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TW201005374A - Optical sheet and backlight unit using the same - Google Patents

Optical sheet and backlight unit using the same Download PDF

Info

Publication number
TW201005374A
TW201005374A TW098121101A TW98121101A TW201005374A TW 201005374 A TW201005374 A TW 201005374A TW 098121101 A TW098121101 A TW 098121101A TW 98121101 A TW98121101 A TW 98121101A TW 201005374 A TW201005374 A TW 201005374A
Authority
TW
Taiwan
Prior art keywords
filler
optical sheet
optical
layer
light
Prior art date
Application number
TW098121101A
Other languages
Chinese (zh)
Other versions
TWI406050B (en
Inventor
Keiichi Osamura
Original Assignee
Jiro Corporate Plan Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiro Corporate Plan Inc filed Critical Jiro Corporate Plan Inc
Publication of TW201005374A publication Critical patent/TW201005374A/en
Application granted granted Critical
Publication of TWI406050B publication Critical patent/TWI406050B/en

Links

Classifications

    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/02Diffusing elements; Afocal elements
    • G02B5/0205Diffusing elements; Afocal elements characterised by the diffusing properties
    • G02B5/021Diffusing elements; Afocal elements characterised by the diffusing properties the diffusion taking place at the element's surface, e.g. by means of surface roughening or microprismatic structures
    • G02B5/0226Diffusing elements; Afocal elements characterised by the diffusing properties the diffusion taking place at the element's surface, e.g. by means of surface roughening or microprismatic structures having particles on the surface
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/07Flat, e.g. panels
    • B29C48/08Flat, e.g. panels flexible, e.g. films
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/04Prisms
    • G02B5/045Prism arrays
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2305/00Condition, form or state of the layers or laminate
    • B32B2305/30Fillers, e.g. particles, powders, beads, flakes, spheres, chips
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/20Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
    • B32B2307/21Anti-static

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Laminated Bodies (AREA)
  • Optical Elements Other Than Lenses (AREA)
  • Liquid Crystal (AREA)
  • Planar Illumination Modules (AREA)

Abstract

The object of the invention is to provide an optical sheet with an excellent anti-adhesive property and a higher total transmittance for inhibiting interference and uneven brightness thereby possessing high economic efficiency and thinness, and a backlight unit using the optical sheet. The optical sheet of this invention comprises a transparent substrate film, an optical layer laminated on one side of the substrate film, and an anti-adhesive layer laminated on the other side of the substrate film, characterized in that: the anti-adhesive layer contains fillers and its resin-made binders, the flat portion of the anti-adhesive layer has an average thickness greater than 50nm and less than 150nm, and the average particle diameter of the fillers is greater than 70nm and less than 200nm. The fillers contain main ingredient of small-diameter fillers and minor ingredient of large-diameter fillers, wherein the average particle diameter of the small-diameter fillers is greater than 50nm and less than 150nm.

Description

201005374 六、發明說明: 【發明所屬之技術領域】 H日月係關於—種光學片及使用其之背光單元,詳細 而5 ’本發明係關於一種具有使透射光線擴散、朝法線方 向側折射、聚光等之光學功能,且尤其適宜用於液晶顯示 裝置中之光學片及背光單元。 【先前技術】 關於液晶顯示裝置中,普遍採用自背面照射液晶層而 使其發光之背光方式,液晶層之下面側裝有端面照光型、 直下型等之背光單元。該端面照光型背光單元50如圖5( a) 所不,基本上具備:作為光源之線狀燈源5 1、以端部沿著 該燈源51之方式進行配置的方形板狀之導光板52、以及積 層於該導光板52上之複數個光學片。該光學片具有使光線 的峰方向朝法線方向側折射之功能、使亮度分布擴散之功 能等既定的光學功能,具體而言有配設於導光板52之表面 側之光擴散片53及稜鏡片54等。再者,雖未圖示,但作 為光學片,除了光擴散片53及稜鏡片54以外,亦有配設 於導光板52之背面側的反射片、表面設有微透鏡陣列之微 透鏡片等。 以下對該背光單元50之功能加以說明,首先,自燈源 5 1入射至導光板52之光線被導光板52背面之反射點、配 設於導光板5 2之背面側的反射片(未圖示)、及導光板W 之各側面反射,並自導光板52表面射出。自導光板52出 射之光線入射至光擴散片53,受到擴散、朝法線方向側折 201005374 射等既定的光學作用,從而自光擴散片53夕本 之表面出射。4卜 後,自光擴散片53出射之光線入射至稜鏡片54,並藉由, 成於其表面上之棱鏡部54a而作為在大致正上方向^示I 峰值之分布的光線出射。 ”、、τ出 如上所述,自燈源、射之光線藉由導光板52而向 表面側折射,且藉由光擴散片53而得到擴散等,進而藉: 複鏡片54以在大致正上方向顯示出峰值之方式而折射從 而對上方之未圖示之液晶層的整個面進行照明。再者,雖 未圖示,但亦存在在稜鏡片54的表面側進一步配設有其他 棱鏡片或光擴散片之背光單元。 ' 作為先前之光擴散片53’ 一般如圖5(b)所示,包括 基材膜55、形成於基材膜55之表面上的光擴散層%、及 積層於基材膜55之背面上之防黏層57(例如參照日本專利 特開2_-89007公報等)。該光擴散層56構成為對透射光 線具有光擴散功能,且黏合劑58中含有光擴散劑59。 上述先前之光擴散片53中,防黏層57係藉由於基材 膜55之背面塗佈含有構成黏合劑之聚合物、樹脂珠粒61、 溶劑:之樹脂組成物而形成,黏合劑6〇中分散有樹脂珠粒 61,藉由該樹脂珠粒61而使背面具有凸部。藉由形成於該 防黏層57之背面上的凸部’來防止光擴散片53之背面與 導光板52等密著而產生干涉條紋之缺點。 就防黏之觀點而言,上述防黏層57之樹脂珠粒6 1可 使用平均粒徑為5 #m〜2〇 之丙烯酸酯珠粒等。因 此上述防黏層57會因為在樹脂珠粒61之界面的反射、 201005374 折射導致自背面入射之光線產生某種程度的散射的缺陷。 、上述先刚之光擴散片53,有可能會因防黏層57而導 致透光率等光學功能的下降。 又’為了將上述平均粒徑之樹脂珠粒61加以固定,而 字防黏層57之平均厚度設為5 以上、&quot;爪以下。 2此上述先刖之光擴散片53有悖於目前液晶顯示裝置之 溥型化之要求’且藉由防黏層57之兩界面上之折射而使透 射光線產生干擾現象,從而可能會導致產生疊紋等。 進而,因防黏層5 7含有樹脂珠粒6丨,故尤其是背面之 凸部等會變得相對質軟’從而於液晶顯示裝置之組裝時或 堆積保存、搬送時可能會受到損傷。若該防黏層57的背面 丈損,則可能會因光之散射而導致產生液晶顯示裝置畫面 冗度下降、出現亮度不均等問題。 又’因此如上所述藉由塗佈等而形成有防黏層57,故 而,製造光擴散片53時,至少需要如下三個步驟:使基材 膜55成形之步驟、於該基材膜55之表面上形成光擴散層 56之步驟、以及於基材膜55之背面上積層防黏層57之步 驟’且為了謀求達成目前的要求即降低製造成本,則要求 簡化製造步驟。 該光擴散片53之缺點亦發生於稜鏡片54、或其他微透 鏡片、扁豆狀(lenticular)透鏡片、菲涅爾(Fresnel)透鏡片等 光學片。 [專利文獻1]日本專利特開2000-89007公報 【發明内容】 201005374 之問镅 本發明係鑒於該等問 種防黏性優異、罝有广…兀成者’其目的在於提供一 現象及亮度不均、進…:先率、能有效地抑制干擾 片及使用其之背光單元的經濟性及薄臈性之光學 之手段 為解決上述問題而完成之發明如下: 一種光學片,其係具備透 膜之一面之光學層m 基材膜、積層於該基材 增及積層於基材 者,其特徵在於: 、 一面之防黏層 該防黏層含有填料及其樹脂製黏合劑, 防黏層之平扫部$承 下, P之千均厚度為50細以上、⑽麵以 填料之平均勒;彳&amp;在7Λ 丁 口植仏為7〇nm以上、2〇〇nm以下。 防黏::=中’防黏層含有填料及樹脂製黏合劑,該 防黏層之千坦部之平均厚度為Μ _以上 填料之平均粒徑為70nm以上、2〇〇 、 〇_以:, 奈米尺寸之填料,可於 爪以下’故而’精由 微細的凸部…果=外表面上較密且均勻地形成 地抵接…較密且均勾之凸部而散點狀 與片且右卜 敎導先板、稜鏡片等。因此,該光 :有較'的防黏性,且能防止因黏附而產生干擾條紋。 ?〇 W巾,發揮㈣性之㈣之平均粒徑為 Γ=、—τ,故而,填料之平均粒徑小於: 見光之波長,即便S?人λ 4·古Η °人填料’亦可顯著地降低對透光性 6 201005374 之阻礙,故具有較高的總透光率。 進而,於該光學片中,防黏層之平坦部之平均厚度為 5〇 nmui、15〇 ,因此防黏層之平坦部之平均厚 度小於可見光的波長,&amp;而可減少防黏層之兩界面上之折 射所產生的透射弁綠&gt; 45 jb a ''' 干擾見象’可有效地抑制疊紋等之 產生。 又’於該光學片中,防黏層之平坦部之平均厚度明顯 小於先前之平均厚度,I而可促進目前所要求之液晶顯示 裝置之薄型化。進而,該光學片巾,為了於外表面形成微 細之凸部而使防黏層中含有填料,但不含先前的光學片中 之樹脂珠粒,&amp;而,可於實施利用擠出成形法之基材膜的 成形步驟之生產線中來積層防黏層,其結果,可省略先前 之製成光學片等基材灸之塗佈等其他步驟,從*可顯= 地提高製造作業性且促進製造成本下降。 填料之平均粒徑可大於上述防黏層之平坦部之平均厚 度。藉由如上所述使填料之平均粒徑大於防黏層之平坦部 之平均厚度,可於防黏層之外表面顯著地形成微細之凸 部’從而可進一步提高防黏性。 上述填料中,含有主成分之小徑填料、及平均粒經大 於該小徑填料之副成分之大徑填料,且該小徑填料之平均 粒控可為50 nm以上、;! 5〇 nm以下。如上所述,填料中含 有主成分之小徑填料及副成分之大徑填料,可於防黏層外 表面上’藉由主成分之小徑填料而於大致整個面上形成微 細之凸部’並藉由副成分之大徑填料而散點狀地形成有較 201005374 大的凸部,結果使防黏性顯著提高。 上述防黏層中之填料之含量, ^ a ft/ 馬2〇質量%以上、 5〇質董%以下。藉由如上所述 、、 黏層之填料之含量虚认 上述範圍内,使得形成於防黏層外表 ; ,,, 〈微細的凸部之_ 致性及密度適合於防黏,從而防黏性進一步提古。 構成上述黏合劑之聚合物可具有二 间 ,,^ χ 令—維父聯結構。藉由 如上所述使黏合劑聚合物具有三維交 ^ ... 、'口構’故防黏層内 之填料之固定性及保護性提高,增内 ,, ^ ’助於填料之均勻分 政性進而防黏性之提高。又,因黏合劑聚合物且 : 聯結構,故防黏層之光滑性及耐磨性提高。 、父 上述黏合劑可由含有丙烯酸多元 ,少此 岬夕兀知及硬化劑之聚合物 ^物㈣成。藉由如上料使㈣有㈣酸多元醇及硬 款聚合物組成物來作為黏合劑的形成材料,故而可办 易且確實地進行於基材膜上積層防黏層之積層作業,且: 合劑具有較高之透明性,進而,可藉 ,、 J楮甶硬化劑之選定而容 易地形成上述三維交聯結構。 作為上述填料,較佳為膠體二氧化妙。上述膠體 化石夕於防黏層中之透光性優異,具有於黏合劑聚合物中之 ,好之分散性’進而有助於防黏層之耐熱性、剛性等之提 高。 作為上述小徑填料之粒徑分布之變異係數,較佳為鳩 以下。藉由如上所述使小徑填料之變異係數為2〇%以下, 可使侍形成於防黏層外表面之微細凸部之一致性及突出高 度適合於防黏,從而防黏性進一步提高。 8 201005374 上述防黏層中可分散含有抗靜電劑。藉由如上所述於 防黏層中分散含有抗靜電劑,故可賦予該光學月抗靜電 性,從而對於該光學片及重疊於其背面側之導光板、稜鏡 片等的防黏性進一步提高。 上述光學層可含有光擴散劑及其黏合劑。該光學片係 所明光擴散片,具有藉由光學層中之複數個光擴散劑而使 透射光線擴散之功能,且藉由該防黏層而具有較高之防黏 ί·生〜透光率、壳度等之均勻性、經濟性及薄膜性。 又,上述光學層亦可具有具備折射性之微細凹凸形 狀。該光學片係所謂微透鏡片、稜鏡片、扁豆狀透鏡片、 菲埋爾透鏡片等之追隨模具形狀的光學片,具有藉由各種 先學層而使透射光線聚光、朝法線方向側折射、擴散等各 種光:功能’ II由該防黏層而具有較高之防黏性、總透光 率冗度荨之均勻性、經濟性及薄膜性。 四此,使燈源所發 盈g -壯 取田彳則义孜晶 置用之背光單元中,#具備該光學片,則如上述般 :先學片具有較高之防黏性、總透光率、亮度等之均句性、 及薄膜性’因此可顯著提高燈源所發出之光 :效率,可促進目前社會上所要求之高亮度化、 卽省能量化及薄型輕量化。 、 防黏層之平坦部 平均粒徑」及「 此處,所謂「 在填料之區域。「 係體積基準之數值 粒徑分布之變異係數 之效果 201005374 如上所述,本發明之光 的總透光率,能有效地抑制 有較高的經濟性及薄膜性。 進所使用之液晶顯示裝置之 成本化及薄型化。 學片之防黏性優異、具有較高 干擾現象及亮度不均,進而具 因此,本發明之背光單元可促 高亮度化、亮度之均勻性、低 【實施方式】 叫叫盯卿3凡% +赞明之竇祐 形態。圖1係表示本發明—實施形態之光學片之示意性剖 面圖圖2係圖1之光學片之示意性仰視圖,圖3係表示 與圖之光學片形態不同之光學片之示意性剖面圖,圖丁* 係表不與SJ i及圖3之光學片形態不同之光學片之示 剖面圖。 ▲圖1之光學# 1係光擴散片,其具備:基材膜2、積層 於该基材膜2的背面之防黏層3、及積層於基材膜2之表面 之光學層4。 基材膜2必須可使光線透過,因此其係由透明、尤其 疋無色透明之合成樹脂形成。對於該基材膜2中所使用之 一成樹月曰並無特別限定’例如可列舉:聚對苯二甲酸乙_ §曰&amp;奈二曱酸乙二醇酯等聚酯系聚合物,二乙醯基纖維 素、三乙醯基纖維素等纖維素系聚合物,聚碳酸酯系聚合 物’聚甲基丙烯酸曱酯等丙烯酸系聚合物,聚苯乙烯、丙 婦猜'笨乙稀共聚物等苯乙烯系聚合物,聚乙烯、聚丙稀、 具有環狀乃至降冰片烯構造之聚烯烴、乙烯-丙烯共聚物等 烯蛵系聚合物,氣乙烯系聚合物’尼龍或芳香族聚醯胺等 201005374 醯胺系聚合物,醯亞胺系聚合物 聚合物,聚鍵_系聚合物 # “聚合物,聚越礙系 系聚合物,㉟二氯乙烯系聚合物本硫醚系聚合物,乙烯醇 芳酯系聚合物,聚f盤系聚合物二婦縮丁酸系聚合物, 中,較佳為透明性優異、強度較* μ基系聚合物等。其 更佳為可换性能得到改善之^二之聚對苯二歹酸乙二醋, 作為該基材膜2之形成材料本上一1酸乙二,旨。201005374 VI. Description of the Invention: [Technical Fields According to the Invention] H-Day and the Moon are related to an optical sheet and a backlight unit using the same, and the present invention relates to a method for diffusing transmitted light and refracting toward the normal side. The optical function of collecting light, etc., and is particularly suitable for use in an optical sheet and a backlight unit in a liquid crystal display device. [Prior Art] In the liquid crystal display device, a backlight system in which a liquid crystal layer is irradiated from the back surface to emit light is generally used, and a backlight unit such as an end surface illumination type or a direct type is provided on the lower surface side of the liquid crystal layer. As shown in Fig. 5(a), the end-illuminated backlight unit 50 basically includes a linear light source 51 as a light source and a square plate-shaped light guide plate having end portions arranged along the light source 51. 52. And a plurality of optical sheets laminated on the light guide plate 52. The optical sheet has a predetermined optical function such as a function of refracting the peak direction of the light toward the normal direction side and a function of diffusing the luminance distribution, and specifically, the light diffusion sheet 53 and the edge disposed on the surface side of the light guide plate 52. Lens 54 and the like. Further, although not shown, in addition to the light diffusion sheet 53 and the cymbal sheet 54, the optical sheet may be provided with a reflection sheet disposed on the back side of the light guide plate 52 or a lenticular sheet having a microlens array on its surface. . Hereinafter, the function of the backlight unit 50 will be described. First, the light incident from the light source 51 to the light guide plate 52 is reflected by the back surface of the light guide plate 52, and the reflection sheet disposed on the back side of the light guide plate 52 (not shown). Each side surface of the light guide plate W is reflected and emitted from the surface of the light guide plate 52. The light emitted from the light guide plate 52 is incident on the light-diffusing sheet 53, and is diffused and folded toward the normal direction by a predetermined optical action such as 201005374 to be emitted from the surface of the light-diffusing sheet 53. After that, the light emitted from the light-diffusing sheet 53 is incident on the cymbal sheet 54, and is emitted as a light having a distribution of I-peaks in a substantially normal direction by the prism portion 54a formed on the surface thereof. As described above, the light emitted from the light source and the light emitted from the light source 52 is refracted toward the surface side by the light guide plate 52, and is diffused by the light diffusion sheet 53, and the composite lens 54 is substantially vertically The direction is refracted so as to refract the entire surface of the liquid crystal layer (not shown). Further, although not shown, another prism sheet or another prism sheet may be further disposed on the surface side of the cymbal sheet 54. The backlight unit of the light diffusion sheet. 'As the prior light diffusion sheet 53', as shown in FIG. 5(b), the base film 55, the light diffusion layer % formed on the surface of the base film 55, and the laminate are The anti-adhesion layer 57 on the back surface of the base film 55 (for example, see Japanese Patent Laid-Open Publication No. Hei 2-89007, etc.). The light diffusion layer 56 is configured to have a light diffusing function for transmitted light, and the light diffusing agent is contained in the adhesive 58. In the above-described light diffusing film 53, the anti-adhesion layer 57 is formed by coating a resin composition constituting a binder, a resin bead 61, and a solvent as a resin composition on the back surface of the base film 55, and a binder. Resin beads 61 dispersed in 6〇 by the tree The bead 61 has a convex portion on the back surface. The convex portion formed on the back surface of the anti-adhesion layer 57 prevents the back surface of the light-diffusing sheet 53 from being adhered to the light guide plate 52 and the like to cause interference fringes. From the viewpoint of adhesion, the resin beads 6 1 of the above-mentioned release layer 57 may be acrylate beads having an average particle diameter of 5 #m to 2 Å, etc. Therefore, the above-mentioned release layer 57 may be used in the resin beads 61. The reflection of the interface and the refraction of 201005374 cause a certain degree of scattering of light incident from the back surface. The light diffusion sheet 53 of the above-mentioned light may cause a decrease in optical function such as light transmittance due to the release layer 57. Further, in order to fix the resin beads 61 having the above average particle diameter, the average thickness of the word anti-adhesion layer 57 is set to 5 or more and &quot;claws or less. 2. The light diffusion sheet 53 of the above-mentioned precursor is contrary to the current liquid crystal. The requirement for the squeezing of the display device' and the transmission of light by the refraction at the two interfaces of the anti-adhesive layer 57 may cause duplication, etc. Further, since the anti-adhesion layer 57 contains resin beads 6 丨, so especially the convex part of the back It may become relatively soft', and may be damaged during assembly or storage and transportation of the liquid crystal display device. If the back surface of the anti-adhesion layer 57 is damaged, liquid crystal display device may be generated due to scattering of light. Further, the image redundancy is lowered, and unevenness in brightness, etc. occurs. Further, since the release layer 57 is formed by coating or the like as described above, when the light diffusion sheet 53 is manufactured, at least three steps are required: the substrate film is required. The step of forming 55, the step of forming the light-diffusing layer 56 on the surface of the base film 55, and the step of laminating the anti-adhesion layer 57 on the back surface of the base film 55 and reducing the manufacturing cost in order to achieve the current requirements The manufacturing process is required to be simplified. The disadvantages of the light diffusing sheet 53 also occur in the cymbal sheet 54, or other lenticular sheet, lenticular lens sheet, Fresnel lens sheet or the like. [Patent Document 1] Japanese Patent Laid-Open Publication No. 2000-89007 [Draft of the Invention] 201005374 The present invention is based on the fact that the above-mentioned types of anti-adhesive properties are excellent, and the purpose of the invention is to provide a phenomenon and brightness. Unevenness, advancement: the first rate, the optical means capable of effectively suppressing the interference sheet and the backlight unit using the same, and the optical means for solving the above problems are as follows: An optical sheet having a transparency The optical layer m on one side of the film, the base film, and the layered on the substrate are laminated on the substrate, and are characterized in that: one side of the anti-adhesive layer, the anti-adhesive layer contains a filler and a resin binder thereof, and an anti-adhesive layer The flat sweeping portion is taken down, the average thickness of P is 50 or more, and the (10) surface is averaged by the filler; 彳& is 7 〇nm or more and 2 〇〇nm or less at 7 Λ. Anti-adhesive::=The anti-adhesive layer contains filler and resin binder. The average thickness of the anti-adhesive layer is Μ _ The average particle size of the above filler is 70nm or more, 2〇〇, 〇_ to: , Nano-sized filler, can be below the claws. Therefore, the fine protrusions are made by the fine convex part. The fruit is densely and evenly formed on the outer surface. The dense and uniform hooks are scattered and the spots are scattered. And the right dice guides the first board, the bracts and so on. Therefore, the light has a relatively 'anti-sticking property and can prevent interference fringes due to adhesion. 〇W towel, play (4) (4) The average particle size is Γ =, - τ, therefore, the average particle size of the filler is less than: see the wavelength of light, even S? λ 4 · Gu Η ° people filler ' can also Significantly reduce the barrier to light transmission 6 201005374, so it has a higher total light transmittance. Further, in the optical sheet, the average thickness of the flat portion of the release layer is 5 〇 nmui, 15 〇, so that the average thickness of the flat portion of the release layer is smaller than the wavelength of visible light, and the two of the release layer can be reduced. The transmission 弁 green generated by the refraction at the interface &gt; 45 jb a ''' interference sees 'can effectively suppress the generation of embossing and the like. Further, in the optical sheet, the average thickness of the flat portion of the release layer is remarkably smaller than the previous average thickness, and I can promote the thinning of the currently required liquid crystal display device. Further, the optical sheet has a filler in the release layer in order to form a fine convex portion on the outer surface, but does not contain the resin beads in the prior optical sheet, and can be subjected to extrusion molding. In the production line of the step of forming the base film, the anti-adhesive layer is laminated, and as a result, other steps such as coating of the base material such as the optical sheet can be omitted, and the manufacturing workability can be improved and promoted. Manufacturing costs have fallen. The average particle size of the filler may be greater than the average thickness of the flat portion of the release layer. By making the average particle diameter of the filler larger than the average thickness of the flat portion of the release layer as described above, the fine convex portion can be remarkably formed on the outer surface of the release layer to further improve the release resistance. In the above filler, a small-diameter filler containing a main component and a large-diameter filler having an average particle larger than a subcomponent of the small-diameter filler, and the average particle size of the small-diameter filler may be 50 nm or more; . As described above, the filler containing a small-diameter filler of a main component and a large-diameter filler of a subcomponent can form a fine convex portion on substantially the entire surface by the small-diameter filler of the main component on the outer surface of the anti-adhesive layer. Further, a convex portion larger than 201005374 is formed in a scattered manner by the large-diameter filler of the subcomponent, and as a result, the anti-sticking property is remarkably improved. The content of the filler in the above anti-adhesion layer is ^ a ft / horse 2 〇 mass % or more, and 5 〇 mass % % or less. By the above-mentioned, the content of the filler of the adhesive layer is imaginary within the above range, so that it is formed on the outer surface of the anti-adhesive layer; ,, <The fineness and density of the fine convex portion are suitable for anti-adhesion, thereby preventing stickiness Further mention the ancient. The polymer constituting the above binder may have two, ^ 令 - - - - - - - - - - - - - - - - - - - - - - - By making the adhesive polymer have a three-dimensional cross-linking and 'mouth structure' as described above, the fixing property and the protective property of the filler in the anti-adhesive layer are improved, and the inside of the adhesive is assisted. Sex and anti-adhesion. Further, due to the binder polymer and the joint structure, the smoothness and wear resistance of the anti-adhesive layer are improved. The parent may be made of a polymer containing four parts of acrylic acid, less of which is known as a hardening agent. By using (iv) a (tetra) acid polyol and a hard polymer composition as a material for forming a binder as described above, it is possible to easily and surely perform a lamination operation of laminating an anti-adhesive layer on a substrate film, and: a mixture It has high transparency, and further, the three-dimensional crosslinked structure can be easily formed by the selection of the J楮甶 hardener. As the above filler, colloidal oxidizing is preferred. The colloidal fossil is excellent in light transmittance in the anti-adhesive layer, and has a good dispersibility in the binder polymer, which contributes to an improvement in heat resistance and rigidity of the anti-adhesive layer. The coefficient of variation of the particle size distribution of the small-diameter filler is preferably 鸠 or less. By setting the coefficient of variation of the small-diameter filler to 2% or less as described above, the uniformity and the protrusion height of the fine convex portions formed on the outer surface of the release layer can be made suitable for anti-adhesion, and the anti-adhesive property is further improved. 8 201005374 The above anti-adhesive layer can be dispersed and contains an antistatic agent. By dispersing the antistatic agent in the anti-adhesion layer as described above, the optical moon antistatic property can be imparted, and the anti-stick property of the optical sheet and the light guide plate, the ruthenium sheet and the like which are superimposed on the back side thereof can be further improved. . The above optical layer may contain a light diffusing agent and a binder thereof. The optical sheet is characterized in that the light diffusing sheet has a function of diffusing transmitted light by a plurality of light diffusing agents in the optical layer, and has a high anti-adhesion property to light transmittance by the anti-adhesive layer. Uniformity, economy and film properties of shell and the like. Further, the optical layer may have a fine uneven shape having refractive properties. The optical sheet is an optical sheet that follows a mold shape, such as a microlens sheet, a cymbal sheet, a lentil lens sheet, or a phenanthrene lens sheet, and has a plurality of precursor layers to condense transmitted light toward the normal direction side. Various kinds of light such as refraction and diffusion: The function 'II has high anti-adhesion property, uniformity of total transmittance, uniformity, economy and film property. In this case, the light source is used to generate the surplus g-strong, and the optical unit is used in the backlight unit. The optical film is as described above: the first film has high anti-adhesiveness and total transparency. The uniformity of the light rate and brightness, as well as the film properties, can significantly increase the light emitted by the light source: efficiency, which can promote the high brightness, energy saving and thin weight reduction required by the society. , the average particle diameter of the flat portion of the anti-adhesive layer, and "here, the "in the region of the filler." The effect of the coefficient of variation of the numerical particle size distribution of the volumetric reference 201005374 As described above, the total light transmission of the light of the present invention Rate, can effectively suppress high economical and thin film. The cost and thinness of the liquid crystal display device used in the process. The film has excellent anti-sticking property, high interference phenomenon and uneven brightness, and thus Therefore, the backlight unit of the present invention can promote high brightness, uniformity of brightness, and low [embodiment], which is called the singularity of the singularity of the singularity of the invention. FIG. 1 is a view showing the optical sheet of the present invention. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 2 is a schematic bottom view of the optical sheet of FIG. 1, and FIG. 3 is a schematic cross-sectional view showing an optical sheet different from the form of the optical sheet of the drawing, and the drawing is not related to SJ i and FIG. A cross-sectional view of an optical sheet having different optical sheet shapes. ▲ Optical #1 light diffusing sheet of Fig. 1 comprising: a base film 2, an anti-adhesive layer 3 laminated on the back surface of the base film 2, and a laminate The optical layer 4 on the surface of the substrate film 2. The base film 2 must be made to transmit light, and therefore it is formed of a transparent, especially colorless, transparent synthetic resin. The one used in the base film 2 is not particularly limited. For example, a pair can be cited. Polyester polymer such as ethylene phthalate _ 曰 曰 &amp; ethylene glycol dicarboxylate, cellulose polymer such as diethyl hydrazine cellulose or triethylene fluorenyl cellulose, polycarbonate polymer 'Polyacrylic polymers such as polymethyl methacrylate, styrenic polymers such as polystyrene, Cyanchao's stupid ethylene copolymer, polyethylene, polypropylene, polyolefin with cyclic or even norbornene structure , an olefin polymer such as an ethylene-propylene copolymer, a gas-vinyl polymer, a nylon or an aromatic polyamine, etc. 201005374 a guanamine polymer, a ruthenium-based polymer polymer, a poly bond _-polymer # "Polymer, polymerization polymer, 35 dichloroethylene polymer, this thioether polymer, vinyl aryl ester polymer, poly f disk polymer dibutyric acid polymer, medium Preferably, the transparency is excellent, and the strength is higher than that of the *μ base polymerization. Wait. More preferably, it is a polyethylene terephthalate which is improved in exchangeability, and is used as a material for forming the base film 2.

種或混合使用2種以上。又, 逑私合物可單獨使用J 候性、機械性質、尺寸穩定性I進了對加工性、耐熱性、耐 材膜2之形成材料^昆合入各種二改善、改質,可於基 例如可列舉··潤滑劑、交聯劑〃 &quot;°作為該添加劑, 劑、防焰劑、絡治添, 知丨、抗靜電劑、阻燃 防焰劑、發泡劑、防黴劑、填料 劣化劑、分散劑等。 、 ,/、、可塑劑、防 對於基材臈2之厚度(平 較佳為無特別限定,但 1RR 250 &quot;m以下,更佳為20 以上、 188 # m以下。若基材膜2 上 2 ^ μ 、之厚度未達上述範圍,則當基 材膜之表面上積層有用於形成光學層(用於作為光學片 而發揮功能之層)之聚合物組成物時,易於發生捲曲、使 用^困難4問題。反之1基材膜2之厚度超過上述範圍, 則安裝有該光學片1之液晶顯示裝置之亮度可能會下降, 且背光單元之厚唐掩4· y/Λ X曰大,從而亦有悖於液晶顯示裝置之 型化要求。 ' 防黏層3合有:以層狀並且間隔配設之複數個填料5、 11 201005374 及將該填料5固定 黏合齊&quot;之背面(二::之背面側的黏合劑6。藉由自 之背而埒 卜表面)大出之填料5,而於該防黏層3 與導光 凸邻7。因此,若將該光學片i 之表面,從而層’則以背面之凸部7抵接於導光板等 夢此可&lt; #光學片1之整個背面與導光板等相抵接。 …1:止光學片1與導光板等之黏附,且抑制液晶顯 不展置之晝面上產生亮度不均。 機填Γ:!:5之具體材料,可大致區分為無機填料與有 =二為該無機填料,例如可使用:選自元素週期表 ^ 6族之几素(例如石夕、紹、辞、欽、結等)之 =物:氫氧化铭、硫化鋇、石夕酸鎮或者該等之混合物。 較j之2為’容易獲得奈米級之粒徑、且光線之遮蔽性 =Γ二氧切。x,作為有機填料,例如可使用: 〇曰㈣腈樹脂、聚胺基甲酸|旨、聚氣乙烯、 t、聚丙烯腈'聚醢胺等。其中,較佳為硬化後之 ;月:較…晞酸系樹脂,更佳為聚甲基丙稀酸甲醋 (MA,polymethyl methacrylate)。 對於填料5之形狀並無特別限定,例如可列舉:球狀' :錘=針狀、棒狀、立方體狀 '板狀、鱗片狀、纖維狀 孚’其中’較佳為凸部7形忐 办珉於防黏層3之背面之形成性 優/、、表現出良好之防黏性之球狀。 作為填料5之平均粒徑的下限,較佳為7()_,更佳為 l°0nm。另一方面’作為填料5之平均粒捏之上限,較佳 :、200nm,更佳為15〇_。若填料5之平均粒徑未達上述 12 201005374 下限,則表面能量會婵古,从工 黏合劑6 t,而且,二::斗:能難以分散含有於 之…變小,從而有可能 填料5之平均粒徑超過上述上限,==。反之,若 得遮蔽光線之穿透的效果 ^長之影響而使 之總透光率下降。,,料H而於可能會導致該光學片1 之填料5的防黏層3,即便不 t上述平均粒徑範圍内 之背面的县…”更不形成使其容易接著於基材膜2 物,從而可降低製造成本:ί二直r積層防黏層用組成 你也人士 攻丰只現輕量化及薄膜化。進而, =有上述奈米尺寸之填料5之防黏層3,除了上述透光 防黏性外,抗靜電效果及防止損傷之效果亦良好。 防黏層3中之填料5之含量(防黏層用組成物中之以 固體成分換算之含量)的下限,較佳為2〇質量%,更㈣ 另一方面,作為填料5之含量之上限,較佳為 ⑽里’更佳$ 40質量%。若填料5之含量小於上述下 限’則形成於防黏…背面的凸部7之均勾分散性及密 度會下降,從而可能無法充分地獲得防黏效果。另一方面 若填料5之含量超過上述上限,則無法進一步提高防黏效 果’從而可能導致透光性下降。 作為填料5之粒徑分布之變異係數,較佳為2〇%以下, 更佳為10%以下。藉由使填料5之變異係數處於上述範圍, 防黏層3之背面上所形成之微細…&quot;之突出高度的均 勻性提高,從而防黏性進一步提高。又,藉由使填料5之 變異係數處於上述範圍内,可促進不利於防黏之小徑填料$ 13 201005374 之減V化及單位面積内之填料5之減少化,且可促進防 上述防黏層3上之散射等而導致光學功能下降之效果。 黏合劑6可藉由使含有基材聚合物之聚合物組成物硬 化而形成ϋ由邊黏合劑6,使填料5以大致相等的密度配 置固定於基材膜2之背面。 就提高透光性之觀點而言,黏合劑6中所使用之基材 聚σ物本身較佳為透明纟,更佳為無色透明者。對於該基 材聚合物並無特別限定,例如可列舉:聚曱基丙烯酸、聚 竣土本基甲基丙稀醯胺等聚曱基丙烯酸系樹脂,以聚(聯苯 基)苯乙稀等聚苯乙烯系樹脂等為代表之聚稀烴系樹脂,以 聚(2,6 一曱基_ι,4_苯醚)為代表之聚醚系樹脂,以聚(氧基羰 氧基-Μ-伸苯基異亞丙基—Μ_伸苯基)為代表之聚碳酸酯系 樹脂,以聚(氧基_2,2,4,4_四甲基],3_環伸丁基氧基對苯二 甲醯基)為代表之聚g旨系、樹脂,以聚(氧基Ή苯基績酿基 -1,4-伸苯基)、聚(氧基·Μ-伸笨基異亞丙基巧’4•伸苯基氧基 -:,4-伸苯基續醯基_Μ_伸苯基)等為代表之聚石風系樹脂,以 聚(亞胺基間苯二甲醯基亞胺基_4,4’_伸聯苯基)為代表之聚 醯胺系樹脂,以聚(硫代―丨,‘伸苯基磺醯基_丨,4_伸苯基)為代 表之聚硫化物系樹脂’不飽和聚醋系樹脂,環氧系樹脂,Two or more types are used in combination or in combination. In addition, 逑 合物 可 可 可 可 可 可 可 可 可 可 可 可 可 可 可 可 可 可 可 可 可 可 可 可 可 可 可 可 可 可 可 可 可 可 可 可 可 可 可 可 可 可 可 可 可 可For example, lubricants and cross-linking agents quot &quot;° as the additive, agent, anti-flame agent, collateral, knowing, antistatic agent, flame retardant, flame retardant, foaming agent, antifungal agent, A filler deterioration agent, a dispersant, or the like. , /,, plasticizer, anti-layer thickness of the substrate ( 2 (flat is preferably not particularly limited, but 1RR 250 &quot; m or less, more preferably 20 or more, 188 # m or less. If the substrate film 2 When the thickness of 2 ^ μ is less than the above range, when a polymer composition for forming an optical layer (a layer for functioning as an optical sheet) is laminated on the surface of the base film, curling and use are liable to occur. Difficult problem 4. On the other hand, if the thickness of the substrate film 2 exceeds the above range, the brightness of the liquid crystal display device on which the optical sheet 1 is mounted may be lowered, and the thickness of the backlight unit is large, so that the thickness of the backlight unit is large. There is also a need for the type of liquid crystal display device. 'The anti-adhesive layer 3 is composed of a plurality of fillers 5, 11 201005374 which are layered and spaced apart, and the back of the filler 5 is fixedly bonded (2: : the adhesive 6 on the back side, by means of the back surface, the filler 5 is enlarged, and the anti-adhesion layer 3 is adjacent to the light guiding protrusion 7. Therefore, if the surface of the optical sheet i is Therefore, the layer 'will be abutted on the light guide plate by the convex portion 7 on the back side. The entire back surface of 1 is in contact with the light guide plate, etc. ...1: The optical sheet 1 is adhered to the light guide plate and the like, and unevenness of brightness is generated on the surface of the liquid crystal which is prevented from being displayed. Machine filling: :: 5 specific The material can be roughly classified into an inorganic filler and the second is the inorganic filler, and for example, it can be used: a substance selected from the group of the elements of the periodic table (for example, Shi Xi, Shao, Ci, Qin, Kie, etc.): Hydroxide, strontium sulphide, sulphuric acid or a mixture of these. Compared with 2, it is 'easy to obtain the particle size of the nanometer, and the shielding of light = erbium dioxide. x, as an organic filler, for example Can be used: 〇曰 (4) nitrile resin, polyaminocarboxylic acid | purpose, polyethylene, t, polyacrylonitrile 'polyamide, etc. Among them, preferably after hardening; month: more than ... tannic acid resin, more The shape of the filler 5 is not particularly limited, and examples thereof include a spherical shape: a hammer = a needle shape, a rod shape, a cubic shape, a plate shape, and a scale. Shape, fiber shape, which is preferably a convex portion 7 shape, and the formation of the back surface of the anti-adhesion layer 3 is excellent, and performance A good anti-adhesive spherical shape. The lower limit of the average particle diameter of the filler 5 is preferably 7 () _, more preferably 1 ° 0 nm. On the other hand, the upper limit of the average granule pinch as the filler 5 is Good: 200nm, more preferably 15〇_. If the average particle size of the filler 5 does not reach the lower limit of 12 201005374, the surface energy will be old, the work adhesive is 6 t, and, the second:: bucket: can be difficult to disperse The content contained therein becomes small, so that it is possible that the average particle diameter of the filler 5 exceeds the above upper limit, ==. Conversely, if the effect of blocking the penetration of the light is long, the total light transmittance is lowered. H may cause the anti-adhesive layer 3 of the filler 5 of the optical sheet 1 to be formed so as not to be easily adhered to the substrate film 2 even if it is not t (the county having the back surface within the above average particle diameter range). Reduce the cost of manufacturing: ί 二直 r laminated anti-adhesive layer with the composition of you also people who are only lightweight and thin film. Further, the anti-adhesive layer 3 having the above-mentioned nano-sized filler 5 has an antistatic effect and an effect of preventing damage in addition to the above-mentioned light-transmitting and anti-adhesive property. The lower limit of the content of the filler 5 in the anti-adhesive layer 3 (the content in terms of solid content in the composition for the anti-adhesive layer) is preferably 2% by mass, more preferably, the upper limit of the content of the filler 5 is on the other hand. Preferably, (10) is 'better $ 40% by mass. If the content of the filler 5 is less than the above lower limit, the uniform dispersibility and density of the convex portion 7 formed on the back surface of the anti-adhesion may be lowered, and the anti-adhesive effect may not be sufficiently obtained. On the other hand, if the content of the filler 5 exceeds the above upper limit, the anti-sticking effect cannot be further improved, and the light transmittance may be lowered. The coefficient of variation of the particle size distribution of the filler 5 is preferably 2% by mole or less, more preferably 10% or less. By setting the coefficient of variation of the filler 5 in the above range, the uniformity of the protrusion height formed on the back surface of the anti-adhesion layer 3 is improved, and the anti-sticking property is further improved. Further, by making the coefficient of variation of the filler 5 within the above range, the reduction of the V of the small-diameter filler which is unfavorable for the anti-adhesion, and the reduction of the filler 5 per unit area can be promoted, and the anti-adhesion prevention can be promoted. The scattering or the like on the layer 3 causes an effect of a decrease in optical function. The binder 6 can be formed by hardening the polymer composition containing the base polymer to form the crucible edge-bonding agent 6, and the filler 5 can be fixed to the back surface of the base film 2 at substantially equal density. From the viewpoint of improving light transmittance, the substrate yttrium used in the binder 6 itself is preferably a transparent ruthenium, more preferably a colorless transparent one. The base polymer is not particularly limited, and examples thereof include poly(methacrylic) resins such as poly(methacrylic acid) and polybenzal methyl acrylamide, and poly(biphenyl)styrene. A polyether-based resin represented by a polystyrene-based resin or the like, a polyether-based resin typified by poly(2,6-fluorenyl-, 4-phenylene ether), and a poly(oxycarbonyloxy-oxime) -Polyphenyl-based resin represented by phenyl isopropylidene-yttrium-phenylene), poly(oxy-2,2,4,4-tetramethyl), 3_cyclobutyloxy (p-phenylene fluorenyl) is a polyglycol, a resin, a poly(oxyindoleyl-phenylene-phenylene), a poly(oxyanthracepin-1,4-phenylene group) A fluorinated wind-based resin represented by propylene, '4, phenyloxy-:, 4-phenylphenyl fluorenyl hydrazine a polyamido-based resin represented by a mercapto imido group, 4,4'-biphenyl), which is a poly(thio-anthracene, 'phenylphenylsulfonyl-[,phenylphenylene]-phenyl) Represented polysulfide resin 'unsaturated polyester resin, epoxy resin,

三聚氰胺«脂,鄰苯二甲酸二烯丙醋系樹脂,紛系樹脂 聚醯亞胺系樹脂,聚磷腈系樹脂,由有機烷氧基矽烷化&lt; 物所構成之⑦氧㈣脂等;該等聚合物可使用丨種或混^ 使用2種以上。 E 尤其自加工性高 利用塗佈等方法可容易地形 成防黏 14 201005374 層3之方面而言,上述基材聚合物較佳為多元醇。又自 下述二維交聯結構之形成性方面而言, ° 上返基材聚合物較 佳為聚烯烴系共聚物。 可如圖2所示具有三維交聯 6之聚合物1〇具有三維交聯 的固定性及保護性提高,且 至防黏性之提高。而且,因 故而防黏層3之硬度、光滑 構成黏合劑6之聚合物1 〇 結構。因如上所述構成黏合劑 結構,故防黏層3内之填料5 有助於填料5之均勻分散性乃 聚合物1 0具有三維交聯結構, 性、对磨性等提高。 對於構成該三維交聯έ士播夕士 .+^ 再父%構之方法亚無特別限定,可採 =知:方法,一般而言’該三維交聯結構可藉由使上述 基材I物之聚合組成物中含有具有2個以上不飽和基之 多官能早體而形成。所謂該具有2個以上不飽和基之多宫 能單體’係指具有2個以上可與單體或預聚合物進行丘聚 合的不飽和官能基之單體,作為可進行共聚合之官能基, Ζ列舉··乙基乙縣、丙烯醯基、甲基丙稀醒基 又 刀子中含有2個以上不同的可進行乒聚人之官 能基之單體,,亦包含於本發明中之多官能單體。—— 作為該具有2個以上不飽和基之多官能單體,例如可 =舉:乙二醇二(甲基)丙稀酸醋、二乙二醇二(甲基)丙稀酸 Γ三乙二醇二(甲基)丙婦酸醋、甘油㈡三甲基)丙烯酸 -曰、二!甲基丙炫(二/三)(甲基)丙稀酸醋、季戊四醇(二/三 /四)(甲基)丙稀酸醋等之多元醇的二_(甲基)丙婦酸醋類、三 _(甲基)丙稀酸醋類、四(甲基)丙烯酸醋類;對二乙稀基苯、 15 201005374 鄰二乙烯基苯等之# 西旨、(甲丙能單體;(甲基)丙烯酸乙烯基 西曰(甲基)丙烯酸稀丙基酉旨等之醋類;丁二稀 —烯等之二烯類;以二氯 導入之具有磷腈骨架之單體原料且將聚合多官能基 有雜原子環狀骨架之多官能單料。 # 該具有2個以上不餘知其々夕a ,..^ 土之夕g能單體的配合量’較 佳為二維父聯聚合物中合 里权 … 質量%以上、80質量%以下。 未達上述_,存在無法 而導致耐熱性、耐溶劑性等 仃-維又和 合量超過上述範圍,則有時合I:1向。另-方面,若配 膠之特性下降。則有時會使耐撞擊性等下降、作為塑 作為上述多元醇,例如可列舉: 單士、八有3經基不飽和 早體之早體成刀進行聚合而獲得之 之鉻杜下媒&quot;々取々 夕兀知、或在過量羥基 之條件下獲仵之聚醋多元醇等,料 合使用2種以上。 珣使用,或者犯 作為含羥基不飽和單體,可列兴. 翔其7_ 牛· ( a)例如丙烯酸2- 包基乙S曰、丙烯酸2-羥基丙酯、曱其 m 〇 土丙稀®夂2-經基乙g旨、 基丙烯酸2·經基丙醋、丙烯醇、高丙稀醇 豆醇等含經基之不飽和單體;(b)例如 皮二 丙二醇、環氧丙烷、丁二醇、環氧 展巩 環己烷、苯基縮水甘油基醚、癸酸縮 1土 土) r n . , β /由酉曰、Placcel FM-1 C Da1Cel Chetmcal Industries 股份有限公 一 或環氧基化合物,與例如丙烯酸、甲 2元酵 缺 T基丙烯酸 '順丁烯二 馱、反丁烯二酸、丁烯酸 '衣康酸等 寺不飽和綾酸進行反應 16 201005374 而獲得之含羥基之不飽和單體等。可將選自該等含羥基之 不飽和單體中之1種或2種以上進行聚合而製造上述多元 醇。 又,上述多元醇亦可將選自丙烯酸乙酯、丙烯酸正丙 酯、丙浠酸異丙酯、丙烯酸正丁酯、丙烯酸第三丁酯、丙 稀酸乙基己酯、曱基丙烯酸乙酯、曱基丙稀酸正丙酯、甲 基丙稀酸異丙酯、甲基丙稀酸正丁酯、甲基丙浠酸第三丁 酯、曱基丙烯酸乙基己酯、曱基丙稀酸縮水甘油酯、甲基 丙烯酸環己酯、苯乙烯、乙烯基曱苯、丨_甲基苯乙烯、丙烯 酸、曱基丙烯酸、丙烯腈、乙酸乙烯酯、丙酸乙烯酯、硬 脂酸乙稀酯、乙酸丙稀酯、己二酸二烯丙酯、衣康酸二稀 丙酿、順丁烯二酸二乙酯、氯乙浠、偏二氯乙嫦、丙烯醯 胺、N-經甲基丙烯醯胺、N_ 丁氧基甲基丙烯醯胺、雙丙酮 丙稀醯胺、乙烯、丙烯、異丁烯等中之1種或2種以上乙 稀性不飽和單體’與選自上述(a)及(b)中之含羥基不飽 和單體進行聚合而製造。 使含有含經基不飽和單體之單體成分進行聚合而獲得 之多元醇的數量平均分子量為1⑽〇以上、5〇〇〇〇〇以下,較 佳為5000以上、1〇〇〇〇〇以下。又,其羥值為$以上、3〇〇 乂下’較佳為10以上、2〇〇以下,更佳為2〇以上、15〇以 下。 作為在過量經基之條件下而獲得之聚酯多元醇,可使 (e)例如乙二醇、二乙二醇、丙二醇、二丙二醇、-丁 一醇、1,4_丁二醇、戊二醇、新戊二醇、ι,6-己二醇、 17 201005374 1,10-癸二醇、2,2,4-二甲其113;^-;1(^ ^ —曱基_1,3-戍一酵、三羥甲基丙烷、己 三酵、丙三醇、季戊四醇、環己二醇、氣化雙盼A、錄 基甲基)環己&amp;、對苯二盼雙(羥基乙趟)、異氰尿酸三⑽基 乙基)醋、鄰苯二甲醇等多元醇,與⑷例如順丁稀二酸、 反丁烯二酸、丁二酸、己二酸、癸二酸、壬二酸、偏苯三 甲酸、對苯二甲酸、鄰苯二甲酸、間苯二甲酸等多元酸, 於丙一醇、已一醇、聚乙二醇、三羥曱基丙烷等多元醇中 的經基數多於上述多元酸的竣基數之條件下進行反應而製 造° 該在過量羥基之條件下而獲得之聚酯多元醇的數量平 均分子量為500以上、300000以下’較佳為2〇〇〇以上' 麵⑼以下。又,其經值為5以上、3〇〇以下,較佳為⑺ 以上、2〇〇以下,更佳為2〇以上、ι5〇以下。 作為用作該聚合物組成物之基材聚合物的多元醇,較 佳為,將含有上述聚酯多元醇及上述含羥基不飽和單體之 單體成分進行聚合而獲得之具有(甲基)丙烯醯基單元等的 丙烯酸多元醇。將該聚酯多元醇或丙烯酸多元醇作為基材 聚合物之黏合劑6的财候性較高’可抑制防黏層3之黃變 專。再者’可使用該聚醋多元醇及丙烯酸多元醇中之任— 者’亦可使用兩者。 再者,關於上述聚酯多元醇及丙烯酸多元醇中之經其 的個數’只要滿足每1個分子中含有2個以上即可,並益 特別限定,但若固體成分中之羥值為10以下,則存在交聯 點數會減少,耐溶劑性、耐水性、耐熱性、表面硬度等被 18 201005374 膜物性下降之傾向。 作為上述基材聚合物,較佳為具有環烷基之多元醇。 如上所述,藉由對構成黏合劑6之作為基材聚合物的多元 醇中導入環院基,可使黏合劑6之斥水性、耐水性等疏水 性變高,且高溫高濕條件下該光學片丨之耐彎曲性、尺寸 穩定性等得到改善。x,使防黏4 3之耐候性、硬度、厚 度感、耐溶劑性等塗膜基本性能得到提高。進而,使黏合 劑6與表面上固定有有機聚合物之填料5之親和性、及: 料5之均勻分散性變得更佳。 對於上述環烷基並無特別限定,例如可列舉:環丁美、 環戊基、環己基、環庚基、環辛基、環壬基、環癸基、土環 十一烧基、環十二烧基、環十三烧基、環十四烧基、環十 五烧基、環十六烧基、環十七㈣、環十人貌基等。 具有上述環烧基之多元醇,係藉由使具有環院基之聚 合性不飽和單體進行共聚合而獲得。所謂該具有環烧基之 聚合性不飽和單體’係指分子内具有至少1個環院基:聚 ^生不飽和單體。對於該聚合性㈣和單體並無特別限 疋例如可列舉:(甲基)丙稀酸環己醋、(甲基)丙婦酸甲美 裱己酯、(甲基)丙烯酸第三 土 二烷基酿等。 …酉曰(甲基)丙稀酸環十 當如上述般使用多元醇作為基材聚合物時, 成物中可含有作為硬化劑之聚異氰錢化合物 令物氰酸醋進行聚合而獲得之二聚物、: t物、四聚物箅衍生物。 一 口來合物組成物中含有聚異氰酸 19 201005374 酯硬化劑,而可容易且確實地形成下述三維交聯結構,且 防黏層3之被膜物性進一步提高。又,藉由配合入聚異氰 酸酯化合物可使聚合物組成物之硬化反應速度提高,故 而,即便聚合物組成物中含有有助於微小無機填充劑之分 散穩定性的陽離子系抗靜電劑,亦可充分地彌補因陽離子 系抗靜電劑而產生之硬化反應速度之下降,從而可進一步 提高生產性。 作為上述聚異氰酸酯化合物,較佳為二曱苯二異氰酸 酯衍生物、或者該二甲苯二異氰酸酯衍生物與脂肪族二異 氰酸酯衍生物之混合物。該二甲苯二異氰酸醋衍生物,因 其對聚合物組成物的反應速度之提高效果較大,又,於芳 香族一異氰酸酯衍生物中由於熱或紫外線所造成之黃變及 劣化較j故而,可減低該光學片1之透光率的經時性下 降另方面,與芳香族二異氰酸酯衍生物相比,脂肪族 二異氰酸酯衍生物之反應速度提高效果較小,但因紫外線 等而引起之用變、劣化等極小,故而,藉由與二甲苯二異 氣S夂sa何生物相混合’可平衡性良好地達成反應速度提高 效果、及黃變等之防止效果。 上述聚異氰酸酯化合物之配合量(相對於聚合物組成 物中之聚0物成分i00份之經固體成分換算之配合量)的 下限’較佳為2份’更佳為5份。另一方面,硬化劑之上 述配合量之上限較佳為2G份,更佳為15份。藉由如上所 述使聚異氰酸酯化合物之配合量處於上述範圍,可使上述 聚合物組成物有效地發揮提高硬化反應速度之作用。 20 201005374 作為上述無機填料5,可使用其表面固定㈣機聚合物 。藉由如上所述使用固定有有機聚合物之無機填料5,可 提高黏合劑6中之分散性或與黏合劑6之親和性。關於該 固定之有機聚合物,其分子量、形狀、組成、官能基之有 無專方面並無特別限定,可使用任意之有機聚合物。又, 關於有機聚σ物之形狀,可採用直鍵狀、支鍵狀、交聯結 構等任意形狀。 f 為構成上述有機聚合物之具體樹赌,例如可列舉:(甲 基)丙烯酸系樹脂、聚苯乙烯、聚醋酸乙烯酯、聚乙烯或聚 丙烯等聚烯烴、聚氣乙稀、偏二氯乙烯、聚對苯二甲酸乙 二酯等聚酯以及該等之共聚物;或利用胺基、環氧基、羥 基、羧基等官能基進行部分改質後所得之樹脂等。其中, 將(甲基)丙烯酸系樹脂、(甲基)丙稀酸_苯乙稀系樹脂、(甲 基)丙烯酸-聚醋系樹脂等含有(甲基)丙烯酸單元之有機聚合 物作為必需成分者,具有被膜形成功能,故較佳。另一方 I 面較佳為與上述聚合物組成物的基材聚合物具有相溶性 之樹脂,因此,最佳為與聚合物組成物中所含之基 物具有相同組成者。 Λ 口 —再者,無機填料5之微粒子内亦可包含有機聚合物。 藉此可賦予作為填料5的核心之無機物適度的柔軟度及 韌性。 又 作為上述有機聚合物,只要使用含有烷氧基者即可, 其含量較佳為將固定有有機聚合物之填料5每1 g中含有 0.01 mmol以上、5〇麵〇1以下。藉由該烷氧基,可提高與 21 201005374 構成黏合劑6 $ 暂ifel· Bt i nn 基貝树月曰之間的親和性、及黏合劑6中之 分散性。 上述燒氧基係表示與形成微粒子骨架之金屬元素相鍵 結之R〇基。該R為亦可被取代之烷基,微粒子中之r〇基 可相同亦可不同。作為R之具體例’可列舉例如曱基、乙 ^ 丙基異丙基、正丁基等。較佳為使用與構成填料5 之金屬相同的金屬之烷氧基’且當填才斗5為膠體二氧化矽 時’較佳為使用以矽作為金屬之烷氧基。 關於固定有有機聚合物之無輸斗5中之有機聚合物 的3有率並無特別限定,但較佳為以填料5為基準,達 到〇_5質量。/〇以上、5〇質量%以下。 口定於填料5上之上述有機聚合物’係使用含有經基 者構成黏a劑6之聚合物組成物中,可含有選自具有2 個以亡可與羥基發生反應的官能基之多官能異氰酸酯化合 物、三聚氰胺化合物及胺基樹脂中之至少1種。藉此,填 料與黏合劑6之基質樹脂以交聯結構而鍵結,從而使保 存穩定性、耐污毕性、·?Γ &amp; α , 了撓性、耐候性、保存穩定性等變 好,進而使所得被膜具有光澤。 ^,可將抗靜電劑以微分散狀態混合於聚合物組成物 中。猎由以混合有該抗靜電劑之聚合物組成物來形成黏合 劑6可使該光千片1表現出抗靜電效果,從而可防止吸附 灰塵、或因帶靜電而難以與稜鏡片等重疊等之問題。又, 若將抗靜電劑塗佈於表面,則表面會產生黏性或污濁,但 藉由如上所述而使抗靜電劑混練於聚合物組成物中可減少 22 201005374 該弊端。對於該抗靜電劑並無特 基硫酸鹽、烷基磷酸鹽等陰離子系二钶如可使用:烷 味哇琳化合物等陽離子系抗靜電劑'二電齊/;四級銨鹽、 婦山梨糖醇酐單硬脂酸醋、乙醇::二醇系、聚氧乙 劑,聚丙婦酸等高分子系抗靜電南 ^專非離子系抗靜電 :末,金屬氧化物粉末,碳奈米;等。::導電性之金屬 电效果較大之陽離子系抗靜電劑厂’較佳為抗靜 子系抗靜電劑,可發揮抗靜電效果。*加少量的該陽離 再者,作為用於形成該黏合劑 了基材聚合物、填科5、辟斗制 乏聚合物組成物,除 硬化劑、抗靜電劍 配合入例如可塑劑、分散劑、各:亦可適當 抗氧化劑、黏性改質劑、潤滑劑、光穩定:心 防黏層3之平坦部 广。 平均厚度)之下限較佳為5〇 &amp; (無填料5之區域内之 敕佳為50 nm,更佳為7〇 防黏層3之平坦部之 :〇_。另-方面, 佳為120 nm。若防 X 义較佳為15〇nm,更 右防黏層3之平均厚度τ 可能導致難以將填料s ^ 、上述下限,則 若㈣… 真枓5固疋於基材膜2的背面。另一方面, 防黏層3之平均厚度T超過上述上限,則藉 形成於黏附防止層3昝 科而 該光學以之防黏功凸部^會變小,結果可能導致 超過上述上限,二:。又,若防黏層3之平均… 生透射光線之干^見^防黏層3之兩界面上之折射而產 丁優現象,故而產生疊紋等。 防黏層3之昔而七A/r 之异術平均粗度(Ita )較佳為〇.〇5 &quot; mu上、〇.15 Mm以下,更佳為〇 〇8 μιη以上、〇 12 Μ 23 201005374 m以下。防黏層3之背面之最大高度(Ry)較佳為〇·4 &quot; 、上0.9 // m以下’更佳為〇 6 &quot; m以上、〇 7 &quot;爪以 下。防黏層3之背面之十點平均粗度(Rz)較佳為〇 3㈣ ::上、〇·8…下,更佳為〇.5…上、0.6…下。 若防黏層3之背面之算術平均粗度(叫、最大高度(^) 及十點平均粗度(Rz)小於上述範圍,則可能導致防黏層3 之背面的微細凸部減小、防黏性下降。反…防黏層3 之背面之算術平均粗度(Ra)等超過上述範圍,則可能導 致液晶顯示裝置之晝面上產生眩光,導致品質下降。 光學層4具備:大致均句配設於基材膜2的表面之複 數個光擴散劑8、及該複數個光擴散劑8之黏合劑9。該複 數個光擴散齊&quot;被黏合劑9所包覆。藉由如上所述光學層4 中所含有之複數個光擴散劑8,可使從光學層4的背侧向表 側透射之光線均句地擴散。x,藉由複㈣光擴㈣8而 於光學層4之表面上大致均句地形成微細之凹凸。藉由如 上所述形成於光學# 1的表面之微細之凹凸透鏡之折射作 用,可使光線更好地擴散。再者,對於光學層4之平均厚 度並無特別限定’例如設為i…上、3〇…下左右。 光擴散劑8係具有使朵綠j虛# 卞八韦便尤線擴散之性質之粒子,大致被 f為填料與有機填料。作為填料,例如可使用:二氧化石夕、 風氧化銘、氧化銘、氧化鋅'硫化鎖、石夕酸鎮、或者該等 二合物。作為有機填料之材料,例如可使用:丙稀酸系 :月曰二烯腈樹脂、聚胺基甲酸sl、聚氯乙婦、聚苯乙稀、 以稀腈、聚酿胺等。以,㈣ 24 201005374 树月曰,更佳為聚τ基丙婦酸^醋㈤ma)。 、對於光擴散劑8之形狀並無特別限定,例如可列兴. 球狀、紡錘狀、針狀、樁 + 纖維狀等,其中較佳為光擴散性優異之球狀珠粒〜片狀 作為光擴散劑8之平均粒徑的下限,較佳為, 更佳為2 # m,最佳為5 取佳為5 &quot; m。另-方面,光擴散劑8之 平均粒徑之上限,較佳為 為50 ,更佳為20 ,最佳 為1…。若光擴散齊&quot;之平均粒徑未達上述範圍,則夢 由光擴散齊&quot;所形成之光學層4表面的凹凸會變小,從: 有可能無法滿足作為光擴散片所必需之光擴散性。反之, 若光擴散齊&quot;之平均粒徑超過上述範圍,則光學片 度會增大’並且難以均勻地擴散。 光擴散劑8之配合量(相對 介馬黏合劑9的形成材 料之聚合物組成物中的基材聚合物 &gt; 物100伤之經固體成分換 异之配合量)的下限’較佳為1〇份,更佳為2〇份,最佳 為50份,該配合量之上限較佳^ 5〇〇份更佳為_份, 最佳為2〇0份。其原因在於:若光擴散劑8之配合量未達 上述範圍’則光擴散性會變得不充分’另—方面,若光擴 散齊&quot;之配合量超過上述範圍,則固定擴散齊&quot;之效果會 下降。再者,於配設於稜鏡片表面側之所謂上用光擴散片 之情形時,必須具有較高之光擴散性,因此光擴散齊&quot;之 配合量較佳為Η)份以上、40份以下,更佳為iq份以上、 30份以下。 黏合齊&quot;係藉由使含有基材聚合物之聚合物組成物進 25 201005374 仃父聯硬化而形成。利用該人 ^ ?〇幻9將光擴散劑8大致等 街度地配置固疋於基材膜2 夕取人此,_U L 、 表面上。用以形成該黏合劑9 之聚合物組成物,係使用盥 用以形成上述防黏層3之黏人 劑6的聚合物組成物相同者。 σ 形成黏合劑9之聚人物έ 士 ,,^ 物組成物中可含有微小無機填充 劑。藉由使該黏合劑9中合右g , 有微小無機填充劑,而使光學 層4以及光學片i之耐埶 70干 # …、生k n。對於構成該微小無機填 充劑之無機物並無特別限定,柄* ^ . 仏為無機氧化物。該無機 虱化物被定義為:金屬亓妾+ π _ ‘、飛 占 '、要經由與氧原子的鍵結而構 ^ ^ _ 虱金屬化合物。作為構成無機氧 物之金屬元素’例如較佳A、s ώ -主 ^ — 土 权佺為選自兀素週期表第2族〜第6 無之凡素,更佳為選自元音 n 兀素週期表第3族〜第5族之元素。 更佳為選自Si、Al、Ti;^7 - r之元素,就提高耐熱性之效果 及均勻为放性之方面而言,金 ,,.鱼屬兀素為Si之膠體二氧化矽 機填充劑係最佳者。又,微小無機填充劑之形 ^、針狀、板狀、鱗片狀、破碎狀等任意之粒 子开/狀,並無特別限定。 .1Λ *開之+均粒控的下限較佳A 5 _,更佳 為 l〇tim。另一古: ΑΔ,ί “面,微小無機填充劑之平均粒徑之上限較 m 為nm。其原因在於:若微小無機填充 劑之平均粒徑夫洁μ、+ &gt; …、 量合.古,…未達上述範圍,則微小無機填充劑的表面能 上:r:攸而易於發生凝集等’反之’若平均粒徑超過 全地二+ :由於短波長的影響而產生白濁,從而無法完 王地維持光學片1之透明性。 26 201005374 微小無機填充劑之相對於基材聚合物1〇〇份之配合量 (僅無機物成分之配合量)的下限,以固體成分換算,較 佳為5份,更佳為5〇份。另一方面,微小無機填充劑之上 述配《里之上限較佳為5〇〇份,更佳為2〇〇份,最佳為ι〇〇 伤其原因在於.若微小無機填充劑之配合量未達上述範 圍,則有可能無法充分表現光學片i的耐熱性,反之,若 配合量超過上述範圍,則難以配合入聚合物組合物中,從 # 而有可能使光學層4之透光率下降。 作為上述微小無機填充劑,與上述填料5同樣,可使 用其表面丨固定有有機聚合物者。#由如上所述使用固定 有有機聚合物之微小無機填充劑,可提高黏合劑9中之分 散性及與黏合劑9之親和性。 、作為該光學#丨之製造方法,只要能製造出具有上述 才=每者’則無特別限定,但較佳為使用具有如下步驟之製 造方法·’ (a)基材膜形成步驟,藉由使用τ型模之擠出成 、形法而形成由熱可塑性樹脂所構成之基材膜擠出體,(b ) 積層步驟’於基材膜擠出體之—面上積層防黏層用組成 物,(Ο拉伸步驟,將基材膜擠出體及防黏層用組成物層 之積層體拉伸’·(d)形成光學層4之步驟,藉由將黏合劑 9之聚合物組成物中混合有光擴散劑8之光學層用組成物積 層於基材臈2的表面上’再使其硬化而形成光學層4。又, 亦可藉由使用T型模之共擠出成形法而同時實施上述基材 臈形成步驟及上述稽声讳_ 逻槓層乂驟。藉由使用上述擠出成形法之 造方法’因於將基材膜擠出體及防黏層用組成物層之積 27 201005374 層體拉伸的拉伸步驟之前,實施於基材膜擠出體之一面上 積層防黏層用組成物之積層步驟,故而,可使積層步㈣ 基材膜形成步驟及拉伸步驟在同一生產線上(亦即 線内積層步驟)上實施,其結果,可抑制製造成本、改善 生產性及作業效率而製造光學片。 該光學片1中,藉由光學層4中所含有之光擴散劑8 之界面上的反射或折射以及形成於光學層4表面之微細凹 a凸上的折射’而具有較高之光擴散功能(方向性擴散功 能)。此外,該光學片i之防黏層3含有填料5及其樹脂 製黏合劑6 ’該防黏層3之平坦部之平均厚度為_以 上、以下,填料5之平均粒徑為7〇nm以上、_職 以下,因此藉由奈米尺寸之填料5而於防黏層3之外表面 二多且均勾地形成微細之凸部7’其結果,可由較密分散 。&quot;散點狀地抵接於重疊於背面側之導光板Melamine «lipid, propylene phthalate-based phthalate resin, poly-resin polyimide resin, polyphosphazene-based resin, 7-oxo (tetra) ester composed of organic alkoxy oxime &lt; These polymers may be used alone or in combination of two or more. E is particularly self-processable and can be easily formed into a release-preventing method by a method such as coating. 14 201005374 In terms of layer 3, the above substrate polymer is preferably a polyol. Further, from the viewpoint of the formability of the two-dimensional crosslinked structure described below, the upper substrate polymer is preferably a polyolefin-based copolymer. The polymer having three-dimensional crosslinks 6 as shown in Fig. 2 has three-dimensional crosslinkability and improved adhesion and adhesion resistance. Further, for the reason, the hardness of the anti-adhesive layer 3 and the smoothness constitute the polymer 1 〇 structure of the binder 6. Since the binder structure is formed as described above, the filler 5 in the anti-adhesion layer 3 contributes to the uniform dispersibility of the filler 5, and the polymer 10 has a three-dimensional crosslinked structure, and the properties and the abrasion resistance are improved. There is no particular limitation on the method of constituting the three-dimensional cross-linked gentleman. The parental structure of the three-dimensional cross-linking is not limited, and it is generally known that the three-dimensional cross-linked structure can be made by the above-mentioned substrate I. The polymer composition is formed by containing a polyfunctional precursor having two or more unsaturated groups. The polyfunctional monomer having two or more unsaturated groups means a monomer having two or more unsaturated functional groups capable of undergoing mound polymerization with a monomer or a prepolymer as a functional group capable of copolymerization. , Ζ · · · · · · · · · · · · · · · · · ············································································· Functional monomer. - as the polyfunctional monomer having 2 or more unsaturated groups, for example, ethylene glycol di(meth)acrylic acid vinegar, diethylene glycol di(methyl) acrylate triterpene Glycol di(methyl) propyl acetoacetate, glycerol (di)trimethyl) acrylate - hydrazine, two! Di-(methyl)-propyl acetoacetate of polyols such as methyl propyl (di/tri) (meth) acrylate vinegar, pentaerythritol (di/tri/tetra) (methyl) acrylate vinegar , tri-(methyl)acrylic acid vinegar, tetrakis (meth)acrylic acid vinegar; p-diethylbenzene, 15 201005374 o-divinylbenzene, etc. #西的, (甲丙能单;; Methyl)acrylic acid vinyl sulfonium (meth) acrylate propyl acetonate; diene-diene-based diene; dichloride-introduced monomer material having a phosphazene skeleton and polymerized A polyfunctional monomer having a hetero atomic cyclic skeleton. #有有更更知知其々 a,..^土之夕 g monomer monomer compounding amount is preferably a two-dimensional parent The weight of the polymer in the polymer is 5% by mass or less and 80% by mass or less. If the above-mentioned _ is not obtained, the heat resistance and solvent resistance may not be caused, and if the amount is more than the above range, the I: 1 direction may be combined. On the other hand, if the characteristics of the rubber are lowered, the impact resistance and the like may be lowered, and the plastic may be used as the above-mentioned polyol. For example, it may be mentioned that: (3) The chromium ruthenium obtained by the polymerization of the early body of the unsaturated body of the unsaturated body, and the polyacetal polyol obtained by the extraction of the hydroxy group under the condition of excess hydroxyl group, etc. 2 or more. 珣 use, or as a hydroxyl-containing unsaturated monomer, can be listed. Xiangqi 7_ cattle · (a) such as 2-PS-ethyl acrylate, 2-hydroxypropyl acrylate, 曱其m 〇 Propylene-containing phthalocyanine- 2, thiol-based acrylate, propylene glycol, high-acrylic sterol, etc., containing a trans-unsaturated monomer; (b) for example, dipropylene glycol, ring Oxypropane, butanediol, epoxide cyclohexane, phenyl glycidyl ether, decanoic acid 1 soil) rn . , β / by 酉曰, Placcel FM-1 C Da1Cel Chetmcal Industries Or an epoxy compound, which is obtained by reacting with, for example, acrylic acid, methacrylic acid-deficient T-based acrylic acid, maleic acid, fumaric acid, butenoic acid, itaconic acid, etc. 16 201005374 a hydroxyl group-containing unsaturated monomer or the like. One or two or more selected from the group of the hydroxyl group-containing unsaturated monomers may be polymerized to produce the above polyol. Further, the above polyol may also be selected from the group consisting of ethyl acrylate, n-propyl acrylate, isopropyl propionate, n-butyl acrylate, tributyl acrylate, ethyl hexyl acrylate, ethyl decyl acrylate. , n-propyl decyl acrylate, isopropyl methacrylate, n-butyl methacrylate, tert-butyl methacrylate, ethyl hexyl acrylate, mercapto propylene Glycidyl methacrylate, cyclohexyl methacrylate, styrene, vinyl benzene, fluorene methyl styrene, acrylic acid, methacrylic acid, acrylonitrile, vinyl acetate, vinyl propionate, ethylene stearate Ester, propylene acetate, diallyl adipate, diconazole of itaconic acid, diethyl maleate, chloroacetamidine, dimethylidene chloride, acrylamide, N-A One or two or more ethylenically unsaturated monomers of acrylamide, N_butoxymethyl acrylamide, diacetone acrylamide, ethylene, propylene, isobutylene, etc. and selected from the above (a And the hydroxyl group-containing unsaturated monomer in (b) is produced by polymerization. The number average molecular weight of the polyol obtained by polymerizing the monomer component containing the ethylenically unsaturated monomer is 1 (10) Å or more and 5 Å or less, preferably 5,000 or more and 1 Å or less. . Further, the hydroxyl value is US$ or more, and 3 乂 ’ is preferably 10 or more and 2 Å or less, more preferably 2 Å or more and 15 Å or less. As the polyester polyol obtained under the conditions of excess radical, (e) such as ethylene glycol, diethylene glycol, propylene glycol, dipropylene glycol, -butanol, 1,4-butanediol, pentane Glycol, neopentyl glycol, iota, 6-hexanediol, 17 201005374 1,10-decanediol, 2,2,4-dimethylpyrazine 113;^-;1(^^-mercapto-1, 3-戍-Yin, Trimethylolpropane, Tri-fermented, Glycerol, Pentaerythritol, Cyclohexanediol, Gasified Double A, Recordylmethyl) Cyclohexane & Phenyldiphenyl Polyhydric alcohols such as acetamidine), tris(10)ethylethyl isocyanurate, phthalic acid, and the like (4), for example, cis-butane diacid, fumaric acid, succinic acid, adipic acid, sebacic acid, Polybasic acids such as sebacic acid, trimellitic acid, terephthalic acid, phthalic acid, isophthalic acid, etc., in polyols such as propanol, monohydric alcohol, polyethylene glycol, trihydroxypyridyl propane, etc. The number average molecular weight of the polyester polyol obtained by the reaction of the excess hydroxyl group is 500 or more and 300,000 or less, preferably 2, by the reaction under the condition that the number of base groups is more than the number of the above-mentioned polybasic acid. 〇 Above 'face (9) below. Further, the warp value is 5 or more and 3 Å or less, preferably (7) or more and 2 Torr or less, more preferably 2 Å or more and ι 5 〇 or less. The polyol used as the base polymer of the polymer composition preferably has a (meth) group obtained by polymerizing a monomer component containing the polyester polyol and the hydroxyl group-containing unsaturated monomer. An acrylic polyol such as an acrylonitrile unit. The use of the polyester polyol or the acrylic polyol as the binder of the base polymer 6 is highly economical, and the yellowing of the release layer 3 can be suppressed. Further, either of the polyhydric phenol and the acrylic polyol may be used. In addition, the number of the polyester polyol and the acrylic polyol may be particularly limited as long as it satisfies two or more per molecule, but the hydroxyl value in the solid component is 10 In the following, the number of crosslinking points is reduced, and solvent resistance, water resistance, heat resistance, surface hardness, and the like tend to be lowered by the film properties of 18 201005374. As the above substrate polymer, a polyhydric alcohol having a cycloalkyl group is preferred. As described above, by introducing a ring-shaped base into the polyol constituting the binder 6 as the base polymer, the water repellency and water resistance of the binder 6 can be made high, and the high-temperature and high-humidity conditions are high. The bending resistance, dimensional stability, and the like of the optical sheet are improved. x improves the basic properties of the coating film such as weather resistance, hardness, thickness, and solvent resistance of the anti-adhesive. Further, the affinity between the binder 6 and the filler 5 to which the organic polymer is fixed on the surface, and the uniform dispersibility of the material 5 are further improved. The cycloalkyl group is not particularly limited, and examples thereof include cyclobutylene, cyclopentyl group, cyclohexyl group, cycloheptyl group, cyclooctyl group, cyclodecyl group, cyclodecyl group, earth ring eleven alkyl group, and ring ten. Dialkyl, cyclotridecyl, cyclotetrahydrocarbyl, cyclopentadienyl, cyclohexadecane, ring seventeen (four), ring ten person base. The polyol having the above-mentioned cycloalkyl group is obtained by copolymerizing a polymerizable unsaturated monomer having a ring-based group. The polymerizable unsaturated monomer having a cycloalkyl group means having at least one ring-based group in the molecule: a polyunsaturated monomer. The polymerizability (tetra) and the monomer are not particularly limited, and examples thereof include (meth)acrylic acid cyclohexanol, (methyl) propyl acetoacetate, and (meth)acrylic acid third earth. Alkyl and the like.酉曰(Methyl)acrylic acid ring When the polyol is used as the substrate polymer as described above, the product may be obtained by polymerizing a polyisocyanate compound as a curing agent. Dimer, t substance, tetramer oxime derivative. The monolith composition contains a polyisocyanate 19 201005374 ester hardener, and the following three-dimensional crosslinked structure can be easily and surely formed, and the film properties of the anti-adhesive layer 3 are further improved. Further, by blending the polyisocyanate compound, the curing reaction rate of the polymer composition can be increased. Therefore, even if the polymer composition contains a cationic antistatic agent which contributes to the dispersion stability of the fine inorganic filler, The productivity of the curing reaction rate due to the cationic antistatic agent is sufficiently compensated, and the productivity can be further improved. The polyisocyanate compound is preferably a diphenylene diisocyanate derivative or a mixture of the xylene diisocyanate derivative and an aliphatic diisocyanate derivative. The xylene diisocyanate vinegar derivative has a large effect of increasing the reaction rate of the polymer composition, and yellowing and deterioration due to heat or ultraviolet rays in the aromatic monoisocyanate derivative. Therefore, the temporal deterioration of the light transmittance of the optical sheet 1 can be reduced. On the other hand, the effect of improving the reaction rate of the aliphatic diisocyanate derivative is smaller than that of the aromatic diisocyanate derivative, but it is caused by ultraviolet rays or the like. Since the use, the deterioration, and the like are extremely small, the effect of improving the reaction rate and the effect of preventing yellowing can be achieved by blending with the xylene diison gas S夂sa and the living organism. The lower limit ' of the compounding amount of the polyisocyanate compound (the amount of the solid component converted to the i00 part of the polymer component in the polymer composition) is preferably 2 parts', more preferably 5 parts. On the other hand, the upper limit of the amount of the above-mentioned hardening agent is preferably 2 G parts, more preferably 15 parts. By setting the amount of the polyisocyanate compound in the above range as described above, the above polymer composition can effectively exhibit the effect of increasing the rate of the curing reaction. 20 201005374 As the above inorganic filler 5, a surface-fixed (tetra) organic polymer can be used. By using the inorganic filler 5 to which the organic polymer is immobilized as described above, the dispersibility in the binder 6 or the affinity with the binder 6 can be improved. The specific molecular weight, shape, composition, and functional group of the immobilized organic polymer are not particularly limited, and any organic polymer can be used. Further, the shape of the organic poly-σ material may be any shape such as a straight bond, a bond, or a crosslinked structure. f is a specific tree constituting the above organic polymer, and examples thereof include a (meth)acrylic resin, a polystyrene, a polyvinyl acetate, a polyolefin such as polyethylene or polypropylene, a polyethylene oxide, and a dichlorochloride. A polyester such as ethylene or polyethylene terephthalate or a copolymer thereof; or a resin obtained by partially modifying a functional group such as an amine group, an epoxy group, a hydroxyl group or a carboxyl group. Among them, an organic polymer containing a (meth)acrylic acid unit such as a (meth)acrylic resin, a (meth)acrylic acid-styrene resin, or a (meth)acrylic acid-polyacetic resin is used as an essential component. It is preferred to have a film forming function. The other side I is preferably a resin having compatibility with the base polymer of the above polymer composition, and therefore, it is preferably one having the same composition as the substrate contained in the polymer composition. Λ - Further, the fine particles of the inorganic filler 5 may also contain an organic polymer. Thereby, moderate softness and toughness of the inorganic material as the core of the filler 5 can be imparted. Further, the organic polymer may be an alkoxy group, and the content of the filler 5 in which the organic polymer is fixed is preferably 0.01 mmol or more and 5 Å or less per 1 g of the organic polymer. By the alkoxy group, the affinity between the adhesive of 6 201005374 and the dispersibility of the binder 6 and the adhesion of the binder 6 can be improved. The above alkoxy group means an R fluorenyl group bonded to a metal element forming a fine particle skeleton. The R is an alkyl group which may be substituted, and the r fluorenyl group in the fine particles may be the same or different. Specific examples of R include, for example, an anthracenyl group, an ethyl propyl isopropyl group, an n-butyl group, and the like. It is preferable to use an alkoxy group of the same metal as the metal constituting the filler 5 and when the filling hopper 5 is a colloidal cerium oxide, it is preferable to use an alkoxy group having ruthenium as a metal. The rate of the organic polymer in the non-container 5 in which the organic polymer is fixed is not particularly limited, but it is preferably based on the filler 5 to achieve 〇_5 mass. /〇 or more, 5〇% by mass or less. The above-mentioned organic polymer defined on the filler 5 is formed by using a polymer composition containing a binder 6 as a binder, and may contain a polyfunctional group selected from two functional groups which react with a hydroxyl group. At least one of an isocyanate compound, a melamine compound, and an amine resin. Thereby, the matrix resin of the filler and the binder 6 is bonded by a crosslinked structure, thereby improving storage stability, stain resistance, Γ &amp; α, flexibility, weather resistance, storage stability, and the like. Further, the obtained film has gloss. ^, the antistatic agent may be mixed in the polymer composition in a finely dispersed state. The formation of the binder 6 by the polymer composition in which the antistatic agent is mixed can cause the light sheet 1 to exhibit an antistatic effect, thereby preventing adsorption of dust or being difficult to overlap with the ruthenium or the like due to static electricity. The problem. Further, if an antistatic agent is applied to the surface, the surface may be sticky or dirty, but by dissipating the antistatic agent in the polymer composition as described above, the drawback can be reduced 22 201005374. For the antistatic agent, there are no anionic diterpenoids such as a sulphate or an alkyl phosphate. For example, a cationic antistatic agent such as an alkyl odorant compound can be used, and a quaternary ammonium salt or a sorbitan can be used. Alcoholic anhydride monostearic acid vinegar, ethanol: glycol, polyoxyethylene, polyglycolic acid, etc., antistatic, anti-static, non-ionic antistatic: end, metal oxide powder, carbon nano; . :: Conductive metal The cationic antistatic agent factory with a large electrical effect is preferably an antistatic antistatic agent, which exerts an antistatic effect. * Adding a small amount of the cation to the substrate, as a base polymer for forming the adhesive, filling the base 5, and using the polymer composition for the fight, in addition to the hardener, the antistatic sword is incorporated into, for example, a plasticizer, dispersed Agents, each: suitable antioxidants, viscous modifiers, lubricants, and light stabilization: the flat portion of the core anti-adhesive layer 3 is wide. The lower limit of the average thickness is preferably 5 〇 &amp; (the area in the region without filler 5 is preferably 50 nm, more preferably the flat portion of the 7 〇 anti-adhesive layer 3: 〇 _. In addition, the aspect is 120 If the anti-X sense is preferably 15 〇 nm, the average thickness τ of the right anti-adhesive layer 3 may cause the filler s ^ , the lower limit, if (4)... the true 枓 5 is fixed to the back of the substrate film 2 On the other hand, if the average thickness T of the anti-adhesive layer 3 exceeds the above-mentioned upper limit, the anti-adhesive convex portion can be made smaller by the adhesion preventing layer 3, and the result may cause the above upper limit to be exceeded. :. Also, if the average of the anti-adhesive layer 3... the dryness of the transmitted light ^ see the refraction of the two interfaces of the anti-adhesive layer 3 to produce a good phenomenon, thus creating a double-grain, etc. The average roughness (Ita) of A/r is preferably 〇.〇5 &quot; mu upper, 〇.15 Mm or less, more preferably 〇〇8 μιη or more, 〇12 Μ 23 201005374 m or less. Anti-adhesive layer The maximum height (Ry) of the back side of 3 is preferably 〇·4 &quot;, above 0.9 // m, more preferably 〇6 &quot; m or more, 〇7 &quot; below the claw. Anti-adhesive layer 3 The tenth point average roughness (Rz) of the surface is preferably 〇3 (four) :: upper, 〇·8..., more preferably 〇.5...up, 0.6.... if the arithmetic mean roughness of the back side of the anti-adhesive layer 3 (The maximum height (^) and the ten-point average roughness (Rz) are smaller than the above range, which may result in a decrease in the fine convex portion on the back surface of the release layer 3 and a decrease in the anti-adhesive property. If the arithmetic mean roughness (Ra) or the like exceeds the above range, glare may occur on the surface of the liquid crystal display device, resulting in deterioration of quality. The optical layer 4 is provided with a plurality of substantially uniform surfaces disposed on the surface of the substrate film 2. a light diffusing agent 8 and a binder 9 of the plurality of light diffusing agents 8. The plurality of light diffuses are coated by the binder 9. The plurality of light diffuses contained in the optical layer 4 as described above The agent 8 allows the light transmitted from the back side of the optical layer 4 to the front side to be uniformly spread. x, by the complex (four) light spread (four) 8, the fine unevenness is formed substantially uniformly on the surface of the optical layer 4. The refraction of the fine meniscus lens formed on the surface of the optical #1 as described above allows the light to diffuse better Further, the average thickness of the optical layer 4 is not particularly limited. For example, it is assumed to be i...upper, three 〇...down. The light diffusing agent 8 has the property of diffusing the green color of the green The particles are substantially filled with a filler and an organic filler, and as the filler, for example, a dioxide dioxide, an oxidized quartz, a oxidized sulphur, a zinc oxide sulphide, a sulphuric acid, or the like can be used. As the material of the organic filler, for example, an acrylic acid system: a ruthenium diene nitrile resin, a polyamino carboxylic acid sl, a polychloroethylene, a polystyrene, a dilute nitrile, a polynitramine or the like can be used. To, (four) 24 201005374 Shu Yue, better for poly-t-butyl acrylate vinegar (five) ma). The shape of the light diffusing agent 8 is not particularly limited, and may be, for example, a spherical shape, a spindle shape, a needle shape, a pile type, a fiber shape, or the like. Among them, a spherical beads having a high light diffusibility are preferably used as a sheet shape. The lower limit of the average particle diameter of the light diffusing agent 8 is preferably 2 # m, more preferably 5 is preferably 5 &quot; m. On the other hand, the upper limit of the average particle diameter of the light diffusing agent 8 is preferably 50, more preferably 20, most preferably 1... If the average particle diameter of the light diffusion is less than the above range, the unevenness of the surface of the optical layer 4 formed by the diffusion of the light will become small, and the light necessary for the light diffusion sheet may not be satisfied. Diffusion. On the other hand, if the average particle diameter of the light diffusion is larger than the above range, the optical length will increase 'and it is difficult to uniformly spread. The lower limit of the blending amount of the light diffusing agent 8 (the amount of the base polymer in the polymer composition of the material forming the binder 9) and the solid content of the object 100 is preferably 1 Preferably, the amount is preferably 2 parts, preferably 50 parts, and the upper limit of the compounding amount is preferably 5%, preferably 2 parts. The reason is that if the blending amount of the light diffusing agent 8 does not reach the above range, the light diffusibility may become insufficient. In addition, if the blending amount of the light diffusing exceeds the above range, the fixed diffusion is uniform. The effect will drop. Further, in the case of a so-called upper light-diffusing sheet disposed on the surface of the enamel sheet, it is necessary to have a high light diffusibility, and therefore the amount of light diffusion is preferably Η) or more and 40 parts or less. More preferably, it is iq or more and 30 or less. Adhesive bonding is formed by hardening a polymer composition containing a substrate polymer into a curing agent. Using the person, the light diffusing agent 8 is disposed in a substantially equal manner on the substrate film 2, _U L , on the surface. The polymer composition for forming the binder 9 is the same as the polymer composition of the binder 6 for forming the above-mentioned release layer 3. The composition of the σ-forming binder 9 may contain a minute inorganic filler in the composition of the composition. By bonding the adhesive 9 to the right g and having a fine inorganic filler, the optical layer 4 and the optical sheet i are made resistant to dryness 70. The inorganic substance constituting the micro inorganic filler is not particularly limited, and the handle * ^ is an inorganic oxide. The inorganic telluride is defined as: metal 亓妾 + π _ ‘, fly occupies', to form a ^ ^ _ metal compound via a bond with an oxygen atom. As the metal element constituting the inorganic oxygen species, for example, preferably A, s ώ - main ^ - soil weight 佺 is selected from the group 2 to the sixth element of the periodic table of the halogen, more preferably selected from the vowels n 兀Elements of Groups 3 to 5 of the Periodic Table of the Prime Term. More preferably, it is an element selected from the group consisting of Si, Al, Ti; ^7 - r, and in terms of improving the heat resistance and uniformity of the release property, the gold, and the fish is a colloidal ceria which is a Si. The filler is the best. Further, the shape of the fine inorganic filler, the needle shape, the plate shape, the scaly shape, and the crushed shape are not particularly limited. The lower limit of .1Λ *open + uniform particle control is preferably A 5 _, more preferably l〇tim. Another ancient: ΑΔ, ί "face, the upper limit of the average particle size of the micro-inorganic filler is m is nm. The reason is: if the average particle size of the micro-inorganic filler is clean, μ &gt; Ancient, ... not reaching the above range, the surface energy of the micro inorganic filler is: r: 攸 and easy to agglomerate, etc. 'Conversely', if the average particle size exceeds the total ground 2 +: white turbidity due to the influence of short wavelength, and thus The transparency of the optical sheet 1 is maintained by the king. 26 201005374 The lower limit of the amount of the fine inorganic filler relative to the base polymer (the amount of the inorganic component only) is preferably in terms of solid content. 5 parts, more preferably 5 parts. On the other hand, the upper limit of the above-mentioned fine inorganic filler is preferably 5 parts, more preferably 2 parts, and the best is ι〇〇 When the amount of the fine inorganic filler is less than the above range, the heat resistance of the optical sheet i may not be sufficiently exhibited. On the other hand, if the amount exceeds the above range, it is difficult to blend into the polymer composition, and It is possible to make the transmittance of the optical layer 4 As the fine inorganic filler, as in the case of the above-described filler 5, an organic polymer may be used in which the surface layer is fixed. # Use the fine inorganic filler to which the organic polymer is fixed as described above, and the binder 9 can be improved. The dispersibility and the affinity with the binder 9. The method for producing the optical fiber is not particularly limited as long as it can produce the above-described ones, but it is preferable to use a production method having the following steps. ' (a) a substrate film forming step of forming a substrate film extrudate composed of a thermoplastic resin by extrusion molding using a τ-type mold, and (b) a laminating step of squeezing the substrate film a composition for laminating an anti-adhesive layer on the surface of the body (the stretching step is to stretch the laminate of the substrate film extrudate and the anti-adhesive layer composition layer) (d) to form the optical layer 4 The step of forming the optical layer 4 by laminating the composition for the optical layer in which the light-diffusing agent 8 is mixed in the polymer composition of the binder 9 onto the surface of the substrate 2 to form the optical layer 4. Simultaneously by co-extrusion molding using a T-die The substrate 臈 forming step and the above-described 讳 逻 逻 逻 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 201005374 Before the stretching step of the layer stretching, the step of laminating the composition for the anti-adhesive layer on one side of the substrate film extrudate is carried out, so that the step of forming the substrate film and the stretching step can be performed The optical sheet is produced by suppressing the manufacturing cost, improving the productivity, and the work efficiency. The optical sheet 1 is diffused by the light contained in the optical layer 4 as a result of the same production line (that is, the in-line lamination step). The reflection or refraction at the interface of the agent 8 and the refraction of the fine concavities formed on the surface of the optical layer 4 have a high light diffusion function (directional diffusion function). Further, the anti-adhesive layer 3 of the optical sheet i contains the filler 5 and a resin-made adhesive 6'. The average thickness of the flat portion of the anti-adhesion layer 3 is _ or more, and the average particle diameter of the filler 5 is 7 〇 nm or more. Since the filler of the nano-size is used, the fine convex portion 7' is formed on the outer surface of the anti-adhesion layer 3 by a nano-sized filler 5, and as a result, it can be densely dispersed. &quot; scatter-like contact with the light guide plate overlapping the back side

Li::,該光學…有較高之防黏性,且可能防止: 黏附而產生干擾條紋。 為7〇又’該光學片1中,發揮防黏性之填料5之平均粒徑 於:以上、2〇〇 _以下,因此’填料5之平 =見光的波長,即便配合人料5亦可顯著地降低對透 先性的影響,從而具有較高的總透光率。 、該光予片1中’防黏層3之平坦部之平均厚度 〇又崎M) nm以卜、1 平均… 15〇随以下’因此防黏層3之平坦部之 兩^度小於可見光的波長,從而可降低由於防黏層3之 面上的折射所產生的透射光線的干擾現象,可有效抑 28 201005374 制疊紋等之產生。 又’與先前之平均度 予又相比,該光學片1之防黏屉. 之平坦部之平均厚声★ 曰, 小’從而可促進目前所要求之液曰 顯示裝置的薄型化。谁而 日曰 進而,於該光學片1中,為了於外矣 面形成凸部7而使防黏層 衣 學片之樹脂絲,故而,了I;/料5,但^含先前的光 玟而,可於實施利用擠出成形法之 膜2的成形步驟之線内積層㈣層3,其結果,可省 之製成光學片等基材膜後之塗佈等其他步驟,: 地提高製造作業性且促進製造成本下降。 者 圖3之光于片u具備:基材膜2、積層於該基材膜2 的背面之防黏们2、及積層於基材臈2的表面之光學層々 該基材膜2、光學層4、填料5之種類、含量、形狀等以及 黏合劑6及製造方法等’與上述目】之光學片&quot;目同,因 而附上相同編號並省略其說明。 防黏層12與圖!之光學片i同樣地具有:以層狀並且 間隔配設之複數個填料5、將該填料5固定於基材膜2 面側之黏合劑6。作為該填料5,含有主成分之小徑填料〜 及平均粒徑大於該小徑填料5a之副成分之大徑填料讣。 該光學片11含有主成分之小徑填料化及副成分之大徑 填料5b作為填料5,藉此利用主成分之小徑填料5a而於防 黏層12的背面(外表面)形成相對更密分散之微細之凸部 7a,利用副成分之大徑填料5b而散點狀地形成相對更大的 凸部7b,從而使防黏性顯著地提高。 小徑填料5a之平均粒徑之下限較佳為5〇 _,更佳為 29 201005374 80 nm。另一方面,小徑埴 、’4 5a之平均粒徑之上限較 150 nm,更佳為12〇 nm。若小 為 J k填料5 a之平均粒經未遠 述下限,則可能導致表面能 木逹上 ^ , 里^尚,因而難以分散含有於 黏合劑ό中,且藉由小徑填 ^ ^ '斗5 a而形成於防黏層3之皆 之凸部7a會變小,而無法發 亦面 皁防黏功此。反之,若小今 料5a之平均粒徑超過上述ip 、 疋上限,則可能導致由於短波長的 影響而使遮蔽光線透射之效果鐵+ 反食的 政果變大,從而導致導致該光畢 片丨1之總透光率下降。 予 大徑填料5b之平均敖僻+ τ 十^隹仫之下限較佳為2〇〇 nm, 3 00 nm。另一方面,大徑埴祖仏 … “填科讣之平均粒徑之上限較佳為 .&quot;m,更佳為…。若大徑填料讣之平均粒徑小於 上述下限,則散點狀地形成於防黏層12的背面之凸部7b 會減小’I而無法實現提高防黏性之效果。另—方面,若 大徑填料5b之平均粒徑超過上述上限,則使防黏層η中 之大控填料5b之固定性下降,進 令進而有悖於防黏層12之薄 膜化之要求。 大徑填料5b相對於總填料5之配合比較佳為5質量% 以上、30質量%以下,更佳為1〇質量%以上、2〇質量%以 下。若大徑填料5b之配合比小於上琉&amp; $ J於上述範圍,則如上述般散 點狀地形成於防黏層12背面之較大的凸部几之密度會下 降,從而無法實現上述防黏性之提高效果。另—方面Y若 大扭填料5b之配合比超過上述範圍 日 &lt; 礼固則無去實現防黏性之 提高效果’反之,由於配合入大徑填肖5b,可能會導致該 光學片11之透光線性下降。 30 201005374 圖4之光學片2〇 折射、擴散等光學功能、:車父向之聚光、朝法線方向側 基材膜2、積層於該義斤明微透鏡片。該光學片20具有: 於基材膜2的背面之=广之表面之光學層21、及積層 述圖1之光學片!相同㉟3。該基材膜2及防黏層3與上 光學層^具備:籍I而附上相同編號並省略其說明。 積層於基材膜2的表面之片壯却 及形成於該片狀部22Μ Θ衣曲之片狀部22、 學層中亦可不存在片此面之微透鏡陣列23。再者,該光 成該光學層21。總之,部22’而僅由微透鏡陣列23構 微透鏡陣列23。又,亦可將::=臈2之表面上直接形成 光學層21必須可使ϋ 基材膜2 一體成形。 疋無色透明之合成樹脂 ^ 尤八 成m P 形成。作為光學層21所使用之合 成树知,例如可列舉 乙二醇醋、丙稀酸夺樹:?二甲酸乙二醋、聚蔡二甲酸 乙酸纖維素、耐候性丄“酸酿、聚苯乙烯、聚烯烴、 豆 烯、活性能量線硬化型樹脂等。 樹脂、電子束硬化型樹性優異之紫外線硬化型 及強;s、 射線硬化型樹脂、或透明性 广上:人:之’對苯二甲酸乙二酯。再者,於光學層21中, 除上速合成樹脂外,亦 劑、防劣化劑、分散劑等〇入例如填料、可塑劑、穩定 微透鏡陣列23係由多個 24係形成為丰讨壯r A a 4所構成。該微透鏡 於基材,,、、,(匕3近似半球之形狀),並突出設置 於基材膜2之表面側。再者 球狀凸透鏡… 鏡24並不限^於上述半 ’、&quot;”'、、球狀凹透鏡之微透鏡。該半球狀凹 31 201005374 同樣具有優異之光學功 透鏡之微透鏡亦與上述微透鏡24 月£ 微透鏡24,係較密且以幾 * 】学方式配設於基材膜2的 表面。,、體而言,微透鏡24係以 其鈇0 * * —角形格子圖案配設於 基材膜2之表面。因此料 ㈣…入A 24之間距(p)及透鏡間 距離(S )全部為固定。續凡 ° °又圖案可最密集地配設微透鏡 。再者,微透鏡24之配設圖幸, 莱並不限定於可稠密填充 之上述正二角形格子圖案,例 亦可為正方形格子圖案或 隨機圖案。藉由該隨機圖宰,在 风圑系在將§亥光學片20與其他光學 構件重疊之時可減少疊紋的產生。 微透鏡24之直徑(d )的下限軔杜或,Λ 〃 w卜I民較佳為i 〇 &quot; m,更佳為 100…最佳為20…。另—方面,微透鏡24之直徑 ⑻之上限較佳為100&quot;m’更佳為70”m。若微透 鏡24之直徑(D)小於1〇心’則繞射之影響會變大,易 於引起光干性旎之下降或色彩分離,從而導致品質下降。 另方面右微透鏡24之直徑(D)超過1〇00 # m,則易 於產生厚度增大或亮度不均,從而導致品質下降。又,藉 由將微透鏡24之直徑(D)設為1〇〇心以上,而使單位 面積之微透鏡24變少,從而使作為微透鏡片之該光學片2〇 的大面積化變得容易,從而減輕製造時之技術及成本上的 負擔。 微透鏡24之表面粗度(Ra)的下限較佳為〇.〇1 #爪, 更佳為0.03 #m。另一方面’微透鏡24之表面粗度(Ra) 之上限較佳為0.1 ’更佳為〇 〇7 。藉由如上所述 32 201005374 將微透鏡24之表面粗度(Ra)設為上述下限以上,可使該 光學片20之微透鏡陣列23的成形性變得較為容易,從而 減輕製造時之技術及成本上的負擔。另一方面,藉由將微 透鏡24之表面粗度(Ra)設為未達上述上限,而降低微透 鏡24表面上之對光的散射,可提高微透鏡24之聚光功能 或朝法線方向側之折射功能,從而因該良好之光學功能而 實現正面方向的高亮度化。 微透鏡24之高度(H)相對於曲率半徑(R)之高度比 (H/R)的下限,較佳為5/8,更佳為3/4。另一方面,該高 度比(H/R )之上限較佳為!。藉由如上所述將微透鏡 之π度比(H/R )設為上述範圍,而有效地發揮微透鏡24 中之透鏡性折射作用,從而顯著地提高該光學片2〇之聚光 等光學功能。 微透鏡24之透鏡間距離(s ; p_D )相對於直徑(D ) 之間隔比(S/D)之上限,較佳為1/2,更佳為1/5。藉由如 上所述將微透鏡24之透鏡間距離(s)設為上述上限以下, 而減少不利於光學功能之平坦部,從而顯著地提高該光學 片20之聚光等光學功能。 微透鏡24之填充率之下限較佳為4〇%,更佳為6〇%。 藉由如上所述將微透鏡24之填充率設為上述下限以上,而 提高微透鏡24於該光學片20表面中之佔有面積,從而顯 著地提高該光學片20之聚光等光學功能。 再者,上述高度比(H/R)、間隔比(S/D )及填充率 之數值範圍,係基於採用蒙地卡羅法(M〇nte Carl〇 ) 33 201005374 之非逐次光線追蹤之亮度分析模擬而導出者。 構成光學層21之材料之折射率的下限較 佳為1.45。另一方面,該材料之折射率之上限較佳’3 ’更 更佳為1.6。在此範圍内,構成光學層2ι之 I8’ 最佳為…藉由如上所述將構成光學層:之折射率 率設為上述範圍,而有效地發揮微透鏡Μ 料的折射 用,從而進一步提高該光學片2。之聚光等光學功:折射作 該光學Μ 20之製造方法,只要可製造且 ^ 無特別限定,適宜採用包括下列㈣之製造方法:“者則 材膜形成步驟’藉由使用τ型模之擠出成形法’ (a = 可塑性樹脂所構成之基材膜播出體;(b)積層步驟= 材膜擠出體之一面上積層防黏層用組成物;(c)拉伸步驟二 將基材膜擠出體及防黏層用組成物層之積層體拉伸; 於基材膜2之表面上形成光學層以之步驟。 作為形成上述光學層21之方法,具體而言有: (a)依序於具有微透鏡陣列23表面之反轉形狀之片體 合成樹腊及基材膜2,再將此片體模具剝離而形 成该光學層2 1之方法; ⑴對片體化之樹脂進行再加熱,再與基材膜2 一併 =具有微透鏡陣列23表面的反轉形狀之模具與金屬板 之間進行壓製,而轉印形狀之方法; 2通過周面具有微透 一輥之間的捏口,而 (c )使熔融狀態之樹脂及基材膜 鏡陣列23表面之反轉形狀的輥模與另 轉印上述形狀之擠出片成形法; 34 201005374 (d)將紫外線硬化型樹脂塗佈於基材膜2上,再擠壓 於具有與上述相同的反轉形狀之片體模具、模具或輥模 上,從而將形狀轉印至未硬化的紫外線硬化型樹脂上,並 照射紫外線以使紫外線硬化型樹脂硬化之方法; (e )將未硬化之紫外線硬化性樹脂填充塗佈於具有與 上述相同之反轉形狀之模具或輥模上,利用基材膜2進行 擠壓使其平整’並照射紫外線以使紫外線硬化型樹脂硬化 之方法; (f) 將未硬化(液狀)的紫外線硬化型樹脂等從微細 的噴嘴中射出或釋出於基材臈2上而形成微透鏡24,並使 其硬化之方法; (g) 使用電子束硬化型樹脂來代替紫外線硬化型樹脂 之方法等。 又,亦可藉由使用T型模之共擠出成形法而同時實施 上述基材膜形成步驟與上述積層步驟。進而,亦可藉由使 用T型模之共擠出成形法’與上述基材膜形成步驟及上述 積層步驟同時進行形成光學層21之步驟。具體而言,將熔 融合成樹脂從T型模中擠壓至周面具有與微透鏡陣歹4 23表 面呈相反形狀的輥模與另—親之間的挾持部(nip),並使盆 硬化,藉此可同時形成該光學片20。藉由採用此種擠出成 形法之製造方法,在將基材膜擠出體與防黏層用組成物層 之積層體進行拉伸之拉伸步驟之前,進行於基材膜擠出體 之面上積層防黏層用組成物的積層步驟及光學層形成步 驟,因此可使積層步驟及光學層形成步驟與基材膜形成步 35 201005374 驟及拉伸步驟在同一生產線( 上實施,從而可抑制製造成本 製造光學片。 即作為生產線中積層步驟) 、改善生產性及作業效率而 再者作為具有與上述微透鏡陣列u呈相反形狀之損 ㈣:)之製造方法,例如可藉由以下方法製造:利用光 ::基材上形成斑點狀之立體圖案,將該立體圖案加 机動而使其曲面化,藉此製作微透鏡陣列模型,再 利用電鑄法將金屬層積層於該微透鏡陣列模型之表面,再 將该金屬層剝離。又,作為上述微透鏡陣列模型之製作方 法,亦可採用上述(f)中記載之方法。 該光學片20,藉由微透鏡陣列23而具有較高的聚光、 朝法線方向側的折射、擴散等光學魏,並且可容易且確 實地控制其光學功能。因此,該光學4 ,例如可將入射 光線朝背光單元之稜鏡片入射之峰值方向控制在對於朝法 線方向側的折射而言為最佳的傾斜角。此外,該光學片加, 藉由防黏| 3而具有較高之防黏性、總透光率、亮度等之 均勻性、經濟性及薄膜性。 /再者,所謂上述「微透鏡」,係指界面呈部分球面狀 ,微小透鏡,例如半球狀凸透鏡、半球狀凹透鏡等。所謂 直位(E))」,係心微透鏡之基底或開口之直徑。所謂「高 度(Η)」,於微透鏡為凸透鏡之情形時,係指自微透鏡之 基底面至最頂部為止的垂直距離;於微透鏡為凹透鏡之情 形時,係指自微透鏡的開口面至最底部為止的垂直距離。 所謂「透鏡間距離」’係指鄰接之一對微透鏡間的最短距 36 201005374 離。所謂「填充率」,係指表面投影形狀中的單位面積之 微透鏡的面積比。所謂「正三角形格子圖案」,係指將表 面區分為同一形狀之正三㈣,且將微透鏡配設於該正三 角形的各頂點之圖案。Li::, the optics... has a high anti-stick properties and may prevent: adhesion and interference fringes. In the optical sheet 1, the average particle diameter of the filler 5 which exhibits the anti-adhesive property is at least 2 Å or less, so that the level of the filler 5 is the wavelength of the light, even if it is blended with the material 5 The effect on the permeability can be significantly reduced, resulting in a higher total light transmittance. The average thickness of the flat portion of the anti-adhesive layer 3 in the light-applying sheet 1 is M, M is nm, and the average is 15 〇 as follows: Therefore, the two flat portions of the anti-adhesive layer 3 are smaller than visible light. The wavelength, which can reduce the interference phenomenon of the transmitted light due to the refraction on the surface of the anti-adhesion layer 3, can effectively suppress the occurrence of the dull pattern of 201005374. Further, the average thickness of the flat portion of the anti-adhesive sheet of the optical sheet 1 is smaller than that of the previous average, so that the thickness of the currently required liquid helium display device can be promoted. In the optical sheet 1, in order to form the convex portion 7 on the outer surface of the optical sheet 1, the resin yarn of the anti-adhesive layer is formed, so that I; / material 5, but including the previous aperture Further, the layer (4) can be laminated in the line by the molding step of the film 2 by the extrusion molding method. As a result, other steps such as coating after forming a base film such as an optical sheet can be omitted. Workability and promote reduction in manufacturing costs. The light of FIG. 3 includes a base film 2, an anti-adhesive layer 2 laminated on the back surface of the base film 2, and an optical layer laminated on the surface of the substrate 2, the base film 2, and an optical layer. 4. The type, content, shape, and the like of the filler 5, as well as the adhesive sheet 6 and the manufacturing method, etc., are the same as those of the above-mentioned optical sheet, and the same reference numerals are attached thereto, and the description thereof is omitted. Anti-adhesive layer 12 and figure! Similarly, the optical sheet i has a plurality of fillers 5 disposed in a layered manner and spaced apart from each other, and the binder 6 is fixed to the surface of the base film 2. The filler 5 contains a small-diameter filler of a main component and a large-diameter filler crucible having an average particle diameter larger than that of the minor component of the small-diameter filler 5a. The optical sheet 11 contains a small-diameter filler having a main component and a large-diameter filler 5b as a filler 5, whereby the small-diameter filler 5a of the main component is used to form a relatively denser surface on the back surface (outer surface) of the release layer 12. The fine convex portion 7a which is dispersed is formed by the large-diameter filler 5b of the subcomponent, and the relatively large convex portion 7b is formed in a scattered manner, so that the sticking resistance is remarkably improved. The lower limit of the average particle diameter of the small-diameter filler 5a is preferably 5 〇 _, more preferably 29 201005374 80 nm. On the other hand, the upper limit of the average diameter of the small diameter 埴 and '4 5a is 150 nm, more preferably 12 〇 nm. If the average particle size of 5 k of J k filler is not far from the lower limit, it may cause the surface energy to be on the raft, and it is difficult to disperse it in the binder, and fill it with a small diameter. The convex portion 7a formed in the anti-adhesive layer 3 of the bucket 5 a becomes small, and it is impossible to prevent the sticking of the soap. On the other hand, if the average particle size of the small material 5a exceeds the upper limit of the above ip and 疋, the effect of shielding the light transmission due to the influence of the short wavelength may increase the effect of the iron + anti-food, resulting in the optical film. The total light transmittance of 丨1 decreases. The lower limit of the average diameter of the large-diameter filler 5b + τ 10 ^ 较佳 is preferably 2 〇〇 nm, 300 纳米. On the other hand, the large diameter 埴祖仏... "The upper limit of the average particle size of the filled sorghum is preferably .&quot;m, more preferably... If the average diameter of the large diameter filler 小于 is less than the above lower limit, then scatter The convex portion 7b formed on the back surface of the anti-adhesion layer 12 is reduced by 'I and the anti-adhesive property is not improved. On the other hand, if the average particle diameter of the large-diameter filler 5b exceeds the above upper limit, the anti-adhesion layer is provided. The fixing property of the large-control filler 5b in η is lowered, and the order is further reduced by the thin film formation of the anti-adhesion layer 12. The blending of the large-diameter filler 5b with respect to the total filler 5 is preferably 5% by mass or more and 30% by mass. In the following, it is more preferably 1% by mass or more and 2% by mass or less. When the mixing ratio of the large-diameter filler 5b is less than the upper side & $ J in the above range, the anti-adhesive layer 12 is formed in a scattered manner as described above. The density of the large convex portions on the back side will decrease, so that the above-mentioned anti-sticking effect can not be improved. On the other hand, if the blending ratio of the large twisted filler 5b exceeds the above range, the solid is not achieved. The effect of improving the sex', on the contrary, due to the matching of the large diameter to fill the 5b, may result in The optical transmission of the optical sheet 11 is linearly reduced. 30 201005374 The optical film of Fig. 4 has optical functions such as refraction and diffusion, and the light is distributed by the father, and the base film 2 toward the normal direction is laminated on the jinming The lenticular sheet has the optical layer 21 on the back surface of the base film 2, the optical layer 21 on the surface, and the optical sheet of the first embodiment: 353. The base film 2 and the release layer 3 are The upper optical layer is provided with the same reference numerals and the description thereof is omitted. The sheet laminated on the surface of the base film 2 is formed and formed in the sheet portion 22, the layer of the sheet portion 22 There may be no microlens array 23 on the side of the sheet. Further, the light is formed into the optical layer 21. In summary, the portion 22' is formed only by the microlens array 23. Further, it may be::=臈The optical layer 21 is formed directly on the surface of the surface of the film 2, and the base film 2 of the base material must be integrally formed. The colorless transparent synthetic resin is formed by the formation of a fine resin. As the synthetic tree used for the optical layer 21, for example, ethylene glycol is exemplified. Vinegar, acrylic acid to win the tree:? Ethylene diformate, cellulose acetate, cellulose, weathering Stuffed, polystyrene, polyolefins, alkenyl bean, an active energy ray curable resin. Resin, electron beam hardening type, excellent ultraviolet curable type and strong; s, ray hardening type resin, or transparency. Widely used: human: ethylene terephthalate. Further, in the optical layer 21, in addition to the super-speed synthetic resin, an anti-deteriorating agent, a dispersing agent, etc., such as a filler, a plasticizer, and a stable microlens array 23 are formed of a plurality of 24 systems. r A a 4 is composed. The microlens is formed on the substrate, on the surface side of the substrate film 2, and is (approximate to the shape of the hemisphere). Further, the spherical convex lens is not limited to the above-mentioned semi-', &quot;", microlens of a spherical concave lens. The hemispherical concave 31 201005374 also has an excellent optical work lens microlens and the above micro The lens 24 months, the microlens 24 is densely arranged and disposed on the surface of the substrate film 2 in a few ways. In terms of the body, the microlens 24 is arranged in a 鈇0**-angular lattice pattern. On the surface of the substrate film 2. Therefore, the distance between the material (4) and the A 24 (p) and the distance between the lenses (S) are all fixed. The pattern can be densely arranged with the microlens. Fortunately, the lens 24 is not limited to the above-mentioned regular digonal lattice pattern which can be densely filled, and may also be a square lattice pattern or a random pattern. By the random pattern, the wind system is in the optical system. When the sheet 20 overlaps with other optical members, the generation of the moiré can be reduced. The lower limit of the diameter (d) of the microlens 24 is preferably i 或 or Λ 卜 卜 民, preferably better than i 〇 &quot; m, more preferably 100... Preferably, it is 20... On the other hand, the upper limit of the diameter (8) of the microlens 24 is preferably 100&quot; More preferably 70 "m. If the diameter (D) of the microlens 24 is less than 1 ’, the influence of the diffraction becomes large, which tends to cause a decrease in the light dryness or color separation, resulting in deterioration of quality. On the other hand, if the diameter (D) of the right microlens 24 exceeds 1 〇 # # m, it is liable to cause an increase in thickness or uneven brightness, resulting in deterioration in quality. In addition, by making the diameter (D) of the microlens 24 1 〇〇 or more, the number of microlenses 24 per unit area is reduced, and the area of the optical sheet 2 as the lenticular sheet is increased. It is easy to reduce the technical and cost burden of manufacturing. The lower limit of the surface roughness (Ra) of the microlens 24 is preferably 〇.〇1 # claw, more preferably 0.03 #m. On the other hand, the upper limit of the surface roughness (Ra) of the microlens 24 is preferably 0.1 Å, more preferably 〇 7 . By setting the surface roughness (Ra) of the microlens 24 to the above lower limit or more as described above, 32 201005374, the formability of the microlens array 23 of the optical sheet 20 can be made easy, thereby reducing the manufacturing technique and The burden on the cost. On the other hand, by reducing the surface roughness (Ra) of the microlens 24 to the above upper limit, the scattering of light on the surface of the microlens 24 is lowered, and the condensing function of the microlens 24 or the normal line can be improved. The refractive function on the direction side achieves high luminance in the front direction due to the good optical function. The lower limit (H/R) of the height (H) of the microlens 24 with respect to the radius of curvature (R) is preferably 5/8, more preferably 3/4. On the other hand, the upper limit of the height ratio (H/R) is preferably! . By setting the π-degree ratio (H/R) of the microlens to the above range as described above, the lens refraction in the microlens 24 is effectively exerted, and the optical light such as the condensing of the optical sheet 2 is remarkably improved. Features. The upper limit of the inter-lens distance (s; p_D ) of the microlens 24 with respect to the diameter (D) is preferably 1/2, more preferably 1/5. By setting the inter-lens distance (s) of the microlens 24 to the above upper limit or less as described above, the flat portion which is disadvantageous to the optical function is reduced, and the optical function such as condensing of the optical sheet 20 is remarkably improved. The lower limit of the filling ratio of the microlens 24 is preferably 4% by weight, more preferably 6% by weight. By setting the filling ratio of the microlens 24 to the above lower limit or more as described above, the area occupied by the microlens 24 on the surface of the optical sheet 20 is increased, and the optical function such as condensing of the optical sheet 20 is remarkably improved. Furthermore, the numerical range of the height ratio (H/R), the spacing ratio (S/D) and the filling ratio is based on the brightness of the non-sequential ray tracing using the Monte Carlo method (M〇nte Carl〇) 33 201005374. Analyze the simulation and export it. The lower limit of the refractive index of the material constituting the optical layer 21 is preferably 1.45. On the other hand, the upper limit of the refractive index of the material is preferably '3 ' or more preferably 1.6. In this range, I8' constituting the optical layer 2 is optimally formed by using the refractive index of the optical layer as described above as the above range, thereby effectively exhibiting the refraction of the microlens material, thereby further improving The optical sheet 2. Optical work such as condensing: refracting the manufacturing method of the optical yoke 20, as long as it can be manufactured and is not particularly limited, it is suitable to employ a manufacturing method including the following (4): "The material film forming step" is performed by using a τ type mold Extrusion molding method ' (a = substrate film broadcast body composed of plastic resin; (b) lamination step = composition for laminating anti-adhesive layer on one side of the material film extrudate; (c) stretching step 2 The substrate film extrudate and the anti-adhesive layer layer are stretched; the optical layer is formed on the surface of the base film 2. As a method of forming the optical layer 21, specifically: a) a method of synthesizing the wax and the base film 2 in a sheet having an inverted shape on the surface of the microlens array 23, and peeling off the sheet mold to form the optical layer 21; (1) The resin is reheated and then pressed together with the substrate film 2 = a mold having a reversed shape of the surface of the microlens array 23 and a metal plate, and a method of transferring the shape; 2 having a micro-transparent roller through the peripheral surface a pinch between the (c) and a molten film of the resin and the substrate mirror array a roll mold having a reversed shape of the surface and an extrusion sheet forming method of transferring the above shape; 34 201005374 (d) applying an ultraviolet curable resin to the base film 2, and then extruding the same as described above a method of inverting a shape of a sheet mold, a mold or a roll mold to transfer the shape onto an uncured ultraviolet curable resin and irradiating ultraviolet rays to harden the ultraviolet curable resin; (e) unclamping ultraviolet rays A method in which a curable resin is applied to a mold or a roll mold having the same reverse shape as described above, and is pressed by the base film 2 to be flattened and irradiated with ultraviolet rays to harden the ultraviolet curable resin; (f) a method of forming an uncured (liquid) ultraviolet curable resin or the like from a fine nozzle or releasing it onto a substrate 臈 2 to form a microlens 24 and hardening it; (g) using an electron beam curing resin A method of replacing the ultraviolet curable resin, etc. Further, the base film forming step and the laminating step may be simultaneously performed by a co-extrusion molding method using a T-die. Further, it is also possible to use T The co-extrusion molding method of the mold performs the step of forming the optical layer 21 simultaneously with the substrate film forming step and the laminating step. Specifically, the molten synthetic resin is extruded from the T-die to the peripheral surface and has a microlens The surface of the array 4 23 is a nip between the roll die of the opposite shape and the other, and the pot is hardened, whereby the optical sheet 20 can be simultaneously formed. By the extrusion molding method In the method of stretching the laminate of the base film extrusion and the laminate for the release layer, the laminate of the composition for the release layer is laminated on the surface of the extruded substrate film. In the step and the optical layer forming step, the layering step and the optical layer forming step can be carried out on the same production line as the substrate film forming step 35 201005374 and the stretching step, whereby the optical sheet can be manufactured at a manufacturing cost. That is, as a step of laminating in the production line, improving productivity and work efficiency, and further, as a manufacturing method having a damage (four) which is opposite to the above-described microlens array u:), for example, it can be manufactured by using light:: Forming a speckled three-dimensional pattern on the material, and manipulating the three-dimensional pattern to make a curved surface, thereby fabricating a microlens array model, and then depositing a metal layer on the surface of the microlens array model by electroforming, and then The metal layer is peeled off. Further, as the method of fabricating the microlens array model, the method described in the above (f) may be employed. The optical sheet 20 has a high concentration of light, such as refraction and diffusion toward the normal direction side by the microlens array 23, and can easily and surely control its optical function. Therefore, the optical 4 can, for example, control the peak direction of incident light rays toward the pupil of the backlight unit to be controlled at an inclination angle optimum for the refraction toward the normal direction side. In addition, the optical sheet has a higher anti-adhesive property, uniformity of light transmittance, brightness, etc., economy, and film properties by the anti-adhesive|3. Further, the above-mentioned "microlens" means a partial spherical surface, a microlens such as a hemispherical convex lens or a hemispherical concave lens. The so-called straight (E))", the diameter of the base or opening of the microlens. The term "height" refers to the vertical distance from the base surface to the top of the microlens when the microlens is a convex lens. When the microlens is a concave lens, it refers to the open surface of the microlens. The vertical distance to the bottom. The term "inter-lens distance" means the shortest distance between one of the adjacent pairs of microlenses 36 201005374. The "filling rate" refers to the area ratio of the microlens per unit area in the surface projection shape. The "triangular lattice pattern" refers to a pattern in which the surface is divided into three (four) of the same shape, and the microlenses are arranged at the respective vertices of the regular triangle.

本發明之液晶顯示裝置用背光單元具備:方形之導光 板、沿著導光板的長邊側邊緣配設之燈源、及積層於導光 板表面之光擴散片、稜鏡片等方形之光學片;其^用該光 學片卜11、2〇作為該光擴散片、稜鏡片#。因如上:般 該光學片具有較高之防黏性、總透光率、亮度等之均勻性、 經濟性及“性,故該背光單元可顯著地提高燈源所發出 之光線之利用效率,可促進目前社會所要求之高亮度化、 高品質化、省能源化及薄型輕量化。 再者,本發明之光學片及背光單元並不限定於上述實 施形態。例如’該光學片並不限定於上述光擴散片及微透 鏡片’亦可應用於其他之稜鏡片、扁豆狀透鏡片、菲淫爾 透鏡片等光學片。ϋ由將該防黏層積層於該稜鏡片、扁豆 狀透鏡片、ΙΜ里爾透鏡片等光學片之背面,可提高防黏性、 總透光率、亮度等之均勻性、經濟性及薄膜性。 又除基材膜、光學層及防黏層外,亦可於該光學片 中積層有紫外線吸㈣u、抗靜電劑層、外塗層 層等其他層。 者 。藉 霉占合 元的 進而,上述聚合物組成物中可含有紫外線吸收劑 由如上所述由含有紫外線吸收劑之聚合物組成物形成 劑6’可賦予該光學片抗紫外線功能,從而將自背光單 37 201005374 ’立原發出之微里抗%外線’彳(防止液晶層遭紫外線破壞。 作為該紫外線吸收劑,只要係可吸收紫外線、且高效 地將其轉換成熱能、且對光為穩定之公知的化合物即可, 並無特別限定。其巾,較佳為紫外線吸收功能較高、與上 述基材聚合物的相溶性良好、且 物中之水揚酸系紫外線吸收劑 劑、苯并三唑系紫外線吸收劑、 可穩定地存在於基材聚合 '二苯甲酮系紫外線吸收 及氰基丙烯酸酯系紫外線 吸收劑;可使用選自該等之群組中的i種或2種以上。又, 作為紫外較㈣,亦可較佳地使用分顿巾具有紫外線 吸收基之聚合物(例如’日本觸媒股份有限公司製造之 使用該分子鏈中具有紫外 6之主聚合物之相溶性較The backlight unit for a liquid crystal display device of the present invention includes a square light guide plate, a light source disposed along a long side edge of the light guide plate, and a light optical sheet such as a light diffusion sheet or a slab laminated on the surface of the light guide plate; The optical sheet 11 and the second sheet are used as the light diffusion sheet and the sheet #. Because the optical sheet has the higher uniformity, economy, and "sex" of the anti-adhesive property, the total light transmittance, the brightness, and the like, the backlight unit can significantly improve the utilization efficiency of the light emitted by the light source. Further, the optical sheet and the backlight unit of the present invention are not limited to the above-described embodiments. For example, the optical sheet is not limited. The light diffusing sheet and the microlens sheet can also be applied to other optical sheets such as a scorpion sheet, a lenticular lens sheet, and a lenticular lens sheet. The anti-adhesive layer is laminated on the enamel sheet and the lentil lens sheet. The back surface of the optical sheet such as the cyrillic lens sheet can improve the uniformity, economy and film properties of the anti-sticking property, the total light transmittance, the brightness, etc. In addition to the substrate film, the optical layer and the anti-adhesive layer, Further, other layers such as an ultraviolet ray (iv) u, an antistatic agent layer, and an overcoat layer may be laminated on the optical sheet. Further, the polymer composition may further contain an ultraviolet absorber as described above. Containing purple The polymer composition forming agent 6' of the line absorbent can impart ultraviolet ray resistance to the optical sheet, thereby preventing the liquid crystal layer from being damaged by ultraviolet rays from the backlight sheet 37 201005374 The absorbent is not particularly limited as long as it is a compound which can absorb ultraviolet rays and is efficiently converted into heat energy and is stable to light. The towel preferably has a high ultraviolet absorbing function and the above-mentioned base. The compatibility of the material polymer is good, and the water-based acid-based ultraviolet absorber and the benzotriazole-based ultraviolet absorber are stably present in the substrate to polymerize 'benzophenone-based ultraviolet absorption and cyanoacrylate. The ester-based ultraviolet absorber; one or two or more selected from the group of the above-mentioned groups can be used. Further, as the ultraviolet (four), a polymer having an ultraviolet absorbing group of the split towel can be preferably used (for example, The compatibility of the main polymer with UV 6 in the molecular chain manufactured by Nippon Shokubai Co., Ltd.

Yudaburu UV」系列等)。藉由 線吸收基之聚合物,而與黏合劑 高,從而可防止因紫外線吸收劑之渗出等而引起之紫外線 吸收功能的劣Μ匕。再者,亦可將分子鏈中具有紫外線吸收 基之聚合物作為黏合劑6之基材聚合物,X,亦可將該鍵 結有紫外線吸收基之聚合物作為黏合冑6 &lt;基材聚合物, 進而該基材聚合物中亦可含有紫外線吸收劑,&amp;而可進一 步提高紫外線吸收功能。 上述紫外線吸收劑相對於黏 量的下限,較佳為0· 1質量%, 質量% ;紫外線吸收劑之上述含 質 量%,最佳為5質量%。其原因在於:若紫 %,更佳為 外線吸收劑相對於基材聚合物 光學片無法有效地發揮紫外線 合劑6之基材聚合物之含 更佳為1質量%,最佳為3 量之上限’較佳為1 〇質量 之質量比小於上述下限,則 吸收功能;反之,若紫外線 38 201005374 吸收劑之質量比超過上述上限,則會對基材聚入 良影響,且導致黏合劑6之強度、耐久性等下口造成不 亦可使用紫外線穩定劑(包含分子鍵上鍵^右 穩定基之基材聚合物)來代替上述、 、、· 乂尔?τ琛吸收劑, 紫外線穩定劑與紫外線吸收劑同時使 ^ , 定劑,可使紫外線所產生的自由基、活性=紫外線穩 办丨王虱4去活性, 高紫外線穩定性、㈣性等。作為該料線穩定劑, 可適且使用對紫外線的穩定性較高之受阻胺系紫外線釋定 劑。再+者1由將紫外線吸收劑與紫外線穩定劑加以併用, 可顯著提高紫外線之防劣化及耐候性。 實施例 ::下,基於實施例詳述本發明,但本發明並非基於該 貫施例之δ己載而被限定性地解釋。 [實施例1] 將聚對苯二甲酸乙二自旨(以下稱為「ΡΕΤ」)供給至丁 型核’進行擠出成形而形成 双FhT臈擠出體,將此ρΕΤ膜擠 出體沿著膜長度方向拉伸 欣乂士 3七。其次,製備以固體成分換 异含有100份之聚酯多元 A/r 醇(東乎紡績公司製造之「Vylonal MD1250」)、12〇 份 之肷焱異虱酸酯(苐一工業製藥公司 製 k 之 Elastron H-3 , ) π 」^ 、及50份之平均粒徑為100 nm 之膠體二氧化梦之防產Yudaburu UV" series, etc.). By absorbing the polymer of the line, it is high in adhesion to the binder, thereby preventing the inferiority of the ultraviolet absorbing function due to bleeding of the ultraviolet absorber or the like. Further, a polymer having an ultraviolet absorbing group in a molecular chain may be used as a base polymer of the binder 6, and X may also be a polymer having an ultraviolet absorbing group bonded thereto as a binder &6 &lt; Further, the base polymer may further contain an ultraviolet absorber, and the ultraviolet absorption function may be further enhanced. The lower limit of the ultraviolet absorber with respect to the viscosity is preferably 0.1% by mass and % by mass, and the above-mentioned % by mass of the ultraviolet absorber is preferably 5% by mass. The reason for this is that if the % is purple, it is more preferable that the outer absorbent is not more effective than the base polymer optical sheet, and the content of the base polymer of the ultraviolet compound 6 is preferably 1% by mass, preferably the upper limit of the amount of 3 Preferably, the mass ratio of 1 〇 mass is less than the lower limit, and the absorption function; on the other hand, if the mass ratio of the ultraviolet ray 38 201005374 absorbent exceeds the above upper limit, the substrate concentration is affected, and the strength of the adhesive 6 is caused, In the case of durability, etc., it is not possible to use a UV stabilizer (a base polymer containing a molecular bond and a right stabilizer) instead of the above, , and琛 琛 absorbent, UV stabilizer and UV absorber at the same time make ^, the agent, can make the free radicals generated by ultraviolet rays, activity = UV stabilized 丨 虱 虱 4 deactivation, high UV stability, (four) and so on. As the strand stabilizer, a hindered amine-based ultraviolet release agent having high stability against ultraviolet rays can be suitably used. Further, the combination of the ultraviolet absorber and the ultraviolet stabilizer is used to significantly improve the deterioration of the ultraviolet rays and the weather resistance. EXAMPLES Hereinafter, the present invention will be described in detail based on the examples, but the present invention is not limitedly construed based on the δ loading of the examples. [Example 1] Polyethylene terephthalate (hereinafter referred to as "ΡΕΤ") was supplied to a butadiene core to perform extrusion molding to form a double FhT crucible extrudate, and this p-ruthenium film extrudate was extruded. Stretching the gentleman's 3 seven in the length direction of the film. Next, a 100 parts polyester polyhydric A/r alcohol ("Vylonal MD1250" manufactured by Tosoh Textile Co., Ltd.) and 12 parts of bismuth isophthalate (manufactured by Sigma-Industrial Pharmaceutical Co., Ltd.) were prepared. Elastron H-3, ) π ”^, and 50 parts of colloidal oxidized dreams with an average particle size of 100 nm

毒層用組成物,藉由輥塗法將該防黏 層用組成物塗佈於PET ,^ M擠出體上,從而形成該防黏層用 ,、且成物之層與上述ΡΕτ趙徐 „ Α 膜擠出體之積層體。繼而,將該積 層體沿著膜寬度方向拉柚石, 拉伸至3倍,藉此獲得平均厚度為丨88 39 201005374 之光學片用基材丨(防黏層之平均厚度為ι〇〇麵)。 該等步驟均在同一生產線上連續進行。 其次,向以固體成分換算含有1〇〇份之丙稀酸多元醇 (大日精化工業公司製造之「肪B Μ腿UM s A」)及5份 之硬化劑(日本聚㈣公司製造之「c。削咖敗」)之聚 合物組成物中,混合100份之平均粒徑為15 ^瓜之丙烯酸 系樹脂珠粒(積水化成品工業公司製造之「ΜΒχ_ΐ5」), 而製造光學層用組成物。藉由輥塗法將該光學層用組成物 以達到15〆(以固體成分換算)之方式塗佈於上述光學 片用基材片之表面,並使其硬化’藉此形成光學層,最後 裁剪成20 cm見方,藉此獲得實施例丨之光學片。 [實施例2] 將與實施例丨中所使用者相同之防黏層用組成物與 PET分別供給至多層塑模中,並進 疋叮,、儕出成形,藉此形成 由防躲層用組成物層與PET臈擠出體所構成之共擠出成形 體。繼而,以膜長度方向為3倍且膜寬度方向&amp; 3倍之拉 伸比對該共擠出成形體進行同時雙轴拉伸,藉此獲得平均 厚度為188 ”之光學片用基材片(防黏層之平均厚 lOOnm)。該等步驟均在同一生產線上連續進行。又‘ 接著’以與實施合&quot;同樣之方式,將上述光學&amp;The composition for the toxic layer is applied to the PET, the M extrudate by a roll coating method to form the anti-adhesive layer, and the layer of the object and the above-mentioned ΡΕτ „ 积 The laminate of the film extrusion. Then, the laminate is stretched to 3 times along the width direction of the film, and stretched to 3 times, thereby obtaining a substrate for an optical sheet having an average thickness of 丨88 39 201005374 (prevention The average thickness of the adhesive layer is 〇〇 〇〇.) These steps are carried out continuously on the same production line. Secondly, the acrylic acid polyol is contained in a solid content conversion (manufactured by Dairi Seiki Co., Ltd.) 100 parts of the polymer composition of the hardener ("C.") A resin bead ("ΜΒχ_ΐ5" manufactured by Sekisui Kogyo Co., Ltd.) was used to produce a composition for an optical layer. The composition for an optical layer is applied to the surface of the substrate sheet for an optical sheet by a roll coating method to be 15 Å (in terms of solid content), and is cured, thereby forming an optical layer, and finally cutting. An optical sheet of Example was obtained in a 20 cm square. [Example 2] The same anti-adhesive layer composition and PET as those used in the Example were supplied to a multilayer mold, respectively, and then formed into a multi-layer mold, thereby forming a composition for preventing the hiding layer. A coextruded formed body composed of a layer of material and a PET crucible extrudate. Then, the co-extruded molded body was simultaneously biaxially stretched at a stretching ratio of 3 times in the film length direction and 3 times in the film width direction, thereby obtaining a substrate sheet for an optical sheet having an average thickness of 188 Å. (the average thickness of the anti-adhesive layer is 100 nm). These steps are all carried out continuously on the same production line. And 'Next' in the same way as the implementation of the &quot;

成物塗佈於該光學片用基材片之表 H A 此竹』 上而形成光學層, 裁剪成20 cm見方,藉此獲得實施例2之光學片。 [比較例] 使用作為基材膜之厚度為188心的透明聚對苯二甲 201005374 酸乙二酯製膜,作為光學層用組成物之與上述實施例1同 =的光子層用組成物,作為防黏層用組成物之在以固體成 分換算含# 1GG份之丙烯酸多元醇(大日精化卫業公司製 仏之RUB MEDIUM SA」)、及5份之硬化劑(日本聚胺The optical film of Example 2 was obtained by coating the object on the surface of the substrate sheet for the optical sheet, and forming an optical layer, and cutting it into 20 cm square. [Comparative Example] A film made of transparent polyethylene terephthalate 201005374 with a thickness of 188 core as a base film was used as a composition for an optical layer, and a photonic layer composition of the same as in the above Example 1 was used. As a composition for the anti-adhesive layer, an acrylic polyol containing #1GG parts (RUB MEDIUM SA manufactured by Daisei Seiki Co., Ltd.) and 5 parts of a hardener (Japanese polyamine) in terms of solid content conversion

酯公司製造之「Cor〇nateHX」)之聚合物組成物中含有U 伤之平均粒#為3 # m之丙婦酸系樹脂珠粒(積水化成品 工業公司製造之「臟_3」)而成的組成物。將該光學層 用組成物以達到15g/m2 (以固體成分換算)之方式積層於 基㈣表面’將防黏層用組成物以達到3 g / m 2 (以固體成分 換算)之方式積層⑨基材膜背面,#此獲#比較例 片。 [特性之評價] 、使用上述實施例1及2之光學片及比較例之光學片, 進:该等光學片之防黏性的評價,及總透光率、霧值及正 面亮度相對值的測定。將其結果示於下述表i。 該防黏性,係將以有水間隔之狀態下將光學片之背面 與丙烯酸板重疊而成者在環境試驗條件下(7〇ciCxRH95%) 放置24小時,並嘗試進行光學片與丙烯酸板之剝離,將容 易剥離之情形評價為Q,將不容易剝離之情料價為χ。 又’總透光率、霧值及正面亮度相對值,係根據jis_k7i〇5 並使用suga Test Instrument股份有限公司製造之霧值計進 行測定。 41 201005374 . [表 1] 防黏性之評價 總透光率 (Tt) 霧值 正面免度相對值 實施例1 〇 69.5 95.8 102 實施例2 〇 69.0 95.7 101 比較例 X 67.9 95.7 1〇〇 (上述數值之單位全部為[%]) 如上述表i所示,實施例丄及2之光學片,與比較例 之光學片進行比對,具有較高的防黏&amp;,而且具有優異的 總透光率、霧值及正面亮度相對值。 再者,對實施例i之光學片之防黏層背面之算術平均 粗度(Ra)、最大高度(Ry)及十點平均粗度(Rz)進行 測定,結果分別為0.09 口、〇.63㈣及〇52心。該 光學片之防黏層之鉛筆硬度A Η〜2Ηβ該表面性狀之算: 平均粗度(Ra) '最大高度(Ry)及十點平均粗度㈤, :根據JIS刪01_1994,將截止波長λ c設為2 5麵、將評 價長度没為12.5 mm,並使用東京精密股份有限公司製造之 觸針式表面粗度測定機r Surfc〇m 47〇 A」進行則—衣 產業上之可利q忖 如上所述,I發明之光學片m乍液晶顯 光單元的構成要素,尤其適用於穿透式液晶顯示裝置。 【圖式簡單說明】 Μ 圖1係表示本發明一實施形態之光學片 ο之不意性剖面 42 201005374 圖。 圖2係圖1之光學片之示意性仰視圖。 圖3係表示與圖1之光學片形態不同之光學片之示意 性剖面圖。 圖4係表示與圖1及圖3之光學片形態不同之光學片 之示意性剖面圖。 圖5 ( a )係表示普通端面照光型背光單元之示意性立 體圖,圖5 ( b )係表示普通光學片之示意性剖面圖。 【主要元件符號說明】 1 ' 11 、20 光學片 2、 55 基材膜 3 &gt; 12 '57 防黏層 4、 21 光學層 5 填料 5a 小徑填料 5b 大徑填料 6、 9、 58 ' 60 黏合劑 7、 7a 、7b 凸部 8 ' 59 光擴散劑 10 聚合物 22 片狀部 23 微透鏡陣列 24 微透鏡 50 端面照光型背光單元 43 201005374The polymer composition of "Cor〇nateHX" manufactured by Ester Co., Ltd. contains U-injury average granules #3#m of propylene fosphate resin beads ("dirty _3" manufactured by Sekisui Kogyo Co., Ltd.) The composition of the composition. The composition for the optical layer was laminated on the surface of the base (4) in a manner of 15 g/m 2 (in terms of solid content). The composition for the release layer was laminated to 3 g / m 2 (in terms of solid content). The back surface of the substrate film, #本得#Comparative example. [Evaluation of Characteristics] Using the optical sheets of the above Examples 1 and 2 and the optical sheets of the comparative examples, the evaluation of the anti-adhesive properties of the optical sheets, and the relative values of the total light transmittance, the haze value, and the front luminance Determination. The results are shown in the following Table i. The anti-adhesive property is to be placed under the environmental test conditions (7〇ciCxRH95%) for 24 hours in the state where the back surface of the optical sheet is overlapped with the acrylic sheet at a water interval, and an optical sheet and an acrylic sheet are tried. In the case of peeling, the case where the peeling is easy is evaluated as Q, and the price of the material which is not easily peeled off is χ. Further, the relative values of the total light transmittance, the fog value, and the front luminance were measured in accordance with jis_k7i〇5 using a fog value meter manufactured by Suga Test Instrument Co., Ltd. 41 201005374 . [Table 1] Evaluation of anti-sticking property Total light transmittance (Tt) Haze value positive degree of relative value Example 1 〇69.5 95.8 102 Example 2 〇69.0 95.7 101 Comparative Example X 67.9 95.7 1〇〇 (above The unit of the numerical value is all [%]. As shown in the above Table i, the optical sheets of Examples 丄 and 2 are compared with the optical sheets of the comparative example, and have a high anti-adhesion &amp; Relative values of light rate, fog value and front brightness. Further, the arithmetic mean roughness (Ra), the maximum height (Ry), and the ten-point average roughness (Rz) of the back surface of the anti-adhesive layer of the optical sheet of Example i were measured, and the results were 0.09, 〇.63 (4), respectively. And 〇 52 hearts. The pencil hardness of the anti-adhesive layer of the optical sheet A Η 〜 2 Η β The calculation of the surface properties: Average roughness (Ra) 'Maximum height (Ry) and ten-point average roughness (V), : According to JIS deletion 01_1994, the cutoff wavelength λ c is set to 2 5 faces, the evaluation length is not 12.5 mm, and the stylus type surface roughness measuring machine r Surfc〇m 47〇A manufactured by Tokyo Precision Co., Ltd. is used for the clothing industry. As described above, the constituent elements of the optical sheet m乍 liquid crystal display unit of the invention of the invention are particularly suitable for a transmissive liquid crystal display device. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a view showing an unintentional cross section of an optical sheet according to an embodiment of the present invention 42 201005374. Figure 2 is a schematic bottom view of the optical sheet of Figure 1. Fig. 3 is a schematic cross-sectional view showing an optical sheet different from the optical sheet of Fig. 1. Fig. 4 is a schematic cross-sectional view showing an optical sheet different from the optical sheet of Figs. 1 and 3. Fig. 5(a) is a schematic perspective view showing a conventional end face illumination type backlight unit, and Fig. 5(b) is a schematic cross-sectional view showing a general optical sheet. [Main component symbol description] 1 '11, 20 optical sheet 2, 55 base film 3 &gt; 12 '57 anti-adhesive layer 4, 21 optical layer 5 filler 5a small-diameter filler 5b large-diameter filler 6, 9, 58 ' 60 Adhesive 7, 7a, 7b Projection 8' 59 Light diffusing agent 10 Polymer 22 Sheet portion 23 Microlens array 24 Microlens 50 End-illuminated backlight unit 43 201005374

51 52 53 54 54a 56 61 D H P R S T 線狀燈源 導光板 光擴散片 棱鏡片 棱鏡部 光擴散層 樹脂珠粒 微透鏡24之直徑 微透鏡24之高度 微透鏡24之間距 微透鏡24之曲率半徑 透鏡間距離 平坦部之平均厚度 4451 52 53 54 54a 56 61 DHPRST Linear Light Source Light Guide Light Diffuser Prism Piece Prism Light Diffusion Layer Resin Bead Microlens 24 Diameter Microlens 24 Height Microlens 24 Between Curvature Radius of Microlens 24 Lens Average thickness of the flat portion 44

Claims (1)

201005374 丁味寻刊範圍·· 種光予片,其係具備透明之基材膜 膜之一面之光學 材膜、積層於該基材 者,其特徵在於:I積層於基材膜之另一面之防黏層 該防黏層含有填料及其樹脂製黏合劑, 防黏層之平坦部之 下, 干句厚度為50 nm以上、150 nm以 + H ^ 7() nm以上、⑽請以下。 2. 如申請專利範圍第1項之光學片,其中: 填料之平均粒徑大於該防黏層之平坦部之平均厚度。 3. 如申請專利範圍第1項之光學片,其中:_ °亥填料含有主成分之小徑填料、及平均粒徑大於該小 徑填料之副成分之大徑填料, 6亥小徑填料之平均粒徑為50 mn以上、15〇 nm以下。 4. 如申請專利範圍帛1項之光學片,其中: 該防黏層中之填料之含量為2〇質量%以上、5〇質量〇/〇 以下。 、 5. 如申請專利範圍帛1項之光學片,其中: 構成該黏合劑之聚合物具有三維交聯結構。 6. 如申請專利範圍帛i項之光學片,其中: 該黏°劍係由含有丙烯酸多元醇及硬化劑之聚合物組 成物而形成。 7. 如申請專利範圍帛1項之光學片,其中: 該填料係使用膠體二氧化矽。 45 201005374 8.如申請專利範圍第3項之光學片,其中. =填料之粒徑分布之變異係數為2。%以下 如申請專利範圍第1項之光學片,直中: 該防黏層中分散含有抗靜電劑。’、. 其中: 1〇.如申請專利範圍第1項之光學片 該光學層含有光擴散劑及其黏合劑 其中: :1.如申請專利範圍第1項之光學片,其 °玄光學層具有帶折射 、 注之微細凹凸形狀。 出 八 .種液晶顯示裝置用之 之光線分散並導向表面侧者,其特:在於、係使燈源所發 具備申請專利範圍第}〜 中 、· 頁中任一項之光學片。 、圖式: (如次頁) 46201005374 Dingwei's Scope of Circulation ···················································· Anti-adhesive layer The anti-adhesive layer contains a filler and a resin-made adhesive. Below the flat portion of the anti-adhesive layer, the thickness of the dry sentence is 50 nm or more, 150 nm to + H ^ 7 () nm or more, and (10) below. 2. The optical sheet of claim 1, wherein: the average particle size of the filler is greater than the average thickness of the flat portion of the release layer. 3. For the optical sheet of claim 1 of the patent scope, wherein: _ ° hai filler contains a small diameter filler of a main component, and a large diameter filler having an average particle diameter larger than a subcomponent of the small diameter filler, 6 HAI small diameter filler The average particle diameter is 50 mn or more and 15 〇 nm or less. 4. For the optical sheet of claim 1, wherein the content of the filler in the anti-adhesion layer is 2% by mass or more and 5 〇 or less. 5. The optical sheet of claim 1, wherein: the polymer constituting the binder has a three-dimensional crosslinked structure. 6. The optical sheet of claim ii, wherein: the viscous sword is formed from a polymer composition comprising an acrylic polyol and a hardener. 7. The optical sheet of claim 1 wherein the filler is a colloidal cerium oxide. 45 201005374 8. An optical sheet according to item 3 of the patent application, wherein the coefficient of variation of the particle size distribution of the filler is 2. % or less As in the optical sheet of Patent Application No. 1, straight: The anti-adhesive layer contains an antistatic agent dispersed therein. ',. Among them: 1 〇. As claimed in the patent scope of the first optical sheet, the optical layer contains a light diffusing agent and its binder. Among them: 1. The optical sheet of claim 1 of the patent scope, its optical layer It has a fine concavo-convex shape with refraction and annotation. The light source for the liquid crystal display device is dispersed and guided to the side of the surface, and is characterized in that it is an optical sheet of any one of the patent application scopes. , pattern: (such as the next page) 46
TW098121101A 2008-07-18 2009-06-24 Optical sheet and the use of its backlight unit TWI406050B (en)

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KR101056638B1 (en) 2011-08-12

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