder. However, in the case of the present invention, even if a large amount of (a) antibacterial zeolite powder is blended (for example, 5 mass% or more with respect to the total amount of the two-layer type powder cosmetic), significant redispersibility can be obtained. <(d) Formulation amount of zinc salt of benzene-based acid sulphate> The content of benzoic acid-acid zinc salt in the double-layer powder cosmetic is preferably 〇 relative to the total amount of the two-layer powder cosmetic.  1 to $% by mass, more preferably 0. 1~1. 5 mass%, more preferably 〇 3~〇 7 mass 〇 / "not full 〇" mass % can not expect a significant increase in redispersibility, and even if the blending exceeds 5 mass %, the effect cannot be expected to increase. <(e) a metal salt of a divalent or higher valence of a fatty acid> 15 201138838 In the present invention, in addition to a combination of a glutathione and/or an L-cysteine and a phenolic acid, a fatty acid is formulated. The metal salt above the valence will further enhance the redispersibility of the antibacterial zeolite powder and exhibit good redispersibility after standing for a long period of time, which was discovered by the inventors of the present invention. The metal salt of two or more valences of the fatty acid is preferably, for example, calcium stearate, zinc stearate, magnesium stearate, calcium palmitate or aluminum stearate, and particularly preferably calcium stearate. <(e) Formulation amount of metal salt of two or more valences of fatty acid> The content of the metal salt of the divalent or higher valence of the fatty acid in the two-layer type powder cosmetic is preferably 相对 with respect to the total amount of the two-layer type powder cosmetic. 1 to 5 mass%. Less than 0. At 1% by mass, it is impossible to expect a further increase in redispersibility, and even if 5 masses/◦ are blended, the effect cannot be expected to increase. <(1) Water> In the present invention, it is preferred to mix water in stepwise. The amount of water to be formulated is preferably from i to 4% by mass, more preferably from 1 to 25% by mass, even more preferably from 1 to 5% by mass, based on the total amount of the two-layer type powder cosmetic. In the external preparation for skin of the present invention, in addition to the above-mentioned essential components, it is also necessary to appropriately mix other components used in usual cosmetics, such as powders, liquid fats, solid fats, waxes, hydrocarbon oils, higher fatty acids, high: alcohols, esters Oil, polyoxygenated oil, anionic surfactant, cationic boundary agent. , amphoteric surfactant, nonionic surfactant 'diabetes agent, film agent, ultraviolet absorber, metal integrator, lower alcohol, h alcohol, glycosyl acid 'organic amine, polymer emulsion (4) UU (four), pH adjuster The skin nutrients, vitamins, antioxidants, antioxidants, perfumes, and the like are produced according to the desired dosage form by a usual method. In the following, the specific ingredients of the present invention can be prepared by preparing one or more of the above-mentioned essential components and the following components. Further, the powder wettability or oil content caused by the volatilization in the present invention is also good. In order to prevent the floating powder (floating white) of ethanol or water after application, the type or amount of the moisturizing agent or the oil component which is formulated in a liquid state at room temperature is not limited, and as long as it is used in the above (4), A humectant containing a butylene glycol or a polypropylene glycol is preferably from 1 to 15% by mass. Further, in the present invention, it is preferable that the tackifier is used from the viewpoint of usability (preventing dripping phenomenon after application, etc.). The tackifier is not particularly limited as long as it can be dissolved in a base agent having 50% by mass or more of ethanol and can exhibit a viscosity-increasing effect, and is preferably a hydroxypropylcellulose from the viewpoint of usability. When hydroxypropylcellulose is used for the above purpose, it is preferably formulated in an amount of from 1 to 5 % by mass based on the total amount of the two-layer type powder cosmetic. Not full. 〇 1 . Bays % cannot expect to prevent the use of the drip phenomenon. If the deployment is more than 5. When 0% by mass, the viscosity becomes too high, and even if the powder is left still, it does not settle and cannot be a two-layer type powder cosmetic. Furthermore, even if the tackifier is formulated in a two-layer powder cosmetic, the viscosity in the system is increased (the thickness is imparted from the viewpoint of the usability of the coating). This is generally true for the redispersibility of the powder. Under the unfavorable tackifier blending conditions, the present invention still has a remarkable effect of highly maintaining good powder redispersibility. Examples of the powder component other than the antibacterial zeolite include inorganic powders (for example, talc, kaolin, mica, sericite, muscovite, phlogopite, synthetic mica, red mica, biotite, vermiculite). 17 201138838 Carbonated town, carbonated feed, aluminum alumite, bismuth citrate, bismuth citrate, magnesium bismuth, magnesium strontium, metal tartrate, magnesium, cerium oxide, barium sulfate, sulfuric acid (plaster gypsum), phosphoric acid crane, fluoroapatite, hydroxyapatite, ceramic powder, metal soap (for example, zinc zinc citrate, calcium palmitate, aluminum stearate, boron nitride, etc.); organic powder ( For example, polyamide resin powder (nylon powder), polyethylene powder, polymethyl methacrylate powder, polystyrene powder, copolymer of styrene and acrylic acid, benzoguanamine resin powder, poly Tetrafluoroethylene powder, cellulose powder, etc.; inorganic white pigments (such as titanium dioxide, zinc oxide, etc.); inorganic red pigments (such as iron oxide (iron oxide red), iron titanate, etc.); Color pigments (for example iron oxide, 7 "inorganic yellow pigments (e.g., yellow iron oxide, loess and the like); inorganic black pigments (for example insects ·. :, cerium oxide, low-temperature titanium oxide, etc.; inorganic purple pigments (such as manganese violet, recorded i, etc.) 'inorganic green pigments (such as chromium oxide, chromium hydroxide, cinnamate, etc. h inorganic basket color pigments ( For example, ultramarine blue, Prussian blue, etc.; pearlescent pigments (Example 1 titanium oxide coated mica, titanium oxide coated oxygen gasified silk, oxidized Qin coated 'moon stone Syria' color silver oxide coated mica, oxychlorinated secret, fish scale box Etc.); is a ♦ knife end pigment (for example, Ming powder, copper powder, etc., a few wrong colors, locks or the name of the color of the temple (such as red 201, red withdrawal, red version, red 2 0 5, red Organic pigments such as 唬, 唬 220唬, red 226, red 228, red ^05, horn, orange 2G3, orange 2 (10), yellow 2G5, yellow 401 7 and blue 404, red 3 No. 'Red 104, Red 106, Red 2 Bar 227唬, Red 23〇, Red 4〇1, Red 5〇5, Light 2 咕205, Yellow 4, Yellow 5, Yellow 202 Just, Huang Ben, ~, Green No. 3 and Blue No. 1, etc.); natural pigments (eg 18 201138838 leaf green , β-carotene, etc.) Liquid oils such as avoca oil, camellia oil, macadamia nut oil, corn oil, olive oil, rapeseed oil, eggs Butter, sesame oil, persic oil, wheat germ oil, sasanqua oil, castor oil, linseed oil, safflower oil, cottonseed oil, perilla oil, soybean oil, peanut oil, tea seeds Oil, oyster sauce, rice bran oil, Chinese tung oil, Japanese tung oil, jojoba oil, germ oil, triglycerin, etc. Solid oils such as cocoa butter, raisin oil, hardened oil, standard oil, palm kernel oil , wood wax nuclear oil, hardened oil, wood wax, hardened castor oil, etc. waxes such as beeswax, candelabra wax, cotton wax, Brazilian palm ant, bayberry wax, insect wax, montan wax ( Montan wax), wax, lanolin, kapok wax, lanolin acetate, liquid lanolin, mellow pier, water-containing lanolin fatty acid isopropyl ester, hexyl laurate, reduced lanolin, jojoba Wax, hard lanolin, shellac wax, p E lanolin ether, POE lanolin acetate 'poe cholesterol ether, lanolin fatty acid polyethylene glycol ester, POE hydrogenated lanolin ether, etc. Candle oil such as liquid paraffin, ozokerite, squalane, Pristane, paraffin, squalene, petrolatum, etc. Higher fatty acids such as lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, undecylenic acid, Stearic acid, linseed oleic acid, linoleic acid, eicosapentaenoic acid? VIII), docosahexaenoic acid (DHA) and the like. Higher alcohols such as linear alcohols (for example: lauryl alcohol, cetyl alcohol, stearyl alcohol, 19 201138838 窬 sterol, meat ugly alcohol, oleyl alcohol, cetostearyl alcohol 4 ) branched alcohols ( For example, monosteary 丨giyCerine ether 'salmonol batyl alc〇h〇1, 2 mercaptotetradecyl alcohol, lanolin alcohol, cholesterol phytosterol, hexyldodecanol, isostearyl alcohol, octane Glycosyl alcohol, etc.). = is an ester oil, and examples thereof include isopropyl myristate, cetyl octanoate, octyldodecyl myristate, isopropyl palmitate, butyl stearate, laurel I, and soy bean acid. Carnitine, oleic acid vinegar, hexyl octyl octyl decyl phthalate, cetyl lactic acid, myristyl lactate, lanolin acetate, stearic acid isopropyl vinegar 'isostearic acid, 12 Tertyl stearate cholesterol Sa- 2 ethylhexanoate ethylene glycol ester, dipentaerythritol fatty acid ester, monoisostearic acid-N-alkyl glycol ester, neopentyl glycol dipentate, malic acid II Isostearyl ester, glyceryl di-2-heptyl undecanoate, trimethylolpropane trioxoethylhexanoate, trimethylolpropane diisostearate, tetra-2-ethylhexanoic acid Pentaerythritol ester, tris-2-ethylhexanoic acid glyceride, tricaprylin, triisocalyxate/succinyl succinate, dimethylglycol 2-ethylhexanoate, cetyl 2-ethylhexanoate 2_ethylhexyl palmitate, glyceryl trimyristate, glyceryl tris-heptyl undecanoate, fatty acid methyl ester of castor oil, oleyl oleate, acetamidine glycerol 'palmitate-2-heptyl Undecyl ester, Diisobutyl phthalate, 沁月桂醯基面面酸-2· 辛基十二录§, adipic acid 2_2_heptyl decyl-garden vinegar, lauric acid vinegar, azelaic acid _2·ethylhexyl vinegar, myristic acid _2_hexyl broth, palmitic acid 2-hexyl decyl phthalate, adipic acid · 2 hexyl decyl phthalate, diisopropyl sebacate, cyanoic acid - 2 · Ethylhexyl ester, # triethyl citrate, and the like. Examples of the polysulfuric acid oil include: a chain-like polyoxan (for example, dimethyl 20 201138838-based polyoxyxane, nonylphenyl polyoxyalkylene, and diphenyl polyoxyalkylene-like poly-stone Oxygen crater (for example, octamethylcyclotetrazepine oxy-octogen, decamethylcyclopentafluorene, decylmethylcyclohexaoxane, etc.), a three-dimensional network structure of polyoxynium tree Polyoxyxene rubber, various modified polyoxyalkylene oxides (amine-based modified polyoxonium condensate-scaled poly-stone concentrating oxygen hospital, burn-based modified poly-stone oxy-combustion, sturdy modified poly-stone eve: burning, etc. Anionic surfactants such as fatty acid soaps (such as sodium laurate, sodium palmitate, etc.); higher alkyl sulfate salts (such as sodium lauryl sulfate, potassium lauryl sulfate, etc.); alkyl ether sulfates ( For example, p〇E_ lauryl triethanolamine, POE-sodium lauryl sulfate, etc.; N_mercaptocreatine (such as sodium lauryl sarcosinate); higher fatty acid decyl sulfonate (such as N_) Myristyl-N-methyltaurine sodium, coconut oil fatty acid methyl taurate, sodium lauryl methyl taurate, etc.; Ester salts (such as pE-oleyl ether sodium phosphate, POE-stearyl ether phosphate, etc.), sulfosuccinates (such as di-2-ethylhexylsulfosuccinic acid) Sodium, single laurel, soap, ethanol, decylamine, polyoxyethylene, sulphate, sodium lauryl succinate, etc.; alkyl benzene sulfonate (such as sodium linear dodecyl benzene sulfonate) , linear dodecylbenzene acid triethanolamine, linear dodecyl benzene acid, etc.; higher fatty acid ester sulfate salt (such as hardened coconut oil fatty acid glycerol sulfate, etc.); N-mercapto glutamate (such as N-lauric acid glutamic acid monosodium, N-stearyl glutamic acid disodium, N-myristyl-L-glutamic acid monosodium, etc.); POE-alkyl ether carboxylic acid; P0E-hospital dilute propyl ether carboxylate; α-dilute hydrocarbon sulphate; higher fatty acid ester sulfonate; secondary alcohol sulphate; higher fatty acid alkyl decyl sulphate sulfate; Ethanol amide succinate; Ν-palm 21 201138838 Stiffened aspartic acid bistriethanolamine; casein sodium, etc. Cationic surfactant, for example, trimethyl ketone Salt (for example, stearyl chloride trimethyl record, gasification laurel trimethyl sulphate, etc.); burnt base (iv) wrong salt (for example, gasification _ base. ratio. error, etc.); gasification (4) Dialkyldimethylammonium salt; gasified poly(N,N•dimethyl_3,5·methylenepiperidin); calcined quaternary salt;戍基录盐,·炫基异喧琳锧 salt, one yard base salt; Ρ0Ε. Hyunylamine; alkylamine salt; polyamine fatty acid He bio, sterol fatty acid derivatives; gasification section burning; gasification of benzethonium chloride (benzethonium chloride). The amphoteric surfactant may, for example, be an amphoteric surfactant (for example, '2·undecyl-N,N,N-ethylethylcarboxymethyl) oxazoline, 2-cocoon Base-2-mythracene hydroxide, small tickyl ethoxy 2 sodium salt, etc.); beet test system surfactant (for example, 2-7 heptyl group · ν _ 基 甲 IN · · 乙基 乙基 乙基°m ° sit rust betaine, lauryl di-f-aminoglycolic acid beet test, burnt beet test, guanamine beet test, continuous beet test, etc.). The lipophilic nonionic surfactant may, for example, be a sorbitan fatty acid ester (for example, sorbitol wild oleic acid vinegar, sorbitol liver isostearic acid vinegar, sorbitol needle monolaurate vinegar' sorbitol liver single Grazing acid ester, sorbitol liver monostearic acid brewing, sorbitol needle sesquiole oleic acid vinegar, sorbitol liver trioleic acid vinegar, pentaethylhexyl glycerol sorbitan liver, tetras-2-ethylhexyl Acid diglycerin sorbitol field, etc.; polyglycerol fatty acid glycerol brewing (for example, single cottonseed oil fatty acid glycerin vinegar, monofenic acid glycerin vinegar, sesquioleic acid glycerin vinegar, monostearic acid glycerin vinegar, oleic acid glutamate Glycerol glycerin, monostearic acid glycerin malic acid vinegar, etc.; propylene glycol fatty acid vinegar (for example, glyceryl monostearate, etc.); hardened castor oil 22 201138838 derivative; glycerin burning ether. The hydrophilic nonionic surfactant may, for example, be a POE-sorbitan fatty acid ester (for example, POE-sorbitan monooleate, POE-sorbitan monostearate, POE-sorbitol single) Oleate, POE-sorbitan tetraoleate, etc.; POE-sorbitol fatty acid esters (for example, POE-sorbitol monolaurate, POE-sorbitol monooleate, POE-sorbent Sugar alcohol pentaoleate, POE-sorbitol monostearate, etc.; POE-glycerol fatty acid esters (for example, POE-glycerol monostearate, POE-glycerol monoisostearate, POE- POE-monooleate such as glycerol triisostearate; POE-fatty acid esters (for example, Ρ Ο E - distearic acid vinegar, Ο Ο E monooleic acid vinegar, Ρ Ο E - two oil Acid@, bis-stearic acid glycol, etc.; POE-alkyl ethers (for example, POE-lauryl ether, POE-oleyl ether, POE-stearyl ether, POE-cedocyl ether, POE-2- Octyl dodecyl ether, POE-cholesteryl alcohol ether, etc.; Pluronic type (eg, Pluronic, etc.); POE · POP-alkyl ethers (eg, POE · POP) - cetyl ether, POE · POP -2-mercapto Tetramethyl ether, POE · POP-monobutyl ether, POE · POP-hydrated water-containing lanolin, POE · POP-glyceryl ether, etc.; four POE · tetra-POP-ethylenediamine condensate (for example, Tetronic ( Tetronic), etc.; POE-castor oil hardened castor oil derivatives (for example, POE-castor oil, POE-hardened castor oil, Ο Ο E - hardened castor oil monoisostearic acid S, Ρ Ο E - hardened castor oil Triisostearate, POE-hardened castor oil, monopyroglutamic acid monoisostearate diacetate, POE-hardened castor oil, maleic acid, etc.; P0E-beeswax, aqueous lanolin derivative (eg, POE) - sorbitol beeswax, etc.; alkanolamine (for example, coconut oil fatty acid diethanolamine, lauric acid monoethanolamine, fatty acid isopropanolamine, etc.); POE-propylene glycol fatty acid ester; POE-alkane Base amine; POE-fatty acid 23 201138838 Stear amine; sucrose fatty acid ester; alkyl ethoxy dimethyl amine oxide; trioleyl phosphate. Examples of the humectant include polyethylene glycol, propylene glycol, glycerol '丨, 3-butanediol, xylitol, sorbitol, maltitol, chondroitin sulfate, hyaluronic acid, and mucopolysaccharide sulfate. Acid), atelepeptide collagen (atelocollagen) '12-hydroxystearic acid cholesterol ester, sodium lactate, bile acid salt, racemic-pyrrolidone carboxylate, short-chain soluble collagen, diglycerin (EO) P 〇 Additive, R〇sa roxburghii Tratt extract, Achillea millefolium extract, melilot extract. The following compounds are mentioned as a ultraviolet absorber. (1) Benzoic acid-based ultraviolet absorbers, for example, p-aminobenzoic acid (hereinafter, abbreviated as PABA), PABA monoglyceride, N,N-dipropoxy PABA ethyl ester, N,N-diethoxy PABA ethyl ester, N,N-dimethyl PABA ethyl ester, hydrazine, hydrazine-dimethyl PABA butyl ester, N,N-dimethyl PABA ethyl ester, and the like. (2) Anthranilic acid is an ultraviolet absorber, for example, homomenthyl-N-acetylanthranilate or the like. (3) Salicylic acid-based ultraviolet absorbers, for example, amyl sulphate, salicylate, salicylic acid, sulphuric acid, phenyl sulphate, benzyl sulphate, sulphuric acid Alcohol benzene vinegar and the like. (4) cinnamic acid-based ultraviolet absorbers, for example, octyl cinnamate, ethyl-4-isopropylcinnamate, decyl-2,5- 24 201138838 isopropyl cinnabarine, ethyl-2, 4_isopropyl cinnamic acid g, methyl-2, isopropyl cinnamate, propyl-p-methoxycinnamate, isopropyl-p-methoxy cinnamon Ss_Sa, isoamyl -p-methoxy cinnamic acid vinegar, octyl-p-methoxy cinnamate (2-ethylhexyl-p-methoxycinnamate), 2-ethoxyethyl-p-methoxy Cinnamate, cyclohexyl-p-methoxycinnamate, ethyl_α_cyano-β-phenylcinnamate, 2-ethylhexyl-α-cyano-β-phenyl cinnamate And glyceryl mono-2-ethylhexyl-di-p-methoxy cinnamate. (5) Triazine-based ultraviolet absorber For example, bisresorcinyltriazine. More specifically, such as bis{[4-(2-ethylhexyloxy)-2-hydroxy]phenyl}-6-(4-decyloxyphenyl) ι, 3,5-triazine, 2 , 4,6-tris{4-(2-ethylhexyloxycarbonyl)anilino}1,3,5-triazine, and the like. (6) Other ultraviolet absorbers, for example, 3-(4'-benzylidene)-racemic decane, 3-phenylhydrazinyl-racemic calcination, 2-phenyl-5-methyl Benzene is alkoxy. 2-phenyl-5-methylbenzoxazole, 2,2'-hydroxy-5-nonylphenyl benzotriazole, 2-(2,-hydroxy-5'-third octyl leather) benzotriene Azole, 2_(2,_hydroxy-5, octylphenyl) benzotriazole, difentanyl, 4-decyloxy-4,-tert-butyldiphenylfluorene, 5- ( 3,3 -monomethyl-2-norbornyl fluorenyl)-3 - 3 嗣 嗣 嗣 (5-(3,3-dimettiyl-2-norbonlidene) 3-penten-2-one), two 〇末琳四 H 嗔 ° 酮 秦 (dimorpholinopyridazinone) and so on. Qin Yan. biological. The metal chelating agent may, for example, be 1-hydroxyethane-1,1-disulfonic acid, 1-hydroxyethane-1,1-disulfonic acid tetrasodium salt, disodium ethylenediaminetetraacetate or ethylenediamine. Trisodium tetraacetate, tetrasodium edetate, sodium citrate, sodium polyphosphate, 25 201138838 sodium metaphosphate, gluconic acid, phosphoric acid, citric acid, ascorbic acid, acetoacetate, ethylene glycol Amino hydroxyethyl triacetate trisodium and the like. Examples of the lower alcohol include, for example, ethanol 'propanol, isopropanol, isobutanol, t-butanol, and the like. Polyhydric alcohols include, for example, dihydric alcohols (for example, ethylene glycol, propylene glycol, and trimethylene glycol). 1,2-butanediol, l,3-butanediol, tetramethylene glycol, 2,3-butanediol, pentadecanediol, 2-butene-I,4-diol, Hexanediol, butylene glycol, etc.); a trihydric alcohol (for example, glycerol dimethylolpropane, etc.); a tetrahydric alcohol (for example, pentaerythritol such as 1,2,6-hexanetriol, etc.); a glycol (eg, xylitol, etc.); a 6-valent alcohol (eg, sorbitol, mannitol, etc.); a polyol polymer (eg, diethylene glycol, dipropylene glycol, triethylene glycol, polypropylene glycol, four) Ethylene glycol, diglycerin, polyethylene glycol, triglycerin, tetraglycerol, polyglycerol, etc.); alkyl ethers of 2 alcohols (for example, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol single Butyl ether, ethylene glycol monophenyl ether, ethyl ketone early hexyl ether 'ethylene glycol mono 2 decyl butyl ether, ethylene glycol isoprene, ethylene glycol benzyl ether, ethylene glycol isopropyl ether, ethylene glycol Dimethyl ether, ethylene glycol Ether, ethyl alcohol-butyl ether, etc.; 2-alcohol alkyl ethers (for example, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, ethylene glycol diethyl ether, glycol monoterpene ether, triethylene glycol) Ethylene glycol dimethyl ether, diol oxime ether, triethylene dimethyl ether, propylene glycol mono 6 diethylene glycol monobutyl ether, diethylene glycol butyl ether, diethylene glycol monoethyl ether, propylene glycol monoether C: alcohol Dibutyl ether, propylene glycol isopropyl ether, dipropylene glycol methyl ether, di-n-alcohol ether, dipropylene glycol butyl ether, etc.; 2-valent alcohol ether esters (for example, 6 bis-dimethyl ether 鱿 曰 曰, ethylene glycol Monoethyl ether acetate, ethylene glycol monobutyl ether acetate S 曰 ethyl alcohol mono phenyl chlorinated acetic acid, ethylene glycol diadipate 酉, B; recorded &gt; 26 201138838 broken glutamate, diethylene glycol single Ethyl acetate, diethyl benzoic acid, propylene glycol monoterpene ether acetate, propylene glycol monoethyl ether acetate, propanol monopropyl ether acetate, propylene glycol monophenyl ether acetate, etc.; Glycerol monoalkyl ether (eg, xylitol, selachyl aic〇h〇l, meal 'hepatitol, etc.); sugar alcohol (eg, sorbitol, maltitol, Maltotriol, mannitol, sucrose, erythritol, glucose, fructose, starch-decomposing sugar, maltose 'xylose, starch-decomposing sugar-reducing alcohol, etc.; tetrahydrofuran methanol; p〇E_ra hydrogen-biting methanol; POP-butyl ether; POP. POE_butyl ether; trimeric hydroxypropene glyceryl ether; p〇p_ glyceryl ether; P〇p-glyceryl ether phosphate; pop. Poe-neopentitol ether; polymonosaccharide, for example, a tri-carbon sugar (for example, D-glyceraldehyde, dihydroxy acetonide, etc.) 'four carbon sugar (for example, D-erythrose) , D-erythro-ketose, D-threose, erythritol, etc.; five-carbon sugar (for example, L-arabinose, D-xylose, L_lyxose (L_iyx〇) Se), anthracene arabinose, D-ribose, D_ribulose, D-xylulose, L-xylulose, etc. "hexasaccharide (for example, glucose D-talose, D-allo-sugar (D- psicose), D-galactose, D-fructose, [-galactose, L-mannose, D-tagat〇Se, etc.); =carbose (for example, heptose, Heptanose); octasaccharide (eg, 〇ct〇diui〇se, etc.) _, deoxy sugar (eg, 2_deoxy-D-ribose, 6-deoxy-L-galactose, 6-deoxy L-mannose) Sugar, etc.; amino sugar (for example, D-glucosamine, D-galactose saliva k, amino sugar acid, muramic aci, etc.); uironic acid (for example, D- Glucuronic acid, D_mannuronic acid, l·glucuronic acid, D_galacturonic acid, L-iduronic acid ). 27 201138838 Oligosaccharides 'for example, sucrose, umbelliferose, lactose, planteose, isoglucan (is〇Hgn〇se), αα•trehalose, cottonseed Sugar, lignose, stachyose, mullein, etc. Polysaccharides, for example, cellulose, alfalfa seeds, chondroitin sulfate, Ιχ·tai galactan, dermatan sulfate, sugar Original, gum arabic, heparan sulphate, hyaluronic acid 'tragacanth gum, keratin sulfate, chondroitin, sinensis gum, guar gum, guar gum, Portuguese Glycan, keratin sulfuric acid, locust bean gum, glass station glucan, glutinic acid, etc. Amino acid, for example, Shikou, neutral amino acid (for example, threonine, semi-deaminic acid, etc.); An acidic amino acid (for example, a hydroxyl group such as a hydroxyl acid, etc.), etc. Further, the amine hydrazine derivative may, for example, be sodium decyl sarcosinate (sodium lauryl sarcosinate), thiol glutamate or hydrazine. Base β-alanine, pyrrolidone carboxylic acid, etc. Organic amines, for example, 'monoethanol , diethanolamine, triethanolamine, oraloline, triisopropanolamine, 2·amino-2-mercapto-1,3-propanediol, 2-amino-2-mercapto-1-propanol, etc. ΡΗ a pH adjusting agent such as a buffer such as lactic acid-sodium lactate, citric acid-sodium citrate or sodium succinate-succinate, etc. Vitamins may, for example, be vitamins A, B, B2, b6, c, e and derivatives thereof. , pantoic acid (pant〇icacid) and its derivatives, biotin and the like. Examples of the antioxidant include tocopherols, dibutylhydroxyindole, butylated hydroxyanisaldehyde, gallic acid ester, and the like. The antioxidant auxiliary agent' may, for example, be phosphoric acid, citric acid 'ascorbic acid, enelic acid-acid, succinic acid, fumaric acid, cerebral palsy 28 201138838 (cephalin), hexamelate, phytic acid' Ethylenediaminetetraacetic acid and the like. Other adjustable components may, for example, be 'preservatives (for example, p-benzoic acid hydrazine vinegar, p-benzoic acid ethyl vinegar, p-benzoic acid butyl vinegar, phenoxyethanol, etc.); anti-inflammatory agents (for example) , glycyrrhizic acid (glyCyrrhizinic acid) derivative, glycyrrhetinic acid derivative, salicylic acid derivative, hinokitol, zinc oxide, allantoin, etc.; whitening agent (for example, Saxifrage extract , arbutin, tranexamic acid, L-ascorbic acid, magnesium L-ascorbyl phosphate, L-ascorbate, 4-methoxysalic acid, etc.; various extracts (for example, cork) , yellow lotus, purple root, peony, medicine, birch, sage, alfalfa, carrot, aloe, mallow, iris, grape, scorpion, loofah, lily, saffron, Chuanxiong, ginger, younger cut grass, onion, Garlic, pepper, dried tangerine peel, angelica 'seaweed, etc.; an activator (for example, royal jelly, photoreceptor, cholesterol derivative, etc.); blood circulation promoter (for example, benzyl nicotinate, nicotinic acid beta) - Butoxyethyl ester Capsaicin, zingerone, Cantharides tincture, ichthammol, tannic acid, α_borneol (bc) rne〇1), tocopherol to alkaline acid, muscle Alcoholic nicotinic acid (inosit〇l hexaniacinate), cyclandelate, cinnamon cinnarizine, benzyl. Sitting on the Lin, the sputum test, the verapamil, the cepharanthine, the r-oryzanol, etc.; the anti-lipid leakage agent (for example, sulfur, dithizone) (thianthol), etc.; fungicides (for example, benzoic acid and its salts, isopropyl decyl phenol, undecylenic acid and its salts, undecylenic acid monoethanol decylamine, chlorinated cetyl methacrylate Recorded, gasified cetyl. Bismuth rust, benzalkonium chloride, benzethoniuni 29 201138838 chloride, gasified alkyldiaminoethylglycine, chlorine Chlorhexidine, o-phenylphenol, glucosinolate, cresol, cloprone T, gas dioxin, gas, chlorphenesin, gas butanol, 5- 5-Chloro-2-methyl-4-isothiazolin-3-one, salicylic acid and its salts, 1,3-dimethylol -5,5-dimethylhydantoin, alkyl isoquinolinium bromide, domiphen bromide, sorbus Acids and their salts, Citronol, thyram, dehydroacetic acid and its salts, triclosan, trichlorocarbanilide, p-hydroxybenzoic acid, p-chlorobenzene, Cloflucarban, pyrogallol, benzodiazepine, hexachlorophene, 2-methyl-4-iso-sertidine, sitin-3-one, N,N'-methylene (Ν'-( 2- fluorenyl-2,5-dioxo-4-milylidene, sodium lauryl sarcosinate, resorcinol, etc.). The two-layer powder cosmetic of the present invention can be applied to Deodorant cosmetic such as deodorant lotion or ball bottle type deodorant ball bottle (roU-on). EXAMPLES Hereinafter, the present invention will be specifically described by way of examples. The present invention is not limited thereto. The amount of the preparation is not particularly limited, that is, the mass % relative to the total amount. The two-layer type powder cosmetic (deodorant lotion (the deodorant lotion) of the examples and the comparative examples using ethanol as a main base is manufactured by the method of the above-mentioned method. L〇ti〇n)), and review the redispersibility and anti-tarnishing effect of the antibacterial zeolite powder. The evaluation method, the use The effect of the present invention and the effect of the present invention is shown in "Table 1". 30 201138838 <Evaluation method> "Evaluation method for redispersibility (1)" The sample (two-layer powder cosmetic of the examples and the comparative examples) was filled in 50 mL. The glass tube was allowed to stand for 1 day (room temperature) to allow the powder to settle. The glass tube was shaken by hand (the number was counted as one), and the number of times the powder was judged to be uniformly redispersed was visually confirmed.

The number of oscillations was evaluated as ◎ for 5 times or less, 6 for 6 to 1 times, 〇 for 11 to 20 times, △ for 21 times to 30 times, and △ for more than 31 times, and evaluation of P for "redistribution". Method (2) A sample (the two-layer powder cosmetic of the examples and the comparative examples) was filled in a glass tube of 50 mL, and allowed to stand for one month (room temperature) to precipitate the powder. The glass tube was shaken by hand (the number was counted as one), and the number of times the powder was judged to be uniformly redispersed was visually confirmed. The number of oscillations was evaluated as ◎ for 5 times or less, 〇 for 6 to 10 times, 〇 Δ for 11 to 20 times, Δ for 21 times to 30 times, and X for 31 times or more. "Anti-tarnishing effect" A sample which is sufficiently oscillated to redisperse the powder (Example and Comparative Lipid Double Layer Powder Cosmetics) and artificial sweat (water up to 100% by weight, sodium chloride 0.8 wt ° / 〇, cesium acetate .5 wt%, disodium hydrogen phosphate 12 water salt 0.8 wt%) After mixing with 1:1, 30 / z L was weighed and applied to a white cotton cloth (white cloth attached to the JIS standard color fastness test). After the cloth coated with the sample was exposed to sunlight (10 minutes), it was judged to be x when it was visually confirmed to be discolored, and it was judged to be 〇 when it was not confirmed. 31 201138838 [I ί Comparative Example 4 79.3 〇CN d ο Ο d »η 〇ο XXX Example 6 78.45 Ο CN 〇ο in ο in ο IT) 0.35 ο ◎ ◎ 〇 Example 5 77.95 d CS oo ο in 0.35 ο 〇〇 △ 〇 Example 4 77.45 in O (N 〇»-Η m ο Ο 0.35 100 ◎ 〇〇 Example 3 77.95 c5 CN 〇m ο ο ΙΟ 0.35 Ο 〇〇 △ 〇 Example 2 78.65 oo ο ο Ο to 0.35 Ο ◎ ◎ 〇 Example 1 79.15 oo ο in ο ι〇l〇0.35 ο ◎ 〇〇Comparative Example 3 79.65 oo ο ο ο ΙΟ in 0.35 ο &lt; X 〇Comparative example: 2 79.5 oo ο ο ο u^» o ο XXX Comparative Example 1 oo ο ο ο o ο rH XXX General name (b) Ethanol (d) p-Phenolsulfonate hydroxypropylcellulose PEG-9 methyl ether dimercaptodecyloxyne (PEG-9methyletherdimethicone * 1 (a) MQ resin coated antibacterial zeolite powder *2 (8) Antibacterial zeolite powder *3 (e) Stearic acid matry glycol polypropylene glycol (f) purified water (c) Glycyrrhizin total redispersibility Evaluation (1) Redispersibility evaluation (2) Anti-tarnishing effect 201138838 [Table 2] General name Example 7 Example 8 Example 9 (b) Ethanol 74.15 74.15 73.65 (d) p-Phenolsulfonate 0.5 0.5 0.5 Hydroxypropyl Cellulose 0 0 0 PEG-9 Oxime Dimercaptodecyl Oxane (PEG -9methyletherdimethicone) *1 0 0 0 (a) MQ resin coated antibacterial zeolite powder *2 5 5 5 (a) Antibacterial zeolite powder *3 0 0 0 (e) Calcium stearate 0 0 0.5 Butanediol 5 5 5 polypropylene glycol 5 5 5 (f) purified water 10 10 10 (C) glutathione 0 0.175 0 (c) L-cysteine 0.35 0.175 0.35 Total 100 100 100 Redispersibility evaluation (1) ◎ ◎ ◎ Evaluation of redispersibility (2) 〇〇 ◎ Anti-tarnishing effect 〇〇〇*1 : Shin-Etsu Chemical Co., Ltd. KF_6016 *2 : MQ resin-coated antibacterial zeolite powder, which was subjected to the usual method using decamethylcyclopentanyl The oxane solvent was subjected to a coating treatment with an MQ resin having an M/Q molar ratio of 0.8. The coating amount was about 3% by mass.

*3 : SINANEN ZEOMIC cellamedic AJ 10N Co., Ltd. From the above results, it is clear that in the double-layer type powder cosmetic composition in which ethanol is used as the main base and the insoluble antibacterial zeolite powder is blended in the ethanol base, By blending glutathione as an anti-tarnishing agent for the antibacterial zeolite powder, and further adjusting the phenolsulfonic acid as a redispersibility enhancer for the antibacterial zeolite powder, the discoloration of the antibacterial zeolite powder when it adheres to clothes can be suppressed, and further By oscillating the container during use, the dispersibility of the antibacterial zeolite powder is significantly improved (Example 〇. In order to improve the usability, hydroxypropyl cellulose is formulated as a tackifier, and the redispersibility of the antibacterial zeolite powder is private. In a more difficult time, similarly, by blending glutathione as an anti-tarnishing agent for the antibacterial zeolite powder and adjusting the zinc phenolsulfonate as a redispersibility enhancer, sufficient good redispersibility can be imparted ( Examples 3 and 5). Further, for zinc phenolsulfonate, redispersibility of the antimicrobial zeolite powder can be enhanced when only glutathione is formulated. 'This effect cannot be exerted by the separate formulation (Comparative Examples 1 and 2). In addition to the combination of glutathione and zinc phenolsulfonate, it is also clear that the metal salt of two or more valences of fatty acids is hard. With calcium humate, the redispersibility of the antibacterial zeolite powder was further improved, and good redispersibility was exhibited after standing for a long period of time (Examples 2, 4, and 6). Further, excellent redispersibility was confirmed. In terms of effect, 'providing the viscosity of the system to increase the viscosity of the system, hydroxypropyl cellulose' can increase the excellent redispersibility (Example 6). Also, even if L-cysteine is used alone. Or a mixture of glutathione and an anti-tarnishing agent as an antibacterial zeolite powder, and a formulation which is excellent in redispersibility and disintegration of the antibacterial zeolite powder (Examples 7 and 8) can be obtained. Calcium citrate can further enhance the redispersibility of the antibacterial zeolite powder (Example 9). Further, 'the present invention' allows for the separate formulation of a divalent metal salt of a fatty acid (hard fat) which is generally used as a dispersing agent for powders. Calcium acid Further, the redispersibility of the sufficient antibacterial zeolite powder could not be obtained (Comparative Example 4). Examples of the present invention are exemplified below. 34 201138838 [Example 1 0: deodorant lotion] Formulation component mass % Ethanol 86.6 Refined water 7 Antibacterial zeolite powder 5 Glutathione 0.5 Pairs of zinc phenolsulfonate 0.35 Glycerol 5 Menthol 0.4 (Example 11: Deodorant ball bottle) Formulation component mass % Ethanol 88.5 Refined water 5 MQ resin coated antibacterial Zeolite powder 5 glutathione 0.4 p-Benzene acid zinc salt 0.5 Calcium stearate 0.5 Hydroxypropyl cellulose 0.1 Perfume amount (Example 12: Deodorant lotion) Formulation component mass % Ethanol 78 Refined water 5 MQ Resin-coated antibacterial zeolite powder 5 35 201138838 glutathione 0.4 p-phenol sulfonate 0.5 stearic acid 0.3 polypropylene glycol 10 N,N-dimercapto acrylamide-2-propenylamine-2-mercapto Propane 〇.5 sodium sulfonate copolymer flavor amount (Example 13: deodorant ball bottle) Formulation component mass % Ethanol 84.3 Refined water 5 MQ resin coated antibacterial zeolite powder 5 Glutathione 0.1 Pairs of zinc phenolsulfonate 0.1 Polypropylene glycol 5 Calcium stearate 0.5 (Example 14: Deodorant ball bottle) Formulation component mass % Ethanol 76.5 Refined water 10 MQ resin coated antibacterial zeolite powder 5 Glycopeptide 1.5 Pairs of zinc phenolsulfonate 1.5 Polypropylene glycol 5 36 201138838 m Stearic acid mother 0.5 (Example 15: Deodorant ball bottle) Formulation component mass % Ethanol 73.8 Refined water 15 MQ resin coated antibacterial zeolite powder 5 Bran Glutathione 0.5 p-Phenolsulfonate 0.7 Polypropylene glycol 5 (Example 16: Deodorant ball bottle) Formulation component mass % Ethanol 84.4 Purified water 5 MQ resin coated antibacterial zeolite powder 5 Glutathione 0.3 Phenolsulfonate Acid zinc salt 0.3 Polypropylene glycol 5 (Example 17: Deodorant ball bottle) Formulation component mass % Ethanol 79.05 Refined water 10 MQ resin coated antibacterial zeolite powder 5 Glutathione 0.35 Phenol sulfonate 0.5 37 201138838 « * Polypropylene glycol 5 calcium stearate 0.1 (Example 18: Deodorant ball bottle) Formulation component mass % Ethanol 74.15 Refined water 10 MQ resin coated antibacterial zeolite powder 5 Glutathione 0 .35 p-Phenolsulfonate 0.5 Polypropylene glycol 5 Calcium stearate 5 (Example 19: Deodorant ball bottle) Formulation component mass % Ethanol 50 Refined water 40 MQ resin coated antibacterial zeolite powder 5 Glutathione 1 Zinc phenolsulfonate 1 Polypropylene glycol 2.5 Calcium stearate 0.5 (Example 20: Deodorant ball bottle) Formulation component mass % Ethanol 87.7 Refined water 1 38 201138838 MQ resin coated antibacterial zeolite powder 5 Glutathione 0.3 Benzene acid zinc salt 0.5 Polypropylene glycol 5 Calcium stearate 0.5 (Example 21: Deodorant ball bottle) Formulation component mass % Ethanol 63.3 Refined water 25 MQ resin coated antibacterial zeolite powder 5 L-cysteine 0.7 p-phenol phthalate zinc salt 0.5 polypropylene glycol 5 calcium stearate 0.5 The present invention is a two-layer type powder cosmetic in which an antibacterial zeolite powder is dispersed in an ethanol base, and is mainly used as a deodorant cosmetic. The two-layer type powder cosmetic of the present invention is excellent in re-dispersibility of (3) antibacterial zeolite in use at the time of use, and can effectively prevent discoloration of the antibacterial bergue powder when it is attached to clothing. Therefore, as a blending antibacterial Buddha: The industrial value of the double-layered powder cosmetic is extremely high. 1 [Simple description of the diagram] None 39 201138838 [Description of main component symbols] None 40

Claims (1)

201138838 VII. Patent application scope: 1 · A double-layer powder cosmetic section characterized by: (a) an antibacterial zeolite powder and ethanol as a base - mass%, and further containing (c) glutathione and/or Or ^cysteine, and W) p-benzoic acid zinc salt '纟中' The (4) antibacterial zeolite powder is excellent in redispersibility and color discoloration* 2. Double-layer powder as in the scope of claim The cosmetic further contains (e) a metal salt of two or more valences of the fatty acid. 3. For example, apply for a two-layer powder cosmetic of the scope of the patent, and further contain (1) water. S 4. The double-layer powder cosmetic according to item 2 of the patent application, and further contains (f) water. The two-layer type powder cosmetic according to any one of the items (1), wherein the antibacterial zeolite of the component (a) is an MQ resin represented by the following average formula (1). Covered, (R3Si〇i/2)2 ♦ nSi02 (1) (wherein R is a monovalent hydrocarbon group, and η is a number from 1 to 5). 6. The double-layer type powder cosmetic of any one of the first to fourth aspects of the patent application, wherein the metal salt of the (e) fatty acid having a price of 2 or more is stearic acid. 7. The double-layer type powder cosmetic according to item 5 of the patent application, wherein (e) the metal salt of two or more valences of the fatty acid is stearic acid.