TW201026773A - Polyfarnesenes and compositions comprising thereof - Google Patents

Abstract

Provided herein are polyfarnesenes and compositions comprising the polyfarnesenes including farnesene homopolymers derived from a farnesene and farnesene interpolymers derived from a farnesene and at least a vinyl monomer and the processes of making and using the polyfarnesenes. The polyfarnesenes can be prepared by polymerizing the farnesene and an optional vinyl monomer in the presence of a catalyst. In some embodiments, the farnesene is prepared from a sugar by using a microorganism. Provided also herein are methods of making the polyfarnesenes disclosed herein, and methods of using the polyfarnesenes disclosed herein for various applications such as molded articles and adhesive compositions.

Description

201026773 VI. Description of the Invention: [Technical Field to Which the Invention Is Applicable] The present invention relates to P〇lyfamesenes and a composition of a polythene-diluted composition. In particular, this compound includes a method of derivatization of a molecular homopolymer, a farnesene molecule, and at least one ethylene-derived derivatized interpolymer. The present invention also provides a method for the preparation of a polymethene, and a method for the application of the polyfarnesene of the present invention, such as a molded article and an adhesive formulation. [Prior Art] Terpenes or isoprenoid compounds are organic molecules having a large molecular weight and a wide variety, which can be widely produced from polyhedral materials such as silk earning materials and such as Swallowtail butterfly. - Some isoprenoid compounds can also be converted from organic substances such as sugars by microorganisms such as those prepared by microorganisms. Since the olefinic or isoprenoid compounds are available from a variety of renewable lion caps, these compounds are ideal monomers for the preparation of affordable and reusable polymers. The olefin polymer derived from a terpene or isoprenoid compound is a very useful polymer material. For example, polyisoprene, polypimehydride and polymeric terpenes (polymerized oxime, 8 decadiene) can be used in the production of paper coatings, adhesives, rubber compounds and other industrial products. Most of the existing terpene polymers are typically derived from c 5 and c i quinones such as isoprene, #浠, myrcene, 3-#ene, basilene and thinning. These dilute monomers may be polymerized or copolymerized with other monomers to form the corresponding terpene homopolymer or copolymer. However, polymers containing aene or isoprene having at least 15 carbon atoms or 201026773. Copolymers are rare or non-existent. Due to the length of their long bonds, i 2 compounds such as ruthenium (acacia), farnesol (farnesol), flowering two, 'Zhu=Feng shouting, law grass woman, big root geranene and lan Xiangtan can produce polymers or copolymers with unique physical and biological properties. A. People need a more environmentally friendly and/or more recyclable polymer, such as a polymer that can be obtained from a raw material to obtain an isoprene compound. In addition, there is a need for a new polymer with unique physical, chemical and biological properties. , ❿ , Drilling agent is a substance (such as a drill or substrate) that bonds materials together by surface attachment. Pressure sensitive adhesives (PSAs) usually require pressure to produce a paste with the dead body so that the material can be gambling. The pressure sensitive adhesive can be a permanent or removable dry glue. Removable pressure sensitive adhesives have been widely used for refillable stickers such as P〇st-lt®. Pressure sensitive adhesives are generally based on polymers, solubilizers and petroleum materials. Some common pressure sensitive adhesives are based on, for example, natural rubber, synthetic rubbers (such as benzene rubber and styrene-isoprene-styrene copolymer), polypropylene, polymethacrylate, and poly-α- a polymer such as an olefin. The agent is solid at % temperature and can be heated to combine the adherent or substrate with the material after the cooling spear is cured. Sometimes, in use, if the substrate is not heat-resistant, the bonded substrate can be removed by remelting the hot melt adhesive. Hot rubber-like paper products, packaging materials, plywood strips, linings, vehicles, plastics _ belts, labels and various - secondary goods such as disposable diapers, medical, feminine sanitary napkins and • surgical orders. Generally, these hot melt adhesives are based on a polymer, tackifier and wax. Some common pressure sensitive adhesives are based on, for example, natural rubber, synthetic rubbers (such as styrene butadiene rubber and styrene-isoprene-stupyl ethylene copolymer), polypropylene, polydecyl acrylate, and poly 201026773 olefins. polymer. The ideal property of hot melt adhesives is that no liquid carrier is required, eliminating the costly and solvent hazards associated with solvent removal. Polymers derived from terpene or isoprenoid compounds are useful polymeric materials. For example, polyisoprene, polypimehydride and polymeric terpenes (polymerized 2,8-decadiene) can be used to produce paper coatings, rubber compounds and other industrial products. However, an adhesive composition consisting of a terpene compound or an isoprene-derived polymer is rare, and a polymer produced from an isoprene compound having at least 15 carbon atoms is more rare. Although we have a variety of hot melts and waste sensitive adhesives available, there is still a need for new adhesive compositions with unique adhesive properties to meet new requirements. Moreover, there is a need for polymers that are more or more recyclable, such as polymers produced from isoprene compounds from natural sources. SUMMARY OF THE INVENTION The various aspects disclosed herein can satisfy the above needs. In one aspect, the invention is a polyfarnesene combination X composition consisting of one or more polymer molecules having the following structure (X,): (X,), wherein η is from 1 to An integer of about ι〇〇, 〇00; m is an integer from 〇 to about 1〇〇〇〇〇; X has one or more structures included in the following formula (I)-(vnr): R1 (Γ) ,4 (II,), 吣(ΙΙΓ), ί (IV,), 201026773

l· H3C CH,

R3 ?3 ch3 enters into (νι,), > (vn,) and (V,), R4 i (νπτ); and γ has the structure of the formula (IX,): R5 R8 (DC,), where R1 Structure with formula (XI): ❿

Where R2 has the structure of formula (xn)

Where R3 has the structure of (式)

Ρα); and (XII), (XIII); and wherein R4 has the formula (ΧΙΥ):

(XIV), wherein 'R5, R6, R7 and R8 are each independently hydrogen, alkyl, cycloalkyl, aryl, cycloalkenyl, heterocyclyl, alkoxy, aryloxy, carboxy, alkoxycarbonyl, Amidoxime, amide, dimethylamine, decyloxy, nitrile or phthalocyanine; the tenth of which is 'when m is 0' (I,) has the highest content of compounds The molecular percentage of about 8 〇 wt.% of the total weight of the condensed method and the ratio of i or greater than i and χ & γ is approximately: 201026773 4 to about 100:1.

In some embodiments, the compound having the formula (ΙΓ) accounts for about 5 wt.0 / 〇 to 99 wt.% of the total weight of the polyfarnesene. In some embodiments, the compound having the formula (ΠΓ) accounts for about 70% by weight of the total weight of the polymethod. In certain embodiments, at least a portion of the double bonds of one or more compounds having the formula (Γ)_(ΠΓ), (V')-(VH'), (χΐ)-(χιγ), and stereoisomers are hydrogenation. In some implementations, 〇1 of the formula (\,) is 0 and X has one or more structures of the formula (ι')-(ιν'). In some implementations, 111 in the formula (also) is 〇 and : ^ has one or more structures such as the formula (V') - (VIir). In certain embodiments, the compounds of formula (V,) and (vr) comprise from about 1 wt. 〇 / 〇 to 99 wt 〇 / 〇 of the total weight of the polyfarnesene. In certain embodiments, the compound having the formula (vir) comprises from about iwt.% to 99 wt.%, based on the total weight of the polyfarnesene. In some implementations, 111 in the formula (also ') is about 1-1 〇〇, 〇〇〇, and 115, 尺 6, 117, and R are both Η. In certain embodiments, in the formula (also,) m is about 11 Å, (8) 〇, and R5 is aryl, and R6, R7 and R8 are both H. In certain embodiments, the aryl group is a phenyl group. In some embodiments, m is about 1-100,000 in formula (X,), and the polyfarnesene is any farnesene copolymer. In certain embodiments, m in formula 0,) is about 0.001, and the polyfarnesene is a block farnesene copolymer. In some embodiments, the block farnesene copolymer consists of one block containing X and two blocks containing gamma, wherein the block containing ruthenium is located between two blocks containing ruthenium. In certain embodiments, the polyfarnesenes disclosed in the present invention have a Mw molecular weight greater than about 60, 〇〇〇Dalton. In some implementations, the polymethods disclosed in the present invention are bound.

The Tg is less than about -60 °C. In some implementations, the sum of the values of 111 and 11 in the formula (χ,) is greater than * 300 〇, 8 201026773. In another aspect, the present invention provides a microstructure in which the catalyst is present in the presence of a catalyst. The ratio of the content to the 罝 is at most 80% by weight. The invention of the polyhedron 2 provides that the proportion of the catalyst in the presence of the catalyst is the most obsolete, and the ratio of the microstructure to the total weight of the polyfarnesene is the highest. 1 wt % to 99 wt %. The present invention is based on the presence of a catalyst in the presence of (4) scales. ❹ / H is at least partially double-hydrogenated in the granules of the lining in the seasonal supplement. In certain embodiments, the process used in the polymerization step disclosed in the present invention is copolymerized with a vinyl monomer to form a diene copolymer. In some implementations, the 'ethylene monomer is a phenyl group. In some embodiments, it is dilute by microbial preparation. In the step-by-step implementation, the method was prepared by using a single sugar. In some embodiments, the hydrogenation age for the addition of a Newcasting step is hydrogen in a hydrocracking agent. In certain embodiments, the hydrogenation catalyst is a 10% carbon/carbon catalyst. In another aspect, the invention provides a method of making a polyfarnesene comprising copolymerizing a process and at least one vinyl monomer in the presence of a catalyst, said farnesene The molar percentage of the monomer is about i: 4 to about excitation: i. In another aspect, the invention provides a method of making a polyfarnesene comprising: causing microbial monosaccharide formation scales; and, in the case of miscellaneous, diluting and at least one vinyl monomer Copolymerization. In hiding the towel, the molar percentage of the law and the ethylene monomer is about 1: 4 to 1 : 1:. In a specific implementation, at least one vinyl monomer does not contain (d). In other embodiments of 201026773, at least one ethylene monomer is ethylene, 0:-olefin, substituted or unsubstituted vinylate, vinyl ether, acrylonitrile, acrylate, methacrylate, propylene. Or mercapto acrylamide or a combination thereof. In a further embodiment, at least one of the vinyl monomers is a phenyl group. In certain embodiments, the catalyst used in the polymerization or copolymerization step is a Ziegler-Natta catalyst, a Kaminsky catalyst, a metallocene catalyst, an organolithium reagent or The combination. In other implementations, the catalyst is an organic clock reagent. In a further implementation, the catalyst may further comprise indole, 2-bis(diguanylamino)ethane. In a further implementation, the organolithium reagent is n-butyllithium or sec-butyllithium. In another aspect, the invention discloses a method of preparing a polyfarnesene as referred to herein. In another aspect, the invention discloses a multi-compound composition comprising a polydatin and at least one additive as referred to herein. In a specific implementation, the additive is a filler, a graft initiator, a tackifier, a slip agent, an anti-blocking agent, a plasticizer, an antioxidant, a foaming agent, a foaming agent activator, a UV stabilizer, Acid scavenger 'Coloring © Back J or pigment coagent, lubricant, antifogging agent, glidant, processing aid, extrusion aid, coupling agent, crosslinking agent, stability control agent, nucleating agent, A surfactant, a flame retardant, an antistatic agent, or a combination thereof. In a specific implementation, the additive is a filler or a crosslinking agent. In a specific implementation, the polymer composition provided by the present invention may further comprise a second polymer. In other embodiments, the ratio of the polyfarnesene to the second compound is in the range of 1: " 99 to 99.1. In a further embodiment, the second polymer is a polyolefin, polyurethane, 10 201026773 polyester, polyamide, styrene polymer, phenolic resin, polyacrylate, polydecyl acrylate or a combination thereof. In another aspect, the invention discloses an article comprised of a polyfarnesene or polymer composition as referred to in the present invention. In certain implementations, the article is a molded article, film, sheet or foam. In other implementations, the article is a molded article selected from the group consisting of toys, clamps, soft handles, cushion strips, flooring, automotive mats, wheels, casters, furniture and electrical pads, labels, seals, gaskets, and dynamics. Seals, car doors, cushions, grille components, rocking plates, hoses, linings, office supplies, seals, gaskets, diaphragms, tubes, covers, stoppers, punches, delivery systems, kitchen appliances, shoes, Shoe bag and sole. In another aspect, the adhesive composition of the present invention comprises a polyfarnesene and a tackifier, and wherein the polyfarnesene has the formula (χ,) disclosed herein, wherein 11 is from 1 to about 1〇〇, an integer of 〇〇〇; m is an integer from 0 to about 100 000; X is derived from the law ^ 'Y derived from ethylene monomer' when the condition is m is greater than or equal to 1, the molar of X and ❹Y The percentage is between 1: 4 and 100: 1. In certain embodiments, X in formula (X,) has one or more of the structures of formula (r)-(vm,) or a stereoisomer thereof as disclosed herein. In still other embodiments, gamma in formula (X,) has the structure of the formula (drinking) or its stereoisomers as disclosed herein. In a further embodiment, the tackifier is present in an amount from about 5% to about 70% by weight based on the total weight of the ingredients of the composition. • In a specific implementation, the adhesives disclosed herein include additives selected from the group consisting of plasticizers, oils, waxes, antioxidants, UV stabilizers, colorants and pigments, fillers, glidants, and couplings. Agents, crosslinkers, surfactants, solvents, and combinations thereof. ~ In certain embodiments, the adhesive compositions disclosed herein may also comprise a second 201026773 polymer. In other implementations, the second polymer is natural rubber, synthetic rubber, polyacrylate, polydecyl acrylate, polyfluorene-olefin, ethylene homopolymer, ethylene copolymer, styrene block copolymer or Their combination.

In another aspect, the invention discloses an adhesive composition comprising a polyfarnesene and a tackifier, wherein the polyfarnesene is prepared according to the process disclosed herein. In a specific implementation towel, the farnesene is a magnetic terpene, a polymer, or a combination thereof. In other shots, the polyfarnesene towel has a maximum content of about 80% by weight of the total weight of the polyfarnes. In a further implementation, a vinyl monomer is present and the polythene is a farnesene. In some embodiments, the composition is a combination of a composition or a pressure sensitive adhesive composition.

Another aspect is the article of the invention disclosed in the invention, wherein all or one of the substrate coatings is a hairpin disclosure composition. In specific implementations, ^ is paper products, package riding, plywood strips, kitchen countertops, vehicles, labels, disposable diapers, medical sputum, feminine sanitary napkins, surgical drapes, tapes, boxes, paper, trays

Medical equipment "band. In other implementations, the product is worn, box-like, @therapy equipment or bandages. $ π 1 Force-Wan, the present invention discloses a method for attaching a composition to another one. In the middle, the first chelating agent is the same as the second one. In another embodiment, the <5> agent is different from the first. In further implementation, each agent's wrap, wood, paper, turn, rubber, glass, stone: ::: stone, stone, research, pottery, brick, research, cement,: material, cloth, lin, Silk red _ combination.钱进-步步施中 ^ 12 201026773 • The shape of the second and second adhesives are each a sheet, a strip, a tape, a label, a sign, a v net, a disc, a sheet, a film or any model. Another aspect disclosed herein is an adhesive composition comprising a rubber and a solubilizer wherein the tackifier comprises the polyfarnesene disclosed herein. In some embodiments, the content of the poly] ruthenium is from about 5 wt.0 / 〇 to 7 〇 . Wt% of the total weight of the adhesive composition. In other embodiments, the polyfarnesene has a ring and ball softening point greater than or equal to 8 Torr, as determined by ASTM 28-67. In a further implementation, the rubber has a Tg of less than 2 〇. C° [Embodiment] General Definition "Polymer" refers to a polymeric compound formed by polymerization of the same or different types of monomers. The polymer 'is a generic term including "homopolymer,", "copolymer", "trimer," and "interpolymer." "Reciprocal (10)" refers to a polymer formed by polymerization of at least a monomer. Interpolymers are "copolymers," which generally refer to polymers obtained by polymerizing two different monomers. And the "trimer," (--usually refers to the polymer of three kinds of polymers that are not polymerized). "Interpolymers" also include polymers formed by the polymerization of four or more types of monomers. "Organic" refers to any type of genus that is not replaced by any mechanical type, and one of the slave atoms has a free valence, such as CH3CH2-, ClCHj-, CH3C(=〇)-, 4-pyridinium. alkyl. "Hydrocarbyl group, which is any 13 201026773 monovalent group (such as ethyl), cycloalkyl (such as cyclohexyl) and aryl (such as phenyl) formed by removing one hydrogen atom from a hydrocarbon molecule. · "Heterocyclyl," refers to any monovalent group formed by the removal of a hydrogen atom from an atom in the ring of a heterocyclic ring. "Alkyl" or "alkyl group" refers to a monovalent group of the formula CnH2n+1 derived from a saturated, unbranched or branched aliphatic hydrocarbon obtained by withdrawing a hydrogen atom, where n., - an integer Or an integer between 1 and 2 or an integer between 1 and 8. For example, green may include but not limited to the following groups: (C^) a group such as an anthracene group, an ethyl group, a propyl group, an isopropyl group, or 2 -mercapto-1-propyl ester, 2-methyl-dipropyl, 2-fluorenyl butyl, 3-methyl butyl hydrazino 2 fluorenyl-3-butanyl, 2, pentyl, ' Methyl-1_pentyl, 2-methyl-2-pentyl, 3-methyl-2-pentyl, 4-methyl-2-pentyl, 2,2-didecylbutyl, 3, 3 dimethylbutyl butyl, diethyl butyl butyl, butyl vinegar, isobutyl, tert-butyl, pentyl, isopentyl, neopentyl, hexyl, heptyl, octyl The longer alkyl group includes a fluorenyl group and a fluorenyl group. One group may be substituted or unsubstituted with one or more suitable substituents. Further, the group may be a branch group or a linear group. a group. In certain embodiments, the filaments comprise at least 2, 3, 4, 5, 6, 7, or 8 carbon atoms. 'or 'cyclic group, refers to a unit price derived from the removal of a hydrogen atom from a non-aromatic, mono- or polycyclic ring group containing a hydrocarbon in a cycloalkane molecule. Group. For example, a cycloalkyl group can include, but is not limited to, the following groups: (ere?) cycloalkyl groups such as % propyl, butyl butyl, cyclopentyl, cyclohexyl and cycloheptyl, saturated cycloalkenyl and bis % alkenyl and (QC: 7) cyclopropyl, cyclobutane, cyclopentenyl, cyclo 'thinyl and cycloheptenyl, unsaturated J- and bis-cycloalkenyl. A cyclic group can be substituted or unsubstituted by one or more suitable substituents. Further, the cycloalkyl group may be monocyclic or polycyclic. In certain embodiments, the cycloalkyl group contains at least 5, 6, 7, 8, 9, 10 or 10 carbon atoms. "Aryl H group" refers to an organic group formed by the removal of a hydrogen atom from a monocyclic or polycyclic aromatic hydrocarbon. There are many examples of aryl groups, including benzene, naphthalene, • > or an acetylene group, six diamine groups, phenanthrenyl groups, anthracenyl groups, coronenyl groups. And diphenylacetylene phenyl. One aryl group φ may be substituted or unsubstituted with one or more suitable substituents. Further, the aryl group may be a monocyclic group or a polycyclic group. In certain embodiments, the aryl group contains at least 6, 7, 8, 9, or 10 carbon atoms. ~ -ϊ 'Isoprene" and "Isoformyl dilute compound" are used interchangeably herein to refer to a compound derived from isopentenyl diphosphate. "Substit" 'Secret Description - In the case of a partial molecular composition of a compound, it is meant that at least one of the hydrogen atoms in the partial molecular composition of the compound or compound is replaced by a second molecular composition. Whereas the second molecular composition herein can be any one that does not adversely affect the ideal of the compound. Substituted, the substituents of the radical include the typical compounds mentioned in the present invention and the compounds mentioned in the embodiments, as well as _ s, alkyl; heteroalkyl, alkenyl, alkynyl, aryl, heterocyclic Base, subtraction, record base, silk, secret, thiol group, two = imine oxime, cyano group, guanamine group, hept salt, hydrogen, silk, thio group, hetero group, reductive amine , fluorenyl, ethoxylated, oxy-hydrogen, carbonyl, _ sulphonyl (such as tris-methyl), carbocyclic, monocyclic or fused or secret "salmon (such as lying, butyl hexyl) Cyclopentyl) or heterocycloalkyl, monocyclic or fused or non-fused polycyclic aromatic hydrocarbons; length 15 201026773 L-, foxazin, morphinyl or pyridazinyl); carbocyclic or heterocyclic, monocyclic or fusion Or non-integrated multi-ring filaments (such as benzene, naphthalene, trans, ah, feed, 嗟 κ κ "oxox, isoxazole, azo, triazole, tetrazole, pyrazole, pyridine, quinoline, isoquine Orion (isoquinolinyl), acridine, pyridinium, pyridazine, pyrimidine, imidazole, benzothiophenyl or furan), amine (primary, secondary or tertiary), ortho-low alkyl, ortho-aryl-aryl , Fang-C〇2CH3 : -COKH, ; ; -Κ„2: ,〇2Ν:2 ;.^: ;CF3;. _OCF3, -NH(alkyl); -N(alkyl)2; -NH(aryl);_N(alkyl X-aryl 'Base'; -N(aryl)2; -CHO; -CO(hospital);_CO(aryl);_c〇2(alkyl)❹ and ~C〇2(aryl);卩 and these molecules The composition can also be selectively substituted by a fusion ring structure or bridge such as _00120. These substitutional filaments are further substituted. The chemical groups disclosed in the present invention can be substituted unless otherwise stated. The organic clock reagent '' refers to an organic clock compound that directly forms a chemical bond between a broken atom and a clock atom. Examples of organic axes are not limited to these examples, including vinyl clocks, aromatic lithium (such as stupid lithium), and alkyl lithium ( For example, n-butyllithium, sec-butyllithium, tert-butyllithium, methyl quinone, isopropyl (iv) other lysing agents having L20 carbon porridge) - a composition towel "substantially no" - the composition of the composition contains * ❹ in the total amount of the composition is less than 2 〇 wt 〇 / 〇, less than 1 〇 wt%, less than 5

Wt%, less than 3%, less than 1 wt.%, less than 0.5 wt.°/〇, less than 0.1 wt%, less than 0.01 wt.%. A polymer is "substantially linear," meaning that the ratio of the *, the star structure, or other or irregular structure composition contained in the polymer to the polymer foam is less than 2 G wt.%, Less than 1G wt %, less than 5 wt %, less than 3 wt %, less than, 1 wt.%, less than 〇·5 wt.〇/0, less than 〇]%, less than 〇〇1 wt % 2010.16 201026773 A polymer is "substantially branched," meaning that the polymer contains linear, star-shaped structures or other regular or irregular structural compositions that account for less than the total amount of the polymer. 20 wt.%, less than 1 〇 wt.%, less than 5 wt.%, less than 3 wt.%, less than 1 wt.%, less than 0.5 wt.%, less than 〇1 wt%, less than 〇〇1 wt %. A polymer is "substantially star-shaped", meaning that the polymer contains a branch, a linear structure or other regular or irregular structural composition in a proportion of less than 20 wt.% of the total amount of the polymer, Less than l〇wt 〇/〇, less than 5 machine%, less than 3 wt 〇/., less than ❿ 1 wt.%, less than 0.5 wt·%, less than 01 plus %, less than 〇〇1 wt In the following, the number of dews mentioned is irrespective of the expression "approximately, or "approximate," and may be an approximation. The value may be one percent, one percent, two percent, and sometimes five percent. The change of the child or 2〇. The range of the unrecorded value is in the disclosed low limit rL, or the high limit # inside the 'the _ seam side will be _ sure. Especially the lower ship _ value will clear the road ' RR +k*(R -R ), where k is the variable between i %t]嶋 directly ^1%, gPk^1%' 2%' 4〇/〇, 5〇/〇,..50 0/ 0, 5Γ〇^ refers to 52%, ... 95%, 96%, 97%, genus, 99% or qing%. Moreover, any range of values defined by the above two Μ values will also be Disclosure. The age of the morning of the morning is a slave, and may also contain his own, as disclosed in the present invention. In the case of human cutting, the composition disclosed in the present invention contains: a thickening agent: a tackifier. In the implementation of the step-by-step, some of the polymers, the granules, or the dilute homopolymer thereof are derived from at least one The method is like 'farnesene homopolymer' and the method is combined. In a specific implementation, the polymorphs or their group of terpene interpolymers, and the farnesene interpolymerization 17 201026773 αα has the original In the implementation of the method, the farnesene interpolymer is derived from styrene and at least one method is further developed. In practice, the interferon is a random, sputum or alternation in a more advanced implementation, and the interpolymer is a 2-, 3-, or other multi-block interpolymer. In some embodiments, the preparation of the "bake-baked homopolymer" is carried out in the presence of a catalyst suitable for polymerization such as ethylene, styrene or isoprene, and (iv)

Rare, combined and completed. In other embodiments, the methacrylate contains one or more constituent units having the formula (1), (9), (10), (Ιγ) or a stereoisomer thereof or a combination thereof:

Wherein R1 has the structure of formula (XI):

(XI); and wherein R2 has the structure of formula (XII):

Meals, where m, n, l and k are each an integer, the range is! Up to about 5, 〇〇〇1 to about 10,000, 1 to about 50,000, 1 to about 100,0004 to about 2, 〇〇〇, 1 to about 500,000, 2 to about _〇, 〇〇〇, 2 Up to about 5 〇, _, 2 to about 18 201026773 100,000, 2 to about 200,000 or 2 to about 5 〇〇, _. In some implementations, m, n, l, and k are each an integer from 丨 to about 1 分别, respectively. In other implementations, m, n, 1 and k are each an integer from 2 to ι〇〇, 〇〇〇. In a particular embodiment, the <RTI ID=0.0>>""""""""" In other embodiments, the farnesene homotide contains at least one unit component of formula (9) wherein the value of n is greater than double, 5 or 1000. In other embodiments, the farnesene homopolymer comprises at least one unit unit of (#), wherein the value of 1 is greater than 300, 500 or 1 Torr. In other embodiments, the dilute homopolymer comprises at least one unit component of formula (IV), wherein the value of k is greater than 3 Å, 500 or 1 Å. In some embodiments, the farnesene is homopolymerized. The composition contains at least one unit of formula 1 and at least one formula (Π), wherein the sum of the values of 111 and 11 is greater than 3〇〇, 5〇〇 or (1)(8). In certain embodiments, the farnesene homopolymer comprises at least one unit component of formula (7) and at least one formula (ΙΠ) wherein the sum of the values of m and 1 is greater than 300, 500 or 1000. In some espresso applications, the farnesene homopolymer contains at least one unit component of formula (H) and at least one formula (melon) wherein the sum of the values of η and 1 is greater than 3 〇〇, 5 〇〇 or 1 Hey. In a further application, the farnesene homopolymer comprises at least one unit of formula (I), at least one formula (II) and to a formula (III), wherein the values of m, η and 丨 are And greater than 3 〇〇, 5 (8) or 1000. In still further embodiments, the virgin homopolymer comprises at least one formula (I), at least one formula (Π), at least one formula (III), and at least one formula (IV). Unit composition, • where the sum of the values of m, η, 1 and k is greater than 300, 500 or 1000. In still further embodiments, one or more of the constituents of the farnesene homopolymer disclosed herein have the formula (I), (II), (ΠΙ) or (IV) arranged in any order. 19 201026773 In a specific implementation, the preparation of the farnesene homopolymer is carried out by polymerization of farnesene in the presence of a catalyst suitable for the polymerization of olefins. In other embodiments, the farnesene homopolymer comprises one or more constituent units having the formula (v), (VI), (νπ), (VIII) or a stereoisomer thereof or a combination thereof:

H3c ^ ”m , 1", R k (VIII) ° (V),

(VII) or

Where R3 has the structure of (式):

H3C

(xm); and

Where R4 has the structure of formula (XIV):

Wherein m, n, l and k are each an integer, respectively, ranging from J to about 5, 〇〇〇, J to about 10,000, 1 to about 50, ·, ! Up to about 1〇〇〇〇〇1 to about 2〇〇〇〇〇, 1 to about 50_0, 2 to about 10, _, 2 to about 5〇, _, 2 to about 100,000, 2 to about 200,000 or 2 to About 5 years old, hehe. In other implementations, m, n, 1 and k are each an integer of 2 to 1 〇〇, 〇〇〇. In a particular embodiment, the farnesene homopolymer comprises at least one unit component of formula (V) wherein the value of m is greater than 300, 5 or 1 Torr. In other embodiments, the farnesene homopolymer 3 has at least one unit component of formula (VI) wherein the value of n is greater than 3〇〇, 20 201026773 500 or 1000. In other embodiments, the farnesene homopolymer comprises at least one unit component of formula (νπ), wherein the value of 1 is greater than 300, 500 or 1 Torr. In other embodiments, the farnesene homopolymer comprises at least one unit component of formula (VIII) wherein the value of k is greater than 300, 500 or 1000. In some embodiments, the 'dough homopolymer contains at least one unit of formula (V) and at least one unit of formula (VI), wherein the sum of the values of melon and !! is greater than 3 〇〇, 5 〇〇 or 1 〇. Hey. In certain embodiments, the 'farnesene homopolymer contains at least one unit component of formula (V) and at least one formula (VII), wherein the sum of the values of m and 1 is greater than 3, 500 or 1 〇〇〇. . In other embodiments, the farnesene homopolymer comprises at least one unit (V!) and at least one unit component of formula Y' wherein the sum of the values of η and 1 is greater than 3 〇〇, 5 〇〇 or 1 〇〇. (^ In a still further implementation, the farnesene homopolymer comprises at least one formula (7), at least one formula yj) and at least one unit component of formula (VII) wherein the sum of the values of m, ]1 and 1 is greater than 300 , 500 or 1〇〇〇. In still further implementations, the farnesene homopolymer comprises at least one unit of formula (V), at least one formula (VI), at least one formula (YJJ), and at least one formula, wherein m, η, 1 is The sum of the values of k is greater than 3〇〇, 5〇〇 or 1〇〇〇. In still further embodiments, one or more of the constituent units of the farnesene homopolymer disclosed herein have the formula (V), (VI), (VII) or (vm) arranged in any order. In certain embodiments, the farnesene homopolymer is prepared by the polymerization of alpha-farnesene and streptardene in the presence of a catalyst suitable for the polymerization of olefins. In other embodiments, the farnesene homopolymer comprises one or more constituent units having the formulae (I), (II), (hi), (IV), (V), (vi) disclosed herein. ), (νιι) or (vm) or a stereoisomer thereof or a combination thereof. In still further implementations, one or more of the constituent units of the farnesene homopolymer disclosed herein have the formula (1), (11), 21 201026773 (10), αν), (v) of the present invention. , (10), (10) or (10)), and arranged in any order. In some implementations, the farnesene homopolymer contains two or more constituent units having two non-forms, which are respectively assigned to the formula (I), (π), _, • ( V)' (ν^νπκνπ ΐΜΜ ΐΜΜ 或 or its combination of smoke. It is expected that the formula of these methods can be expressed as: AXBy, where X and y are each at least and each of a and B Having the formula (Ι), (ιι), (iv) (four), (V), (VD, (VII) or (Vm), and A and B are different. In a further implementation, X and y are each greater than 1, for example 2,3,4,5,6,7,8,9,1〇, 20 25 30'35'4〇° , Α^β is a linear way to connect H or the branch or star on the real f In other implementations, A and B are randomly distributed along the Faraday polymer homopolymer chain. In other embodiments, A and B form a segmental structure of the F. , such as AA--A-BB...b. In other implementations, A and b can be distributed along the law to the homopolymer chain parental distribution 'from Xiaocheng-a dimorphic homopolymer with variable structure' Such as AB, ABA, ABAB, ABABA or class Structure ❹ In some implementations, the genus homopolymer contains three or more constituent units, and they have a different formula 'These formulas are the formulas 1, (9), (III), αν disclosed herein, respectively. , (V), (VI), (VII), (νπι) or a stereoisomer thereof or a combination thereof. In other embodiments, the formula of three farnesene homopolymers can be expressed as: AxByCz, Let X, y, and z each be at least i, and wherein A, B, and c each have a ground (11), an elevation (eight), (10), (10), or (10)), and the formulas of A, B, and C are different. In a further implementation, Υ and Ζ are each greater than 1, for example 2, 3, 4, 5, 6, 7, 8, 9, 1 〇, ^ 20, 25, 30, 35, 40 or greater. In some implementations, a, B, c with real 22 201026773 The linear village is connected in the beginning, _ on the reverse. In other implementations _, A, B, d this branch or star way phase / / D 耆 methodene homopolymerization The chain of things is randomly divided into #, he is familiar with, A, B, and c form a sum in three "segments." A farnesene homopolymer thereof, such as mB_cc-c. In other real K-type structures c can be along the law-polymer chain (four), ❹ specific implementation, the poly-method is a woman interpolymer. In the other, the second preparation is carried out by polymerization of at least one farnesene with a vinyl monomer. In an implementation of the further steps, the disclosed method comprises: (8) one or more of her units, which have the formula 1 (IV) disclosed by Lin Wen; (b) one or more constituent units They have the formula (ιχ) ·· R5 1

10 (IX) where 'P is an integer' ranging from 1 to about 5,000, 1 to about 1 〇, ! About 50,000, 1 to about 100,000, 1 to about 200,000, 1 to about 500, 0 (2 to about i 〇, 〇〇〇, 2 to about 5 〇〇〇〇 2 to about ι 〇〇〇〇〇, 2 to Approximately 2 〇〇 (or 2 to about 5 〇〇, 〇〇〇. and 115, 116, 117 and ; ^ are each hydrogen, an organic group @ or a functional group in some implementations, R5, R6, R7 R8 is not a monovalent hydrogen group containing 4 carbon atoms. In certain embodiments, R5, R6, R7 and R8 are not alkyl groups having 4-8 carbon atoms. 23 201026773 In certain implementations, The exposed farnesene interpolymer contains: (8) - one domain unit, which has the formula (v), (νι), (iv) ' and (vm); * (b) - or A plurality of constituent units having the formula (D^). In other implementations, the disclosed farnesene interpolymer comprises: (8) one or more constituent units having the formula 1, (9) disclosed herein, (), (IV), (V), (VI), (νπ), and (VIII); (b) one or more constituent units having the formula (dq. In some implementations, disclosed herein Farnesene interpolymer is a kind In other implementations, this (4) is a random interpolymer, in which the vinyl monomer and farnesene composition can be randomly and randomly distributed. The implementation of the towel, the farnesene interpolymer disclosed in the present invention is a random interpolymer, wherein the ethylene monomer and the farnesene composition can be randomly distributed, and the farnesene composition has Formulas (I), (II), (III), (4), (V), (VI), (VII), (νπι) and (χι) are distributed in a random, alternating or block manner.

In certain embodiments, the farnesene interpolymers disclosed herein are an alternate interpolymer Q. In other embodiments, the farnesene interpolymer of the present invention is an alternating interpolymer. The vinyl monomer and the farnesene composition may be alternately distributed. In still further embodiments, the farnesene interpolymer disclosed in the present invention is an alternating interpolymer, wherein the vinyl monomer and the dilute composition are alternately distributed, and the dilute composition has Formulas (I), (II), (III), (IV), (V), (10), (VII), _) and (χι) are distributed in a manner that is irregular, alternating or block. · In a specific practice, the 'farnesene interpolymer contains one or more quantities of two components. The composition of the first block component has the formula 1, (π), (in), (IV) or a combination thereof; the constituent unit of the second block component has the formula (!X). In a further implementation, the farnesene interpolymer contains one or more amounts of two block components, the constituent units of the first block component having the formula (V), (VI), (VII), (YJH) Or a combination thereof; the constituent unit of the second block component has the formula (!χ). In still further embodiments, there is a first block and a second block, wherein the first block is located between the second blocks. In still further embodiments, each of the second blocks contains a unit composition conjugate derived from styrene. In certain embodiments, the farnesene block interpolymer is polystyrene-polyfarnesene-diblock polyfarnesene, polystyrene-polyfarnesene-3 block polyfarnesene or The combination. In certain embodiments, the formula of the farnesene interpolymer can be expressed as: PxQy, wherein χ and y are each at least 1, and wherein ρ has the formula (ix), q has the formula (I), (II), (m), (IV), (V), (VI), (VII) or (νιπ). In a further implementation, χ and y are each greater than, for example, 2, 3, 4, 5, 6, 7, 8, 9, 10, 15, 20, 25, 30, 35, 40 or greater. In some implementations, the Ps-Shaw Qs μ is connected in a substantially linear manner in a manner opposite to a substantially branched or star-shaped manner. In other implementations, & and Qs are randomly distributed along the farnesene interpolymer chain. In other implementations, ps and Qs form a farnesene interpolymer having a block structure in the form of two or more blocks or segments, such as PP-P-QQ-Q or PP „P_qq—q_p_„ Pp. In other implementations, & and Qs may be alternately distributed along the dilute homopolymer chain to form a variable-structured farnesene interpolymer such as pQ, pQp, pQpQ, pQp-q_p or the like. . In certain implementations, 'each Q has the formula AxBy or disclosed herein. In a specific implementation, the polyfarnesene molecule of the present invention has a formula 1 content of up to 85 wt%, 8 wt%, 7 wt%, and 仞25 201026773 in the total weight of the polyfarnesene. Wt·%, 50 wt·%. In other embodiments, the polyfarnesene molecule of the present invention has a ruthenium compound having a formula of at least 1 〇 〇 / 〇, 15 ' wt % of the total weight of the polyfarnesene. %, 20 wt.%, 25 wt.%, 30 wt.%, 40 wt.%, 50 wt.%, 60 wt.%, .70 wt.%, 80 wt.%, 9 〇wt.0/〇 , 95 wt.%, or 99 wt.%. In a further embodiment, the content of the formula (Π) in the polyfarnesene molecule of the present invention accounts for 1 wt.%/〇_99 wt.% of the total weight of the polyfarnesene. 5 wt.%-99 wt.%, 10 wt.〇/Q -99 wt.%, or 15 wt.%-99 wt.%. In a further embodiment, the composition of the polyfarnesene molecule of the present invention having the formula (IV) has a content of up to 0.1 wt.%, 0.5 wt.%/〇 in the total weight of the polyfarnesene. 1 wt.%, 2 wt.%, 3 wt.%. In certain embodiments, the polyfarnesene disclosed herein is substantially free of compositions of formula 1, (II), (ΠΙ) or (IV). In the specific implementation project, the polyfarnesene molecule disclosed in the present invention has the formula (V), (VI), (VII) or (VIII) up to 1 wt. 〇 / 0, 5 wt.%, 1 〇wt%, 2〇wt%, 30 wt.%, 40 wt.%, 50 wt.%, 60 wt.%, 70 wt.%, 80 wt.%, or 90 wt.%, the specific ratio according to the polymerization method It depends on the total weight of the olefin. In other embodiments, the polycondensation molecules of the present invention have the formula (V), (yj), (YU) or (Vm) up to 1 ❹ wt.% ' 2 wt.%' 3wt .%' 5 wt.% > 10 wt.% > 20 wt.% ' 30 wt.% > 40 wt.% ' 50 wt.%, or 60 wt.%. The specific ratio depends on the total weight of the polyfarnesene. In a further embodiment, the ratio of the content of the formula (y^, (yj), (VII) or (VIII) in the polyfarnesene molecule of the present invention to the total weight of the polythene thinning丨wt%_99 wt%, 5 wt.%-99 wt.%, 10 wt.% -99 Wt.%, or 15 plus% _99 wt%. In some embodiments, the present invention A composition of the formula (V), (yj), (VH) or (vm) is substantially absent. 26 201026773 In other implementations, the sum of the values of m and η is greater than 250, 300, 500, 750, 1000 Or 2000. In a further implementation, the sum of the values of m and 1 disclosed herein is greater than 250, 300, 500, 750, 1000 or 2000. In a specific implementation, the values of η and 1 disclosed herein are The sum is greater than 250, 300, 500, 750, 1000 or 2000. In certain implementations, the sum of the values of m, η, 1 and k disclosed herein is greater than 250, 300, 500, 750, 1000 or 2000. In a specific implementation, the polyanthene of the present invention has a number average molecular weight φ (Mn), a weight average molecular weight (Mw), and a viscosity average molecular weight (Mz) greater than 60,000 Daltons, 100,000 Daltons, 20 0,000 Daltons, 300,000 Daltons, 500,000 Daltons, 750,000 Daltons, 1, 〇〇〇, 〇〇〇 Dalton, 1, 5 〇〇, 〇〇〇 Dalton or 2,000,000 Daltons In other implementations, the %, Mw, or Mz values of the polyfarnesene disclosed herein are less than 1 〇, 〇〇〇, 〇〇〇 Dalton, 5, 〇〇〇, 〇〇〇 Dalton 1, 〇〇〇, 〇0〇 Dalton, 750,000 Daltons or 500,000 Daltons. In some implementations, the polyfarnesene has at least a glass transition temperature (Tg) below - 55 °C, -60 °C, -65 °C, -70 °C, -75. (:, based on ASTM D7426-08 "DSC-related methods of operation for the determination of polymer and elastomeric compounds Tg (Standard Test) Method for Assignment of the DSC Procedure for

Determining Tg of a Polymer oran Elastomeric Compound)" see the references attached to the present invention. In certain embodiments, 'the compound of formula (3⁄4 is up to 80 wt.% in total weight of polyfarnesene. In other implementations, the sum of the values of m, n and 丨 is greater than 3 〇〇. In further In practice, at least a portion of the double bonds in the one or more compositions having formula 1, (II), (III), (IV), (jXy, (χι), (XII), and stereoisomers are hydrogenated. 201026773 In certain embodiments, the polyfarnesene is a farnesene interpolymer. In a further implementation, the farnesene interpolymer disclosed herein comprises one or more combinations derived from farnesene. And the content of these farnesene is at least 5 mole percent, 1 mole percent, 15 mole percent, 2 mole percent, 30 mole percent, 4 mole percent, 5 Å throughout the farnesene interpolymer. Molar percentage, 6 mole percent, 7 mole percent, 80 mole percent or mole percent. In still further embodiments, the farnesene interpolymer of the present invention contains one or more derived from ethylene. Unit of monomer composition, and these vinyl sheets The content is at least 5 mole percent, 1 mole percent, 15 mole percent, 2 mole percent, 30 mole percent, 4 mole percent, 50 mole percent, 60 mole percent, 70 throughout the farnesene interpolymer. Molar percentage, 80 mole percent or 9 mole percent. In a specific implementation, 'polyfarnesene is composed of one or more polymer molecules, wherein the polymer molecule has the following formula (X,): (χ,), Wherein 'η is an integer ranging from 1 to about 5, 〇〇〇, 1 to about lo ooo, 1 to 大约 about 50,000, 1 to about 1 〇〇, 〇〇〇, 丨 to about 2 〇〇, 〇〇 〇, or 1 to about 500.000; m is an integer 'which ranges from 〇 to about 5,000, 〇 to about 1 〇〇〇〇, 〇 to about 50,000, 〇 to about loo ooo, 〇 to about 2 〇〇, 〇〇〇 Or 〇 to about 500.000; X is derived from farnesene, γ is derived from a vinyl monomer. In certain embodiments, X has one or more of the following formula (I,) _ (VIII,): ^

28 201026773 R2 (IV,),

In a specific implementation, Υ has the formula (IX,):

R5

Wherein R1, R2, R3, R4 are the compositions defined in the invention; and R5, r6, r7 and R are each a hydrazine, an organic group or a functional group.

Generally, the polyfarnesene contains a mixture of polymer molecules, each of the polymers having the formula (X) wherein each of m and η is a certain value. The average value and distribution of the η or m values disclosed in the present invention depend on the respective factors, such as the complementary molar ratio, reaction time and temperature, presence or absence of chain termination reagents, initiator materials, and polymerization conditions. The farnesene interpolymer having the formula (X') may include unreacted comonomer, but even if the comonomer is 16 degrees; f is extremely small or undetectable, its density is usually small. The polymerization of the m and n values of the mosquitoes affects the proportion of the polymer product. In some embodiments, the 'n is an integer' wire is around 丨 to about 1 〇, _, 1 to about 5 〇, _, 1 to about er, _, 1 to about 200,000, 1 to about 500,000, not The integer ' ranges from 5,000 to about 5,000, 〇 to about 10, _, 〇 to about 50,000, 〇 to about 〇〇, 〇 to about 2, _ or 〇 to about 5 〇. In other implementations, n may range from 1 to about 5 GGG, 1 to 29, 2009, 26,773, about 2,500, 1 to about 1000, 1 to about 500, 1 to about 100, 1 to about 5, respectively; 〇 to about 5 〇〇〇, 〇 to about 2500, 0 to about 100 〇, 〇 to about 500, 0 to about 1 〇〇 or 〇 to about 5 〇. One of ordinary skill in the art will recognize that the range of amplification of η and m needs to be well thought out and that its value should be within the scope of the present disclosure. In some embodiments 'Formula (X,) includes two terminal groups, as shown below:

Wherein, the designation (*) of the towel indicates a terminal group, and the polymer t of the group in different polyfarnesene may be changed or unchanged, and the test may be based on various factors, such as raw materials. The state of the specific polymerization process in the presence or absence of the chain terminating reagent, the amount of the initiator, and the end of the polymerization reaction.

In some implementations, the x(Y) of the formula (X,) is linearly i-connected. In other embodiments, Xs and Ys in the formula (X,) are in a substantially branched manner. In the step of the step of the step, the edge of the towel of the formula (X,) is connected to the star of the star. In the further implementation, each of Xs and Ys is at least one block along the polymerization 2 cloth, and thus at least one of the two _ _ _ _ _ _ ❹ 互 互 互 互X enemy segment and a γ segment. In further facts, = Υ along the filament chain minus random distribution, thereby forming a random method of mutated two = poly: χ and γ · a cross in the law === Ming disclosed by the interfacial copolymer The woman in the law contains: 25ml. / The ratio is greater than 1·5^%, 2·0-^.μ°, 5%%, 1% reduction, 15%% or 20mole%. At 30 201026773, he implemented 'the farnesene content of the farnesene interpolymer disclosed in the present invention in the total weight of the farnesene interpolymer is less than 90 mole %, 80 mole %, 70 mole 〇 /〇, 60 mole %, 50 mole %, 40 mole % or 30 mole %. In some embodiments, the proportion of vinyl monomer 3 in the farnesene interpolymer of the present invention is greater than U mole %, 2.0 mole %, based on the total weight of the denitre. 2.5 mole %, 5 mole %, 10 mole %, 15 mole % or 20 mole %. In other embodiments, the farnesene content of the farnesene interpolymer disclosed in the present invention accounts for less than 90 mole 0/〇, 80 mole 0/Q, in the total weight of the φ 晞 晞 interpolymer. 70 mole %, 60 mole %, 50 mole %, 40 mole % or 30 mole 〇 / 〇. In some embodiments, the mole percent of the farnesene to the ethylene monomer is about i: 5 to 100:1. In other implementations, the molar percentage of XttY ranges from 1:4 to 1 :1, 1:3.5 to 100 ··1, 1:3 to 100: JJ : 2 5 to 1〇〇: i or ]: 2 to 100: 1. In some embodiments ten, m is a value of 1 or greater, and the molar ratio of X to Y is about 1:4 to 100:1.具体 In a specific implementation, the content of the formula (1,) in the poly-fabric molecule disclosed in the present invention accounts for up to 85%, Tao%, 7〇%, and 6〇 in the total weight of the polyfarnesene.

Wt.%, 5G Wt%. In other embodiments, the composition of the polyfarnesene molecule disclosed in the present invention has a content of at least 1 Gwt%, 15 wt.%, 20 wt.%, 25 wt% of the composition of the formula. 〇/. 3〇〇/ n/ t. /g, 40 wt. /g, 50 wt.%, 60 wt.〇/〇, .70 w,/0 . 8〇wt〇/〇. 9〇wt〇/〇 ^ 9s wt% ^ ^ ^ wt% 把 把 把 把 的 的 的 的 的 的 的 的 的 冗 冗 冗 冗 冗 冗 冗 冗 冗 冗 冗 冗 冗 里 里 里 里 里 里 里 里 里 里 里 里 里 里 里 里 99 99 99 99 99 99 % > 5 wt.%-99 wt.% > i〇wt.% -99 wt.%, or 15 wt.0/. -99 wt 0/ /^

Wt/o. In a further implementation, the present invention 31 201026773, the disclosure of the new material, rape, money, ^ ^ 0, wt 〇 / 0. 〇, wt% ^ t wt% In some implementations, the disclosed method of polythene In essence, ^Γ.%. In the composition of (IV,). Permeability..., Formula (I)' (II,), (III,) In the specific implementation project, the polymethod disclosed in the present invention has (V,), (VI,), (VII,) or (vm, In addition, 卞 has the general formula, H) wrn) up to lwt%, 5wt%, i〇wt%2〇wt. /ίι, 30 wt.%, 40 wt.%, 50 wt °/ λλ n/ 刈wt. / . , 60 wt%, 7〇 wt %, 8〇 ^ %, or 90 Wt.%. The specific ratio depends on the total weight of the method. In other embodiments, the polyfarnesene molecules disclosed in the present invention have the formula (10), (vr), (arm) or (viii,) at most! Wt.%, 2 wt%, 3 wt%, 5 %%, 1 〇 plus %, 2〇 heart ^ 30 wt·%, 40 wt·%, 50 wt.〇/. , or 60 wt%. The specific ratio depends on the total weight of the polyfarnesene. In the step-by-step real wealth, the polyfarnesene molecule disclosed by the hair duck has the formula (V'), (VI'), (VII,) or (VIII,) in the total weight of the polyfarnesene. The proportion in the range is 1 wt.%-99 wt.%, 5 wt.%-99 wt.%, 10 wt.% -99 Wt.%, or 15 wt.%-99 wt.%. In certain embodiments, the polyfarnesene of the present invention is substantially free of combinations of formula (V,), (VI,), (νίΓ) or (νπτ). Any of the vinyl groups containing a polymerizable with farnesene, i.e., _CH==CH2, can be used as the vinyl monomer to prepare the farnesene interpolymer of the present invention. The vinyl monomer disclosed in the present invention comprises ethylene, i.e., CH2=CH2. In a specific implementation, the vinyl monomer has the formula (XV): R6 R7 〇鲈 (XV), wherein each of R 5 , R 6 , R 7 and R 8 is H, an organic group or a functional group 32 201026773 Towels, with 峨), (DC,) from v), r5, r6, r7^8 to v have an organic turn. In the further step, the organic group is a hydrocarbon group, a substituted hydrocarbon group, and a silk base peach. In the weiwei towel, the RWW having the formula (4), (or (XV) may each be hydrogen, silk, cyclofilament, aryl, cycloalkenyl, county, heterocyclic group, silk group, aryloxy group, silk, burnt Test group, amine methyl sulfhydryl group, burn bribe base, second brittle base, brewing oxy group, nitrile or halogen. Among them, r5, r6, = and R8 can each be used for money, recording, ring, silk, cycloalkenyl, Alkynyl, hexyloxy aryloxy, thiol, oxo, amide, acryl, hydrazine, carbonitrile, nitrile or ruthenium. R5 of the formula (4), taken, or (XV) is an aryl group, and both r6 and r8 are H. In a further implementation, r5 having the formula (IX), (IX,) or (Χ·Κ5 is a phenyl group, r6, r^r8_h, in a specific real money, having a), (ix,) or (d), One of 5 to 1 in r6 and r8 is hydrogen. In a specific implementation, R R , R and R in the formula (IX), (IX,) or (XV) are homogeneous. In the step of the implementation, R5 of the formula (10), (a), ❹ or qing) is a hydrocarbon group, and r6 and r8 are both H. In still further implementations, the domains are alkyl, cyclofilament or aryl. In a further embodiment, R5, R6, ultra 7 and r8 having the formula (IX), (IX) or (4) have neither or no dilute ring groups. In still further embodiments, Between the formulas R, R, R and R8 are neither or not containing a thiol group, a substituted hydrocarbyl group, a heterocyclic group or a substituted heterocyclic group. 8 In a specific implementation, there is a formula) At least one of R5, R6, R7 and R of (IX,) or (XV) is a functional group containing _, 0, N, s, oxime or a combination thereof. Examples of these include silk, alkoxy, 33 201026773 aryloxy, amino, nitro, thiol, thioether, imido, cyano, amino, phosphorylated (-P(=0)( 0-alkyl) 2,-P(=〇)(〇-aryl) 2, or _p(=0)(0-alkyl))〇-aryl), hypophosphite [-Ρ(=〇 (〇-alkyl)alkyl, -Ρ(=〇)(〇-aryl)alkyl, -Ρ(=〇)(〇- 'alkyl)aryl or -Ρ(=0)(0- Aryl)aryl], carboxy, thiocarbonyl, sulfonium (-s(=0)2 alkyl or -S(=0)2 aryl), sulfonamide [-so2nh2, -so2nh(alkyl), -so2nh (aryl), -S〇2N(alkyl) 2 -so2n(aryl)2, or -S02N(aryl)(alkyl), keto, aldehyde, ester group, carbonyl, amino (primary, secondary or tertiary)-C〇2CH3, -CONH2 _OCH2CONH2, -NH2, -〇CHF2, -〇CF3, -NH(alkyl), -N(alkyl 13 group) 2, -NH(alkyl), -N(alkyl)(aryl), -N( Aryl) 2, -CHO, -CO(alkyl), -CO(aryl), -c〇2(alkyl) or -co2(aryl). In certain embodiments, the functional group is or contains Alkoxy, aryloxy, carboxy, alkoxycarbonyl, aminyl, alkylamino, monoalkylamine, decyloxy, nitrile or halogen. In other implementations, having the formula (DQ, (IX) R5, R6, R7 and R8 of ') or (XV) are neither or contain functional groups. In other embodiments, R5, R6, R7 of formula (IX), (IX,) or (XV) R8 is neither or does not contain an alkoxy group, an aryloxy group, a carboxyl group, an alkoxycarbonyl group, an amine mercapto group, an alkylamino group, a dialkylamino group, a decyloxy group, a nitrile or an i element. The ethylene monomer is a substituted or unsubstituted olefin such as ethylene or styrene, dentated ethylene, vinyl ether, acrylonitrile, acrylate, Alkyl acrylate, acrylamide, methacrylamide or a combination thereof. In other embodiments, the monomer is ethylene, hydrazine or a combination thereof. Non-limiting examples of suitable smog include Phenylethylene, propylene, 1_butyl, i-diluted, L-octene, 4-methyl + pentene, norbornene, decene, 1,5-hexadiene and combinations thereof. In certain embodiments, the vinyl monomer is an aryl group such as styrene, alpha-methyl benzophenone or 34 201026773 2-ethyl decyl benzene. Additional examples include functionalized vinyl aryl groups such as those disclosed in U.S. Patent No. 7, 41,761, which is incorporated herein by reference. % In certain embodiments, the farnesene interpolymer disclosed herein is derived from at least one farnesene and at least one olefin monomer. Olefins refer to unsaturated hydrocarbyl compounds having at least one carbon-carbon double bond. In a particular implementation, the olefin is a conjugated diene. Any olefin may be used in the practice described herein and in accordance with the catalyst selected. Non-limiting examples of certain suitable olefins include c22() aliphatic compounds and 8-20 φ aromatic compounds containing unsaturated ethylenic compounds and cyclic vinyl compounds such as butene, cyclopentene, and dicyclopentadiene. Alkene and norbornene, norbornene includes, but is not limited to, a substituted-Cl 2 hydrocarbon group or a cyclic hydrocarbon group _5, 6-substituted norbornene compound. Non-limiting examples of suitable olefins include these olefins and mixtures thereof with diolefins.

Non-limiting examples of certain suitable olefin or olefin monomers include styrene, ethylene, propylene, isobutylene, butene, pentene, 1 hexamethylene, 1-heptacene, 1-octene , 1-壬女' 1-decene and i twelve rare, L fourteen rare, i•hexadecene, eighteen women, ten carbon diacid, 3-methyl small butene, 3 _ methyl Small amylose, 4_methyl_J _ 戍 Λ, Λ6-dimethyl chlorhexidine, 4 _ ethyl cyclohexene, 乙 环 环 烧 , , , , , , , , , , , , , , , , , , , , Alkene, cyclohexene, dicyclopentadiene, octene, c (tetra) olefin, including but not limited to butadiene, u. pentadiene, dihexamethylene, hexamethylene bis-1'7-octane Alkene, anthracene, 9-decadiene, other smoke and the like. In the implementation of - the monomer is propylene, butadiene, pentylene, dilute, virgin or a combination thereof. The farnesene interpolymers that were covered in this July can be derived from diuretic and styrene. Method 35 201026773 The dilute interpolymer may also contain at least one c2.2. An olefin, at least one c4.18 diolefin, fluorene at least one alkenylbenzene or a mixture thereof. Suitable unsaturated comonomers can be used for the terephthalic polymerization. These co-organisms include vinylated mirrors and lysines, (iv) (such as conjugated or non-coaldiene, and sylvestre). These counties include olefins such as propylene, butyl sulphate, h-butyl sulphate, dipyridyl, 1-pentene, 4-methyl + pentene, 2 Γ - G H, and 1-壬, i • Terpenes and similar compounds. Other suitable monomers include styrene, halogen or silk-substituted styrene, ethylene-butylene, hydrazine, 4-hexadiene, 1,7-octadiene, and cyclic olefins such as cyclopentene, cyclohexene, and Cyclooctene. Some suitable non-co-bending diene monomers may be linear, branched or cyclic hydrocarbon dienes containing 6-ls carbon atoms. Non-limiting examples of certain suitable non-common diene fumes include linear acyclic di-negatives such as (4) hexamethylene dichloride, anthracene, 6-octane dithizone, anthracene, 7-octanedioxene, 1,9-fluorene. Diene, branched acyclic diuret such as 5 · mercapto • hexadiene, dimethyl-1,6-octadiene, 3,7-dimethyl--octadiene and dihydromyrcene a mixture of dihydromyricene and dihydr〇〇dnene, a monocyclic cycloaliphatic such as i,3-cyclopentadiene; M_cyclohexane; a 5-ring; a dilute and a , 5-ring-tweldium dilute and polycyclic alicyclic fusion and bridging two women such as tetrahydroindene, methyl tetrahydrogen (te her ydr〇indene), dicyclopentadiene, bicyclo (2, 2 , 1)^_ 2,5 _diene; olefin, silk, cyclomethine, icy icy, such as 5 · methyl-2 _ norbornene (MNB), 5, _ 2 _ norbornene, 5 Isopropyl-2 -norborn,5-(4-cyclopentenyl)_ 2 _norborn, 5 -cyclohexylene _ 2 _norbornene, 5-vinyl-2_norbornene And the ice tablets are thin. Among the typical diene compounds used in the preparation of tripropylene propylene rubber (EPDM), the most preferred secondary is hexamethene 36 201026773 (HD), 5-ethylidene-2-norbornene (ENB), 5-vinylidene-2_norbornene (vnb), 5-indenyl-2-norbornene (MNB), and dicyclopentadiene^cpD). In a specific embodiment, the diene is 5 ethylethylene norbornene (ENB) or 1,4-hexadiene (hd). In other embodiments, the farnesene interpolymer is not derived from polyenes such as dienes, trienes, tetraenes, and the like. In some embodiments, the <RTI ID=0.0>>"""""" Non-limiting examples of suitable olefins include ethylene, propylene, isobutylene, decene-butene, decene-pentene, h-hexene, 4-methyl-1-pentene, and blister. In certain embodiments, the farnesene interpolymer disclosed herein is not derived from ethylene. In certain embodiments, the farnesene interpolymers disclosed herein are not derived from one or more olefins. In a specific implementation, the vinyl monomer does not contain a boxene. In other embodiments, the vinyl monomer does not contain a compound selected from the group consisting of isoprene, dipentene, post-dilute, terpinolene, lemon (dipentyl), ortho Aldehyde, terpene, 3-palli, terpene, juniperene, caryophyllene, laurel, basil, cedarene, bisabolene, zingiberene, hopsene, citronellol, aromatic Alcohol, geraniol, flowering alcohol, dentate, terpineol, D_terpineol _(4), dinitrocarvyl alcohol, nerolidol, farnesol, eucalyptol, The sample is taken, D_ is citronella, fragrant residue, D-hu thin, Hu _, fragrant bud _, red _, rarity, sandalwood, vitamin A, rosin acid and combinations thereof. In a further implementation, the maternal base does not contain an isoflavone. The farnesene intertwining material can be functionalized by combining with at least one functional base of the polymeric structural towel. Typical functional groups may include ethylated unsaturated monocarboxylic acid carboxylic acid groups, ethylated unsaturated mono- and bis-anhydride functional groups and salts thereof, and functional groups such as 37 201026773 esters can also be converted. The method of dilute interpolymers in the midbrain can be used to form an interpolymer, a test filament monomer and other optional co-organisms. Professional wealth, to apply any known transfer function base method. A special functional group is cis-butyl dianhydride. In the functionalized farnesene interpolymer, the number of functional groups may vary. In these implementations, these Wei Gu are in the same way. (4) ^ 〇 chest.%, Z5wt%, 5wt%, 7.5wt .%, 1% machine down. In other =, these functional groups account for less than 4% milk%, 3〇wt.%, 25wt%, 2% by weight, and 15% by weight of the total weight of the farnesene interpolymer. Any catalyzed process - polymerization or silk - _ can be used to prepare the polymethods mentioned in the present invention. Suitable catalysis - some non-limiting examples include organic clocks, Ziegler Natta catalysts, Kaminsky catalysts and metallocene catalysis. In certain embodiments, the catalyst is a Ziegler Natta catalyst, a Kaminsky catalyst, a metallocene catalyst, or a combination thereof. In certain implementations, the catalyst may comprise a cocatalyst. In the further implementation of the step 0, the secondary catalyzing agent is a hydride, a singly or aryl group of a metal, or a combination thereof. In a further implementation, the metal is Ming, Zhong, Zinc, Tin, Tin, Bond, and Town. - A certain implementation of t catalyzed 胄彳 is organic 胄彳. Any organic catalyst capable of performing olefin polymerization can be used. Some non-limiting examples of suitable organic clock reagents include n-butyl H, sec-butyl (tetra) tert-butyl. The right way to test - some non-limiting; 7 including tetramethylethylenediamine (tmeda; >, pentamethyldiethylamine (PMDTA) - or eagle claw reading. - Dew's organic money seen in R Qing. pGrt et al., 38 201026773 • "The Chemistry π〇rganQlithium.C〇mp〇Unds", Part 1 (2004) and Volume 2 (2006), both of which are included In the literature referenced in the accompanying drawings. In some embodiments, the catalyst is a mixture of an organolithium reagent and a Lewis base. Any Lewis which can depolymerize the organic clock reagent to increase the solubility and activity of the organic chain reagent can be used. Polymerized organic clock reagents typically have a combination of clocks on multiple carbon atoms and a combination of carbons on multiple clock atoms. Some non-limiting examples of suitable Lewis tests include tetramethylethylenediamine. , bis-diethylenediamine triacetin, including I,2-bis(monoamido)ethene (also known as tetramethylethylenediamine or τμε〇α), n,n'n', n', n"·pentaindiethylenetriamine (PMDTA), hawkskin test and its combination. In a second implementation, the catalyst is Ziegler _ Tower catalyst. Generally, the Ziegler-Natta catalyst can be a lion or a job. In the New Zealand implementation, the Ziegler Natta catalyst of the polyfarnesene polymerization of the present invention is heterogeneous Ziegler. _Natta Catalysts. Some useful Ziegler 'Natta catalysts can be found in J. Boor's WZigler-Natta catalyst and polymerization (''ziegler ga a Catalysts and polymeri_^ (Saunders College Publishing) , page (10) 7 (W9 years); and view (7) Chiss · Stevens ((Introduction to Polymer Chemistry (Cultural Gifts, Such as Qing, (10) Intr〇 (h (cii〇n)" (Oxford University Press, Third Edition, p. 236 245 (1999)), both articles can be found in the reference attached to the present invention. The heterologous Ziegler-Natta catalyst generally comprises (1) a transition metal compound containing a group element of the periodic table; (2) An organometallic compound of a Group WII metal element of the Periodic Table of the Elements. When an organometallic compound is considered as a cocatalyst or agonist, the transition metal compound can be referred to as a catalyst. The transition metal compound usually contains a 39.

I 201026773. Some non-limiting examples of suitable metals. Suitable anions and ligands - some, alkoxy, acetophenone, cyclopentadienyl metal and one or more anions and ligands including titanium, niobium, chromium, pin, wrong, iron, limited Examples include halides, _oxides and benzene.

Any aromatic metal capable of ionizing an organometallic complex to form an active dilute fumes, which is often used as a weathering, burning compound or sinter, bell, zinc, tin, ore, wrinkle, magnesium. Compound.面面杂_-Face mosquito liver including domain based on oxygen barrier», occupation), ethyl 魄m35 Wei), silk pure compound (trimethyl aluminum, diethyl aluminum, diethyl aluminum chloride, Trimethylaluminum, triisobutylaluminum, trioctane, diethylzinc, di(isobutyl)zinc, di(n-hexyl)zinc, ethyl (T-butyl). Other suitable cocatalysts include An acid salt containing a non-nucleophilic anion. These compounds generally include attachment to a city ligand. The non-limiting examples of these suitable compounds include the bell four (pentafluorophenyl), which is a clock of four (pentafluorophenyl bud, aniline IV). (Pentafluorobenzene fine acid, etc.. Suitable _catalytic _ - some non-limiting examples include tumbling, including side and - thief base, silk. The other non-limiting examples of these compounds include substitution And unsubstituted trialkyl and triaryl salts, such as tris(pentafluorophenyl) side, triphenyl boron, tri-n-octyl boron salts, etc. These and other suitable boron-containing auxiliary Catalysts or activators can be found in the disclosures of U.S. Patent Nos. 5,153,157, 5,198, 401, and 5,241,025, the disclosure of which is incorporated herein by reference. In practice, Ziegler Natta catalysts can be impregnated in support materials. Some useful support materials can be found in Malco丨mP Stevens' Introduction to Polymer Chemistry (Oxford University press ' Third Edition, page 251 (1999) Please refer to the reference attached to the invention of 40 201026773. Supporting materials: Non-limiting examples of supporting materials for inserting or basic inserting lions include chlorine tilting, cerium oxide, suitable oxidation domains _, H, oxygen Recorded as activated porous rare earth windings and oxygen _ and its group of acid, between 8 and 8, depending on one, = e = - rrrrrf_Emmet Yao (four) silk surface view method, its two years of "American Chemical Society Miscellaneous" [60 (309)], refer to the reference of the present invention. In some implementations, the surface area of the support material is about lGm2 / ☆ move m2 / g. In the step-by-step real shot, the surface of the gambling material is on the side of 25 m2 / g M2/g. The support material has an average particle size of about 2G to 3 (8) microns, to coffee, meters, 20 to 200 microns, 2 to 15 microns, 2 to 12 microns, 3 to 10 or 30. To 90 «. Domain (four) meaning bribe or 0.9-1.3 g / ml. In the implementation, for The catalyst of the present invention is or contains a Kaminsky catalyst, also known as a homologous Ziegler-Natta catalyst. The Kaminsky catalyst can also be used to produce the poly structures of the present invention having specific structural and physical properties. Farnesene. A description of some Kaminsky catalysts or homologous Ziegler-Natta catalysts can be found in Malc〇lm P. Stevens' Introduction to Polymer Chemistry (published by 〇xfor£j University Press (1999) 2nd edition (page 245-251) and John Scheirs and Walter Kaminsky, "Metallocene-Based Polyolefins: Preparation, Properties, and Technology", Volume 1 41 201026773 Ping this = towel too much can be used to rape this (four) _ reference. In a second implementation, the present invention discloses a card suitable for the preparation of a poly-thickness card (in the catalyzed transition: a transition metal atom between the ferro-molecule ring structures. In the implementation of the Octa, the formula of the Kaminsky catalyst It can be expressed as Cp2MX2 in pots or postal _ prime (such as α), _ their group. Money — #_巾, + electrocatalyst with R 2

R (XVI). ^ can be a ruthenium group, usually C(CH3)2, S1 (C_ ΗΓ = Γ M is a transition metal (for example, wrong, titanium or Ht), X疋_素 ( Such as chloro), alkyl or a combination thereof. In some non-limiting examples, the Kaminsky catalyst has the formula (tick):

❹ (xvii) > where Μ is Zr, Hf or Ti. In the practice of the invention, the catalyst is catalyzed by a fine card. The cocatalyst can be any of the side faces of this month. At the specific time, the lion's agent is Aluminium Oxide (MAO). An oligomeric compound having a general formula and wherein η is 1-H). The sub-layer has the following fine (four): it completely replaces the gas (XVIII) with (XIX) 42 201026773 atoms to alkylate the metallocene precursor; and produces a catalytically active ion pair Cp2MCH3+/MAO_, wherein the cationic group The group participates in the polymerization reaction, while the MACT acts as a *weak anion. Some non-limiting examples of MAO include equations (XX) through (XXI):

(XX) and ch3 (CH3)2A. 〇-aI-ai(ch3)2 (XXI) ❹ In a specific implementation, the catalyst used to produce the farnesene interpolymer of the present invention may be or include A metallocene catalyst. Some metallocene catalysts can be found in "Modification of a Ziegler-Natta catalyst with a metallocene catalyst and its olefin polymerization behavior" by Tae Oan Ahn et al. From p〇iymer

Engineering and Science, (7), 25 pages (1999); and J〇hn

Scheirs and Walter Kaminsky, "Preparation, Properties and Related Techniques of Metallocene-Polyolefins", Vol. 1 (Wiley, 2000), both of which are incorporated herein by reference. In other implementations, the metallocene catalyst comprises a transition metal complex having a core comprising a metal domain and a large (tetra) ligand containing a % diimine or a diketimine. In an advanced step, the metallocene catalyst has the formula (XXII):

43 201026773 Which is recorded or put. In some embodiments, the catalyst used in the present invention may be or include a mono-anionic ligand-metallocene catalyst. A non-limiting example of a priming agent has the formula (XXIII):

In other embodiments, the catalyst used in the present invention may be or include a metallocene catalyst containing alpha and m "between two imine groups and may impart a triad of her." A Pei Jin Linhua _ heterogeneous example and formula (xxiv): ',

In some embodiments, the catalyst used in the present invention may be or include a metallocene catalyst #1, which contains a sulphur-based catalyst. Foot v):

\/1 2 (XXV) ° In some known, the farnesene homopolymer of the present invention can be prepared by the following steps: 44 201026773 *(8) Microbial monosaccharide or non-fermented carbon raw material formation method And (8) conducting the polymerization of farnesene in the presence of the catalyst disclosed in the present invention. In-body implementation towel The disclosed farnesene interpolymers can be prepared by the following various steps: (8) microbial monosaccharide or non-Weic carbon supplement county (four): and (b) catalysts disclosed in the present invention In the presence of the copolymer, at least one ethylene monomer is copolymerized. In some embodiments, the polyfarnesene disclosed in the present invention is prepared by the polymerization of /3-fabric in the presence of a catalyst, wherein the polythene content of the polythene compound is occupied by a polycondensation method. The proportion of total weight of nitenol is most often wt%, π wt%, 7〇w%, 65 wt.% or 60 wt.%. In some embodiments, the ?-farnesene will undergo a copolymerization reaction with a vinyl monomer to form a farnesene copolymer. In other implementations, the vinyl monomer is a phenyl group. In a further implementation, the farnesene copolymer is a block copolymer. In a specific implementation, the polyfarnesene disclosed in the present invention is prepared by polymerization of φ-% farnesene in the presence of a catalyst, wherein the cis-1,4 microstructure of the polyfarnesene is occupied by a polymerization method. The ratio of the total weight of the olefin ranges from 1 wt% to 99 wt.%, i〇wt%_99 wt.%, 20 wt.% to 99 wt.%, 30 wt.% to 99 wt.%, 40 wt_% _99 wt. %, 50 wt.% -99 wt.%' 1 wt.% -99 wt.% -1 wt.% -90 wt.%' 1 wt.% -80 wt.% ' 1 wt%-70wt.% or 1 wt.% - 60 wt ° / 〇. In some implementations, the farnesene will be copolymerized with a vinyl monomer to form a farnesene copolymer. In other embodiments the 'vinyl monomer is a phenyl group. In a further embodiment, the farnesene copolymer is a block copolymer. In certain embodiments, the polyfarnesene of the present invention may be subjected to a partial or total nitridation reaction by any of the hydrogenating agents known to those skilled in the art. For example, the preparation of a saturated polyfarnesene can be achieved by two aspects (8) in the presence of a catalyst, by the sample, the method provided by the series (4), and the antimony of the granules; At least some of the double bonds are hydrogenated in the unsaturated polycondensation. In some implementations: the dilute will be copolymerized with the ethylene-based monomers disclosed herein to form a farnesene copolymer. In other implementations, the Ethylene filaments are based on silk. In the further implementation, the farnesene copolymer is a copolymer. In a further implementation, the farnesene is & farnesene, /3-farnesene or a combination thereof. In a specific implementation, the hydrogenation reagent is present in a deuteration catalyst ## hydrogen. In some implementations, the hydrogenation catalyst is a catalyst, carbon/platinum, platinum oxide,

Ru(PPh3)2Cl2, Raney nickel or a composition thereof. In one embodiment, the catalyst is a catalyst. In another implementation, the hydrogenation catalyst is 5% palladium on carbon. In a further implementation, the catalyst is 10% palladium/broken in a high pressure reaction crucible and the hydrogenation reaction can be continued until completion. Usually, after the completion of the translation, the reaction mixture is washed with water, concentrated and dried to obtain the corresponding hydrogenated product. In addition, any reducing agent that reduces the bond to the C-C bond is also used. For example, polyfarnesene can be hydrogenated by hydrazine in the presence of a catalyst such as 5-ethyl-3-methyl-3-methyllumiflavinium perchlorate in the presence of a catalyst such as 5-ethyl-3-methyllumiflavinium perchlorate. Hydrogenated product. The disclosure of the 肼 reduction reaction can be found in the literature by Imada, which is included in the magazine j.Am.

Chem. S〇c" (2005, 127, pp. 14544-14545, see the literature attached to the present invention. - In some embodiments, at room temperature and in the presence of a catalyst and hydrogen, poly-farnesene At least a portion of the C=C double bond is reduced to the corresponding CC bond. In other implementations, 46 201026773 one or more having the formula ^ d 'Hnr), (v) in the presence of a catalyst and hydrogen at room temperature To some of the double bonds in the compounds of ')-(vn'), (χι)-(χιν) and stereoisomers are reduced to the corresponding CC bonds. In a further implementation, the chlorination catalyst is 10% palladium on carbon. In a specific implementation, the vinyl monomer is a phenyl group. In certain embodiments, the method is alpha-farnesene, /5-farnesene, or a combination thereof. In other embodiments, the farnesene is prepared by microorganisms. In a further implementation, the farnesene is prepared by a monosaccharide or non-fermented carbon feedstock φ. 'farnesene Farnesene can be derived from any starting material or prepared by any skilled artisan using any known method. In certain embodiments, the farnesene may be derived from a chemical feedstock such as petroleum or coal or obtained by chemical synthesis. In the case of a non-implemented towel, the process can be prepared by using petroleum or coal. In the implementation of the step, the method of chemical synthesis is obtained. Examples of suitable chemical synthesis methods include: • Dehydration of neroli with a toothed phosphonium in the mouth, and the appearance of (E, Z)-〇f-, (Ζ, Ζ)-ο;- and (Ζ) the synthesis of farnesene (Synthesis〇f (E,Z)-a-,(Z,Z)-〇s and (Z) must famesene)》 (Aust. LCh^\,197〇123(10)2101-2108 Page number) 'See the literature attached to the invention. In a second implementation, the method can be directly obtained or prepared from naturally occurring scales to be 'naturally generated'. A woman can be obtained from multi-faceted objects such as cypress gum, giant salamander, insects such as swallowtail, leaf beetle & white sacrifice and pine leaf bee; and marine life such as vines, sponges, _, mollusks And preparation class. Kebo gum tree or shaft also county Chai Lin face division Buddy became the 47 201026773 kupa丨y, cabismo, and COpaiiv 腴 surname smoke. Usually, gum trees can produce a large amount of shots per year (four) women © Lin she sighs needle _ and Daxie planted wealth. The needles are in the plant's pine 1 white door or pine cypress, usually a conical plant with a vascular tissue, most of the conifers Trees, some are shrubs. Suitable for confined coniferous plants including cedar, cypress, douglas fir, fir, alfalfa, "Santaram or s = leaf ^, - pine, redwood, spruce And the yew plant. Euphorbia m π species are distributed throughout the world, and the secrets of the species are many of the plant genus. The plant is about 2_, which is the most secret in the secret. , is a compound in the compound _ _ is - 嶋 big, _ compound, including = ene, bismuth, two _, two times Wei, three _, four _ Therefore, the law can be separated by _ oil Or derived from, and thus used in the present invention, the dienes can be prepared from biological raw materials. In addition, the other can be obtained from the hard-to-find carbon raw materials. In the implementation of the step-by-step, the squama is prepared by the carbon-reactive cells under suitable conditions. The de-nene is used to solidify the isoprene compound, θ = towel, rhyme, shape, and carbon source. Any sugar substance. In a specific implementation, the sugar is a combination of sugar or a combination of us. In other implementations, the sugar is - 双r. 'Disaccharide.' Some non-limiting examples of suitable monosaccharides include hexose, galactose early 48 201026773, beta ribose ribose and combinations thereof. Suitable disaccharides - some Qualitative.|, including sugar, sugar, maltose, trehalose, cellobiose, and combinations thereof. In other implementations, the 'single-sugar is sucrose. In the specific implementation towel, bioengineered fuel The composition can be obtained from a polysaccharide. Some non-limiting examples of suitable polysaccharides include house powder, glycogen, cellulose, chitin, and combinations thereof. A sugar-like material suitable for the production of farnesene can be prepared from a crop-like crop or a raw material towel. Suitable non-limiting examples of raw materials include Gan Yan, Gan Ning, Miscanthus, Alfalfa Beet, Sorghum 'Rice, switchgrass, barley, hemp, ramie, horse bell, red, cassava to hollyhock fruit, Sugar, whey or skim milk, corn, turn, fortune, wheat, generation, straw, cotton, various cellulosic waste and other biomass. In the implementation of the f body, suitable crops or secrets include raisins, beets and corn. In other applications, the sugar source is licorice juice or molasses. * Non-fermented carbon raw materials are carbon raw materials that cannot be converted into ethanol by organisms. Some non-limiting examples of suitable carbon materials include acetic acid and glycerin. In the specific implementation of Xinyu, the method can be prepared in a device capable of biosynthesizing isoprene. The facility may comprise any structure that utilizes microbial preparation & isoprenoids such as farnesene, pure dilute, decyl alcohol or farnesol. In certain implementations, the biological production equipment can include one or more of the cells disclosed in the flip cap. In other embodiments, the biological production device comprises cells comprising at least one CM isoprene, the content of the isoprene being at least wt.%, 5 wt.%, of the total weight of the cell culture, 1〇wt%, 20 wt%, 3〇%. In a further implementation, the biological production facility includes a fermentation unit containing one or more of the cells disclosed in the present invention. 49 201026773 Any fermenter that can provide a stable, optimal growth and breeding environment for cells or bacteria can be used in the present invention. In certain embodiments, the fermentor can include a "cell culture device" containing one of the cells disclosed in the present invention. In other embodiments, the fermentor can include a cell culture device, the culture. The device is capable of biologically producing a FPA. In a further implementation, the fermentor can comprise a cell culture device capable of biologically producing isoprenoid (IV) ( IPP). In other embodiments, the cell culture apparatus included in the biological production apparatus contains at least one Cls isoprene, and the content of the isoprene is at least i wt%, 5 wt% of the total weight of the cell culture. %, 10% by weight, 20% by weight, 3〇〇wt.%. The facility can also contain any oil that can be used from the class of bismuth, such as A method, ruthenium, thief, or ruthenium. The structure of the chelate or oil_additive. The structure may comprise a reaction device for hydrogenating A farnesene 4 farnesene, nerolidol or farnesol. Any conditions that are known to the skilled person (4) A reaction apparatus for converting ethanol to an olefin can be made in the present invention The reaction apparatus may comprise a dehydrogenation catalyst as disclosed herein. In some embodiments, the construction may further comprise a mixture of a mixer, a vessel, and a dehydrated product obtained from the dehydration step. The disclosure of the olefinic biosynthesis step can be found in U.S. Patent No. 7,399,323, U.S. Patent Application Serial No. 2//274, 523, and International Patent No. 2007/140,339 and WO 2007/139924, all of which are incorporated herein by reference. - 〇ί-法呢绿. 〇? The structure of the law is as follows: 50 201026773 • Eight can be found in different biological materials, including ants' Du Fu glands and apples and pears in the skin 'but not limited to These examples. From a biochemical point of view, the 仏 method is produced by FPP under the action of a farnesene synthase. Some suitable examples of nucleotide sequences that encode the synthase include __34. Pyms face this * tivardAnjou) and (AY182241, Malusdomestica). See Plantous et al., Planta (2004, 219(1): pp. 84-94). 泛 Pan-Fajiao/5-Fa The structure of the alkene is as follows: 3 It can be used in different biological materials, including insects, essential oils, and peppermint oil, but it is not limited to some examples. In some plants such as wild potatoes, the method is synthesized into a narrow space. The insects drive to lie. From the biological office, the material is generated by FPP under the action of shouting dilute synthase. Some suitable non-t-limiting examples of nucleotide sequences encoding the synthetase can be found in (Fun 4615; Menthaxpiperita) with (Αγ83 measured.

Artemisiaannua). See picaud et al., phyt〇ch__, 961-967 (2005). The structure of farnesol farnesol is expressed as follows: It can be found in non-biomass, including insects and essential oils, and its cap oil comes from citron oil Wb cyclamen, grass, tuberose and rose. From a biochemical point of view, 51 201026773, farnesol is produced by ρρρ under the action of a light enzyme such as farnesol synthase. Non-limiting examples of some suitable nucleotide sequences encoding the synthetase can be found in (AF529266; Zeamays) and (YDR481C; Saccharomyces ce-). See Song, L., "AppliedBiochemistiyand"

Biotechnology 128: 149-158 (2006). The structure of the scented tertiary alcohol neroli is shown below:

^ Can be found in non-biological materials, including insects and essential oils, of which essential oils come from dialing, ginger, jasmine, lavender, tea tree, and lemon grass. From a biochemical point of view, the gerbera alcohol-like enzyme such as nerolidol synthase is produced by FPP. A non-limiting example of some suitable (tetra) acid sequences encoding the synthetase can be found in the ΑΡ529266 sequence in s (maize, gene genetpsl). The smoothing of the farnesol canthraquinone alcohol of the present invention can be converted into a mixture of a stilbene and a chiralene by a hydrogen-free reagent or an acid. Any such non-limiting example of a dehydrogenating reagent or acid catalytic network capable of converting ethanol to _ can be used in the present invention. Some non-limiting examples of suitable dehydrogenating or acid catalysts include gamma chloride, water vaporized zinc, squaric acid, and sulfuric acid. The general 埚ρ big-range reaction: the copolymerization of farnesene with hydrocarbons can be compared in comparison. In a specific implementation, the temperature of the polymerization reaction is _30 201026773. (: -280 °C, 30. 〇180 °C or 60 °C -100 〇C. Partial pressure range of ethylene comonomer, around 15 psig (0.1 MPa) - 50,000 psig (245 MPa), 15 psig ( 0.1 MPa) -25,000 psig (172.5 MPa), 15 psig (0.1 Mpa) _1 〇〇〇〇 psig (69 MPa), 15 psig (0.1 MPa) - 5,000 psig (34.5 MPa) or 15 psig (01 Mpa) - 1,000 Psig (6.9 MPa) ° The density of the catalysts disclosed in the present invention for the formation of polydatin depends on a number of factors. In some implementations, the density can range from 0.01 micromoles per liter to 1 micromoles per liter Φ. Within the range, the length of the polymerization depends on the type of the reaction process, the density of the catalyst, and other factors. Usually, the polymerization time is from several minutes to several hours. The polymerization process of the homopolymer in a solution is not limited. The sexual examples are summarized as follows: A farnesene such as f farnesene can be added to a solvent such as cyclohexane to form a solution in the reaction apparatus. The reaction apparatus can be placed in a nitrogen or argon atmosphere. The desiccant is dried by a molecular sieve, and the catalyst such as an organolithium reagent can be used. Into the reaction device, and then heat the reaction device to a certain temperature level until the total amount of farnesene in the ❿ or the majority of the A is completed. The dilute homopolymer can be settled from the reaction mixture' and in the vacuum oven Drying. A non-limiting example of the polymerization of a farnesene interpolymer in solution is outlined below: a farnesene such as /3_farnesene can be added to a solvent such as cyclohexane. Forming a solution in a reaction apparatus under a nitrogen or argon atmosphere. The dilute solution can be dried by using a desiccant such as a molecular sieve, and prepared in a second reaction apparatus placed in a nitrogen or argon atmosphere:: 10% cyclohexane in styrene solution, and dried under a desiccant such as molecular sieve. After heating to a certain level, styrene can be polymerized with a catalyst such as an organic solvent until all or most of the styrene has been reacted. , the method is dissolved in the two anti-weaving of the ruthenium. The reaction of all or most of the farnesene on the anti-ship side is allowed to complete. Then, the two gas stone coupling agent (for example, at 1, 2 Two of trichloroethane The decyl dichlorowei) is added to the second reaction unit to form a dilute interpolymer. Polyphafarnes The polyfarnesene can be used to prepare polyfarnesene compositions for various purposes. In some implementations The polyfarnesene composition comprises the polyfarnesene of the present invention and the second polymer or at least one additive. In a specific implementation, the polyfarnesene contains a second polymer. In the practice, the polyfarnesene composition does not contain a second polymer. The second polymer can be an ethylene polymer or a polyfarnesene, a non-ethylene polymer or a polyfarnesene or a combination thereof. A non-limiting example of some ethylene polymers and polyfarnesene can be found in Malcolm P. Stevens' Introduction to Polymer Chemistry (0xf〇rd University).

Press '' Third Edition, pp. 17-21 and 167-279 (1999), see the references attached to the present invention. Non-limiting examples of suitable second polymers include polyolefins, polyurethanes, polyesters, polyamides, styrenic polymers, diabase resins, polyacrylates, polydecyl acrylates, or combinations thereof. In a specific implementation, the ratio of the polyfarnesene to the second polymer ranges from about 1:99 to 99:1,1:50 to 50:1,1:25 to 25:1 or 1:10 to 10: 1. In certain embodiments, the second polymer is a polyolefin [eg, polyethylene, polypropylene, ethylene/α-olefin interpolymer, copolymer of ethylene and propylene, and ethylene and vinyl acetate copolymer (EVA)], Polyurethane, polyester, polyamide, styrene polymer (eg polystyrene, poly(acrylonitrile butadiene styrene), poly(styrene butadiene styrene), phenolic resin, polyacrylate Polymethacrylate or a combination thereof. In some embodiments, the second polymer is a polyethylene, polypropylene, polystyrene, vinyl acetate and ethylene copolymer, 54 201026773 poly(acrylonitrile-butadiene) -styrene), poly(styrene-butadiene-styrene) or a combination thereof. It can be combined with farnesene/interpolymer before the second polymer is added to the polyfarnesene composition. In some embodiments, the second polymer can be added directly to the polyfarnesene composition without mixing with the farnesene interpolymer. The polyfarnesene in the polymer composition The weight ratio of the two polymers is 1:99 -99 : 1, 1: 50 -50 : 1, 1 : 25 -25 : 1,1 : 10 -10 : 1,1 : 9 -9 : 1 Ί : 8 -8 : 1 Ί : 7 -7 : 1 Ί : 6 -6 : 1 ' 1 : 5 -5 : 1 Ί : 4 -4 : I 1,1 : 3 -3 : 1,1 : 2 -2 : Bu 3 : 7 -7 : 3 or 2 : 3 -3 : 2. In some implementations, the second aggregation The polyolefin is a polyolefin. Any polyolefin which may be partially or completely compatible with the polyfarnesene may be used. Non-limiting examples of suitable polyolefins include polyethylene, polypropylene, polybutene (such as polybutylene-1). , polypentene-1; polyhexene-1; polyoctene; polydecene-1; poly-3-methylbutene-1; poly-4-methylpentene-1; polyisoprene , polybutadiene, poly-1,5 diene; interpolymers derived from olefins, olefins and other polymers such as polyvinyl chloride, polystyrene, polyurethane interpolymers, and the like, and mixtures thereof. In some embodiments, the polyolefin is a homopolymer such as polyethylene, fluorene polypropylene, polybutene, polypentene-1, poly-3-methylbutene-1, poly-4-methylpentene ——Poly isoprene, polybutadiene, poly-1 '5 diene, polyhexene-1, polyoctene 丨 and polydecene-1 〇 suitable poly Non-limiting examples of olefins include ultra low density polyethylene (ULDPE), linear low density polyethylene (LLDPE), low density polyethylene (LDPE), medium density polyethylene (MDP^, high density polyethylene, high molecular weight) High density polyethylene '(HMW-HDPE), ultra high molecular weight polyethylene (UHMW-P and combinations thereof. Non-limiting examples of polypropylene phosphonium chloride include low density polypropylene (LDPP), high density polypropylene 55 201026773 Alkene (HDPP), refractory hard polypropylene (HMS-ΡΡ), and combinations thereof. In certain embodiments, the second polymer is or contains refractory strength polypropylene (HMS_pp), low density polyethylene (LDPE), or a combination thereof. In certain Beschs, the polyfarnesene compositions disclosed herein comprise at least one additive' to achieve improved and/or lion-tolerant properties, physical, chemical, and/or physical appearance of the polythene-diluted composition. The purpose of mechanical properties. In certain embodiments, the poly-fabric composition does not contain an additive. Any of the valve additions known to those skilled in the art can be used in the polyfarnesene compositions disclosed herein. Examples of suitable secret additives include fillers, graft initiators, tackifiers, slip agents, anti-blocking agents, plasticizers, antioxidants, blowing agents, blowing agent activators (such as zinc oxide, stearic acid) Acid zinc, etc.), UV stabilizer, acid scavenger, (10) or pigment, active adjuvant (such as tri-propyl propyl cyanate), lubricant, anti-fogging agent, glidant, processing aid, extrusion Auxiliaries, coupling agents, cross-linking agents, stabilizing side, testing, surfactants, flame retardants, antistatic agents, or combinations thereof. ^ 总量 The total amount of additives in the total weight of the multi-hybrid composition (4) is greater than 〇, %, _1% _, % _6Q%, αιν·, 1% _ or 1% to 50%. Some of the additives can be found in the "Plasta Additives Handbook" by Zweifd Hans et al., H_r Gar_p, pp., 2005, see the literature attached to the present invention. The composition of the sloped polyfarnesene may also contain an anti-drying agent. In certain implementations, the disclosed polyfarnesene rail complexes may not contain an anti-. Anti- _ can be used to prevent the layer of material produced by the polymerization process from being entangled, especially in the case of storage, production and pressure-and-heating. Any of the secret agents known to the weavers 56 201026773 can be incorporated into the poly-fabric compositions disclosed herein. Non-limiting examples of anti-drying agents include minerals (such as clay, chalk, calcium carbonate), synthetic silicones (such as Syl〇bl〇C® from Grace Davison), and natural quartz purchased from Celite Corporation by SUPER FLOSS® Company), talc (such as OPTIBLOC® from Luzenac), zeolite (such as SIPERNAT® from Degussa), aluminate (such as siLTON® from Mizusawa Industrial Chemicals), limestone (such as CARBOREX®)

Omya), spherical polymer particles (such as EP0STAR® poly(mercaptomethyl methacrylate) particles, purchased from Nippon Shokubai and TOSPEARL®, resin particles purchased from GE Silicones), wax, guanamine (such as erucamide, oleic acid amide, stearin, decyl behenate, bis-stearate, succinate, succinic acid and other anti-slip agents), molecular sieves and their The combination. Mineral particles can create a physical separation between the articles to reduce stickiness, but the release agent moves to the surface of the material to limit surface stickiness. In use, the release agent in the polymer composition may be present in excess of 〇3 wt%, 〇 12 粤 wt/ in the total amount of the polymer composition. 0.001] plus % or 〇 delete _ 〇 5 wt%. Some anti-adhesive agents can be found in the Handbook of Plastic Additives by Hans et al., Hanser Gardner Publicatiss (2001), 5th Edition, Chapter 7, page 585_6, see the accompanying documents of the present invention. The disclosed polyfarnesene composition may also contain a plasticizer. Generally, a plasticizer is a chemical which increases the elasticity and lowers the ratio of the conversion temperature of the polymer. Any plasticizer known to those skilled in the art can be added to the disclosed polylithic composition. Non-limiting examples of plastics include mineral oil, phthalate, adipic acid, and benzoate. Acid, azelaic acid, benzoic acid, gasified paraffin, citric acid, epoxide, ethylene glycol and its steroids, glutamate, hydrocarbon oil, isobutyrate , oleate, penta pent. 57, 201026773 alcohol derivatives, phosphates, phthalates, esters, polybutenes, ricinoleate, fats, fatty acid salts, sulfonamides, triphenyl hexaformate and coke Stupid hexamate, biphenyl derivative, stearin salt, difuryl ester, fluoroplasticizer, paraben, isocyanate adduct, polycyclic aromatic compound, natural product derivative, nitrile , #氧丝增, tar-based products, thioethers and combinations thereof. In use, the release amount of the polymer composition may exceed 〇 15 wt%, 〇 5_1 〇 wt% or 1 _ 5 wt% in the total amount of the polymer composition. Some plasticizers are found in George Wypych's "Handb〇〇k〇fpiasticizers>

For the disclosure of ChemTec Publishing (2004), please refer to the @Documents section of the present invention. In certain embodiments, the polyfarnesene compositions disclosed herein comprise an anti-blocking agent that prevents oxidation of the polymer and organic additives in the polymer composition. Any antioxidant known to those of ordinary skill in the art can be incorporated into the polyfarnesene compositions disclosed herein. Non-limiting examples of suitable antioxidants include aromatic amines or hindered amines such as alkyl diphenylamines, phenylnaphthylamines, alkyl or aryl alkyl substituted phenyl naphthylamines, alkyl p-phenylenediamines, tetraterpenes Alkyl or aralkyl groups such as bisaminodiphenyl hydrazine; phenols, Ο 6 _-tert-butyl-p-guanidine, 1,3,5-trimethyl-2,4,6-tris (3',5 ,-di-tert-butyl-4'-carbylbenzyl)benzene; tetra[(methylene(3,5-di-tert-butyl-4-hydroxyphenyl)]decane (eg IRGan〇xtm of Ciba Geigy, New York) 1〇1〇)); propylene-based, 18- 3,5-di-tert-butyl-4-hydroxystyrene (such as IRGANOXTM 1076 from Ciba Geigy, New York); phosphate and phosphazene; hydroxylamine, Benzofuranone derivatives and combinations thereof. In use, the antioxidant in the polymer composition may exceed wt0/〇, 0.0001-2.5 wt%, 0.001-11 wt〇/0 or 〇 in the total amount of the polymer composition. · 〇〇ι_〇·5 wt%. Some antioxidants can be found in the plastics Additives Handbook by Zweifel Hans et al. 58 201026773

Published by Hanser Gardner Publications (2〇〇ι年), Fifth Edition, Chapter Pages * 1-140, please refer to the literature attached to the present invention. In other embodiments, the polyfarnesene compositions disclosed herein may further comprise a UV stabilizer which prevents or reduces polymer degradation by UV radiation. Any UY stabilizer known to those skilled in the art can be added to the polyfarnesene compositions disclosed herein. Non-limiting examples of suitable UV stabilizers include xylene ketone, benzotriazole, aryl ester, oxalic anilide, acrylate, hydrazine, Φ carbon black, hindered amine, nickel quencher, hindered amine, phenol Antioxidants, metal salts, zinc compounds, and combinations thereof. In use, the UY stabilizer in the polymer composition may exceed 0-5 Wt%, 0.01 _3 wt〇/〇, 0.1-2 wt〇/〇 or o.w wt% in the total amount of the polymer composition. Some uv stabilizers can be found in "piastics" by Zweifel Hans et al.

Handbook published by Hanser Gardner Publications (Cincinnati, 2001)

Ohio), Fifth Edition, Chapter 2, page I4i_426 ‘Reference to the literature attached to the present invention. In a further implementation, the polyfarnesene compositions disclosed herein may also comprise a color former or pigment which alters the macroscopic appearance of the polymer. Any colorant or pigment known to those skilled in the art can be added to the poly-form composition disclosed herein. Non-limiting examples of suitable color formers or pigments include inorganic pigments such as metal oxides (e.g., iron oxide, oxidized words, titanium dioxide, mixed metal oxides, carbon black), organic linings such as sm puzzles, money and monovalent compounds, aromatic Indoleamine, benzimidazolone, B0NA lake, diketopyrazine: Yue compound, diarylamine compound, Wei Shiji diisohydrodiazepine, metal complex, monoazo salt, naphthene, & naphthalene Hope, naphthol lake, perylene, perinones, phthalocyanine, ketone, quinacin, 59 201026773 ketone and 喧 并 二 曱 曱 曱 q q q q And their combinations. In use, the colorant or pigment content of the polymer composition may exceed 0-1 in the total amount of the polymer composition (^ 〇, 0.1_5 rating 1% or 0.25_2 replies. Some colorants may be found in

"Plastics Additives Handbook" Hanser Gardner by Zweifel Hans et al.

Publications (2 〇〇 1), Fifth Edition, Chapter 15, page 813 882, please refer to the literature attached to the present invention. The disclosed polythene compositions may also contain a filler for adjusting the polythene, particularly a filler which adjusts the volume, weight, cost and/or technical properties of the polyfarnesene. Any filler known to those skilled in the art can be added to the polyfarnesene compositions of the present invention. Non-limiting examples of suitable fillers include talc, carbonic acid, chalk, sulfuric acid, dry soil, kaolin, strontium, glass, gas phase dioxide, mica, ash, feldspar, aluminosilicate, tannin Calcium, alumina, hydrated alumina such as aluminum trihydrate, glass microspheres, ceramic microspheres, thermoplastic plastic microspheres, barite, wood flour, glass fiber, carbon fiber, marble cement, cement dust, oxygen tilt, hydroxide Lock, cerium oxide, zinc oxide, barium sulfate, titanium dioxide, titanate, and combinations thereof. In some embodiments, the filler is barium sulphate, talc, carbonated dance, sapphire, glass, fiberglass, oxonium oxide, titanium dioxide, or combinations thereof. In certain embodiments, the filler is talc, carbonic acid, barium sulfate, fiberglass, or a combination thereof. In use, the filler content of the polymer composition may be greater than 0-80 wt%, 016 () wt%, 0.5-40 wt%, (d) let or 1 〇 _4 migration in the total weight of the polymer composition. . Disclosure of some suitable fillers can be found in U.S. Patent 6,103,803 and by Piweis by Zweifel Hans et al.

Additives Handbook, Hanser Gardner Publications, (2001), Fifth Edition, pp. 9-l-948, please refer to the literature attached to the present invention. 60 201026773 . The polyfarnesene composition disclosed herein may also comprise a lubricant. In general, lubricating oils can be used, inter alia, to adjust the rheological properties of the polyfarnesene composition, to improve the surface finish of the molded article, and/or to promote the dispersion of the filler or pigment. Any lubricant known to those skilled in the art can be added to the polyfarnesene compositions of the present invention. Non-limiting examples of suitable lubricating oils include fatty alcohols and their dicarboxylates, fatty acid esters of short chain alcohols, fatty acids, fatty acid guanamines, metal soaps, oligomeric fatty acid esters, long chain alcohol fatty acid vinegars, brown coal briquettes , polyethylene sulphate, polypropylene sulphate, natural and synthetic sarcophagus, fluoropolymer e and combinations thereof. In use, the proportion of lubricant in the polymer composition in the total weight of the polymer composition may be greater than 〇_5 wt%, 〇 M wt% or 〇1_3 research %. The disclosure of some suitable lubricating oils can be found in "Plastics Additives Handbook," by Hanweier Hans et al., "Cansin Gardner Publh ^^, Cincinnati, Ohio", 5th Edition, Chapter 5, pages 511-552, please refer to the present invention. Attached literature. The polyfarnesene compositions disclosed herein may also comprise an antistatic agent. As a general rule, antistatic agents increase the conductivity of the polylithic composition and prevent static buildup. Any antistatic agent known to the skilled artisan can be added to the polyfarnesene composition disclosed in the secret. Non-limiting examples of suitable antistatic agents include conductive fillers (such as carbon black 'metal particles and their scaled particles), linoleic acid esters (10) such as glyceryl monostearate, ethoxylated dadamine, diethanolamine, Ethoxylated alcohols, alkyl amides, hydrocarbons, quaternary ammonium n-based beets, and combinations thereof. The ratio of the antistatic agent content in the polymer composition to the total weight of the polymer composition may be greater than o-5 wt%, aoi_3 wt% or o.W wt%. Some suitable antistatic agents can be found in the description of Zweifd Hans et al., such as "piastics 61 201026773".

Gardner Publicati〇ns (2001, Cincinnati, Ohio) '5th edition, page l 627-646' Please refer to the literature attached to the present invention. The polyfarnesene compositions disclosed herein may also comprise a blowing agent for making a foamed article. The blowing agent may include an inorganic blowing agent 'organic foaming agent, a chemical foaming agent, and combinations thereof' but is not limited to these examples. A description of some of the disclosed blowing agents can be found in "Polymeric Foams And Foam Technology" by Sendijarevic et al.

Hanser Gardner PubliCationS (Cincinnati, Ohio, 2004), 2nd edition, Chapter 18, pp. 5_547, may be referred to the accompanying documents of the present invention. Non-limiting examples of suitable inorganic blowing agents include carbon dioxide, nitrogen, chlorine, water, air, nitrogen, and gas. Non-limiting examples of suitable organic blowing agents include aliphatic hydrocarbons of 6 carbon atoms, fatty alcohols of 1-3 carbon atoms, all and partially dentated 丨4 carbon atom aliphatic hydrocarbons. Non-limiting examples of suitable aliphatic hydrocarbons include methane, ethane, propane, butane, isobutane, n-pentane, isopentane, pentane, and the like. Non-limiting examples of suitable fatty alcohols include methanol, ethanol, n-propanol, isopropanol. Non-limiting examples of suitable wholly and partially halogenated aliphatic hydrocarbons include fluorocarbons, gaseous hydrocarbons, and fluorine vaporized carbon. Non-limiting examples of suitable fluorocarbons include methylplate, perfluoroanthracene, ethylidene, 〇U difluoroethane (HFC-152a), 1,1,1-trifluoro (HFC-143a) 1,1,1,2-tetrafluoroethane (HFC-134a), pentafluoroethane difluoroanthracene, full ethane, 2,2-difluoropropanone, 1,1,1-trifluoro Propane, perfluoropropane, dichloropropane, difluoropropane, perfluorobutane, perfluorocyclobutane. Suitable examples of non-gas hydrocarbons and CFCs include gas methane, dichlorodecane, ethyl chloroform, 1,1,1-trieethane, U-digas _ i _ fluoro Ethylene (HCFC-141b), 1-chloro-1,1 fluoroethane (HCFC-142b), 1,1 - digas _ 2,2,2-tris, fluoroethane (HCFC-123) and 1 - Chloro-1,2,2,2-tetrafluoroethane (HCFC-124). Suitable 62 201026773 Examples of heterogeneous halogenated CFCs include trichloromonomethane (cfc_(1), two

Suitable chemical foaming _ non-limiting examples include azomethine, azobisisobutyric acid

A phenolphthalein, p-toluenesulfonium sulfonium, hydrazine azo, dinitrogenated phthalamide and tridecyltriazine. In some nitrogen, the amine is isobutylated, carbon dioxide or a mixture thereof. The content of the blowing agent in the polymer composition disclosed in the present invention accounts for the farnesene

Grams or 1.0-2.50 moles/kg. The polymethine composition disclosed in the present invention comprises a slip agent. In other implementations, the disclosed polymorphic compositions of the present invention do not include an anti-slip agent. Slip refers to the slidability between the surfaces of the film or between other substrates. The measurement of the slip properties of the film can be carried out by ASTM D 1894, "Static and Kinetic Coefficients of Friction of Plastic Film and Siting". Usually, the slip agent can pass

Any slip agent known to those skilled in the art can be added to the polyfarnesene composition wipes disclosed herein. Examples of increasing __ are limited to carbon atoms, (for example, fenfluramine 'de- _, hard imide and behenic acid lysine); secondary guanamine has a large 63 201026773 about 18-80 carbon atoms (such as alkyl mustard) Acid decylamine, succinic acid amide, methyl erucamide and ethyl erucamide, and secondary-bis-decylamine have about 18-8 Å carbon atoms (eg, ethylene-bis-. stearin) Amines and ethylene-bis-oleic acid amines and combinations thereof. - In some implementations, the slip agent is a primary amine (e.g., stearin and behenyl sulphate) containing a saturated fat of 18 to 4 carbon atoms. In other embodiments, the slip agent is a primary amine having an unsaturated fatty group, wherein the unsaturated fatty group contains at least one carbon-carbon double bond and a carbon atom between 18 and 40 (eg, erucyl erucamide) And oleic acid amide. In a further embodiment, the slip agent is a primary amine having at least 2 carbon atoms. In a further embodiment, the slip agent is erucamide, oleic acid amide, stearylamine, sulphate, ethylene-bis-stearylamine, ethylene-bis-oleic acid guanamine, Stearyl erucamide, behenic acid erucamide or a combination thereof. In one particular implementation, the slip agent is decyl decanoate. In further implementations, 'slip agents are commercially available, such as ATMertmsa (Uniqema, Belgium), ARMOSLIP® (Akz, Nobel P〇lymer Chemicals, USA), KEMAMIDE® (Witco, USA), and CRODAMIDE® (USA) Croda) These brands of slip agents. In use, the slip agent content of the polymer composition may be greater than 〇_3 〇 wt%, 0.0001 1-2 wt% ' 0.001-1 wt%, 0.001-0.5 wt% or 〇 in the total weight of the polymer composition. .05_〇.25 wt%. A description of some slip agents can be found in "piastics Additives" by Zweifel Hans et al.

Handbook, Hanser Gardner Publications, published (2001), 5th edition, Chapter 8, pages 601-608, see the accompanying documents of the present invention. In certain embodiments, the polyfarnesene compositions disclosed herein include a solubilizer. In other embodiments, the polylithic compositions of the present invention are free of solubilizers. In the present invention, any substance which can be added to the elastomer to produce adhesion can be used as a supplement. Some non-limiting examples of additives include natural and processed coffee, glycerin or woven, rosin pentaerythritol vinegar, thinly coated copolymers or terpolymers, multi-alkenyl tree or hydrogenated I! Women's resin, benzene-aged (four) resin or its gasification derivative, aliphatic or lipid jelly or its secret derivative, resin or saki biological, aromatic soil processing of the moon 曰 aliphatic or alicyclic smoke A resin or a hydrogenated derivative thereof or a combination thereof. In other embodiments, the bulking agent has a ring and ball softening point equal to or greater than 60, 70. (:, 75 C 80 C, 85 ° C, 90. (: or 100. (:, the measurement is based on ASTM 28-67, see the literature attached to the present invention. In other implementations, the increasing agent according to ASTM 28_67) The ring and ball softening point is equal to or greater than 8 〇 ° C. In other embodiments, in the polyfarnesene composition disclosed herein, the tackifier content is in the range of 〇lwt % _7 在 of the total weight of the composition. Wt%, 0.1wt.%-60wt.% > lwt.%-50wt.% > 0.1wt.%-40wt.% ' 〇.lwt.%-30wt.%, 〇.lwt.%-20wt.% Or 〇.lwt.%-l〇wt·%. In other embodiments, the tackifier content of the compositions disclosed herein ranges from 1 wt.% to 70 wt.%, 5 wt% of the total weight of the composition. .0/〇-70wt.%, ❿ 10wt.%-70wt·%, 15wt.°/〇-70wt.%, 20wt.%-70wt·%, or 25wt%-70wt.%. Or, the present invention The exposed polyfarnesene composition may comprise petroleum wax materials such as low molecular weight polyethylene or polypropylene, synthetic waxes, polyolefin waxes, beeswax, vegetable waxes, soy waxes, palm waxes, candle waxes or melting points greater than 25 ° C. Ethylene/α-olefin interpolymer. In other implementations, wax is a Low molecular weight polyethylene or polypropylene having a molecular weight of about 400 to 6,000 g/mol. The wax may range from 10% to 50% or 20% to 40% in the total amount of the composition. 65 201026773 Alternatively, the present invention The polyfarnesene composition of the present invention may be partially or fully crosslinked. When a parent is required, the disclosed polylithic composition contains a crosslinker which can be used to crosslink the polyfarnesene composition. , thereby increasing the modulus and rigidity of the polyfarnesene composition compared to others. One advantage of the polyfarnesene composition is that it can be crosslinked in the side chain, rather than like other polymers such as isoprene and butyl. The diene, their cross-linking sites are on the backbone of the polymer, etc. Any cross-linking agent known to those skilled in the art can be added to the polyfarnesene compositions disclosed herein. Illustrative examples include organic peroxides (e.g., leuco peroxides, aromatic peroxides, peroxyesters, peroxylated carbonic acid, biguanide, peroxyl ketones, and cyclic peroxides) and Shi Xi Shao (such as vinyl trimethoxy oxalate, vinyl Triethoxy decane, vinyl tris(2-methoxy) zebra, ethylene triacetate, acetonitrile dimethoxy zeoxime and 3 fluorenyl propylene propylene oxide In the use, the proportion of the crosslinking agent of the polymer composition in the total weight of the polymer composition may be greater than 〇 2 〇 wt%, 01 -15 wt% or 1-10 wt%. A description of some suitable crosslinkers can be found in "Plastics Additives Handbook" by Zweifel Hans et al., Hanser Gardner Publications (2001) '5th Ed., Chapter 14 on page 725-812, see the accompanying documents of the present invention.某些 In some embodiments, the farnesene interpolymer of the present invention comprises a farnesene-modified polymer prepared by copolymerization of one or more farnesene with one or more ethylene monomers. In a particular implementation, the non-modified polymer derived from one or more ethylene monomers can be any known dilute hydrocarbon homopolymer or interpolymer. In a further embodiment, none of the one or more ethylene monomers have an unsaturated side chain capable of reacting with the crosslinking agent. In other implementations, the unmodified 'polymer derived from one or more ethylene monomers can be any known olefin homopolymer or interpolymer. 66 201026773 In a specific implementation, the farnesene content of the disclosed farnesene-modified polymer's total amount of the farnesene-modified polymer is about 1 wt.%-20 wt.%, 1 wt. %-10 wt·%, 1 wt.%-7.5 wt.% ' 1 wt.%-5 wt.% ' 1 wt.%-4 wt.% ' 1 wt.%-3 wt.% or 1 wt. %-2 wt.%. In other embodiments, the one or more monomers of the disclosed dilute-modified polymer comprise from about 80 wt.% to about 99 wt.%, 90 wt.% of the total amount of the farnesene-modified polymer. /〇-99wt.%, 92.5wt.%-99wt·%, 95 wt.%-99 wt.%, % wt.%-99 wt.%, 97 wt.%-99 wt.% or 98 wt.% -99

Wt·%. The crosslinking reaction of the polyfarnesene composition can also be initiated by the radiation method used in any technique, which includes electron beam irradiation, calcium irradiation, sodium irradiation, corona discharge irradiation, with or without a crosslinking catalyst, And ultraviolet radiation, but is not limited to the examples given. The electron beam irradiation method disclosed in U.S. Patent Application No. 1/〇86, 〇57 (Disclosure No. US2002/0132923 A1) and Patent No. 6,8〇3, 〇14 can be used in the practice of the present invention. The preferred method of radiation can be 70 megarads by using high energy, ionizing electrons, ultraviolet light, X-rays, xenon rays, and electrons. The source can be any electron beam generator that operates at a range of approximately 150 kV to 6 MV to meet the desired radiation dose. The voltage can be adjusted to an appropriate level, such as 1 〇〇, 〇〇〇, 3 〇〇, _, 100_0, 2000000, 3, _, 〇〇〇 or __ or higher or lower. Many light, sub-materials H are technically known equipment. Usually, the dose is about 3 mega-la, within the range of -35 recorded, preferably 8-2 〇 rad. In addition, it is easy to carry out the shooting. When the temperature is higher and lower, such as 0. C-60. The radio operation can also be ordered under C. The preferred radiation operation time after molding or manufacturing. This 67 201026773 (4) Use the 仏 ’ '(10) and the 崎 加 加 合 合 应 应 应 应 应 应 应 应 应 应 应 应 应 应 应 应 应 应 应 应. #use. People, can promote the father's association. Any catalyst with this function can sleep with titanium and sputum. Generally, it includes organic tests, acid retardation, and organometallic compounds (organic oleic acid, tin dioctoate dimaleic acid, two Butyl-tin-diacetic acid 'dibutyl. Kick · two-kick octanoic acid, tin acetate, octanoic acid, IJ £ 〇 和 and multi-work _:=:: include:: limit, organic peroxide 2_day, four Pentaerythritol methacrylate, pentamidine, ethylene glycol, dimethyl propyl sulfonate, monopropyl propyl maleic acid, leucovoric acid, over-stress 1 P maleic propyl propyl monopropyl Urine β ', Ben, a tert-butyl peroxide, t-butyl perbenzoic acid, peroxygenated benzene, uncle akisaki, remnant, ❹ 舻:, 5- to 1-butyl peroxide Base) calcined, silk peroxide, tert-butylperethyl hydrazine, oligobutyl sulphate or a combination thereof. The illuminating additive is a versatile (ie, at least two functional) groups, such as Or a compound such as c = o. At least one pre-irradiation additive can be introduced into the method 2 interpolymer by any known method. The fine 'introduction of the face-injection __ method is to contain the disk method. 2 Pre-irradiation of the same or different test resin. Pre-irradiation of the agent: The high density of the material, such as the percentage of the total weight of 25 (the total weight of the total weight) 68 201026773 at least one effective dose The pre-irradiation additive is introduced into the polyfarnesene. It is preferred that the ratio of the at least one pre-irradiation additive introduced into the total weight of the farnesene interpolymer is 〇.〇〇5-5wt% 'better ratio 〇.〇〇5_2.5wt%, the best ratio is 0·015, 1 wt% 〇 In addition to electron beam irradiation, it can also be cross-linked by ultraviolet irradiation. The method includes 'before and during fiber formation. The photoinitiator is mixed with the polymer in a later period of time. The photoinitiator may be mixed with or without the photocrosslinking reagent beforehand, and then the fiber is exposed to a sufficient dose of ultraviolet light to expose the polymer to the polymer. The crosslinking reaction reaches a desired level. In the present invention, the photoinitiator used is an aromatic ketone such as a benzophenone or a monoacetal of 1,2-dione. The main photochemical reaction of monoacetal is hydrazine. 1 bond of the homogenization reaction, resulting in The base and di-alkoxyalkyl groups such α_ cleavage reaction is the reaction type known NorrishI, which is described in the D.Armesto W.Horspool and "Organic Photochemistry: A Comprehensive Treatment," British Ellis

Horwood Limited published in 1992; J. Kopecky's "Organic

Photochemistry: A Visual Approach, VCH Publishers Inc., New York, USA, 1992; NJ Turro et al., in Acc. Chem. Res. (1972 (5): 92) and JT Banks et al., J. Am. Chem. Soc. (1993 (115): 2473) article. The monoacetal synthesis of aromatic 1,2,2-dione, Ar-CO-C(OR)2-Ar, can be found in the U.S. Pharmacopoeia 4,190,602 and USP 4,190,602 and Ger. Offen. 2,337,813. The preferred compound for this reaction grade is 2,2-dimethoxy-2-phenylacetophenone, and C6H5-CO-C(OCH3)2-C6H5 (commercially available from Ciba-Geigy, Inc., trade name Irgacure 651). Other examples of aromatics useful as photoinitiators in the present invention are the compounds Irgacure 184, 369, 819, 907 and Irgacure 2959, both available at 69 201026773

Ciba-Geigy Corporation. In one embodiment of the invention, a photoinitiator is used in conjunction with a photocrosslinking reagent. Two or more polyolefin molecular backbones can be linked as soon as the radicals are generated, and a photocrosslinking reactant which forms a covalent bond with the molecular backbone can be used. The preferred photocrosslinking reagents should be multiplexed reagents' which contain two or more sites which, upon actuation, form a covalent bond with the polyfarnesene backbone composition. Representative photocrosslinking reactants include, but are not limited to, such as polyfunctional ethylene or propylene compounds (e.g., cyanuric SiL-lyl propyl ester, diallyl isocyanurate, pentaerythritol tetramethyl acrylate) Salt, ethyl ethoxide dimercapto acrylate, diallyl maleic acid, di-propyl propyl maleic acid, di- propyl propyl mono-propyl uric acid, etc. The preferred photocrosslinking reagent for use in the present invention It is a compound having a polyfunctional group (ie, at least 2). Particularly preferred photocrosslinking reagents are triallyl cyanurate (TAC) and triallyl isocyanurate (TAIC). It can be used as both an initiator and a photoinitiator and a photocrosslinking reagent. These compounds are characterized by the ability to generate two or more reactants (eg, free radicals, stone olefins, nitrenes, etc.) under ultraviolet light. The 'parallel-step" forms a covalent bond with the two polymer chains. In the present invention, any compound having these two functions can be used, and a representative ruthenium compound includes sulfonium azide. In another embodiment, 'poly' The second cross-linking reaction is carried out in a thin manner, that is, in addition to photocrosslinking In the other way, the parental reaction can be carried out. In this embodiment, the photoinitiator can be used as a non-light (four) reactant such as Wei, or the polymethod can be subjected to electron beam irradiation under a light beam. The implementation of the towel can be transferred to the actual situation. (4) Light·Reagents _ At least i photo-additives, that is, photoinitiators and 70 201026773 photocrosslinking reactants can be introduced into the polyfarnesene by any known technique. The preferred photo-additive can be introduced through a masterbatch concentrate containing polyfarnesene. The preferred masterbatch photo-additive concentration is greater than 10 wt.°/〇, 15 wt.%, 20 wt.% or 25 wt.%. At least one photo-additive is introduced into the polyfarnesene at any effective dose. The preferred amount of 疋' at least 1 photo-additive is 〇.wtwt%-5wt.%, based on the total weight of the poly-dioxide. A more desirable ratio is 〇.〇〇5wt.〇/0_2.5wt·%, and the most desirable ratio is 0.015wt%-lwt.%. 光 Photoinitiators can be added at different stages of the fiber or film manufacturing process. Set photocrosslinking reagent. If the photo additive can withstand the extrusion temperature, polyolefin tree It can be mixed with the additive and then fed into the extruder, for example through a masterbatch. In addition, the additive can be introduced into the extruder before the strip groove is pushed out, but in this case it is important to be effective before extrusion. Mixing the composition. In another method, the smoky additive can be used to extract the polystyrene fiber. Then, the photoinitiator and the industrial process of the additive or the other post-treatment industrial process are carried out by a kiss roll process, spraying, dropping into an additive solution or other post-treatment. / or photocrosslinking agent for the extrusion operation of fiber reinforced. The fiber obtained by the photo additive is treated by continuous or intermittent electromagnetic light injection. It is mixed with polyolefin by using conventional composite equipment such as single and twin screw extruders. (4) Selecting the electromagnetic light power and the irradiation time based on the effective father of the poly-α substance without domain degradation and/or the defects of the three-dimensional structure. Preferred _ visible coffee with 8 suppression 2 description.妓 热 热 热 ( 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四Attentively, the money is on the way, the score is reduced, the better the miscellaneous dimension or the preparation, the fabric, and then the fabric is collected on a spool. 71 201026773 Use UV light to finish shooting J/cm2. The source of illumination can be any radiation intensity of Έ 75ΠΟΠ FX ecology, and its output power is about 50 watts - the leakage watt is "for the required sugar. The power can be reduced to an appropriate level, such as tile, side tile, 6 〇〇〇 瓦 or higher, lower. There are many measurable materials in the processing technology. Qingcai is 3 Qin ^· Lake J/scm ', 100 selects 5 W to carry W. In addition, the illumination can be Conveniently carried out at room temperature, for example 0. (10) X Chen Gao and lower degrees can also be carried out. The higher the temperature, the faster the photocrosslinking process. The preferred radiation operation time after molding or manufacturing. In a preferred embodiment, the polymerization method has been mixed with a photo-additive _iQW_5〇J/cm2 dose. The composition of the composition of the composition of the tears. The composition of the ruthenium-depolymerized composition is a ruthenium-baked interpolymer. Additives, optional second polymers (such as polyethylene and polypropylene) and additives (such as crosslinkers) may be mixed or stirred by methods known to the skilled person. Non-limiting examples of suitable mixing methods include Melt mixing, solvent mixing, extrusion, etc. In some embodiments, the composition of the polyfarnesene composition may be a melt mixing method as mentioned in U.S. Patent No. 4,152,189 to the name of Guerin et al. First, any solvent is heated to 100 〇C-200 °. C or 150 ° C - 175 ° C and remove from the composition at a pressure of 5 torr (667 Pa ^ K) torr (1333 Pa). Then, the desired proportion of the composition is added to the container, The beads are formed by heating the contents of the container and allowing them to be mixed. In other implementations, these compositions are treated using a solvent mixing process. First, the desired foam composition is dissolved in a suitable solvent. The mixture is mixed or stirred. After 72 201026773, the solvent is removed to obtain a foam. Further, in the preparation of the homologous agitating material, a cake-making device having a method of dispersing mixing, mixing or dispersing and separating and separating may be used. Both methods of batch and continuous mixing can be used. Non-limiting examples of batch methods include BRABENDER® mixing equipment (eg BRABENDER pREp center8 purchased in the United States C: W. Brabender Instruments, In c. Company) or BANBURY® internal mixing and grinding rolls (Farrel CGmpany, A_ia, c_μ). The method is not limited to 10 turns and includes single screw fine, twin screw fine, fine, reciprocating single screw extrusion, Single-screw extrusion with a needle. In some implementations, the ruthenium polymer, the second optional polymer, or the bead extrusion can be added to the extrusion H through a feed hopper or feed port. A description of the method of mixing or winning polymers can be found in "P〇iymer Extrusi〇n" by C. Rauwendaal, published in Pubs, pp. 322-334 (1986), with reference to the accompanying documents of the present invention. When the polyfarnesene composition requires one or more additives, the desired amount of the added sound agent can be added to the hexenylene, second polymer or polymer composition one or more times. Furthermore, ' can be added in any order. In some implementations, the additive needs to be mixed with the farnesene interpolymer to form an additive-containing interpolymer and a second polymer. In other implementations, the additive is first added, mixed with the second polymer or lion, and then the second polymer containing the additive is mixed with the dimeric interpolymer. In a further implementation, the farnesene interpolymer is mixed with a second polymer which is then mixed with the polymer. The ridge combination _ ingredients can be mixed in any suitable mixing or semi-injection known to the skilled person (four). The temperature below the temperature of the _ decomposition temperature is again 73. In the joint agent, the composition of the polymer chelate can also be aged to ensure uniform mixing and storage. After the polymer composition has been relatively uniformly mixed, it is subjected to a molding treatment, and then placed under conditions such as heat, pressure, shear, etc., to form a bubble with a sufficient amount of a blowing agent and a crosslinking agent. Gold has a combination of low-density and low-density. The polyfarnesene or polyfarnesene composition has a very wide range of uses. For example, the gauge can be used in a variety of thermoplastic manufacturing processes to produce useful articles, including at least one film in a film article such as a single layer film; in a multilayer film made from a mold, blown film, calendered or pressed adhesive. At least - film; chi products such as blow molding, injection molding, articles, county goods, fiber and textiles or non-woven fabrics. Thermoplastic valve compositions containing the two materials referred to in the present invention include other shifting or merging, sirring, barrier additives, anti-oxidation, stabilizers, colorants, extenders, and plasticizers. In particular, the "fibers" of the various compositions have at least one of the outer layers of the outer layer of one layer. One or more of the fibers of the r 2 _ 露 露 聚 聚 聚 聚 聚 聚 聚 聚 聚 聚 聚 聚 聚 聚 聚 聚 聚 聚 聚 聚 聚 聚 聚 聚 聚 聚 聚 聚 聚Example = two = and monofilament. Any fiber technology, sputum, gel fiber visit: weaving; = dimension, including spinning articles including aging, _, == rod side dimension made of extrusion, daily service, stretching, twisting or rolling The flower's electric wire gauge is fine, and the material is her secret. 'Flip = 201026773 • Plastic u or medium rotomolding process. The polythene-diluted or poly-fabricated composition disclosed in the present invention can also be used to manufacture fibrous articles. For example, the conventional processing technology is a polyolefin processing process well known to the skilled person. The compositional powders (both aqueous and non-aqueous) can also be formed using the presently disclosed poly-fabric sizing compositions. The polyfarnesene or polyfarnesene compositions disclosed in the present disclosure can also be used to make non-foaming. The polymer may be crosslinked by any known method, such as hydrogen peroxide, electron beam, Wei, Wei, or other cross-linking techniques. The polymer can also be modified chemically, such as by grafting (for example, by Malay _ (ΜΑΗ), Wei's butterfly, self-chemical, aminated, ship or other chemical modification methods. Suitable end uses for the above products include elastic films and Fibers such as soft touch goods (toothbrush handles and tool handles), gaskets and frames; dry agents (including heat transfer, pressure sensitive), households = including soles and shoe linings; automotive (10) parts and profiles; foam products (including open ^ and , in closed cells); thermoplastic polymers such as high density polyethylene, polypropylene or other impact modifiers for women's cigarettes; coated fabrics, hoses, pipes, sowing strips, cap liners粘度, viscosity index modifier for floor lubricants (also known as gel point modifiers). The polyfarnesene compositions disclosed herein can also be used to produce articles for a variety of applications, such as automotive, construction, medical, food and beverage, electronics, home appliances, and commercial machines. In some implementations, the 'French scale combination is finer than the manufacture of flip parts or products such as toys, clamps, soft handles, cushion strips, flooring, car mantles, casters, furniture and electrical pads, labels, seals. , static and dynamic sealing rings, + car doors, buffer belts, grille components, rocking plates, hoses, linings, office supplies, two liners, diaphragms, tubes, covers, plugs, punches, delivery systems, mill appliances , shoes, shoes 75 201026773 Leather and soles. In certain embodiments, the polyfarnesene compositions disclosed herein are used to prepare wedge-shaped articles, such as by extrusion of known polymeric foams (e.g., extruded sheets and profiles). , sheet and foam; forming (eg injection molding, rotational molding and blow molding); spinning, blown film and tungsten film treatment. Generally, weaving pressure refers to continuously pushing a polymer through a high temperature and high pressure region, causing it to melt, compress, and finally pass through a casting tank. The extruder can be a single screw squeeze, a multi-screw squeeze (four), a collar machine or a press. The mold may be a diaphragm mold, a blown film mold, a mold plate, a sleeve mold, a tube mold or a profile mold. The bribe of the (four) compound can be found in c Rauwendaal @ % "PolymerExtrusion" published by HanserPublishers (1986); and M.J.

Stevens's "Extruder Principals and 〇peration" EllsevierAppUed

Published by Sciencepublishers (1985), please refer to the references attached to the present invention. Zhuang Plastic is also widely used in the manufacture of plastic parts for many different applications. Generally, the process of plastic molding refers to a process in which a polymer is melted at a high pressure and injected into a mold to form a desired shape to form a desired shape and size. The mold can be made of metal such as steel and aluminum. A description of the injection molding of polymers can be found in Beaum〇nt's article "Succe Editor Injection Molding: process, Design, and Simulati〇n" USA H_r

Published by Gardner Publications (2002), please refer to the references attached to the present invention. The molding is usually carried out by melting a polymer, and the introduction mold is formed into a desired shape by reverse molding to form a part of a desired shape and size. The mold can be a pressureless or pressure sensitive mold. A description of the mold of the polymer can be found in "An Introduction to Plastics" by Hans_Ge〇rg, published by Wiiey_VCH, Germany, page 16M65. (2003) 'Reference to the literature attached to the present invention. 76 201026773 • Rotational molding is commonly used to produce hollow plastic products. Through post-processing operations, complex components can be efficiently fabricated like other types of casting and extrusion processes. Unlike other processing methods, heating, refining, forming, and cooling in the hybrid process are all performed after the polymer is placed in the mold, so there is no external pressure during the forming process. A description of the rotomolding of the image can be found in GlennBean's Rotati〇nalM〇iding:

Design, Materials & Processing, & Hanser Gardner, (cindnnati, Ohio, 1998), with reference to the literature attached to the present invention. 10 Blow molding can be used to make plastic hollow containers. The process involves the softening of the polymer placed on the health tool h, when the gas bar material hits the inflator, and the bond solidifies into a product by cooling. In general, there are three methods of blow molding: extrusion blow molding, injection blow molding, and stretch blow molding. Injection blow molding can be used for polymers that cannot be extruded. Pull-blowing can be used for crystals that are difficult to blow and crystallizable polymers such as polypropylene crystals. The blow molding of polymers can be found in the description of Norman C. Lee, "Blow molding technology (Understanding B1〇w

Molding), Hanser Gardner Publicati (10), published (U.S. 〇hi〇, 2〇〇〇), with reference to the accompanying documents of the present invention. The poly-farnesene composition of the present invention can be used as a spinner or a binder. Can be used to make any item that requires or contains hot melt adhesive or pressure sensitive adhesive. Non-limiting examples of suitable articles include paper products, packaging materials, wood panels, kitchen countertops, vehicles, labels, disposable diapers, hospital sputum, feminine hygiene napkins, surgical drapes, tapes, cartons, trays, medical equipment, and bandages. . In a further implementation, the adhesive group is used in tapes, cartons, trays, medical equipment and bandages. In certain Beschs, the compositions disclosed herein are useful as hot melts. Such hot mix compositions are useful in the industry, including packaging, particularly for low temperature applications such as dairy or cold rolls, 77 201026773 food packaging, and in disposable sanitary consumer articles such as diapers, feminine care pads, and napkins. Other suitable applications include bookbinding, woodworking, and labels. Some hot melt adhesives describe the "Adhesion and Adhesives Technology, Manufacture and Applications" by AVP 〇cius, and the Noyes Data Corp publication sees the references attached to the present invention. The composition disclosed herein can be used as a pSA. Such a pSA gel composition can be used as a (four) sheet product (e.g., ornament, reflector, and _), a sticker, and a magnetic ν substrate. It can be any suitable material, depending on the desired route of use. In other implementations, the substrate comprises a non-woven fabric, paper, polymeric film (eg polypropylene (eg biaxially oriented polypropylene (BOPP)), poly Ethylene, polyurea or polyester (eg polyester (PET)) or factory piping (eg bismuth steel pipe). Some descriptions of pSAs can be found in human V.

Pocius article "Berding and Adhesive Technology (Adhesi〇n _

Technology), Hanser Gardner Publications, (2002), 2nd ed., 9th eve, pp. 238-259; and Istvan Benedek, "Technology of Pressure-Sensitive Adhesives and ❹"

Products) CRC it} version (2 deleted) 'Please refer to the reference attached to the present invention.

In other implementations, the composition can also be used to make tape. For example, psA or gel coat compositions are at least suitable for the production of one side of tape. The dry composition can be subjected to a crosslinking reaction to further increase its shear strength. Any suitable crosslinking method (9) such as exposure to ultraviolet or electron beam radiation or a crosslinking agent additive (e.g., a secret and alkane curing agent) can be used. 78 201026773 • The adhesive composition disclosed in the present invention may be applied to a desired substrate or attached by any known process, particularly in conventionally manufactured tapes, cartons, trays, medical equipment pastes (4) Turn it over. In other embodiments, the ageing compound can be applied through the nozzle or nozzle portion of the associated equipment. In addition to other conventional forms, the adhesive composition can also be used as a fine grain, a spot or a spray coating. In certain embodiments, the dry binder composition can be applied by melt extrusion techniques. Regarding the application of the dry composition, continuous or batchwise mode. _ should be _ ❹ 为 为 为 - - 个 个 个 个 个 个 个 个 个 个 个 个 个 个 个 个 个 个 个 个 个 个 个 个 个 个 个 个 个 个 个 个 个 个 个 个 个 个 个The method of continuous forming involves withdrawing the glue-off composition from a heated film mold and subsequently contacting the drawn composition with a moving plastic mesh or other suitable substrate. In other implementations, the dry binder composition can be used as a coating in a solvent process. For example, the varnish composition can be applied by knife coating, roll coating, gravure coating, bar coating, curtain coating, air knife coating, and the like. The applied solvent-type dry agent is dried to remove the solvent. The preferred method is that the application of the solvent-type dry composition is easy to heat up, for example, to be supplied in a box to accelerate drying. In other implementations, the touch is fined as a hot leg sensitive adhesive. - A description of some of the pressure sensitive adhesives can be found in "Application Technology of Pressure Sensitive Adhesives and Their Products, iTeehnology 〇mes__Sensitive Adhesives - pr〇ducts" by IS_Benedek> Crc Publishing (2008), Chapter 3, please refer to the attached References. In some of the real money 'compositions (10) rubber paste or touch secret agent ... some rubber glue or touch-drying agent can be found in Av. p〇cius "dry and dry technology" Adhesion and Adhesives Technol〇gy), Hanser Gardner 79 201026773

Publications, 2nd edition, with attached references. Chapter 9, pages 259-265 (2002), please refer to the present invention. The following example (10) is a real scale case, but it is less than the content proposed by this judgment. Unless otherwise indicated, all units and percentages are in weight ^. All values are approximate. It should be recognized that while the scope of the invention described herein is not limited to the scope of the invention, the scope of the invention described in the & In each of the examples, the details of the specific description should not be considered as a must. x County body example of the starting material purification method is rare, including hydrocarbon non-pure substances such as ginger, sweet myrrh, dimethoate epoxide, farnesene isomer, E, E farnesol , keratin, ergosterol and some dimers. The fine ring is burned under nitrogen to remove moisture and stored with a desiccant. Shame Scanning Thermal Method The TA Q200 Differential Scanning Calorimeter was used to determine the glass transition temperature (Tg) of the disclosed polymer samples. 5mg# is placed in _. The σσ mass of the blank control steel and the sample ασ steel was maintained within ± 0.01 mg. The sample scan temperature is approximately from about 0 C to about 75 C and the scan rate is 1 〇〇 c/min. Tg can be identified during the transitional phase of the heat flow. The transition midpoint value is considered to be 1 of the sample. Gel permeation Xin._. Gel permeation chromatography (GPC) is used to determine the molecular weight and degree of polymerization of the polymer sample. Waters 2414 Refractive Detector and Waters 1515 Constant Solvent Composition High Performance Liquidus 80 201026773 . Chromatography (®LC®-use. HPLC gradient tetranitrogenate as solvent. Gel permeation chromatography collects the fractional value of the degree of polymerization distribution. The molecular weight of a sample is generally recorded as 'average molecular weight value (_ or the weight of the average molecular weight (Mw). When the heavy (four) value of the degree of polymerization characteristic of each peak is masked, the peak molecular weight (Mp) is included. The thermogravimetric analysis uses the thermogravimetric analysis (TGA) to determine the degradation temperature of the sample. The 2〇mg sample is placed in the weigh and the amount of money. The balance is in the human domain. The balance of the simple seam. The sample is heated from room temperature to 580. °C, heating rate is 1〇 minutes. When the weight loss of the sample is 1% and 5%, the corresponding temperature is recorded separately. UV-Vis spectrometer is used to monitor the reaction process. The consumption of the body was continued until the entire monomer was consumed. The Shimadzu UV^SOUVM/is was used as a photometer. Five measurements were made with an empty quartz tube to calculate the average of the measured background. Pumping Take a special sample and place it in a square quartz tube. The distance between the samples is 1 cm. The absorbance of the sample is proportional to the monomer concentration. The UY-Vis spectrometer monitors the reaction process and is characterized by the absorption of decadiene. The peak value is 230 nm. The tensile strength of the tensile strength sample is measured using an INSTR〇Nti^l tensile tester. The sample is cast into a thin film and cut to the appropriate size. After the measurement, the thickness and width of the sample are measured. The gauge length is 2_54cm and the crosshead speed is 25 mm/min. Lap test 81 201026773 The lap joint is on the test sample _ compliant f. _ mixture combines the two substrates together. Then 'cut the dopant to open Substrate. There are three types of lap joints. When the failure occurs, the substrate is called the substrate failure. When the dry agent is removed from the knife, it is called the failure. When the interface between the components fails, it is called adhesive failure. Use INSTRO, tensile tester to check the force of failure. On the substrate, the size of the W is the same, the crosshead rate is 25 _ minutes. Piece. Before connecting, use B. Cleaner Ming. 4 and 13C nuclear magnetic; j# b and 13c NMR are used to verify the chemical microstructure of the sample. Varian ❹

A Me fine y 300 MHz NMR spectrometer was used for the measurement. Gas chloroform is used as a solvent. Multiple measurements were repeated to obtain spectral values. 105,000 ^ 1,4 ^ n-butyl clock (1.85 Χ 10.3 mol, purchased from Acros, Shichi (10), USA) was added to the reactor as a reaction initiator, and then the reaction vessel was heated at 5 〇%. Hours, until all f-farnesene is consumed, monitor the reaction with a spectrometer. ❹ Do not use 1% ethanol and t-butyl catechol ( purchased from Sigma_Aldrich, don't

Louis, MO) The compound of Example 1 was precipitated from the reaction mixture. 6 (vacuum under vacuum for 2 hours, after which the compound of Example 1 was placed under vacuum for 16 hours. Then, the product of Example 1 was collected and bought as 89.83 g (yield 97%). The refrigerator was stored to prevent the occurrence of the test before the test. The reaction was carried out by UV-Vis spectrometer, and the disappearance state of the bed of farnesene was observed. The synthesis process of Example 1 can be monitored. Figure 1 shows the case 1 and the method of UV-visible light 82 201026773 (UV- The UV-Vis ultraviolet spectrum of Vis in Figure 1 shows the characteristic absorption peak of /3-farnesene at 230 nm, but the example 1 shown in Figure 1 lacks the UV-Vis ultraviolet spectrum/3-method of 230-nm. The peak of absorption was determined. The molecular weight and degree of polymerization of Example 1 were determined by gel permeation chromatography (GPC). Fig. 2 shows the GPC curve of Example 1. The contents shown in Table 1 are the number average molecular weight (Μη) and weight of Example 1. Average molecular weight (Mw), peak molecular weight (Mp), z average molecular weight (Mz), z+1 average molecular weight (Mz+1), Mw/Mn (ie, degree of polymerization distribution), ]\^/]\^ and ❿ Mz+i/Mw 〇Mn, Mw, Mz, Mz+1, Mp and the definition of degree of polymerization can be found in "TechnicalBulletinTB021" Article "MW mean the definition of its sub

Molecular Weight Distribution and Definitions of MW

Averages) published by Polymer Laboratories, see attached literature. Some useful support materials can be found in "Introduction to Polymer Chemistry" by Malcolm P. Stevens (〇xford University Press, Third Edition, pp. 35-58 (1999). See the accompanying reference of the present invention. Calculation Example 1 The number of farnesene units is about 490. Table 1 Property Example 1 Mn 104,838 g/mol Mw 147,463 g/mol Mp 144,216 g/mol Mz 207,084 g/mol Μζ+ι 314,887 g/mol Polymerization degree distribution 1.406588 ' Mz/Mw 1.404311 83 201026773 _J^/1VLw 2.135360 - X and 76.77 ppm 'both peaks associated with atmospheric chloroform for collecting i3C NMR spectra. The characteristic peak of Example 1 is 139.05 ppm. Figure 4 shows the 1H nuclear magnetic resonance spectrum of Example 1. Peaks at 4.85 ppm and 4.81 ppm, both with 3,4_microstructure phase_peak. Peaks at 5 17 ah 5 16 _, 5 14 ppm and 5.13 ppm 'both are related to microstructure and 3,4 microstructures The peak value of the peak area according to Fig. 4 is exemplified by the fact that approximately 12% of the dilute units are found to have a μ _ microstructure. ❹ Figure 5 shows the DSC curve of Example 1. The DSC is used to determine the fresh characteristics of the example! -76 °C. No other thermal detection values were _175 τ, _75 τ. Example 1 Thermogravimetric Analysis (TGA) curve determined in air. The decomposition temperature of Example 1 was determined by tga. Example 1 The temperature at 1% weight loss in air was 2i (rc, 5% by weight in air) 3〇7. Figure 7 shows the TGA curve measured in Example 1. Nitrogen. The temperature at which 1% is reduced by weight in nitrogen is 3G7°C, and the temperature at 5% by weight in nitrogen is 339<> c. It is observed that Example 1 has a dryness. Figure 8 shows the results of the lap test of Example 1. The dryness of the sample of Example 1 was determined by the test. The energy of the dot compound of Example 1 can be seen as (8) gamma 2, and the peak The pressure is about 314 N/m2. j^! L2Mn_^_245,000 of 1. 4 polymerization method. Example 2 is 5,000η is 245,000 g/mol of 1,4 polyfarnesene, except with sec-butyl lithium. In addition to the agent, the procedure of Example 2 was followed by a procedure similar to that of Example 1. The net weight of Example 2 was 83 59 g (production rate: 71.4%). Since an aliquot of the product was used to monitor the progress of the reaction, the yield was low. 84 201026773 The molecular weight and degree of polymerization distribution of Example 2 were determined by gel permeation chromatography (GPC). Figure 9 shows the GPC curve of Example 2. Table 2 shows the distribution of Mn, Mw, %, and m. , The magnitude of each side Mz / Mw, and Mz + 1 / Mw of. Calculate the number of units in Example 2, with a value of approximately 2000. Since the molecular weight of Example 2 is large, the winding time and the relaxation time are longer than those of the example. Table 2 lit ~ Example 2 - Mn " 1 244,747 g/mol Mw 457,340 g/mol~—- Mp 501,220 g/mol~~~-- Mz 768,187 g/mol~~ - Μ_ζ+ι '1,132,362 g/mol ~~' Degree of polymerization distribution 1.886622' mz/mw ~~ 1.679684 " Mz+i/Mw 2.475971 ~'~~

Tg is -76 °C. Figure 11 shows the tensile test results of Example 2. The tensile force of Example 2 was measured by a lap test. It was observed that Example 2 was characterized by softness, viscosity, and rapid formation. As shown in Figure η, the elongational extreme value of Example 2 reached 6% of the maximum tensile force of 19 batches. The modulus of Example 2 was 4.6 kpsi. Example 2 was continuously prepared as a 40% stretched product.聚法娇娇85 201026773 In addition to n-butyl lithium (1.71xl 〇-3 mol) added to N, N, N, N, - tetramethylethylenediamine (TMEDA, 1.71xl0·3 mol, speaking Example 3 was synthesized by following the procedure similar to that of Example 1 by Sigma-Aldrich, St. Louis (USA). The net weight of Example 3 was 82.72 g (yield 97%). The molecular weight and degree of polymerization of Example 3 were determined by gel permeation chromatography (GPC). Figure 12 shows the GPC curve of Example 3. The two peaks of Fig. 12 suggest two components of Example 3 having significantly different qualities. Table 3 shows the respective measured values of Mn, Mw, Mz, Mz+1, degree of polymerization distribution, Mz/Mw, and Mz+1/Mw of Example 3. The % of the first peak of the calculation example 12 was about 97, 165 § / 111 141 141 of the second peak of the calculation example 12 was about 46, 582 § / 111 〇 1. The number of farnesene units in Example 3 was approximately 24 〇. Table 3 Properties Example 3 Mn 45,818 g/mol Mw 47,644 g/mol Mz 49,134 g/mol 50,527 g/mol Polymerization degree #性---- 1.039844 mz/mw 1.031269 Mz+1/Mw 1.060509 and 76.77 mouth 1) 111' is a peak associated with the ruthenium chloroform of the collection 13(:;]^]^ spectrum. The characteristic peak of Fig. 13'., the exemplified example 1 has a regular microstructure. ❹ 86 201026773 14 shows the 1H NMR spectrum of Example 3. The bee values are 4.85 ppm and 4.S1 ppm, both of which are the microstructure peaks of Example 3. The peaks are at S.nppm'Wppn^.Mppm and 5.13ppm' both with L4-micro Structure and peaks related to 3,4_microstructures. According to the area under the peak of the graph μ, the approximate method of the female unit in Example 3 was found to have a 1.4-microstructure. Figure 15 shows the DSC curve of Example 3. Example 3 was determined by DSC. The thermal characteristics of Example 3. The Tg of Example 3 is -76 ° C. No other thermal detection values are _175 π, _75 τ. Figure 16 shows the thermogravimetric analysis (TGA) curve measured in air. It is true that the decomposition temperature of Example 3 is as follows: Example 1 has a temperature of 191 in air and a temperature of 191, and a temperature of 5% in air is 265 ° C. Example 3 is a viscous liquid. Figure 17 shows the results of the lap test of Example 3. The adhesion of Example 3 was determined by a lap test. The energy of the adhesive of Example 3 can be found as 丨2,9 〇〇J/m2. 'And the peak pressure is about 43〇N/m2. The soil-polystyrene-1,4-polymer method-polyphenyl λ is welded with an argon-dried reaction bottle with three narrow necks, adding 12%/ ?_法? • Dilute preheating / gluten-free solution of the solution. Take a second argon-dried reaction bottle with three necks and force a solution of cyclohexane in a mixture containing 20.65 g of 10% styrene. - Butyl clock (6 88 χι〇_4 mol) was added to the styrene solution in the reactor as a reaction initiator, and then the reaction vessel was heated at 50 ° C for 16 hours ' until all /5-farnesene was consumed At the end, the reaction was monitored by Gpc. Then, 161.8 g of the β-fabric solution (i.e., 19.61 g/3-method) was transferred to a reaction apparatus under nitrogen. The reaction was allowed to proceed until the end of 7 hours. Gpc monitors the reaction. A three-part dioxane coupling agent, purchased from Acros, Morris Plains (USA), is added to the reactor, thus obtaining a [^(^ molar ratio) of the reactant. 1 · 2 'Enjoy the reaction time of the reaction mixture until the completion time' at this time, the color changes from 87 201026773 to yellow. The compound of Example 4 is precipitated from the reaction mixture with a 1 〇 / 0 t-butyl catechol ethanol solution. Come down. 60. 〇: Vacuum drying was carried out for 2 hours, after which the compound of Example 4 was allowed to stand under vacuum for 16 hours. Then, the product of Example 4 was collected in an amount of 3915 g (yield 97%) in a refrigerator to prevent cross-linking reaction from occurring before the test.

Figure 18 shows the GpC curve of polystyrene. Gpc monitors the synthetic reaction steps of polystyrene. The two peaks in Figure 18 suggest that the polyphenylene (10) produced has two components of significantly different quality. Table 4 shows the respective measured values of polyphenylene-n, Mw, Mz, Mz+1, degree of polymerization distribution, Mz/Mw, and Mz+1/Mw. The first peak of Example 18 乂1) is approximately 59,596 §/_. The second peak value of Example 20, _1) is approximately 28,619 curries. Table 4

Polystyrene 28,396 g/mol 29,174 g/mol Μζ+1 degree of polymerization 29,895 g/mol 30,598 g/mol 1.027385

22/μ, Mz+i/Mw 1.024739 1.048810, formed H ethylene as a reaction initiator, triggering the polymerization of 卩_farnesene to form polystyrene·1,4_poly method (four) two iron segments . Figure 19 shows the synthesis reaction step of the dinuclear copolymer '曲' line GPCl to measure the diblock copolymer. The two-stage copolymers produced by the two peaks in Fig. 19 have the same components of good quality. Table 5 is not - H %, Μ:, Μζ + ι of the block filaments, degree of polymerization distribution, 88 201026773

Mz/Mw and individual measurements of Mz+1/Mw. Example 19 is the first peak Mp corresponding to polystyrene-1,4-poly*farnesene-polystyrene, which is about 141,775 g/mol. Example 19 corresponds to the second peak Mp of the diblock copolymer, which is about 63,023 g/mol. The molecular weight of 1.4-polyfarnesene in the diblock copolymer is about 35,000 g/mo. Figure 19 is the third peak Mp corresponding to polystyrene, about 29,799 g/mo. 1,4-polyfarnesene two-stage copolymer Mn 29,434 g/mol Mw 30,345 g/mol Mp-29,799 g/mol Mz 31,172 g/mol Μζ+ι Polymerization degree distribution 31,936 g/mol 1.030949 ^ mz/mw "1.027264 - ~ Mz+1/Mw 1.052449 The polystyrene 1,4-polyfarnesene diblock copolymer was further polymerized to form Example 4. Figure ❿ ❿ mz+i/Mw 1.052449 The polystyrene 1,4-polyfarnesene diblock copolymer was further polymerized to form Example 4. Figure 2A shows the GPC curve of Example 4. The molecular weight and degree of polymerization of Example 4 were determined by gel permeation chromatography (Gpc). The three peaks of Figure 20 suggest that the resulting coupled product has three distinctly distinct components. Table 6 shows the respective measured values of Mn, Mw, %, MW, polymerization degree, Mz/Mw, and Mz+1/Mw of the conjugate. Figure 2A shows that the first peak Mp' corresponding to Example 4 is about 138, 8 〇 2 g/mol. Example 4 is the obtained 10% coupling product. The unit number value of the ☆ olefin monomer of Calculation Example 4 was about 3 Å. Example 2 is the second peak Mp corresponding to poly 89 201026773 styrene-1.4-polyfarnesene diblock copolymer, which is about 63,691 g/mol. Figure 20 is the third peak % corresponding to polystyrene, about 29,368 g/mol. Table 6 Properties Example 4 H;~~~~ 138,240 g/mol 142,147 g/mol 146,636 g/mol M-z+l 151,848 g/mol Polymerization degree distribution"1.028264 ~ m2/mw T〇3l576 ~~ Mz+i/Mw SS Two ρ*λ:.Ι/Ιαζ_13 〜1,, 1.068242 -...一-外,Μ 〇曰-峰 The peak value of Ρ 瓜 〇 〇 〇 υ υ ppm is the peak associated with the collection of 13C NMR spectra of chloroform. The other peaks shown in Figure 21 are related to 1,4-polyfarnesene and polystyrene. Figure 21 shows that the characteristic peak of Bu___ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _

Q Figure 22 shows the 1st magnetic resonance spectrum of Example 4. Peaks are at 4.85 ppm and 4_81 ppm, both peaks associated with 3,4_microstructures. At 5 1〇, 5 12 Peng, 5 i4_ have peak values associated with 1,4-microstructures and 3,4-microstructures. According to the peak product of Figure 22, in Example 4, about 3% of the farnesene units were found to have 3,4_microstructures. Figure 23 shows the DSC curve of Example 4. The thermal properties of Example 4 were determined by Dsc. Example 聚 Polyfarnesene. Example * in the polystyrene tons. No other thermal tests were found at -175 °C, -75 °C. Eight 90 201026773 • ® 24 V V 4 air towel residual thermal weight loss analysis (TGA) curve. The decomposition temperature of Example 4 was confirmed by TGA. The temperature at which the weight loss in Example 1 was 3 〇 7 was observed. Oh, the temperature at 5% of the weight loss in air is 333 °C. Figure 25 shows the results of the tensile test of Example 4. The tensile force of Example 4 was measured by a lap test. Example 4 has a rigid character, but it can also be generated. As shown in Fig. 25, the elongation fracture value of Example 4 was 425% of the maximum tensile force of 152 psi. The modulus of Example 4 was 31.9 kpsi. The 330% tensile pressure value of Example 4 was 33.4 psi. It was observed that Example 4 was sticky. Figure 26 shows the results of the lap test of Example 4 (since a bond failure occurred). The energy of the adhesive of Example 4 was found to be 2,928, 〇〇〇 j/m 2 and the peak pressure was about 134,000 N/m 2 . —^ This Ethylene-3.4-Polymer--------------------------------------- A argon-dried three-necked reaction flask was added to a cyclohexane solution containing 12% β-farnesene preheated solution. A second argon-dried three-necked reaction vial was added and a cyclohexane solution containing 10% styrene was added. Then, 141 g of a styrene solution (i.e., 14.82 g of styrene) was transferred to a reaction apparatus under argon. n-Butyllithium (5.84x10 4 mol) and TMED A (5.02X10" 4 mol) were added to the reactor as reaction initiators' and the reaction vessel was heated at 50 ° C for 16 hours until all /3-farnesene After consumption, the reaction was monitored by GPC. Then, 143.07 g of f-farnesene solution (i.e., 15.74 g of /5-farnesene) was transferred to a reaction apparatus under argon. The reaction was allowed to proceed until the end of 16 hours, and the reaction was monitored by GPC. A three aliquot of the dichlorosilane coupling agent was added to the reactor to give a molar ratio of Li to C1 of 1:2. Allowing the reaction mixture to proceed to completion time' then the display color changes from yellow to clear. The compound of Example 5 was precipitated from the reaction mixture with a 1% t-butyl-catechin-ethanol solution. Vacuum drying at 60 °C for 2 hours 91 201026773 The compound of Example 5 was placed under vacuum for 16 hours. Then, the product i of the collection example $ was 28.75 g (yield 96%) and stored under refrigeration to prevent the crosslinking reaction from occurring before the test.

Figure 27 shows the Gpc curve for polystyrene. Gpc monitors the synthetic reaction steps of polystyrene. The two peaks in Figure 27 suggest that the resulting polystyrene has two distinctly distinct components. Table 7 shows the respective measured values of Mn, Mw, Mz, Mz+1 'degree of polymerization distribution, Mz/Mw, and Mz+1/Mw of polystyrene. The first peak of Example 27 is 1), which is about 65,57 (^/_. The second peak of Example 27) is about 32,122 curry][. Table 7

Lit ~- polystyrene Mn 27,915 g/mol ^ ~~- 30,898 g/mol Mz ' 32,608 g/mol Μζ+ι 33,819 g/mol Polymerization degree distribution 1.106849 1.055361 Mz+i/JVLw 1.094557 Polystyrene formed as The reaction initiator initiates polymerization of farnesene to form a polystyrene-3.4-polyfarnesene diblock copolymer. Figure 28 shows the GPC curve of the diblock copolymer. GPC monitors the synthesis reaction step of the diblock copolymer. The two peaks of Figure 28 suggest that the resulting diblock copolymer has two distinctly distinct components. Table 8 shows the respective measured values of ^, Mw, %, Μζ+ι, degree of polymerization distribution, Mz/Mw, and M2+1/Mw of the diblock copolymer. Example 28 is the first peak Mp corresponding to polystyrene_3·4-poly 92 201026773 'de-baked-polystyrene, about 174,052 g/mol. Example 28 is the second peak % corresponding to the copolymer of the first stage, which is about 86,636 g/m 〇1. The molecular weight of 3,4-polyfarnesene in the diblock copolymer is about 54, which is the second peak gamma corresponding to polystyrene, which is about 33,955 g/mo.

Polystyrene-3.4-polyfarnesene diblock copolymer Mn — 27,801 g/mol Mw '~ 31,379 g/mol Mz ~~ 33,539 g/mol ^z+l 35,033 g/mol Polymerization degree distribution 1.128697 mz /mw 1.068833 Mz+l/Mw 1.116447 ^Segment total (four) further step formation

Figure 29 shows the GPC curve for Example 5. The molecular weight of Example 5 and the degree of cleavage of the 5 degree were determined by gel permeation chromatography (Gpc). The three peaks of Figure 29 suggest that the resulting coupled product has three distinctly distinct components. Table 5 shows the respective measured values of Mn, Mw, Mz, Mz+1, degree of polymerization, and Mz/Mw of Example 9. Figure 29 is the first peak Mp corresponding to Example 5, which is about 148,931 g/mol. Example 5 is the obtained 33% coupling product. The number of units of the dilute monomer in Example 5 was calculated to be about 3 Å. The peak value of the block in Example 5 is about 32,000-1〇8, 〇〇〇_32,0〇(^/]11〇, and Example 29 corresponds to polystyrene 93 201026773 -3, 4-polymerization method. The second peak % of the decene diblock copolymer is about 81,424 curries 1. Figure 29 is the third peak Mp corresponding to polystyrene, which is about 32,819 curries 1. Table 9 Properties ~~ ~~ Example 4 Mn 28,179 g/mol Mw 30,815 g/mol Mz 32,590 g/mol 33,905 g/mol Polymerization degree distribution 1.093554 — 1.057606 M^Mw ~ .ΓΤ—^ 1.100250 and 76.87 ppm, both collected and collected spectrum The peaks of Xenon are related to the peaks. The other peaks in Fig. 3 are related to polyphenylene (IV). _3嶋 Example} The characteristic peak of 4 is at 139.05 ppm 'Prompt Example 5 has a rule microstructure.

Ppm

Figure 31 shows the 4-nuclear magnetic resonance spectrum of Example 5. The peaks are at 4851)]?111 and 4.81) 111, both peaks associated with 3,4-microstructures. In (3) drunk, the peak of 5 13 ppm is the peak associated with 1,4-microstructure and 3,4-microstructure. According to the area under the peak of Figure 31, about 5% of the farnesene units of Example 5 were found to have a 1.4-microstructure. Figure 32 shows the DSC curve of Example 5. The thermal characteristics of Example 5 were determined by DSC. In Example 5, the three polyfarnesene's were _72 〇c. In Example 5, the polystyrene 1 was 94. No other thermal tests were found at -175 °C, -75 °C. 94 201026773 . Figure 33 shows the thermogravimetric analysis (TGA) curve measured in Example 5 air. The decomposition temperature of Example 5 was determined by TGA. Example 5 The temperature at which the weight was reduced by 1% in air was 24 Torr, and the temperature at which 5% weight loss in air was 327 °C. Figure 34 shows the results of the tensile test of Example 5. The tensile force of Example 5 was measured by a lap test. Example 5 has a rigid character, but it can also be generated. As shown in Fig. 34, the elongation fracture value of Example 5 was 175% of the maximum tensile force of 768 psi. The modulus of Example 5 was 39,5 kpsi. Example 5 was further purified by repeated extraction with n-hexane four times. Figure 35 shows the GPC curve after purification of hydrazine in Example 5. GPC evaluated the case of extracting Example 5 from the coupling product. After the extraction, the first peak shown in Fig. 35 indicates that the extraction product of Example 5 was increased by 6%. The polystyrene-3,4-polyfarnesene diblock copolymer shown in the figure is reduced to 3% by weight of the extracted product. The second peak shown in Figure % indicates that the polystyrene is reduced to the extracted product. 'Show the GPC curve of the extracted agent. After extraction, the first peak shown in Figure 36 shows that the content of Example 5 in the solvent is very low. The second peak of Figure 36 is not significant, quite a lot of polystyrene - The 3,4-polyfarnesene diblock copolymer was extracted by extraction solvent. The second peak of Figure 36 shows that 'the vast majority of polystyrene is extracted by the extraction solvent. Figure 37 shows that Example 5 was purified. Tensile test results. The tensile strength of the purified Example 5 was measured by a tensile test. Example 5 was soft and easily formed. As shown in Fig. 37, the elongated fracture value of the purified Example 5 was the maximum tensile force 34. The purity of the purified Example 5 was 65.9 kpsi. The tensile strength of the purified Example 5300 was 57. The purified Example 5 was observed to have a high dryness. Figure 38 shows the purification. The lap test results of Example 5 (because of the occurrence of -subsequent failure). The adhesion of the purified Example 5 was determined by the lap test. The energy of the binder of 5 can be seen as J/m2, and the peak pressure is about 120,000 state 〇12. 95 201026773 Example 6 Example 6 is the product obtained by vulcanization of Example 1. In order to obtain the formula of the reaction mixture, 62.7 Example 1 of g and 3.20g zinc oxide, i.25g stearic acid, 〇.94g Rubbermakers SulfUrMC-98 substance, 〇_13 gAccelerat or TMTD (dithiotetramethyl thiuram) and 0.63 g Accelerat or 〇BTS ( N-oxydiethyl-2-benzothiazepine hydrochloride is mixed. Zinc oxide, stearic acid, Rubbermakers SulfurMC_98, 0.13 g Accelerat or TMTD, and Accelerat or OBTS are purchased from

Akrochem Corporation (USA). The compound was placed in a vulcanization mold, and the gas was removed at 14 (rc) for about 30 minutes. Thereafter, the compound was treated at 17Q for 15 minutes. After remolding, 70.4 g of an example 6 elastic solid was obtained (yield 81 〇/0). Fig. 39 shows the results of the tensile test of Example 6. The tensile force of Example 6 was measured by the lap test. Fig. 39 The elongation fracture value of Example 6 was 16 p_38% of the maximum tensile force. The modulus of repair was 58. Example 7 Example 7 is the product obtained by vulcanization of Example 2. Except for the case of lffi6〇3_2, the procedure of Example 7 can be synthesized according to the procedure similar to Example 6. The net weight of Example 7 is 6 ❹ rate 78%). : Figures 40, 4 Results of tensile test of Example 7. The figure shows that the elongation fracture value of Example 7 is 25% of the maximum tensile force of 10 Psi. The modulus of Example 7 was 66 kpsi. Although the present invention has been described in terms of the implementation of the number of buttons, the specific features of the present invention are not applicable to other implementations. Any implementation does not represent all aspects of the present invention. In certain embodiments, the compositions or methods may comprise two compounds or procedures not mentioned in the present invention. In certain embodiments, the compositions or methods of the reference 96 201026773 do not contain or substantially exclude compounds or procedures not mentioned herein. There are also different and adjusted content than those described in the described implementation. Finally, the disclosed digits indicate an approximation regardless of whether the text is expressed as approximately or approximated. The claims appended hereto are intended to cover all variations and modifications which are within the scope of the invention. The above are only the preferred embodiments of the present invention, and all changes and modifications made to the scope of the present invention are intended to be within the scope of the present invention. Φ [Simple description of the diagram] Figure 1 shows the ultraviolet-visible (uv-vis) spectrum of the example 1 and /3 farnesene. Figure 2 shows the gel permeation chromatography (Gpc) curve of Example 1. Figure 3 shows the C 13 nuclear magnetic resonance _ phantom spectrum of Example 1. Figure 4 shows the H1 nuclear magnetic resonance spectrum of Example 1. Figure 5 shows a differential scanning calorimetry (DSC) curve of Example 1. Figure 6 shows the thermogravimetric analysis (TGA) curve measured in the air of Example 1. $ Figure 7 shows the thermogravimetric analysis (TGA) curve measured in Example 1 Nitrogen. Figure 8 shows the results of the lap test of Example 1. Figure 9 shows a gel permeation chromatography (GPC) curve of Example 2. Figure 10 shows a differential scanning calorimetry (DSC) curve of Example 2. Figure 11 shows the results of the tensile test of Example 2. Figure 12 shows a gel permeation chromatography (GPC) curve of Example 3. Figure 13 shows the C nuclear magnetic resonance spectrum of Example 3. Figure 1.4 shows the Η NMR spectrum of Example 3. Figure 15 shows the differential scanning calorimetry (DSC) curve for Example 3 of the axe. 97 201026773 Figure 16 shows the thermogravimetric analysis (TGA) of Example 3. Figure 17 shows the results of the lap test of Example 3. ♦ Figure 18 shows the gel permeation chromatography (GPC) curve of the polystyrene formed. Figure 19 shows a gel permeation chromatography (GPC) curve of the formed polystyrene-1,4-polyfarnesene diblock copolymer. Figure 20 shows a gel permeation chromatography (GPC) curve of Example 4. Figure 21 shows the 13C nuclear magnetic resonance spectrum of Example 4. Figure 22 shows the 1 Η nuclear magnetic resonance spectrum of Example 4. ❹ Figure 23 shows a differential scanning calorimetry (DSC) curve of Example 4. Figure 24 shows the thermogravimetric analysis (TGA) of Example 4. Figure 25 shows the results of the tensile test of Example 4. Figure 26 shows the results of the lap test of Example 4. Figure 27 shows a gel permeation chromatography (Gpc) curve of the formed polystyrene. Figure 28 shows a gel permeation chromatography (GPC) curve of the formed polystyrene_3.4-polyfarnesene diblock copolymer. ❿ Figure 29 shows the gel permeation chromatography (GPC) curve of Example 5. Figure 30 shows the 13C nuclear magnetic resonance spectrum of Example 5. Figure 31 shows the 1 Η nuclear magnetic resonance spectrum of Example 5. Figure 32 shows the differential scanning calorimetry (DSC) curve of Example 5. Figure 33 shows the thermogravimetric analysis (TGA) of Example 5. Figure 34 shows the results of the tensile test of Example 5. Figure 35 shows the gel permeation chromatography (GPC) curve of Example 5 after the extraction. Fig. 36 is a graph showing the positively-burned gel permeation chromatogram after the extraction of the compound of Example 5 (Gp 98 98 9826 2626 Figure 37 shows the results of the tensile test of Example 5. Figure 38 shows the results of the lap test of Example 5. Figure 39 shows Example 6 The tensile test results are shown in Fig. 40. The tensile test results are shown in Example 7. [Main component symbol description]

99

Claims (1)

201026773 VII. Patent application scope: 1. A polyfarnesene composition comprising one or more polymer molecules having a structure of the following formula (X,): (x'), wherein η An integer from 1 to about 100,000; m is an integer from 0 to about 1 〇〇, (8) ;; X has one or more structures encompassed by the following formula (Ι')-(νΐΙΓ): (IV,), (ν'), (vr), 7 (VII,) and R4 (Vlir); and ¥ have the structure of the following formula (1, again): R8 (IX,), wherein R1 has the structure of the following formula (XI): (XI;); and a structure in which R2 has the following formula (XII): 201026773 wherein R3 has the structure of the following formula (χιιι): CH3 pLJ, h3c (XIII); and a structure in which r4 has the following formula (xrv): Hs ?H3 CH3 (χινχ wherein R1 2, R3, R4 and R5 are each independently hydrogen, alkyl, cycloalkyl, aryl, cycloalkenyl, alkynyl, heterocyclyl, alkoxy, aryloxy, a carboxyl group, an alkoxycarbonyl group, an amine carbenyl group, an alkanocarbylmethyl group, a dialkylamine fluorenyl group, a decyloxy group, a nitrile or a halogen; wherein the conditional 疋 'rich m is 〇' (p) The compound content is up to about 80% by weight of the total weight of the polythene and when m is 1 or greater than 1 and the molecular ratio of X to Y is about 1:4 to about 100:1. a polyfarnesene having a formula (Π,) in an amount of from about 5 wt.% to about 99 wt% of the total weight of the polyfarnesene. The polyfarnesene according to claim 1, wherein the formula (III) The content of the polyfarnesene is about 7% by weight of the total weight of the polyfarnesene. The polyfarnesene of the formula 1 is one or more of the formula (Γ)-(ΠΓ), 2 (yχχι)~(χιγ) to At least a portion of the double 3 bond of the compound of the stereoisomer is hydrogenated. 4 5. The polyfarnesene according to claim 1 wherein m of the formula (X,) is Q and X has one or more The structure of the formula d'Hiv,). 5-6. The polymethod described in Item 1 of the previous month, wherein m is G and X has one or more structures such as the formula (v'Hvnr). 201026773 Mud ==, its change) and (vr) content accounts for about ^ tV 至 to 99wt 〇 / o. In general, the content of the base is about _R7 and ^ Η 桃 纽 纽 其 f f ( 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 四 聚 聚 , , , , , , , , , , , , , , , Is ι·ω_〇, V is an aryl group, and R, R and 圮 are both ❹!. The polyfarnesene according to the item 1G, wherein the aromatic group is a phenyl group. The method of claim 14, wherein m is about 1 1 GG, _' and the hexene is a random copolymer. . The method of any one of claims 1 to 4, wherein the melon is about 1 = _GG, and the polyfarnesene described therein is a block farnesene copolymer. The polyfarnesene according to claim 13, wherein the block method is composed of a block containing X and a block containing γ, wherein the segment containing ruthenium is located Between two blocks containing γ. The poly-scale of the poly-fabric as described in claim arbitrarily, wherein the polymethicone has a molecular weight of greater than about 6 〇〇〇 Daltons. K is as arbitrarily as described in the item M1. c. The method of any one of the items 1-11, wherein the sum of the number of melons and ^ is greater than 300. -^ In the catalysis, in the time of the order of the Nasaki (four), the secret method is thin, and the _ meal M micro-structure content accounts for the total of the total "80 1〇2 201026773 wt.%. 19. The method of polymerizing cerium lanthanum in the presence of a catalyst, wherein the polyfarnesene has a cis-1,4 microstructure content of up to 1 wt% of the total weight of the polyfarnesene. .% to 99 wt%. 20·- A kind of polyfarnesene prepared by: () in the presence of 4 令 法 法 法 法 法 法 法 法 法 法 法 法 法 法 法 法 法 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合 聚合The polymethod t is at least partially double-hydrogenated. 21. A β-equivalent copolymer such as any one of the poly-ethylene monomers described in any one of the items is copolymerized to form a dilute copolymer. The bake-baked monomer is styrene. Bio-prepared. Wherein the farnesene is polyfarnesene, the farnesene is _-contained by micro = single = item _ arbitrary -, the catalyst of the farnesene source comprises 25. as claimed in claim 18 -20 any organolithium reagent. The method described in the article, as described in the item, 26. The request is based on the amine group. 27. If requested, sec-butyl lithium. 28. The method of claim 25, wherein the catalyst further comprises, 2 - 2 (dimethyl 25 4 poly(tetra). The organic matter is n-butyl clock or 2 〇 escaped, Cardiac test is present in a hydrogen addition to 103 201026773 hydrogen catalyst. 29. The polyhydrogenation catalyst described in claim 28 is 10% palladium on carbon I It!' percentage about 1: 4 to About 2 丨. ° 'The method of phase and the single cell of the B-cell 31. A method of manufacturing poly-plutonium, including; and a small amount of vinyl monomer (a) The use of monosaccharides to form farnesene by microorganisms (b) Thinning and polymerization in the presence of a catalyst. 32. The method of claim 31, wherein the method is dilute to the vinyl monomer in a molar percentage of about 1:4 to 100: lD 33. as claimed in any one of claims 30-32. In the method, the at least one ethylenic monomer does not contain a terpene. 4. The method of any one of clauses 30 to 32, wherein the at least one ethylene monomer is an ethylene 4 olefin, a substituted or unsubstituted ethoxylate, a _, a propylene Alkonitrile acrylonitrile H-based decyl acid, propylene methacrylamide or a combination of two. The method of any one of clauses 30 to 32, wherein the at least one vinyl precursor is a woman. The polyfarnesene of any one of claims 30-32, wherein the catalyst is a Qiele-Natta catalyst, a Kaminsky catalyst, a metallocene catalyst, an organolithium reagent, or a combination thereof. 37. The method of any of claims 30-32, wherein the catalyst comprises a 104 201026773 smoke, a poly, a poly, a polystyrene polymer, a styrene polymer, a polyacrylic acid vinegar, a poly Mercaptoacrylic shouts their combination. 1 C-Phase phase material (4) Material-subtraction--------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- The molded product is selected from: H body and electric (four), Lai, fine, (four) and coffee seal ring, steam seal mat, ^ mast, grid her, smashing, hose, lining, office supplies, shoes *, diaphragms, tubes, covers, stoppers, punches, carrying systems, kitchen appliances, shoes, shoe bags and soles. From the age-old complex, which contains the m-series and the t-mail method, has the following formula (X,), Q, the integer of the η rabbit, the integer of 100,000, and the m of the spoon; m is From 〇 to about 10 〇, the piece of true volume 'X is derived from the law, Y is derived from a vinyl monomer, the attached strip 100 is greater than or equal to 1, and the molar percentage of lanthanum and cerium is about 1: 4 The structure of the dry composition of the formula (1^°, 51, the oxime has one or more workers-VIIr) and their stereoisomers: 106 201026773 f (Γ)R2 ΠΛ/, i (II,) (III,) H3c αν,), I-(V,), R3 ch3 R3(vr), d (vir), and ❹ ❹ (VIII,), wherein R1 has the structure of the following formula (xi): CH3 CH3 wherein R2 has the structure of the following formula (XII): Γ3 ΐΗ3 πΗ2 (ΧΠ)? Structure having the following formula (XIII): ?H3 CH3 H3C into eight in /y, (leg); and wherein R4 has the structure of the following formula (XIV): 9h3 CH3 rw , (XIV) ο In the composition of the composition, the content of the (I,) is about 80% by weight based on the total weight of the polyfarnesene. 54. The fc composition of claim 52, wherein said (Π') is present in an amount of about 5 wt.% to 99 wt.% based on the total weight of the polyfarnesene. 107 201026773 Organic clock reagent. 38. The catalyst of the method of claim 37, further comprising io,2-di(dimethylamino)ethane. 39. The organolithium reagent according to the method of claim 37, which is an n-butyllithium or a sec-butyl clock. 40_ - A poly-fabric prepared by the method of any one of claims 30-32. A polymeric composition comprising the polyfarnesene of any one of the claims and claim φ, and at least one additive. The polymer composition according to claim 41, wherein the additive is a filler, a graft initiator, a tackifier, a slip agent, an anti-blocking agent, a plasticizer, an antioxidant, and a foaming agent. , foaming J activator, rabbit external stabilizer, acid scavenger, colorant or pigment, active help] / door β antifogging agent, glidant, force auxiliaries, extrusion aids, coupling Agent, cross-linking know! %, bismuth controlling agent, nucleating agent, surfactant, flame retardant, antistatic agent or a combination thereof. 43. The polymer composition of claim 41, wherein the additive is a filler. The polymer composition according to item 41, wherein the additive is a crosslinking agent. .45. The polymer composition of claim 11, wherein the additive is a second polymer. 46. The enthalpy composition of claim 45, wherein the ratio of the polyfarnesene to the first nucleus is about 1: 47. The polymer as claimed in claim 45 The composition, the second polymer is a polyene 105 201026773 Lit, the % of the conjugate, the ratio of π,) is about 70 wt.% of the total weight of the polyfarnesene. The composition of claim 52, wherein the one or more of the formulae = (m'), (V'HVII,) and at least a portion of the double bonds of the stereoisomers thereof Hydrogenated. τ 51 The contact composition of the item 'the γ has the formula (κ,) and its stereoisomer: (IX,), wherein K5, R6 R7 disc R8 is long & * > /, self 虱, alkyl, cycloalkyl, aryl, cycloalkenyl, block, heterocyclic, methoxy, off Prepared,,, aryl, carboxyl, oxycarbonyl, amidoxime, alkylamine, diamine, sulfhydryl, nitrile or a nutrient. In the dry composition, the R5 is a aryl group and R6, R7 is a dry composition according to the above item 58, wherein the aryl group is a phenyl group. Polymer/M51 is a smuggling compound, and the method of the method is as described in claim 51, the melon is about (9), and the The polyfabric is dilute to any random random farnesene copolymer. Shi. The dry composition of the invention according to Item 51, wherein the melon is about to be a copolymer of the four-fourth method. A dry binder composition according to the above item 62, wherein the block farnesene copolymer is a copolymer of 108 201026773. 74. The adhesive composition of claim 68, wherein the farnesene is prepared from a microorganism. 75. The adhesive composition of claim 68, wherein the farnesene is prepared from a monosaccharide. 76. The adhesive composition of claim 68, wherein the catalyst comprises an organolithium reagent. 77. The adhesive composition of claim 76, wherein the catalyst further comprises 1,2-di(diammonium)ethane. The adhesive composition according to claim 68, wherein the composition is a hot-melt adhesive composition or a pressure-sensitive adhesive composition. 79, a product' and all or a portion of the article is coated with the adhesive composition of claim 68. 8. The article of claim 79, which is a paper product, an agricultural material, a glued name, a kitchen countertop, a car, a label, a disposable diaper, a medical mattress, a female cotton, a surgical list, Tape, box, carton, tray, medical equipment or end belt. 81. The article of claim 80, which is a therapeutic device or a braid. V-phase paper tray, tray, 82. - A method of drying up 'This method is to use a chelating chelating agent such as the request item ^ 立 ^ ^, the first taste __ (four) = with = 83 · as requested The method of item 82, wherein the first one is the same. 110 201026773 • H blocks containing x and two blocks containing y # block, the x-containing stagnation • located between the two Y-containing blocks. 64. The adhesive composition of claim 51, wherein the tackifier is present in an amount from about 5 wt.% to about 70 wt.%, based on the total weight of the polythene. The adhesive composition according to claim 51, which further comprises an additive derived from a plasticizer, an oil, a hydrazine, an antioxidant, a UV stabilizer, a colorant, and a filler, a filler, a glidant, Coupling agents, crosslinking agents, surfactants, solvents, and combinations thereof. 66. The adhesive composition of claim 51 further comprising a second polymer. 67. The adhesive composition of claim 66, wherein the second polymer is natural rubber, synthetic rubber, polyacrylic acid vinegar, polymethacrylic acid, poly(tetra)hydrocarbon, ethylene#polymer 'Ethylene copolymer, styrene block copolymer or a combination thereof. A 68'-waste composition comprising a poly-fabric and a solubilizer, said poly-formation claim 3M2 being prepared by any method. ❿ i The contact chelate as described in item 68, which is a dilute method, a farnesene or a combination thereof. 7〇 The main & 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 The puncture composition of claim 68, wherein the ethylene monomer is present and the n-ene is a farnesene copolymer. The adhesive composition according to the invention of claim 6, wherein the vinyl monomer is a dry composition, and the method is a dry composition. The mourning segment 109 201026773. The method body as described in the claim & is different from the second adherend. The first adhesion stage of the crucible 85. The method according to claim 82, wherein the first metal, wood, paper, plastic, rubber, broken, and the second dry body are each covered with a stone, Pottery, branch, charm, cement, stone, granite, marble, non-woven, leather or a combination thereof. , sand, chalk, fabric, cloth, ❹ 86. The method of claim 82, wherein the first is a shape of a sheet, a strip, a tape, or a first adherent body of any of the molded shapes. A binder composition comprising: a polyfarnesene of the formula (X,), a solubilizer, and the Γχ ^ f1〇 0,000 ° ^ Participate in the χ γ γ · (4) monomer, the condition is m greater than or equal:: The molar percentage with Y is about 1:4 to about (10):1. The amount of the mixture composition of about ΓΓ=87, wherein the polyfarnesene comprises from about 5% by weight to about 7% by weight based on the total weight of the composition. The thorns of the spurs of the 87th _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ The adhesive composition according to Item 87, wherein the rubber has a Tg of less than 20. The dry composition of any one of the above-mentioned items, wherein the oxime has one or more of the formula (I'Hviir) and their stereoisomers: 111 201026773 R1 R1 (r), II,), (III,) R2 (IV,) -K factory (V,), R3 CH, R[ CH3Λ人入(VI,), > (VII,) and h3c (VIII,), wherein R1 has the structure of the following formula (XI) ❹ (XI); wherein R2 has the structure of the following formula (XII) (XII), wherein R3 has the structure of the following formula (XIII) 〇 (XIII); and wherein R4 has the structure of the following formula (XIV): CH H3C, V V V V /, (XIV) 〇 92. The adhesive composition according to any one of claims 87 to 90, wherein Y has a structure of the following formula (IX') or a stereoisomer thereof: R5 R6 112 (IX,), 201026773 wherein R 5 , R 6 , R 7 and R 8 are each independently hydrogen, alkyl, cycloalkyl, aryl, cycloalkenyl, alkynyl, heterocyclyl, alkoxy, aryloxy, carboxy , alkoxycarbonyl, amidino, alkylamine • carbonyl, dialkylamine carbonyl, decyloxy, nitrile or halogen. Eight, the pattern: φ 113