200951269 九、發明說明： 【發明所屬之技術領域】 本發明係有關於—種聚丙烯不 =種嘴塗竹炭粉末於聚丙稀不織布的：的加工方法，尤指 戾粉末均勻結合於奄 σ工方法’其可將竹 丙烯不織布上。 【先前技術】 由於竹厌材料本身具有優異之 電磁波、除、、# 4 附此力、調濕性、抗 此竹炭材料廣泛使用於功能性广夕重功能’因 合於纖维上甘繃、土 士亡此 科’如將竹炭材料結 果增加衣物服雜沾λ处引用竹厌的機能性效 ，力衣物服飾的功能性。例如，利用竹 外線和負離子的功能，使含有竹炭 一生&工 土隹Α V 才斗的衣·物服飾達成促 進血液循環以及蓄熱保溫等功能。 然而，當欲將竹炭材料結合於亨 右从山U 於聚丙烯不織布上時，卻 有竹厌材料分散性不佳的現象，因而 ^ 1^"竹厌材料於聚 丙烯不織布上的應用。因此，如何 、 於臂^ 厌材料均勻地結合 於t丙烯不織布上乃成為業界致力研究的課題。 【發明内容】 有鑑於現有使竹炭材料結合於聚丙稀不織布的方法盈 法使竹炭均勻分布，本發明之目的在於提供—種喷塗竹二 :末於聚丙烯不織布的加工方法，其可以提高竹炭的分= 為達成以上的目的，本發明之噴塗竹炭粉末於聚丙 不織布的加工方法係包括以下步驟： 、 200951269 提供-預處理竹炭粉末：將竹炭 合攪拌，而後過遽並供乾該竹炭粉末得料=偶合劑現 末； 忒預處理竹炭粉 提供一樹脂溶液； 浸潰一聚丙烯不織布：將㈣ 脂溶液中丨 π个螂布次潰於該樹 之聚丙婦不織 加熱該聚丙烯不織布：加熱該已浸潰 布，使樹脂固定於該聚丙烯不織布上. 喷塗該預處理竹炭粉末：混合該預 及醇類形成一混合溶液，並 竹厌叔末、水 不織布上；以及 並將该混合溶液噴塗於該聚丙烯 熱麼該聚丙稀不織布：使該已噴塗昆 不織布進行熱壓定型處理。 、 σ/奋液之聚丙烯 卓乂 l的疋，e玄石夕燒偶合劑係為苯基三 — xysilane ; PTES)或复 ^ ^ ^ (phenyl 基石夕烧（TE〇S)等。/、他&適之錢偶合劑’如四乙 較佳的是，該樹月旨係為聚丙稀酸甲酉旨樹脂。 較佳的是，該提供—預處理竹炭粉末之步驟中， 使竹厌粉末與水混合並在溫度為85~9 :停止加熱並加入彻合劑规拌，隨後過料::末： 其烘乾，得到該預處理竹炭粉末。 末將 較佳的是，該樹脂溶液係以水和㈣調和而成。 較佳的是，該噴塗㈣處理竹炭粉末 類係為乙醇。 ^t該醇 6 200951269 幸父佳的是，該熱壓哕 溫度為90〜II〇t，時間^ 7不織布之步驟中，係進行 較佳的《 ^ 為0〜90秒之熱壓定型處理。 聚丙婦不織布置入—執卜荆席不A布之步驟中，係將該 及時間3〇 90 f '”、至疋1機_，以9〇〜！l〇°C的溫度以 士 0〜9〇秒’供烤該聚丙烯不織布。 發明可達成的具體功效包括： 1 ·本發明係使聚丙夺 再利用經矽烷偶“，烯不織布先d貝於樹脂溶液中， 烯不嘰布上门口知預處理之竹炭粉末溶液噴塗於該聚丙 布上I二粉末可牢固地結合於該聚两稀不織 丙稀不2 布提供各式機能性效果，包括提升聚 性等，且以本發二;二：離子釋放量、抗菌性及消臭 氣性，可利用降低聚丙稀不織布的透 务明所製得之成品作為濾材使用，如口罩 之過濾材料等。 干 處理，利所使用之竹炭粉末由於先以矽烷偶合劑預 烷偶合劑同時具親疏水基團的特性使竹碳盥 聚丙烯不織布之p爿 队八 0入5⑯的分散結合效果，因此竹炭粉末 、Λ丙稀不織布上時有較佳的分散性H吏以本發明 之方法加 ^丙烯不織布可具有較佳的質感。 【實施方式】 本發明之比較例與實施例所使用的材料與藥品如下： h聚丙烯不織布（基重30g/m2) 2 山、 •竹厌粉（景天科技，粒徑大小：小於80 μ m) 3·聚丙烯酸曱酯樹脂：（克萊思，AL-500BN，固成份 200951269 40%) 4·石夕烷偶合劑（3Acros ’苯基三乙氧矽烷；phenyl triethoxysilane ； PTES) 5.乙醇（濃度95%) 本發明之比較例與實施例所使用的實驗設備如下： 1 ·柔軟度試驗機（Inteco，45度傾斜） 2·拉伸強度試驗機（Alphaten 400) ❹ 3. 掃描式電子顯微鏡（SEM，JSM-6700F) 4. 電子天平（FA-2000) 5·負離子測試儀（ITC_201A) 6·噴搶W-71 (塗裝方式：重力式喷嘴直徑：l5mm使 用壓力：70PSI耗氣量：6 CFM霧幅寬度：17〇mm 量：4〇〇cc) J ^ 7.熱壓定型機 =下列舉數個實施例以使本發明之特徵及優點更為清 =以下之實施例並㈣來限制發明的範圍而是用來 申、：：:本發明的方法及材料，本發明的範圍應 甲叫專利範圍為準。 4心 僅使用樹脂黏著竹炭粉末於聚丙稀不織布 .U丙稀不織布剪裁成46一46咖之大小. 分鐘 3::::;:，度為¥的樹叫 。 场不織布…樹脂溶液中，浸潰時間為1〇 將聚丙稀不λ 卜猫^布置入熱壓定刑秘+ 度疋型機中，以loot的溫 8 200951269 不織布使稀釋過後之樹脂固 s周製濃度為10.0g/L之竹戾 S字型喷塗，將噴塗的量固 正面喷塗完畢，時間設定為 度及時間60秒，烘烤聚两稀 定於聚丙烯不織布上。 5.取出聚丙烯不織布後， 和純水混合液置入噴搶桶内以 定為25ml，在聚丙烯不織布的 3 0秒。 為織布後直接放置針板上，進行溫度 上置收密封;:::秒之熱塵定型處理，等待取出後，馬 7.再以2軌的竹^複卜2、3、4、5、6步驟。 ~~以PTES對竹炭粉末進行加工並進行喷塗 …，、第—圖所示，本實施例之過程如下： 下力二與水(濃度為1〇g/L)混合在溫度… __ 2Q “，^之^止加熱，加人PTES (濃度為5 過濾竹厌將其烘乾，得PTES竹炭粉末。 •將聚丙稀不織布剪裁成—χ 4 I洗後放置⑽後❹。 幻、.& 4脾牙樹知調和成濃度為20 g/L的樹脂溶液。 分鐘。、丙烯不織布次潰於樹脂溶液中，浸潰時間為1 〇 溫度以及時稀不織布置入熱壓定型機中，以1〇(^的 脂先固’烘烤聚㈣不織布使稀釋過後之樹 w1丙烯不織布上。200951269 IX. Description of the invention: [Technical field to which the invention pertains] The present invention relates to a processing method in which a polypropylene is not used to coat a bamboo charcoal powder in a polypropylene non-woven fabric, in particular, a method in which a tantalum powder is uniformly bonded to a crucible 'It can be used to make bamboo propylene non-woven. [Prior Art] Because the bamboo anaesthetic material itself has excellent electromagnetic wave, decoupling, #4, this force, humidity control, and resistance to this bamboo charcoal material are widely used in the function of the function of the function of the sun. Tusi death in this section, such as the bamboo charcoal material results in the increase in clothing and miscellaneous λ quotation refers to the functional effect of bamboo disgust, the functional of clothing. For example, the function of the bamboo outer line and the negative ion is used to achieve the functions of promoting blood circulation, heat storage and heat preservation, etc., which are contained in the bamboo charcoal life & However, when the bamboo charcoal material is to be combined with the right side of the mountain from the mountain U to the polypropylene non-woven fabric, there is a phenomenon that the bamboo dispelling material has poor dispersibility, and thus the application of the bamboo disgusting material on the polypropylene non-woven fabric. Therefore, how to uniformly bond the arm and the anaesthetic material to the t-propylene non-woven fabric has become a research topic in the industry. SUMMARY OF THE INVENTION In view of the existing method for binding bamboo charcoal material to polypropylene non-woven fabric, the bamboo charcoal is evenly distributed, and the object of the present invention is to provide a processing method for spraying bamboo two: a polypropylene non-woven fabric, which can improve bamboo charcoal. In order to achieve the above objective, the method for processing the sprayed bamboo charcoal powder of the present invention in the polypropylene non-woven fabric comprises the following steps: , 200951269 Providing - pre-treating the bamboo charcoal powder: stirring the bamboo charcoal, and then drying the bamboo charcoal powder for drying Material = coupling agent at present; 忒 pre-treated bamboo charcoal powder to provide a resin solution; impregnated a polypropylene non-woven fabric: ( 螂 螂 ( ( ( 于 于 于 该 该 该 该 该 该 该 该 : : : : : : : : : : : : : Heating the impregnated cloth to fix the resin on the polypropylene non-woven fabric. spraying the pretreated bamboo charcoal powder: mixing the pre-alcohol to form a mixed solution, and disposing the bamboo, the water, and the non-woven fabric; and The mixed solution is sprayed on the polypropylene to heat the polypropylene non-woven fabric: the sprayed non-woven fabric is subjected to a hot press setting treatment. σ/ 奋 之 聚丙烯 聚丙烯 疋 疋 e e e e e e e e e e e e e e e e e e e e e e e e e e e e e e e e e e e e e e e e e e e e e e e e Preferably, the tree is intended to be a polymethyl methacrylate resin. Preferably, the step of providing a pretreatment of the bamboo charcoal powder makes the bamboo boring The powder is mixed with water at a temperature of 85 to 9: the heating is stopped and the mixture is added to the mixture, and then the material is passed:: the final: it is dried to obtain the pretreated bamboo charcoal powder. Finally, it is preferred that the resin solution is Preferably, the spraying (4) treatment of the bamboo charcoal powder is ethanol. ^t the alcohol 6 200951269 Fortunately, the hot pressing temperature is 90~II〇t, time ^ 7 In the step of non-woven, the preferred "^ is 0~90 seconds of hot pressing and shaping treatment. The polypropylene woman is not woven into the arrangement - the step is not the A cloth, and the time is 3〇90 f '", To 疋1 machine _, to the temperature of 9 〇 ~! l 〇 ° C to ± 0 〇 ' ' to bake the polypropylene non-woven fabric. The invention comprises the following steps: 1 · The invention adopts a polypropylene-based re-use of a decane-coupled one, and an ene-non-woven fabric is first d-shelled in a resin solution, and a bamboo charcoal powder solution which is pretreated on the door of the enamel cloth is sprayed on the polypropylene cloth, and the second powder can be sprayed on the polypropylene cloth. The combination of the two kinds of non-woven propylene non-woven fabrics provides various functional effects, including the improvement of the aggregation property, etc., and is based on the second; second: ion release amount, antibacterial property and deodorizing gas property, and can be utilized. The finished product obtained by reducing the transparency of the polypropylene non-woven fabric is used as a filter material, such as a filter material for a mask, etc. The dry-processed bamboo charcoal powder used has a hydrophilic-hydrophobic group with a pre-alkane coupling agent of a decane coupling agent. The characteristics of the bamboo carbon fiber polypropylene non-woven fabrics of the 爿 八 八 516 516 516 516 516 516 516 516 516 516 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹[Embodiment] The materials and medicines used in the comparative examples and examples of the present invention are as follows: h polypropylene non-woven fabric (basis weight 30 g/m2) 2 mountain, • bamboo powder (Sjing Technology, particle size) Big : less than 80 μ m) 3·polyacrylic acid decyl acrylate resin: (Clys, AL-500BN, solid component 200951269 40%) 4 · oxalate coupling agent (3Acros 'phenyl triethoxy silane; phenyl triethoxysilane; PTES 5. Ethanol (concentration: 95%) The experimental equipment used in the comparative examples and examples of the present invention is as follows: 1) Softness tester (Inteco, 45 degree tilt) 2. Tensile strength tester (Alphaten 400) ❹ 3 Scanning Electron Microscope (SEM, JSM-6700F) 4. Electronic Balance (FA-2000) 5. Negative Ion Tester (ITC_201A) 6. Spraying W-71 (Coating Method: Gravity Nozzle Diameter: l5mm Operating Pressure: 70PSI gas consumption: 6 CFM fog width: 17〇mm Quantity: 4〇〇cc) J ^ 7. Hot press setting machine = Several examples are listed below to make the features and advantages of the present invention clearer = the following implementation The examples and (4) are intended to limit the scope of the invention and are used to claim:::: The method and material of the invention, the scope of the invention shall be determined by the scope of the patent. 4 hearts Only use resin to stick bamboo charcoal powder to polypropylene non-woven fabric. U-propylene non-woven fabric is cut into 46-46 coffee size. Minute 3::::;:, the tree of degree is called. Field non-woven fabric... In the resin solution, the impregnation time is 1〇, the polypropylene is not λ, and the cat is placed in the thermostating system + degree 疋 type machine, to the temperature of the loot 8 200951269, the fabric is solidified after the dilution. The bamboo shoot S-type spray with a concentration of 10.0g/L sprayed the front surface of the sprayed solid. The time was set to 60 seconds for the degree and time. The baking and the two were fixed on the polypropylene non-woven fabric. 5. After taking out the polypropylene non-woven fabric, mix it with pure water and put it into the spray bucket to set it to 25 ml, 30 seconds in the polypropylene non-woven fabric. After weaving, place the needle plate directly, and place the temperature on the seal; ::: seconds of hot dust setting treatment, wait for the removal, horse 7. Then take 2 tracks of bamboo ^ 2, 3, 4, 5 , 6 steps. ~~The bamboo charcoal powder is processed and sprayed by PTES..., as shown in the figure, the process of this embodiment is as follows: The lower force and the water (concentration is 1〇g/L) are mixed at the temperature... __ 2Q , ^ ^ ^ ° heating, add PTES (concentration is 5 filter bamboo boring to dry it, get PTES bamboo charcoal powder. • Cut polypropylene non-woven fabric into - χ 4 I after washing and placing (10) ❹. Magic,.& 4 The spleen tree is tuned to a resin solution with a concentration of 20 g/L. Min., propylene non-woven fabric is broken in the resin solution, the immersion time is 1 〇, and the time is thin and woven into the hot press setting machine, to 1 〇 (^'s fat first solid 'bake poly (four) non-woven fabric to make the diluted tree w1 propylene non-woven fabric.
6.取出聚兩稀不織布後，調製濃度為10.0g/L之PTES 9 200951269 二厌水洛液和濃度為術。之乙醇水溶液置人噴搶桶内以$ 字里噴塗W噴塗的量固定為25ml，在聚丙烯不織布的正 面噴塗完畢，時間設定為30秒。 7. 噴塗元後將聚丙烯不織布直接放置針板上，進行溫 度為時間為6Q秒之熱敎型處理，等待取出後， 馬上置收密封袋中待測。 6 8. 再以20g/L的PTES竹炭水溶液重複2、3、[ ❹ 7步驟。 1 較例與實施例之成品分別進行下列物性測試： 微鏡（SEM)之觀寧 好將：加工之聚丙烯不織布以及各成品以掃描式電子顯 察其表面結構。由第二圖可得知未加…丙:不 :布之表面結構，可看出其纖維的表 == ❹ 聚丙稀不織布的表面結構，由圖中可看：:〇:L加工之 脂接著在纖維表面的情炉， 厌畚末經由樹 於纖維表面，還可'“末形成分散的現象黏著 散狀結構。由第^ 與纖維間的接著部份呈現分 -机加工之聚知，，經樹脂濃度20机且竹炭濃度 經由樹塘接著在纖维表不面織^表面結構’可看出竹炭粉末 象點著於纖维表面、^⑽月形’竹炭粉末形成圏聚的現 構。 "月曰與纖维間的接著部份呈球狀結 卜第五圖為樹脂濃度2〇 ^ g/L加工處理 TES竹戾濃度10 丙席不織布的表面結構，由第六圖中可 200951269 看出竹炭粉末經由樹脂接著在蛾祕+ 考在纖維表面的情形，竹炭粉末 形成團聚的現象黏著於纖維表面， $面還可以看出樹脂與纖維 間的接著部份呈現聚集結構。筮$ m * 苒第五圖為樹脂濃度20 g/L處 理且PTES竹炭濃度20 g/L知丁南m g加工處理之聚丙烯不織布的表 面結構，由圖中可看出竹启於古e丄丄 私末經由樹脂接著在纖維表面 的情形，竹炭粉末形成小塊團聚的現象黏著於纖維表面， 還可以看㈣脂與纖維間的接著部份呈現聚集結構。 柔軟度 將未加工之聚丙烯不織布（原布）以及各成品分別依 CNS 12915 —般不織布試驗法 /人 铖忐匕19.1節剛軟度檢驗之。於 、.里向及緯向各取2cm X I5em > 1 μ 場續抽Φ古 —之试片，將試片置於平台上 緩緩推出，直至試片一端接觸 ^ ^ ^ ^ 』4：>斜面，柔軟度以試片 /月订的長度表示之，測試結果如 表一原6. After taking out the two non-woven fabrics, PTES 9 200951269 with a concentration of 10.0 g/L was prepared. The aqueous solution of ethanol was placed in a spray bucket and fixed in a volume of 25 ml by spraying W in the word. The spray was completed on the front side of the polypropylene non-woven fabric, and the time was set to 30 seconds. 7. After the spraying element, put the polypropylene non-woven fabric directly on the needle plate, and carry out the hot-type treatment with the temperature of 6Q seconds. After waiting for the removal, immediately put it in the sealed bag for testing. 6 8. Repeat steps 2, 3, and [20 steps] with 20 g/L PTES bamboo charcoal solution. 1 The following physical properties were tested in the comparative examples and the finished products of the examples: Micro-mirror (SEM) observation: The processed polypropylene non-woven fabric and each finished product were observed by scanning electrons. It can be seen from the second figure that there is no addition of ... C: No: the surface structure of the cloth, it can be seen that the surface of the fiber == 表面 The surface structure of the polypropylene non-woven fabric can be seen from the figure: 〇: L processed fat In the case of the surface of the fiber, the end of the sputum is through the tree on the surface of the fiber, and it can also form a dispersing phenomenon to adhere to the scattered structure. The sub-machine between the second and the fiber presents the sub-machine processing. After the resin concentration of 20 machines and the concentration of bamboo charcoal through the tree pond followed by the surface structure of the fiber surface, it can be seen that the bamboo charcoal powder is spotted on the surface of the fiber, and the (10) moon-shaped bamboo charcoal powder forms a polycondensation. "The subsequent part of the sputum and the fiber is spherical. The fifth picture shows the resin concentration of 2〇^ g/L. The surface structure of the TES 戾 10 10 10 10 丙 不 不 2009 2009 51 51 51 51 51 51 51 51 It can be seen that the bamboo charcoal powder adheres to the surface of the fiber through the resin and then on the surface of the fiber. The phenomenon of agglomeration of the bamboo charcoal powder adheres to the surface of the fiber, and the surface of the resin and the fiber exhibits agglomerated structure. * 苒The fifth picture shows the resin concentration of 20 g / L and PTE The surface structure of the polypropylene non-woven fabric treated with S bamboo charcoal concentration of 20 g/L Zhidingnan mg can be seen from the figure. The bamboo charcoal powder forms a small piece through the resin and then on the fiber surface. The phenomenon of agglomeration adheres to the surface of the fiber, and it can also be seen that (4) the subsequent part between the fat and the fiber exhibits an aggregate structure. The softness of the unprocessed polypropylene non-woven fabric (original fabric) and the finished products are respectively tested according to CNS 12915. People test the softness test in Section 19.1. Take 2cm X I5em > in the 1st and 1st fields, and then push the test piece on the platform. Until the end of the test piece touches ^ ^ ^ ^ 』4:> bevel, the softness is expressed by the length of the test piece/month, and the test result is as shown in Table 1.
B =竹炭，P =聚丙烯不織布，s: A =聚丙烯酸甲酯樹脂 紗院偶合劑（PTgg) W㈣織布㈣軟度與製品使用時的手感與舒適性 有1而測出之伸懸長度越大，其柔軟卢# Μ # 越好。Α去 丹系軟度就越差；反之則 的實驗結果得知，經不同竹# 過之聚丙烯兀她士朴 个竹厌叔末濃度加工B = bamboo charcoal, P = polypropylene non-woven fabric, s: A = polymethyl acrylate resin yarn yard coupling agent (PTgg) W (four) woven fabric (4) softness and feel and feel when using the product 1 and the measured suspension length The bigger it is, the softer it is ### the better. The lower the softness of the Dan system, the worse the experimental results show that the different bamboos passed through the different types of bamboo.
加工對不衅士 "仴差但有無利用PTES 、、之柔軟度並未造成太大影可推知加入不 11 200951269 同濃度之竹炭粉末後，因 面上，所以對聚丙烯不織布：;：末只是附著在纖维的表 3·抗心 帝的柔軟度影響不大。 將未加工之聚丙烯不 CNS56M不織布試驗法第4 '、布及各成品分別依 經向及緯向試片，試片長度條法"式驗之。分別切取 佶田宁、Φ哆 又 mm ’試片寬度25.4 ， 使用疋«張❹力試驗機，夾 咖， 參 mm/min，測試結果如表二所示。 mm、料度1 〇〇Processing is not gentleman's 仴 仴 但 但 但 但 PT PT PT PT PT PT PT PT PT PT PT PT PT PT PT PT PT PT PT PT PT PT PT PT PT PT PT PT PT PT PT PT PT PT PT PT PT PT PT PT PT PT PT PT PT PT PT It is only attached to the fiber of Table 3. The softness of the anti-heart is not significant. The unprocessed polypropylene is not the CNS56M non-woven test method 4', the cloth and each finished product are tested according to the warp and weft test pieces, and the length of the test piece is tested. Cut the width of the test strips of Putianning, Φ哆 and mm ′ 25.4 respectively. Use 疋«张❹力试验机, 咖咖, 参mm/min, the test results are shown in Table 2. Mm, material 1 〇〇
由表二的實驗結果得知， 比原布還要強，因谢， 強度 以強因樹月曰加強了不織布之抗拉 脂增強纖維間之互相纏妹 推知樹According to the experimental results in Table 2, it is stronger than the original cloth. Thanks to the strength, the strength is stronger because of the tree stagnation, and the non-woven fabric of the non-woven fabric is strengthened.
❿ 相遲、’°之效應有關。而竹炭濃度10 g/L 之成品相比，不織布之抗拉強度會並不會因竹炭 浪度的增加而有增加的趨勢。而有加樹脂的加工不織布盘 未加工不織布比較’可以發現到強度有明顯的影響。” 熱保溫枓淛封 " 以鹵素燈在距離試樣職m處照射原布以及各 成品’使用紅外線熱像測溫儀(Therm〇visi〇n)在距離5〇咖 得熱影像，分析試樣表面溫度，即可獲得試樣的升溫 效果，以評定遠紅外線功能，測試結果如表三所示。 12 200951269 表三原布以及成品之蓄熱保溫性測試數據 樣品種類 竹灰粉末(g/L) 特定熱源與條件下之表面溫度（） 表溫ΓΟ* 表溫rc) ** 溫度上升(°c) 原布 — 28.09 30.76 2.67 ABSP 20 26.06 35.52 9.64 ABSP 10 25.58 31.63 6.05 ABP 20 26.90 34.18 7.28 ABP 10 28.52 34.29 5.77 註：*=照射前溫度，**=照射後溫度 由表三的實驗結果得知，聚丙烯不織布經竹炭加工後 前，表面溫度之溫度上升有顯著的提高，亦即添加竹炭粉 Ο 末後，聚丙烯不織布之遠紅外線蓄熱保溫性也越佳，而利 用 PTES加工亦有助於提升聚丙烯不織布之遠紅外線蓄熱 保溫性。 5 .負離子性測試 將原布以及各成品置入測試箱（尺寸： 300mm*200mm*200mm) ，以負離子測試儀測試箱内之負 離子濃度、溫度及溼度，測試結果如表四所示。 表四原布以及成品之負離子性測試數據 樣品 種類 竹炭粉末 (g/L) Max (Ions/ml) Min (Ions /ml) Avg (Ions /ml) 溫度fc) 溼度 (RH)% 大氣壓力 (hpa) 原布 — 248 193 210 22 52 1008 ABP 10 613 512 532 22 52 1008 ABP 20 655 601 628 22 52 1008 ABSP 10 577 486 506 22 52 1008 ABSP 20 584 475 510 22 52 1008 註：Mobility: 1.3 由表四的實驗結果得知，未加工聚丙烯不織布之負離 子濃度有210 Ions /ml，此乃空氣中所釋放之負離子。而 經由不同竹炭粉末濃度10g/L及20g/L處理的加工聚丙烯 不織布，發現添加的竹炭粉末濃度越高，則釋放之負離子 13 200951269 濃度也越多，但增加的幅度不大。 6.抗菌性淛試 測試條件如下所述： 1.菌種··金黃色葡萄球菌 2·測試方法：依JIS L 1902 : 2002定量檢驗 3. Ma=未加工樣〇小時立即沖刷後菌數；Mb=未加工 樣1 8小時後菌數；Mc =加工樣！ 8小時培養後菌數。 4. 細菌成長活性值=l〇gMb-l〇gMa，細菌成長活性值 >1.5表示實驗有效。 參 5.依據曰本纖維製品新機能評價協議會（jafet)之抗 菌標準’抑菌值>2.〇表示測試樣本有抑菌效果，殺菌值〉〇 表示測試樣本有殺菌效果，測試結果如表五所述。 ；-土棉，、原布以及成品之抗菌性測試數據 檢測項目 金黃色葡萄 球菌(ATCC 6538P)❿ Relatively late, the effect of '° is related. Compared with the finished product with a bamboo charcoal concentration of 10 g/L, the tensile strength of the non-woven fabric will not increase due to the increase of the bamboo charcoal wave. The processing of non-woven fabrics with resin added to the unwoven non-woven fabrics can be found to have a significant effect on the strength. "Thermal insulation 枓浙封" is irradiated with the halogen lamp at a distance from the sample m and the finished product 'Using an infrared thermal image thermometer (Therm〇visi〇n) at a distance of 5 〇 calorie images, analysis test The surface temperature of the sample can be used to obtain the temperature rising effect of the sample to evaluate the far-infrared function. The test results are shown in Table 3. 12 200951269 Table 3 Thermal storage and thermal insulation test data of the original cloth and the finished product Sample type Bamboo ash powder (g/L) Surface temperature under specific heat sources and conditions () Table temperature ΓΟ * Table temperature rc) ** Temperature rise (°c) Original cloth — 28.09 30.76 2.67 ABSP 20 26.06 35.52 9.64 ABSP 10 25.58 31.63 6.05 ABP 20 26.90 34.18 7.28 ABP 10 28.52 34.29 5.77 Note: *=temperature before irradiation, **=temperature after irradiation is obtained from the experimental results in Table 3. Before the processing of polypropylene non-woven fabric by bamboo charcoal, the temperature rise of surface temperature is significantly improved, that is, bamboo charcoal powder is added. At the end, the far infrared ray heat storage and heat insulation of the polypropylene non-woven fabric is also better, and the use of PTES processing also contributes to the improvement of the far infrared ray heat storage and heat insulation of the polypropylene non-woven fabric. The original cloth and each finished product are placed in the test box (size: 300mm*200mm*200mm), and the negative ion concentration, temperature and humidity in the test box are tested by the negative ion tester. The test results are shown in Table 4. Table 4 Negative ions of the original cloth and the finished product Sex Test Data Sample Type Bamboo Charcoal Powder (g/L) Max (Ions/ml) Min (Ions /ml) Avg (Ions /ml) Temperature fc) Humidity (RH)% Atmospheric Pressure (hpa) Original Fabric - 248 193 210 22 52 1008 ABP 10 613 512 532 22 52 1008 ABP 20 655 601 628 22 52 1008 ABSP 10 577 486 506 22 52 1008 ABSP 20 584 475 510 22 52 1008 Note: Mobility: 1.3 From the experimental results in Table 4, unprocessed The negative ion concentration of polypropylene non-woven fabric is 210 Ions /ml, which is the negative ion released in the air. The processed polypropylene non-woven fabric treated with different bamboo charcoal powder concentrations of 10g / L and 20g / L, found that the higher the concentration of added bamboo charcoal powder, Then the negative ion released 13 200951269 The concentration is also increased, but the increase is not large. 6. The antibacterial test conditions of the test are as follows: 1. Species · Staphylococcus aureus 2 · Test method: According to JIS L 1902: 2002 quantitative test 3. Ma = number of bacteria after scouring immediately after unprocessed sample; Mb = number of bacteria after 18 hours of unprocessed sample; Mc = processed sample! The number of bacteria after 8 hours of cultivation. 4. Bacterial growth activity value = l〇gMb-l〇gMa, bacterial growth activity value > 1.5 indicates that the experiment is effective. Reference 5. According to the antibacterial standard of the new functional evaluation protocol (jafet) of the 曰 纤维 fiber product, 'bacteriostatic value> 2. 〇 indicates that the test sample has antibacterial effect, bactericidal value 〇 indicates that the test sample has bactericidal effect, the test result is as follows Table 5 is stated. ;-Anti-bacterial test data of cotton wool, original fabric and finished product Test items Staphylococcus aureus (ATCC 6538P)
MeIWf® 原布 0 8 E+5 <20MeIWf® original fabric 0 8 E+5 <20
ABSP 0.8 E+5 UW 試驗方法 JIS LI 902-2002 由 A x λα a -----L a _ 的實驗結果得知，聚丙嫌 後具有顯著的^ V丙衫織布利用竹炭加工 的抗囷和殺菌效果。 測試條件如下： 1 ·參照日太 檢知管、去，*^而之消臭性能評價試驗方法檢驗。 …將HW10cm之樣品，置入含有3L i〇〇ppm 14 200951269 初始濃度氣體之5L-Tedlar Bag中，最後再以檢知管測定 濃度降低的程度，藉以評估除臭效果。 2.消臭率（％) = (空白試樣值一試樣值）/空白試樣值X 100%。 測試結果如下表六所示。 • 表六原布以及成品之除臭性測試數據 對臭氣氨之消臭性能 樹脂 (g/L) 樣品 種類 竹灰粉末 (g/L) Ohr 24hr 對自每迪白 臭氣氨之 初始濃度(ppm) 臭氣氨之 殘留濃度(ppm) 到吳热热匕丨冃呆 率(％) — 空白 — 100 90 — — 原布 — 100 71 21 20 ABP 10 100 46 49 ABP 20 100 30 67 由表六結果得知，不同竹炭粉末濃度加工對不織布消 臭性能最佳可達消臭率67%，次則為49%。由此可知，竹 炭對於不織布的消臭性能上有很大的影響。 8. 透氣性測試 測試條件如下： # 1.參照 JIS L1096-1999 8.27.1.A 壓力差：125Pa，面積 3 8cm2去做測試。 2.檢驗結果單位為（c.c/cm2/sec) 表七原布以及成品之透氣性測試數據 樹脂 (g/L) 樣品種類 竹炭粉末 (g/L) 透氣性(c.c/cm2/sec) — 原布 — 258.8 ABSP 10 247.1 20 ABSP 20 240.9 ABP 10 248.6 ABP 20 244.0 由表七結果得知，不同的竹炭粉末濃度加工，對於聚 15 200951269 丙烯不織布的透氣性來說影響不大， 例之成品可應用#為濾；1；才。 & I發明較佳實施 ^應用本發明之較佳實施 不織布上時，竹炭材料於 ，且聚丙烯不織布的機能 由上述測試結果可以得知， 例的方法喷塗竹炭材料於聚丙歸 聚丙烯不織布上有較佳的分散性 性亦得到明顯提昇。 【圖式簡單說明】 第一圖係為本發明實施例之流程圖。 第二圖係為未加工聚丙烯不織布之SEM ffi)(x600)。 第三圖係為經竹炭（濃度1〇g/L)噴塗聚丙烯不織布之 SEM 圖（χ6〇〇) 〇 第四圖係為經竹炭（濃度20 g/L)喷塗聚丙烯不織布之 SEM 圖（χ6〇〇)。 第五圖係為經利用PTES加工後的竹炭（濃度1〇g/L)喷 塗聚丙烯不織布之SEM圖（x600)。 第六圖係為經利用PTES加工後的竹炭（濃度20 g/L)喷 塗聚丙烯不織布之SEM圖（x600)。 【主要元件符號說明】 無 16ABSP 0.8 E+5 UW Test Method JIS LI 902-2002 It is known from the experimental results of A x λα a -----L a _ that there is a significant anti-cracking effect of bamboo charcoal processing after the polypropylene is suspected. And bactericidal effect. The test conditions are as follows: 1 · Refer to the day too to detect the tube, go, *^ and deodorant performance evaluation test method test. ... A sample of HW 10 cm was placed in a 5L-Tedlar Bag containing 3 L i 〇〇 ppm 14 200951269 initial concentration gas, and finally the extent of the concentration reduction was measured by the inspection tube to evaluate the deodorizing effect. 2. Deodorization rate (%) = (blank sample value - sample value) / blank sample value X 100%. The test results are shown in Table 6 below. • Table 6 Raw cloth and finished product deodorization test data for odor ammonia deodorizing performance resin (g/L) Sample type bamboo ash powder (g/L) Ohr 24hr Initial concentration of ammonia from each white odor (ppm) Residual concentration of odor ammonia (ppm) to Wu hot stagnation rate (%) — blank — 100 90 — — original fabric — 100 71 21 20 ABP 10 100 46 49 ABP 20 100 30 67 Six results show that the different deodorization performance of non-woven fabrics with different bamboo charcoal powder concentration can reach the deodorization rate of 67%, followed by 49%. It can be seen that bamboo charcoal has a great influence on the deodorizing performance of the non-woven fabric. 8. Gas permeability test The test conditions are as follows: # 1. Refer to JIS L1096-1999 8.27.1.A Pressure difference: 125Pa, area 3 8cm2 for testing. 2. The test result unit is (cc/cm2/sec). Table 7 Raw cloth and finished product permeability test data resin (g/L) Sample type Bamboo charcoal powder (g/L) Gas permeability (cc/cm2/sec) - original Cloth—258.8 ABSP 10 247.1 20 ABSP 20 240.9 ABP 10 248.6 ABP 20 244.0 It is known from Table 7 that different bamboo charcoal powder concentration processing has little effect on the permeability of poly 15 200951269 propylene non-woven fabric, and the finished product can be applied. #为滤;1;才. Preferred Embodiments of the Invention When applying the preferred embodiment of the present invention to a non-woven fabric, the function of the bamboo charcoal material and the polypropylene non-woven fabric can be known from the above test results, and the method of spraying the bamboo charcoal material on the polypropylene-based polypropylene non-woven fabric The better dispersibility is also improved. BRIEF DESCRIPTION OF THE DRAWINGS The first figure is a flow chart of an embodiment of the present invention. The second figure is the SEM ffi) (x600) of the unprocessed polypropylene nonwoven fabric. The third picture is the SEM image of the polypropylene non-woven fabric sprayed with bamboo charcoal (concentration 1〇g/L) (χ6〇〇). The fourth picture is the SEM image of the sprayed polypropylene non-woven fabric with bamboo charcoal (concentration 20 g/L). (χ6〇〇). The fifth figure is an SEM image (x600) of a polypropylene nonwoven fabric sprayed with bamboo charcoal (concentration: 1 〇g/L) processed by PTES. The sixth figure is an SEM image (x600) of a sprayed polypropylene non-woven fabric of bamboo charcoal (concentration: 20 g/L) processed by PTES. [Main component symbol description] None 16