TW200814927A - Active compound combinations having insecticidal and acaricidal properties - Google Patents

Abstract

The present invention relates to novel active compound combinations comprising firstly at least one known compound of the formula (I), in which R is as defined in the description, and secondly at least one further known active compound from the class of the pyrethroids, which combinations are highly suitable for controlling animal pests such as insects and unwanted acarids.

Description

200814927 IX. DESCRIPTION OF THE INVENTION: TECHNICAL FIELD OF THE INVENTION The present invention relates to novel active compound compositions comprising, firstly, at least one compound of formula (I) known, and secondly, at least one other class Compounds of pyrethroids, such compositions are highly suitable for controlling animal pests, such as insects and unwanted mites. [Prior Art] Compounds of formula (I) are known.

N

N-R

CI (I) wherein R represents a methyl or cyclopropyl group having insecticidal activity (Reference: ΕΡ-Α 0 539 588), specifically, the relevant compound may be compound (la) and (lb): 20 (la) ):

N

CI

N——CH. (la) -6- 200814927 (lb) ·· (lb)

10

SUMMARY OF THE INVENTION Furthermore, it is known that certain compounds from pyrethroids have insecticidal and acaricidal properties, and it has now been found that at least one compound of formula (I) and at least one selected from Includes the following classes of compounds: 1. Aninin (acrinathrin)

15

Learned from: EP_A-048 186, 2. alpha-cypermethin

200814927 Learned from: EP-A-067 461, 3 · β-赛康宁 (betacyfluthrin)

Learned from: EP-A-206 149, ίο 4. γ_ 赛马宁 (gamma-cyhalothrin)

Learned from: DE-A-2 802 962, 5. Cypermethrin

〇 CN

Learned from: DE-A-2 326 077, 6. Detamethrin 20 200814927

10 Learned from: DE-A-2 326 077, esfenvalerate

15

Learned from: DE-A-2 737 297, 8. Efenning (ethofenprox)

Learned from: DE-A-3 117 510, 9. Fenpropathin 20

Learned from: DE-A-2 231 312, -9- 200814927 10. Fenvalerate

10 Learned from: DE-A-2 335 347, 11·flucythrinate

Learned from: DE-A-2 757 066, 15

12. λ-赛洛宁 (lambda-cyhalothrin) 20

Learned from: EP-A-106 469, 13. Permethrin -10- 200814927

Learned from: DE-A-2 326 077, 14. Fortune (taufluvalinate)

10

Learned from: EP-A-038 617, 15. Tralomethrin 15

Learned from: DE-A-2 742 546, 16, zeta-cypermethrin 20

200814927 Learned from: EP-A-026 542, 17. cy fluthrin

5

10 Learned from: DE-A-27 09 264, 18. Bifenthrin

Learned from: EP-A-049 977, 19. cycloprothrin 15

Learned from: DE-A-2653189, 20·eflusilanate 20 200814927

5 Learned from: DE-A-36 04 781, 21 · Fuffenprox

10

Learned from: DE-A-37 08 231, 22. Pyrethrin (pyrethrin) 15

20 R = -CH3 or -C02CH3 version 11, R! -CH=CH2 or "CH3 or -ch2ch3 learned from: The Pesticide Manual, 1997, p. 1056, 23. Resmethrin -13- 200814927

Learned from: GB-A] 168 797, and 24. Tefluthrin

F CH0 is known from: EP-A1 31 199, 15 20 The composition produced is a synergistic active and suitable for controlling animal pests, surprisingly, the active compound composition according to the invention is killed The insect and acaricidal activity is much greater than the sum of the activities of the individual active compounds. There is an unanticipated true synergistic effect, and not just the additive value of the activity. In addition to at least one active compound of the formula (I), the active compound composition according to the invention comprises at least one pyrethroids which are individually listed in the above 1 to 24 species. Preferably, the active compound composition according to the invention comprises an active compound of one of formula (la)-14-200814927 or (lb) and from 1 to 24 pyrethroids individually listed above. One. The compositions listed in Table 1 are in accordance with preferred embodiments of the present invention. Table 1

The mixture comprises the compound pyrethroids of formula (I) 1. Ia and 1 arrinathrin 2. la and 2 α-cypermethrin 3. Ia and 3 β-saiconin ( Betacyfluthrin) 4. Ia and 4 gamma-cyhalothrin 5· Ia and 5 cypermetMn 6. la and 6 deltamethrin 7. la and 7 esfenvalerate 8. Ia and 8 etfinenprox 9. la and 9 fenpropatMn 10. la and 10 fenvalerate 11. Ia and 11 flucythrinate 12. Ia and 12 λ - lambda-cyhalothrin 13. Ia and 13 permethrin 14. Ia and 14 sets of taufluvalinate 15. Ia and 15 tralmethrin 16. la and 16 (zeta -赛杀宁)(zeta-cypermethrin) -15- 200814927 17. Ia and 17 cy fluthrin 18. la and 18 bifenthrin 19. la and 19 cycloprothrin 20. Ia and 20 Eflusilanate 21. Ia and 21 fiiffenprox 22. la and 22 pyrethrin 23. Ia and 23 resmethrin 24. Ia and 24 tefluthrin In addition, the compositions listed in Table 2 are also preferred embodiments in accordance with the present invention. 5 Table 2

The mixture comprises the compound pyrethroids of formula (I) 1. lb and 1 acdnathrin 2. lb and 2 α-cypermethrin 3. lb and 3 β-赛保宁 ( Betacyfluthrin) 4. lb and 4 gamma-cyhalothrin 5. lb and 5 cypermethrin 6· lb and 6 deltamethrin 7. lb and 7 esfenvalerate 8· lb and 8 etfinenprox 9' lb and 9 fenpropathrin -16- 200814927 10. Ib and 1 fenvalerate 11. lb and 11 flucythrinate 12 Ib and 12 lambda-cyhalothrin 13. Ib and 13 permethrin 14. Ib and 14 sets of taufluvalinate 15. Ib and 15 tralmethrin 16. Ib and 16 (zeta-cypermethiniii) 17. Ib and 17 cyfluthrin 18. Ib and 18 bifenthrin 19. Ib and 19 cycloprothrin 20. Ib and 20 Eflusilanate 21. Ib and 21 fubfenprox 22. Ib and 22 de-worming Pyrethrin 23. Ib and 23 resmethrin 24. Ib and 24 tefluthrin This synergistic effect is especially in the active compound composition according to the invention. The weight ratio is apparent in the presence of a weight ratio, however, the weight ratio between the active compounds in the active compound composition can vary within a relatively wide range. Generally, the active compounds of formula (I) and from 1 to 24 are included according to the invention. A preferred and particularly preferred mixing ratio of the pyrethroid-like composition is: -17- 200814927 Preferred mixing ratio: 125:1 to 1:125 Particularly good mixing ratio 25:1 to 1:25 This mixing ratio is based on the weight ratio, and the weight ratio is understood to mean the active compound of the formula (1): pyrethroids. 5 The active compound composition of the present invention, in combination, is well tolerated by plants and its toxicity is beneficial to warm-blooded animals, and can endure the environment well, and is suitable for protecting plants and Plant organs, for enhanced harvesting | quantity, for improving the quality of harvested materials and for controlling pests, especially with agriculture, horticulture, animal husbandry, forestry, gardens and leisure facilities, 10 storage of products and materials, And related insects, mites, worms, nematodes and mollusks in the health field, they should be used as a plant protection agent, they are active against normal sensitive and resistant species, and against them. For all or individual developmental stages, the above-mentioned pests include: 15 Anoplura (Phthiraptera) organisms, for example, Damalinia spp., t 铋M (Haematopinus spp.), Rhododendron spp. Genus (Pediculus π/?·), Ranunculus

(Trichodectes spp.) Q Arachnida organisms, for example, 20 n 粗 ) , , 桔 桔 桔 桔 桔 桔 桔 桔 桔 桔 桔 桔 桔 桔 桔 ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; Dcw/ws spp·, Amaranthus (Amblyomma 5), Argas spp, Boophilus (Spirit ρ·), Brevipalpus spp., Selling moth (Bryobia) Praetiosa), itch-like genus, chicken skin thorn (Derw (four)), worm-like spider -18- 200814927 5

10 15

20 Eutetranychus spp., Eriophyes spp., Eriophyes spp., Hemitarsonemus spp., genus (//ya/omwa π;?·), hard 蜱Genus (Τχοί/α s/?;?·), black widow, latrodectus mactans, $KMetatetranychus spp., Oligonychus spp., Ornithodoros spp., spider (Panonychus spp·), Phyllocoptruta oleivora, Polyphagotarsonemus latus, Psoroptes spp·, Rhipicephalus spp., Rhizoglyphus spp· , Sarcoptes spp., Scorpio maurus, Stenotarsonemus spp., Tarsonemus spp., $cl Tetranychus spp., Vasates lycopersici. A bivalve (Bivalva) organism, for example, a Chilopoda creature, for example, a genus Spp·, a fisherman M (Scutigera spp., a Coleoptera creature, for example, a bean bean o& eciMS), long golden tortoise (yUoreiws sigh /7·), eucalyptus sylvestris (dge/fl such as cfl, golden worm (dgrbies s/τρ·), horse age collection (Amphimallon solstitialis), like 倶Anobium punctatum, Anoplophora πρ·, Anthonomus spp., Anthrenus spp., Apogonia spp., Atomaria spp .), ticket, good idiot {Attagenus spp), ll {Bruchidius obtectus), l I blast [Bruchus spp.), 1 oxygen t{Ceuthorhyhchus spp·,, Cleonus -19- 200814927 mendicus, Conoderus spp·, H nose {Cosmopolites spp·,, ^%H{Cryptorhynchus lapathi), l 亀 亀 {Dermestes spp·, DDiabrotica spp·, Epiiachna spp·, 5 scoop ^XEpilachna spp· , Faustinus cubae, naked or [Gibbium psylloides), Heteronychus arator, Hylamorpha e Legans, North American yak 〇Κ / / 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 leg leg leg leg leg leg leg leg leg leg leg leg leg leg leg leg leg leg leg leg leg leg leg leg leg leg leg {Lissorhoptrus oryzophilus), Lz·胤s spp·), Lyctus spp., Meligethes aeneus, Melolontha melolontha, {Migdolus spp), year of the year {Monochamus spp〇5 ® S ^^(Naupactus xanthographus) 9 ψ (Niptus 15 hololeucus), 厍 金 {Oryctes rhinoceros), forged boxes • (Oryzaephilus surinamensis), black grapes Otiorrhynchus, Cbcyceiow/a Jwewwi/a, Phaedon cochleariae, Phylchoga spp., H 豕 龟, 小 (Pre/w(10)πρ·) , Psylliodes chrysocephala, Ptinus spp.

Rhizobius ventralis, family Rhizopertha dominica, KSitophilus spp·), Sphenophorus spp·, Sternechus spp·, Symphyletes spp·, XTenebrio molitor, Tribolium spp· , Trogoderma spp., like 1f (Tychius -20- 200814927 spp·), Xyhtrechus spp., Modulus step (Zabrus SPP·, Collembola) For example, hoppers (〇. he and armatus) ° 5 genus (DermaPt (10)) organisms, for example, the European 蠼auricularia) D 〇 纲 ( (Diplopoda) organisms, for example, with zebra land (Shi gu guttulatus) ° double Diptera (for example, Aedes sinensis), by 10 Anopheles spp., Bibio hortulanus, Red-headed flies (Cfl/ZbAora, Mediterranean fruit fly (Cer^) m. along cflpfiflia), genus Gypsophila (C7i〇^om>^ sir), Spiral Flies (Cochliomyia spp.) 'Corporate Tumor Sister (Cor Office / οΜα anthropophaga), 瘅 瘅 (Culex spp. ), genus (Cuterebra 15 spp.) > /) This milk thistle / (10) e), skin fly • Aown / i / s) 'fruit rope 577 / 7.., toilet rope (Fimw / α printed /? ·), stomach rope is printed; 7.), the rope属 *?/?;?·), genus Hyppobosca spp., Hypoderma spp., Liriomyza spp., Lucilia spp., Musca Spp·), 20 Nezara spp·, Nasal genus 57?;?·), Swedish straw rope (C^c/«e//a/h7) 'Beet leafy flower rope Aj; c^cj; izmz· ), spring wheat (Phomabia spp.), I Trangoxys spp., Tabanus spp, Tannia spp, Tipula paludosa, Wohlfahrtia Spp.). -21 - 200814927 Gastropoda creatures, for example, Aryan (10) sigh /?·), flat peak (10,000 spp·), blister snail (square spp), ero (Derocenxs spp·), bandit Genus (Ga/heart spp·), snail (Aymnfleiz spp.), snail (C) «come/(3nfa spp.), spp·) 〇5 Helminths, for example, duodenal hookworm {Ancylostoma Duodenale), Ceylon worm (cey/izw/cwm), Brazilian hookworm (jc less/oWowfl braziliensis), hookworm (Ancylostoma spp.), fine sense (Ascaris lubricoides), elephant genus *?/?;? ), Malay Filaria (Brwg/a mfl/noisy), Brugia timorf, Bunostomum spp·, ^XChabertia spp·, Clonorchis spp·, leather-replacement Elephant 餍 (Cooperia), Gun genus (Z)/crc?C (9e//wm ρ·), filamentous worm (Dictyocaulus filaria),% Xin sXDiphyllobothrium latum), Long Qin Dracunculus medinensis, Echinococcus 15 granulosus, XEchinococcus multilocularis, JEnterobius vermicularis, Faciola spp·, Twist 1 transfer is πρ·), crypt (Zie/erflKs π;?·), short capsule (Hymenolepis nana), Hyostrongulus spp·, Luo Μ 丝, 备(16^1^0), duodenum Nematode within the genus (^>like ^/?;7.), 20 knots & (Oesophagostomum spp.) 'Opisthorchis spp.', green tail, XOnchocerca volvulus), Ostertagia spp, Paragonimus spp, Schistosomen spp, Strongyloides fuellebomi, Dung 4, rod, thread (Strongyloides stercoralis), Stronyloides spp., not enough beauty -22- 200814927 5

10 15

20 (Taenia saginata), Taenia soHum, Trichinella spiralis, Trichinella nativa, Trichinella britovi, Trichinella nelsoni, Trichinella pseudopsiralis , Trichostrongulus spp., Trichuris trichuria, Wuchereria bancrofti. It is also possible to control protozoa, for example, Eimeria. Heteroptera organisms, for example, Phytophthora (乂(10) like tristis), Antestiopsis spp·, Blissus spp., Calocoris spp., Campylomma livida, Cavelierus spp. , Cimex spp·, H Mao Dongfeng (Creontiades dilutus), pepper 蝽 《 "ws piperis", Dichelops furcatus,

Diconocoris 厶ewe#/, cotton red 蝽spp·,, brown eucalyptus (Euschistus spp.), genus Eurygaster spp., Heliopeltis spp·, Horcias nobilellus, peak pain {Leptocorisa spp.), leaf foot Leptolossus phyllopus, Lygus spp., sturdy black scorpion (from (3 (:^9/? to (: 仰加), 蝽) (^/^>/ (^ shape), Nezara spp., Oebalus spp., Pentomidae, beet 拟 network (朽^^(2^^(3 (3/(3), 埯( Corpse / with 0 ^ / (9 factory like * 5 / 7; 7.), cotton pseudo-spotted legs blind 蝽〇 P such as / / ws ser / aiws), persea, cone worm (Rhodnius spp), 3 can be bred {Sahlbergella singularis, Scotinophora spp, Stephanitis nashf, Tibraca spp·, Suction: Triatoma spp. Homoptera, for example, green feather Genus (Acyrthosipon spp.), Aeneolamia spp., Agonoscena spp·, -23- 200814927 powdery, vegetable mealworm «treatment", cotton ^{Aleurothrixus spp.) 9 Amrasca spp. > Anuraphis cardui ^ 4(10)577/7·), pear tumor wealth (々?/z(10)ow/gmapzW), Fruit field (Aphis spp.), Arboridia apicalis, Aspidiella spp., Aspidiotus spp., Atanus spp., Aulacorthum solani ^ ^ ^ (Bemisia spp.) > ^ A ^ (Brachycaudus /ze//c/z^)^z·/), microtubular worm sp;?·), vegetable [blowing powder] p iBrevicoryne, small rice brown fly (CW/z'gypowiz marginata), Carneocephala fulgida, to CumMvizcwwfl /a?n'gem, Cercopidae, Ceroplastes spp., Chaetosiphon /rflgfle/i> //z·), Yan Huang Xuedun fega/ewsb), Chlorita onukii, Walnut black, Chromaphis juglandicola, Tea brown 蛉 (CTzrysom/^a^s/icMS), 叶蝉w~ 7(2), 15 Coccomytilus halli, Coccus spp·, Cryptomyzus • ribis, Dalbulus spp., ^ ^ (Dialeurodes spp., Diaphorina spp., Diaspis spp.) , Drosicha s;?;?,), CDysap/n's, powderworm (D^Asmz.caccws, micro-leaf sigh/?.), apple (mian) insect sigh/?·), spot Leaf 20 蝉[Er Ythroneura spp.), Eucelelis bilobatus, Geococcws cojffeae ' 琉 蝉 蝉 (//oma/oi/isca coagw/aia) '桃大尾财(办《/〇;?仏隐 s arw /zi/z·«以), ( cerjfl , Idiocerus spp., Idioscopus spp., inverse level {Laodelphax striatellus) y (Lecanium spp.), blast (Lepidosaphes -24- 200814927

10 15

20 明!?.), mustard, worm, worm, spp·), Mahanarva fimbriolata, Melanaphis sacchari, Metcalfiella spp·, I (Metopolophium dirhodum), black, marginal spot Monellia costcdis, Monelliopsis pecafnj, genus (Myzws printed /?), lettuce money (on (10) "ον/α, black-tailed 蝉s/?;?.), rice brown feizi {Nilaparvata lugens 5 Oncometopia spp., Metaphor (Orthezia, ParMemzWa myrfci/e, Woodworm (Parair/ozfl s/?/?.), Star Shield (Par/izior/a π;?· ), 瘿 虫 ( (PempAfgMs sigh /?·) 'Peregn'WMs mafi/zj, Phenacoccus spp. 5 Phloeomyzus passerinii ^ Phorodon humuli, Phylloxera spp. ), Pinnaspis aspidistrae, Planococcus spp., Protopulvinaria pyriformis, Pseudaulacaspis pentagona, Pseudococcus spp., Psylla spp. ), Pteromalus spp., Pyrilla spp., Wi * (Quadraspidiotus spp.), Quesada gigas , Rastrococcus spp., Rhopalosiphum spp.?k, Saissetia spp., Scaphoides titanus, Schimaphis, West Indian sylvestris (iSe/ewflwzWws ariz. Cw/aiws), Inaz OSogflia sigh /?·), Whitebacked worm/wrcz/era), Flying worm (Sogatodes spp.) 5 ^ ^{Stictocephala festina) 5 Tenalaphara, American walnut black fangs (77«0Ciz/ //*s, 蝉 spp·), 岔 岔 ( (Tbxoj^era *?/?;?·), greenhouse mealworm-25- 200814927 (Trialeurodes vaporariorum), 豕 grade (Trioza spp.),,},叶缉spp·), shield sighs;?.), grape root nodule teeth (smart like vitifoli) ° 5

10 15

20 Hymenoptera organisms, for example, Eucalyptus (Ζ) ζ·;?η·(10) SPP.), Hopiocampa spp., Lasius spp·, ♦ (Monomorium pharaonis), Vespa spp. Isopoda creature, for example, vw/gare, ball rat (6>«仏cms like 6//milk), black worm Scaber) Isoptera, for example, the termite genus spp.) ^ Termite (Odontotermes *?/?/?·) Lepidoptera, for example, white caterpillar (Jcrom'cM ma/ Or), Electric Moth (dei/z.fl /ewcowe/iZ5), Night Moth Print /?·), Cotton Leaf Spodoptera argi//aeea), Soybean Spodoptera 5 (), Cabbageworm, Cotton leaf perforated moth (Bucculatrix thurberiella), Bulkus piniarius, Caoeck, G3/7Wiz reifcw/β/ΐβ, Icarocapsa pomonella, Cheimatobia brumata, snail (7/»7(>印/7.), spruce leaf moth ((^0 plant plus 6^xianguang (2/^/ and /67^«(3), grape fruit moth (C7j^fl, Liriodendron (C/iflpAiz/ocemy 57?;?·), cotton spotted moth Five π/like insulana), micro town (Ephestia, brown tail moth (five w/?n9ciz\s, cut rootworm 5^/7.), brown leaf moth (Fe/such as s/7;?·), Giz//enh mellonella ' Helicoverpa spp., Heliothis spp·, -26- 200814927, Hofmannophila pseudospretella, Homona magnanima, Hyponomeuta padella, night Moth (Laphygma spp.), XLithocolletis blancardella), Lithhophane antennata, Loxagrotis albicosta, dance [Qin] weaving 5 *?/?/?·), Canopy caterpillar (Ma/izcosoma «ewsirz'fl ), Cabbageworm (MameWriz, M. meridae)

Mythimna separata, Oria spp., Oulema _ or less zee, CPfl/io/zi/Zammefl, (Pectinophora gossypiella), orange fine Moth (corpse /^//oc« along 10 citrelld), Cabbage spp., Plutella xylostella P/wie//a xylostella), Prodenia spp., Pseudaletia spp. Soybean larvae / this / wde like), wild model (jPjKrizwWfl nubilalis), [point preparation] night weaving (Spodoptera spp), Thermesia gemmatalis, nettle moth (Tinea pellionella), baggy moth (Tineola 15 bisselliella), steady leaf Moth (Tortrix viridana), Noctuidae (Trichoplusia _ ring). Orthoptera organisms, for example, house moths, 蟀dome ' 'cms), oriental 蜚蠊 (Β/βίίβ oWe«ia//s), German cockroaches (5/αίίβ//α germawica), 蝼蛄 ( G^y//(9i(3/pa India/?·), Leucophaea maderae, Flying Emperor spp.), Melanoplus spp., American creep: (Periplaneta Americana ), the wasteland worms OSc/n• ocercfl gregar/a) The genus (Siphonaptera) organisms, for example, the genus Ceratophyllus spp., Oriental tKXenopsylla cheopis. -27- 200814927 Symphya organism, for example, Scutigerella immaculata, Thysanoptera, for example, rice locust (such as /(6) biformis), Enneothrips flavens, t 蓿箾马Frankliniella 5 cases?·), Hummer (Heliothrips 577;?·), Greenhouse horses buckle femoralis) ·' Kakothrips spp· '气镇】钱马^Rhipiphorothrips cruentatus), Hummer {ScirtothHps spp.), Guan Ma (jaeni〇thrips sold cardamoni), Suma {Thrips spp·, Th 缨 ura (Thysanura) organism, for example, 10 saccharina) 0 Plant parasitic line bombs include, for example, the genus Trichomonas MP.) ' Leaf buds Nematodes (Aphelenchoides sigh/?·), spp·, sinensis XBosaphelenchus spp·), i worm XDUylenchus dipsaci) 'Globodera spp', Heliocotylenchus 15 spp· 'tL t each (Heterodera spp. ), qi qi {JLongidorus ps/?;?·), Rhizoctonia genus 57?;?), root rot nematode {Pratylenchus spp.), snail gas (Radopholus similes), snail, snail (Rotylenchus spp·), Root line (Trichodorus spp.), post-chemical according to & (Tylenchorhynchus spp.), the image of the insect XTylenchulus 20 sigh ·), citrus elegans; (do / e / ic / zw / (10), the sword genus { Xiphinema spp.) 0 suitably, the active bead composition according to the invention may also act as a herbicide, safener, growth regulator or agent for improving the properties of plants, or at certain concentrations or application rates, or As a microbicide {for example, as a fungal agent, an anti-infective agent, a bactericide, a viricide [including as a viroid agent], or as an anti-ML 〇 (mycoplasma-like microorganism) and RLO (Microorganisms of the genus rickettsia) are used, and, where appropriate, they are also used as intermediates or as a precursor to be used for the synthesis of other active compounds. According to the present invention, it can be used to treat plants and plant parts of a whole plant. It is understood that the term "plant" refers to all plants and plant groups, for example, desired and unwanted wild plants or crop plants (including natural occurrences). Crops, plants, plants that can be bred, from traditional breeding and optimization methods, or through biotechnology and genetic engineering, or combined with these methods, including transgenic genes Plants and unprotected plant species including those that are subject to the rights of planters; plant parts are understood to refer to plants on the surface and all plants in the underground part with crying officials, for example, young shoots, leaves , flowers and roots, examples which may be mentioned are leaves 15 20 leaves, stems, tree stems, flowers, fruit bodies, fruits, seeds, roots, bulbs and stolons; parts of plants also include harvested materials and growth in the middle The treatment of plants and plant parts with active compounds according to the invention, for example, seedlings, bulbs, stolons, cuttings and seeds, is treated directly in a conventional manner The plant itself acts on its u environment, living space or storage, for example by dipping, spraying, dizzying, spreading, spreading, injecting, and, for u ", 政可% Special 3 seeds can still be treated by applying one or more layers of coating.活性 活性 活性 疋 疋 疋 疋 疋 疋 疋 疋 疋 疋 疋 疋 疋 疋 疋 疋 疋 疋 疋 疋 疋 疋 疋 疋 疋 疋 疋 疋 疋 疋 疋 疋 疋 疋 疋 疋 疋 疋

10 15

20 = object, better - 'Therefore, the pests of the crops are planted by the pests, which can occur as early as possible during seed storage and when the seeds are introduced into the soil and the plants are germinated in a very short time. Attack, during this period = the ground is the key point, because the roots and seedlings of the growing plants are sensitive, and even a small amount of damage will lead to the death of the whole plant, by using appropriate composition to protect the seeds. And the plants in the germination are therefore of great interest. The method of treating plant seeds to control pests has been known for a long period of time and is a continuous improvement target. However, the treatment of seeds often encounters a series of problems that cannot be satisfactorily solved. Therefore, it is necessary to develop a method for protecting the seed and the germinated plant, so that it is not necessary to apply the crop protection agent immediately after sowing or after the germination of the plant, and it is also necessary to optimize the amount of the active compound applied to provide a The most appropriate protection of the seed and the plant in the bud, from the attack of the pest, but does not let the active compound used harm the plant itself; in particular, the method for treating the seed should also be transferred to the plant The nature of the internal killing spider is taken into consideration so that the seed and the germinated plant can use the minimum amount of crop protection agent to achieve the most appropriate protection. Accordingly, the invention is also related, in particular, to a method of protecting a seed and a germinated plant against attack by a pest, comprising treating the seed with the active compound composition according to the invention; for protecting the seed and germination according to the invention The method of attacking a pest against a plant comprises a method wherein the seed is simultaneously treated with an active compound of formula Z and a pyrethroid of from 1 to 24; the invention also comprises a -30- 200814927 10 15 20 The method 'there is a treatment of the active compound of the formula I and the fibril g of the type 1 i 24; the invention is used for the active compound composition according to the invention The seed is treated to protect the seed and the plant germinated therefrom against the pest; furthermore, the invention is treated according to the active compound composition of the invention so as to be protected from pests; the invention also relates to Simultaneously, the active compound of the formula (1) and the seed of the 1 to 24 class of pyrethroid treated seeds; the present invention also relates to at different time points The active compound of the formula (1) and the compound of the formula (1) and a kind of 1 to 4 scoop of human beings may exist in different seeds at different time points in the treatment of the compound and the species i i 24 . In this context, the compound and optionally the pyrethroid vinegar are present in the middle of a plug 2 # to 24; the invention is also a continuation of the pseudo-insect 'H-, 1) The active compound and the component form of the 1st to the layer of the invention, or as a further advantage of the present invention, the special systemicity of the compound composition according to the present invention, the seed itself is a raw shell, These compositions treat the seeds not only for biological attack, but also for the germinated plants to be protected from harmful short-time A. This way, the treatment that is carried out at the time of crop planting and after 1 crop can be omitted. 77. An advantage of the synergistic increase in the synergistic composition of the active compound composition of the individual active compound according to the present invention - 31 - 200814927 5

The activity of 10 15 20 insects far exceeds the activity of the two active compounds which are expected to be applied and, in addition, the active compounds according to the invention, compared to the individual active compounds of the fungi, the tongue The synergistically increased fungicidal activity of the composition is also much greater than the activity of the two activated individuals of the axis and the active compound II that makes it possible to optimize the application. It is considered that the active compound composition according to the present invention can also be converted into a gene by the Yingyi 'axis, whereby the plant grown by the scorpion can express the protein directly against the pest, by the present invention The combination of active compounds reduces such seeds, and the pest can be prevented by, for example, 'only the insecticidal protein f being expressed, and additionally protected against damage by the active compound composition according to the invention. The active compound composition according to the invention is suitable for the protection of any of the plant varieties described in agriculture, greenhouse, forestry or horticulture - in particular for the use of seeds of the following plants: corn, peanuts, canola, two to I millet, soybean, cotton, sugar beet (such as sugar beet and fodder beet), rice, sorghum and millet, wheat, barley, oats, rye, sorghum, terminal grass, horse-aged potato or vegetable (eg, name, cabbage) According to the present invention, the composition of the compound is also suitable for the treatment of fruit trees and seeds of vegetables as described above. It is particularly important to use seeds for the treatment of corn, soybean, cotton, wheat, and canola or alfalfa. As already mentioned above, it is also of particular importance to treat the transgenic gene with the active compound composition according to the invention, which is conventionally employed, the type of plant seed treated by -32-200814927 comprises at least one which can be controlled, in particular Is a heterologous gene of the performance of a polypeptide having insecticidal properties. In this context, a heterologous gene in the seed of a transgenic gene may be derived from a microorganism, such as a bacillus (eg, "like), rhizobium (and He--circle, Pseudomonas CPsewi/om (10), 5 Serratia, Trichoderma (7WcA〇i/er_), Corynebacterium (C/aWZmcier), cystic in vivo mycorrhizal fungi ( G/omt«) or Penicillium cloacae The present invention is therefore particularly suitable for the treatment of genes comprising at least one heterologous source from the genus Bacillus, and the gene product exhibits activity against European corn borer and/or corn cutting roots. Seeds of the transgenic gene of the worm, particularly preferably, the heterologous gene line is derived from the genus Suricus thuringiensis) ° In the context of the present invention, the active compound composition according to the invention is used alone or in a suitable formulation Applied to the seed, Preferably, the seed is in a stable state sufficient to avoid damage during processing; typically, the seed can be treated by p at any point between harvesting and sowing, and the seed is usually isolated from the plant. The cob, shell, stem, coat (English), hair or flesh have been removed. When treating seeds, it is usually very important to take into account the amount of the active compound composition according to the invention applied to the seed and/or the amount of the additionally selected 20 additives, so that the germination of the plant is not adversely affected. The effect, or damage to the plant, is to be kept in mind, under application of the active compound which causes phytotoxicity at a certain application rate. The active compound combination can be converted into a conventional formulation, for example, a solution, an emulsion, a wettable powder, a water- and oil-based suspension, a powder-.33-200814927, a dust, a paste, Soluble powders, soluble granules, granules for spreading, suspension-emulsion concentrates, natural materials infiltrated with active compounds, synthetic materials infiltrated with active compounds, fertilizers, and microcapsules coated in polymeric materials are use. These formulations are produced in a known manner, for example, by mixing an active person with a stretching agent, which refers to a liquid solvent and/or a solid paraplegic type, optionally devolatilizing, ie, emulsifying Fine and = agent and / or foam forming agent; the formulation can be made in a suitable factory:: is prepared before use or at the time of use. Zeer or a user suitable as an adjuvant is suitable for addition to a composition or a formulation derived therefrom (eg, 'spray, seed dressing) towel handle and/or other technical properties and/or special biological properties , Code: The adjuvants are: extenders, solvents and carriers. 15 , appropriate extension materials, such as 'water, polar and non-bribery liquids' such as 'aromatic and non-aromatic hydrocarbons (for example, to the furnace * to the phenylalkyl naphthalenes) Chlorobenzenes) 'Alcohols and polyols Π which can be substituted, graded and/or graded), noodles (for example, every '20 of acetone (including fats and oils) and (poly)ethers are unsubstituted And::), pain 'melamines, indoleamines (for example, Ν-burning base 酉 酉 ^ 酉 , , , , , , , , , , , , , , , , , , , , , , , 石 石 石 石 石 石 ( ( (叫和内~ If the propellant used is water, it is also possible to use 'for example, an agent as an auxiliary solvent, mainly a suitable organic group' such as xylene, toluene or cyanophthalene; chlorination; Aromatic emulsified fat _, for example, chlorobenzenes, vinyl chlorides or dichloro 2 and -34- 200814927 aliphatic hydrocarbons, such as cyclopentene oxime or paraffin, for example, petroleum partitions .11=1% heart, for example, butanol or glycol and its ethers and sputum cheeks, sig, for example, C, J, 、, 'strong polarity> granules such as dimethyl Sulfone; and water Suitable solid carriers are: for example, ammonium salts and grinding point soils, and salts: minerals, for example, kaolin, standing soil, moonstone, chalk, P; pot _ ^ + v ^ , Wu Guo active clay, montmorillonite or 矽10 15 20 Shi Xi,, 4 Bu 4 Τ '田1 口 into minerals' such as 'highly dispersed dioxide such as flat (tetra) acid salts; suitable for the preparation of granules Solid carrier is, for example, 'natural rock that is broken and divided, for example, calcite, marble, f stone, sepiolite and dolomite' and synthetic particles of inorganic and organic scraps' and particles of organic materials , for example, paper, sawdust, coconut shell, corn cobs and stems; suitable emulsifiers and/or formations (iv): for example, nonionic and anionic emulsifiers, for example, polyoxygen (10) fatty acid vinegars, polyethylene Aliphatic alcohols - 'for example, alkyl aryl alcohol glycol ethers, alkyl ester salts, alkyl sulfates, aryl sulfonates and protein hydrolysates; suitable dispersants are nonionic and / or Ionic materials, for example, the following alcohols, strontium-and/or ΡΟΡ, classes, acids and/or p〇p_p〇E esters, alkyl aryl and/or POP-POE ethers, fats and/or !>0?_1> 0 £ adducts, POE- and/or POP-polyhydroxy derivatives, P〇E_ and / or pop sorbitol or - sugar adducts, alkyl or aryl sulfates, alkyl or aryl sulfonates and alkyl or aryl phosphates or related PO-ether adducts, in addition, suitable oligo- or polymers, for example those derived from vinyl monomers, from acrylics, from EO and/or PO itself or in combination, -35. 200814927 For example, ( Poly)Alcohols or (poly)acid derivatives, unmodified and oxime It is also possible to use lignin and its sulfonated sulfonic acids and their fish: modified cellulose, aromatic and/or fat-drying agents Class ', for example, carboxy = compound. Colloidal natural and synthetic methylcellulose with powdered, granulated or lactenol and polyethylene vinegar, 2 species such as 'arabin gum, polyethoxylate and egg, and synthetic (4) (4) 'For example, 'brain _ may also be used with enamel class' can be used in the formulation of iron, titanium dioxide and prolu, for example, inorganic pigments, such as 10 15 20 dyes, azo dyes; M and organic dyes, for example, Gentleman's Eight Plus L brand 4 and to phthalocyanine dyes, and trace nutrients, for example, salts of iron, manganese, boron m copper, cobalt, molybdenum and zinc. "This, add-on for perfumes, minerals or vegetable oils, selectively modified oils, money and nutrients (including micronutrients), for example, salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc . Stabilizers used to modify #* chemical and/or physical stability, such as 'low temperature 妓, _ coffee, antioxidants, silk mites or other agents, may also be present in the formulation. The formulation typically comprises between 〇〇1 and 98% by weight of the active compound, preferably between 0.5 and 90%. The active compound compositions according to the invention may be formulated in the form of their commercially available formulations, or formulated from the formulation into a use form, or with other active compounds (eg 'insecticides, attractants, infertile agents' , fungicides, acaricides, nematicides, fungicides, growth regulators or herbicides) are used as a mixture; insecticides include, for example, especially -36, 200814927 which are: phosphates, amines Ruthenium esters, carboxylates, gasified hydrocarbons, phenylureas, microbial-producing preparations, etc. ° may also be combined with other known active compounds (eg, herbicides), or Used in combination with fertilizers and growth regulators. When used as an insecticide, the active compound composition according to the invention may also be used in the form of a commercially available formulation, or may be formulated from the formulation into a use form, or may be used in admixture with a synergist, Agent system

10 15

20 A substance which enhances the action of an active compound but which is not necessarily active per se. The active compound content in the use form formulated from commercially available formulations may vary widely, and the active compound concentration in the use form may range from 0,000,000 to 95% by weight of active compound, preferably Between 0.00001 and 1% by weight. The manner of application is in a manner suitable for the type of use. As has been mentioned in the drawings, in accordance with the present invention, in the specific embodiment, the gamma or those obtained by conventional biological breeding methods such as those of the wire (10) are also preferred. :: 'In the appropriate combination of the use of wealth and its ^ by the base H method' and species (genetically modified organic bauxite plant and plant cultivation plant parts, 'or, plants, 苴 people, the known parts ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 37- 200814927 A plant with novel properties ("features") obtained by mutation or by recombination of Li A technology, which can be cultivar (CUl-S), homotype (bi kiss) Pes) or genotype (g_types). > Weed cultivar cultivar, its distribution and growth conditions (soil, soil, milk, growth period, nutritional status), the treatment according to the invention can also lead to super Addition ("co-multiply") effect, material, for example, reduced Rate and / or augmented activity spectrum and / or increase the activity of the 16 quality and composition that can be used according to the invention, (4) plant growth, more high temperature resistance or low / dish 'more resistant to dry or water resistant or resistant Soil salinity, increased flowering, 1〇 easier, accelerated maturity, higher yield, better quality and higher nutritional value, better storage stability of harvested products And/or processability, which may exceed the actual expected effect. Plants or plant cultivars (ie those obtained by genetic engineering methods) that are better treated according to the invention include all 15 Some, = genetically modified, to obtain beneficial and useful features of the plant material of the plant, this notification 'color of the case for better plant growth, more high temperature or low / JEL, more resistant to dry or water or soil Medium salt content, increased flowering period, easier harvesting, accelerated ripening, higher yield, better quality of the harvest and/or higher nutritional value, better storage stability of the harvest and/or 2〇Processability, value An example of such a feature that is particularly emphasized is that plants are more resistant to pests such as animals and microorganisms (eg, insects, mites, phytopathogenic fungi, bacteria and/or viruses) and also increase Plants for certain herbicide-tolerant compounds, plants that can be mentioned as transgenic genes are important crop plants, such as grain (wheat, rice), corn, -38- 200814927 soybean, horse bell I, tons, fan% , beans and other vegetable varieties, cotton, tobacco, canola and fruit trees (apple, pear, citrus and vine), with particular emphasis on corn, soybeans, potatoes, cotton and canola, especially emphasized It is characterized by the ability to increase plant 5 resistance by toxins formed in plants to combat insects, mites, nematodes and yak and ticks, especially those derived from S. faecalis (and Gene material (for example, by gene CryIA (8), CryIA (b), _ CryIA (c), CryllA, CrylllA, CryIIIB2, Cry9c, Cry2Ab,

Cry3Bb and (^1? and also its composition) (later referred to as "planted"); other features that are particularly emphasized are: systemic resistance (SAR), systemin, phytoalexin (卩]^〇&16\丨118), elicitor and resistance genes and related proteins and toxins to increase the defense of plants against fungi, bacteria and viruses; The characteristics of the tune are 'plants for certain herbicidal compounds (eg, I5 imidazolinones, sulfonyl ureas, glyphosate or phosphinotricin (eg "PAT") genes. )) increased tolerance; genes involved in the desired characteristics are undoubtedly also present in a mixed form with other genes in plants of the transgenic genes. Examples of "Bt plants" that may be mentioned are as follows Trade name sold by corn variety, cotton 20 variety, soybean variety and potato variety: YIELD GARD® (eg corn, cotton, soybean), KnockOut® (eg corn), StarLink® (eg corn), Bollgard® (cotton ), Nucotn® (cotton) and NewLeaf® (Masing); the plant-to-killer agents that can be mentioned are corn, cotton and soybean varieties, which are sold under the following trade names: Roundup - 39- 200814927

Rea,® (five) Jia Phossein 'such as corn, cotton, soybeans), (10) kiss [尬10 ki-xin [such as rapeseed], IMI8 (imidazole-resistant ketone) and Talk 8 (resistant to yellow wine ^ 'for example corn); The herbicide-tolerant plants (herbicide-tolerant plants bred in the traditional f formula) which may be mentioned include those which are sold under the name Clearfielf® (for example, corn). Of course, these statements also apply to the characteristics of these genes or It will be developed and/or sold in the future with plant cultivars that will be developed with genetic characteristics. The plants listed can be treated according to the invention in a particularly advantageous manner using the compositions according to the invention, which are suitable for the treatment of these plants, in particular for the preferred range of active compound compositions. It is emphasized that the plants are treated in combination with the active compounds specifically mentioned in the present text. The active compound combination according to the invention is not only active against pests in plants, sanitary and stored products, but also against animal parasites (external-parasites and endo-parasites) of the veterinary school, for example Hard wall • Wind, soft wall wind, being fasted, leaf worm 'claw rope (whole rope and paper rope), parasitic rope larvae, scorpions, head lice, feathers and fleas, these parasites (worms) include: (Anophirida) organisms, for example, Haematopinus spp., Linognathus spp., Pediculus 20 spp., Phtirus spp., buffalo blind Genus (Solenopotes spp〇° Mallophagida and Amblycerina and Ischnocerina suborder organisms, such as, Trimenopon spp., Menopon spp., Trinoton spp., Buffalo-B- 200814927 spp·), Werneckiella spp., Lepikentron spp·, Damalina spp., Trichodectes spp., Felicola spp. Diptera and Nematocerina With short horns (Brac Hycerina) organisms, for example, Aedes spp., Anopheles spp., Culex spp., Simulium SPP., Eusimulium spp. ,Pelebotomus spp., Lutzomyia spp., Culicoides spp., Chrysops spp., Hybomitra spp., yellow it Genus (Atylotusspp.), Taenusspp., Haematopota 10 spp., Philipomyia spp, Braula spp., Musca spp., Hydrotaea spp ·), Stomoxys spp, Haematobia spp., Morellia spp., Fannia spp., Glossina spp., Lily ( Calliphora spp·), Lucilia spp., Chrysomyia spp., Wohifahrtia spp·, Sarcophaga spp., Oestrus • spp·, Drosophila (Hypoderma spp.), Gasterophilus spp., Hippotosca spp., Lipoptena spp., Melophagus spp. o 蚤(Siphonapterida) organisms, for example, is a human flea (Pulex spp ·), 20 flea genus (Ctenocephalides spp ·), the rat flea (Xenopsylla spp ·), is a leaf flea (Ceratophyllus spp.). Heteropterida organisms, for example, Cimex spp., Triatomaspp., Rhodnisspp, Panstrongylus spp. 〇-41 - 200814927 (Blattarida) organisms, for example, Oriental cockroach (5/Gaga on (9) such as / 仏), American cockroach (10), German cockroach germimfcfl), genus Supella spp. [Acari (Acarina)] and the posterior-thoracic valve and the meta-and Mesostigmata organism, for example, Argas spp., Ornithodoros spp. ), Otobius spp., Ixodes spp., Amblyomma spp., Boophilus spp., Dermacentor spp. , Haemophysalisspp·, Hyalommaspp·, Rhipicephalus spp., Dermanyssus spp., Raillietia spp., P. Pneumonyssus spp.), Sternostoma spp., Varroa spp. The genus Actinedida (also known as Prostigmata) and the genus Acaridida (also known as Astigmata), for example, Acarapis spp. Cheyletiella • spp., Ornithocheyletia spp., Myobia spp., Psorergates spp., Demodex spp., Trombula spp. Listrophorus spp·, Acams spp., Tyrophagus spp., Caloglyphus spp., 20 Hypodectes spp., Pterolichus spp., Psoroptes spp., genus Chorioptes spp.), Otodectes spp., Sarcoptes spp., Notoedres spp., Knemidocoptes spp., Cytodites spp. ), Laminosioptes spp. -42- 200814927 The active compound composition according to the invention is also suitable for productive livestock for controlling arthropods to avoid harassment of agriculture, such as cattle, sheep, goats, horses, pigs, scorpions, road rides, buffalo, rabbits, Chickens, turkeys, ducks, geese and bees, other pets, such as dogs, I seedlings, cage birds and 5 fish, and so-called experimental animals, such as hamsters, guinea pigs, big mice and small mice; Controlling these arthropods can reduce the mortality and production of the reared animals (meat, milk, wool, fur, eggs, honey, etc.), _ by using the active compound combination according to the invention to achieve greater hydroxylity Benefits and easier animal feeding. 10 The compounds according to the invention are used in the field of veterinary medicine and in animal feeding, by means of internal administration in a known manner, using, for example, a key, a capsule, a drink, a drink, a granule, a paste, Feeding group, feed and suppository; by non-digestive administration, for example, injection (intramuscular, subcutaneous, intravenous, intraperitoneal, etc.), via implantation, I5 nasal administration , applied by the skin, for example, dipping or bathing, spraying, pouring and spotting, rinsing, powdering, and by means of molded articles containing active compounds, such as collars, ear notes, tail rings' Limbs, bandages, shoe cords, identification devices, and more. When used in cattle, poultry, pets, and the like, the active compound combination 20 can be used as a formulating agent (e.g., a powder, an emulsion, a flowable composition), wherein the amount of the active compound is from 1 to liters. Use directly or diluted 100 to 10,000 times, or as a chemical bath. Furthermore, it has been found that the active compound combination according to the invention has a strong insecticidal action against insects which destroy industrial materials. • 43- 200814927 5

10 15

20 The following insects are exemplified and preferred examples, but are not limited to this: beetles, for example, housewife dow w/ws), pilosis beetle, punctatum, red hair Xestobium rufovillosum y Ptilinus peeticornis ^ Dendrobium pertinex j Ernobius mollis, Priobium carpini, brown stupid (Lyctus, African Frucs β/WcawMS), flat-headed whitefly (like planicollis), Lyctus linearis, Lyctus pubescens, Trogoxylon aequale, Minthes rugicollis, Xyleborus spec., Tryptodendron spec, non-black scorpion monachus, Bostrychus capucins, Heterobostrychus brunneus, 1 Sinoxylon spec., bamboo 1 stupid Dinoderus minuteus; Hymenopterans, for example, A. sylvestris, C/rocerws gz'goy, t/rocerMS gigfls taignus, Urocerus augur; White, for example, European wood Termites (feet^/〇化广"2 to /7 hearts/(:〇//仏), Australian termites kev/s), desert termites indicola) ^Reticulitermes flavipes, Reticuliter Mes santonensis, Reticulitermes lucifugus, full of woven QMastotermes darwiniensis, Zotermopsis nevadensis, Taiwanese white soil (Coptotermes formosanus), western squid, for example, western squid cc/mrzVm) Industrial materials, understood to mean inanimate materials, for example, preferably plastics, adhesives, pastes, papers and cards -44-200814927 paper, leather, wood and reinforced Wood products and coating compositions. Second: the composition 'appropriate, can be further included in the other killing and 'suitable materials, in addition, ❹ 杀 杀 kill 8 doses. 5

For the additional additives of 10 15 20 oil, refer to the above-mentioned insecticides and fungicides. The active compound combinations according to the invention can likewise be applied to objects which are in contact with sea water or (four) flavors of water, in particular the hull, the screen 'nets' buildings, the ship's tools and signalling systems, for combating The attachment is full. Furthermore, the active compound combinations according to the invention, either alone or in combination with other living compounds, can be used as anti-bioadhesive agents. The active compound composition is also suitable for the control of animal pests in the protection of the household, sanitary and stored products, in particular in the enclosed space (eg, residence, guard hall, office, In the garage, etc., insects, spiders and mites, in order to control these harmful animals, they can be used alone or in combination with other active compounds and adjuvants in the insecticidal products used in the residences of the courts, they are active Against the sensitive and resistant varieties and all their developmental stages, these pests include: Scorpionidea organisms, for example, hate (10) This is also (10). Acarina creatures, for example, Persian conceicus, Argas reWexus, BryoMa ssp, chicken gray hedgehog (Derm(10); ga/.fle), home sweet potato (G/yc) /p/mgt^ , blunt edge 瞒 ((9/τπ·from οί/οη/Α爪(10)^如), 赤红头头蜱-45- 200814927 (Rhipicephalus sanguineus), 恙 恙, 茜 (Trombicula alfreddugesi), Neutrombicula autumnalis , Dermatophagoides pteronissimus , Dermatophagoides forinae ° 5

10 15

20 Araneae organisms, for example, Aviculariidae, Araneidae; Opiliones, for example, to be paid (the body of this wdoscorpzowe·? chelifer), Pseudoscorpiones cheiridium, ^ ^ {Opiliones phalangium) ° Isopoda creatures, for example, the squirrel (the worm), black, larvae XJPorcellio scaber), the genus Diplopoda, for example, with zebra land (wan/aWw/ws guttulatus) ^ Polydesmus spp.; Chilopoda creatures, for example, eating fruit and entertainment. Zygentoma, for example, aphid spp.), Lepisma saccharina, Lepismodes inquilinus ° Blattaria, for example, Oriental cockroach (and /αίία oWenia/fes), German small蠊germaw/ciz), Blattella asahinai, (Leucophaea maderae), Panchlora spp., Parcoblatta spp., Periplaneta australasiae, Americas Earn (Periplaneta dmerfc (10)a), brown cockroach CPeWp/imeM, smoky cockroach -46- 200814927 (Periplanetafuliginosa), ^M^^ (Supellalongipalpa). Saltatoria organisms, for example, domesticus, Dermaptera organisms, for example, European auricularia ° Isoptera organisms, for example, common dry wood termites (Kalotermes spp.) , Reticulitermes spp.

10 15

20 Psocoptera organisms, for example, Lepinatus spp., Liposcelis spp. Coleoptera, for example, Anthremis spp. ^ (Attagenus spp.) M (Dermestes spp〇^ Latheticus oryzae, Necrobia spp., genus (Ptinus spp.), housewife 蠹i/omzWed), Sitophilus granaries, 糸I {Sitophilus oryzae), itI (Sitophilus zeamais), 药谷谷盗 (jSYegO厶o Diptera, For example, Aedes aegypti ciegypti) Aedes albopictus 'Aedes, Anopheles spp., Calliphora erythrocephala, Chrysozona pluvialis, Cw/ex quinquefasciatus, inflammation Acoustic mosquito (Culex, Cw/ex, Drosophila spp.), toilet rope {Fannia canicularis), home now {Musca domestica), Phlebotomus spp. J ^ ^ ^(Sarcophaga carnaria) j Simulium spp. » (Stomoxys calcitrans ), Tipula paludosa; «47- 200814927 Lepidoptera, for example, Jc/zrc^fl grisella, Galleria mellonella, Pludia , moth (Γζ·?2ββ c/(9ace//a), Netweed moth (77wea pellionella), Tineola bisselliella 〇5 Siphonaptera creature, for example, Ctenocephalides canis, Cienocephalides /e/z\s People, wearing a leather snorkel (Tunga;?e«ein2/^), Lueno H (Henosylla cheopis) Hymenoptera, for example, the big black ant 10 herculeanus), 禀, 萆 XL XL XL XL XL XL XL XL ), police, Lasius niger ^ Lasius umbratus ^ Monomorium pharaonis, Paravespula spp·, Tetramorium caespitum, Anoplura creatures, for example, heads CPei/z'ew /(10) capitis), later (Pediculus humanus corporis), Pemphigus spp, Phylloera vastatrix, Phthirus • pubis. Heteroptera, for example, C7mex hemipterus, HGimex lectularius) Rhodimis prolixus, TWaMmiz. 2 In the field of pesticides for household use, they are used alone or in combination with other appropriate Active compounds, for example, in combination with phosphates, urethanes, pyrethroids, neonicotins, growth regulators or other known killing agents. They are formulated into the following forms: Aerosol, non-pressurized spray • 48- 200814927 agents, such as pumped sprays and atomized sprays, automatic

, foaming agent, gel, with a vaporizer product made of cellulose or polymer as a 匕:, a J slice, liquid steamed, gel: the treatment of vascular resistance & ^ W seeking rough Compound, 5 [form of steamed product of the formula] is not energy-consuming, or a passive evaporation system, a moth, a 'strap' bag, and a moth-killing gel, made into granules or dust, placed in a bait for distribution. Or use it in a bait equipment station. _ [Embodiment] 1 The good killing and killing activity of the active compound composition according to the present invention is illustrated by the following examples, in which individual active compounds take into account the weak effect, the composition is presented Its role far exceeds the sum of its individual effects. When the active compound composition exhibits more than the sum of the effects of its individual active compounds in insecticidal and acaricidal action, it has a 15 synergistic effect. ^ _ The expected activity for a given composition containing two active compounds can be calculated as follows according to the formula of S.R. Colby (Weeds (1967), 2〇_22):

2Q X represents the percentage (%) of the kill rate of the untreated control group when the active compound A is applied at a rate of application of g/ha or at a concentration of nippm, and Y represents the application rate at the gram/ha or Percent kill rate of untreated control group at -5, 200814927 (%), E represents the application rate at m and il g/ha or at m and n ppm when active compound B is applied at a concentration of n ppm Percentage of kill rate in untreated control groups when active compounds A and B were administered at concentrations,

X.Y 贝 E II X + Y ———一 100

I 10 If the true killing rate of insecticides or killings exceeds the calculated value, then the effect of the composition is superadditive, ie, a synergistic effect occurs, in which case the truly observed killing occurs. The death rate needs to exceed the expected kill rate (E) calculated using the above formula.

15 Example A Peach Test _ Solvent: 7 parts by weight of dimethylformamide emulsifier: 2 parts by weight of aryl aryl polyglycol ether to give a suitable active compound formulation, 1 part by weight of activity 20 The compound is mixed with the amount of solvent and emulsifier, and the concentrate is diluted to the desired concentration with water containing an emulsifier. The green peach (Mjzws's cabbage leaf (wanraw/cfl oleracea) is immersed in a formulation solution of the active compound at the desired concentration. 25 After a desired period of time, the percentage of kill is determined, 100 % -50- 200814927 means that all the mites have been killed; 〇% means that no mites have been killed, and the determined kill rate is substituted into the Colby formula (see Form 1). In this test, for example, according to the application rate The active compound mixture described below exhibits a synergistic increase in activity compared to the individual application of the active compound. Table A, page 1 Insecticide insects $ji^(Myzus persicae)^^k Active compound concentration (ppm) Kill rate after day 1 %) Compound (la) 0.8 55 Compound (lb) 4 40 cypermethrin 0.032 10 λ-cylonine (lambda-cyhalothrin) 0.16 0 According to the invention: (la + 赛灭宁(25:1) 0·8 + 0.032 measured value * calculated value ** 85 59.5 According to the invention: (lb) + λ-cylonin (25: 1) 4 + 0.16 Value * Calculated value ** 85 40 10 * Measured value = Actual measured activity ** Calculation = Value calculated using Colby's formula of the active

Example B Phaedon cochleariae (1) -51 - 200814927 Solvent: 7 parts by weight of dimethyl decylamine emulsifier: 2 parts by weight of aryl aryl polyglycol ether For the formulation of the active compound, 1 part by weight of the active compound is mixed with the amount of solvent and emulsifier, and the concentrate is diluted to the desired concentration with water containing the emulsifier. After immersing the cabbage leaves (price o/eracea) in the formulation solution of the desired concentration of the tongue compound, place the fennel beetle (the larva of the corpse when the leaves are still moisturized. 10 15

After a desired period of time, the percentage of kills is determined, 1 〇〇% means that all beetle larvae have been killed; 0% means no beetle larvae are killed, and the determined kill rate is substituted into the Colby formula (see Form 丨). In this test, the following active compound mixture according to the application rate shows a synergistic increase in activity compared to the individual application of the active compound. Table B, page 1 Insect plant insects • Horseradish leaf A ( Phaedon cochleariae) Larval test active compound concentration (ppm) 篦:? Killing rate after sputum (%) Compound (la) 100 35 20 0 Compound (lb) 20 11 cypermettirin 4 35 deltamethrin 0.8 44 β-cyfluthrin 4 80 - 52- 200814927 According to the invention: measured value * calculated value ** (la) + 赛宁宁 (25:1) 100 + 4 90 57.75 According to the invention: measured value * calculated value ** (la + 灭灭宁(25: 1) 20 + 0.8 94 44 According to the invention: measured value * calculated value ** (Ib) + dinning (25: 1) 20 + 0.8 78 50.16 according to the invention : Measured value * Calculated value μ (Ia) + P- Sai Fanning (5··1) 20 + 4 95 80 * Measured value = Actual measured activity ** Calculated value == Using Colby Activity calculated by the formula Table B, page 2 5 Insects that damage plants _ ^{Phaedon cochleariae)^j Active compound concentration (ppm) Kill rate after day 3 (%) Compound (la) 100 25 Compound (lb 20 10 γ-赛洛宁 4 45 (gamma-cyhalothrin) 0.8 30 λ_赛洛宁 4 65 (lambda-cyhalothrin) 0.8 10 According to the invention: measured value * calculated value μ (la) + γ- Xeron (25: 1) 100 + 4 100 58.75 according to the invention: measured value 4 calculated value μ (11 >) + γ-cylonine (25: 1) 20 + 0.8 50 37 200814927 According to the invention: measured value * calculated Value ** (la) + λ-cylonin (25: 1) 100 + 4 100 73.75 According to the invention: measured value * calculated value ** (Ι1)) + λ-cylonin (25: 1 ) 20 + 0.8 55 19 * Measured value = actual measured activity ** calculated value = = activity calculated using Colby's formula

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Claims (1)

200814927 X. Patent Application Range: 1. An active compound composition comprising at least one compound of formula (I) N——R (D where ίο R represents methyl or cyclopropyl, and at least one selected from the group consisting of: 1. arrinathrin 2. alpha-cypermethin 3. β-赛康宁 (betacyfluthrin) -55- 200814927 4· γ-cylonin (gamma-cyhalothrin) 10 5 ·赛杀宁(cypermethrin) 〇 CN 15 6. Dimensions (deltamethrin) 20 7. Yissenvale (esfenvalerate) H3C 八 ch3 -56- σ°Ό 〇/^CN 200814927 8. Efenine (ethofenprox) 5 9. Fenpanning (fenpropathrin) 10 1〇· fenvalerate (fenvalerate) 15 11 · 赛赛宁(flucythrinate) 20 12. λ-赛洛宁 (lambda_cyhalothrin) -57- 200814927 13.百因宁(permethrin) 10 14. Set of taufluvalinate 15 Ό 15 · tralomethrin Br, C 20 16. zeta-zepering (zeta-cypermethrin) -58- 200814927 Cl X 17 ·cyfluthrin w n 18. bifenthrin w n 15 19·cycloprothrin Cl 20 och2ch3 -59- 200814927 20. Evlusilanate 21 · Fu Fu (fubfenprox) 22 · Pyrethrin (pyrethrin) 15 20 Ri = -CH=CH2 or -CH3 or -CH2CH3 23. Resmethrin -60- 200814927 and 24·tetrafluthrin (tefluthrin) Ίο 15 20 2. A use of an active compound as defined in claim 1 of the patent application for controlling animal pests. ϋ ! 4 A method for controlling animal pests is characterized by using the active compound composition as defined in claim 1 for use in animal pests and/or their living environment and/or seeds. . According to the method of claim 3, it is characterized in that an active compound of the formula I and a pyrethroid of from 1 to 24 are simultaneously applied to the seed. 5. The method according to item 3 of the patent application, characterized in that an active compound of the formula I and a pyrethroids of from 24 to 24 are applied to the seed at different time points. A method for preparing an insecticidal and acaricidal composition, characterized in that an active compound composition as defined in claim 1 of the patent application is mixed with a stretching agent and/or a surfactant. 7. Use of an active compound composition according to claim 1 of the patent application for the treatment of seeds. 8. A method for the treatment of a transgenic plant according to the method of claim 1, wherein the active compound composition is used in the treatment of the transgenic plant. 9. A use of an active compound composition according to claim 1 of the scope of the patent application for the treatment of seeds of a transgenic plant. 5 10 10 - A seed treated with the active compound composition according to claim 1 of the patent application. η. According to the seed of claim 10, the seed has been treated with an active compound of the formula I and a pyrethroids of 24 to 24 simultaneously. A pyrethrum that has been treated at different times. 12. The seed according to the first aspect of the patent application is treated with an active compound of the formula I and 1 to 24 esters (pyrethroids). -62- 200814927 VII. Designation of Representative Representatives: (1) The representative representative of the case is: (No). (2) A brief description of the symbol of the representative figure: Yi 〇, Λ VIII. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: