201024501 九、發明說明： 【發明所屬之技術領域】 本發明係有關一種石頭紙之製造技術，主要可運用於 紙牌或紙鈔等硬紙產品者。 【先前技術】 按，習用之「高光澤碳酸鈣塗料組合物及經塗覆紙張 以及由其製得之紙板」如中華民國專利公報申請案第0 9 1 1 0 5 4 6 9，一種用於塗料組合物以產生高紙張光澤 ❹ 表面處理之碳酸鈣產物，該產物包括：具有第一平均值第 一粒徑分佈之第一種碳酸鈣粒子，及具有第二平均值第二 粒徑分佈之第二種碳酸鈣粒子，該第一及第二平均值差值 在0.1微米到0. 2微米，該第一種碳酸鈣粒子及第二 種碳酸鈣粒子，係以由5 0 : 5 0到8 0 : 2 0重量比例 提供。 【發明内容】 φ 引以習用之石頭紙製造技術，均以碳酸鈣粒子做為產 物，其使製成之紙板容易碎裂者且不易長期保存，有鑑於 上述之缺失弊端，本發明人認為其有急待改進之必要，針 對既有之缺失加以改良，終乃有本發明石頭紙之製造技術 ，係為一充分符合實用進性之設計，本發明藉由於奈米碳 酸鈣再融合P E塑膠以增進其耐用度與耐腐蝕度，進而增 加該石頭紙使用度及其壽命者。 本發明係有關一種石頭紙之製造技術〔請參閱第一圖 〕，該石頭紙包括P E ( 1 )塑膠與奈米碳酸鈣（2 )所 201024501 共同混合而成；其中： P E (工）p〇lyethylene係一種塑膠材料， 稀，該結構為~(CH2-⑽-，純料特性可 財用不易損餘，且PE⑴介於石頭紙内所佔 為3〜90%; 、重201024501 IX. Description of the invention: [Technical field to which the invention pertains] The present invention relates to a technique for manufacturing stone paper, which can be mainly applied to hard paper products such as cards or banknotes. [Prior Art] According to the conventional "high-gloss calcium carbonate coating composition and coated paper and paperboard made therefrom", such as the Republic of China Patent Gazette Application No. 0 9 1 1 0 5 4 6 9, one for a coating composition to produce a high paper gloss ❹ surface treated calcium carbonate product, the product comprising: a first calcium carbonate particle having a first average first particle size distribution, and a second average particle size distribution The second calcium carbonate particles, the first and second average values are between 0.1 micrometer and 0.2 micrometer, and the first calcium carbonate particles and the second calcium carbonate particles are from 5:50 to 8 0 : 2 0 weight ratio is provided. SUMMARY OF THE INVENTION φ refers to the conventional stone paper manufacturing technology, which uses calcium carbonate particles as a product, which makes the made cardboard easy to be broken and is not easy to be stored for a long time. In view of the above drawbacks, the inventors believe that There is an urgent need for improvement, and the improvement of the existing defects is ultimately the manufacturing technology of the stone paper of the present invention, which is a design that fully meets the practicality. The present invention is based on the remelting of PE plastic by nano calcium carbonate. Improve its durability and corrosion resistance, thereby increasing the use of the stone paper and its life. The invention relates to a stone paper manufacturing technology (please refer to the first figure), which comprises a PE (1) plastic and a nano calcium carbonate (2) 201024501 mixed together; wherein: PE (work) p〇 Lyethylene is a kind of plastic material, thin, the structure is ~(CH2-(10)-, the characteristics of pure material can be used for financial purposes, and PE(1) is 3~90% in stone paper;
奈米碳酸鈣（2)係由粒徑大小介於3 〇〜i n m之奈米顆粒之碳酸鈣所聚結構成，其材料特性可賦使Ζ 頭紙較耐高溫之特質亦增加其擁有紙張之觸感，而奈米碳 酸鈣（2)需配合ρ Ε ( 1 )於石頭紙所佔之填充量，亦 奈米碳酸鈣（2)填充量可於石頭紙内佔丄〇〜9 7%者 本發明其優點在於，融合P E ( 1 )塑膠與奈米碳酸 鈣（2)二者之特性，藉由p E (丄）塑膠之特性，其提 升了石頭紙使用度及其壽命，更可產生抗菌、防水或防蟲 蟻啃咬損壞，而藉由奈米碳酸鈣（2)之特性，其增使石 ❹頭紙賦有紙張硬粒質感並耐高溫，且該二者所構成之石頭 紙可行回收再利用，俾使該石頭紙相當符合環保概念者。 【實施方式】 使用石頭紙之製造技術實施時〔請參閱第二圖〕，首 先將P E ( 1 )塑膠與奈米碳酸鈣（2 )二者混合，因p E ( 1 )塑膠係一種塑膠材料，且該特性係具不易腐蝕並 柔勒賦有彈性’而奈米碳酸約（2)係奈米粒徑所聚結而 成之碳酸鈣原料’該特性係具耐高溫燒燙且内附粒子緊密 並賦有硬度亦使其擁有紙張之觸感，藉此二者混合略可產 201024501 生多種具不同特性之石頭紙成品，依使用者之欲使用之質 感與紙張用途需求’該二者所涵蓋之比例多募各可影響其 石頭紙之質感，當混合比例使用p E ( 1 )塑膠含量最低 可佔3%、奈米碳酸鈣（2)含量則佔9 7%，此成品質 f較似紙張且硬度高耐高溫但較易碎裂其適用於該石頭 欲賦有仿紙之質感所使用之 含量最高可佔Α η 吵 ， 口 占9 0%、奈米碳酸鈣（2 )含量則佔1 〇% ❹欲賦^ 則鹎有較強的韌性 ，其適用於該石頭紙捨其質感 堅杨耐用且不易產生皺摺所使用之，將二者混合 便可使用殿 艮 延之加工方式俾使其混合者呈薄片狀，成形後 f更裁刀大小’以製成石頭紙，另該加工方式亦可使用吹 袋之加工方々 ^ — _々式’同可將該混合者呈薄片狀者。 、’τ、上所述，當知本發明具有新穎性，且本發明未見之 ;任^刊物’當符合專利法第2 1、2 2條之規定。 处唯以上所述者，僅為本發明之一較佳實施例而已，當 ❹不月b以之限定本發明之範圍。即大凡依本發明申請專利範 圍所作之岣等變化與修飾，皆應仍屬本發明專利涵蓋之範 圍内。 耽* 201024501 【圖式簡單說明】 第一圖；本發明之立體外觀示意圖 第二圖；本發明之製造流程圖Nano-calcium carbonate (2) is made up of calcium carbonate with a particle size of 3 〇~inm. The material properties of the paper can make the paper more resistant to high temperature and also have paper. Touch, while nano calcium carbonate (2) needs to match the filling amount of ρ Ε ( 1 ) in stone paper, and the filling amount of nano calcium carbonate (2) can account for ~9 7% in stone paper. The invention has the advantages that the characteristics of the fusion PE (1) plastic and the nano calcium carbonate (2), by the characteristics of the p E (丄) plastic, can improve the use of the stone paper and its life, and can be produced. Antibacterial, waterproof or insect-resistant ants bite damage, and by the characteristics of nano-calcium carbonate (2), it increases the stone grain texture and high temperature resistance, and the stone paper composed of the two can be recycled. Reuse, so that the stone paper is quite in line with the concept of environmental protection. [Embodiment] When using the manufacturing technology of stone paper (please refer to the second figure), first mix PE (1) plastic with nano calcium carbonate (2), because p E (1) plastic is a plastic material. And the characteristic is a calcium carbonate raw material which is not easy to corrode and has a flexibility and the nanocarbonic acid is about (2) a nanometer particle size is aggregated. The characteristic is resistant to high temperature and hot and the particles are tightly attached. And the hardness also gives it the touch of paper, so that the combination of the two can produce a variety of stone paper products with different characteristics of 201024501, depending on the user's desire to use the texture and paper use requirements. Proportion of multiple proportions can affect the texture of the stone paper. When the mixing ratio is p E ( 1 ), the plastic content is at least 3%, and the nano calcium carbonate (2) content is 9 7%. It has high hardness and high temperature resistance, but it is easy to be broken. It is suitable for the texture of the stone to be imitation paper. The highest content can be used for Α η, the mouth is 90%, and the nano calcium carbonate (2) is 1%. If you want to give ^, then you have strong toughness, which applies to the stone. The texture is firm and strong, and it is not easy to produce wrinkles. If you mix the two, you can use the processing method of the temple to make the blender into a thin sheet. After forming, the size of the knife is made to make a stone paper. In addition, the processing method can also use the processing method of the blowing bag 々 _ _ 々 type can also be used to make the mixer flaky. As described above, it is known that the present invention is novel and has not been found in the present invention; any publication 'has to comply with the provisions of Articles 21 and 22 of the Patent Law. The above description is only a preferred embodiment of the present invention, and the scope of the present invention is limited thereto. That is, all changes and modifications made by the applicant in accordance with the scope of the patent application of the present invention are still within the scope of the present invention.耽* 201024501 [Simplified description of the drawings] First drawing; schematic view of the three-dimensional appearance of the present invention; second drawing; manufacturing flow chart of the present invention
【主要元件符號說明】 1 P E 2 奈米碳酸鈣[Main component symbol description] 1 P E 2 nano calcium carbonate