TW200831609A - Coated articles of manufacture made of high Tg polymer blends - Google Patents

Abstract

The present invention relates generally to the field of articles of manufacture in the form of a shaped article comprising a blend of polymers wherein all, or some of, one or more surfaces of the shaped article is coated with a covering material, wherein the covering material has a different composition than the shaped article, and, wherein the shaped article comprises either: (a) an immiscible blend of polymers having more than one glass transition temperature and one of the polymers has a glass transition temperature greater than 180 DEG Celsius; (b) a miscible blend of polymers having a single glass transition temperature greater than 217 DEG Celsius; or, (c) a single virgin polymer having a glass transition temperature of greater than 247 DEG Celsius. The present invention is also directed to light source reflectors comprising a polymer according to (a), (b) or (c) above.

Description

200831609 IX. INSTRUCTIONS OF THE INVENTION: TECHNICAL FIELD OF THE INVENTION The present invention generally relates to the field of article articles in the form of shaped articles comprising a polymer or polymer blend, wherein all of one or more of the surfaces of the shaped article Or some surface coated with a cover material, wherein the cover material has a different composition than the shaped article, and wherein the shaped article comprises one of: a) an immiscible polymer blend comprising at least one polyetherimine a compound having more than one glass transition temperature and wherein the polylysine has a glass transition temperature greater than 217 ° C; ... comprising at least one miscible polymer blend of polyether quinone having greater than 217 t : a single glass transfer μ degree, or c) a single polymer having a glass transition temperature greater than 247 °C. [Prior Art] There is a continuing need for polymers having good manufacturing and performance characteristics at high temperatures. For example, a high heat polymer is used to replace the metal portion of the "under the hood" automotive application. The high heat polymer is capable of withstanding a degree of heat comparable to metal parts but its weight is small and thus helps the car to utilize the fuel more efficiently. Other automotive uses further confirm the continuing need for high thermal polymers. Makeup reflectors (especially for automotive applications) require materials that can withstand the high heat generated by the source, have excellent dimensional stability to focus distant light into a compact pattern, and can be easily machined into complex shapes. These reflectors are typically coated with a metal such as the inscription to provide a highly reflective surface. An extremely smooth pre-coated surface is required to achieve this high reflectivity with low haze. In order to achieve this smooth pre-coated surface at all times, it is often necessary to prime the reflector with a primer before it is molded by metal coating to reflect the I18106.doc 200831609. Direct metallization of the molded part is also challenging because it introduces the need for water to be adhered to the molded part and the molded part to have a very smooth surface. Because of the harmful effects of the error on the environment, lead-free solder has been at least partially replaced in electronic components. The replacement solder has a higher melting point than the lead-based solder, and thus requires a polymer capable of withstanding the extra heat necessary to replace the solder with molten lead for use as, for example, a substrate or coating adjacent to the solder joint. Even the use of polymer components, such as sensing heat from jet engine washing, has created a continuing need for polymers having higher thermal properties than currently marketed polymers. Several high thermal polymers are known in the art. Polyether phthalimide resin is characterized by high heat distortion temperature and high glass transition temperature. Its high heat distortion temperature and high glass transition temperature make it suitable for coating, molding objects, composites and the like in places where high temperature resistance is required. The use is very attractive. However, because of its high glass transition temperature and high melt viscosity, it may be difficult to process polyether oximine into a product. Molding, extrusion, spraying, and the like must be carried out at a high temperature to plasticize the polyether oximine resin. Two properties that may limit the use of the polyether oxime composition (especially in injection molding applications) are demolding and melt flow. Polyfluorene is also known for its use in high temperature applications, as are polyether oximes and polyphenylene ether oximes. See U.S. Patent Nos. 3,634,355, 4,008,203, 4,108,837, and 4,175,175. The polyoxo copolymers in the field of polymers are also known. See U.S. Patent Nos. 4,404,350, 4,808,686 and 4,690,997. See U.S. Patent No. 5,916,997, the disclosure of which is hereby incorporated by reference in its entirety the entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire disclosure The street is born from the aryl ester bond of stupid phenol. There is still a continuing need to demonstrate polymer compositions that have improved demolding and high melt flow. There is always a need for polymers, polymer conjugates and copolymers having new and/or improved properties that allow for easier production, easier processing, and better end-use characteristics. There is a continuing and urgent need for polymers having high glazing that combines with other properties that allow for improved processing, improved interstitial stability, and low cost. SUMMARY OF THE INVENTION The present invention is directed to a shaped article article comprising a polymer or polymer blend, wherein all or some of one or more surfaces of the shaped article are coated with a cover material, wherein the cover material has The shaped article has a different composition, and wherein the shaped article comprises one of: a) an immiscible polymer blend comprising at least one polyether quinone imine having more than one glass transition temperature and wherein the polyether The quinone imine has a greater than 217. . a glass-to-transfer degree, b) a miscible polymer blend comprising at least one polyether quinone imine having a single glass transition temperature greater than 2 irc; or a single glass transition temperature greater than 247 ° C polymer. The present invention is also directed to such articles, wherein the covering material comprises one or more compositions selected from the group consisting of powders, flakes, films, fibers, woven materials, non-solidified liquids, solidified liquids, and any combination of such covering materials. . [Embodiment] The term "article of article" as used by the definition of 118106.doc 200831609 is consistent with the term used by the United States Patent and Trademark Office (1), which is used by the State Patent and Trademark 〇ffiee). In the present invention, the term "light source" means an element (for example, a filament) or a material (for example, 氖) that converts energy into visible radiant energy and/or a necessary container of the element or material 2 (ie, A light source envelope (eg, a bulb, a fluorescent tube) including an envelope base. For the purposes of the present invention, the source is assumed to be a point source unless otherwise indicated. , assuming, for example, a light unit", a "light",,, a headlight,,,

The L.E.D. special noun statement only represents the light source. "Modifier" is a combination of elements or elements whose direct function is to change the distribution or combination of light emitted from a light source by reflecting, refracting, or partially or fully absorbing light. The term "reflector" refers to a light modifying device having a surface that redirects incident light back to the medium f from which it is emitted. The reflector is more generally opaque but can also be transparent. The light that strikes the redirecting surface of the transparent reflector can come from the transparent material of the reflector itself, in which case it redirects to the moon-reflecting material of the reflector, or It can reach the redirecting surface from some other material (eg, air), in which case it redirects back to other materials. The term "transporter is used to include all vehicles that can be used to transport humans, mammals, or any type of cargo' and is intended to include, for example, all types of wheeled vehicles, automobiles, aircraft, and all types of aircraft. , trains, motorcycles, trucks, SUVs, boats, cargo ships, etc. For the purposes of the present invention, "metallized surface" means a surface covered by a coating comprising one or more metals. The molecular composition, whereby the material having the ig molecular combination 118106.doc 200831609 or the structure is a different composition. For the purposes of the present invention, the LED is a light-emitting diode, the term is known to those skilled in the art. "The term refers to a polymer having i8 (rc or higher than 18 〇. 玻璃 glass transition temperature. The term " the ratio of the number of hydrogen atoms to carbon atoms, is a repeating unit of a polymer or a constituent polymer (monomer The ratio of the number of hydrogen atoms to the number of carbon atoms.

The definition of benzylated protons is well known in the art and, for the purposes of the present invention, comprises at least one aliphatic carbon atom chemically bonded directly to at least one aromatic ring, such as a phenyl ring or a benzene ring, Wherein the aliphatic carbon atom additionally has at least one proton bonded directly to the carbon atom. 2 In the context of the present invention, substantially or substantially free of benzylated protons means about 5 mole percent or less of the derivatized structural units of the polymer such as the polythenimine sulfone product (in some embodiments, about 3 摩尔% of the derivative unit, and in other embodiments, about 1# 』1 旲 ❶ / ❶ below the derived structural unit) contains benzylated protons. Except, Tian not 3 methyl protons (also known as benzyl hydrogen) actually 衲 衲 醯 耳 0 莫 莫 0 / " --^ ^ ^ ' Dingsheng from the body and end cap body The structure of the sputum contains benzylated protons or benzoquinones. Based on chemical chemical analysis, the benzoquinone matrix can be determined by re-examining::: The surface is coated with a covering material, which covers all or some of the constituents, and wherein the shaped article contains the following; different 2irc single glass transition temperature Miscible polymer blends:: 118106.doc 200831609 Immiscible polymer blends having more than one glass transition temperature, and those polymers have greater than just. The glass transition temperature of c. The term "coating" means a thin layer or a thin layer applied to a material called a matrix. In the present invention, the matrix is composed of one or more; a compound, a polymer and/or Or a polymer blend composition. The coating may comprise any material that the skilled artisan will use as a coating on the polymeric substrate, including (i.e., without limitation) one or more metals, one or more binders, one or more Paint, or alloys, one or more solid-liquid suspensions, one or more polymers (at least one of the polymers in the coating has a composition different from the polymeric matrix). For the purposes of the present invention, it may be present on the substrate It is necessary to achieve as many coatings as possible for the article of manufacture. The term "thin" as used above means that the thickness of the coating at the thickest point of the coating on the object is less than the center of gravity of the object and extends to but not The length of the line exceeding the outermost boundary of the object. The coating can be applied by any coating method known to the skilled person. For example, it can be electrolyzed, vapor deposited, vacuum evaporated, sputtered or sprayed, calendered, etc. Overmolding , laminating and roller coating mechanical means to apply the coating. The matrix or shaped article in the mouthpiece of the present invention is any polymeric material produced industrially, which is: a) has a single glass transition temperature greater than 217 a miscible polymer blend; or b) an immiscible polymer blend comprising at least one polyether quinone having more than one glass transition temperature and wherein the polyether quinone has greater than 180. Glass transition temperature. The matrix may also comprise a polymer blend comprising at least one polyether quinone imine having a glass transition temperature greater than 247 ° C with 118106.doc -11- 200831609, or In another embodiment, the kebab is a polymer composition comprising at least one species of polyfluorene imine, wherein the blend has a glass transition temperature greater than 217 Å (in another solid (4)) a mono-polymer having a glass transition temperature of a large (fourth). The present invention is also directed to a hydrogen atom number ratio of 0.45 to 0.85, or 50.50_〇.8〇, or 〇55〇75, or 〇6. 〇〇7〇聚 / acid brewed imine shape The present invention is also directed to shaped articles comprising - or a plurality of polyfluorinated imines substantially free of benzylated protons. Another aspect of the invention is a blend of polylysine or polylysine The finished article has sufficient stability for the melt processing to cause a small change in molecular weight during the melting and partial forming process. This requires that the polymer be free or substantially free of changes in molecular weight that will occur in the melt. The presence of a benzyl group proton in a polyether sulfimine generally promotes a change in molecular weight in the melt. Due to the increased melt stability of the resulting polymer, it has been derived from an aromatic diamine, an aromatic dianhydride, and a capping end. The polyether quinone imine of the structural unit substantially free of benzylated protons is preferred in some applications, especially for melt separation and melt processing after polymerization. ^ Listed below are representative examples of matrix materials for shaped articles. · High Tg polymer blends of ruthenium-based ruthenium polymers or blends, polyfluorene oxide copolymers and resorcinol-derived polyarylates. Things. Disclosed herein are articles of manufacture comprising a polymer blend, wherein some or all of one surface of the polymer blend is coated with a cover material, wherein the cover material is a composition different from the polymer blend, and wherein Polymer 118106.doc -12- 200831609 The blend comprises: a) selected from the group consisting of polyfluorene (PSu), poly. a high glass transition temperature (T^i8(rc)-resin, b) of a group of 7 1 (f)sulfone) (PES), poly(phenylene ether sulfone) (PPSU), (iv) an oxygen copolymer, such as poly The amphoteric polyoxyimide or polyoxetite polyacid anti-acid S曰' and c) resorcinol-based polyaryl esters, wherein the blend has surprisingly low exotherm values and improved melt flow. 1. Blend polysulfone, polyether sulfone and polyphenylene ether mill component The polysulfone, poly(ether oxime) and poly(phenylene ether oxime) used in the articles described herein are, for example, US patents. Thermoplastic resins as described in Nos. 3,634,355, 4, 8, 2, 3, 4, 108, 837 and 4, 175, 175. Polyfluorene, poly (barium) and poly(phenylene) are linear thermoplastic polymers with many attractive characteristics such as high temperature resistance, good electrical properties and good hydrolytic stability. Polyfluorene comprises a repeating unit having the structure of formula I: "^ 1 butyl 3 butyl (1) wherein R is an aryl group containing a carbon-carbon single bond, a carbon-oxygen-carbon bond or a carbon-carbon and a carbon-oxygen-carbon single bond The bond forms part of the polymer backbone. Poly(ether oxime) comprises a repeating unit having an ether bond and a sulfone bond in the polymer backbone as shown in the formula: 〇--Ar-S-Ar'-0-- ° ( II) wherein Ar and Ar* are the same or different aryl groups. Ar and Ar may be the same or different. When both Ar and Ar' are phenyl groups, the polymer is called poly(phenylene ether). When both Ar and Ar' are aryl groups, the polymer is called poly(aryl ether 118106.doc -13- 200831609 飒). The number of sulfone bonds and the number of ether bonds may be the same or different. The formula (III) shows An exemplary structure showing the number of sulfone bonds different from the number of ether bonds: Ο

-Ar-S-Ar'-O-Ar'^O (III) 〇 wherein Ar, Ar• and Ar" are the same or different aryl groups. Ar, Ar, and Ar, which may be the same or different, such as a heart and Ar, may all be a phenyl group and Ar" may be a bis(1,4-phenylene) isopropyl group. A variety of polysulfones and poly(ether sulfones) are commercially available, including polycondensation products of dihydroxydiphenyl hydrazine and dichlorobenzene, and polycondensation products of bis-A and dichlorodiphenyl hard. Examples include methods for preparing polyfluorenes and poly(_) from 〇1 stomach, heart R, RADEL A and UDEL, and ultras〇n E ° available from BASF c〇. Several methods for extracting td .. ^ k have been fully described in the technology. Both methods, the carbonate method and the alkali metal oxychloride method are known to the skilled artisan. In the metal hydroxide method, 'substantially under anhydrous conditions in the presence of a bipolar, aprotic solvent - is subjected to a metal-recovery plate - ^ yri jl ) I - a compound of this type is contacted. Also disclosed in the art (e.g., U.S. Pat. The hydroquinone salt is heated. Alternatively, polyfluorene and poly (scale) can be prepared by any of a variety of methods known in the art. The molecular weight of polysulfone or poly(ether stone) can be greater than the reduced viscosity data in the field cold refrigerant such as methylene chloride, trichloromethane, N. methyl (4) or the like. Or equal to about 3.3 _, or more specifically, 118106.doc -14- 200831609 at or equal to about 0.4 dl/g, and usually does not exceed about 1.5 dl/g. In some examples, the polysulfone or poly(ether sulfone) may have a weight average molecular weight of from about 10,000 to about 100,000 as determined by gel permeation chromatography using ASTM method D5296 (ASTM METHOD D5296). In some examples, the polysulfone and poly(ether sulfone) can have a glass transition temperature of from about 180 QC to about 250 °C. When a high REC copolymer is blended with polysulfone, poly(ether sulfone) and poly(phenylene ether), polysulfone, poly(ether sulfone) and poly(phenylene ether) ruthenium will have greater than or equal to about Glass transition temperature (Tg) at 180 °C. The polybenzazole resin is further described in ASTM Method D6394 Standard Specification for Sulfone Plastics. In some examples, the polysulfone, poly(ether sulfone), and poly(phenylene ether sulfone) and blends thereof will have a hydrogen to carbon atomic ratio (H/C) of less than or equal to about 0.85. It is not bound by theoretical polymers that have a higher carbon content relative to the hydrogen content (i.e., a lower hydrogen to carbon ratio) and often exhibit improved FR performance. These polymers have lower fuel values and can release less energy when burned. It is also resistant to combustion by the tendency to form an insulating coking layer between the polymeric fuel and the ignition source. Independent of any particular mechanism of action or mode, it has been observed that such polymers having a low H/C ratio have higher flame resistance. In some examples, the H/C ratio can be less than or equal to 0.75 or less than 0.65. In other examples, an H/C ratio of greater than or equal to about 0.4 is preferred in order to obtain a polymeric structure having sufficient flexible bonds to achieve melt processability. The H/C ratio can be determined from the chemical structure of a given polymer or copolymer by counting the carbon and hydrogen atoms independent of any other atoms present in the chemical repeating unit. In the polymer blend, polyfluorene, 118106.doc -15-200831609 poly(scale hard) and poly(phenylene ether sulfone) and blends thereof may be about 1 based on the total weight of the polymer blend. It is present in an amount of about 99% by weight. Within this range, the amount of polysulfone, poly(ether oxime) and poly(phenylene ether hard) and mixtures thereof may be greater than or equal to about 20 weight. /❶, more specifically greater than or equal to about 50% by weight, and even more specifically greater than or equal to about 70% by weight. . The skilled artisan will appreciate that 'poly bowl, poly(sulfonate) and poly(phenylene ether sulfone) and mixtures thereof may be from about 1 to about 99% by weight (and especially from 1 to 7) based on the total weight of the polymer blend. Any real number between 〇 weight %) exists. 2. Polyoxymethylene component of the blend The polyoxynoxy copolymer comprises any of the oxyalkylene copolymers effective to improve the exothermic performance of the composition. In some examples, a polyoxyalkylene copolymer of polyetherimide, polyetherimide sulfone, polysulfone, poly(phenylene ether sulfone), poly(ether sulfone) or poly(phenylene ether) can be used. . In some instances, a fluorinated polyether oxime copolymer or a decane polycarbonate copolymer is effective in reducing exothermic performance and inducing flow rate performance. The invention also encompasses mixtures of different types of oxane copolymers. In one embodiment, the oxyalkylene copolymer comprises from about 5 to about 70 weight percent (and in other instances from 2 to about 5 weight percent) the agglomerated oxygen content relative to the total weight of the copolymer. The block length of the azide fragment of the copolymer can be any effective length. In some examples, the block length can range from about 2 to about 7 moles of a repeating unit. In other examples, the oxetane block length can range from about 5 to about 5 repeat units. In many instances, dimethyloxane can be used. The decyl alkoxy polyimide copolymer is a specific embodiment of a siloxane copolymer that can be used in a polymer blend. U.S. Patent Nos. 4,4,4,35, 4,808,686 and 4,690,997 show examples of these oxane polyether phthalimides totaling 118106.doc -16-200831609. In one example, the oxoxane polyether oximeimide copolymer can be prepared analogously to the manner used to prepare the polyether quinone imine, but wherein the partial or full-portion P-organic amine reactant is via, for example, an amine of formula IV. The terminal organic oxime substitution in the external formula 1V wherein g is an integer having a value of from 1 to about 50 (or more specifically, from about 5 to about 3 Å) and R is from 2 to about 2 carbon atoms. An aryl, alkyl or aryl group.

H2N-r·-si

Formula IV can be prepared by any of the methods well known to those skilled in the art. (IV) Oxygen-fired polyacrylamide copolymers' including the reaction of an aromatic bis(10) anhydride of formula V with a νπ organic diamine.

In Formula V, T is _〇-, -S_, _s〇2- or a formula _z_〇- group in which the divalent bond-0- or _0-Z-0- group is at 3,3 , 3, 4, 4, 3, or 4, 4, position, and wherein Z includes, but is not limited to, a substituted or unsubstituted divalent organic group, such as (4) having from about 6 to about 2G An aromatic hydrocarbon group of a carbon atom and a dentate derivative thereof; (8) a straight bond or a bond extension group having from about 2 to about 20 carbon atoms; (c) a cycloalkane having from about 3 to about 20 carbon atoms; Base, or (a magical % of a divalent group

118106.doc -17- 200831609 In the formula νι, Q includes, but is not limited to, a group selected from _〇_, _s_, , -SCV, -so·, -CyH2y_ (y is an integer from 1 to 8) a divalent group and a fluorinated derivative thereof (including a perfluoroalkylene group), H2N-R1-NH2 (VII) in the formula νπ, the group R in the formula VII includes, but is not limited to, substituted or unsubstituted a substituted divalent organic group such as (a) an aromatic hydrocarbon group having from about 6 to about 24 carbon atoms and a dentate derivative thereof; (b) a linear chain having from about 2 to about 2 carbon atoms Or a branched alkyl group; (c) a cycloalkyl group having from about 3 to about 2 carbon atoms, or (a divalent group of the magic formula VI. An example of a fluorene-free dianhydride and an organic diamine) Illustrative examples of aromatic dianhydrides of the formula (χΙν) include: 3.3-bis[4-(3,4-dicarboxyphenoxy)phenyl]propene, for example, in U.S. Patent Nos. 3,972,902 and 4,455,410. Burning dianhydride; 4,4'-bis(3,4-dicarboxyphenoxy)diphenyl ether dianhydride; 4,4'-bis(3,4-dicarboxyphenoxy)diphenyl sulfide dianhydride ; 4,4'-bis(3,4-diphenylphenoxy)benzophenone dianhydride; 4,4' - bis(3,4-dicarboxyphenoxy)diphenyl sulfone dianhydride; 2,2-bis[4-(2,3-dicarboxyphenoxy)phenyl]propane dianhydride; 4.4-bis (2 , 3-dicarboxyphenoxy)diphenyl ether dianhydride; 4.4-bis(2,3-dimercaptophenoxy)diphenyl sulfide dianhydride; 4.4-bis(2,3-dicarboxyphenoxy) Benzophenone dianhydride; 4.4-bis(2,3-dicarboxyphenoxy)diphenyl sulfone dianhydride; 4-(2,3 < thiophenoxy)-4,-(3,4- Dicarboxyphenoxy)diphenyl-2,2-propane dianhydride; 118106.doc -18 - 200831609 4-(2,3·dicarboxyphenoxy)·4,_(3,4-dicarboxybenzene Oxy)diphenylether dianhydride; 4-(2,3-dicarboxyphenoxy)-4,-(3,4-dicarboxyphenoxy)diphenyl sulfide dianhydride; 4-(2,3- Dicarboxyphenoxy)_4,_(3,'dicarboxyphenoxy)benzophenone di: anhydride; and: 4-(2,3-dicarboxyphenoxy M,-(3,4-di Carboxyphenoxy)diphenyl sulfone dianhydride, and mixtures thereof. In addition to the above-described alkoxyalkylene diamine, examples of suitable diamines include ethylenediamine, propanamine, trimethylenediamine, diethylidene Triamine, tri-ethyltetramine, hexamethyleneamine, heptanediamine, octanediamine, hydrazine Diamine, decane diamine, ii 2 · dodecapine diamine, 1,18-octadecanediamine, hydroxymethylheptanediamine, 4, dimethylheptanediamine, 4-mercaptodecylamine , % methyl hydrazine diamine, 2,5-dimethylhexamethylenediamine, 2,5·didecylheptanediamine, 2,2-dimercaptopropane diamine, N-methyl-diaminolated Propyl)amine, nonyloxyhexanediamine, 1,2-bis(3-aminopropoxy)ethane, bis(3-aminopropyl) sulfide, 14-cyclohexanediamine, biguanide 4_Aminocyclohexyl)methane, m-phenylenediamine, p-phenylenediamine, 2,4-diaminotoluene, 2,6-diamino, indole, m-xylenediamine, p-xylene Amine, 2-methyl-4,6·diethyl-1,3-phenylenediamine, 5-methyl-4,6-diethyl-1,3-phenylenediamine, benzidine, 3,3 - methylbenzidine, 3,3'-dimethoxyoxybenzidine, 1,5-diaminonaphthalene, bis(4-aminophenyl)methane, bis(2-chloro-4-amino) 3,5-Diethylphenyl)decane, bis(4-aminophenyl)propane, 2,4-bis(amino-t-butyl)toluene, bis(p-amino-t-butyl) Phenyl)ether, bis(p-fluorenyl-o-aminophenyl) 118106.doc -19- 200831609 Benzene, double ( p-Methyl-o-aminopentyl)benzene, diamino-4-isopropylbenzene, bis(4-aminophenyl) sulfide, bis('aminophenyl)anthracene, bis('amino group Phenyl) scales and combinations comprising two or more of the foregoing. An example of a special mussel of a nonoxyldiamine is 1,3-bis(3-aminopropyl)tetramethyldiazepine. In one embodiment, the diamine-based compound used in combination with the sulphuric acid diamine is an aromatic diamine, especially m-phenylenediamine and p-phenylenediamine, sulfonyldiphenylamine, and mixtures thereof. Some of the decyl alkoxy polyether oxime copolymers can be formed by reacting a mixture of an organic diamine or a diamine of formula VII with an amine oxo-oxane of the above formula Iv. The monoamine component is physically mixed prior to reaction with the dianhydride, thus substantially forming a random copolymer. Alternatively, a hydrazine or alternating copolymer can be formed by selectively reacting VH and IV with a dianhydride (e.g., Formula V) to produce a subsequently co-reacted polyimine block. In another example, the decane used to prepare the polyether quinone copolymer can have an anhydride rather than an amine functional end group. In one example, the oxoxane polyether oxime copolymer may be of the formula νιπ, wherein T, R' and g are as described above, b has a value of from about 5 to about 100, and Ar1 has from 6 to about 36. a carbon aryl or alkylaryl group.

In some of the anthraquinone polyether oxime imine copolymers, the diamine component of the diarrhea polyether oxime imine copolymer may contain from about 20 to 50 mole % of the amine of the formula IV. Burning about 50 to 80 mole % of the organic amide of formula VII. In some of the helium oxygen H8106.doc -20- 200831609 yuan /, the Shixi oxygen burning component is derived from about 25 to about 40 mole % of the amine or anhydride terminal organic oxime. The polyoxymethylene copolymer component of the poly-5 dope may be present in an amount from about !·! to about 2% by weight based on the total weight of the polymer blend. Within this range, the polyoxo, and the polymer may also be present in an amount of from about 1% by weight (further, from 5 to 5). 3. The resorcinol-based polyarylate component of the blend φ The polyaryl aryl ester based on m-phenylene phenol is a polymer comprising an aryl ester polyester structural unit. The aromatic vinegar polyacetate structural unit The reaction product of the di- and anti-aromatic two (four) to; a portion of the aryl ester polyester structural unit comprising a 1,3-dihydroxyphenyl group (as shown in Formula I) is generally referred to throughout the specification as resorcinol. Or m-benzene: Panki. It is to be understood that, unless otherwise specifically stated, the benzodiazepine or meta-phenylene is used herein to include both the unsubstituted 1,3-di-diphenyl and the substituted 1,3-dihydroxybenzene. i〇lDr〇i

In Formula IX, each occurrence is referred to as Cii2 alkyl, c6_c24 aryl C7_C24 alkylaryl, alkoxy or halogen, and 11 is 0-4. In one embodiment, the polyphenylene vinegar resin based on isophthalic acid comprises greater than or equal to about 50 mole % of an aryl group derived from a strepodiphenol and an aryl dicarboxylic acid or suitable for forming an aromatic vinegar bond. A unit of the reaction product of a dicarboxylic acid derivative (for example, a carboxylic acid dentate, a carboxylic acid vinegar, and a decanoate). Oral monocarboxylic acids include mono- and polycyclic aromatic dicarboxylic acids. Exemplary monocyclic two H8106.doc • 21 - 200831609 The tickic acid includes a mixture of isophthalic acid, terephthalic acid or isophthalic acid terephthalic acid. Polycyclic ditoxanic acid includes dicarboxylic acid, diphenyl-dicarboxylic acid, and naphthalene dicarboxylic acid (e.g., naphthalene-2,6-didecanoic acid). Thus, in one embodiment, the polymer blend comprises a thermally stable polymer having a benzodiazepine unit as shown in Formula X, wherein x"2 and η are as previously defined.

Formula X. A polymer comprising a resorcinol aryl vinegar brewing unit is produced by an interfacial polymerization method. The following method can be used to prepare a polymer comprising a benzenediol aryl ester polyester unit having no anhydride bond on the real f, wherein the first octagonal step causes the resorcinol group and the catalyst to be in water and water essence Non-mixable, Hybrid organic solvent mixture

Binding in matter. Suitable resorcinol compounds are of the formula χι :

Wherein each occurrence of R2 is independently Cl-12 alkyl, aryl, c _

Cm is aryl, alkoxy or halogen and η is 〇-4. If left* Ί石仔, the alkyl group is usually a linear alkyl group, a branched alkyl group or a cycloalkyl group, and although other positions are covered, the alkyl group is most often located ortho to the two oxygen atoms. σL 1 _ 12 炫基包118106.doc -22- 200831609 includes (but not limited to) methyl, ethyl, n-propyl, isopropyl, butyl, isobutyl, tert-butyl, hexyl, ring Alkyl, fluorenyl, fluorenyl and aryl substituted alkyl groups (including benzyl group). In a particular embodiment, the alkyl group is a methyl group. Suitable pixel groups are bromine, chlorine and fluorine. In different embodiments The value of n may range from 0 to 3, in some embodiments from 〇 to 2, and in other embodiments from 〇 to 1. In the embodiment, the resorcinol group is 2-methylisophthalene Phenol. In another embodiment, the resorcinol group is an unsubstituted benzodiazepine having 11 zero. The method further comprises combining the catalyst with the reaction mixture. The total molar amount of the catalyst may be present in various embodiments in a total amount of (ΜΠ to H) mole %, and in some embodiments it may be present in a total amount of from G. 2 to 6 mole %. Suitable catalysts include tertiary amines, quaternary ammonium salts, quaternary scale salts, hexavalent sulfonium salts, and mixtures thereof. Suitable dicarboxylic acid dinansides may comprise derivatives derived from the monocyclic portion. Illustrative examples of the aromatic dicarboxylic acid dihydrates include m-phenylenedifluoride dichloride, p-phenylenedifluoride dichloride or m-phenylenediyl dichloride and p-phenylene dibasic compound. a mixture of humans - moxibustion - σ, a thin 6 ^ _ _ may also contain aromatic bismuth-derivatives derived from the bad part - 几 躞 & ® " a bismuth compound, illustrative examples including diphenyl Two: acid: chlorine: diphenyl, dibenzoic acid dichloride and naphthalene dibasic acid dichloride: 6_dicarboxylic acid dihydrate); or ▼ contains derived from monocyclic and polycyclic A few acids - the aromatic di(tetra) dichloride of a mixture of yours and subtractives. In one embodiment, the dicarboxylic acid dioxime ^ ^ . Emulsion comprises as described in formula XII with the following: a fluorenyl dichloride and/or a p-phenylene dichloride dichloride. 118106.doc -23- 200831609

Formula XII is one or both of phenylmercapto dichloride and p-phenylenediamine dichloride. Name - In the case of i, the dicarboxylic acid dichloride contains a molar ratio of m-benzoic acid to p-dibenzoate of about 25.25-4. 〇:1 between benzodiazepines The mixture of the compound and the terephthaloyl dichloride; in other embodiments the molar ratio is about 〇·4_2·5:ι; and in other embodiments it is about 0.67-1.5:1. , carboxy hydrazine white & only provides a method for preparing the polymer described in the essay, for example, using a sulphuric acid, a second sulphur (four) (especially a live (tetra)) or a sulphonate or a partial salt. The other way around the benzene m key. A chain terminator (also sometimes referred to as a capping agent) can also be used. The purpose of adding a chain terminator is to limit the molecular weight of the polymer comprising the meta-phenylene bond member, which provides a controlled molecular weight and advantageous processability. Chain terminators are typically added when a polymer containing resorcinol arylate is not required and there is a reactive end group for further application. The polymer containing isophthalic acid may be used in solution or recovered from the solution in the absence of a chain terminator for subsequent use in, for example, copolymer formation, which may require isophthalic acid. The reactive end groups, which are typically via groups, are present on the vinegar polyacetate fragment. The chain terminator may be a mono-pane compound, a mono-deoxychloride, a monochloroformate or a combination of two or more of the foregoing. # , , , σ. Hanging, in the case of monophenolic compounds in the case of isophthalic acid and in the case of mono-chloride and / or monochloroformic acid hydrate, the chain terminator can be 0.05 to 118106.doc • 24 - 200831609 1 The amount of 〇mol is present. Suitable monophenolic compounds include monocyclic phenols such as phenol, Ci-C22 alkyl substituted phenol, p-cumyl phenol, p-tert-butyl phenol, hydroxy diphenyl; monophenol monoether (such as Alkoxyphenol). The alkyl-substituted phenol includes a branched alkyl group having 8 to 9 carbon atoms as described in U.S. Patent No. 4,334,053. In some embodiments the monophenolic chain terminators are phenol, p-cumylphenol and resorcinol monobenzoic acid vinegar. Suitable monocapric acid chlorides include monocyclic monocarboxylic acid chlorides such as benzoquinone chloride, benzamidine chloride substituted with C^C:22 alkyl group, toluene chloride, halogenated substituted formazan, Bromobenzoquinone chloride, cinnabarin chloride, 4-nadimidobenzoyl chloride, and mixtures thereof; poly% monocapric acid chloride, such as chlorobenzene trimellitic anhydride and naphthalene醯 chlorine; and a mixture of monocyclic and polycyclic monocarboxylic acid chlorides. A gasification of an aliphatic mono-acid with up to 22 carbon atoms is also suitable. Chlorides of functionalized aliphatic monocarboxylic acids such as acrylonitrile chloride and methacrylium chloride are also suitable. Suitable monochloroformates include monocyclic monochloroformates such as phenyl chloroformate, alkyl substituted phenyl chloroformate, phenyl p-cumyl chloroformate, toluene chloroformate and mixtures thereof. The chain terminator may be combined with resorcinol, may be included in the dicarboxylic acid dichloride solution or may be added to the reaction mixture after the precondensate is produced. If a monocarboxylic acid chloride and/or a monochloroformate is used as the chain terminator, it is often introduced together with the dicarboxylic acid dichloride. The chain terminators may also be added to the reaction mixture at a time when the chloride of the dicarboxylic acid has substantially reacted or the reaction is complete. If a phenolic compound is used as the chain terminator, it may be added to the reaction mixture during the reaction in an embodiment 118106.doc • 25·200831609, or in another embodiment it may be in resorcinol with acid The reaction between the dichlorides is added to the reaction mixture before the start of the reaction. When a precondensate or oligomer containing a hydroxy terminal resorcinol arylate is prepared, a chain terminator may be absent or only present in minor amounts to help control the molecular weight of the oligomer. In another embodiment, a branching agent such as a trifunctional or higher functional carboxylic acid chloride and/or a trifunctional or higher functional phenol may be included. If included, the branching agents can be used in an amount of from 0. 005 to 1 mol%, based on the dicarboxylic acid dichloride or resorcinol used, respectively. Suitable branching agents include, for example, difunctional or higher functional acid chlorinated chlorides such as trimesic acid triacid chloride, 3,3',4,4'-benzophenone tetracarboxylic acid tetrachloride , 1,4,5,8-naphthalenetetracarboxylic acid tetrachloride or benzenetetracarboxylic acid tetrachloride) and trifunctional or higher functional phenols (such as 4,6-dimethyl-2,4,6-three -(4-hydroxyphenyl)-2-heptane, 4,6-dimercapto-2,4,6-di-(4-pyridylphenyl)-heptane, ι,3,5-tri- (4-hydroxyphenyl)-benzene' 1,1,1-di-(4-hydroxyphenyl)-ethane, tris-(4-hydroxyphenyl)-phenylmethane, 2,2-bis-[ 4,4-bis-(4-hydroxyphenyl)-cyclohexylpropane, 2,4-dioxa-4-hydroxyphenylisopropyl)-phenol, tetra-(4-hydroxyphenyl) decane, 2 , 6_bis-(2-hydroxy-5-methylbenzoinyl-methylphenol, 2-(4-hydroxyphenyldihydroxyphenyl)-propane, tetra-(4-[4-hydroxyphenylisopropyl) a phenolic branching agent and an isophthalic acid moiety, which may be first introduced into the phenolic branching agent, 1,4-bis-[(4,4-dihydroxytriphenyl)methyl]-benzene. At the same time, the acid chloride branching agent is co-introduced with the acid monogas. In an embodiment thereof, the article of manufacture comprises The method produces and is substantially free of the thermal stability of at least two of the bond types of the bondage. 118106.doc -26- 200831609 diphenol aryl ester polyester. In a particular embodiment, the polymerization The ester comprises a dicarboxylic acid residue derived from a mixture of isophthalic acid and terephthalic acid as defined by formula XIII:

Wherein R2 is independently Ciu alkyl, CpC24 aryl, alkylaryl, alkoxy or self at each occurrence, and m is greater than or equal to about 5. In various embodiments, η is zero and m is from about 10 to about 3 Torr. The molar ratio of isophthalic acid to the present invention is about G in the embodiment, about 〇·4_2·5:1 in another embodiment, and about Ο· in another embodiment. "·1·5··1. Substantially free of wild keys means that when the polymer is heated at a temperature of about 28 〇 rh. c for five minutes, the polyesters show an increase in molecular enthalpy in one embodiment. Up to 30% and less than in another embodiment. Also included is an article containing resorcinol, which has a total of US$5,916,997. The soft block fragments disclosed herein. (4) (4) The county segments are composed of non-aromatic monomer units. These non-aromatic monomer units are generally aliphatic and are known to impart soft block-containing The polymer is flexible. The copolymer includes copolymers of IX, XIV and XV structural units. · -丨.lXf- R2〇

Formula IX 118106.doc •27- 200831609 ο ο ΛΖΛ

Formula XV Formula XV wherein R2 and η are as previously defined, ζ1 is a divalent aryl group, R3 is a q-cardo-chain alkylene group, (:3·1() branched alkyl or C4_1G ring or a bi-extension ring Alkyl, and r4 and R each independently represent a human or -ch2-o-, wherein formula XV represents from about 1 to about 45 mole percent of the ester linkage of the polyester. Other embodiments provide a composition wherein the formula In some embodiments, it comprises from about 5 to about 40 moles per mole of the ester linkage of the polyester, and in other embodiments from about 5 to about 20 mole percent of the ester linkage of the polyester. Another embodiment A composition is provided, wherein in one embodiment R3 represents C^4 linear alkyl or cw cycloalkyl, and in another K embodiment, R represents Cno linear alkyl or ^--extension ring Alkyl. Formula xiv represents an aromatic dicarboxylic acid residue. The divalent aryl group of the formula χιν can be derived from a suitable dicarboxylic acid residue as defined above in various embodiments, and is included in some implementations. U-phenylene, phenyl or phenylene or a combination of two or more of the foregoing groups. In various embodiments, ζ1 comprises or is equal to about 40 mole % of 153 phenyl. Containing soft block chains In a different embodiment of the copolyester of the member, n in the formula ι is zero. In another embodiment, the resorcinol-based polyarylate may be embedded with a resorcinol-containing aryl ester. The block copolymerization of the combination of the segment segment and the organic carbonate block segment is intended to be a carbonic acid. The copolymer contains m-phenylene aryl vinegar linkage 118106.doc -28- 200831609 The fragment of the member is substantially free of anhydride linkage. Substantially free of anhydride linkage means that when the copolyestercarbonate is heated at a temperature of about 28 Torr to 290 ° C for five minutes, the copolyestercarbonate exhibits a molecular weight reduction of less than 1 在一 in one embodiment. /0 and in another embodiment the molecular weight is reduced by less than 5%. The carbonate post-stage fragment contains carbonic acid derived from the reaction of a bisphenol with a carbonate which forms a substance which produces a polyestercarbonate copolymer, such as carbonium chloride. For example, the resorcinol polyarylate carbonate copolymer may comprise the reaction product of isophthalic acid with terephthalic acid, resorcinol and bisphenol A with carbon ruthenium chloride. Resorcinol polyphthalate reverse ester copolymer prepared by minimizing the number of acid ester bonds This method forms a aryl polyester block by, for example, pre-reacting isophthalic acid with a bis-acid, and then reacting the block with a bisphenol and a carbonate to form a polycarbonate portion of the copolymer. Best effect, between the resorcinol polyester carbonate

Approximately 75 mole % of the bond of the benzenediol or even up to about 9 〇 or 100 mole % of the REC.

And R6 is a divalent organic group:

Formula XVI 118106.doc -29- 200831609 The arylate block has a degree of polymerization (Dp) represented by m, in one embodiment Dp is greater than or equal to about 4, and in another embodiment, greater than or equal to, in another embodiment In the embodiment, it is greater than or equal to about 2 Torr, and in the re- (4) is about Μ to about 150. The Dp of the organic carbonate block represented by ρ is greater than or equal to about 2 in one embodiment, from about 1 Torr to about 2 Torr in another embodiment, and from about 2 to about 200 in yet another embodiment. . The block distribution can provide a copolymer having any desired ratio of aromatic vinegar blocks to carbonate blocks. In general, the aryl ester embefth content is from about 10 to about 95 weight percent in one embodiment relative to the total weight of the polymer and from about 5 to about 95 weight percent in another embodiment. Although a mixture of isophthalic acid ester and terephthalic acid ester is illustrated in Formula XVI, the dicarboxylic acid residue in the aryl ester block may be derived from any suitable dicarboxylic acid residue (as defined above) or suitable A mixture of dicarboxylic acid residues, including dicarboxylic acid residues derived from I guanidine diacid dichloride (so-called "soft block" fragments). In various embodiments, n is zero and the arylate block comprises a dicarboxylic acid residue derived from a mixture of isophthalic acid and a terephthalic acid residue, wherein the isophthalate and the para-xylene are The molar ratio of the acid ester is from about 0.25 to 4.0:1 in one embodiment, from about 0.4 to 2.5:1 in another embodiment, and from about 〇.67 to 15 in yet another embodiment: 1. In the organic carbonic acid S block, each of R6 is independently a divalent organic group at each occurrence. In various embodiments, the group comprises a dihydroxy-substituted aromatic fumes and the total number of groups in the polymer is greater than or equal to about 60 Å/〇 as an aromatic organic group and the remainder are aliphatic, alicyclic Family or aryl. Suitable R6 groups include the exophenyl, paraphenyl, 4,4,-biphenyl, 4,4,-bis(3,5-dimethylphenyl, 2,2-bis (4) -Phenyl)propane, 6,6,-(3,3,3,,3,_四甲118106.doc -30- 200831609 基-1,1,·螺二ΠΗ^满基如似基目, For example, the name or chemical formula of the formula (10) or the formula (the group of the aromatic hydrocarbons of the dihydroxy-substituted aromatic hydrocarbons of the country) is uncleared - some of the solid (four) W are each an aromatic organic group. And in the formula XVII group: /, his embodiment Α 1 - Υ - a2--

Wherein Α1 and Α2 are each a monocyclic divalent aryl group, and γ is a bridging group in which the * atom separates Α1 from Α2. In the formula χνι, 5 固石反, s ^ . ^ A , 2 The free valence bond of Bachuan A is in the position or alignment between γ ^ and a. R6 has the formula χνπ compound is double, and for the sake of brevity, too + 士女古..., Qiaomen ice sees, sometimes used in this article, the term bisphenol, to mean the azole-based substituted aromatic hydrocarbon. However, it should be understood that this type of non-bisphenol compound can also be utilized as appropriate. In the formula XVII, 'AjA2itf is an unsubstituted phenylene group or a substituted derivative thereof'. The illustrative substituent(s) are alkyl, alkenyl and halogen (especially bromine). In the examples, the unsubstituted phenylene group is preferred. Both A1 and W are often p-phenylene, although both may be o- or m-phenyl, or one may be o- or meta-phenyl and the other be p-phenyl. The bridging group Y is a bridging group in which one or two atoms separate A1 from A2. In a particular embodiment, the '- atoms separate ^ from ^. Illustrative groups of this type are -0-, -S_, _80_ or _§〇2·, methylene, cyclohexylmethylene, 2-[2.2.1]-bicycloheptylmethylene, Ethyl, isopropylidene, pentylene, cyclohexylene, cyclopentylene, cyclopentylene, ruthenium, and the like. 118106.doc -31- 200831609 In some embodiments, an alkylene group (commonly referred to as "alkylene") is preferred. However, unsaturated groups are also included. In some embodiments, the bisphenol is 2,2-bis(4-hydroxyphenyl)propane (bisphenol_A or bPA) wherein hydrazine is isopropylidene' and A and A are each a pendant phenyl group. Depending on the age at which the moles present in the reaction mixture are present, the R6 in the carbonate segment can comprise, at least in part, a resorcinol group. In other words, in some embodiments, the carbonate segment of Formula X can comprise a combination of a resorcinol group and at least one other dihydrocarbyl-substituted aromatic hydrocarbon. Including di-segment, triblock and multi-block copolyestercarbonates. The chemical bond between the block comprising the meta-phenylene group and the block comprising the organic carbonate chain member may comprise at least one of the following: 0) an appropriate diterpene acid residue of the aryl group and the organic carbonic acid The ester bond between the oxime-116-oxime groups of the ester group, for example as generally illustrated in formula XVIII, wherein the ruler 6 is as previously defined:

a carbonate bond between the diphenyl phenolic residue of formula VIII and (b) and the gas of the organic carbonate group c=〇)-〇-yl group, as shown by the formula χιχ, wherein R2 and η As previously defined:

Formula XIX 118106.doc -32- 200831609 In one embodiment, the copolyestercarbonate is substantially composed of a carbonated vinegar bond between the resorcinol aryl group and the organic carbonate block. Segment copolymer composition. In another embodiment, the copolyestercarbonate consists essentially of a triblock carbonate-ester-carbonate copolymer having a carbonate linkage between the resorcinol arylate block and the organic carbonate endblock. . Copolyestercarbonates having a carbonate linkage between the thermally stable resorcinol arylate block and the organic carbonate block are typically comprised of one to one less hydroxyl end moiety and one in another in one embodiment In the examples, a resorcinol aryl ester-containing polymer containing at least two hydroxyl terminal moieties was prepared. The average molecular weight of the oligomers is generally from about 1 Torr to about 40,000 in one embodiment, and from about 15, 〇〇〇 to about 3 Å, (10) 〇 in another embodiment. The thermostable copolyester can be prepared by reacting the stilbene-containing aryl ester-promoting polymer with carbon ruthenium chloride, a chain terminator, and a dihydroxy-substituted aromatic hydrocarbon in the presence of a catalyst such as a secondary amine. Carbonate. In one example, the article may comprise a resin selected from the group consisting of polysulfone, poly(ether sulfone), and poly(ether phenyl ether sulfone), and mixtures thereof; polyoxyxylene copolymers and resorcinol-based A blend of a polyarylate (wherein greater than or equal to 5 mole % of the aryl polyester linkage is derived from an aryl ester linkage of resorcinol). The amount of meta-phenylene-based polyarylate used in the polymer blends used to make up the article varies widely depending on the end use of the article. For example, when the article is used for the end use of (iv) heat or increasing the time to reach the exothermic peak, the amount of polymer containing isophthalic acid vinegar can be maximized to reduce the exotherm and prolong the time to reach the exothermic peak. In some instances, resorcinol-based polyaryl esters can be included in the polymer blend! To approximately 5 〇 118106.doc • 33 - 200831609 wt%. Some important compositions will have from about 10 to about 50% by weight, based on the total weight of the polymer blend, of a resorcinol-based polyarylate. In another embodiment, an article comprising a polymer blend comprising: a) from about 1 to about 99% by weight of polylithic wind, poly(10) stone wind), and poly(phenylene) or mixtures thereof; b) from about 0.1 to about 30% by weight of the polyoxyloxy copolymer; c), 'spoon 99 to about 1% by weight of resorcinol-based polyarylate containing greater than or equal to about 50 moles % derived from the resorcinol linkage; d) from 0 to about 20% by weight metal oxide, wherein the weight percent is relative to the total weight of the polymer blend. In other aspects, the article comprising the following polymer blends is encompassed: a) 々50 to about 99% by weight of polysulfone, poly(ether sulfone), poly(phenylene ether sulfone) or mixtures thereof; b) from about 0.1 to about 10% by weight of the polyoxyloxy copolymer; c) from 1 to about 50% by weight of resorcinol-based polyarylate resin containing greater than or equal to about 50 moles % derived from the resorcinol linkage; d) 〇 to about 20% by weight metal oxide; and e) 〇 to about 2 weight. /. A phosphorus-containing stabilizer. PEI, PI, PEIS and mixtures thereof; polyoxyalkylene copolymers; and high Tg blends of aryl polyester resins based on resorcinol. For example, t-oxygen poly- s-imine copolymer or poly-xyloxy polycarbonate copolymer ♦ 矽 oxy-copolymer with high glass transition temperature (Tg) polyimine (PI), poly-imine (PEI) The combination of polyether sulfoxide (PEIS) resin and resorcinol has a surprisingly low exotherm and improved solvent resistance. 118106.doc -34- 200831609 The aryl polyester derived from resorcinol may also be a copolymer containing a bond other than resorcinol, such as resorcinol-bisphenol-A copolyester carbonic acid vinegar. For best results, the resorcinol ester content (REC) should be greater than about 50 mole percent of the polymer bond derived from resorcinol. Higher REC may be preferred. In some instances, REC is required to account for more than 75 mole percent of the bond derived from resorcinol, or even up to 90 or 1 mole percent.

The amount of the resorcinol-containing polymer used in the flame retardant blend can vary widely, using any amount effective to reduce exotherm, increase the time to peak exotherm, or improve solvent resistance. In some examples, the resorcinol containing polymer can comprise from about i% by weight to about 80% by weight of the polymer blend. Some of the important compositions will have 1 G-5 (%) of the predominantly meta-phenylene polyester. In other examples, the polyether quinone or polyether oxime sulfone admixture with the high REC copolymer will have a single glass transition temperature (Tg) of from about 150 to about 10 °C. The resorcinol-based polyaryl vinegar resin should contain greater than or equal to about 50 moles of (tetra)benzene di-energy benzene 4 and a aryl carboxylic acid or dicarboxylic acid derivative suitable for forming an aromatic vinegar bond ( For example, a unit derived from the reaction product of a carboxylic acid dentate, a carboxylic acid hydrazine, and a cerium hydride.曰For other polymer inventions, the resorcinol-based polyarylate is used in the thermally stable meta-phenylene aryl vinegar block and the organic vinegar block and the carbonated vinegar-bonded vinegar carbonate is usually It is prepared by using an oligomer of at least one other embodiment containing at least two di- aryl vinegars in an embodiment. The weight of these oligomers is: ::::: 118106.doc •35- 200831609 Often in the embodiment - about! 〇, 〇〇〇 to about 4 〇, _, and in another embodiment is scoop 15, GGG to about 3G, GGG. The oligomers containing isophthalic aryl vinegar can be prepared by reacting the chloro, at least-chain, and the at least one dihydroxy-substituted aromatic hydrocarbon in the presence of a catalyst such as a tertiary amine. Thermally stable copolyestercarbonate. In the example - the polymer blend having improved flame retardancy comprises a resin selected from the group consisting of polyimine, polyether oximine, polyether sulfoxide, and mixtures thereof, a group of resins, polyoxyl copolymer And the resorcinol-based aryl polyester (wherein greater than or equal to 5 〇 mol% of the aryl poly Lacang sheng from the benzoin oxime bond) will be the term ''polymer bond' Or a "polymer bond" is defined as the reaction product of at least two monomers forming a polymer. In some examples, a hydrogen atom to carbon atom ratio (H/C) of less than or equal to about (d) is used. Poly-imine, poly-longine, polylysine, and mixtures thereof are important. Polymers with a higher hydrogen content (ie, a lower ratio of hydrogen to carbon) are often used. Shows improved FR performance. These polymers have low fuel values and can release less energy when burned. They can also be burned by the tendency to form an insulating coking layer between the polymerized fuel and the ignition source. Irrespective of mechanism or mode, it has been observed that these polymers with low H/C ratio have High flame resistance. In some examples, the 'H/C ratio may be less than 〇85. In other examples, in order to obtain a polymeric structure having sufficient flexible bonds to achieve melt processability, H/C greater than about is preferred. The H/C ratio of a given polymer or copolymer can be determined from the chemical structure by counting carbon and hydrogen atoms independently of any other atom present in the chemical repeating unit. σ 118106.doc -36 - 200831609 In some cases, the flame retardant polymer blend and articles made therefrom will have an exotherm of less than about 65 kW_min/mk for 2 minutes. In other examples, the exothermic peak will be less than about 65 kW/m2e to reach the exothermic peak for greater than the time. Approximately ^ minutes is also a beneficial aspect of certain compositions and articles made therefrom. In other compositions, the peak of the exothermic peak of about 4 minutes. In some compositions, polyimine , polyether quinone imine, poly bond quinone imine; : wind or a mixture thereof with polyoxyl oxy-copolymer and aryl glyceride containing greater than or equal to about 50 moles φ / 生 from the bond of benzodiazepine The blend of resins will be transparent. In one embodiment, by ASTM method m The % transmittance at a thickness of 2 mm of the conjugate of the 〇〇3 measurement is greater than about 5%. In other examples, the turbidity % of the transparent compositions measured by ASTM method D1G()3 Will be less than about 25. In other embodiments, the % transmittance will be greater than about 6% and the % haze will be less than about 20%. In yet another example, the composition and articles made therefrom The light transmittance will be greater than about 50% and the haze value is less than about 25%, and the exothermic peak is less than or equal to 50 kW/m2. • In the flame retardant blend, based on the total weight of the composition, the polyimine, The poly-imine, the polyether sulfoxide or a mixture thereof may be present in an amount of from about i to about 99% by weight. Within this range, polyimine, polyetherimine, polyether sulfoxide or The amount of the mixture may be greater than or equal to about 2% by weight, more specifically greater than or equal to about 50% by weight, or even more specifically greater than or equal to about 70% by weight. In another embodiment, the composition comprises a flame retardant polymer blend as follows: a) from about 1 to about 99 weight. /. The polyether oximine, polyether oxime imide mill and mixtures thereof, H8106.doc -37- 200831609 b) from about 99 to about 1 by weight. / ❶ aryl polyester resin containing greater than or equal to about 50 mole % of a bond derived from resorcinol, e) from about 0.1 to about 30 weight percent of a polyoxyloxy copolymer, d) about Up to about 20% by weight of the metal oxide, wherein % by weight is based on the total weight of the composition. V* In other aspects, a combination comprising the following flame retardant polymer blends a) from about 50 to about 99% by weight of a polyether quinone imine or a polyether quinone sulfoxide resin, b) from about 1 to about 50 weight. /. a resorcinol-based polyarylate containing greater than or equal to about 50 mole % of a resorcinol-derived linkage, c) from about 0.1 to about 1 weight percent of a polyoxyloxy copolymer, d) from about 0 to about 20 by weight. /. a metal oxide, and e) from 0 to about 2% by weight of a scaly stabilizer. Polyimine has the general formula (XX):

(Form XX), where a is greater than 1, large, or more specific

118106.doc wherein a is greater than 1, typically from about 10 to about 1 Torr or greater from about 10 to about 500; and wherein v is a tetravalent bond, which hinders the synthesis or use of the polyimine No limit. (but not limited to): (a) having from about 5 to about 50 carbon atoms -38 to 200831609 Preferred linkers include, but are not limited to, an unsaturated alkyl group; or a combination thereof (XXI) a tetravalent aryl group, such as )〇c,»〇c, (Formula XXI) where W is selected from -〇-, -s-, -c(0)-, S〇2-, -so...-cyH2y_(y

a divalent group of a group having an integer of from 1 to about 8 and a fluorinated derivative thereof (including a perfluoroalkylene group), or a group of the formula -0-Z-0-, wherein a divalent bond Or _〇·Ζ-0-base is at the 3, 3, 3, 4, 4, 3 or 4, 4' position, and wherein the lanthanide is as defined above. Ζ can include an exemplary divalent group of formula (ΧχΐΊ)

c(ch3)2 h3c

(Formula XXII) 118106.doc -39- 200831609 R7 in formula (XX) includes, but is not limited to, substituted or unsubstituted divalent organic groups, such as (a) having from about 6 to about 24 An aromatic hydrocarbon group of a carbon atom and a halogenated derivative thereof; (b) a linear or branched alkylene group having from about 2 to about 20 carbon atoms; (c) a cycloalkane having from about 3 to about 24 carbon atoms a base, or (d) a divalent group of the formula (VI):

Where Q is as defined above. (Formula VI) Some classes of polyamidiamines include polyamidoximines, polyetherimine sulfones, and polyetherimines, especially those having melt processability known in the art. Imines, such as the polyether oximines described in U.S. Patent Nos. 3,803,085 and 3,905,942. The polyetherimide resin may comprise more than one, typically from about 1 Torr to about 1 Torr or more, or, more specifically, from about 1 Torr to about 5 Å (结构ιπ) structural units:

(Formula XXIII) wherein Τ is a -〇- or a formula -0_Ζ-0_ group, wherein the divalent bond or the _〇_ζ_〇- group is at 3,3,3,4,4,3, or 4, 4, position, and 2 of them; as defined above. In one embodiment, the polyimine, polyetherimide or polyether amide may be a copolymer. The mixture is made of a mixture of polyimine, polyetherimide or polyimine. The polyether can be prepared by any method well known to those skilled in the art. 118106.doc -40- 200831609 Amine, including an aromatic bis(ether anhydride) of formula (XVIII)

Reaction with an organic diamine of formula (VII), η2ν_ρΛνη2 (formula VII), wherein hydrazine and R1 are as defined above.

Examples of specific aromatic dianhydrides and organic diamines are disclosed in, for example, U.S. Patent Nos. 3,972,9, 2 and 4,455,410. Illustrative examples of aromatic dianhydrides include: 3.3-bis[4-(3,4-dicarboxyphenoxy)phenyl]propane dianhydride; 4,4'-bis(3,4-dicarboxyphenoxy) Diphenyl ether dianhydride; 4,4 bis(3,4-dimercaptophenoxy)diphenyl sulphate; 4,4'-bis(3,4-dicarboxyphenoxy)diphenyl Anthrone ketone dianhydride; 4,4'-bis(3,4-dicarboxyphenoxy)diphenyl sulfone dianhydride; 2,2-bis[4-(2,3-dicarboxyphenoxy)phenyl] Propane dianhydride; 4,4'-bis(2,3-dicarboxyphenoxy)diphenyl ether dianhydride; 4,4'-bis-P,3-dicarboxyphenoxy)diphenyl sulfide dianhydride; 4.4-bis(2,3-diprotective phenoxy)benzophenone di-hepatic; 4,4'-bis(2,3-dicarboxyphenoxy)diphenyl sulfone dianhydride; 4-(2, 3-dicarboxyphenoxy)_4,_(3,4-dicarboxyphenoxy)diphenyl, hydrazine propane dianhydride; 4-(2,3-dicarboxyphenoxy)-4,_(3, 4_Dicarboxyphenoxy)diphenyl ether dianhydride; 118106.doc •41 - 200831609 4-(2,3-diweiphenoxy)-4,3,4. Anhydride phenoxy)diphenyl Ether ether 4-(2,3-dicarboxyphenoxy)_4,_(3, cardiodicarboxyphenoxy)dibenzoic acid dimium; and 4-(2,3-diphenylbenzene Μ·_(3,4-dico-phenoxy)diphenyl phenolic dianhydride, and various mixtures thereof. Another type of aromatic bis(pentahydride) included in the above formula (XVIII) includes (but is not limited to) Where Τ is the formula (XXIV):

-0~〇~(Η〇>~〇- (Formula XXIV) and the ether bond (for example) is preferably a compound at a position of 3, 3, 3, 4, 4, 3, or 4, 4, and a mixture, and wherein the Q system is as defined above.

Any diamine based compound can be utilized. Examples of suitable compounds are ethylenediamine, propylenediamine, trimethylenediamine, diethylidenetriamine, triethylidenetetramine, hexamethylenediamine, heptanediamine, octanediamine, decanediamine, hydrazine. Diamine, oxime-dodecanediamine, 1,18-octadecanediamine, 3·methylheptanediamine, 4,4-dimethylheptanediamine, 4-methylnonanediamine, 5_Methylguanidine diamine, 2,5-dimethylhexamethylenediamine, 2,5-dimethylheptanediamine, 2,2-dimethylpropanediamine, fluorenyl-fluorenyl-bis (3· Aminopropyl)amine, 3-methoxyhexamethylenediamine, 1,2-bis(3-aminopropoxy)ethane, bis(3-aminopropyl) sulfide, ι,4-ring Hexamethylenediamine, bis-(4-aminocyclohexyl)methane, m-phenylenediamine, p-phenylenediamine, 2,4-diaminotoluene, 2,6-diaminotoluene, m-diphenylene diamine , p-diphenylene diamine, 2-methyl-4,6-diethyl-1,3-phenylenediamine, 5-methyl·4,6-diethyl-1,3-phenylenediamine, Benzidine, 3,3'-dimethylbenzidine, 3,3'-dimethoxybenzidine, 1,5-diaminonaphthalene, bis(4-aminophenyl)methane, bis(2- Chloro-4-amino-3,5-diethylbenzene 118106.doc -42- 200831609 base) methane, double (4- Aminophenyl)propane, 2,4-bis(p-amino-t-butyl) toluene, bis(p-amino-t-butylphenyl)ether, bis(p-methyl-o-aminophenyl) Benzene, bis(p-methyl-o-aminopentyl)benzene, 1,3-diamino-4-phenylpropene, bis(4-aminophenyl) sulfide, bis(4-amine Phenyl)sulfone and bis(4-aminophenyl). Mixtures of such compounds can also be used. Preferred diamine compounds are aromatic diamines, especially m-phenylenediamine and p-phenylenediamine, decyldiphenylamine and mixtures thereof.

In one embodiment, the polysinoin resin comprises a structural unit according to formula (XVII) wherein R is each independently a para-phenyl or an exo-phenyl or a mixture thereof, and hydrazine is a divalent formula (XXV) Group:

A number of processes for preparing polyimines, especially polyetherimine, are disclosed in U.S. Patent Nos. 3,847,867, 3,852,242, 3,803,085, the disclosures of which are incorporated herein by reference. The patents mentioned are used to teach the general and specific methods of preparing polyimine in an illustrative manner. As measured by American Society for Testing Materials, (ASTM) D1238 at 340-370 ° C, using a weight of 6.6 kg (kg), polyimine, polyether quinone and polyether sulfoxide The melt index can range from about 0" to about 10 grams per minute (g/min). In one embodiment, the polyether quinone imine resin has a weight average molecular weight ("¥¥) of about 1 〇, 〇〇〇 to about 150,000 gram, as measured by gel permeation chromatography using polystyrene standards. In another embodiment, the polyether quinone imine has a Mw of from 20,000 to 60,000. As measured at 19,106.doc -43 · 200831609 at 25 ° C in m-nonylphenol, The intrinsic viscosity of the polyetherimide resins is typically greater than about 0.2 liters per gram (dl/g) or, more specifically, from about 0.35 to about 0.7 dl/g. ASTM D5205n Standard Classification System for Polyetherimide (PEI) An example of some of the polyetherimine used in the blends described herein is listed in Materials". The length of the fragment of the fragment of the copolymer can be any effective length. In some instances, it can be 2 to 70 oxoxane repeating units. In other examples, the oxoxane block length can be from about 5 to about 30 repeating units. In many instances, dimethyl methoxy oxane can be used. The ether quinone imine copolymer is a specific example of a usable alkane copolymer. US patent Examples of such fluorinated polyether oximines are shown in U.S. Patent Nos. 4,404,350, 4,8,8,686, and 4,690,997. In one example, they can be prepared analogously to the process for preparing polyetherimine. a polyether oxime oxane, but a part or all of the organic diamine reactant is substituted, for example, by an amine-terminated organoxanthene of formula XXII, wherein g is an integer having from 1 to about another value, in some other In one embodiment, g can be from about 5 to about 30, and Han, an aryl, alkyl or arylalkyl group having from about 2 to about 20 carbon atoms.

(Formula XXII) Some polyether quinone imine oxiranes can be formed by reacting a mixture of an organic diamine or a diamine of the formula XIX with a hydrazine π amine end organic oxyhydrogenation with one or more dianhydrides of the formula XVIII. The diamine component can be physically mixed before reacting with the dianhydride 118106.doc -44·200831609' thus forming a substantially random copolymer. Alternatively, a block or alternating copolymer can be formed by selectively reacting hydrazine and XXII with a dianhydride to prepare a subsequent co-reacting polyimine. In another example, the oxime used to prepare the phthalimide copolymer can have an anhydride rather than an amine functional end group, as described, for example, in U.S. Patent No. 4,404,350. In one example, the oxoxane polyether oxime copolymer may be of the formula wherein T, R' and g are as described above, η has a value of from about 5 to about 1 Torr, and Ar has from 6 to Approximately 36 carbon aryl or alkyl aryl groups.

(Formula XXIII) In some of the anthraquinone polyether oximines, the amine component of one of the oxoxane polyether oxime copolymers may contain from about 20 mole % to about 50 mole % of the χχ 胺 amine end organic A oxetane and from about 50 to about 80 mole percent of the formula XIX organic diamine. In some of the oxy-oxygenated copolymers, the oxane component contains from about 25 to about 40 mole percent of the amine or anhydride terminal organooxane. c. High Tg phase separated polymer blend. Also disclosed herein are phase separated polymer blends comprising: a) a polyaryletherketone (PAEK) selected from the group consisting of polyaryletherketones, polyarylketones, polyetherketones, and polyetheretherketones, and combinations thereof. And b) a mixture of polyether sulfoximine sulfone (PEIS) having a aryl sulfone group-containing bond of greater than or equal to 5 〇 mol%. Phase separation means that PAEK and PEIS are intermixed as independent chemical entities, which can be separated using standard analytical techniques (eg microscopy, differential scanning calorimetry or 118106.doc -45-200831609 dynamic mechanical analysis). A is physically separated to show at least two paraplegia, > different polymer phases, one of which comprises an anthraquinone resin and one of which comprises a PEIS resin. In one such example, each phase will contain greater than about 80% by weight of the respective resin. In the case of 发/, the blend will form separate distinct regions, sized and helmeted, having a size of from about 0.1 to about 50 microns, and in other cases the size of the region is about (U to about 2G microns). The size of the area refers to the longest line size as in the microscopic method: the phase separation blend may be completely immiscible, or

Partial miscibility is shown but must be as follows: • One-to-one performance • The blend shows two or more distinct polymer phases that are at least solid. The ratio of PAEK to PEIS can be any ratio that results in improved properties of the blend compared to any individual resin (i.e., better or worse depending on the end use application). The ratio expressed in parts by weight may be determined depending on the final application and the desired characteristics to be improved. The ratio can range from 15:85 to 85:15 or even 25:75 to 75:25. Depending on the application, the ratio can range from 40:60 to 60:40. The skilled artisan will appreciate that changing pAEK to pEIS2 is any real ratio that falls within the stated range, depending on the desired result. The characteristics of the final blend can be adjusted by varying the composition ratio including thermal deformation temperature and load capacity. For example, in one embodiment, the polyetherimine sulfonate may be present in any amount effective to modify (i.e., improve by increasing) the PAEK blend to its individual component loading capacity. In some examples, the PAEK may be present in an amount from about 30 to about 70% by weight of the total mixture, and the amount of PEIS may be from about 70 to about 30% by weight, wherein the weight percent is relative to the combined weight of PAEK and PEIS. In some embodiments, the heat distortion temperature (HDT) of the phase separated polymer blend is measured by ASTM method D5418 at 3.2 Mpa (66 118106.doc -46 - 200831609 psi) with a 3.2 mm rod. Greater than or equal to about 170 ° C. In other examples, at 0.46 MPA (66 psi), the HDT will be greater than or equal to 200 °C. In other examples, the load capacity of PAEK-PEIS will be shown to be greater than or equal to about 200 of its Vicat temperature by ASTM method D1525 at 50 Newtons (N). In other instances, For example, the load capacity of the phase separated polymer blend is shown as a flexural modulus greater than or equal to about 200 megapascals (MPa) as measured by ASTM method D5418 at 3.2 ° C with a 3.2 mm rod. The phase separated polymer blend can be prepared by mixing a quantity of PAEK with a quantity of PEIS in a molten state. The two components can be mixed by any method known to the skilled person to result in a phase separation blend. Such methods include extrusion, sintering, and the like. The term polyaryletherketone (PAEK) as used herein encompasses several types of polymers containing an aromatic ring (usually a benzene ring) which is primarily bonded by a different sequence of a ketone and an ether group. Examples of the PAEK resin include polyether ketone (PEK), polyetheretherketone (PEEK), polyether ketone ether ketone ketone (PEKEKK), and polyether ketone ketone (PEKK), and copolymerization containing the same and a blend thereof Things. The PAEK polymer may comprise a monomer unit containing an aromatic ring (usually a benzene ring), a keto group and an ether group in any sequence. Other linkage groups may be present at low levels (e.g., less than 10 mole percent) as long as the properties of the PAEK resin are not fundamentally altered. For example, several highly crystalline polyaryletherketones having a melting point above 300 °C can be used in the phase separation blend. Examples of such crystalline polyaryletherketones are shown in structures XXVI, XXVII, XXVIII, XXIX and XXX. 118106.doc -47- (XXVII) (XXVI)200831609

(Χχνίΐι) (XXIX)

(XXX) The general characteristics are included. Applicable to this woman > Moss Β ¥5t 4 people ι,,, ο Other examples of daily polyetheretherketone There are repeating units of the following formula (XXXI):

(XXXI) wherein Ar2 is independently a divalent aryl group selected from the group consisting of phenyl, phenyl or anthranyl, and L is independently .../(ο)..._〇-ΑΓ_ε(〇ν, _s_ _s〇2· or Direct key, and h is an integer having a value from ο to about 10. The skilled artisan should be aware of well-developed and sufficient patent subjects and other literature for the formation and properties of polyaryletherketones. For example, _ also early works ( For example, U.S. Patent No. 3,065,205, the disclosure of which is incorporated herein by reference to U.S. Pat. No. 3, 065, 205, which is incorporated herein by reference. Progress in this category is reached in 175,175, which is shown, for example, by activation of 118106.doc -48- 200831609, a nucleophilic aromatic substitution reaction of an alcohol or a salt thereof

The method for preparing a polyaryl ketone comprises heating a mixture of a substantially homologous bismuth (usually in the form of its double-aged salt) with a bis-benzene type compound (or in other cases, a dentate compound). . In other instances, can I use this? a mixture of compounds. For example, hydrogen can be reacted with a bidentate aryl (chloro benzophenone or - fluorobenzophenone) to form a polyaryl ether ketone. Under other conditions, it is possible to polymerize, for example, a diaryl benzoyl group with an aryl cleavage such as dichlorobenzene to form a PAEK resin. In other instances, it is possible to react, for example, di-diphenyl ether: a secret aryl group with a bis(tetra) ketone such as difluorobenzophenone. In other variants, a dihydroxy compound (such as dihydroxybiphenyl or hydroquinone) having no ether linkage can be used.

Aromatic ditellites and aromatics A wide range of resins. a dihalogen compound having an ether and a ketone bond (for example, bis-(dichlorophenyl)benzophenone) is reacted. In #其实j, 彳 ^ aryl (tetra) acid or a slow acid dentate polymerizes to form a poly An aryl ether ketone. Examples of such compounds are diphenyl ether carboxylic acid, diphenyl ether carboxylic acid chloride, phenoxy-phenoxy benzoic acid or mixtures thereof. In other examples, dicarboxylic acids or dicarboxylic acids may be employed. The acid halide is condensed with a diaryl ether, for example, by reacting meta-phenylenedifluoride chloride or terephthaloyl chloride (or a mixture thereof) with diphenyl ether to form a pAEK resin. The method is described, for example, in U.S. Patent No. 4,176,222. The method comprises heating (1) substantially equimolar (^) and (bi) dihalobenzene type compound and/or (b ii) halogen in a temperature range of from 100 to 400 °C. a mixture of phenols (in which a halogen-based compound or a halogen atom is activated by a -C=〇-group at its ortho or para position) and sodium carbonate or sodium hydrogencarbonate and a second alkali metal carbonate 118106.doc -49- 200831609 Mixture of wind or %I hydrogen hydride (the second metal carbonate or bicarbonate of bicarbonate) The number of atoms is higher than the number of sodium atoms, and the amount of the second alkali metal carbonate or the stone acid hydrogenate is ·1 to 〇2 gram per gram of sodium atom, and the base having the number of atoms of the parent's office The total atom of the metal atom, the alkali metal carbonate or the hydrogencarbonate is at least one alkali metal atom for each phenol group present) and the polymer is subsequently separated from the alkali metal halide.

Other polyaryletherketones can also be prepared according to the methods described in, for example, U.S. Patent No. 4,396,755. In such processes, in the presence of a fluoroalkanesulfonic acid (especially a fluorofibrate), such as: (a) a bis-acid; (b) a divalent aryl group and a mono-aromatic dicarboxylic acid; And (c) (a) reacting with the combined reactants. Other polyaryletherketones can be prepared according to the process described in, for example, U.S. Patent No. 4,398, the disclosure of which is incorporated herein by reference. The polyaryletherketone has a low viscosity of greater than or equal to about 0.4 to about 5.0 dl/g as measured in concentrated sulfuric acid at 2 5 C. The PAEK may have a weight average molecular weight (Mw) of from about 5,000 to about 15 Å, 〇〇〇 g/m〇ie. In other examples mw can be from about 10,000 to about 80, 〇〇〇 g/mole. The second resin component is a polyether phthalimide (PEIS) resin. As used herein, PEIS comprises a structural unit having the formula (VII) wherein greater than or equal to about 50 mole % of the polymer bond has an aryl group, and

Where a is greater than 1, typically from about 1 Torr to about 1 Torr or greater, or more specifically + 118106.doc -50- 200831609 is from about 10 to about 500, and V is a tetravalent bond, P m , In order to synthesize or use the conjugated sulfone ether quinone imine, it is about 5 to about 5 盆 盆 阳 阳 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 A substituted, unsaturated or aromatic monocyclic or polycyclic melon group substituted by a human body, a substituted or unsubstituted direct martial art (b) having less than about 30 carbon atoms a bond, a known or an unsaturated alkyl group; or (c) a combination thereof. Preferred bond P forms include, but are not limited to, a tetravalent aryl group of the formula (VIII), such as: ) »;, (VIII) and Wherein, in some embodiments, W is a divalent group selected from the group consisting of _8〇", s, -C(〇)-, CyH2y- (y is an integer having a value of 丨 to 5) Its self-derivative derivative (including perfluoroalkylene) or the formula _〇_D_〇_ group. The group D may comprise a residue of a bisphenol compound. For example, D can be any of the molecules shown in the formula ιχ.

Let q combine,

‘ch3, H3c Br Br CH3, and 118106.doc -51 · (IX) 200831609

c(ch3)2

The first key-W- or -O-D-O- group can be in the position of 3, 3, 3, 4, 4, 3, or 4, 4. Mixtures of the foregoing compounds can also be used. Groups which do not contain benzylic protons are generally preferred for good smelting stability. The group in which w is 2_ is indeed suggested because it is a method of introducing an aryl hydrazone bond into a polyhard quinone imine resin.

The term "polymer bond" or "a polymer bond" as used herein is defined as the reaction product of at least two monomers forming a polymer, wherein at least one monomer is a dianhydride or a chemical equivalent, The second monomer is one less than one diamine or chemical equivalent. The polymer consists of 1% by mole of such bonds. For example, a bond having a 50 mol% aryl sulfone bond Half (in moles) ι έ having at least one aryl fluorenyl group derived from a dianhydride or a diamine. Suitable dihydroxy-substituted aromatics used as a precursor to the _0-D-fluorene-group Hydrocarbons also include compounds of formula (X):

OH (X); wherein each R is independently hydrogen, chloro, hydrazine, alkoxy, aryloxy or Cl. . The monovalent hydrocarbon or hydrocarbyloxy group and R8 and the argon, aryl, alkylfluoro or Cl-3G hydrocarbyl group. Dihydroxy-substituted aromatic hydrocarbons useful as precursors to the -0-D-0- group include U.S. Patent Nos. 2,991,273, 2,999,835, 3, 〇28,365 118106.doc-52.200831609 And the compounds disclosed in the names or chemical formulas of Nos. 3, 148, 172, 3, 153, 008, 3, 271, 367, 3, 271, 368 and 4, 217, 438. Specific examples of dihydroxy-substituted aromatic hydrocarbons that may be used include, but are not limited to, bis(4-phenylphenyl)sulfone, bis(4-hydroxyphenyl) sulfide, bis(4-hydroxyphenyl)ether , bis(4-hydroxyphenyl) sulfoxide, iota, di-diphenyl, 4,4, _, aryl, 2,2-bis(4-based) hexafluoropropanone, 4 , 4·_(3 3 5_trimethylcyclohexylidene) di-, 4,4'-bis(3,5-dimethyl) di-, 1,1-bis (4-cyto-3- Methylphenyl)cyclohexane, 4,4-bis(4-hydroxyphenyl)heptane, 2,4'-dihydroxydiphenylmethane, bis(2-hydroxyphenyl)methane, double (4_jing Methyl phenyl)methane, bis(4-carbyl-5-decylphenyl)methane, bis(4-carbazino-2,6-li-methyl-3-methoxyphenyl)-methyl, 1,1-bis(4-pyridylphenyl)ethene, bis(4-hydroxyphenyl)ethane, 1,1-bis(4-hydroxy-2-chlorophenyl)ethene, 2,2-double (3-phenyl-4-hydroxyphenyl)propane, 2,2·bis(4-hydroxy-3-methylphenyl)propane, 2,2-bis(4-carbo-3-ethylphenyl) )propane, 2,2-bis(4-carbyl-3-isopropylphenyl)propane, 2,2-bis(4-hydroxy-3,5-dimethylphenyl) Propane, 3,5,3',5'-tetrachloro-4,4,-dihydroxyphenyl)propane, bis(4-hydroxyphenyl)cyclohexylmethyl; 2,2-bis(4-hydroxyl) Phenyl)-1-phenylpropane, 2,4,-dihydroxyphenyl zephyr, diprenylnaphthalene, 2,6-dipyridyl naphthalene, hydrogen storage, isophthalic acid, substituted by Cw alkyl Benzene, methyl-m-phenylene, 1,4-di-propyl-3-methylbenzene, 2,2-bis(4-hydroxyphenyl)butane, 2,2-bis(4-hydroxybenzene) 2-methylbutyring, 1,1-bis(4-hydroxyphenyl)cyclohexane, 4,4,-dihydroxydiphenyl, 2-(3-indolyl-4-hydroxyphenyl _2_(4-hydroxyphenyl)propane, 2-(3,5-dimethyl-4-trans-phenyl)-2-(4-hydroxyphenyl)propane, 2-(3-methyl-4- Hydroxyphenyl)-2-(3,5-dimethyl-4-hydroxyphenyl)propane, bis(3,5-dimethylphenyl-4-hydroxyl 118106.doc-53-200831609 phenyl) Decane, 1,1-bis(3,5-dimethylphenyl-4-hydroxyphenyl)ethane, 2,2-bis(3,5-dimethylphenyl-4-hydroxyphenyl) Propane, 2, 'bis(3,5-dimethylphenyl-4-hydroxyphenyl)-2-methylbutane, 3,3_bis(3,5-dimethylphenyl-4-hydroxyl) Phenyl)pentane, 1,1-bis(3,5-didecylphenyl-4-hydroxyphenyl)cyclopentane, 1,1-bis(3,5-dimethylphenyl-4-hydroxyphenyl)cyclohexane Alkane, bis(3,5-dimethylhydroxyphenyl) sulfoxide, bis(3,5-diindenyl-4-hydroxyphenyl) sulfone and bis(3,5-dimethylphenyl-4) Hydroxyphenyl) sulfide. Mixtures comprising any of the foregoing dihydroxy-substituted aromatic hydrocarbons may also be utilized. In a particular embodiment, a dihydroxy-substituted aromatic hydrocarbon comprising a bisphenol and a sulfone linkage is important because it is another route for introducing an aryl sulfone linkage into the polysulfone ether oxime imide resin. In other examples, bisphenol compounds free of benzyl protons are preferred for the preparation of polyether oxime oximes having higher melt stability. " In the formula (VII), the 'R group is a residue of a diamine compound or a chemical equivalent including, but not limited to, a substituted or unsubstituted divalent organic group such as (a) An aromatic hydrocarbon group having from about 6 to about 24 carbon atoms and a halogenated derivative thereof, (b) a linear or branched bond group having from about 2 to about 2 carbon atoms; (c) having about 3 to a cycloalkyl group of about 24 carbon atoms, or (d) a divalent group of the formula (XI): ^

(XI) wherein Q includes, but is not limited to, selected from _s〇2·, _〇, _s,

Cyil2y-(y is a group of divalent groups having an integer of from 1 to about 5) and a dentate derivative thereof (including a perfluoroalkylene group). In a particular embodiment, & base 118106.doc .54 _ 200831609 does not contain benzyl hydrogen. The existence of benzylated protons can be deduced from the chemical structure. In some specific embodiments, suitable aromatic diamines comprise m-phenylenediamine, p-phenylenediamine, a mixture of m-phenylenediamine and p-phenylenediamine, isomers 2-mercapto- and 5-methyl-4 ,6-diethyl-1,3-phenylenediamine or a mixture thereof, bis(4-aminophenyl)-2,2-propane, bis(2-chloro-4-isoamine·3,5-di Ethylphenyl)methane, 4,4,-diaminodiphenyl, 3,4'-diaminodiphenyl, 4,4,-diaminodiphenyl ether (sometimes referred to as 4,4'- Oxydiphenylamine), 3,4,-diaminodiphenyl ether, 3,3,-diaminodiphenyl scale, 4,4'-diaminodiphenyl sulfone, 3,4,-diamino group Diphenyl sulfone, 3,3 匕diaminodiphenyl sulfone, 4,4'-diaminodiphenyl sulfide, 3,4,-diaminodiphenyl sulfide, 4,4'-diaminodi Benzophenone, 3,4'-diaminobenzophenone, 4,4,-diaminobenzophenone (commonly known as 4,4'-methylenediphenylamine), 4,4,-bis ( 4-aminophenoxy)biphenyl, 4,4»-bis(3-aminophenoxy)biphenyl, i,% diaminonaphthalene, 3,3-dimethylbenzidine, 3 , 3-dimethoxybenzidine, benzidine, m-diphenylene diamine, bis(aminophenoxy)anthracene, bis(aminophenoxy) Benzene, 1>3_bis(3-aminophenoxy)benzene, 1,3-bis(4-aminophenoxy)benzene, 1,4-bis(4-aminophenoxy)benzene, Bis(aminophenoxy)phenylhydrazine, bis(4-(4-aminophenoxy)phenyl)sulfone, bis(4-(3-aminophenoxy)phenyl)sulfone, diamine Benzobenzidine, 3,3'-diaminobenzophenone, 4,4'-diaminobenzophenone, 2,2,-bis(4-(4-aminophenoxy) Phenyl)propane, 2,2-bis[4-(4-aminophenoxy)phenyl]hexafluoropropane, 4,4^bis(aminophenyl)hexafluoropropane, 1,3-diamine 4-isopropylbenzene, 1,2-bis(3-aminophenoxy)ethane, 2,4-bis(β-amino-t-butyl)toluene, bis(p-β-yl- O-aminophenyl)benzene, bis(p-amino-t-butylphenyl)ether and 2,4-toluenediamine. It is also possible to use two or more kinds of 118106.doc -55-200831609 amine mixture monoamine monoterpene (DDS), hydrazine (BAPS) and mixtures thereof as preferred aromatic diamine bis (amine stupid The oxybenzenes described herein may be derived from one or more aromatic diamines or chemically equivalent derivatives thereof and one or more aromatic tetra-rings (hereinafter sometimes referred to as a reactant of an aromatic tetrakisole or an aromatic tetrazoic acid or a derivative thereof capable of forming a cyclic anhydride. In addition, at least a part of one or the other of the reactants containing the aromatic diamine and the aromatic dianhydride Or at least one of each

The fraction comprises an aryl sulfone linkage such that at least 5 mole percent of the resulting polymer linkage contains at least one aryl sulfone group. In a particular embodiment, one or the other of the reactants comprising the aromatic diamine and the aromatic dianhydride is the king of all or each of the other. The hydrazine has at least one sulfone bond. The reactants are polymerized to form a polymer comprising a cyclic quinone bond and a hydrazone bond. Illustrative examples of aromatic dianhydrides include: 4,4'-bis(3,4-dicarboxyphenoxy)diphenyl succinic anhydride; 4,4'-bis(2,3-dicarboxyphenoxy) Diphenyl succinic anhydride; 4-(2,3-dicarboxyphenoxy)-4,-(3,4-dicarboxyphenoxy)diphenyl sulfone dianhydride and mixtures thereof. Other aromatic dianhydrides which may be used include: 2,2_bis(4-(3,4-diphenylphenoxy)phenyl)propane dianhydride; 4,4'-bis(3,4-di Carboxyphenoxy)diphenyl ether dianhydride; 4,4L bis(3,4-dicarboxyphenoxy)diphenyl sulfide dianhydride; 4,4'-bis(3,4-dicarboxyphenoxy) Benzophenone dianhydride; 2,2-bis([heart (2,3·dicarboxyphenoxy)phenyl]propane dianhydride; 4,4f-bis(2,3-dicarboxyphenoxy)di Phenyl ether dianhydride; 118106.doc -56- 200831609 4,4'-bis(2,3-dicarboxyphenylhydrazyl)diphenyl sulfide dianhydride; bis(2,3-dicarboxyphenoxy)diphenyl Methyl ketone dianhydride; 2-[4-(3,4-dicarboxyloxy)phenyl]_2_[4_(2,3-dicarboxyphenoxy) benzyl] propyl sulphide; 4-(2 ,3-dicarboxyphenoxy)_4,_(3,'dicarboxyphenoxy)diphenyl ether dianhydride; 4-(2,3-carboxyloxy)-4'_(3,4_ Dicarboxyphenoxy)diphenyl sulfide dianhydride;

4-(2,3-dicarboxyphenoxy)_4,_(3,4-dicarboxyphenoxy)benzophenone dianhydride; 1,4,5,8-naphthalenetetracarboxylic dianhydride; 3.4 .3, 4f-benzophenone tetrahydro acid di-field; 2.3.3, 4·-dibenzophenone tetracarboxylic dianhydride; 3,4,3f,4^oxydiphthalic anhydride; 3,3',4'-oxydiphthalic acid field; 3,3',4,4*-biphenyltetracarboxylic acid diano; 2,3,3',4f-biphenyltetracarboxylic dianhydride ; 2,3,2·,3·-biphenyltetracarboxylic acid dixanthene; pyromellitic dianhydride; 3,4,3,4 -, benzotriene tetracarboxylic dianhydride; 2,3,3 ', 4f - benzophenan tetracarboxylic dianhydride; 1,4-bis(3,4-dicarboxyphenoxy) dianhydride, and 2,2-bis(3,4-dicarboxylic acid phenyl) Fluoropropane dianhydride. Polysulfone ether imines having a structural unit derived from a mixture of two or two of the above items, 118106.doc -57 - 200831609, are also contemplated. In other examples, the poly-indenimide has greater than or equal to about 50 mole percent of the quinone imine linkage derived from the aromatic ether liver (ie, oxydiphthalate), in an alternative embodiment, There is a bismuth imine bond derived from the liver of oxydiphthalic acid of from about 6 〇 mol% to about 1 〇〇 mol %. In an alternative embodiment, from about 7 mole percent to about 99 moles of imide linkage is derived from oxydiphthalic anhydride or a chemical equivalent. One

The term "oxydiphthalic anhydride" means the oxygen double-adjacent benzoic acid

- (XII) and its derivatives, as further defined below. The formula (ΧΠ) oxydiphthalic anhydride includes 4,4,-oxydiphthalic anhydride, 3,4'-oxydiphthalic anhydride, 3,3,-oxybis phthalic acid Dicarboxylic anhydride and any mixture thereof. For example, a polysulfone ether iodide containing greater than or equal to about 5 mole percent of a quinone imine bond derived from oxydiphthalic anhydride can be derived from a 4,4'-oxy double neighbor of formula (XIII). Phthalic anhydride structural unit hard

(XIII) _ 醯 imine. Examples of the derivatized anhydride group which can serve as a chemical equivalent of oxydi-homoic acid anhydride in the quinone imine formation reaction include the oxydiphthalic acid if derivative of the formula (XIV) 118106.doc -58- ( XIV) 200831609

Wherein R! and R2 of the formula VII can be any of the following: hydrogen, an alkyl group, an aryl group. 1 and 112 may be the same or different to produce oxydiphthalic anhydride, oxydiphthalic anhydride and oxydiphthalic anhydride.

The polyphenolic ether-enamines herein may include a quinone imine bond derived from an oxydiphthalic anhydride derivative having two derived hepatic groups, for example, wherein the oxydiphthalic anhydride derivative is a formula (XV)

Wherein R, R2, Rs and R4 of the formula (XV) may be any of the following: hydrogen, alkyl, aryl. Ri, R2, R3 and R4 may be the same or different to produce oxybisphthalic acid, oxydiphthalate and oxydiphthalate.

Also included are mixtures of oxydiphthalic anhydrides derived from two, three or more different dianhydrides listed above with a flexible bond having almost the same molarity as the oxime The polysulfide ether quinone imine copolymer of the imidization reaction unit further comprises 'having greater than or equal to about 5 phthalic anhydride (including its derivatized % derived from the oxygen bis-o-benzene compound as defined above) a brewing imine bond and a copolymer of up to about 5 G mol% of an alternative dianhydride distinct from oxydiphthalate liver. That is, 'in some instances, it is desirable to have the copolymer in addition to having a bond derived from oxydiphthaloic anhydride of greater than or equal to about 50 mole percent, including what is different from oxydiphthalic anhydride as follows. 118106.doc -59- 200831609 The quinone imine bond of an aromatic dianhydride: for example, bisphenol A dianhydride (BPADA), diterpene, benzophenone dianhydride, bis(carbonphenoxyphenyl), Hexafluoropropane dianhydride, di-di- dianhydride, pyromellitic dianhydride (PMDA), biphenyl dianhydride, sulphur dianhydride, sulfonic dianhydride, and mixtures thereof. In another embodiment, a dianhydride as defined above is reacted with an aryl diamine having a sulfone linkage. In one embodiment, the polysulfone ether imide comprises a structural unit derived from an aryldiamine sulfone of formula (XVI).

H2N-Ar^s〇2-Ar-NH2 (χγΐ) wherein Ar may be an aryl group containing a monocyclic or polycyclic ring. A plurality of aromatic rings may be bonded together via, for example, an ether bond, a sulfone bond or more than one sulfone bond. The aromatic ring can also be fused. In an alternative implementation, the aryldiamine-based amine group may be in the meta or para position, for example in formula (XVII)

(XVII), aromatic diamines include (but are limited to), for example, diaminodiphenyl hard (10) S) and (aminophenoxyphenyl) sulfone (BAPS). The above-mentioned oxydiphthalic acid is condensed into a polyimidazole bond by the reaction of the ruthenium. In some embodiments, by reacting an aromatic di-hepatic monomer with an organic diamine monomer, the two monomers are substantially present in a molar amount. Or one of the oxime, which is not more than about 2% molar excess in the other monomer, and i is present in the reaction mixture in an excess relative to 10% molar excess, 2 and preferably less than Approximately 8% of the system was present in the reaction mixture in excess of about 5% molar excess from 118106.doc -60 to 200831609. In other examples the monomers will be present in an amount that differs by less than 1% molar excess.

The first monoamine can be used in the end cap or chain termination of poly(oxime) oxime imine to, for example, control molecular weight. In a particular embodiment, the mono-monoamine comprises an aromatic first monoamine, illustrative examples of which include aniline, chloroaniline, perfluoromethylaniline, cilamine, and the like. The aromatic first monoamine may have other functional groups attached to an aromatic ring such as, but not limited to, an aryl group, an alkyl group, an aryl group - a soil, a wind-based S-mercapto group, a guanamine group. A dentate, a halogenated alkyl or aryl group, a pyrenyl aryl ether group or an aryl ketone group. The functional groups attached should not interfere with the function of the aromatic monoamine-free molecular weight of the polyaniline. Suitable monoamine compounds are listed in U.S. Patent No. 6,919,422. Aromatic carboxylic anhydride (i.e., an aryl group containing a cyclic anhydride group) can also be used to control the molecular weight of the sulfite. Illustrative examples include phthalate needles, % chloro 4 benzoic acid, and substituted ortho-disaccharide livers and the like. The anhydrides may have other functional groups attached to the (tetra) ring, illustrative examples of which include such functional groups of the above aromatic first monoamines. In two cases, polyfluorene sinoimine having a low content of iso-isoalkyl bonds may be required. In some PAEK blends, the presence of the iso-burning bond is 4 Miscible, which reduces the negative (four) force at high temperatures and will be q-, and has an oxime iso-alkane. The polymer-miscible pEEK-incorporated compound is described, for example, in U.S. Patent No. 5, No. 79, No. 3, and in some examples, a low-content isodecyl group may mean less than 3 Gm. The % polylithium j lysine bond will contain a sulfiso group, and in other instances, the poly(ether) (4) amine bond will contain less than 2 moles of lysine. In other examples, less than ίο mol % iso-isoalkyl will be present in the ether oxime imine bond 118106.doc -61 - 200831609. The polysulfone ether quinone imine may have a melt index of from about 0.1 to about 10 grams per minute (g/min) as measured by American Society for Testing Materials (ASTM) D1238 at 340-425 °C. In one embodiment, the polysulfone ether quinone imine resin has a weight average molecular weight (Mw) of from about 10,000 to about 150,000 grams per mole (g/) as measured by gel permeation chromatography using polystyrene standards. Rnol). In another embodiment, the polyether sulfonimide has an Mw of from 20,000 to 60,000 g/mole 〇 ASTM D5205 "Standard Classification System for Polyetherimide (PEI) Materials11. In some instances, particularly when it is desired to form films and fibers, the composition should be substantially free of fiber reinforcements such as glass, carbon, ceramic fibers or metal fibers. In some instances, substantially no more than 5% by weight of the total composition is meant, and in other instances, less than 1% by weight of the fiber reinforcement should be present in the composition. In other examples, compositions having some degree of crystallinity upon cooling are beneficial. This is even more important in articles having high surface areas, such as fibers and films, which will rapidly cool due to their high surface area and may not exhibit the full degree of crystallinity necessary to achieve optimum characteristics. In some examples, the formation of crystallinity is reflected by the crystallization temperature (Tc), and Tc can be measured by a method such as differential scanning calorimetry (DSC) (e.g., ASTM method D3418). The temperature at which the maximum crystallization rate can be measured is taken as Tc. In some instances, such as at a cooling rate of 80 ° C / min, it is desirable to have a Tc greater than or equal to about 240 °C. In other examples, such as at a lower cooling rate of 118 ° C. / 62 - 200831609 at 20 ° C / min, a crystallization temperature greater than or equal to about 280 ° C may be required. In some examples, the composition will have at least two distinct glass transition pulsations (Tg), a Tg from a PAEK resin or a partially miscible ρΑΕκ blend, and a poly(etheretherimide) resin or The resin is the second Tg associated with the dominant mixture. The glass transition temperatures can be measured by any conventional method such as DSC or Dynamic Mechanical Analysis (DMA). In some examples, the first Tg can be from about 120 to about 200. The second Tg can be From about 240 to about 350 C. In other examples, it may be beneficial to have a second Tg of from about 280 to about 35 (and even more south of TC. In some examples, the specific resin, molecular weight, and The composition is completely different, or the transfer may be partially overlapped. In another embodiment, the measurement is performed at 38 〇 using a capillary rheometer with a shear rate of 100 to 10000 1 / sec by ASTM method D3835. The melt viscosity of the 醯 胺 imine PEAK blend is about 2 〇〇 pascal (seconds) to about 1 〇, 〇〇〇 pa sec (Pa (4). The melt viscosity at 38 〇〇 c is about 200 Pa s to A resin blend of about 1 Torr, which will allow the composition to be more easily formed by using a melt processing technique. In other examples, a lower melt viscosity of from about 200 to about 5,000 Pa_s will be used. The other state of melt processing at the high temperatures required for the PAEK-polymerization of the squamous imine composition described herein The sample is: the melt viscosity of the composition does not undergo excessive changes during the molding or extrusion process. One method of measuring the melt stability is to check the viscosity of the process at a processing temperature (for example, 380 ° C) with a parallel plate rheometer. Variations. In some instances, the initial viscosity should be retained greater than or equal to about 5% after the temperature is maintained at greater than or equal to about 10 minutes. In its example 118106.doc-63-200831609, it lasts at least about 10 minutes. The change in melt viscosity should be less than about 35% of the initial value. The initial melt viscosity value can be measured after the composition has melted and reached equilibrium for 5 minutes. After applying heat to the sample, before measuring (recording) viscosity Usually wait for i-5 minutes to ensure that the sample is completely melted and equilibrated. A suitable method for measuring melt viscosity versus time is, for example, ASTM method D4440. Note that it can be poise (p〇ise, p) or pascal (pa_s) The melt viscosity is reported; 1 Pa-s = 10 P. C. The copolymer of the polyether quinone imide may also comprise a copolymer of a copolyether quinone having a glass transition temperature of greater than or equal to about 218, which Copolymerization Ether quinone imine comprises structural units of formula (I) and (II):

And according to the situation (III) structural unit:

Wherein R1 comprises an unsubstituted Cm divalent aromatic hydrocarbon or a substituted C6_22 divalent aromatic hydrocarbon comprising a halogen or alkyl substituent or a mixture of such substituents; or formula (IV) Bivalent group:

(IV) wherein the group in which the aromatic ring is not assigned a positional isomer is in the meta or para position of Q, and Q is selected from the formula (V):

γ\α 0 〇 CF〇

() II II I -Ο-, -S_, a c-, a s-, a C-, 0 cf3 and a formula CyH2y (where y is an integer having a value from 1 to about 5) of an alkylene group or an alkylene group A covalent bond or member of the group of groups, and R2 is a divalent aryl group; the weight ratio of the unit of formula (1) to the unit of formula (II) is in the range of about 99.9:0.1 and about 25:75. Copolymers having such elements are disclosed in U.S. Patent No. 6,849,706, entitled "COPOLYETHERIMIDES", issued on February 1, 2005 in the name of Bruneiie et al. Further descriptions are described in detail. E. Blend Other Additives In addition to the polymer component of the blend, other beneficial compositions may be added to make improved article articles. Those skilled in the art will appreciate A wide range of ingredients added to the polymer to modify one or more manufacturing or performance characteristics. In some cases, a metal oxide can be added to the polymer of the present invention. In some instances, the 'metal oxide can be reduced by Increasing the time to reach the exothermic peak to further improve the flame resistance _ potency. Titanium dioxide is weight 118106.doc •65- 200831609. Other metal oxides include oxidation, oxidation, oxidation, iron oxide and transition metal oxides. A white metal oxide may be required. The metal oxide may be used alone or in combination with other metal oxides. The effective amount of metal oxide, in some instances, is from 0.0 to 20% by weight of the polymer blend. Other useful additives include smoke suppressants such as metal borate, such as zinc borate, metal or soil. a side acid salt, or other salt. In addition, other boron-containing compounds, (tetra) acid, other materials, boron oxide or other oxides of the shed may be used. In addition, other flame retardant additives such as aryl phosphate vinegar may be used. A brominated aromatic compound, including a polymer containing a bond prepared from a brominated aryl compound. An example of a compound having no compound is a brominated phenoxy resin, a halogenated polystyrene,豳 醯 imine, evolved polycarbonate, brominated epoxy resin and mixtures thereof. = Usable flame retardant additives can be used, for example, sulphuric acid, sulphate and functionalized aromatic sigma # available Any or all of these flame retardant mixtures 0 halogenated aromatic compounds of the luxury & white, ^ examples of brominated epoxy resin, _ polystyrene, bismuth halide imide, after the mountain Stinyl ester, brominated epoxy resin and mixtures thereof Examples of xanthates is resumed full gas butyl potassium, sodium toluene yellow stone, sodium benzene continued, continued dichlorobenzene sodium, potassium diphenyl hard continued and continued for methane sodium. In one case, the genus and the test salt of the soil tester are preferred. Examples of the phosphoric acid vinegar flame retardant (4) Acid Sanfang Zizhi, tricresyl phosphate, acid triphenyl vinegar, di-acid bisphenol A benzene Series, isophthalic acid diphenyl benzene vinegar, phenyl _ bis (''5-methylhexyl phosphate), ethyl diphenyl phosphate, bis(2-ethylhexyl) phosphino-p-propyl phosphate , bis(2·ethylhexyl)-phenyl phosphate, 118106.doc -66- 200831609 tris(nonylphenyl)phosphate, phenylmethyl phosphate, di(dodecyl)-phosphate Tolyl ester, triphenyl ester, tributylphenyl phthalate, 2-chloroethyl diphenyl acid, bis(2,5,5'-trimethylhexyl) phosphate Indole based on hydrazine, 2-ethylhexyl diphenyl phosphate, diphenyl hydrogen phosphate, isophthalic acid diphosphate and the like. In some instances, a flame retardant composition that is substantially free of self-priming atoms (especially / odorous and chlorine) may be required. Substantially free of self-atomic atoms means that in some of the examples, the composition has less than about 1 weight based on the weight of the composition and in other embodiments less than about 1 weight by weight of the halogen atom-containing composition. 1% halogen. The amount of halogen atoms can be determined by general chemical analysis. The composition may also optionally include a fluoropolymer in an amount of from 〇1 to about 5.0% by weight of the composition. The fluoropolymer can be used in any effective amount to provide the drip resistance of the resin composition. Some possible examples of suitable fluoropolymers and methods for preparing such fluoropolymers are set forth in, for example, U.S. Patent Nos. 3,671,487, 3,723,373 and 3,3,83,092. Suitable polymers include homopolymers and copolymers comprising structural units derived from one or more fluorinated alpha olefin monomers. The term "fluorinated alpha terpene hydrocarbon monomer" means an alpha olefin monomer comprising at least one fluorine atom substituent. Some suitable fluorinated dilute tobacco monomers include, for example, fluoroethylene (e.g., CF2 = CF2, CHF = CF2, CH2 = CF2, and CH2 = CHF) and fluoropropene (e.g., CF3CF = CF2, CF3CF = CHF. CF3CH = CF2 ^) CF3CH=CH2 'CF3CF-CHF χ CHF2CH=CHF and CF3CF=CH2). Some suitable fluorinated alpha olefin copolymers include a gentleman green g-, which is derived from two or two 118106.doc-67-200831609 or more murine CX flue-cured tobacco. a copolymer of early ruthenium (eg, poly(tetrafluoroethylene hexafluoroethylene)) and comprising a non-gasified single derived from one or more fluorinated monomers and one or more copolymerizable with a gasifying monomer a copolymer of structural units of an ethylenically unsaturated monomer (e.g., a poly(tetrafluoror, knee ethylene-ethylene-propylene) copolymer). Suitable non-fluorot monoethylenic monomers include (for example, (tetra)hydrocarbon (tetra) (such as ethylene, propylene olefin) @ enoate monomers (such as methyl methacrylate, propylene butyl acrylate and the like) Preferably, the poly(tetrafluoroethylene) homopolymer (PTFE) ruthenium compound may further comprise fillers and reinforcing agents such as fiberglass, milled glass, glass beads, flakes and the like. Minerals such as slip 1, limestone, mica 'kaolin or microcrystalline kaolinite clay, vermiculite, quartz and barite may be added. The composition can also be modified with an effective amount of an inorganic filler such as carbon fibers and tubes, metal fibers, metal powders, conductive carbon, and other additives, including nanoscale reinforcing agents. Eight additives include antioxidants such as linoleates, phosphite diesters and hindered phenols. Phosphorus-containing stabilizers including triaryl phosphites and aryl phosphonates are known as useful additives. Compounds containing difunctional phosphorus can also be utilized. Stabilizers having a molecular weight greater than or equal to about 300 are preferred. In other examples, a phosphorus-containing stabilizer having a molecular weight greater than or equal to 500 can be used. The juice phosphorus-containing stabilizer is usually present in the composition as 〇·〇5-〇·5〇/0 by weight of the formulation. A colorant as well as a light stabilizer and a UV absorber may also be present in the blend. Glidants and mold release compounds are also included. Examples of the release agent are alkyl carboxylates such as, for example, pentaerythritol tetrastearate, glyceryl tristearate, and ethylene glycol distearate. The release agent is usually present in the composition 118106.doc-68-200831609 in an amount of 〇5_〇·5% based on the weight of the formulation. Preferably, the release agent will have a high molecular weight, typically greater than about 300, to prevent release of the release agent from the molten polymer mixture during melt processing. The polymer blends used in the articles of the present invention may also include various additives such as nucleating agents, fining agents, stiffness agents, and/or knot rate agents. These agents are used in a conventional manner and in known amounts. 3. A method of preparing a blend of the present invention by including the material and any other additives desired in the formulation

A plurality of methods of mixing are used to blend the polymer blend used in the article of the present invention with the foregoing ingredients. Although solution blending is also possible, preferred procedures include melt blending. Melt processing methods are generally preferred because of the ability to utilize melt blending equipment in commercial polymer processing facilities. Illustrative examples of equipment made in such melt processing methods include co-rotating and reversing extruders, single-screw extruders, co-kneaders, disk assembly processors, and many other types of extrusion equipment. It is preferred to minimize the melting temperature in the process to avoid excessive degradation of the resin. Although it is possible to maintain the residence time of the resin in the curing apparatus at a very short temperature, it is often necessary to maintain the melt temperature stability in the molten resin composition at about 250. (: between about 370 ° C. In some embodiments, the molten processing composition is discharged from a processing apparatus such as an extruder through a small exit hole in the mold and the straw is passed through the obtained molten resin filament The water bath is used to cool the tow. It can be checked that the cooled tow is cut and/or molded for packaging, further processing or most convenient use of any convenient shape (ie, particulate matter) of the reverse product. The blends described herein are prepared by a variety of melt blending techniques. It is preferred to use a straight ventilated single or twin screw extruder with a good mixing screw. 118106.doc • 69· 200831609 The melt processing temperature of the extruder should be from about 10 ° C to about 15 (TC) of the Tg of the thermoplastic. The mixture of the king components can be fed together at the throat of the extruder using individual feeders or as a mixture. In some cases, such as in a blend of two or more resins, it may be advantageous to first squeeze a portion of the component in a first extrusion, followed by adding the remaining mixture in a second extrusion. The colorant is compounded into a concentrate and then It may be beneficial to mix the shrinkage with the remaining resin composition. In other cases, it may be beneficial to additionally add a portion of the mixture downstream of the throat of the extruder. After extrusion, the polymer may be melted into a tow. And cooling it, then dicing or granulating it into granules of a size suitable for the next manufacturing step. Preferably, the granules are about 1/16 to 1/8 Å long, but the skilled artisan should be aware of any particle size. The granulated thermoplastic resin is then dried to remove water and molded into the article of the invention. It is preferably from about 135 ° C to about 15 (dry for about 4 to about 8 hours, preferably drying time). It will vary with the type of resin. It is preferred to use an injection molding suitable for the temperature, pressure and clamping of articles having a smooth surface. The melting temperature for molding will be about 1 〇〇C to about the Tg of the resin. 200 ° C. The oil heating mold is preferred for higher Tg resins, and the molding temperature can vary from about 5 (TC to about 175.), and about 12 (rc to about 175 ° C temperature) The skilled artisan should be aware that many can be used to prepare the present listening composition. Variations of such composite and molding conditions of the article F. End use of the coated polymer article The high flexural modulus and high resistance of the polymers, copolymers and blends used in the articles of the invention The elongation of the sheet makes it useful for applications such as sheets, where the polymers, copolymers and blends exhibit impact damage resistance and also exhibit 118106.doc 200831609

Fully rigid so that it does not flex or bend under load. The combination of toughness (shown as back elongation at break), stiffness (shown as high flexural modulus), and flame resistance (not shown to be a low exotherm) makes the sheet or other article formed from the compositions extremely useful. For example, the sheets can be used to construct a transport vehicle, such as an eight-car smasher or a train interior. It can also be used for construction and construction. The sheet can be prepared by, for example, extrusion, compression molding, or calendering, and the sheet can be thermoformed or shaped by another method. Films and sheets can also be components of more complex construction. In some examples, 断裂 has a good impact resistance by, for example, having a tensile elongation at break of greater than or equal to about 5% by weight as measured by Method D638. In other examples, the flexural modulus having greater than or equal to about Kpsi (2 (four) Mpa) is, for example, measured by the dome method (10) 显. 1 by layer μ hot stamping, molding (in mold decoration), solution extrusion, two resin co-extrusion or other similar bonding or bonding techniques to make the inclusion of the blend = polycarbonate layer The blends and copolymers exhibit good primer-free adhesion to the barrier layer. Preferred methods include, for example, injection molding, blow molding, compression molding, profile extrusion, sheet or film extrusion, gas assisted mold t, structural bubble molding, and thermoforming. The compositions described herein can be converted into articles using a thermoplastic process such as film and sheet extrusion. Film and sheet extrusion processes can include, but are not limited to, solution casting, blown film extrusion, and calendering. A co-extrusion and lamination process can be used to form a composite multilayer film or sheet. For example, the composition described herein can be converted into a multilayer sheet having a first side and a first side of a second side 118106.doc • 71- 200831609 of which 3 Haidi - The sheet comprises a thermoplastic polymer, and wherein (4) the sheet: the first side is disposed on a first side of the plurality of ribs; and the second sheet has a side and a second side, wherein the second sheet comprises a thermoplastic polymer, wherein a first side of the second sheet is disposed on a second side of the plurality of ribs, and wherein the first side of the plurality of ribs and the second side of the plurality of ribs relatively. The polymer blend of the present invention may also be formed into an elastic film,

Coatings, sheets, strips, tapes, strips and the like. The elastic films, coatings and sheets of the present invention can be made by any method known in the art, including bubble blowing methods (e.g., simple foaming and biaxial orientation techniques such as cut-off foaming, double foaming) And tentering, casting extrusion, injection molding, thermoforming, extrusion coating, profile extrusion and sheet extrusion 0. Compression molding is well known to the skilled person, wherein the polymer blend is placed In the mold cavity or in contact with the corrugated metal surface. Heat and/or pressure is then applied to the polymer blend by, for example, a hydraulic press for a time period, pressure, and temperature, which conditions may vary depending on the characteristics of the blend. The pressure from the molding tool forces the polymer blend to fill the entire mold cavity. _曰 The molded object is cooled and can be removed from the mold with the help of the push-out mechanism. Once the process is complete, the polymer blend will take the shape of a mold cavity or a corrugated metal surface. A method of compression molding is disclosed in U.S. Patent No. 4,698,001 to the entire disclosure of U.S. Pat. Injection molding is the most common method of making non-reinforced thermoplastic parts, and this method is more commonly used for short fiber reinforced thermoplastic composites. Injection molding I18106.doc -72- 200831609 The method can be used to manufacture articles of the present invention. The injection molding method is a method in which a polymer composition which is multiplied by the amount necessary for producing an object is heated in a heating chamber into a viscous liquid and then injected into a cavity under pressure. The polymer blend remains in the mold cavity under high pressure until it is cooled and then removed. The term "injection molding" also includes a relatively new development in injection molding in which a two-part semi-liquid resin blend flows through a nozzle and into a mold cavity where it polymerizes due to reaction. The injection molding and injection molding apparatus is further described in detail in U.S. Patent No. 3,915,6,8 to Hujick, U.S. Patent No. 3,302,243 to Ludwig, and U.S. Patent No. 3,224, to La. Injection molding is the fastest method in the thermoplastic process and is therefore generally used in high volume applications such as automotive and consumer products. The period is in the range of 2 sec and 6 sec. Injection molding also produces a highly repeatable near-net shaped portion. Molding around inserts, holes, and core materials is another advantage. Finally, injection molding generally provides the best surface finish in any method. The skilled artisan will understand whether the injection molding process is the best specific processing method for making a given article of the present invention. Blow molding is a technology for making hollow thermoplastic products. Blow molding involves placing a squeeze tube of the thermoplastic polymer of the present invention in a mold and applying sufficient air pressure to the tube to conform the exterior of the tube to the inner surface of the mold cavity. A method of performing blow molding to produce articles of an article is described in further detail in U.S. Patent No. 5,55,860. Blow molding is not limited to the manufacture of hollow objects. For example, the outer casing 11 can be produced by blowing a unit and then cutting the unit into two halves to manufacture two outer casings. The simple bubble film method is also described, for example, in 77^ 〇/(10) Kirk-Othmer, 3rd edition, John Wiley & 118106.doc -73- 200831609

Sons’ New York, 1981, vol. 16, pp. 416, 417 and vol. i, pp. 191-192. It can be extruded through a blown film or by using a head. Stretching techniques are used to produce oriented films by drawing or calendering a film adjacent to the temperature of hot deformation. For example, a radial stretch scaler can be used for simultaneous multi-axial stretching; the x_y direction can be used to stretch the scaler simultaneously or sequentially in the plane x_y direction. Uniaxial and biaxial stretching can also be achieved using equipment having successive uniaxially stretched portions, such as (d) machines having portions of different speed rollers for longitudinal stretching and tenter portions for lateral stretching. The thermoplastic molding system includes a thermoplastic extrusion die for extruding a thermoplastic plate set by an adjustable die member (ie, a dynamic mold configuration) to change different portions of the extrusion plate The thickness of the extruded material. The thermoplastic extrusion die has a repairing piece for cutting the extruded thermoplastic plate from the extrusion die. A plurality of thermoplastic molds, which may be vacuum or compression molds, are each placed on a movable platform such as a rotary table to simultaneously move a mold into a position to receive the finished thermoplastic sheet from the thermoplastic extrusion mold. The still heated thermoplastic material fed from the extrusion die forms a molded part having a variable thickness. A plurality of molds are placed on the platform to feed a mold into the loading position to receive the thermoplastic sheet from the extrusion die and to feed the second mold into the release position to remove the forming portion from the mold. The platform can be a reciprocating or rotating platform and allows for cooling of the molded parts while the other molded part receives the thermoplastic sheet. A thermoplastic molding process is provided that selects a thermoplastic extrusion die configuration in accordance with a device that adjusts the thermoplastic extrusion die to vary the thickness of the extruded material that passes through it into different portions of the extrusion plate. Heating the thermoplastic material to a fluid state and extruding it through the selected thermoplastic mold, which has been adjusted 118106.doc-74-200831609 to change the thickness of the extruded material in different portions of the extruded sheet, An extruded thermoplastic sheet having a variable thickness is trimmed to a predetermined size and each of the conditioning sheets of the heated thermoplastic material is directed onto the hot forming die and the predetermined component is molded in the mold such that the heated material sheet is formed during extrusion by the material A molded part having a variable thickness. The injection-forming method, the extrusion coating method, the profile extrusion method, and the sheet extrusion method are described, for example, in Plastics Materials and Pr〇cesses.

Seymour S. Schwartz and Sidney H. Goodman, Van

Nostrand Reinhold Company, New York, 1982, pp. 527-563, 632-647 and 596-602. - The shaped article of the invention can be made using a vacuum molding process. According to this method, the sheet of polymeric material of Formula 1 is held by an iron frame or other device that is more easily handled by a jig, and then the sheet is introduced into a device in which the 'H is placed in the upper and lower positions. Heat it with a heater or wire heater. The flakes begin to melt upon heating. Once the sheet I continues to heat after sagging, the sheet is stretched within the frame. By observing the stretching, the sheet can be molded to a uniform thickness without wrinkles or other defects. In this case, the sheet frame is taken out from the heating, positioned adjacent to the mold, and vacuum-molded at a reduced pressure of 1 atm, so that the desired mold-shaped object can be obtained. Thereafter, the object can be cooled with air or atomized water and taken out of the mold. According to the pressure molding, a sheet which has been heated or otherwise made easy to handle is placed on the mold, and pressure is applied to the sheet so that the sheet is subjected to pressure to obtain a shape of the mold. Articles of the article comprising the resin of formula J can also be produced using a stamping process. 118106.doc -75· 200831609 For example, assembling a shaped block of the polymer of formula j in an extrusion die to a vertical press, followed by a pressure of 5 to 500 kg/cm 2 (preferably 1 to 2 kg/em 2 ) The lower part is hot molded to obtain the desired shaped object. The mold is then cooled with air or misted water and the article is removed from the mold. In this molding, the pressure time is usually up to 15 seconds, and is generally 15 to 4 seconds. In order to improve the surface characteristics, the molding is preferably carried out under two-stage pressure conditions. In the first stage, the polymer material is maintained at a pressure of 10 to 20 kg/cm2 for 15 or 4 seconds. Then at the first

The second stage maintains the polymeric material at a pressure of 4 Torr to 5 Torr/cm 2 for at least 5 cores so that a molded article having an excellent surface finish can be produced. This method may be preferred when a thermoplastic resin containing an inorganic filler of the formula 1 having poor fluidity is used. The injection molding method that is well known to us can also use the resin of the formula to manufacture articles. Injection molding is to inject resin into the mold cavity under pressure. The injection pressure is usually 40 to 140 kgW, and preferably 7 to i2 〇 kg/cm2. The skilled artisan will appreciate that articles of manufacture made from the polymer blends disclosed herein can be formed into any desired shape by any of the methods known in the art. These shapes can be simple geometric shapes (such as cuboids, spheres, rods, flakes, cones) and the more complex shapes required to make molded parts for poetic end-use applications. The shape of the polymer blend 1 described herein is only affected by the possible moldings associated with different end use applications using high temperature polymers. These finals include automobiles, aviation: aerospace, military, food service, electronics, lighting and medical. Examples of such things include, but are not limited to, cookware, food service items, medical devices, trays, plates, handles, head covers, animal cages, electrical connectors, electrical equipment, etc. 118106.doc •76- 200831609 Shells, engine parts Automotive engine parts, lighting slots and reflectors, electric motor components, power distribution equipment, communication equipment, computers and the like, including devices molded in snap-fit connectors. Blends and sheets and/components of the lamination system can also be made from the blends described herein, which are mainly composed of meta-phenylene. One or more surfaces of the article of article are coated in accordance with the present invention by a composition different from the underlying polymer blend that constitutes the uncoated article. Coatings according to this month shall include all coatings known to the skilled technician, including all types of paints, sheets, films, and the like. Alternatively, the film and sheet can be prepared by casting a solution or suspension of the composition in a suitable solvent onto a substrate, tape or on top of the substrate followed by removal of the solvent. The film or sheet can also be metallized using standard methods such as plasma deposition, sputtering, vacuum deposition, and foil lamination. A single or multiple layer coating may be further applied to the article of the present invention to impart other characteristics such as electrical conductivity, scratch resistance, UV resistance, aesthetic effects, and the like. For the purposes of the present invention, the term paint is intended to include paints, lacquers, and poly-coatings having a thickness of between about 1 and 500 (more specifically, about 丨〇 nm to about 250 nm). The skilled artisan will appreciate that coatings of any thickness may be utilized in accordance with the present invention, and that specific fields such as 1 〇 7 〇, or even (7) _ represent only coatings that may be used in some of the end uses covered by the present invention. Thickness 'where the coating contains paint, metal and polymer. ^ Month is also directed to a sheet and film comprising the resin of Formula 1, which has a covering layer on all or some of the surfaces of the object. A multi-recorded ne, j> method is used to fabricate a polymer article having a paint finish on a surface, which is made of a compound. According to the methods, the composition of the solid ether quinone imide blend is applied to the surface of the shaped article to be coated or pinned to form a coating. Coating is applied over the d" and then dried in a precise manner for the present invention without weighting all or part of the process, such as to enable the second to be pre-coated or not pre-coated by standard application techniques.

Beiyu, / redundant, brush or flow coating. For commercial manufacturing or large-scale production of coated shaped articles, the use of the blasting method is effective, in particular, by the use of a robotic coating method. According to the invention, the final use of embers 4^ . _ ^

One of the applications for taking and using is the L.ED• pedestal. The LED wafer can be one of many shapes including, but not limited to, inverted trapezoidal, cubic, rectangular or hemispherical. The LED wafer can include a bottom surface that can be contacted with a reflective material or coated with a reflective material. Although the LED wafer can be illuminated from all sides thereof, the LED wafer pedestal can be configured to reflect the emitted light in a single direction. The pedestals are conventional and may include a parabolic reflector, wherein the LED wafer is on the surface of the package pedestal. An example of such a package is shown in U.S. Patent No. 4,920,404, the disclosure of which is incorporated herein by reference. A coated LED pedestal, and more particularly an LED substrate coated with a reflective material, can be made in accordance with the present invention using any of the polymers, copolymers or blends referred to herein. The shaped article of the present invention may also be in the form of a sheet coated with one or more layers of other sheet material. Porous fiber reinforced thermoplastic composite sheets have been described in U.S. Patent Nos. 4,978,489 and 4,670,331, and because of the increase in fiber 118106.doc -78 - 200831609, the strong thermoplastic sheets are easily molded into articles, so they are used in product manufacturing. Many and various applications. The coated article of the present invention may also be in the form of a cable that is core or clad. Skilled artisans should be familiar with fiber optic cables, methods of making fiber optic cables, and fiber optic cable characteristics. The optical properties of the polymers, copolymers, and blends described herein are also desirably used in optical applications other than fiber optic cables, including, for example, coated or uncoated lenses and coated or uncoated The coated material is fired.

Without further elaboration, it will be apparent to those skilled in the art that the invention can be utilized in the description herein. The invention includes the following examples to provide additional guidance to those skilled in the art in practicing the invention. The examples provided are merely representative of the invention and are not intended to teach the invention. Accordingly, the examples are not intended to limit the invention in any way. The entire disclosures of all patents, patent applications, and other publications herein are hereby incorporated by reference in its entirety herein in its entirety herein. EXAMPLES Without further elaboration, the skilled artisan skilled in the art can use the invention herein to carry out and use the invention. The present invention includes the following examples in order to provide the present invention to those skilled in the art to provide the present invention. The examples provided are representative of the invention and are used to teach ^^, illuminate. Accordingly, the examples are not intended to limit the present yoke in any way. All parts are by weight unless otherwise stated below. ύ % Example 1 Example 1-9 118106.doc •79- 200831609 Some features were measured using the ASTM test method. All molded samples were conditioned at 50% relative humidity for at least 48 hours prior to testing. The reverse notched Izod impact value was measured in a 3.2 mm thick rod at room temperature according to ASTM D256. The heat distortion temperature (HDT) was measured in accordance with ASTM D648 at 0.46 MPa (66 psi) with a 3.2 mm thick rod. The tensile properties were measured in accordance with ASTM method D638 with a 3·2 mm class I rod. Flexural properties were measured on a 3.2 mm rod according to ASTM method D790. The Vicat temperature was measured at 50 N according to ASTM method D1525. Differential Scanning Calorimetry (DSC) was performed according to ASTM method D34 18 but using different heating and cooling rates. The sample was heated to 350 ° C at 20 ° C / min and cooled at 20 ° C / min or 80 ° C / min to record the crystallization temperature peak (Tc). Flexural dynamic mechanical analysis (DMA) was performed with a 3.2 mm rod at a Hertz oscillation frequency and a heating rate of 3 °C/min. The DMA test was carried out according to ASTM method D5418 from about 30 to about 300 °C. The ratio of viscosity to shear rate was measured on a capillary rheometer using a 1 X 10 mm mode at 3 80 °C according to ASTM method D3 83 5. The pellets of the blend were dried at 10 °C/min for at least 3 hours at 150 °C using a parallel plate rheometer prior to testing. Measure the change in smelting viscosity over time at 80 °C. The glass transition temperature (Tg) can be measured by several techniques known in the art (e.g., ASTM method D34318). Different heating rates can be utilized in Tg measurements, such as 5 ° C to 30 ° C per minute, or 10 ° C to 20 ° C per minute in other examples. The material PCE is a BPA copolycarbonate containing about 00% by weight of a 1:1 mixture of isophthalate 118106.doc-80 - 200831609 with a terephthalate group, and the balance being a BPA carbonate group, PCE has a Mw of about 28,300 and a Tg of about 175 °C. PSEI-1 is a polyfluorene ether ylide prepared by reacting 4,4'-oxybisphthalic anhydride (ODPA) with about 4 parts of 4'-diaminodiphenyl hydrazine (DDS). , PSEI-1 has a Mw of about 33,000 and a Tg of about 310 〇C 0 : PSEI-2 is about 80 mol% 4,4, oxy phthalic anhydride (ODPA) with: about 20 m Copolyether oxime imine copolymer obtained by reacting a mixture of % bisphenol-A dianhydride (BPADA) with about 4 parts of 4,4 diaminodiphenyl hydrazine (DDS), PSEI-2 Mw is about 28,000 and the Tg is about 280 °C. PSEI-3 is a polysulfone ether imine prepared by the reaction of diterpene-A dianhydride (BPADA) with about 4,4,-diaminodiphenyl hydrazine (DDS), the Mw of PSEI-3. It is about 34,000 and has a Tg of about 247 °C. PSEI-4 is composed of bisphenol-A disodium salt and isomolar 1H-isoindole-1,3(2H)-dione, 2,2'·(sulfonyldi-4,1_stretch The polysulfone ether quinone imine prepared by the phenyl)bis[4-chloro-(9CI)] reaction, PSEI-4 has a Mw of about 50,000 and a Tg of about φ 265 °C. Formulations 1-9 of the invention were prepared using the compositions specified in Table 1. The amounts of all components are expressed in parts by weight per hundred parts by weight of resin, of which total resin weight. Including stabilizers, if present. Polycarbonate (PCE) copolymerization by reacting m-benzoic acid and p-benzoic acid diacid chloride with bisphenol A in the presence of a base and a triethylamine phase transfer catalyst in two phases (dichloromethane/water) Things. Synthetic details of this type of synthesis can be found, for example, in column 13, line 15-45 of U.S. Patent No. 5,521,258. The obtained polyester carbonate copolymer has 60% ester units (mixing ratio of isophthalate to terephthalate units is 1:1) 118106.doc -81- 200831609

And 40% of carbonate units based on bisphenol A. The ingredients as specified in Table 1 were mixed together in a paint shaker and extruded at 575-640 °F at 80-90 rpm on a 2.5 吋 vacuum-ventilated single screw extruder. The resulting blend was pelletized and dried at 275 °F for 4 hours before the pellets were injection molded into a 5 X 7 X 1/8 inch sheet. The molding machine was set to have a melting temperature of 675 °F and a molding temperature of 275 °F. 20 of each molded sample was measured. Gloss, CIE L* value and appearance. The twenty degree gloss was measured according to ASTM D523 using a black tile standard. The CIE brightness (L*) value is measured as described by R. McDonald, ''Colour Physics for Industry, Second Edition', The Society of Dyers and Colourists, Bradford, UK (1997). Appearance refers to the subjective visual inspection of the color and translucency/opacity of the molded part. The sample was then metallized using a layer of approximately 700 angstroms of sputtered aluminum deposited by Leybold Co.'s Dynamet 4V apparatus. The sample was then further coated with a 50-100 angstrom plasma clear polymer derived from hexamethylene diazoxide. The reflectance and diffuse reflectance on the metal coated surface of the metallized component were measured using a Perkin Elmer Lambda 19 UV/Vis/NIR spectrophotometer equipped with an RSA-PE 18 reflectance spectrometer from Labsphere Co. Compare samples to Spectralon mirror standards. The total reflectance % is measured at about 400 nm compared to the standard measured diffuse reflectance (which is a measure of scattered light), and the light is directly reflected by using the optical trap of the measured signal and the diffused light content. (Specular reflection) is partially excluded from the measurement. The turbidity on the metallized samples was measured using a Pacific Gardner XL 835 calorimeter. The % scattered light from the metallized sample is compared to the directly reflected light. The turbidity measured in this way is 118106.doc -82 - 200831609 . It is related to the % non-reflectivity. A panel of 3_5 observers uses a side-by-side comparison of all metallized plates, using a subjective positive (+) or negative (a) scale for visual grading, which corresponds to a surface that is acceptable for use as a long-term retroreflector without defects And negative corresponds to a turbid surface that produces an extremely unclear, hazy reflection that is unacceptable for the ultimate use of the reflector. ' Table 1 Formulation 1 2 3 4 5 6 7 8 9 PCE PSEI-3 PSEI-2 PSEM 60 40 50 50 50 50 30 70 40 60 60 40 70 50 50 60 40 Appearance + + + + + + + + + + + is the acceptable level of the test results defined. Example 2 The above inventive formulations 丨, 2, 3, 4 and 5 were injection molded into a concave, parabolic automobile headlight reflector. The surface of the parts was sputtered with aluminum and a clear coating was applied using the techniques described above. Example 3 Materials made according to formulations 6, 7, 8, and 9 of Table 1 were injection molded into a cavity into an inverted trapezoidal LED pedestal. Current is fed to the LED and the LED reflectivity is acceptable for electronic applications. Example 4 For Formulation 10-3 1, the properties were measured using the ASTM test method. The dry particulate matter was subjected to melt flow rate (MFR) measurement according to ASTM D1238 at 295 ° C using a weight of 6.7 Kg. All molded samples were conditioned for at least 48 h at 118106.doc -83 - 200831609 50% relative humidity prior to testing. The notched Ehrlich collision value was measured at a room temperature of 3.0 mm in accordance with ASTM D256. The heat distortion temperature (HDT) was measured in accordance with ASTM D648 at 1.82 MPa (264 psi) with a body measuring 3. 2 mm thick. The ASTM method D3763 was used to measure the two-axis or mounted collision at 23 〇C on a 102 X 3.2 mm disc, reporting the peak impact energy. Tensile properties were measured in a 3.2 mm type I rod according to ASTM method D638. The deflection characteristics were measured in accordance with the ASTM method 〇790 with a 3.2 111111 rod. The solvent resistance was measured with a 3.2 mm rod using an 8-8 method. Transmittance % (T%) and turbidity % (H%) were measured at 2.0 mm according to ASTM method D1003. An exothermic test was performed on a 15.2 x 15.2 cm plate measuring 2.0 mm thick using an Ohio State University (OSU) exothermic rate device as measured by the method listed in FAR 25.853. The exotherm was measured at two minutes in kW-min/m2 (kilowatt minutes per square meter). The exothermic peak is measured in kW/m2 (kilowatts per square meter). The time to reach the exothermic peak is also measured, expressed in minutes. The exothermic test method is also described in "Aircraft Materials Fire Test Handbook" DOT/FAA/AR-OO/12, Chapter 5 '’Heat Release Test for Cabin Materials" o Materials

The resorcinol ester polycarbonate (ITR) resin used in the formulations is a 1:1 mixture of m-benzoic acid chloride and terephthalic acid chloride with resorcinol, bisphenol A (BPA) and A polymer obtained by condensation of carbon ruthenium chloride. The ITR polymer is named by the approximate molar ratio of the ester bond to the carbonate bond. ITR 9010 has a benzenediol ester linkage of about 82 moles per Å, a sulphuric acid carbonate linkage of 8 mole percent, and a 3 octacarbonate linkage of about 10 mole percent. Tg=131°C 118106.doc -84 - 200831609 PEI=ULTEM 1000 polyether quinone imine, polyether quinone imine from bisphenol A dianhydride and about the molar amount of phenylenediamine from GE Plastics be made of. PEI-nonane is a polyether oxime prepared by imidization of m-phenylenediamine, BPA-dianhydride and bis-aminopropyl-functional fluorenyl polyoxyl oxide containing an average of about 10 polyfluorene oxygen atoms. Imino dimethyl siloxane copolymer. The oxime content was about 34% by weight and the Μη was about 24,000 by gel permeation chromatography. PC is ΒΡΑ polycarbonate available from GE Plastics' LEXAN 130. Prepared by extruding a mixture of resorcinol-based polyester carbonate resin and polyether quinone imine and polyoxymethylene phthalimide copolymer resin in a 2.5 吋 single screw vacuum ventilator Blend. Compositions are listed as % by weight of the total composition unless otherwise stated. Set the extruder to approximately 285 to 340 °C. Blending was carried out at about 90 rpm under vacuum. The extrudate was cooled, granulated north and dried at 120 °C. The test samples were injection molded at a set temperature of 320-360 ° C and a molding temperature of 120 ° C using a 30 second cycle. Brush the object with a UV protectant coating. φ Formulations 10 and 11 of Table 2 show how to replace PC with resorcinol ester polycarbonate (ITR9010) in a PEI/polyoxyn-polyimine copolymer blend, which is surprisingly reduced by two minutes. Exothermic and total exotherm. The time to delay the exotherm to reach the maximum intensity also increases the time to reach the exothermic peak. Note that the addition of isophthalic acid ester polycarbonate also increased fluidity (MFR = melt flow rate g per 10 minutes, measured at 295 ° C) and improved elongation at break. 118106.doc -85 - 200831609 Table 2 Formulation 10 11 PEI 76 76 ITR9010 10 20 PEI-oxane 4 4 PC 10 0 Ti〇2 3 3 Exothermic 2 min (kW-min/m2) 10 12 Peak (kWm2) 34 29 Time to reach value (min) 4.60 4.50 MFR@295〇C 3.0 3.6 Flexing modulus Kpsi 464 462 Flexural strength Kpsi 22.1 22.4 Tensile strength (Y) Kpsi 14.8 15.0 Stretch %(B) 39 50 HDT264psrt 163 164 Elongation Maximum Load ft-lbs 54 56 Notched Ehrlich Impact Strength ft-lbs/in 1.4 1.3 Table 3 shows the copolymerization of various amounts of benzenediol ester polycarbonate and 1 to 4% polyoxyl imine One of a series of PEI blends. Formulations 12-1 8 all showed extremely low two-minute exotherms and low exothermic peaks. The samples all showed a high MFR indicating a good melt flow. In all cases, the HDT is greater than 150 °C. The flexural modulus of the formulation is also 2 400 Kpsi (2760 Mpa). It is also noted that surprisingly low exotherms can be achieved even with low levels of polyetherimine, such as formulations 15 and 17 which are less than half of the total blend. Percent (phr) 3.0 of titanium dioxide and 0.1 phr of 118106.doc -86-200831609 triaryl phosphite are present in this set of formulations 12-18. Table 3 Formulations 12 13 14 15 16 17 18 PEI ITR9010 PEI-oxane 56.5 42.5 1.0 78.0 20.0 2.0 63.0 35.0 2.0 48.0 50.0 2.0 69.5 27.5 3.0 46.0 50.0 4.0 76.0 20.0 4.0 Ti02 and 0.1 of all blends 3 phr Phr of triaryl phosphite Formulations 19 and 20 in Table 4 show the beneficial effect of the addition of 11 〇 2 in reducing the exotherm and increasing the time to reach the exothermic peak. Note that both Examples 19 and 20 have excellent exothermic properties, and the formulation 11 may have a slightly lower exothermic peak and a longer time to reach the exothermic peak, indicating a beneficial effect of the metal oxide additive.

Table 4 Formulation 19 20 21 22 23 24 25 PEI 67.5 67.5 68 58 19.15 18.40 17.65 ITR9010 30.0 30.0 20 30 80.0 80.0 80.0 PEI-oxime 2.5 2.5 2 2 0.75 1.50 2.25 PC 10 10 Triaryl phosphite 0.1 0.1 0.1 Ti 〇2 0.0 3.0 3 3 Exothermic 2 min (kW-min/m2) 16 12 17 15 23 18 18 Peak (kW/m2) 31 29 29 35 39 40 40 Time to peak (minutes) 3.87 4.69 3.21 4.34 3.74 3.34 3.64 Note Foam foam foam Carbon carbon charcoal MFR@295〇C 3.1 3.0 2.6 4.0 13.9 14.8 14.5 Flexural modulus Kpsi 467 470 465 485 399 395 393 Flexural strength Kpsi 23.3 22.9 22.3 21.9 19.3 19.4 19.3 118106.doc -87 - 200831609 Formulation 19 20 21 22 23 24 25 Tensile strength (Y) Kpsi 14.3 14.0 13.8 13.3 12.4 12.4 12.3 Tensile %(B) 52 86 82 100 40 45 46 HDT264 psi°C 169 169 169 161 133 134 133 Elongation Maximum load ft-lbs 54 57 55 58 50.7 50.6 52.9 Notched Ehrlich impact strength ft-lbs/in 0.9 1.0 1.2 1.3 2.7 2.5 2.6 Transmittance %@2.0 mm 74.3 72.4 72.5 Turbidity%@2.0 mm 5.9 6.6 5.8 Table 4 Also shows the formulation 21 and 22. These blends include resorcinol ester polycarbonate, polyether quinone imine and polydecyloxy-polyimine copolymers with other non-arylate polycarbonates, bisphenol-A polycarbonates (PC) combination. The blends can exhibit HDT above 150 °C, a flexural modulus of 2 390 Kpsi (2691 Mpa), and an extremely low two-minute exotherm and exotherm. Formulations 23, 24 and 25 are shown in Table 4. The blends have a high resorcinol ester polycarbonate content. Even with low PEI oxime content and low PEI content, the blends exhibit improved flame resistance as indicated by low exotherm values and long periods of time to reach exothermic peaks. The blends may have excellent flow properties as indicated by high MFR and high modulus and strength. The tensile elongation at break can be higher than 25% in all cases. Note that at 2.0 mm, the transmittance may be higher than 70% while having a low haze, even less than 10% in the three component polymer blends. Notched Ehrlich impact strengths above 2.0 ft-lbs/in 调 Formulations 26, 27 and 28 are shown in Table 5. The blends have about equal amounts of meta- benzenediol ester polycarbonate and PEI. Even with a low PEI oxime content (0.75 to 2.25 wt%), the blends can exhibit low exotherms. Blending 118106.doc -88 - 200831609 The material may have good fluidity as indicated by high MFR and high modulus 390 Kpsi) and strength. In all cases, the tensile elongation at break can be higher than 25%. Note that at 2.0 mm, the % transmittance is higher than 60% while having a low haze, and the turbidity is less than 10% in the polymer blends. Table 5 Example 26 27 28 29 30 31 ΡΕΙ 49.15 48.40 47.65 79.15 78.40 77.70 ITR9010 50.0 50.0 50,0 20.0 20.0 20.0 oxirane 0.75 1.50 2.25 0.75 1.50 2.25 Triaryl phosphite 0.1 0.1 0.1 0.1 0.1 0.1 Exothermic 2 min (kW -min/m2) 14 12 13 13 10 9 Peak (kW/m2) 36 31 33 29 27 26 Time to peak (min) 3.94 4.26 4.62 2.70 2.91 4.69 Notes Foam foam foam foam foam Carbon carbon Carbon body carbon carbon MFR@295〇C 6.7 6.9 7.0 2.1 2.1 2.3 Flexural modulus Kpsi 441 430 433 467 473 473 Flexural strength Kpsi 22.1 21.7 21.8 23.9 24.4 24.2 Tensile strength (Y) Kpsi 13.9 13.7 14.1 16.0 15.8 15.7 Stretch %(Β) 38 54 80 95 72 28 HDT264 psi°C 155 151 151 171 176 175 Elongation Maximum Load fl-lbs 61.1 53.1 59.6 58.3 57.1 62.2 Notched Ehrlich Impact Strength fl-lbs/in 1.4 1.6 L5 1.0 1.0 1.2 Transmittance %@2.0 mm 73.0 72.4 68.8 72.1 70.1 66.4 Turbidity %@2.0 mm 2.5 3.1 5.8 2.5 4.0 7.0 The formulation 29-3 1 is shown in Table 5. The blends contain a lower level of meta- succinyl ester polycarbonate. Although the PEI oxime content (0.75 to 2.25 weight 118106.doc -89 - 200831609%) is extremely low, the blend still exhibits a low exotherm and a low peak to peak time. The blends can exhibit fluidity useful for melt processing applications as well as high modulus (23 90 Kpsi) and strength. The tensile elongation at break in all cases may be higher than 25%. Note that at 2.0 mm, the % transmittance is higher than 60% while having a low haze, and the turbidity is less than 10% in the polymer blends. : Example 5; The characteristics were measured using the ASTM test method. The dry particulate matter (MFR) ® was measured according to ASTM D1238 at 295 °C with a weight of 6.7 Kg. All molded samples were conditioned at 50% relative humidity for at least 48 h prior to testing. The notched Ehrlich collision value was measured in a 3.2 mm thick rod at room temperature according to ASTM D256. The heat distortion temperature (HDT) was measured on a coarse 3.2 mm rod at 1.82 MPa (264 psi) according to ASTM D648. Tensile properties were measured on a 3.2 mm Type I rod according to ASTM method D638. The deflection characteristics were measured on a 3.2 mm rod according to ASTM method D790. An exothermic test was performed on a 2.0 mm thick 15.2 X 15.2 cm plate using an Ohio State 10 University (OSU) exothermic rate device as measured by the method listed in FAR 25.853. The exotherm was measured at two minutes in kW-min/m2 (kilowatt minutes per square meter). The exothermic peak is measured in kW/m2 (kilowatts per square meter). The time to reach the exothermic peak is also measured in minutes. The exothermic test method is also described in ''Aircraft Materials Fire Test Handbook" DOT/FAA/AR-OO/12, Chapter 5"Heat Release Test for Cabin Materials." Materials* Resorcinol used in these examples Ester Polycarbonate (ITR) Resin 118106.doc -90- 200831609 A 1:1 mixture of m-acid and p-benzoquinone is combined with isophthalic acid, double A (BPA) and the mouse. The resulting polymer was named ITR polymer with an approximate molar ratio of vinegar to cesium carbonate. ITR9010 has about 82 mol% of benzenediol ester bond, 8 mol% of benzenediol carbonate. The bond and about 1〇%*%2ΒΡΑ carbonate bond. Tg=13TC. PEI-oxime is made up of m-phenylenediamine, EPA-dianhydride and bis-aminopropyl group containing an average of about 1〇 polyoxynium atom. a poly-acid imine dimethyl oxirane copolymer prepared by the imidization reaction of methyl group I methyl group O. The content of decane is about 34 as measured by gel permeation chromatography. % by weight, and Μη is about 24,000. PSu is a polysulfone prepared by the reaction of bisphenol hydrazine with dibenzophenone, and is sold as a UDEL 1700 from Solvay Co. PES is diphenyl benzene. The polyether oxime obtained by the reaction of a sulfone and a di-diphenyl sulfone is sold as a ULTRASON E from BASF Co. Note that the blend according to this example has a (phr) percent of titanium dioxide added during the compounding period. (Ti〇2). Extrusion of resorcinol-based polyester carbonate resin with polyfluorene or poly-bonds in a 2.5-inch single-screw vacuum-ventilation extruder A mixture of resins to prepare a blend unless otherwise stated 'otherwise the composition is listed as a weight percent of the total composition. The extruder is set at about 285 to 340 ° C. The blend is mixed under vacuum at about 90 rpm. The extrudate is cooled, granulated and dried at l2 (r. at a set temperature of 320-360. (: and the molding temperature is 120 ° C. The test sample is injection molded in a 30 second cycle. The formulation of Table 6 32 shows a blend of resorcinol ester polycarbonate (ITR9010), polysulfone (pSu) and polyoxo-polyimine copolymer (ρΕΙ-decane), which surprisingly reduces two Minutes of exothermic and exothermic 118106.doc -91- 200831609 peak. The two-minute exotherm can be reduced from 63 to 47 kW-min/m2. The thermal peak value drops from 120 to 75 kW/m2. It can also increase the peak exothermic time from 2.56 to 3.72 minutes, delaying the exotherm to reach the maximum intensity. Formulation 3 3 shows polyfluorene and polyethersulfone (PES) and ITR9010 and A blend of polyoxymethylene polyimine which may also have improved exothermic properties and improved flow properties. Table 6 Example* 32 33 34 PSu 62.5 31.25 62.5 PES 0 31.25 0 PEI oxime 2.5 2.5 2.5 ITR9O10 35 35 35 Exothermic 2 min (kW-min/m2) 47 57 31 Peak (kW/m2) 75 75 65 Peak of arrival Time (min) 3.72 2.91 3.74 Appearance Foam Carbon Foam Carbon Foam Carbon MFR@295〇C g/l〇min 13.8 11.9 10.9 * Blend with 3 phr Ti02 Example 6 Table 6, Formulation 34 shows poly A blend of ether oxime (PES) with resorcinol ester polycarbonate (ITR 9010) and 2.5% by weight polyoxymethylene polyimine copolymer. The formulation 34 can be tested according to FAR/OSU and foamed carbon that acts as a barrier against flame spread. It can also have a low exotherm value, a longer time to reach the exothermic peak and can act as a barrier to more effectively prevent flame spread. Example 7 The formulations 35 and 36 in Table 7 show PSU or PES with a higher content (60 weight 118106) .doc -92- 200831609 % by weight) a blend of resorcinol ester polycarbonate copolymer. The blend can exhibit a low two minute exotherm and a low exotherm peak. When burned, the sample produces foam carbon that acts as a barrier against flame propagation. Examples 35 and 36 also exhibited high melt flow, which was surprisingly not burned or flowed away from the flame during the FAR/OSU test. The blend may also exhibit a high flexural modulus of 300 Kpsi or * 2070 MPa) and a high flexural strength 〇 15 Kpsi or 103.5 MPa) and a high; 50%) elongation at break. Table 7 Example* 35 36 Psu 37.5 0 PES 0 37.5 PEI oxime 2.5 2.5 ITR9010 60 60 Exothermic 2 min (kW-min/m2) 59 39 Peak (kW/m2) 70 58 Time to peak (min) 2.65 2.40 Appearance foam carbon foam carbon MFR@295〇C g/l〇min 17.7 13.9 Flexural modulus Kpsi 382 399 Flexural strength Kpsi 17.6 18.3 Tensile strength (Y) Kpsi 11.0 11.7 Tensile modulus Kpsi 372 383 Stretching %(B) 89 110 HDT264 psi°C 134 132 Notched Ehrlich Impact Strength fl>lbs/in 2.6 3.5 * The blend has 3 phr of Ti02. • __ 118106.doc • 93- 200831609 Example 8 The slabs of inventive materials 1, 2, 3 and 4 were held in a rotary holder in a Baltzer vacuum metallization chamber. The chamber is closed and the vacuum pump is activated. The chamber pressure was reduced to a vacuum of 1 (Τ3 and 1〇-4 mBar. The sample was twisted in the holder and pretreated by glow discharge for one minute. The glow discharge method was included in the range of about 0.08 to 0.1 Mbar. The air or argon mixture is introduced into the vacuum chamber under pressure' while the high voltage current source forms a plasma for 1 minute, which improves the surface of the sample. After the glow discharge method is completed, the vacuum pump is started again and the pressure in the chamber is reduced to 1 〇-4. Mbar, and heating the pure aluminum with tungsten wire to evaporate the aluminum and condense on the sample plate. To protect the aluminum layer, apply the coating to the sample, and introduce HMDS (hexamethylene dioxane) during the second glow discharge step In the chamber, HMDS was deposited as a polymer on the aluminum surface to create a light source conditioner. Example 9 The material plates of formulations 1, 2, 3, 4, pSEI_3 and PSEI-4 were clamped in a Baltzer vacuum metallization chamber. Rotating the holder. The chamber is closed and the vacuum pump is activated. The pressure in the chamber is reduced to a vacuum between 10-3 and 10-4 mBari. The sample is rotated in the holder and pretreated by glow discharge for one minute. Glow Discharge French bread The air or argon mixture is introduced into the vacuum chamber at a pressure of about 〇·8 to M1 Mbar, and the high-voltage current source generates a plasma for 1 minute, which improves the surface of the sample. After the glow discharge method is completed, it is started again. Vacuum pump, and reduce the pressure in the chamber to 10 Mb ar 'and heat it with a wire to make it evaporate and condense on the sample 118106. doc -94- 200831609. To protect the aluminum layer, apply the coating to the sample. HMDS (hexamethyldioxane) was introduced into the chamber during the second glow discharge step, and HMDS was precipitated as a polymer on the aluminum surface to produce a light source conditioner. The PSEI-3 and PSEI-4 plates were placed with an initial The temperature was 218 in the Undberg/Blu_flow oven (model Μ01490) and the heat was increased at a rate of approximately 〇·1 C per minute. The plate was tested every 15 minutes until it showed visible signs of loss of reflectance. Table 8 below indicates the temperature at which the plate is reflectively reduced. Similar tests were performed on the annealed psm_3 and PSEI-4 plates before metallization. By heating each plate to a separate glass transfer Annealed, pre-metallized plates are prepared by cooling at a temperature of 2 ° C and at a rate of -1 ° C to 23. 每小时. The data in Table 8 indicates that PSEI_4 is better under certain conditions. PSEI_3. This data also indicates that the molded article is pre-annealed prior to metallization to promote the improvement of the thermal properties of the metal coated article. Table 8. Heat Treatment of Metallized PSEI Plate PSEI-3 PSEI-4 Annealing Temperature (° C) * Temperature (°C)* — is 244 254 No Auntie, ca 232 250 * Temperature at which reflectance loss is observed The present invention has been described with reference to the preferred embodiments, but those skilled in the art should It is understood that various changes can be made and equivalents can be substituted for the elements without departing from the invention. Many modifications can be made to adapt a particular condition or material to the teachings of the present invention without departing from the substance. The invention is not limited to the specific embodiments disclosed for the best mode of the invention, but the invention is intended to cover all embodiments within the scope of the appended claims.

118106.doc 96-

Claims (1)

200831609 X. Patent Application Range: L A shaped article comprising a thermoplastic polymer or a blend of thermoplastic polymers, wherein all or some of the surface of one or more surfaces of the shaped article is covered by a covering material Coating, wherein the covering material has a different composition than the shaped article, and wherein the shaped article comprises one of: a) an immiscible 汆a blend comprising at least one polyether quinone imine, Having more than one glass transition temperature, and wherein the ether quinone imine has a glass transition temperature greater than 217 ° C; b) a miscible polymer blend comprising at least one polyether quinone imine having greater than 217 C Single glass transfer temperature; or c) has greater than 247. Glass of a single polymer that transfers temperature. 2. The article of claim 1 wherein the ratio of carbon atoms to hydrogen atoms of the polyetherimine is between about 0.4 and 〇85. 3. The article of manufacture of claim 1, wherein the polyetherimine is substantially free of benzylated protons. 4. The article of claim 1 wherein the shaped article comprises an immiscible polymer blend having more than one glass transition temperature, wherein one of the poly deltas has a glass transition greater than 180 °C temperature. 5. The article of manufacture of claim 1, wherein the shaped article comprises a miscible polymer blend having a single glass transition temperature greater than 217C. 6. The article of claim 1 wherein the shaped article comprises a single polymer having a glass transition temperature greater than 247 C. 7. The article of claim 1 wherein the covering material comprises one or more selected from the group consisting of powders, flakes, films, fibers, fabrics, molded parts, adhesives, woven materials, A composition of a group of non-coagulated liquids, coagulating liquids, and any combination of such covering materials. The article of claim 1 wherein the covering material is selected from the group consisting of paints, optical coatings, ceramics, conductive coatings, non-conductive coatings, coatings comprising both conductive and non-conductive parts, adhesives and metals. 9. The article of claim 1 comprising a first resin selected from the group consisting of polysulfone, polyether oxime, phenylene ether mill and mixtures thereof, a second resin comprising polyoxyl:polymer, and comprising A blend of a second resin of resorcinol-based aryl polyester tree sap, in the third resin, greater than or equal to 5 Torr. The aryl polyester bond is an aryl ester bond derived from resorcinol. 10. The article of manufacture of claim 9, wherein the polyoxynoxy copolymer is selected from the group consisting of polyamidoxime, polyether oxime oxime, polyether oxime sulfoxide siloxane, polycarbonate A mixture of ester oxime, polyester carbonate oxime, polysulfone oxime, polyether sulfone siloxane, polyphenylene ether oxime, and mixtures thereof. • U· = Products of the item 9 The article wherein the polyoxyloxy copolymer content is from 0.1 to 10.0% by weight of the polymer blend. 12. r. The article of claim 9, wherein the polyoxyloxy copolymer has a content of 5-7 wt%. 13. The article of claim 9 wherein the polyoxy-oxygen copolymer has a decane content of 2 〇 5 重量 重量 / ❶. 14. The article of claim 9, wherein the ratio of hydrogen atoms to carbon atoms (atoms) in the repeating units (monomers) of the polypuland, polyethersulfone, polyphenylene ether, and mixtures thereof is less than or equal to 〇.85. The product of claim 9, wherein the hydrogen atom and the carbon atom (atoms) in the repeating unit (monomer) of the polyfluorene, poly-milling, polyphenylene ether sulfone, and mixtures thereof The ratio is between about 0.40 and about 0.85. The article of manufacture of claim 9, further comprising from 0.1 to 20% by weight of the polymer blend, one or more metal oxides. 17. The article of claim 9, wherein the resorcinol-based aryl I酉9 has the structure shown below: Wherein R is at least one of an alkyl group, (: 6 < 24 aryl, alkylaryl, alkoxy or halogen; and η is 〇·4 and m is at least about 8. 18. The article of claim 17, wherein the resorcinol-based polyester resin is a carbonate-containing copolymer having the structure shown below: Wherein R is at least one of Cm alkyl, CVC24 aryl, aryl, alkoxy or halogen, η is 0-4; R5 is at least one divalent organic group, m is about 4-150 and ρ is about 2-200. 19. The article of manufacture of claim 17, wherein the R5 is derived from a bisphenol compound. 20. The article of claim 1 wherein the phase separated polymer blend comprises 118106.doc 200831609 a mixture of: a) selected from the group consisting of polyaryletherketones, polyaryl ketones, polyether ketones, and polyether ethers. a first resin component of one or more of the groups of ketones; and b) a second resin component comprising at least one polysulfone ether quinone imine, which is greater than or equal to 50 mole % The bond contains at least one aryl group. The article of claim 20, wherein the polyethylidene iodide contains an aryl hydrazine and an aryl ether linkage such that at least 50 mole % of the polyethyl ether quinone imine repeat unit contains at least one aryl ether bond At least one aryl group and at least two aryl quinone bonds. 22. The article of manufacture of claim 20, wherein at least 50 mole percent of the polyethylidene iodide linkages are derived from oxydiphthalic anhydride or a chemical equivalent thereof. 23. The article of manufacture of claim 20, wherein less than 30 mole percent of the polysulfone ether oxime linkage is derived from a diamine or dianhydride containing an isoalkylene group. 24. The article of claim 20, wherein the shaped article has a heat distortion temperature (HDT) greater than or equal to 170 ° C as measured on a 3.2 mm sample at 66 psi (0.46 Mpa) according to ASTM method D648. . 25. The article of manufacture of claim 20, wherein the polysulfone ether iodide is present in an amount of from 30 to 70% by weight of the bulk shaped article. 26. The article of manufacture of claim 20 wherein the shaped article has less than 5% by weight of the fiber reinforcement. 27. The article of claim 20, wherein the shaped article has a modulus greater than about 200 Mpa at 200 ° C as measured by ASTM D5418 on a 3.2 mm sample. 118106.doc 200831609 28. The article of claim 20, wherein the shaped article has a melt viscosity of from 200 to 10,000 Pascals as measured by ASTM Method D3835 at 380 °C. 29. The article of claim 20, wherein the shaped article has a melt viscosity that does not exceed 35 〇/〇 of its initial value after 10 minutes at 38 °C. 30. The article of manufacture of claim 20, wherein the polysulfone ether imine is substantially free of a phenylhydrazine proton. 31. The article of claim 20, wherein the poly(aryl ether ketone), the polyaryl ketone, the polyether ketone, and the polyetheretherketone have a crystalline melting point of 3 Å. 〇 to 38〇. Hey. 32. The article of claim 20, wherein the polysulfone ether imine has a glass transition temperature (Tg) of from 250 °C to 350. Hey. 33. The article of claim 20, as measured by ASTM method D5418, having at least two different glass transition temperatures, wherein the first glass transition temperature is from 120 ° C to 200 ° C and the second glass transition The article has an improved flame retardancy, wherein the shaped article comprises a pigment selected from the group consisting of polyimine, polyether quinone, polyether phthalimide, and the temperature is 25 〇〇c_350 〇C 〇34. a first resin comprising a group of sulfones and a composition thereof, a first resin comprising a polyoxonium copolymer, and a third compound comprising a resorcinol-based aryl polyester resin In the third resin, the aryl polyester bond having a % greater than or equal to the mole % is an aromatic vinegar bond derived from meta-phenylene. 35. The article of claim 34, wherein the polyoxynoxy copolymer is selected from the group consisting of (IV) imine, 7-oxygen, yttrium-imide, poly-imide, vermiculite, and polycarbonate. Appearance, polyester carbonic acid s singular oxy-oxygen, polyfluorite oxime 118106.doc 200831609 36. 37, 38, 39. 40, 41 alkane, polyethersulfone oxirane and polyphenylene ether sulfone oxime One or more of the groups. The article of claim 34, wherein the polyoxymethylene copolymer content is from 〇. to 1〇 〇 weight 〇/〇 of the polymer blend. For example, the article of manufacture of item 34, wherein the polyoxo-oxygen copolymer has a decane content of 2 〇 5 % by weight. The article of manufacture of claim 34, wherein the polyoxo-oxygen copolymer has a decane content of _5-70.0% by weight. The article of claim 34, wherein the ratio of hydrogen atoms to carbon atoms of the polyimine, polyetherimide, polyether sulfoxide, and mixtures thereof is less than or specific to 0.75. The article of manufacture of item 34' further comprises - or a plurality of metal oxides in an amount of up to 20% by weight of the polymeric composition. The article of the invention of claim 34, wherein the phenylene-based aryl polyester has the structure shown below: 42. \ Rn / in wherein R is at least one of a Cw2 alkyl group and a c c element, and the square group means that the radical, the methoxy group or the η is 0-4 and m is at least about 8. : a product article of the request, wherein the isophthalic acid is a copolymer containing a carbonated bond having the structure shown below: E 118106.doc 200831609 Wherein R is at least one of C!-!2 alkyl, C^-C:24 aryl, alkylaryl, alkoxy or halogen, η is 0-4; R5 is at least one divalent organic group Group, m is about 4-150 and ρ is about 2-200. 43. The article of manufacture of claim 42, wherein the R5 is derived from a bisphenol compound. 44. The article of claim 34, wherein the polyimine, polyetherimide or polyetherimine sulfone is prepared from: U) selected from the group consisting of bisphenol A dianhydride, oxygen double neighbors a group of aryl dianhydrides composed of phthalic anhydride, pyromellitic dianhydride, bisphthalic anhydride, sulfonyl dianhydride, sulphur dianhydride, benzophenone dianhydride, and mixtures thereof; and (b) Optional free m-phenylenediamine, p-phenylenediamine, diaminodiphenyl hydrazine, oxydiphenylamine, bisaminophenoxybenzene, bisaminophenoxybiphenyl, bisaminophenyl phenyl hydrazine, An aryl diamine of the group consisting of diaminodiphenyl sulfide and mixtures thereof. 45. The article of manufacture of claim i, wherein the shaped article comprises a copolyetherimine having a glass transition temperature of at least about 218 °C, the copolyetherimine comprising structural units of the two formulas as follows: 〇 0 118106.doc 200831609 Ο π (Π) Wherein R1 comprises an unsubstituted C6-22 divalent aromatic or a substituted 22 divalent aromatic hydrocarbon comprising a halogen or alkyl substituent or a mixture of such substituents; or a divalent group of formula (IV) group: Wherein the group of the isomer of the undefined position of the aromatic ring is at the position or para position between Q and Q is a covalent bond or is selected from the formula (V): (V) 0 -0-, -S-, a member of a group consisting of C or a group of CyH2y alkyl or alkylene groups, in the formula CyH^, y is an integer from 1 to 5, inclusive from 1 to 5, and r2 It is a divalent aryl group; the weight ratio of the unit of the formula [insertion] to the unit of the formula [insertion] is in the range of about 99·9: 〇ι and about 25:75. 46. The article of manufacture of claim 45, which comprises a copolyether quinone imine having greater than 225 art. 47. The article of manufacture of claim 45, which comprises a copolymer of the formula [insert] having the formula [insert] 118106.doc 200831609. 48. The article of claim 45, wherein the Han! is derived from at least one selected from the group consisting of m-phenylenediamine, p-phenylenediamine, 2-methyl-4,6-diethyl-benzene, and 2 females. -Methyl-4,6-diethyl], 3-phenylenediamine, bis(inosylphenyl)-2,2-propane, bis(2-chloroamino-3,5-diethylbenzene Methane, 4,4,-diaminodiphenyl, 3,4'-diaminodiphenyl, 4,4,-diaminodiphenyl ether, 3,4'-diaminodiphenyl Ether, 4,4,-diaminodiphenyl sulfone, 3,4,-diaminobiphenyl wind 4,4-amino benzophenone, 3,4,-diaminobenzophenone, 2 a group of diamines consisting of 4-toluenediamine and mixtures thereof. 49. The article of manufacture of claim 45, wherein R2 is derived from at least one dihydroxy-substituted aromatic hydrocarbon of the formula HO-D-OH, wherein D has the structure of the formula (VII) (Y1) m (R3) p (Y1)m | I, I —A1 r- Λ 1 t E- SA u wherein A1 represents an aryl group; E contains a sulfur-containing bond, a thioether, an anthracene, an anthracene; a bond containing a bond, a phosphonium group, a phosphonium group Ether bond; carbonyl; third nitrogen; oxime bond, decane, decyloxy; cycloaliphatic, cyclopentylene, 3,3,5-trimethylcyclopentylene, cyclohexylene, 3,3-Dimethylcyclohexylene, 3,3,5-trimethylcyclohexylene, indenylcyclohexylene, 2-[2·2·1]-bicycloheptyl, ruthenium , a cyclopentylene group, a cyclocyclododecyl group, an adamantyl group; an alkyl group or a alkylene group, the group optionally being attached to one or more aryl groups having a hydroxy substituent a portion of one or more fused rings; an unsaturated alkylene 118106.doc 200831609 base; or two or more different from alkyl or alkylene groups and selected from a bond-free 苐 diazide bond; an ether bond; ; with a second bond, Shi Xizhuo, decyloxy; a sulfur-containing bond, a thioether, an alkylene, a sulfone; a pendant alkyl group or an alkylene group in which a phosphorus-containing bond, a phosphonium group, and a squaring group are connected; R3 contains hydrogen; a monovalent hydrocarbon group, an alkenyl group, an alkene a propyl group, an alkyl group, an aryl group, an arylalkyl group, an alkylaryl group or a cycloalkyl group; Y is independently selected from the group consisting of inorganic atoms, _ sin; inorganic group 'nitro group; organic group, monovalent hydrocarbon group a group consisting of alkenyl, allyl, alkyl, aryl, aralkyl, alkaryl, cycloalkyl and alkoxy; the letter "m" represents zero and includes zero to Al for substitution Any integer of the number of positions; the letter of the position number "P" means self-zero and includes zero to E to replace the integer; the child "t" means equal to at least an integer, · _ child s indicates special An integer of zero or one; and "V represents any integer, including zero. R2 structural unit phase 50. The article of claim 45, wherein the formula is the same as 0. 51. 52. The article of claim 45 And the middle of the R2 structural unit in the eight T Wang Shao network type is not the same as the J part. Article, J2 R2 Sun Jia K series He Sheng from at least one group selected from the group consisting of the following two groups of aromatic hydrocarbons replaced by 4,4*-(sub-pentyl) diphenol; 4 , 4丨-(3,3,5-tripamethine, T-tiar-pentyl) two; 4,4,- I18106.doc 200831609 (cyclohexylene)diphenol; 4,4,-(3 ,3-dimethylcyclohexylidene)diphenol; 4,4,·(3,3,5-trimethylcyclohexylidene)diphenol; 4,4,-(decylcyclohexylene)diphenol; 4,4'-bis(3,5-diindenyl)diphenol; iota, bis-bis(4-hydroxy-3-methylphenyl)cyclohexane; 4,4-bis(4-hydroxyphenyl) Heptane; 2,4, dihydroxybenzophenone; bis(2-hydroxyphenyl)decane; bis(4-hydroxyphenyl)methane; bis(4-cyano-5-nitrophenyl)anthracene Alkane; bis(4-hydroxy-2,6-dimethyl-3-yloxyphenyl)methane; 1,1-bis(4-hydroxyphenyl)ethane; i,2-bis(4-hydroxyl) Phenyl)ethane; 1,1-bis(4-hydroxy-2-phenylphenyl)ethane; 2,2-bis(4-hydroxyphenyl)propane; 2,2-bis(3-phenyl 4-hydroxyphenyl)propane; 2,2-bis(4-carbyl-3-methylphenyl)propane; 2,2-dual ( 4-hydroxy-3-ethylphenyl)propane; 2,2-bis(4-hydroxy-3-isopropylphenyl)propane; 2,2-bis(4-hydroxy-3,5-dimethyl Phenyl)propane; 3,5,3',5'-tetrakis-4,4,-dihydroxyphenyl)propane; bis(4-hydroxyphenyl)cyclohexylmethane; 2,2-dual (4 -hydroxyphenylphenylpropane; 2,4'-dihydroxyphenyl; ^ wind; dihydroxynaphthalene, 2,6-dipyridyl; hydroquinone; resorcinol; by (: 1,3-alkyl Substituting hydroquinone; 2,2_bis-(4-hydroxyphenyl)butane; 2,2-bis-(4-hydroxyphenyl)-2-methylbutane; 1,1-bis-( 4-Phenylphenyl)cyclohexane; bis-(4-phenylphenyl); bis-(4-hydroxyphenyl) sulfide; 2-(3-methyl-4-hydroxyphenyl-2- (4-phenylphenyl)propane; 2-(3,5-dimethyl-4-hydroxyphenyl)-2-(4-pyridylphenyl)propane; 2-(3-methyl-4 -hydroxyphenyl)_2-(3,5-didecyl-4-hydroxyphenyl)propane; bis-(3,5-dimethylphenyl-4-hydroxyphenyl)decane; 151_double_ (3,5_^monomethyl-based-4-p-phenylene)-ethene; 2,2-bis-(3,5-dimethyl-benbenylphenyl)propane; 2,4-bis-( 3,5-diamidinophenyl phenyl)-2-mercaptobutyl ;3,3-bis-(3,5-diamidinophenyl-4-hydroxyphenyl) 118106.doc -11- 200831609 pentane; 1,1-bis-(3,5-dimethylphenyl) _4_hydroxyphenyl)cyclopentane; U_bis-dimethyl basic-4-phenylphenyl)cyclohexanyl; bis-(3,5·dimercaptophenyl-4-hydroxyphenyl)sulfide Ether, 3·(4-hydroxyphenyl)>^3•triterpeneindan-5-ol; μ(4-hydroxyphenyl)tridecylindan-5-ol, 2,2,2' , 2'-tetrahydro-3,3,3',3丨-tetramethyl-1,1'-spiro[111-茚]_6,6,-diol 0 53. Articles of claim 45 Wherein R2 is derived from bisphenol a. 54. The article of manufacture of claim 45, further comprising a structural unit derived from at least one chain terminator. 55. The article of claim 54, wherein the chain terminator is at least one selected from the group consisting of alkyl halides, alkyl chlorides, aryl cleavage compounds, aryl chlorides, and vapors of the formula Substituted or substituted members: /, the gas substituent is at the 3- or 4-position' and Z3 and Z4 comprise a substituted or unsubstituted alkyl or aryl group. 56. The article of claim 54, wherein the chain terminator is at least one member selected from the group consisting of: chlorodibenzophenone, chlorodiphenyl hard; monochlorophthalimide ; 4-chloro-N-methylphthalimide ' 4-chlorobutyl phthalimide, 4-chloro-: octadecyl phthalimide, 3- Chloromethylphthalimide, 3_chloro_N_ 118106.doc •12- 200831609 Butyl phthalimide, 3-gas-N-octadecyl phthalimide , 4-chlorophenylphthalimide, 3-chloro-N-phenylphthalimide; monosubstituted bis-o-phthalimide; monochlorobis-phenylene Mercaptobenzidine; 1-[Ν-(4-chlorophthalic imino)]-3-(indolyl-phthalimido)benzene; chlorophthalic acid Amino)]-3-(anthracene-o-phthalimido)benzene; monochlorobisphthalimide iminodiphenyl sulfone, monochlorobisphthalimidoiminobenzophenone , chlorobisphthalate iminophenyl ether; 4-[Ν-(4-oxophthalimido)]phenyl-4'-(Ν-o-phthalazinium Amino)phenyl ether 4-[Ν-(3-chlorophthalic imino)phenyl]-4,-(fluorene-phthalimido)phenyl ether and derived from 3,4'-diamine The corresponding isomer of the latter two compounds. 57. The article of claim 45, wherein the weight ratio of the unit of formula I to the unit is in the range of about 99:1 and about 25:75. 58. The article of claim 45, which has a heat distortion temperature of at least 205 ° C below 〇 455 瓜. 59. The article of claim 45, which has a heat distortion temperature of at least 210 under 〇·455. Hey. For example, the article of manufacture of item 45, as measured by ASTM method D3763, has a transfer temperature between the brittle and dynamic states of up to 3 generations. For example, the object of the method of 45 is determined by gel permeation chromatography relative to the polystyrene standard, and the weight and the weight of the knife are about 30, 〇〇〇 and about 8 〇, 〇〇〇 Within the range. The tooth weight comprises a shaped article of the at least two polymer immiscible blends, wherein at least one of the temple polymers has a 60 61 62. 118106.doc • 13- 200831609: a glass transition temperature of a polyether quinone of 24 rc, and additionally wherein all or some of the surfaces of the two articles are coated with a cover, wherein the cover material has a different set than the shaped article 63. An article of matter in the form of a shaped article comprising a miscible polymer blend, wherein at least one of the polymers is a polyetherimine, and further wherein the shaped article is in a surface All or some of the surface Coating by a cover material wherein the cover material has the same shape as the article of material and wherein the shaped article comprises greater than η 7 . A miscible polymer blend of glass transition temperatures. % - an article of matter comprising a single-polymer shaped article, in which all or some of one or more surfaces of the shaped article are coated, wherein the covering material has the shape The composition of the article is different 'and wherein the shaped article comprises having greater than 247. . The glass transition temperature polymer blend. The articles of any one of clauses 7, 16, 30, and 4, wherein the surface of the article or the plurality of surfaces is covered by the metal composition and exhibits no less than about 35 % total reflectance. For example, the article of claim 62, wherein the or the 4 surface covered by the metal composition exhibits a total reflectance of no less than about 5%. The article of manufacture of claim 62, wherein the surface is covered by the metal composition exhibiting a total reflectance of no less than about 65%. The article of manufacture of claim 62, wherein the or the surface covered by the non-metallic composition exhibits a total reflectance of not less than about 65%. 118. The method of claim 62, wherein the or the surface covered by the metal composition exhibits a total reflectance of not less than about 75%. 7. The article of claim 62, wherein the or the surface covered by the metal composition exhibits a total reflectance of no less than about 85%. 71. The article of manufacture of claim 62, wherein the or the surface covered by the metal composition exhibits a total reflectance of no less than about 9%. The article of claim 62, wherein the or the surface covered by the metal composition exhibits a total reflectance of no less than about 95%. 73. A product article of the request, wherein the article comprises a single phase tree sorghum blend of the following materials: a) selected from the group consisting of polysulfone, polyether sulfone, polyphenylene ether sulfone, and the like: a first resin of the group; b) a first: a resin comprising a polyoxyloxy copolymer; c) a third tree comprising a resorcinol-based aryl poly-resin resin 2's towel greater than or equal to 5 The aryl group (tetra) bond of 〇mol is an aryl ester bond derived from resorcinol; and the sentence contains one or more selected from the group consisting of polyarylene ether, polycarbonate, polyester carbon, polyfluorene, polyamine and poly | The fourth resin of the resin of the group. 74. The article of claim i, wherein the shaped article comprises a single phase amorphous resin blend selected from the group consisting of a polyether oxime, an amine, and a single phase blend comprising a polyester and a polyether quinone imine. Compound. /5. The article of manufacture of any one of the items 2, 16, 16, 3, and 4, wherein the covering material comprises one or more metals. The article of matter of item 73, wherein the diffuse reflectance of the metal-covered surface is no greater than about 1 〇/0. 77. A product item of the item 73 of May, wherein the turbidity value of the metal surface of the cover is 118106.doc • 15· 200831609 78. Not more than about 1%. The article of manufacture of claim 73, wherein the metal-coated surface comprises a metal selected from the group consisting of aluminum, copper, silver, gold, nickel, palladium, platinum, zinc, and an alloy comprising at least one of the foregoing. 79. The article of manufacture of claim 78, wherein the metal covering comprises aluminum. 80. The article of manufacture of any of claims 1 or 78, wherein the article comprises a lighting regulator or reflector. 81. The article of manufacture of claim 1, wherein the article comprises a headlight reflector. 82. The article of manufacture of claim 1 or claim 78, wherein the article comprises an LED reflector. 83. The article of manufacture of any of claims 1, 7, 16, 30 or 40, which further comprises a compound comprising at least one boron atom. 84. The article of manufacture of any of claims 1, 7, 16, 30 or 40, which has a heat release of less than about 60 kW-min/m2 as measured by FAR 25.853. The article of manufacture of any of claims 1, 7, 16, 30 or 40, having an exothermic peak of less than about 80 kW/m2 as measured by FAR 25.853. 86. The article of manufacture of any of claims 1, 7, 16, 30, or 40, wherein the shaped article comprises a tensile elongation at break of greater than or equal to about 50% as measured by ASTM D638. Polymer blend. 87. The article of manufacture of claim 1, 7, 16, 30 or 40, wherein the flame retardant polymer blend has a large 118106.doc -16 - 200831609 as measured by ASTM D790 Or equal to a flexural modulus of approximately 300 Kpsi (2070 Mpa). 88. The article of manufacture of claim i, wherein the shaped article encloses at least one material having a Tg of 218 ° C or higher. 89. The article of manufacture of claim 1, wherein the shaped article comprises at least one material having a Tg of 219 ° C or higher. 90. The article of manufacture of claim 1, wherein the shaped article comprises at least one material having a Tg of 220 ° C or higher. 91. The article of manufacture of claim i, wherein the shaped article comprises at least one of Tg 221 . (a material of claim i. 92. The article of claim i, wherein the shaped article comprises at least one material having a Tg of 222 ° C or higher. 93. The article of claim 1 wherein the shaping The article comprises at least one material having a Tg of 223 ° C or higher. 94. The article of claim 1 wherein the shaped article comprises at least one material having a Tg of 224 ° C or higher. 95. The article of manufacture, wherein the shaped article comprises at least one material having a Tg of 225 ° C or higher. 96. The article of claim 1 wherein the shaped article comprises at least one Tg of 230 ° C or higher 97. The article of claim 1 , wherein the shaped article comprises at least one material having a Tg of 235 ° C or higher. 98. The article of claim 1 wherein the shaped article comprises at least one of g is a material of 24 〇 C or more. 99. A product article of the request, wherein the shaped article comprises at least 118106.doc -17. 200831609 a material having a Tg of 245 ° C or higher. Item i The article, wherein the article, comprises at least one material having a Tg of 250 ° C or higher. 101. The article of claim i, wherein the dome comprises at least one of Tg 255. 102 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 The shaped article comprises at least one material having a Tg of 265. or higher. A product article of the request, wherein the shaped article comprises at least one of the materials having a Tg of 270 C or more. 105. An article, wherein the shaped article comprises at least one material having a Tg of 275 ° C or higher. 106. The article of claim of claim 1, wherein the shaped article comprises at least one of Tg of 3 〇〇 ° C or higher 107. The article of claim 1 , wherein the shaped article comprises at least one material having a Tg of 35 〇. or higher. 108. The article of claim i, wherein the shaped article comprises At least one Tg is between about 225 ° C and 250. (: material between: 109. The article of claim i, wherein the shaped article comprises at least one Tg of between about 250. 〇 and 275 ° C The article of claim 1 , wherein the shaped article comprises at least one material having a Tg between about 275 ° C and 300 〇. 111. The article of claim 1 wherein the shaped article comprises Among them at least 118106.doc -18- 200831609 a Tg at about 30 (rc and 35 (rc between materials). 112. An article of matter in the form of a shaped article comprising a polymer blend, wherein all or some of the surfaces of the shaped article are coated with a cover material, wherein the cover material has a shape with the shape a different composition of the article, and wherein the shaped article comprises one of:) an immiscible polymer blend having more than one glass transition temperature and wherein the lowest glass transition temperature is: 140 C; b) having greater than 2 Single ❿-glass transition temperature miscible polymer blend; or. a single polymer having a glass transition temperature greater than (d), and wherein one or more of the polymers a), b) or c) are free of stupid U3. The article of manufacture, or all or some of the surfaces of the article - are coated with a coating material wherein the covering material has a composition different from that of the shaped article and wherein the shaped article comprises one of the following: a) an immiscible polymer blend having one or more glass transition temperatures and wherein the lowest glass transition temperature is greater than 1: b) a miscible polymer composition having a single wcttr degree greater than (10); or Ratio of hydrogen atoms to carbon atoms of a repeating unit having one or more of the glass transition temperatures greater than 247 C, u ' early polymer, and which constitutes one or more of the poly Less than or equal to 0 85. Π4· The article of claim 7, 1 _ and its mixture repeating monomer 飒, (4), polyphenyl (tetra) to the ratio of hydrogen atoms to carbon atoms in about H5. - containing thermoplastic polymer or thermoplastic polymerization Shape of the blend of materials 118106.doc • 19- 200831609 Article of the article 'where the shaped object - or a plurality of surfaces, 5' - the surface is coated with a covering material, wherein the covering material has a different shape than the shaped article Composition, and wherein the shaped article comprises one of the following: φ a a) an immiscible poly blend comprising at least one polyether quinone imine having more than one glass transition temperature and wherein The polyiminable imine has a glass transition temperature greater than 217 t; b) comprises at least one polyether oxime yoghurt polymer blend having a single glass transition temperature greater than C; or 〇) a glass having greater than 247 c The ratio of the number of hydrogen atoms to the number of carbon atoms in the PEI in the a) or b) is 0.40.085. The article comprises a product article in the form of a shaped article of a polymeric compound, which covers all or some of the surfaces of one or more of the objects; coating 'where the covering material has a different shape than the shaped article And wherein the shaped object comprises the following materials: a) having more than one glass, the phoenix and/or the medium minimum glass transition temperature is greater than the immiscible polymer blend; b) having greater than 217. . a single glass transition temperature miscible, 玄 247 ° Γ ^ ^ δ blend; or (〇 has a glass transition temperature greater than 247 C Μ Μ “ 早 早 且 且 且 且 且 且 且 and a), b) or The refractive index of one or more of the polymers of c). 7. The object of claim 116, above: s. 62. One or one of the objects or coatings of the 仟 疋 疋 is in the form of a foam. A composite sheet material comprising: at least one porous core layer, the layer comprising at least one thermoplastic material selected from the group consisting of: a) having more than one glass transition temperature 118106.doc - 20. 200831609 and an immiscible polymer blend having a minimum glass transition temperature greater than 140t; b) a miscible polymer blend having a single glass transition temperature greater than 217T; or c) having greater than 247t: a single polymer having a glass transition temperature; and fibers of from about 20% by weight to about 8% by weight based on the total weight of the porous core layer; and at least a sheath, each covering at least one of the at least one porous core layer - part of the surface, The outer skin comprises a thermoplastic film, an elastomer ★, a metal foil, a thermosetting coating, an inorganic coating, a fiber-based scrim, a non-woven fabric, and a woven fabric, as measured according to Brain 4589. The limiting oxygen index is greater than about 22. 119. An article of matter in the form of a shaped article comprising a polymer blend, wherein all or some of the surfaces of the two-shaped article are coated with a material The covering material has a different composition from the shaped object: and wherein the shaped article comprises one of the following: a) no 2 base hydrogen, having more than one glass transition temperature and wherein the minimum glass degree is greater than un: unmixable Soluble polymer blend; b) benzene free: = a miscible bismuth compound having a single glass transition temperature greater than 217 °; or a single polymer having a glass transition temperature greater than 24 rc. A product article in the form of a shaped article of a material composition, wherein all or some of the surfaces of one or more of the covering members are composed of 'the covering material having the shaped object Different, and formed, and wherein the shaped article comprises one of the following substances: a) excluding 118106.doc • 21· 200831609 a benzylated proton, an immiscible polymer blend having more than one glass transition temperature and wherein the lowest glass transition temperature is greater than 140 ° C; b) comprising at least one polyether quinone imine having a Tg greater than 217 ° C, a miscible polymer blend having a single glass transition temperature; or c) a single polymer having a glass transition temperature greater than 247 °C. 118106.doc 22- 200831609 VII. Designation of Representative Representatives (1) The representative representative of the case is: (none) (2) A brief description of the component symbols of this representative figure·· _ VIII. If there is a chemical formula in this case, please reveal the most Chemical formula that shows the characteristics of the invention: (none) 118106.doc