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TW200932920A - Titanium aluminum alloy applied in golf club head - Google Patents

Titanium aluminum alloy applied in golf club head Download PDF

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Publication number
TW200932920A
TW200932920A TW097101708A TW97101708A TW200932920A TW 200932920 A TW200932920 A TW 200932920A TW 097101708 A TW097101708 A TW 097101708A TW 97101708 A TW97101708 A TW 97101708A TW 200932920 A TW200932920 A TW 200932920A
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TW
Taiwan
Prior art keywords
titanium
golf club
club head
alloy
aluminum alloy
Prior art date
Application number
TW097101708A
Other languages
Chinese (zh)
Inventor
Liang-Ho Tsai
Cheng-Tao Lee
Original Assignee
Advanced Int Multitech Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Advanced Int Multitech Co Ltd filed Critical Advanced Int Multitech Co Ltd
Priority to TW097101708A priority Critical patent/TW200932920A/en
Priority to US12/046,936 priority patent/US20090181794A1/en
Priority to JP2008080195A priority patent/JP2009167518A/en
Publication of TW200932920A publication Critical patent/TW200932920A/en

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    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63BAPPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B53/00Golf clubs
    • A63B53/04Heads
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C14/00Alloys based on titanium
    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63BAPPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B2209/00Characteristics of used materials
    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63BAPPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B60/00Details or accessories of golf clubs, bats, rackets or the like
    • A63B60/54Details or accessories of golf clubs, bats, rackets or the like with means for damping vibrations

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Physical Education & Sports Medicine (AREA)
  • Golf Clubs (AREA)

Abstract

The present invention discloses a titanium aluminum alloy applied in a golf club head, including 88 to 92 percent by weight of titanium and 7.5 to 10 percent by weight of aluminum. The titanium aluminum alloy can be selectively added with trace elements such as niobium, vanadium, molybdenum, chromium, iron, silicon, oxygen, nitrogen to compose a material with a high extensibility in which the extensibility is between 11 percent and 18 percent and the tensile strength is between 650 and 950 Mpa. By applying the material with the high extensibility to the main body of the golf club head and combining with the striking panel of 6AI-4V-Ti alloy or β alloy with better rigidity, the golf club head thus formed may accomplish a golf club head product having the advantages of good striking feeling, good damping and performance control, and the angle of the club portion is adjustable so as to be customized.

Description

200932920 九、發明說明: 【發明所屬之技術領域】 本發明係有關一種應用於高爾夫球桿頭之高延伸材 料,特別係有關一種調配鈦、銘重量百分比之比例,並藉 由添加銳、飢、鉬、鉻、鐵、石夕、氧及/或氮等微量元 素,以具有高延伸性之高爾夫球桿頭合金材料。 【先前技術】 目前所開發應用於高爾夫球桿頭之合金技術主要為鈦 合金材料,如美國專利US 2006/0045789中揭示習知 6A卜4V -Ti鈦合金(即重量百分比為鋁及釩,其餘為鈦金 屬),其成分包含5.5〜6.75重量百分比之人1、3.5~4.5重 量百分比之叙、最大值為0.3重量百分比之鐵,以及最大 值為0.2重量百分比之氧。以6A1-4V-Ti鈦合金製造之高 爾夫球桿頭,雖具有相對高於早期以不銹鋼材料製成的球 桿頭之彈性變形力、相同的強度及更低的密度等特性,因 此可在不增加高爾夫球桿頭重量的前提下來增加高爾夫球 桿頭的體積,以使其較佳擊球點的面積相對增加,以是高 擊球成功率。另外,該高於不鏽鋼的彈性變形力,可在擊 球時提供較大的彈性變形能力,亦能產生較大的彈性變形 程度-伸長率,並可相對地減少高爾夫球在碰撞打擊面板 時所造成的球體壓縮變形,以降低擊球應力被阻尼吸收的 程度,避免擊球應力的能量損失,並得以進一步提昇擊球 距離。 5 200932920 • 然而,至目前為止,在高爾夫球桿頭體積大型化及多 樣化的客製需求下,便有需要開發低密度、高延展性,但 仍保持原有機械強度,以提高設計裕度。 .▼ 【發明内容】 ' 有鑑於上述需求,本發明所欲解決的問題係在於提供 一種高塑性、高延展率鈦鋁合金,以供調整高爾夫球桿頭 之彈性變形能力。本發明另一所欲解決的問題係在於提供 一種高延展率之鈦銘合金,並可利用微量的改質元性,對 鈦鋁合金進行改質微調。 為解決上述問題,本發明所提出之技術手段為提供一 種鈦鋁合金,其重量百分比包含:鈦88至92%,鋁7. 5 至10%,密度範圍為4.25至4. 45g/cm3。 上述之鈦鋁合金係以延伸率在8%〜18%、抗拉強度在 680〜950Mpa的鈦合金,應用鑄造、锻造或機械加工成 型。 © 本發明所提出之另一技術手段係提供一種欽紹合金, 其重量百分比包含:鈦88%至92%、鋁7. 5%至10%、鈮 S 2%、釩 S 2%、鉬 S 2%、鉻 S 2%、鐵 S 1%、矽 S 1%、氧 S 0. 3%及氮S 0. 05%,其組成之密度範圍為4. 25至 4. 45g/cm3。 本發明之鈦鋁合金中之鈦及鋁的含量較習用6A1-4V-Ti高,鋁含量的提高對於提高合金的常溫和高溫強度、 降低比重、增加彈性模量有明顯效果;鈮、釩、鉬、鉻、 6 200932920 鐵為/5穩定元素,與6A1_4V-Ti相比,鈒的添加量大為 減少,從而降低了鈦鋁合金的製造成本。又本發明具有良 好的熱加工成型性,易於工廠量產,且其密度也低於同類 、 合金,有利於高爾夫球桿頭之大型化,並而提高其設計裕 * 度。 【實施方式】 茲配合圖表將本發明較佳實施例說明如下。 請參照圖1、圖2及圖3所示,本發明第一實施例之 鈦鋁合金,其合金元素之重量百分比包含:鈦88%至92% 以及鋁7. 5%至10%,其組成之密度範圍為4. 25至 4. 45g/cm3。 本發明另可藉由添加微量的改質元素,如由鈮、釩、 鉬、鉻、鐵、矽、氧及氮等元素組成的群組中選擇,來調 整其特性,例如,可藉由添加微量的銳,來提升合金之強 度,但不致減低其延伸特性;可藉由相對地降低釩的添加 ❿ 量,來提高鑄造時之流動性及輔助除氣效果,但仍不致影 響原合金之機械性質;可藉由添加微量的鉬,使合金析出 均勻分布之碳化物,並提高耐熱性,以減少合金之焊接熱 裂現象,亦可增加合金硬化能力及高溫強度;可藉由添加 適量之鉻,來提昇合金之防鏽耐蝕性,增加高爾夫球桿頭 之使用壽命;可藉由添加微量的鐵,以具有良好的塑性, 便於加工處理之施行;藉由添加微量之矽,以改善熔融金 屬之流動性。本發明中所選擇添加之改質元素中,其含量 7 200932920 百分比為鈮S 2%、釩S 2%、鉬S 2%、鉻S 2%、鐵S 1 %、矽 S 1%、氧SO. 3%及氮 SO. 05%。 以下將本發明之較佳之第一實施例至第四實施例與習 用6A1-4V-Ti鈦合金之特性比較如下列表1所示: 表1 材質 抗拉強度 (Mpa) 0.2%降伏強度(MPa) 伸長率 (°/〇) 硬度 (HRC) 習用之6A卜4V-Ti 830-900 760-830 3~5 30-35 本發明第一實施例 8Α1-ΤΪ 685-705 640-660 15-16 25-28 本發明第二實施例 8A1-2V-Ti 818-827 775-780 11-6 26-29 本發明第三實施例 7.5A1-2V-Ti 816-825 766-770 10.2 27-29 本發明第四實施例 7A1-2V-Ti 815-822 750-760 8.5 28-30 相較於習用之6A1 —4V-Ti合金,本發明藉由提高之 相對的鋁元素的含量、並降低釩的元素含量,可降低合金 密度並增加其韌性,而獲得優異的延展塑性,又能保持低 密度之特性。 〇 本發明之實施例與習用的鈦合金之元素組成比較表如 下列表2所示:200932920 IX. INSTRUCTIONS: [Technical Field] The present invention relates to a high-stretch material applied to a golf club head, in particular to a proportion of titanium, the weight percentage, and by adding sharpness, hunger, A trace element such as molybdenum, chromium, iron, stellite, oxygen, and/or nitrogen, which is a golf club head alloy material having high elongation. [Prior Art] The alloy technology currently developed for use in golf club heads is mainly titanium alloy materials, as disclosed in US Patent No. 2006/0045789, which is known as 6A Bu 4V-Ti titanium alloy (ie, weight percent aluminum and vanadium, and the rest) It is a titanium metal), and its composition contains 5.5 to 6.75 weight percent of a person, 3.5 to 4.5 weight percent of iron, a maximum of 0.3 weight percent of iron, and a maximum of 0.2 weight percent of oxygen. The golf club head made of 6A1-4V-Ti titanium alloy has relatively high elastic deformation force, the same strength and lower density than the early club head made of stainless steel, so it can be Increasing the weight of the golf club head increases the volume of the golf club head so that the area of the preferred hitting point is relatively increased, so as to have a high hitting success rate. In addition, the elastic deformation force higher than that of the stainless steel can provide a large elastic deformation ability when hitting the ball, and can also generate a large degree of elastic deformation-elongation, and can relatively reduce the golf ball when hitting the impact panel. The resulting ball is compressed and deformed to reduce the degree of damping of the ball striking stress, avoid the energy loss of the ball striking stress, and further increase the hitting distance. 5 200932920 • However, until now, with the large-scale and diversified customer demand for golf club heads, there is a need to develop low-density, high-ductility, but still maintain the original mechanical strength to improve design margin. . . [Explanation] In view of the above needs, the problem to be solved by the present invention is to provide a high-plasticity, high-expansion titanium-aluminum alloy for adjusting the elastic deformation ability of a golf club head. Another problem to be solved by the present invention is to provide a titanium alloy having a high elongation and to fine-tune the titanium-aluminum alloy by using a small amount of modified element. In order to solve the above problems, the technical means provided by the present invention is to provide a titanium-aluminum alloy, the weight percentage thereof comprising: 88 to 92% of titanium, 7.5 to 10% of aluminum, and a density ranging from 4.25 to 4.45 g/cm3. The titanium aluminum alloy described above is cast, forged or machined by a titanium alloy having an elongation of 8% to 18% and a tensile strength of 680 to 950 MPa. Another technical means proposed by the present invention is to provide a Chinso alloy, the weight percentage thereof comprising: titanium 88% to 92%, aluminum 7.5% to 10%, bismuth S 2%, vanadium S 2%, molybdenum S 2 至4. 45克/厘米。 The density of the composition of the range of 4. 25 to 4. 45g / cm3. The content of titanium and aluminum in the titanium-aluminum alloy of the invention is higher than that of the conventional 6A1-4V-Ti, and the improvement of the aluminum content has obvious effects on increasing the normal temperature and high temperature strength of the alloy, lowering the specific gravity, and increasing the elastic modulus; bismuth, vanadium, Molybdenum, Chromium, 6 200932920 Iron is a /5 stabilizing element. Compared with 6A1_4V-Ti, the amount of niobium added is greatly reduced, thereby reducing the manufacturing cost of titanium aluminum alloy. Further, the present invention has good hot formability, is easy to mass-produce in a factory, and has a lower density than that of the same type and alloy, which is advantageous for the enlargement of the golf club head and improves the design margin. [Embodiment] A preferred embodiment of the present invention will be described below in conjunction with the drawings. Referring to FIG. 1 , FIG. 2 and FIG. 3 , the titanium alloy according to the first embodiment of the present invention has a weight percentage of alloying elements including: 88% to 92% of titanium and 7.5% to 10% of aluminum. The density ranges from 0.25 to 4.45 g/cm3. The invention can also adjust its characteristics by adding a trace amount of a modified element, such as a group consisting of elements such as lanthanum, vanadium, molybdenum, chromium, iron, lanthanum, oxygen and nitrogen, for example, by adding A slight amount of sharpness to enhance the strength of the alloy, but not to reduce its elongation characteristics; it can improve the fluidity during casting and assist the degassing effect by relatively reducing the amount of vanadium added, but still does not affect the machinery of the original alloy. Properties; by adding a small amount of molybdenum, the alloy can precipitate a uniformly distributed carbide and improve the heat resistance, thereby reducing the welding hot cracking phenomenon of the alloy, and also increasing the hardening ability and high temperature strength of the alloy; by adding an appropriate amount of chromium To improve the rust and corrosion resistance of the alloy and increase the service life of the golf club head; it can be processed by adding a small amount of iron to have good plasticity; and to improve the molten metal by adding a trace amount of bismuth Liquidity. Among the modified elements selected for addition in the present invention, the content of 7 200932920 is 铌S 2%, vanadium S 2%, molybdenum S 2%, chromium S 2%, iron S 1 %, 矽S 1%, oxygen SO 3% and nitrogen SO. 05%. The following compares the characteristics of the preferred first to fourth embodiments of the present invention with the conventional 6A1-4V-Ti titanium alloy as shown in the following Table 1: Table 1 Material tensile strength (Mpa) 0.2% relief strength (MPa) Elongation (°/〇) Hardness (HRC) Conventional 6A Bu 4V-Ti 830-900 760-830 3~5 30-35 First Embodiment of the Invention 8Α1-ΤΪ 685-705 640-660 15-16 25- 28 Second Embodiment of the Invention 8A1-2V-Ti 818-827 775-780 11-6 26-29 Third Embodiment of the Invention 7.5A1-2V-Ti 816-825 766-770 10.2 27-29 The fourth aspect of the present invention Example 7A1-2V-Ti 815-822 750-760 8.5 28-30 Compared with the conventional 6A1 - 4V-Ti alloy, the present invention can increase the relative aluminum content and reduce the elemental content of vanadium. Reduces the density of the alloy and increases its toughness, while achieving excellent ductility and maintaining low density.比较 A comparison of the elemental compositions of the embodiments of the present invention with conventional titanium alloys is shown in Table 2 below:

成分 (wt%) 習用之 6A1-4V-Ti重量百分比 本發明實施例之一 8A1-Ti重量百分比 鋁(A1) 5. 5-6. 75 7. 9-8.3 釩⑺ 3. 5-4.5 0.001 碳(C) 0.1 I 0.010-0.012 氮(N) 0.05 I 0. 005-0.01 氧(〇) 0.2 1 0. 09-0.11 鐵(Fe) 0. 3 I 0. 06-0. 007 矽(Si) 0.1 I 0.01-0.03 200932920 上述實施例之合金材料係以鈦鋁合金為主要合金,其 係以延伸率在8〜18%(8%以上)’抗拉強度在 680〜950(680Mpa以上)的鈦合金,以鑄造、鍛造、機械加 工而成型。Ingredient (wt%) Conventional 6A1-4V-Ti Weight Percentage One of the Examples of the Invention 8A1-Ti Weight Percent Aluminum (A1) 5. 5-6. 75 7. 9-8.3 Vanadium (7) 3. 5-4.5 0.001 Carbon (C) 0.1 I 0.010-0.012 Nitrogen (N) 0.05 I 0. 005-0.01 Oxygen (〇) 0.2 1 0. 09-0.11 Iron (Fe) 0. 3 I 0. 06-0. 007 矽(Si) 0.1 I 0.01-0.03 200932920 The alloy material of the above embodiment is a titanium alloy as the main alloy, which is a titanium alloy having an elongation of 8 to 18% (8% or more) and a tensile strength of 680 to 950 (680 MPa or more). It is formed by casting, forging and machining.

本發明之延展性較高,適合作為高爾夫球桿頭之本 體,另以剛性較佳的之材料成為打擊面:其材料組成可為 6A卜4V-Ti鈦合金、石鈦合金等,以鑄造、鍛造、機械加 工而成型。本發明之高延展性本體加上高強度打擊面板之 材料組合,於本體内部結構設計再輔以配重結構與肋片嘹 計,即可達職打齡(制震性佳)及控球性佳且桿部可鳴 角予以客制化之高爾夫球頭產品,其本發明8M_Ti 用6A1-4V-Ti之加工性能比較列表如表3所示。 表3 加工性能 習用之 6A1-4V-Ti Ο 冷調角 —平均 工量 — ""平均每顆 磨量 材料性質相較為脆,調角至1 g 度球頭桿部會發生裂痕 ’ 本發明實施例之-8Α1-ΤΪ 至 1. 5g 3. 5度球頭桿部無發生任何 0. 9g 12gThe invention has high ductility and is suitable as the body of the golf club head, and the material with better rigidity becomes the striking surface: the material composition thereof can be 6A, 4V-Ti titanium alloy, stone titanium alloy, etc., for casting, Forging, machining and molding. The high-ductility body of the invention is combined with the material combination of the high-strength striking panel, and the internal structural design of the body is supplemented by the weight structure and the rib piece ,, so that the age of the job (good shock resistance) and the ball control property can be achieved. The golf head product which can be customized by the horn can be customized. The comparison of the processing performance of the 8M_Ti 6A1-4V-Ti of the present invention is shown in Table 3. Table 3 6A1-4V-Ti 加工 cold processing angle - average amount of work - "" average material per brittle material is relatively brittle, the angle will be 1 g degrees, the ball head will crack. 9g 12g。 The -8Α1-ΤΪ to 1. 5g 3. 5 degrees of the club head without any occurrence of 0. 9g 12g

另外’本發明以8A1-Ti材斜盔者^ ^ 科為只施例製成高爾夫球 頭本體再心SP7(H)高強度鈦合麵打擊面, 二 高爾夫球(球規格為9G) 55·8 ro/ 、、,工轉專用 下砲墼、、PiU , 已孑速度,通過3000 包辜測式,打擊面板與球頭本體 破裂及裂痕。 曰視舁探知測式均無 9 200932920 綜上所述,本案所發明之鈦鋁合金已具有產業利用 性、新穎性與進步性,符合發明專利要件。惟以上所述 者,僅為本發明之較佳實施例,並非用以限定本發明實施 之範圍。即凡依本發明申請專利範圍所做的均等變化與修 飾,皆為本發明專利範圍所涵蓋。 【圖式簡單說明】 第1圖繪示本發明應用於高爾夫桿頭之鈦鋁合金實施例之 放大50倍金相圖; 第2圖繪示本發明應用於高爾夫桿頭之鈦鋁合金實施例之 放大100倍金相圖;以及 第3圖繪示本發明應用於高爾夫桿頭之鈦鋁合金實施例之 放大200倍金相圖。 【主要元件符號說明】In addition, the present invention uses the 8A1-Ti material Helmet Helmets as the only example to make the golf head body re-centering SP7 (H) high-strength titanium joint face, two golf balls (ball size is 9G) 55· 8 ro / , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , In view of the above, the titanium-aluminum alloy invented in this case has industrial utilization, novelty and progress, and meets the requirements of invention patents. The above is only the preferred embodiment of the invention, and is not intended to limit the scope of the invention. That is, the equivalent changes and modifications made by the scope of the patent application of the present invention are covered by the scope of the invention. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a magnified 50-fold metallographic diagram of a titanium-aluminum alloy embodiment of the present invention applied to a golf club head; FIG. 2 is a view showing an embodiment of a titanium-aluminum alloy applied to a golf club head according to the present invention. The magnification is 100 times the metallographic map; and the third figure shows the magnified 200 times metallographic diagram of the titanium-aluminum alloy embodiment of the present invention applied to the golf club head. [Main component symbol description]

Claims (1)

200932920 十、申請專利範圍: 1. 一種應用於高爾夫球桿頭之鈦鋁合金,其重量百分比包 含:鈦88%至92%以及鋁7. 5%至10%。 2. 如申請專利範圍第1項所述之應用於高爾夫球桿頭之鈦 銘合金,其中該鈦铭合金組成之密度範圍為4. 2 5至 4. 45g/cm3。 3. 如申請專利範圍第1項所述之應用於高爾夫球桿頭之欽 鋁合金,其中該鈦鋁合金係以延伸率在8%〜18%、抗拉強 度在680〜95 OMpa的鈦合金,應用鑄造、锻造或機械加 工成型。 4. 如申請專利範圍第1項所述之應用於高爾夫球桿頭之鈦 鋁合金,其中該鈦鋁合金更包含一改質元素,該改質元 素係選自銳、飢、I目、鉻、鐵、破、氧及氮所組成之群 組。 5. 如申請專利範圍第4項所述之應用於高爾夫球桿頭之鈦 鋁合金,其中該改質元素包含鈮2%以下。 6. 如申請專利範圍第4項所述之應用於高爾夫球桿頭之鈦 鋁合金,其中該改質元素包含釩2%以下。 7. 如申請專利範圍第4項所述之應用於高爾夫球桿頭之鈦 鋁合金,其中該改質元素包含鉬2%以下。 8. 如申請專利範圍第4項所述之應用於高爾夫球桿頭之鈦 鋁合金,其中該改質元素包含鐵1%以下。 9. 如申請專利範圍第4項所述之應用於高爾夫球桿頭之鈦 鋁合金,其中該改質元素包含矽1%以下。 11 200932920 10. 如申請專利範圍第4項所述之應用於高爾夫球桿頭之鈦 鋁合金,其中該改質元素包含氧〇 3%以下。 11. 如申請專利範圍第4項所述之應用於高爾夫球桿頭之鈦 鋁合金,其中該改質元素包含氮〇.〇5%以下。 12. —種應用於高爾夫球桿頭之鈦鋁合金,其重量百分比 包含:鈦88%至92%、鋁7. 5%至10%、鈮$2%、釩芸2%、 鉬S 2%、鉻$ 2%、鐵g 1%、矽$丨%、氧^ 〇. 及氮 S 0· 05% ’其組成之密度範圍為4. 25至4. 45g/cm3。200932920 X. Patent application scope: 1. A titanium-aluminum alloy applied to a golf club head, the weight percentage thereof including: 88% to 92% of titanium and 7.5% to 10% of aluminum. 2. The titanium alloy of the golf club head according to claim 1, wherein the titanium alloy composition has a density in the range of 4.25 to 4.45 g/cm3. 3. The austenitic aluminum alloy applied to a golf club head according to claim 1, wherein the titanium alloy is a titanium alloy having an elongation of 8% to 18% and a tensile strength of 680 to 95 OMpa. Apply casting, forging or machining. 4. The titanium-aluminum alloy applied to a golf club head according to claim 1, wherein the titanium alloy further comprises a modified element selected from the group consisting of sharp, hungry, I mesh, and chromium. a group of iron, broken, oxygen and nitrogen. 5. The titanium aluminum alloy applied to a golf club head according to claim 4, wherein the modified element comprises 铌2% or less. 6. The titanium aluminum alloy applied to a golf club head according to claim 4, wherein the modified element contains vanadium of 2% or less. 7. The titanium aluminum alloy applied to a golf club head according to claim 4, wherein the modified element comprises molybdenum of 2% or less. 8. The titanium aluminum alloy applied to a golf club head according to claim 4, wherein the modified element contains iron less than 1%. 9. The titanium aluminum alloy applied to a golf club head according to claim 4, wherein the modified element comprises 矽1% or less. The invention relates to a titanium aluminum alloy applied to a golf club head according to the fourth aspect of the invention, wherein the modified element comprises oxyhydroxide 3% or less. 11. The titanium aluminum alloy applied to a golf club head according to claim 4, wherein the modified element comprises nitrogen 〇. 5% or less. 12. A titanium-aluminum alloy applied to a golf club head, the weight percentage thereof comprising: titanium 88% to 92%, aluminum 7.5% to 10%, 铌$2%, vanadium bismuth 2%, molybdenum S 2%,至约。 45. The thickness of the composition is 0.25 to 4. 45g / cm3. 12 200932920 七、指定代表圖: (一) 本案指定代表圖為:圖(1)。 (二) 本代表圖之元件符號簡單說明: 益 八、本案若有化學式時,請揭示最能顯示發明特徵的化學 式: 無 20093292012 200932920 VII. Designated representative map: (1) The representative representative of the case is: Figure (1). (2) A brief description of the symbol of the representative figure: Benefits 8. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: None 200932920 發明專利說明書 (本說明書格式、順序及粗體字,請勿任意更動,※記號部分請勿填寫) ※…分類雜:=) ※申請案號: ※申請日期:π」. 、發明名稱:(中文/英文) 應用於高爾夫球桿頭之鈦鋁合金 、申請人:(共1人) 姓名或名稱:(中文/英文) ❹ 明安國際企業股有限公司 ADVANCED INTERNATIONAL MUmTECH CO.,LTD. 代表人:(中文/英文)鄭錫坤/CHENQ HSI KUN 住居所或營業所地址:(中文/英文) 南雄市小港區中林路26號 NO.26, JHONGLIN RD., SIAOGANG DISTRICT, KAOHSIUNG CITY, TAIWAN R.O.C. 國籍:(中文/英文)中華民國/ TAIWAN, R.O.C. 三、發明人:(共2人) 〇 姓名:(中文/英文) 1. 蔡良和/TSAI, LIANG HO 2. 李政道 / LEE,CHENG TAO 國籍:(中文/英文) 1.-2.中華民國/了人11他,1?.0.(:. 1 200932920 四、聲明事項: ]主張專利法第二十二條第二項□第一款或□第二款規定之事實,其 事實發生曰期為:年月曰。 ]申請前已向下列國家(地區)申請專利: 【格式請依:受理國家(地區)、申請日、申請案號順序註記】 □有主張專利法第二十七條第一項國際優先權: □無主張專利法第二十七條第一項國際優先權: □主張專利法第二十九條第一項國内優先權: 【格式請依:申請日、申請案號順序註記】 □主張專利法第三十條生物材料: □須寄存生物材料者: 國内生物材料【格式請依:寄存機構、曰期、號碼順序註記】 國外生物材料【格式請依:寄存國家、機構、日期、號碼順序註記】 □不須寄存生物材料者: 所屬技術領域中具有通常知識者易於獲得時,不須寄存。 200932920 九、發明說明: 【發明所屬之技術領域】 本發明係有關一種應用於高爾夫球桿頭之高延伸材 料,特別係有關一種調配鈦、鋁重量百分比之比例,並藉 由添加銳、鈒、鉬、鉻、鐵、石夕、氧及/或氮等微量元 素,以具有高延伸性之高爾夫球桿頭合金材料。 【先前技術】 目前所開發應用於高爾夫球桿頭之合金技術主要為鈦 ® 合金材料,如美國專利US 2006/0045789中揭示習知 6A1-4V -Ti鈦合金(即重量百分比為銘及飢,其餘為鈦金 屬),其成分包含5. 5〜6. 75重量百分比之銘、3. 5〜4. 5重 量百分比之叙、最大值為0.3重量百分比之鐵,以及最大 值為0. 2重量百分比之氧,其密度約為4. 43 土 0. 3 g/cm3。以6A1-4V-Ti鈦合金製造之高爾夫球桿頭,雖具 有相對高於早期以不銹鋼材料製成的球桿頭之彈性變形 0 力、相同的強度及更低的密度等特性,因此可在不增加高 爾夫球桿頭重量的前提下來增加高爾夫球桿頭的體積,以 使其較佳擊球點的面積相對增加,以是高擊球成功率。另 外,該高於不鏽鋼的彈性變形力,可在擊球時提供較大的 彈性變形能力,亦能產生較大的彈性變形程度-伸長率, 並可相對地減少高爾夫球在碰撞打擊面板時所造成的球體 壓縮變形,以降低擊球應力被阻尼吸收的程度,避免擊球 應力的能量損失,並得以進一步提昇擊球距離。 5 200932920 而,罕-Q 一、 則為止,在高爾夫球桿頭體積大型化及多 樣化的客製需求下,便有需要開發低 仍保持原有機械強度,以提高設計裕度。 仁 【發明内容】 f鑑於上述需求’本發明所欲解決的問題係在於提供 種回塑It㈤延展率鈦|3合金,以供調整高爾夫球桿頭 之彈I·生k形I力。本發明另—所欲解決的問題係在於提供 ❹Invention patent specification (Do not change the format, order, and bold text of this manual, please do not fill in the ※ part) ※...Classification:=) ※Application number: ※Application date: π"., invention name: ( Chinese/English) Titanium-aluminum alloy applied to golf club heads, Applicant: (1 in total) Name: (Chinese/English) AD ADVANCED INTERNATIONAL MUmTECH CO.,LTD. :(中文/英文)郑锡坤/CHENQ HSI KUN Residence or Business Office Address: (Chinese/English) No.26, Zhonglin Road, Xiaogang District, Nanxiong City NO.26, JHONGLIN RD., SIAOGANG DISTRICT, KAOHSIUNG CITY, TAIWAN ROC Nationality :(Chinese / English) Republic of China / TAIWAN, ROC III. Inventor: (Total 2 persons) 〇 Name: (Chinese / English) 1. Cai Lianghe / TSAI, LIANG HO 2. Li Zhengdao / LEE, CHENG TAO Nationality: (Chinese/English) 1.-2. Republic of China/People 11 He, 1?.0. (:. 1 200932920 IV. Declarative matters:] Propose the second paragraph of Article 22 of the Patent Law □ The second paragraph Facts, the facts occur in the following periods: Years and Months.] Before applying, you have applied for patents from the following countries (regions): [Format please: Accept the country (region), application date, application case number note] □ Have patents Article 27: The first international priority: □ No claim for patent law Article 27, first international priority: □ Claim Patent Law Article 29, first domestic priority: [format please According to: application date, application case number note] □ claim patent law Article 30 Biological materials: □ Those who need to deposit biological materials: Domestic biological materials [format: please note: registration agency, period, number order note] Foreign Biomaterials [format: please note: country, organization, date, number order] □ Those who do not need to deposit biomaterials: When there is general knowledge in the technical field, they are not required to be registered. 200932920 IX. Invention: [Invention TECHNICAL FIELD The present invention relates to a high-stretch material applied to a golf club head, and more particularly to a weight ratio of titanium and aluminum. The proportion of the golf club head alloy material with high extensibility by adding trace elements such as sharp, bismuth, molybdenum, chromium, iron, ashes, oxygen and/or nitrogen. [Prior Art] Currently developed applications The alloy technology for golf club heads is mainly Titanium® alloy materials, as disclosed in US Patent No. 2006/0045789, the conventional 6A1-4V-Ti titanium alloy (ie, the weight percentage is Ming and hunger, the rest is titanium metal), its composition 5重量百分比的氧的密度约约约。 5. 5〜6. 75重量百分比的第一,3. 5~4. 5重量百分比的的, The maximum is 0.3% by weight of iron, and the maximum is 0.2% by weight of oxygen, the density is about 4. 43 0. 3 g/cm3. The golf club head made of 6A1-4V-Ti titanium alloy has relatively high elasticity, zero strength, the same strength and lower density than the earlier club head made of stainless steel. The volume of the golf club head is increased without increasing the weight of the golf club head so that the area of the preferred hitting point is relatively increased, so as to have a high hitting success rate. In addition, the elastic deformation force higher than that of stainless steel can provide a large elastic deformation ability when hitting the ball, and can also generate a large degree of elastic deformation-elongation, and can relatively reduce the golf ball when hitting the impact panel. The resulting ball is compressed and deformed to reduce the degree of damping of the ball striking stress, avoid the energy loss of the ball striking stress, and further increase the hitting distance. 5 200932920 However, under the customary requirements of large and diversified golf club heads, there is a need to develop low mechanical strength to improve design margin. [Invention] In view of the above needs, the problem to be solved by the present invention is to provide a reworked It (five) ductility titanium|3 alloy for adjusting the elastic I of the golf club head. Another problem to be solved by the present invention is to provide ❹ 一種高延展率之餘合金,並可利额量的改質元素的特 性,對鈦鋁合金進行改質微調。 為解決上述問題,本發明所提出之技術手段為提供一 種欽紹合金,其重量百分比包含:鈦88至92%,銘7.5 至10%,延伸率在8%〜16%。 上述之鈦鋁合金係密度範圍為4. 4〇g/cm3以下、抗拉 強度在68G~95GMpa的鈦合金’應用鑄造、鍛造或機械加 工成型。 本發明所提出之另一技術手段係提供一種鈦鋁合金, 其重量百分比包含:鈦88%至92%、鋁7. 5%至10%、鈮 $2%、鈒 $2%、鉻 $2%、鐵 $1%、石夕 $1%、氧 $〇. 3%及氮SO. 05%,其組成之延伸率在8%〜μ%,密度範 圍為4. 40g/cm3以上。 本發明之鈦鋁合金中之鈦及鋁的含量較習用6A1_4V_ Tl高’鋁含量的提高對於提高合金的常溫和高溫強度、 降低比重、增加彈性模量有明顯效果,·鈮、鈒、鉬、鉻、 200932920 鐵為/5穩定元素,與6Al-4V~Ti相比,釩的添加量大為 減少,從而降低了鈦鋁合金的製造成本。又本發明具有良 好的熱加工成型性,易於工礙量產,且其密度也低於同類 合金,有利於高爾夫球桿頭之大型化,並而提高其設計裕 度。 【實施方式】 茲配合圖表將本發明較佳實施例說明如下。 〇 請參照圖1、圖2及圖3所示,本發明第一實施例之 鈦鋁合金,其合金元素之重量百分比包含:鈦88%至92% 以及銘7. 5%至10%,其組成之延伸率在§〜16%’密度範圍 約為4. 40g/cm3以下。 本發明另可藉由添加微量的改質元素,如由銳、銳、 鉬、鉻、鐵、矽、氧及氮等元素組成的群組中選擇,來調 整其特性,例如,可藉由添加微量的銳,來提升合金之強 度’但不致減低其延伸特性’可藉由相對地降低飢的添加 〇 量,來提高鑄造時之流動性及輔助除氣效果,但仍不致影 響原合金之機械性質;可藉由添加微量的鉬,使合金析出 均勻分布之碳化物,並提高耐熱性,以減少合金之焊接熱 裂現象,亦可增加合金硬化能力及高溫強度;可藉由添加 適量之鉻,來提昇合金之防鏽耐蝕性,增加高爾夫球桿頭 之使用壽命;可藉由添加微量的鐵,以具有良好的塑性, 便於加工處理之施行;藉由添加微董之硬,以改善溶融金 屬之流動性。本發明中所選擇添加之改質元素中,其含量 7 200932920 百分比為鈮$2%、釩$2%、鉬$2%、鉻$2%、鐵、矽 $1%、氧$0.3%及氮$〇. 05%,延伸率為8%〜16%且其密度 約為4. 40 g/cm3以上。 以下將本發明之較佳之第一實施例至第四實施例與習 用6A1-4V-Ti鈦合金之特性比較如下列表1所示:A high elongation alloy, which can be modified and fine-tuned for titanium alloys. In order to solve the above problems, the technical means proposed by the present invention is to provide a Chinso alloy, the weight percentage of which comprises: 88 to 92% of titanium, 7.5 to 10% of the inscription, and an elongation of 8% to 16%. The titanium alloy described above has a density of 4. 4 〇g/cm3 or less and a titanium alloy having a tensile strength of 68 G to 95 GMpa is applied by casting, forging or mechanical processing. Another technical means proposed by the present invention provides a titanium aluminum alloy, the weight percentage thereof comprising: titanium 88% to 92%, aluminum 7.5% to 10%, 铌$2%, 鈒$2%, chromium $2%, iron $1%, 石夕$1%, oxygen $〇. 3% and nitrogen SO. 05%, the composition has an elongation of 8% to μ%, and a density range of 4.40 g/cm3 or more. The content of titanium and aluminum in the titanium-aluminum alloy of the present invention is higher than that of the conventional 6A1_4V_Tl' aluminum content, which has obvious effects on improving the normal temperature and high temperature strength of the alloy, lowering the specific gravity, and increasing the elastic modulus, 铌, 鈒, molybdenum, Chromium, 200932920 Iron is a stable element of /5. Compared with 6Al-4V~Ti, the addition amount of vanadium is greatly reduced, thereby reducing the manufacturing cost of titanium aluminum alloy. Further, the present invention has good hot workability, is easy to hinder mass production, and has a lower density than similar alloys, which is advantageous for the enlargement of the golf club head and improves the design margin. [Embodiment] A preferred embodiment of the present invention will be described below in conjunction with the drawings. Referring to FIG. 1 , FIG. 2 and FIG. 3 , the titanium alloy according to the first embodiment of the present invention has a weight percentage of alloying elements including: 88% to 92% of titanium and 7.5% to 10% of inscription. The composition has an elongation in the range of §~16%' density of about 4.40g/cm3 or less. The invention can also adjust its characteristics by adding a trace amount of modified elements, such as a group consisting of elements such as sharp, sharp, molybdenum, chromium, iron, strontium, oxygen and nitrogen, for example, by adding A slight amount of sharpness to enhance the strength of the alloy 'but not to reduce its elongation characteristics' can improve the fluidity during casting and assist the degassing effect by relatively reducing the amount of hunger added, but still does not affect the machinery of the original alloy. Properties; by adding a small amount of molybdenum, the alloy can precipitate a uniformly distributed carbide and improve the heat resistance, thereby reducing the welding hot cracking phenomenon of the alloy, and also increasing the hardening ability and high temperature strength of the alloy; by adding an appropriate amount of chromium To improve the rust and corrosion resistance of the alloy and increase the service life of the golf club head; it can be processed by adding a small amount of iron to have good plasticity; to improve the melting by adding the hardness of the micro-dong The mobility of metals. Among the modified elements selected in the present invention, the content of 7 200932920 is 铌$2%, vanadium $2%, molybdenum $2%, chromium $2%, iron, lanthanum $1%, oxygen $0.3%, and nitrogen $〇. 05% The elongation is 8% to 16% and the density is about 4.40 g/cm3 or more. The characteristics of the preferred first to fourth embodiments of the present invention and the conventional 6A1-4V-Ti titanium alloy are compared as follows in the following Table 1: ❹ _L_5A1-2V-Ti 本發明第四實施例 7A1-2V-Ti____ …υ ώ〇~^υ 相較於習用之6A1_4V-Ti合金,本發明藉由提高之 相對的紹元素的含量、並降低飢的元素含量,可降低合金 绝、度並增加其勒性’而獲得優異的延展塑性,又能保持低 密度之特性。 本發明之實施例與習用的鈦合金之元素組成比較表如 下列表2所示: 表2 成分 (Wt%) 習用之 6A1-4V-Ti重量百分比 本發明實施例之一 8A1-Ti重量百分比 銘(A1) 5. 5-6. 75 7. 9-8. 3 3.5-4. 5 0.001 "5(C)~~ 0.Π 0.010-0.012 ~ΜΓ~ 0. 05 i "〇. 005-0. 01 0.21 0.09-0.11 ~mle) 0.3J, 0.06-0. 007 矽(Si) 0.H 0.01-0.03 200932920 上述實施例之合金材科係以敍紹合金為 係以延伸率在δ〜⑽⑽以上金,其 ,_ρ"上)的欽合金:強= 工而成型。 楸以、機械加 本發明之延展性較高,適合作為高目夫 二另/=金佳的之材料成為打擊面:其材料組成可ΐ == 金等,造、锻造、機械加 =成f。本發明之高延展性本體加上高強度打擊面板之 材料組。’於本體内部結構設計再辅以配重結構與肋片設 計,即可達到具打感佳(制震性佳)及控球性佳且桿部可調 角予以客制化之同爾夫球頭產品,其本發明,與習 用6AHV-Ti之加工性能比較列表如表3所示。 表3 〇 加工性能 ~f¥i; -- 6A1-4V-Ti i發明實施例之一 ~~' 8A1-Ti 冷調角 材料性質相較為脆,調角至1>5 度球頭桿部會發生裂痕。 材料性質相較為軟韌,調角至 3.5度球頭桿部無發生任何裂 紋。 于巧母賴琢頭加 工量 1. 5g 〇.9g 干网母顆琢頭研· 磨量 12g 9.3g 另外,本發明以8A1-Ti材料為實施例製成高爾夫球 頭本體再焊以SP700高強度鈦合金為打擊面’經砲擊專用 回爾夫球(球規格為90) 55.8 m/s砲擊速度,通過3000 下砲擊測試,打擊面板與球頭本體經目視與探傷測試均無 破裂及裂痕。 9 200932920 綜上所述,本案所發明之鈦鋁合金已具有產業利用 性、新穎性與進步性,符合發明專利要件。惟以上所述 者,僅為本發明之較佳實施例,並非用以限定本發明實施 之範圍。即凡依本發明申請專利範圍所做的均等變化與修 飾,皆為本發明專利範圍所涵蓋。 【圖式簡單說明】 第1圖繪示本發明應用於高爾夫桿頭之鈦鋁合金實施例之 放大50倍金相圖; 第2圖繪示本發明應用於高爾夫桿頭之鈦鋁合金實施例之 放大100倍金相圖;以及 第3圖繪示本發明應用於高爾夫桿頭之鈦鋁合金實施例之 放大200倍金相圖。 【主要元件符號說明】 200932920 五、中文發明摘要: 本發明揭示一種應用於高爾夫球桿頭之鈦銘合金,其 係包含重量百分比之鈦88%至92%、鋁7. 5%至1〇%,延伸率 為8%〜16%。該鈦鋁合金並可選擇性地添加鈮、飢、翻、 鉻 一〜尔 組取玩拉強度在 65〇~95GMpa之高延伸特料’此高延伸特料運古 爾夫球桿頭之本體,結合剛性較佳之6AHTi_ _L_5A1-2V-Ti The fourth embodiment of the present invention 7A1-2V-Ti____ ... υ υ ~ ^ υ Compared with the conventional 6A1_4V-Ti alloy, the present invention improves the relative content of the element and reduces hunger The elemental content can reduce the alloy's degree of extinction and increase its rigidity, and obtain excellent ductility and low density. A comparison of the elemental compositions of the examples of the present invention with conventional titanium alloys is shown in Table 2 below: Table 2 Ingredients (Wt%) Conventional 6A1-4V-Ti Weight Percentage One of the examples of the present invention 8A1-Ti weight percent A1) 5. 5-6. 75 7. 9-8. 3 3.5-4. 5 0.001 "5(C)~~ 0.Π 0.010-0.012 ~ΜΓ~ 0. 05 i "〇. 005-0 01 0.21 0.09-0.11 ~mle) 0.3J, 0.06-0. 007 矽(Si) 0.H 0.01-0.03 200932920 The alloy material of the above embodiment is based on the sulphate alloy with an elongation of δ~(10)(10) or more. Gold, its, _ρ" on the alloy: strong = work and molding.楸I, mechanical plus the invention has higher ductility, and is suitable as a material for Gaomufu 2/=Jinjia: the material composition can be ΐ == gold, etc., making, forging, mechanical plus = f . The highly malleable body of the present invention is coupled to a material set of high strength striking panels. 'In the internal structure design of the main body, supplemented by the weight structure and rib design, can achieve the ball with good feel (good shock resistance) and ball control and the adjustable angle of the rod is customized. A comparison of the processing properties of the head product, the present invention, and the conventional 6AHV-Ti is shown in Table 3. Table 3 〇Processing performance~f¥i; -- 6A1-4V-Ti i One of the invention examples ~~' 8A1-Ti The property of the cold-adjusting angle material is relatively brittle, and the angle is adjusted to 1> A crack has occurred. The material properties are relatively soft and tough, and the angle of the ball is adjusted to 3.5 degrees without any cracks in the club head. The processing amount of the 巧 琢 琢 1 1 1 1 1 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9.3 9.3 9.3 9.3 9.3 9.3 9.3 9.3 9.3 9.3 9.3 9.3 9.3 9.3 9.3 9.3 9.3 9.3 9.3 9.3 9.3 9.3 9.3 9.3 The strength of the titanium alloy is the impact surface 'the special round of the shelling ball (the ball size is 90) 55.8 m / s shelling speed, through 3000 shots test, the impact panel and the ball head body through the visual and flaw detection test are no cracks and cracks. 9 200932920 In summary, the titanium-aluminum alloy invented in this case has industrial utilization, novelty and progress, and meets the requirements of invention patents. The above is only the preferred embodiment of the invention, and is not intended to limit the scope of the invention. That is, the equivalent changes and modifications made by the scope of the patent application of the present invention are covered by the scope of the invention. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a magnified 50-fold metallographic diagram of a titanium-aluminum alloy embodiment of the present invention applied to a golf club head; FIG. 2 is a view showing an embodiment of a titanium-aluminum alloy applied to a golf club head according to the present invention. The magnification is 100 times the metallographic map; and the third figure shows the magnified 200 times metallographic diagram of the titanium-aluminum alloy embodiment of the present invention applied to the golf club head. [Main component symbol description] 200932920 V. Abstract of the invention: The invention discloses a titanium alloy for golf club head, which comprises 88% to 92% by weight of titanium and 7.5% to 1% by weight of aluminum. The elongation is 8% to 16%. The titanium-aluminum alloy can be selectively added with strontium, hunger, turn, chrome, and a group of high-stretching materials with a tensile strength of 65 〇 to 95 GMpa. This high-stretching special material transports the body of the golf club head. , combined with 6AHTi with better rigidity 或点合金之擊球面板所形成之高爾夫球桿頭,。金 打感佳、制震性及控球性佳i扣 逆到具 高爾夫球頭產品。 匕之 六、英文發明摘要: 3 200932920 十、申請專利範圍: 1. 一種應用於高爾夫球桿頭之鈦鋁合金,其重量百分比包 含:鈦88%至92%以及鋁7. 5%至10%,其組成延伸率為 8%〜16%之欽銘合金。 2. 如申請專利範圍第1項所述之應用於高爾夫球桿頭之鈦 鋁合金,其中該鈦鋁合金更包含一改質元素,該改質元 素係選自銳、飢、錮、鉻、鐵、碎、氧及氮所組成之群 組。 ® 3.如申請專利範圍第2項所述之應用於高爾夫球桿頭之鈦 鋁合金,其中該改質元素包含鈮2%以下。 4. 如申請專利範圍第2項所述之應用於高爾夫球桿頭之鈦 鋁合金,其中該改質元素包含釩2%以下。 5. 如申請專利範圍第2項所述之應用於高爾夫球桿頭之鈦 鋁合金,其中該改質元素包含鉬2%以下。 6. 如申請專利範圍第2項所述之應用於高爾夫球桿頭之鈦 _ 鋁合金,其中該改質元素包含鐵1%以下。 7. 如申請專利範圍第2項所述之應用於高爾夫球桿頭之鈦 鋁合金,其中該改質元素包含矽1%以下。 8. 如申請專利範圍第2項所述之應用於高爾夫球桿頭之鈦 鋁合金,其中該改質元素包含氧0.3%以下。 9. 如申請專利範圍第2項所述之應用於高爾夫球桿頭之鈦 鋁合金,其中該改質元素包含氮0.05%以下。 10. —種應用於高爾夫球桿頭之鈦鋁合金,其重量百分比 包含:鈦88%至92%、鋁7. 5%至10%、鈮$2%、釩$2%、 11 200932920 鉬S 2%、鉻S 2%、鐵S 1%、矽S 1%、氧S 0. 3%及氮 SO. 05%,其組成之延伸率為8%〜16%Or the golf club head formed by the alloy hitting panel. Gold has a good sense of feel, shock resistance and good ball control.匕六, English Abstract: 3 200932920 X. Patent application scope: 1. A titanium-aluminum alloy applied to a golf club head, the weight percentage thereof including: titanium 88% to 92% and aluminum 7.5% to 10% , the composition of the elongation rate of 8% ~ 16% of the Chin Ming alloy. 2. The titanium-aluminum alloy applied to a golf club head according to claim 1, wherein the titanium alloy further comprises a modified element selected from the group consisting of sharp, hunger, cockroach, chromium, A group of iron, broken, oxygen, and nitrogen. The titanium-aluminum alloy applied to a golf club head according to claim 2, wherein the modified element contains 铌2% or less. 4. The titanium aluminum alloy applied to a golf club head according to claim 2, wherein the modified element contains vanadium of 2% or less. 5. The titanium aluminum alloy applied to a golf club head according to claim 2, wherein the modified element comprises molybdenum of 2% or less. 6. The titanium _ aluminum alloy applied to a golf club head according to claim 2, wherein the modified element contains iron less than 1%. 7. The titanium aluminum alloy applied to a golf club head according to claim 2, wherein the modified element comprises 矽1% or less. 8. The titanium aluminum alloy applied to a golf club head according to claim 2, wherein the reforming element comprises oxygen of 0.3% or less. 9. The titanium aluminum alloy applied to a golf club head according to claim 2, wherein the modified element contains nitrogen of 0.05% or less. 10. A titanium-aluminum alloy applied to a golf club head, the weight percentage thereof comprising: titanium 88% to 92%, aluminum 7.5% to 10%, 铌$2%, vanadium $2%, 11 200932920 molybdenum S 2% , chromium S 2%, iron S 1%, 矽S 1%, oxygen S 0. 3% and nitrogen SO. 05%, the elongation of its composition is 8% to 16% 12 200932920 七、指定代表圖: (一) 本案指定代表圖為:圖(1)。 (二) 本代表圖之元件符號簡單說明: 無 ® 八、本案若有化學式時,請揭示最能顯示發明特徵的化學 式:12 200932920 VII. Designated representative map: (1) The representative representative of the case is: Figure (1). (2) A brief description of the symbol of the representative figure: None ® 8. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention:
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