TW200535255A

TW200535255A - High-performance hardmetal materials

Info

Publication number: TW200535255A
Application number: TW94108009A
Authority: TW
Inventors: Shaiw-Rong Scott Liu
Original assignee: Genius Metal Inc
Priority date: 2004-03-17
Filing date: 2005-03-16
Publication date: 2005-11-01
Also published as: TWI339219B

Abstract

Hardmetal compositions each including hard particles having a first material and a binder matrix having a second, different material comprising rhenium or a Ni-based superalloy. Tungsten may also be used a binder matrix material. A two-step sintering process may be used to fabricate such hardmetals at relatively low sintering temperatures in the solid-state phase to produce substantially fully-densified hardmetals. A hardmetal coating or structure may be formed on a surface by using a thermal spray method.

Description

200535255 九、發明說明：【發明所屬之技術領域】本發明係有關於硬金屬組合物及其製作技術，以及相關的應用。【先前技術】硬金屬（hardmetals)包括各種的複合材料，而特別設計成具有硬與耐火之特性，並且展現非常強的耐磨耗特性。在許多常用的硬金屬中，係包括有燒結或接合的碳化物、石反氮化物或其組合。許多硬金屬被稱作陶瓷金屬 (cermets)，該陶曼金屬所具有的組合物係可包括與黏結劑金屬粒子互相黏結之陶瓷粒子（例如TiC)。在一些技術文獻中已經有揭示一些既定的硬金屬組合物。例如，硬金屬組合物的綜合的編輯物係發表於Br〇〇kes的世界辭典以及硬金屬手冊（Handbook of Hardmetals，sixth edition，200535255 IX. Description of the invention: [Technical field to which the invention belongs] The present invention relates to hard metal composition and its manufacturing technology, and related applications. [Previous Technology] Hardmetals include a variety of composite materials, and are specifically designed to have hard and fire-resistant characteristics and exhibit very strong abrasion resistance. Among many commonly used hard metals, sintered or bonded carbides, stone denitrides, or combinations thereof are included. Many hard metals are called cermets, and the composition of the Taurman metal can include ceramic particles (such as TiC) that are bonded to the metal particles of the binder. There are already some known hard metal compositions disclosed in some technical literature. For example, a comprehensive compilation of hard metal compositions is published in Brokes's World Dictionary and Handbook of Hardmetals (sixth edition,

International Carbide Data，United Kindom 1996)中。硬金屬有許多的應用，例如可應用於切割金屬、石頭與其他硬材料的切割工具，拉金屬線的鋼膜，77具，切割煤炭、礦石和岩石的切割研磨工具，以及鑽油田或其他的工具。除此之外，可根據元件的特別需要，而作成構造用的外罩夕卜表面或一些層而符合元件在某些環境下的操作應用。許多硬金屬可以先將硬且耐火的碳化物或碳氮化物的粒子政佈於黏結基質（blnder matdx)中然後將此混合物执壓和燒結1燒結製程使黏結基質與上述粒子黏結並使該International Carbide Data, United Kindom 1996). There are many applications for hard metals, such as cutting tools that can be used to cut metals, stones and other hard materials, steel membranes for drawing metal wires, 77 tools for cutting and grinding coal, ore and rocks, and drilling oil fields or other tool. In addition, according to the special needs of the component, the cover or surface of the structure can be made to meet the operation and application of the component in certain environments. For many hard metals, hard and refractory carbides or carbonitride particles can be deposited in a bonding matrix (blnder matdx), and then the mixture can be pressed and sintered. 1 The sintering process can bond the bonding matrix with the particles and make

1057D-6939-PF 200535255 混合物緻密化，而形成硬金屬。這些硬粒子係主要貢獻於硬金屬的硬特性與耐火特性【發明内容】本發明的目的在於提供一種新的硬金屬組合物及其製作技術。 ' 本發明的硬金屬組合物的特徵係：具有第_材料的硬粒子以及具有與第一材料不同之第二材料之一黏結劑基質 (bindermatrix)。其中，上述硬粒子係以實質均勻的方式散佈於該黏結劑基質中。丨中’用以構成上述硬粒子的該第 -材料可以包括下列材料，例如：wc基的材料、加基的材料、WC基與TiC基混合的材料或其他碳化物、氮化^、硼化物、矽化物以及上述材料的組合。其中，用以構成該黏結劑基質之該第二材料係可以包括下列材料，例如二元素、Re和Co的混合物、Ni基超合金、恥基超合金與 Re的混合物、Ni基超合金的混合物、犯和c〇的混合物，以及上述材料與其他材料之混合物。w也可當作硬金屬材料的黏結劑基質。還有’該Ni基超合金可以在”，相中。本發明的硬金屬組合物的組成例如是：該第二材料係佔該硬金屬組合物總體積的3〜4〇騁體積/〇。在一些應用例中’該黏結劑基質可以包括有銖(Re)元素，且鍊元素係佔該硬金屬組合物黏結劑基質該硬金屬組合物總重旦的乃重量％以上。在其他應用例中，該第二材料可：包二基超合金，該Ni基超合金可包括川與其他元素（例如: 而應用於既定應用例中。1057D-6939-PF 200535255 The mixture is densified to form a hard metal. These hard particle systems mainly contribute to the hard characteristics and fire resistance characteristics of hard metals. SUMMARY OF THE INVENTION The object of the present invention is to provide a new hard metal composition and a manufacturing technology thereof. 'The hard metal composition of the present invention is characterized by hard particles having a first material and a binder matrix having one of a second material different from the first material. The hard particles are dispersed in the binder matrix in a substantially uniform manner. The first material used to form the hard particles may include the following materials, for example: wc-based materials, base-added materials, WC-based and TiC-based materials, or other carbides, nitrides, boride , Silicide, and a combination of these materials. The second material used to form the binder matrix may include the following materials, for example, two elements, a mixture of Re and Co, a Ni-based superalloy, a mixture of a rudimentary superalloy and Re, and a mixture of a Ni-based superalloy. Mixtures of arsenic, guilty and co, as well as mixtures of the above and other materials. w can also be used as a binder matrix for hard metal materials. There is also "the Ni-based superalloy may be in" phase. The composition of the hard metal composition of the present invention is, for example, that the second material accounts for 3 to 40 vol / vol of the total volume of the hard metal composition. In some application examples, the adhesive matrix may include Ba (Re) elements, and the chain element accounts for more than 1% by weight of the total heavy denier of the hard metal composition adhesive matrix. In other application examples, The second material may include a two-base superalloy, and the Ni-based superalloy may include Sichuan and other elements (for example, and is used in a predetermined application example.

1057D-6939-PF 6 200535255 s 在製造上述硬金屬材料方面，其中一種製程包括：⑴在真二條件下，於固相中燒結該材料混合物，以及（2)在具有壓力的惰性氣氛中，進行固相燒結（solid_phase sintering)。也可以利用熱噴塗法在表面上形成硬金屬塗層或硬金屬結構。根據上述硬金屬材料不同的實施方式，可有至少下述優點·具有非常好的硬度、提升在高溫下的硬度，以及改善對腐鍅及氧化的抵抗性。籲在本應用中多種特別的實施方式將概述如下，第一類 265種實施方式如下： 1 · 一種硬金屬組合物，包括··具有第一材料的硬粒子，以及具有與第一材料不同之第二材料之一黏結劑基質 (binder matrix);其中，該第二材料係佔該硬金屬組合物總體積的3〜40〇/〇 ;其中，該黏結劑基質包括銖（Re)元素，且銖元素係佔該硬金屬組合物總重量的2 5 %以上；其中，上述硬粒子係以實質均勻的方式散佈於該黏結劑基質中。 _ 2·如第1項或第14項所述之硬金屬組合物，該第一材料包括一含鎢的碳化物。 3 ·如第2項所述之硬金屬組合物，其中該碳化物為 WC。 4 ·如第3項所述之硬金屬組合物，其中該第一材料更進一步包括另一種含不同於W的金屬元素之碳化物。 5·如第4項所述之硬金屬組合物，其中該金屬為Ti。 6·如第4項所述之硬金屬組合物，其中該金屬為Ta。 1057D-6939-PF 7 200535255 7 ·如第4項所述之硬金屬組合物，其中該金屬為Nb。 8·如第4項所述之硬金屬組合物，其中該金屬為v。 9·如第4項所述之硬金屬組合物，其中該金屬為Cr。 10·如第4項所述之硬金屬組合物，其中該金屬為Hf。 11·如第4項所述之硬金屬組合物’其中該金屬為M〇。 12·如第2項所述之硬金屬組合物，其中該第_材料更進一步包括氮化物。 13·如第2項或第12項所述之硬金屬組合物，其中該氮化物包括 TiN、 ZrN、 VN、NbN、 TaN 或 HfN。 14· 一種硬金屬組合物，包括：具有包括氮化物的第一材料之硬粒子；以及具有與第一材料不同之第二材料之一黏結劑基質（binder matrix);其中，該第二材料係佔該硬金屬組合物總體積的3〜40% ;其中，該黏結劑基質包括鍊 (Re)7L素’其中，上述硬粒子係以實質均勻的方式散佈於該黏結劑基質中。 15·如第14項所述之硬金屬組合物，其中該氮化物包 •括 TiN、ZrN、VN、NbN、TaN 或 HfN。其中黏結劑基質 16 ·如第1項所述之硬金屬組合物更進一步包括Co。 17‘-種硬金屬組合物’包括：具有第—材料的硬粒子；以及具有與第-材料不同之第二材料之—黏結劑基質 (binder matrix);其中，該第二材料係佔該硬金屬組合物總體積的3〜桃；其中，該黏結劑基質包括鍊㈣和錄⑽ 元素’其中，上述硬粒子係以實質均勾的方式散佈於該黏1057D-6939-PF 6 200535255 s In the manufacture of the above-mentioned hard metal materials, one of the processes includes: 烧结 sintering the material mixture in a solid phase under Shinji conditions, and (2) under a pressured inert atmosphere, Solid phase sintering. It is also possible to form a hard metal coating or a hard metal structure on the surface by a thermal spray method. According to the different embodiments of the hard metal material described above, there are at least the following advantages: it has very good hardness, increases the hardness at high temperature, and improves the resistance to rot and oxidation. A number of special implementations in this application will be summarized as follows. The first type of 265 implementations are as follows: 1 A hard metal composition, including hard particles with a first material, and A binder matrix of a second material; wherein the second material accounts for 3 to 40/00 of the total volume of the hard metal composition; wherein the binder matrix includes a Ba element; and The baht element accounts for more than 25% of the total weight of the hard metal composition; wherein the hard particles are dispersed in the binder matrix in a substantially uniform manner. 2. The hard metal composition according to item 1 or 14, wherein the first material includes a tungsten-containing carbide. 3. The hard metal composition according to item 2, wherein the carbide is WC. 4. The hard metal composition according to item 3, wherein the first material further includes another carbide containing a metal element different from W. 5. The hard metal composition according to item 4, wherein the metal is Ti. 6. The hard metal composition according to item 4, wherein the metal is Ta. 1057D-6939-PF 7 200535255 7-The hard metal composition according to item 4, wherein the metal is Nb. 8. The hard metal composition according to item 4, wherein the metal is v. 9. The hard metal composition according to item 4, wherein the metal is Cr. 10. The hard metal composition according to item 4, wherein the metal is Hf. 11. The hard metal composition according to item 4, wherein the metal is Mo. 12. The hard metal composition according to item 2, wherein the first material further includes a nitride. 13. The hard metal composition according to item 2 or 12, wherein the nitride comprises TiN, ZrN, VN, NbN, TaN or HfN. 14. A hard metal composition comprising: hard particles having a first material including a nitride; and a binder matrix having one of a second material different from the first material; wherein the second material is It accounts for 3 ~ 40% of the total volume of the hard metal composition; wherein the binder matrix includes a chain (Re) 7L element, wherein the hard particles are dispersed in the binder matrix in a substantially uniform manner. 15. The hard metal composition according to item 14, wherein the nitride comprises TiN, ZrN, VN, NbN, TaN or HfN. Wherein the binder matrix 16 The hard metal composition as described in item 1 further includes Co. 17'-hard metal composition 'includes: hard particles having a first material; and a binder matrix having a second material different from the first material; wherein the second material accounts for the hard material The total volume of the metal composition is 3 ~ peach; wherein the adhesive matrix includes chain elements and recording elements, wherein the hard particles are dispersed in the adhesive in a substantially uniform manner.

1057D-6939-PF 8 200535255 結劑基質中。 18. -種硬金屬組合物，包括：具有第一材料的硬粒子；以及具有與第一材料不同之第二材料之一黏結劑基質 (binder matrix);其中，該第二材料係佔該硬金屬組合物總體積的3〜40%;其中，該黏結劑基質包括銖…约和鉬（m〇) 元素’其中’上述硬粒子係以實質均勻的方式散佈於該黏結劑基質中。 19. -種硬金屬組合物，包括：具有包括氮化物第一 • 材料的硬粒子；以及具有與第一材料不同之第二材料之一黏結劑基質(bind…rix);其中，該第二材料係佔該硬金屬組合物總體積的3〜40%;其中，該黏結劑基質包括銖和鐵㈣元素，其中，上述硬粒子係以實質均句的方式散佈於該黏結劑基質中。 20. -種硬金屬組合物，包括：具有第一材料的硬粒子；以及具有與第一材料不同之第二材料之一黏結劑基質 (bind⑽atrix);其中’該第二材料係佔該硬金屬組合物她鲁體㈣3〜桃；其中，該黏結劑基質包括鍊㈣和絡㈣元素，其中，上述硬粒子係以實質均勻的方式散佈於該黏結劑基質中。 •具有第一材料的硬粒二材料之一黏結劑基質 21 · —種硬金屬組合物，包括子；以及具有與第一材料不同之第 (bindermatHx);其中，該第二材料係佔該硬金屬組合物她體積的3〜4〇% ;其中，該黏結劑基質包括銖（Re)* Ni基超合金元素’其中，上述硬粒子係以實質均勾的方式散佈於1057D-6939-PF 8 200535255 Binder matrix. 18. A hard metal composition comprising: hard particles having a first material; and a binder matrix having a second material different from the first material; wherein the second material accounts for the hard material The total volume of the metal composition is 3 to 40%; wherein, the binder matrix includes Baht ... about and molybdenum (m0) element 'wherein' the above-mentioned hard particles are dispersed in the binder matrix in a substantially uniform manner. 19. A hard metal composition comprising: hard particles having a first material including a nitride; and a binder matrix (bind ... rix) having one of a second material different from the first material; wherein the second The material accounts for 3 to 40% of the total volume of the hard metal composition; wherein the binder matrix includes baht and iron rhenium elements, and the hard particles are dispersed in the binder matrix in a substantially uniform manner. 20. A hard metal composition comprising: hard particles having a first material; and a binder⑽atrix having a second material different from the first material; wherein 'the second material accounts for the hard metal The composition contains talus body 3 ~ peach; wherein, the binder matrix includes chain element and complex element, and the hard particles are dispersed in the binder matrix in a substantially uniform manner. • a binder matrix 21, which is one of the hard material two materials of the first material, a hard metal composition including a seed, and a binder material different from the first material (bindermatHx); wherein the second material accounts for the hard material 3 to 40% of the volume of the metal composition; wherein the binder matrix includes Ba (Re) * Ni-based superalloy elements, wherein the hard particles are dispersed in a substantially uniform manner

1057D-6939-PF 9 /200535255 該黏結劑基質中。 2 2 ·如第2 1項所述之硬金屬組合物，其中該黏結劑基質材料更進一步包括Co 23 · —種硬金屬組合物，包括：具有第一材料的硬粒子，其中該第一材料具有至少一下列混合物：（1)WC，TiC 與TaC的混合物，（2)WC，TiC與NbC的混合物，（3)WC，TiC 與至少TaC與NbC中之一的混合物，（4)WC，TiC與至少 HfC與NbC中之一的混合物；以及具有與第一材料不同之 9 第二材料之一黏結劑基質（binder matrix);其中，該第二材料係佔該硬金屬組合物總體積的3〜40% ;其中，該黏結劑基質包括銖（Re)元素；其中，上述硬粒子係以實質均勻的方式散佈於該黏結劑基質中。 24. —種硬金屬組合物，包括：具有第一材料的硬粒子’其中該弟一材料具有至少一下列混合物：（i)wc TiC! 與TaC的混合物，（2)WC，TiC與NbC的混合物，（3)wc，Tic 與至少TaC與NbC中之一的混合物，（4)WC，TiC與至少 * HfC與NbC中之一的混合物；以及具有與第一材料不同之第二材料之一黏結劑基質（binder matrix);其中，該第二材料係佔該硬金屬組合物總體積的3〜4〇% ;其中，該黏結劑基質包括銖（Re)元素及Ni基超合金；其中，上述硬粒子係以實質均勻的方式散佈於該黏結劑基質中。 25. —種硬金屬組合物，包括：具有第一材料的硬粒子，其中該第一材料具有M〇2C與TiC的混合物；以及具有與第一材料不同之第二材料之一黏結劑基質（binder1057D-6939-PF 9/200535255 in the adhesive matrix. 2 2 · The hard metal composition according to item 21, wherein the binder matrix material further includes Co 23 · a hard metal composition including: hard particles having a first material, wherein the first material Have at least one of the following mixtures: (1) WC, a mixture of TiC and TaC, (2) WC, a mixture of TiC and NbC, (3) WC, a mixture of TiC and at least one of TaC and NbC, (4) WC, A mixture of TiC with at least one of HfC and NbC; and a binder matrix having one of 9 and a second material different from the first material; wherein the second material accounts for the total volume of the hard metal composition 3 ~ 40%; wherein the adhesive matrix includes Ba (Re) element; wherein the hard particles are dispersed in the adhesive matrix in a substantially uniform manner. 24. A hard metal composition comprising: hard particles having a first material, wherein the first material has at least one of the following mixtures: (i) a mixture of wc TiC! And TaC, (2) a mixture of WC, TiC and NbC A mixture, (3) a mixture of wc, Tic and at least one of TaC and NbC, (4) a mixture of WC, TiC and at least one of * HfC and NbC; and one of the second materials having a difference from the first material A binder matrix; wherein the second material accounts for 3 to 40% of the total volume of the hard metal composition; wherein the binder matrix includes a Ba element and a Ni-based superalloy; wherein, The hard particles are dispersed in the binder matrix in a substantially uniform manner. 25. A hard metal composition comprising: hard particles having a first material, wherein the first material has a mixture of MoC and TiC; and a binder matrix having one of a second material different from the first material ( binder

1057D-693 9-PF 10 200535255 matrix) ’其中’該第二材料係佔該硬金屬組合物總體積的 3〜40體積％;其中，該黏結劑基質包括銖（Re)元素；其中，上述硬粒子係以實質均勻的方式散佈於該黏結劑基質中。 26· 種硬金屬組合物，包括··具有包括TiN、Mo2C 與TiC第一材料的硬粒子；以及具有與第一材料不同之第二材料之一黏結劑基質（binder matrix);其中，該第二材料係佔該硬金屬組合物總體積的3〜4〇% ;其中，該黏結劑基質包括銖（Re)元素；其中，上述硬粒子係以實質均勻的方 • 式散佈於該黏結劑基質中。 27· 種硬金屬組合物’包括：具有包括m〇2C與TiC 的第一材料之硬粒子；以及具有與第一材料不同之第二材料之一黏結劑基質（bindermatrix);其中，該第二材料係佔該硬金屬組合物總體積的3〜4〇% ;其中，該黏結劑基質包括銖（Re)元素及Ni基超合金；其中，上述硬粒子係以實質均勻的方式散佈於該黏結劑基質中。 _ 28. —種硬金屬組合物的成形方法，包括下列步驟：經由混合具有硬粒子的粉末與包括有銖（Re)的一黏結劑基質材料，而形成一階段性的粒子；以及利用該黏結劑基質材料黏結該等硬粒子，而進行一製程使上述階段性的粒子被製造成-固態的硬金屬材料；其中該製程包括：⑴在真，條件下，於固相中燒結該階段性的粒子，以及⑺在具有壓力的惰性氣氛中，於固相中燒結該階段性的粒子。 29.如第28項所述之硬金屬組合物的成形方法，其中該黏結劑基質係更包括鎳基超合金。1057D-693 9-PF 10 200535255 matrix) 'wherein' the second material is 3 to 40% by volume of the total volume of the hard metal composition; wherein the binder matrix includes Ba (Re) element; wherein, the hard The particles are dispersed in the binder matrix in a substantially uniform manner. 26. A hard metal composition including: hard particles having a first material including TiN, Mo2C, and TiC; and a binder matrix having a second material different from the first material; wherein the first Two materials account for 3 ~ 40% of the total volume of the hard metal composition; wherein the binder matrix includes Ba (Re) element; wherein the hard particles are dispersed in the binder matrix in a substantially uniform manner. in. 27 · A kind of hard metal composition 'including: hard particles having a first material including m 2 C and TiC; and a binder matrix having one of a second material different from the first material; wherein the second The material system accounts for 3 to 40% of the total volume of the hard metal composition; wherein the binder matrix includes Ba (Re) elements and Ni-based superalloys; wherein the hard particles are dispersed in the bond in a substantially uniform manner. Agent matrix. _ 28. A method for forming a hard metal composition, comprising the following steps: forming a staged particle by mixing a powder having hard particles and a binder matrix material including Ba (Re); and using the adhesion The matrix material binds the hard particles, and a process is performed to make the above-mentioned stepwise particles into a solid metal material. The process includes: sintering the stepwise solid phase in a solid phase under real conditions. The particles and rhenium are sintered in a solid phase in a solid inert atmosphere under pressure. 29. The method for forming a hard metal composition according to item 28, wherein the binder matrix further comprises a nickel-based superalloy.

1057D-6939-PF 11 200535255 30.如第29項所述之硬金屬组合物的成形方法，其令該黏結劑基質係更包括鈷（Co)。 ~ 3】·如第28項所述之硬金屬組合物的成形方法，其中該黏結劑基質係更包括鈷（Co)。 32.如第28項所述之硬金屬組合物的成形方法，其中上述每一步驟的燒結製程係在低於該等硬粒子與該黏結劑基質的共熔（eutectic)溫度下進行。 33· —種硬金屬組合物，包括··具有第一材料的硬粒子；以及具有與第一材料不同之第二材料之一黏結劑基質 (binder matrix)，該第二材料係包括鎳基超合金；其中上述硬粒子係以貫質均勻的方式散佈於該黏結劑基質中。 34·如第33項或第47項所述之硬金屬組合物，其中該第一材料係包括含有鎢的碳化物。 35·如第34項所述之硬金屬組合物，其中該碳化物係包括單原子的碳化鎢（WC)。 3 6·如第34項所述之硬金屬組合物，其中該第一材料 1更包括含有不同於鎢的金屬之碳化物。 37·如第36項所述之硬金屬組合物，其中該金屬係鈦 (Ti)。 38·如第36項所述之硬金屬組合物，其中該金屬係鈕 (Ta)。 ' 39·如第36項所述之硬金屬組合物，其中該金屬係銳 (Nb) 〇1057D-6939-PF 11 200535255 30. The method for forming a hard metal composition according to item 29, wherein the binder matrix further comprises cobalt (Co). ~ 3] The method for forming a hard metal composition according to item 28, wherein the binder matrix further comprises cobalt (Co). 32. The method for forming a hard metal composition according to item 28, wherein the sintering process of each step is performed at a temperature lower than the eutectic temperature of the hard particles and the binder matrix. 33. A hard metal composition comprising: hard particles having a first material; and a binder matrix having one of a second material different from the first material, the second material comprising a nickel-based An alloy; wherein the hard particles are dispersed in the adhesive matrix in a uniform and uniform manner. 34. The hard metal composition according to item 33 or item 47, wherein the first material comprises tungsten-containing carbide. 35. The hard metal composition according to item 34, wherein the carbide system comprises a single-atom tungsten carbide (WC). 36. The hard metal composition according to item 34, wherein the first material 1 further comprises a carbide containing a metal different from tungsten. 37. The hard metal composition according to item 36, wherein the metal is titanium (Ti). 38. The hard metal composition according to item 36, wherein the metal is a button (Ta). '39. The hard metal composition according to item 36, wherein the metal is sharp (Nb).

40·如第36項所述之硬金屬組合物，其中該金屬係釩 1057D-6939-PF 12 200535255 (v)。 41. 如第36項所述之硬金屬組合物，其中該金屬係鉻 (Cr)。 42. 如第36項所述之硬金屬組合物，其中該金屬係铪 (Hf)。 43·如第36項所述之硬金屬組合物，其中該金屬係鉬 (Mo)。 44·如第34項所述之硬金屬組合物，其中該第一材料籲更包括一氮化物。 45·如第44項所述之硬金屬組合物，其中該氮化物係包括 ZrN，HfN、VN、NbN、TaN 及 TiN。 46.如第44項所述之硬金屬組合物，其中該氮化物係包括HfN。 47·如第33項所述之硬金屬組合物，其中該第一材料更包括一氮化物。 48. 如第47項所述之硬金屬組合物，其中該氮化物係 _ 包括至少 ZrN、VN、NbN、TaN TiN 及 HfN 之一。 49. 如第33項所述之硬金屬組合物，其中該鎳基超合金係主要包括鎳元素以及更包括其他元素。 5〇·如第49項所述之硬金屬組合物，其中該其他元素係包括 Co, Cr，Al，Ti，Mo, Nb，W 與 Zr。 5 1 ·如第3 3項所述之硬金屬組合物，其中該黏結劑基質更包括不同於鎳（Ni)基超合金的一第二超合金。40. The hard metal composition according to item 36, wherein the metal is vanadium 1057D-6939-PF 12 200535255 (v). 41. The hard metal composition according to item 36, wherein the metal is chromium (Cr). 42. The hard metal composition according to item 36, wherein the metal is hafnium (Hf). 43. The hard metal composition according to item 36, wherein the metal is molybdenum (Mo). 44. The hard metal composition according to item 34, wherein the first material further includes a nitride. 45. The hard metal composition according to item 44, wherein the nitride system comprises ZrN, HfN, VN, NbN, TaN, and TiN. 46. The hard metal composition according to item 44, wherein the nitride system comprises HfN. 47. The hard metal composition according to item 33, wherein the first material further comprises a nitride. 48. The hard metal composition according to item 47, wherein the nitride system includes at least one of ZrN, VN, NbN, TaN TiN, and HfN. 49. The hard metal composition according to item 33, wherein the nickel-based superalloy mainly includes nickel and further includes other elements. 50. The hard metal composition according to item 49, wherein the other element system includes Co, Cr, Al, Ti, Mo, Nb, W, and Zr. 51. The hard metal composition according to item 33, wherein the binder matrix further comprises a second superalloy different from a nickel (Ni) -based superalloy.

5 2 ·如第5 1項所述之硬金屬組合物，其中該黏結劑基 1057D-6939-PF 13 200535255 質係更包括銖（Re)。 53. 如申請專利範圍帛52項所述之硬金屬組合物，其中該黏結劑基質係更包括錄（c 〇)。 54. 如申請專利範圍帛33項所述之硬金屬組合物，直中該黏結劑基質係更包括鍊（Re)。 ^ 55. -種硬金屬組合物，包括：具有第一材料的硬粒子；以及具有與第一材料不同之第二材料之一黏結劑基質 _叫，該第二材料係包括鎳基超合金、銖(及銘㈣元素4中，上述硬粒子係以實質均句的於該黏結劑基質中。 ^ 56. -種硬金屬組合物，包括：具有第一材料的硬粒子；以及具有與第-材料不同之第：材料之—黏結劑基質 (W —ίΧ) ’該第二材料係包括鎳基超合金及銘(Co)元上述硬粒子係以實質均勻的方式散佈於該黏結 •具有第一材料的硬粒二材料之一黏結劑基質鎳基超合金及鎳（Ni)元勻的方式散佈於該黏結5 2 The hard metal composition as described in item 51, wherein the binder base 1057D-6939-PF 13 200535255 includes Baht (Re). 53. The hard metal composition according to item 52 of the application, wherein the binder matrix system further includes (c). 54. The hard metal composition described in item 33 of the application, wherein the adhesive matrix system further includes a chain (Re). ^ 55. A hard metal composition comprising: hard particles having a first material; and a binder matrix having a second material different from the first material. The second material includes a nickel-based superalloy, In Baht (and Ming Yuan Element 4, the above-mentioned hard particles are substantially homogeneous in the adhesive matrix. ^ 56.-A hard metal composition comprising: hard particles having a first material; and Different materials: the material-the binder matrix (W — ί) 'The second material system includes nickel-based superalloys and Co (Co) yuan The above hard particles are dispersed in the bond in a substantially uniform manner. One of the cementitious materials of the material, the binder matrix nickel-based superalloy and the nickel (Ni) element are dispersed in the adhesive in a uniform manner.

57· —種硬金屬組合物，包括子；以及具有與第一材料不同之第 (binder matrix)，該第二材料係包括素；其中，上述硬粒子係以實質均劑基質中。 •具有第一材料的硬粒子；以及具有與第一材料不同之第- 叶1更位弟一材料之一黏結劑基質 (bmder matnx)，該第二材料係包括鎳基超合金及鐵（Fe)元素，其中，上述硬粒子係以實質、—勻的方式散佈於該黏結57. A hard metal composition comprising a substrate, and a binder matrix different from the first material, the second material system comprising a substrate; wherein the hard particles are in a substantially homogenous matrix. • Hard particles with a first material; and a binder matrix (bmder matnx), which is one of the first and second materials that is different from the first material. The second material includes a nickel-based superalloy and iron (Fe ) Element, wherein the hard particles are dispersed in the cement in a substantially uniform manner.

1057D-6939-PF 14 200535255 劑基質中。 59. —種硬金屬組合物，包括··且旱·以；5且古盥筮4, /、有第材料的硬粒子及具有與弟一材料不同之第二材料之-黏結劑基質 (binder matrix)，該第二材料、 ...^ , 匕秸鏢基超合金及鉬（Mo) ^ tF ^ ^ ^ 以貝貝均勻的方式散佈於該黏結劑基質中。子.：及屬組合物’包括：具有第-材料的硬粒 :.，d :、弟一材料不同之第二材料之-黏結劑基質 (bmder matnx)，該第二材料得辛·盆中，卜、f石“ 2 ，、匕括鎳基超合金及鉻（Cr)元 :其中上述硬粒子係以實質均勾的方式散佈劑基質中。 61·如弟33項所述之硬全屬金屬組合物，其中該黏結劑基質係更匕括不同於鎳基超合金的其他合金。工，Γ·二種硬金屬組合物，包括··具有第-材料的硬粒、’、該第一材料具有Tic與TiN ;以及具有與第一材料不同之第：材料之_黏結劑基質（_⑽咖χ)，該第二材料係包括至少Ni、Μ ^ — 興Μ〇β之一，其中，上述硬粒子係以貫質均勻的方式散佈於該黏結劑基質中。 63.-種硬金屬組合物’包括：具有第一材料的硬粒 ::該第-材料具有Tic與TiN;以及具有與第一材料不同之第—材料之一黏結劑基質matrix)，該具有素的第二材料係包括至少Ni、M〇與Μ。,之一；1057D-6939-PF 14 200535255 agent matrix. 59. A kind of hard metal composition, including ... and dryness; 5 and ancient toilet 4, 4, hard particles with a first material, and a binder with a second material different from the first material (binder) matrix), the second material, ... ^, dart base superalloy and molybdenum (Mo) ^ tF ^ ^ ^ are dispersed in the adhesive matrix in a uniform manner. Sub .: and the composition 'includes: hard particles with a first material:., D :, a second material of a second material which is different-a binder matrix (bmder matnx), the second material is in Xin · Bazhong , Bu, f "2", dagger nickel-based superalloy and chromium (Cr) element: wherein the above-mentioned hard particles are dispersed in the agent matrix in a substantially uniform manner. 61. The hard as described in item 33 A metal composition in which the binder matrix is other alloys different from nickel-based superalloys. ， · Two kinds of hard metal composition, including hard particles having a first material, ', the first The material has Tic and TiN; and a material different from the first material: the material's binder matrix (_⑽ coffee χ), the second material includes at least one of Ni, M ^ — Xing M0 β, wherein the above Hard particles are dispersed in the binder matrix in a uniform and homogeneous manner. 63. A hard metal composition including: hard particles having a first material: the first material having Tic and TiN; and A material is different-one of the materials is a binder matrix), and the second material having a prime includes Less Ni, Mo and M., one;

其中’上述硬粒子係以實質均勻的方式散佈於該黏結劑基質中。 1057D-6939-PF 15 200535255 64· 如第μ 質係更包括錄(c〇)項所述之硬金屬組合物，其中該黏結劑基 6 5 · 如第質係更包括_^之硬金^合物’其中該黏結劑基 66. 如第& 質係二包括C:。之硬金屬組合物，其中該黏結劑基種硬金屬組合物，包括子，JL中兮镩祜具有弟一材料的硬粒 ’、〜—材料具有Ti<：與TiN ;以及且右|^ 料不同之笫-从」乂及具有與第一材第—材料之一黏結劑基質心鎳（Ni)基超合金 tnx)該具有一；盆 /弟一材科係包括至少Ni、M〇與M〇2C之 ’上述硬粒子係以實質均匂的古斗血从劑基質中。、勺的方式放佈於該黏結 _ 種硬金屬組合物的成形方法，包括下列步驟：經由混合具有硬粒子的粉末與* 劑基質材料，而形成一階段性的粒==的-黏結美皙鉍Μ # α 子，以及利用該黏結劑Among them, the aforementioned hard particles are dispersed in the binder matrix in a substantially uniform manner. 1057D-6939-PF 15 200535255 64 · The hard metal composition as described in the item (c) of the μ-mass system, wherein the binder group 6 5 · The hard gold of the ^^ system includes ^^ Conjugate 'wherein the binder group is 66. As & A hard metal composition, wherein the binder-based hard metal composition includes a hard particle having a material of J1 in JL, and a material having Ti <: and TiN; and The difference is the "from" and has a binder matrix core nickel (Ni) -based superalloy tnx) which is one of the first material, the material has at least one; the pedestal / brief material family includes at least Ni, Mo and M 〇2C of the above-mentioned hard particles are substantially homogeneous Gudou blood from the agent matrix. The method of forming a hard metal composition in a spoonful manner includes the following steps: By mixing a powder with hard particles and a base material of the agent, a one-stage particle is formed ==-the adhesion is beautiful Bismuth M # α and its use

土貝材科黏J口該等硬粒子，而進一私工4备丨、裳私使上述階段性的 4子被製造成一固態的硬金屬材料。 ,69.如第68項所述之硬金屬組合物的成形方法，該製程係連續地進行下列步驟： (1 ) 一衝壓製程； (2) —第一燒結製程； (3) —成形製程；以及 (4)一第二燒結製程。 70.如第68項所述之硬金屬組合物的成形方法，在該 1057D-6939-PF 16 200535255 混合步驟之前’更包括使該黏結劑基質更包括有銖（Re)之一預備製程。 7 1 ·如第6 8項所述之硬金屬組合物的成形方法，在該混合步驟之前，更包括使該黏結劑基質更包括有鈷（c〇)之一預備製程。 72. 如第68項所述之硬金屬組合物的成形方法，其中該製程包括在一熱均壓製程中的一固相燒結。 73. 如第68項所述之硬金屬組合物的成形方法，其中 ♦該製程包括：⑴在真空條件下，於固相中燒結該階段性的粒子，以及（2)在具有壓力的惰性氣氛中，於固相中燒結該階段性的粒子。 AIπ、低口 Μ π砜取万法，在該混合步驟之前’更包括使該等硬粒子具有小於0 5_的粒子徑，用以降低該等燒結製程的溫度。The soil shell material sticks the hard particles in the mouth, and a private worker prepares the above-mentioned four phases to be made into a solid hard metal material. 69. The method for forming a hard metal composition according to item 68, the process continuously performs the following steps: (1) a stamping process; (2) — the first sintering process; (3) — the forming process; And (4) a second sintering process. 70. The method for forming a hard metal composition according to item 68, before the 1057D-6939-PF 16 200535255 mixing step ', further comprising a preliminary process of making the adhesive matrix further include Ba (Re). 7 1. The method for forming a hard metal composition according to item 68, further comprising a preliminary process of making the adhesive matrix further include cobalt (c) before the mixing step. 72. The method for forming a hard metal composition according to item 68, wherein the process includes a solid phase sintering in a hot homogenization process. 73. The method for forming a hard metal composition according to item 68, wherein the process includes: (1) sintering the phased particles in a solid phase under a vacuum condition, and (2) an inert atmosphere under pressure The stepwise particles are sintered in a solid phase. AIπ, low-mouth Mπ sulfone extraction method, before the mixing step, ′ further includes making the hard particles have a particle diameter smaller than 0 5_ to reduce the temperature of the sintering process.

_ 75.-種硬金屬組合&，用以當作是具有一耐磨部分的元件的構成材料’該耐磨部分用以去除—物品的該耐磨部分的構成材料包括：且及具有與第一材料不同之第_=:枓的硬粒子；以 mat. . ^墙之第—材枓之一黏結劑基質（binder lx)’ ^弟—材料係包括銖與鎳基超合金；其中，硬粒子係以實質均勾的方式散佈於該黏結劑基質中。^ 如第75項所述之硬金屬組合物，直質係更包括鈷(Co)。 -中該黏結劑基種硬金屬組合物，以一材料，該❹it件件的構成件的構成材料包括··具有第一材料的硬粒_ 75.- A kind of hard metal combination & used as a constituent material of a component having a wear-resistant portion 'the wear-resistant portion is used to remove—the wear-resistant portion of the article includes: The first material is different from the _ =: 枓 hard particles; with mat. Hard particles are dispersed in the adhesive matrix in a substantially uniform manner. ^ The hard metal composition as described in item 75, the direct system further includes cobalt (Co). -The binder-based hard metal composition is made of a material, and the constituent materials of the component include hard particles having a first material.

1057D-6939-PF 17 /200535255 子；以及具有與第一材料不同之第二材料之一黏結劑基質 (binder matrix)，該第二材料係包括鎳基超合金；其中，上述硬粒子係以貫質均勻的方式散佈於該黏結劑基質中。 78. —種硬金屬組合物，包括··具有第一材料的硬粒子，其中該弟一材料具有至少一下列混合物··（ 1)wc，τιc 與TaC的固溶體，（2)WC，Tic與Nbc的固溶體，（3)wc，Tic 與至少TaC與NbC中之一的固溶體，（4)WC，TiC與至少 HfC與NbC中之一的固溶體；以及具有與第一材料不同之 _ 苐一材料之一黏結劑基質（binder matrix);其中，該第二材料係佔該硬金屬組合物總體積的3〜4〇% ;其中，該黏結劑基質包括銖（Re)元素；其中，上述硬粒子係以實質均勻的方式散佈於該黏結劑基質中。 79·如第78項所述之硬金屬組合物，其中該等硬粒子包括WC，TiC與TaC的固溶體，且該黏結劑基質係由純銖 (Re)元素所構成。 8 〇 ·如第7 9項所述之硬金屬組合物，其中該固溶體係修佔該硬金屬組合物總體積的72%，而該係銖（Re)元素佔該硬金屬組合物總體積的28%。 8 1 ·如苐7 9項所述之硬金屬組合物，其中該固溶體係佔該硬金屬組合物總體積的85體積％，而該銖（Re)元素係佔該硬金屬組合物總體積的15%。 82·如第79項所述之硬金屬組合物，其中TiC與TaC 係約等量，且Tic與TaC的總量係少於WC的量。 8 3 ·如第7 8項所述之硬金屬組合物，其中該硬粒子包 1057D-6939-PF 18 200535255 括WC，TiC與TaC的固溶體。 84·如第83項所述之硬金屬組合物，其中Tic係佔該硬金屬組合物總重量的3至6%，TaC係佔該硬金屬組合物總重量的3至6%，而WC佔該硬金屬組合物總重量的78 至 89%。 8 5 ·如第8 3項所述之硬金屬組合物，其中該黏結劑基質更包括Co。 86.如第83項所述之硬金屬組合物，其中該鎳基超合 Φ 金係主要包括鎳以及其他元素，上述其他元素包括Co, Cr， Al，Ti，Mo, Nb，W，Zr，B，C 與 V。 8 7 · —種硬金屬組合物，包括：具有第一材料的硬粒子，其中該第一材料具有至少一下列混合物：（1)WC，TiC 與TaC的固溶體，（2)WC，TiC與NbC的固溶體，（3)WC，TiC 與至少TaC與NbC中之一的固溶體，（4)WC，TiC與至少 HfC與NbC中之一的固溶體；以及具有與第一材料不同之第二材料之一黏結劑基質（binder matrix);其中，該第二材 _ 料係佔該硬金屬組合物總體積的3〜40% ;其中，該黏結劑基質包括銖（Re)元素；其中，上述硬粒子係以實質均勻的方式散佈於該黏結劑基質中。 88·如申請專利範圍第21項所述之硬金屬組合物，其中該鎳基超合金包括Re。 89.如第24項所述之硬金屬組合物，其中該鎳基超合金包括Re。 90·如第27項所述之硬金屬組合物，其中該鎳基超合 1057D-6939-PF 19 ••200535255 金包括Re。 91· 一種硬金屬組合物，包括：呈，、有弟一材料的子；以及具有與第一材料不同之第二更位 η ^ 點結劑基質 (binder matrix)，該第二材料係包括鎳基超合金其中、述硬粒子係以實質均句的方式散佈於該黏結#|㈣中，’ ^ 中該鎳基超合金含有Re。〃 92· —種硬金屬組合物，包括〔具有 /、3罘材枓的硬粒子；以及具有與第一材料不同之第-好袓乐一材枓之一黏結劑基質 (binder matrix)，該第二材料係包括鎳基超合金；其中，、述硬粒子係以實質均句的方式散佈於該黏結劑基質中，其中該鎳基超合金在γ-γ’相中。〃 93· -種硬金屬組合物，包括：具有第一材料的硬粒子；以及具有與第一材料不同之第二材料之一黏結劑基質 (binder matrix)，該第二材料係包括鎳基超合金係主要包括鎳以及其他元素，上述其他元素包括c〇, Cr，A1，Ti，Μα，Nb， W，Zr 與 Re。 94·如第17項所述之硬金屬組合物，其中該第一材料包括一观化物。 95.如第94項所述之硬金屬組合物，其中該硼化物為1057D-6939-PF 17/200535255; and a binder matrix having a second material different from the first material, the second material includes a nickel-based superalloy; wherein the hard particles are It is dispersed in a homogeneous manner in the adhesive matrix. 78. A hard metal composition comprising: hard particles having a first material, wherein the material has at least one of the following mixtures: (1) a solid solution of wc, τιc and TaC, (2) WC, A solid solution of Tic and Nbc, (3) a solid solution of wc, Tic and at least one of TaC and NbC, (4) a solid solution of WC, TiC and at least one of HfC and NbC; A material is different_ one of the materials is a binder matrix; wherein the second material accounts for 3 to 40% of the total volume of the hard metal composition; wherein the binder matrix includes Ba (Re ) Element; wherein the hard particles are dispersed in the adhesive matrix in a substantially uniform manner. 79. The hard metal composition according to item 78, wherein the hard particles include a solid solution of WC, TiC, and TaC, and the binder matrix is composed of pure Ba (Re) elements. 80. The hard metal composition according to item 79, wherein the solid solution system accounts for 72% of the total volume of the hard metal composition, and the Ba (Re) element accounts for the total volume of the hard metal composition. 28%. 8 1 · The hard metal composition according to item 苐 9, wherein the solid solution system accounts for 85% by volume of the total volume of the hard metal composition, and the Ba (Re) element accounts for the total volume of the hard metal composition. 15%. 82. The hard metal composition according to item 79, wherein TiC and TaC are about the same amount, and the total amount of Tic and TaC is less than the amount of WC. 8 3. The hard metal composition according to item 78, wherein the hard particles include 1057D-6939-PF 18 200535255 including a solid solution of WC, TiC and TaC. 84. The hard metal composition according to item 83, wherein Tic is 3 to 6% of the total weight of the hard metal composition, TaC is 3 to 6% of the total weight of the hard metal composition, and WC is 78 to 89% of the total weight of the hard metal composition. 8 5. The hard metal composition according to item 83, wherein the binder substrate further comprises Co. 86. The hard metal composition according to item 83, wherein the nickel-based super-coated Φ gold system mainly includes nickel and other elements, and the other elements include Co, Cr, Al, Ti, Mo, Nb, W, Zr, B, C and V. 8 7 · A hard metal composition comprising: hard particles having a first material, wherein the first material has at least one of the following mixtures: (1) solid solution of WC, TiC and TaC, (2) WC, TiC Solid solution with NbC, (3) solid solution of WC, TiC and at least one of TaC and NbC, (4) solid solution of WC, TiC and at least one of HfC and NbC; and A binder matrix of a second material with a different material; wherein the second material is 3 to 40% of the total volume of the hard metal composition; wherein the binder matrix includes baht (Re) Element; wherein the hard particles are dispersed in the adhesive matrix in a substantially uniform manner. 88. The hard metal composition according to item 21 of the patent application scope, wherein the nickel-based superalloy includes Re. 89. The hard metal composition according to item 24, wherein the nickel-based superalloy includes Re. 90. The hard metal composition according to item 27, wherein the nickel-based supercomposite 1057D-6939-PF 19 • 200535255 gold includes Re. 91. A hard metal composition comprising: a substrate having a material; and a second matrix η ^ bond matrix different from the first material, the second material system including nickel In the base superalloy, the hard particles are dispersed in the bond # | ㈣ in a substantially uniform manner, and the nickel-based superalloy contains Re. 〃 92 · —A kind of hard metal composition, including [hard particles with /, 3 罘 material ；; and a binder matrix different from the first material, a binder matrix, the The second material system includes a nickel-based superalloy; wherein, the hard particles are dispersed in the binder matrix in a substantially uniform manner, and the nickel-based superalloy is in a γ-γ 'phase. 〃 93 ·-A hard metal composition including: hard particles having a first material; and a binder matrix having one of a second material different from the first material, the second material comprising a nickel-based The alloy system mainly includes nickel and other elements, and the above other elements include co, Cr, A1, Ti, Mα, Nb, W, Zr, and Re. 94. The hard metal composition as described in item 17, wherein the first material includes a speculative compound. 95. The hard metal composition according to item 94, wherein the boride is

TiB2, ZrB2, HfB2、TaB2、VB2、MoB2、WB 及 W2B 其中之一0 96·如第17項所述之硬金屬組合物，其中該第一材料包括一石夕化物。 97·如第96項所述之硬金屬組合物，其中該矽化物為 1057D-6939-PF 20 •200535255 夤One of TiB2, ZrB2, HfB2, TaB2, VB2, MoB2, WB, and W2B. 0 96. The hard metal composition according to item 17, wherein the first material includes a petrochemical. 97. The hard metal composition according to item 96, wherein the silicide is 1057D-6939-PF 20 • 200535255 夤

TaSi2、Wsi2、NbSi2 及 MoSi2 其中之一。 98·如第17項所述之硬金屬組合物，其中該第一材料包括一碳化物。 99·如第98項所述之硬金屬組合物，其中該碳化物為 TiC，ZrC， HfC、VC、NbC、TaC、Cr2C3、Mo2C 及 WC 其中之一。 100·如第17項所述之硬金屬組合物，其中該第一材料更進一步包括一氮化物。 • 101·如第1〇〇項所述之硬金屬組合物，其中該氮化物包括至少TiN、ZrN、HfN、VN、NbN及 TaN其中之一。 102·如第100項所述之硬金屬組合物，其中第一材料更進一步包括一碳化物。 103·如第102項所述之硬金屬組合物、其中碳化物包括至少 Tic、ZrC、HfC、VC、NbC、TaC、Cr2C3、Mo2C 及we其中之一。 104.如第102項所述之硬金屬組合物、其中氮化物包 # 括至少 TiN、ZrN、HfN、VN、NbN 及 TaN 其中之一 105·如第18項所述之硬金屬組合物，其中該第一材料包括一硼化物。 1 〇 6 ·如第1 0 5項所述之硬金屬組合物，其中棚化物包括 TiB2、ZrB2、HfB2、TaB2、VB2、MoB2、WB 及 W2B 其中之一 107·如第18項所述之硬金屬組合物，其中該第一材料包括一石夕化物。 1057D-6939-PF 21 200535255 • 108.如第107項所述之硬金屬組合物，其中該石夕化物為 TaSi2、Wsi2、NbSi2 及 MoSi2 其中之一 I 09·如第1 8項所述之硬金屬組合物，其中該第一材料包括一碳化物。 110·如第109項所述之硬金屬組合物，其中該碳化物包括 TiC、ZrC、HfC、VC、NbC、TaC、Cr2C3、Mo2C 及 WC其中之一 111. 如第18項所述之硬金屬組合物，其中該第一材 _ 料包括一氮化物。 112. 如第111項所述之硬金屬組合物，其中該氮化物包括至少TiN、ZrN、HfN、VN、NbN及TaN其中之一。 113·如第111項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物。 114·如第113項所述之硬金屬組合物，其中該碳化物包括至少 TiC、ZrC、HfC、VC、NbC、TaC、Cr2C3、Mo2C 及 WC其中之一。 Φ 11 5 ·如第113項所述之硬金屬組合物，其中該氮化物包括至少TiN、ZrN、HfN、VN、NbN及TaN其中之一。 116·如第19項所述之硬金屬組合物，其中該第一材料包括一碳化物。 117.如第116項所述之硬金屬組合物，其中該碳化物包括至少 TiC、ZrC、HfC、VC、NbC、TaC、Cr2C3、Mo2C 及 WC其中之一。 II 8 ·如第19項所述之硬金屬組合物，其中該第一材 1057D-6939-PF 22 -200535255 料包括一硼化物。 1 1 9.如第1 1 8項所述之硬金屬組合物，其中該硼化物為 TiB2，ZrB2、HfB2、TaB2、VB2、MoB2、WB 及 W2B 其中之一。 120. 如第19項所述之硬金屬組合物，其中該第一材料包括一矽化物。 121. 如第120項所述之硬金屬組合物，其中該矽化物為 TaSi、Wsi2、NbSi2 及 MoSi2 其中之一。 # 122.如第19項所述之硬金屬組合物，其中該第一材料包括一氮化物。 123. 如第122項所述之硬金屬組合物，其中該氮化物包括至少TiN、ZrN、HfN、VN、NbN及 TaN其中之一。 124. 如第122項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物。One of TaSi2, Wsi2, NbSi2 and MoSi2. 98. The hard metal composition according to item 17, wherein the first material includes a carbide. 99. The hard metal composition according to item 98, wherein the carbide is one of TiC, ZrC, HfC, VC, NbC, TaC, Cr2C3, Mo2C, and WC. 100. The hard metal composition according to item 17, wherein the first material further comprises a nitride. 101. The hard metal composition according to item 100, wherein the nitride includes at least one of TiN, ZrN, HfN, VN, NbN, and TaN. 102. The hard metal composition according to item 100, wherein the first material further includes a carbide. 103. The hard metal composition according to item 102, wherein the carbide includes at least one of Tic, ZrC, HfC, VC, NbC, TaC, Cr2C3, Mo2C, and we. 104. The hard metal composition according to item 102, wherein the nitride # includes at least one of TiN, ZrN, HfN, VN, NbN, and TaN 105. The hard metal composition according to item 18, wherein The first material includes a boride. 1 06. The hard metal composition according to item 105, wherein the shelf compound includes one of TiB2, ZrB2, HfB2, TaB2, VB2, MoB2, WB, and W2B 107. The hard material according to item 18 A metal composition, wherein the first material includes a petrified compound. 1057D-6939-PF 21 200535255 • 108. The hard metal composition according to item 107, wherein the petrified compound is one of TaSi2, Wsi2, NbSi2 and MoSi2 I 09 · Hardness according to item 18 A metal composition, wherein the first material includes a carbide. 110. The hard metal composition according to item 109, wherein the carbide includes one of TiC, ZrC, HfC, VC, NbC, TaC, Cr2C3, Mo2C, and WC. 111. The hard metal according to item 18 A composition, wherein the first material includes a nitride. 112. The hard metal composition according to item 111, wherein the nitride comprises at least one of TiN, ZrN, HfN, VN, NbN, and TaN. 113. The hard metal composition according to item 111, wherein the first material further includes a carbide. 114. The hard metal composition according to item 113, wherein the carbide includes at least one of TiC, ZrC, HfC, VC, NbC, TaC, Cr2C3, Mo2C, and WC. Φ 11 5 The hard metal composition according to item 113, wherein the nitride includes at least one of TiN, ZrN, HfN, VN, NbN, and TaN. 116. The hard metal composition according to item 19, wherein the first material includes a carbide. 117. The hard metal composition according to item 116, wherein the carbide includes at least one of TiC, ZrC, HfC, VC, NbC, TaC, Cr2C3, Mo2C, and WC. II 8-The hard metal composition according to item 19, wherein the first material 1057D-6939-PF 22 -200535255 comprises a boride. 1 1 9. The hard metal composition according to item 118, wherein the boride is one of TiB2, ZrB2, HfB2, TaB2, VB2, MoB2, WB, and W2B. 120. The hard metal composition according to item 19, wherein the first material comprises a silicide. 121. The hard metal composition according to item 120, wherein the silicide is one of TaSi, Wsi2, NbSi2, and MoSi2. # 122. The hard metal composition according to item 19, wherein the first material includes a nitride. 123. The hard metal composition according to item 122, wherein the nitride comprises at least one of TiN, ZrN, HfN, VN, NbN, and TaN. 124. The hard metal composition according to item 122, wherein the first material further includes a carbide.

125. 如第124項所述之硬金屬組合物，其中該碳化物包括至少 TiC、ZrC、HfC、VC、NbC、TaC、Cr2C3、Mo2C 籲及WC其中之一。 126. 如第125項所述之硬金屬組合物，其中該氮化物包括至少TiN、ZrN、HfN、VN、NbN及 TaN其中之一。 127·如第20項所述之硬金屬組合物，其中該第一材料包括一硼化物。 128.如第127項所述之硬金屬組合物，其中該硼化物為 TiB2，ZrB2、HfB2、TaB2、VB2、MoB2、WB 及 W2B 其中之一。 23125. The hard metal composition according to item 124, wherein the carbide includes at least one of TiC, ZrC, HfC, VC, NbC, TaC, Cr2C3, Mo2C, and WC. 126. The hard metal composition according to item 125, wherein the nitride comprises at least one of TiN, ZrN, HfN, VN, NbN, and TaN. 127. The hard metal composition according to item 20, wherein the first material includes a boride. 128. The hard metal composition according to item 127, wherein the boride is one of TiB2, ZrB2, HfB2, TaB2, VB2, MoB2, WB, and W2B. twenty three

1057D—6939—PF ,200535255 129. 如第20項所述之硬金屬組合物，其中該第一材料包括一碎化物。 130. 如第129項所述之硬金屬組合物，其中該矽化物為 TaSi、Wsi2 ' NbSi2 及 MoSi2 其中之一。 131·如第20項所述之硬金屬組合物，其中該第一材料包括一碳化物。1057D-6939-PF, 200535255 129. The hard metal composition as described in item 20, wherein the first material includes a crushed material. 130. The hard metal composition according to item 129, wherein the silicide is one of TaSi, Wsi2'NbSi2, and MoSi2. 131. The hard metal composition according to item 20, wherein the first material includes a carbide.

132. 如第131項所述之硬金屬組合物，其中該碳化物包括至少 TiC、ZrC、HfC、VC、NbC、TaC、Cr2C3、Mo2C • 及we其中之一。 133. 如第20項所述之硬金屬組合物，其中該第一材料更進一步包括一氮化物。 134·如第133項所述之硬金屬組合物，其中該氮化物包括至少TiN、ZrN、HfN、VN、NbN及 TaN其中之一。 135·如第133項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物。 136·如第135項所述之硬金屬組合物，其中該碳化物 _ 包括至少 TiC、ZrC、HfC、VC、NbC、TaC、Cr2C3、Mo2C 及we其中之一。 137·如第135項所述之硬金屬組合物，其中該氮化物包括至少TiN、ZrN、HfN、VN、NbN及 TaN其中之一。 13 8.如第21項所述之硬金屬組合物，其中該第一材料包括一碳化物。132. The hard metal composition according to item 131, wherein the carbide includes at least one of TiC, ZrC, HfC, VC, NbC, TaC, Cr2C3, Mo2C, and we. 133. The hard metal composition according to item 20, wherein the first material further comprises a nitride. 134. The hard metal composition according to item 133, wherein the nitride includes at least one of TiN, ZrN, HfN, VN, NbN, and TaN. 135. The hard metal composition according to item 133, wherein the first material further includes a carbide. 136. The hard metal composition according to item 135, wherein the carbide _ includes at least one of TiC, ZrC, HfC, VC, NbC, TaC, Cr2C3, Mo2C, and we. 137. The hard metal composition according to item 135, wherein the nitride includes at least one of TiN, ZrN, HfN, VN, NbN, and TaN. 13 8. The hard metal composition according to item 21, wherein the first material comprises a carbide.

13 9.如第138項所述之硬金屬組合物，其中該碳化物包括至少 TiC、ZrC、HfC、VC、NbC、TaC、Cr2C3、m〇2C 1057D-6939-PF 24 -200535255 及 WC其中之一。 140.如第21項所述之硬金屬組合物，其中該第一材料包括一彌化物。 1 4 1 ·如第1 4 0項所述之硬金屬組合物，其中該侧化物為 TiB2，ZrB2、HfB2、TaB2、VB2、MoB2、WB 及 W2B 其中之一。 142·如第21項所述之硬金屬組合物，其中該第一材料包括一砍化物。 # M3·如第M2項所述之硬金屬組合物，其中該矽化物為 TaSi、Wsi2、NbSi2 及 MoSi2 其中之一。 144·如第21項所述之硬金屬組合物，其中該第一材料包括一氮化物。 145·如第144項所述之硬金屬組合物，其中該氮化物包括至少TiN、ZrN、HfN、VN、NbN及 TaN其中之一。 146.如第144項所述之硬金屬組合物，其中該第一材料更進一步包括一礙化物。 _ 147·如第146項所述之硬金屬組合物，其中該碳化物13 9. The hard metal composition according to item 138, wherein the carbide includes at least TiC, ZrC, HfC, VC, NbC, TaC, Cr2C3, mO2C 1057D-6939-PF 24 -200535255 and WC One. 140. The hard metal composition according to item 21, wherein the first material comprises a dispersant. 1 4 1 The hard metal composition according to item 140, wherein the side compound is one of TiB2, ZrB2, HfB2, TaB2, VB2, MoB2, WB, and W2B. 142. The hard metal composition according to item 21, wherein the first material includes a chopped compound. # M3. The hard metal composition according to item M2, wherein the silicide is one of TaSi, Wsi2, NbSi2, and MoSi2. 144. The hard metal composition according to item 21, wherein the first material includes a nitride. 145. The hard metal composition according to item 144, wherein the nitride includes at least one of TiN, ZrN, HfN, VN, NbN, and TaN. 146. The hard metal composition according to item 144, wherein the first material further includes an interfering compound. _147. The hard metal composition according to item 146, wherein the carbide

包括至少 Tie、ZrC、HfC、VC、NbC、TaC、Cr2C3、Mo2C 及WC其中之一。 148·如第147項所述之硬金屬組合物，其中該氮化物包括至少TiN、ZrN、HfN、VN、NbN及 TaN其中之一。 149·如第22項所述之硬金屬組合物，其中該第一材料包括一硼化物。 1 5 0 ·如第12 7項所述之硬金屬組合物，其中該爛化物 1057D-6939-PF 25 200535255 負為 TiB2，ZrB2、HfB2、TaB2、VB2、MoB2、WB 及 W2B 其中之一。 1 5 1 ·如第22項所述之硬金屬組合物，其中該第一材料包括一砍化物。 1 5 2 ·如第1 5 1項所述之硬金屬組合物，其中該矽化物為 TaSi、Wsi2、NbSi2 及 MoSi2 其中之一。 153.如第22項所述之硬金屬組合物，其中該第一材料包括一碳化物。 φ 1 5 4 ·如第1 5 3項所述之硬金屬組合物，其中該碳化物包括至少 Tie、Zi*C、HfC、VC、NbC、TaC、Cf2c3、Mo2C 及we其中之一。 155.如第20項所述之硬金屬組合物，其中該第一材料更進一步包括一氮化物。 1 5 6 ·如第1 5 5項所述之硬金屬組合物，其中該氮化物包括至少TiN、ZrN、HfN、VN、NbN及 TaN其中之一。 157·如第155項所述之硬金屬組合物，其中該第一材 ® 料更進一步包括一碳化物。 1 5 8 ·如第1 5 7項所述之硬金屬組合物，其中該碳化物Includes at least one of Tie, ZrC, HfC, VC, NbC, TaC, Cr2C3, Mo2C, and WC. 148. The hard metal composition according to item 147, wherein the nitride includes at least one of TiN, ZrN, HfN, VN, NbN, and TaN. 149. The hard metal composition according to item 22, wherein the first material includes a boride. 1 50. The hard metal composition according to item 127, wherein the decay product 1057D-6939-PF 25 200535255 is negatively TiB2, one of ZrB2, HfB2, TaB2, VB2, MoB2, WB, and W2B. 1 5 1 The hard metal composition according to item 22, wherein the first material comprises a chopped compound. 1 5 2 The hard metal composition according to item 151, wherein the silicide is one of TaSi, Wsi2, NbSi2, and MoSi2. 153. The hard metal composition according to item 22, wherein the first material includes a carbide. φ 1 5 4 The hard metal composition according to item 153, wherein the carbide includes at least one of Tie, Zi * C, HfC, VC, NbC, TaC, Cf2c3, Mo2C, and we. 155. The hard metal composition according to item 20, wherein the first material further comprises a nitride. 1 56. The hard metal composition according to item 155, wherein the nitride includes at least one of TiN, ZrN, HfN, VN, NbN, and TaN. 157. The hard metal composition according to item 155, wherein the first material ® further comprises a carbide. 1 5 8 · The hard metal composition according to item 1 5 7, wherein the carbide

包括至少 Tie、ZrC、HfC、VC、NbC、TaC、Cr2C3、Mo2C 及we其中之一。 159.如第157項所述之硬金屬組合物，其中該氮化物包括至少TiN、ZrN、HfN、VN、NbN及 TaN其中之一。 1 60·如第24項所述之硬金屬組合物，其中該第一材料更進一步包括一氮化物。 1057D-6939-PF 26 200535255 裊 1 6 1 ·如第1 60項所述之硬金屬組合物，其中該氮化物包括至少TiN、ZrN、HfN、VN、NbN及TaN其中之一。 1 62·如第24項所述之硬金屬組合物，其中該黏結劑基質更進一步包括Co。 163 ·如第24項所述之硬金屬組合物，其中Re約佔該硬金屬組合物總重量的1·5%至24.4%、該鎳基超合金約佔該硬金屬組合物總重量的0.86%至4.88%以及其中包括 TlC的第一材料約佔該硬金屬組合物總重量的3%至14.7 _ %、含TaC的該第一材料約佔該硬金屬組合物總重量的3 %至6.2%而含Wc的該第一材料所佔該硬金屬組合物總重量百分比約高於64%約低於88%。 1 64·如第23項所述之硬金屬組合物，其中該黏結劑基質更進一步包括一鎳基超合金。 1 6 5 ·如弟1 6 4項所述之硬金屬組合物，其中該黏結劑基質更進一步包括Co。 166·如第27項所述之硬金屬組合物，其中該黏結劑 •基質更進-步包括Co。 1 6 7 ·如第2 7項所述之硬金屬組合物，其中約佔該硬金屬組合物總重量的8·8%至23_8%、鎳基超合金約佔該硬金屬組合物總重量的3%至10·3%，且其中M〇2c約佔該硬金屬組合物總重量的13.8%至15.2%，而Tic約佔該硬金屬組合物總重量的59.4%至65.7%。 168·如第47項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物。Include at least one of Tie, ZrC, HfC, VC, NbC, TaC, Cr2C3, Mo2C, and we. 159. The hard metal composition according to item 157, wherein the nitride comprises at least one of TiN, ZrN, HfN, VN, NbN, and TaN. 160. The hard metal composition according to item 24, wherein the first material further comprises a nitride. 1057D-6939-PF 26 200535255 袅 1 6 1 The hard metal composition according to item 160, wherein the nitride includes at least one of TiN, ZrN, HfN, VN, NbN, and TaN. 162. The hard metal composition according to item 24, wherein the binder matrix further comprises Co. 163. The hard metal composition according to item 24, wherein Re accounts for about 1.5% to 24.4% of the total weight of the hard metal composition, and the nickel-based superalloy accounts for about 0.86 of the total weight of the hard metal composition. % To 4.88%, and the first material including TlC accounts for about 3% to 14.7% of the total weight of the hard metal composition, and the first material containing TaC accounts for about 3% to 6.2 of the total weight of the hard metal composition % And the total weight percentage of the hard metal composition of the first material containing Wc is higher than 64% and lower than 88%. 164. The hard metal composition according to item 23, wherein the binder matrix further comprises a nickel-based superalloy. 165. The hard metal composition as described in item 164, wherein the binder matrix further comprises Co. 166. The hard metal composition according to item 27, wherein the bonding agent further comprises -cobalt. 1 6 7 · The hard metal composition according to item 27, wherein about 8.8% to 23-8% of the total weight of the hard metal composition, and nickel-based superalloys account for about 8% of the total weight of the hard metal composition. 3% to 10.3%, and wherein Moc is approximately 13.8% to 15.2% of the total weight of the hard metal composition, and Tic is approximately 59.4% to 65.7% of the total weight of the hard metal composition. 168. The hard metal composition according to item 47, wherein the first material further includes a carbide.

1057D-6939-PF 27 200535255 1 6 9 ·如弟1 6 8項所述之硬金屬組合物，其中該;g炭化物包括至少 Tie、ZrC、HfC、VC、NbC、TaC、Cr2C3、Mo2C 及we其中之一。 170.如第168項所述之硬金屬組合物，其中該氮化物包括至少TiN、ZrN、HfN、VN、NbN及TaN其中之一。 171·如第49項所述之硬金屬組合物，其中該其他元素包括 Cr、Co、Fe、Al、Ti、Mo、W、Nb、Ta、Hf、Zr、B、 C 及 Re。 Φ 172.如第51項所述之硬金屬組合物，其中該第一材料包括一碳化物。 173·如苐172項所述之硬金屬組合物，其中該第一材料更進一步包括一氮化物。 174.如第50項所述之硬金屬組合物，其中該其他元素更進一步包括Fe、Ti、Hf、C及Re。 175·如第51項所述之硬金屬組合物，其中該第一材料包括一氮化物。 _ 1 76 ·如第5 5項所述之硬金屬組合物，其中Re約佔談硬金屬組合物總重量的0.4%至1.8%、該鎳基超合金約佔該硬金屬組合物總重量的2.7%至4·5%、c〇約佔該硬金屬組合物總重量的3 %至4· 8%，以及其中含wc的該第一材料約佔該硬金屬組合物總重量的90.4%至91.5%而Vc約佔該硬金屬組合物總重量的0 · 3 %至〇. 6 %。 177·如第55項所述之硬金屬組合物，其中該第一材料更進一步包括一氮化物。 1057D-6939-PF 28 200535255 17 8.如第55項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物。 179. 如第56項所述之硬金屬組合物，其中該第一材料更進一步包括一氮化物。 180. 如第179項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物 181·如第56項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物。 φ 182.如第5項所述之硬金屬組合物，其中該第一材料更進一步包括一氮化物。 183. 如第182項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物。 184. 如第57項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物。 185. 如第58項所述之硬金屬組合物，其中該第一材料更進一步包括一氮化物。 • 186.如第185項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物。 187.如第58項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物。 18 8.如第59項所述之硬金屬組合物，其中該第一材料更進一步包括一氮化物。 189.如第188項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物。 1057D-6939-PF 29 200535255 190·如第59項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物。 1 9 1 ·如第6 0項所述之硬金屬組合物，其中該第一材料更進一步包括一氮化物。 192·如第191項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物。 193·如第60項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物。 # 194•如第75項所述之硬金屬組合物，其中該第一材料包括一碳化物。 195.如第194項所述之硬金屬組合物，其中該碳化物包括至少 Tie、ZrC、HfC、VC、NbC、TaC、Cr2C3、Mo2C 及we其中之一。 196·如第75項所述之硬金屬組合物，其中該第一材料更進一步包括一氮化物。 197.如第196項所述之硬金屬組合物，其中該氮化物 # 包括至少TiN、ZrN、HfN、VN、NbN及 TaN其中之一。 198·如第196項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物。 199·如第198項所述之硬金屬組合物，其中該第一材料包括WC、Tie、TaC以及Mo2C。 200.如第198項所述之硬金屬組合物，其中該碳化物包括至少 Tie、ZrC、HfC、VC、NbC、TaC、Cr2C3、Mo2C 及WC其中之一。 1057D-6939-PF 30 200535255 % 201. 如第198項所述之硬金屬組合物，其中該氮化物包括至少TiN、ZrN、HfN、VN、NbN及 TaN其中之一。 202. 如第75項所述之硬金屬組合物，其中該第一材料更進一步包括一侧化物。 203. 如第202項所述之硬金屬組合物，其中該第一材料至少包括 TiB〗，ZrB〕、HfB2、TaB〗、VB2、ΜοΒ2、WB 及 W2B其中之一。 204·如第75項所述之硬金屬組合物，其中該第一材 _ 料更進一步包括至少一侧化物及至少一碳化物。 205.如第204項所述之硬金屬組合物，其中該第一材料包括 WC、TiC、TaC 及 B4C。 206·如第75項所述之硬金屬組合物，其中該第一材料包括一碎化物。 2 0 7 ·如第7 5項所述之硬金屬組合物，其中該石夕化物為 TaSi2、WSi2、NbSi2 及 MoSi2 其中之一。 208·如第75項所述之硬金屬組合物，其中Re約佔該 ❿硬金屬組合物總重量的9·04%至9·32%、該鎳基超合金約佔該硬金屬組合物總重量的3 · 5 3 %至3 · 64%，以及其中含 WC的該第一材料約佔該硬金屬組合物總重量的67.24%至 69.40%、TiC約佔該硬金屬組合物總重量的6.35%至6.55 %、TaC約佔該硬金屬組合物總重量的6.24%至6.44%、 TiB2約佔該硬金屬組合物總重量的0.40%至7.39%而B4C 約佔該硬金屬組合物總重量的0.22%至4.25%。 209·如第75項所述之硬金屬組合物，其中Re約佔該 1057D-6939—PF 31 200535255 硬金屬組合物總重量的8.96%至9_3 7%、該鎳基超合金約佔該硬金屬組合物總重量的3·50%至3.66%，以及其中含 WC的該第一材料約佔該硬金屬組合物總重量的5 8·6 1 %至 66.67%、TiC約佔該硬金屬組合物總重量的14·69%至 15.3 7%、TaC約佔該硬金屬組合物總重量的6.19%至6.47 %而M〇2C約佔該硬金屬組合物總重量的〇%至6.1 5%。 210·如第75項所述之硬金屬組合物，其中該黏結劑基質更進一步包括Ni。籲 2 11 ·如第7 5項所述之硬金屬組合物，其中該點結劑基質更進一步包括Fe。 2 12 ·如第7 5項所述之硬金屬組合物，其中該黏結劑基質更進一步包括Mo。 2 13 ·如苐7 5項所述之硬金屬組合物，其中該黏結劑基質更進一步包括Cr。 214·如第83項所述之硬金屬組合物，其中該鎳基超合金係主要包括鎳以及其他元素，上述其他元素包括c〇, _ Cr，Al，Ti，Mo, Nb，W，Zr 與 Re。 215.如弟91項所述之硬金屬組合物，其中該第一材料包括一碳化物。 216·如第215項所述之硬金屬組合物，其中該碳化物包括至少 Tie、ZrC、HfC、VC、NbC、TaC、Cr2C3、Mo2C 及we其中之一。 2 1 7 ·如第9i項所述之硬金屬組合物，其中該第一材料更進一步包括一氮化物。 1057D-6939-PF 32 200535255 % 218.如第217項所述之硬金屬組合物，其中該氮化物包括至少TiN、ZrN、HfN、VN、NbN及 TaN其中之一。 219·如第217項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物。 220·如第219項所述之硬金屬組合物，其中該碳化物包括至少 Tie、ZfC、HfC、VC、NbC、TaC、Cr2C3、Mo2C 及we其中之一。 221.如第91項所述之硬金屬組合物，其中該第一材 φ 料更進一步包括一硼化物。 222·如第221項所述之硬金屬組合物，其中該第一材料至少包括 TiB2, ZrB2、HfB2、TaB2、VB2、M0B2、WB 及 W2B其中之一。 223·如第91項所述之硬金屬組合物，其中該第一材料更進一步包括至少一棚化物及至少一碳化物。 224·如第223項所述之硬金屬組合物，其中該第一材料包括WC、TiC、TaC以及Mo2C。 _ 225·如第91項所述之硬金屬組合物，其中該第一材料包括矽化物。 226·如第225項所述之硬金屬組合物，其中該矽化物至少包括TaSi2、WSi2、NbSi2及MoSi2其中之一。 2 2 7 ·如第91項所述之硬金屬組合物，其中該黏結劑基質更進一步包括Ni。 2 2 8 ·如第91項所述之硬金屬組合物，其中該黏結劑基質更進一步包括Fe。 1057D-6939-PF 33 200535255 鳥 229·如第9 1項所述之硬金屬組合物，其中該黏結劑基質更進一步包括Mo。 23 0.如第91項所述之硬金屬組合物，其中該黏結劑基質更進一步包括Cr。 23 1.如第92項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物。 23：2·如第231項所述之硬金屬組合物，其中該碳化物包括至少 TiC、ZrC、HfC、VC、NbC、TaC、Cr2C3、Mo2C ❿ 及we其中之一。 23 3·如第92項所述之硬金屬組合物，其中該第一材料更進一步包括一氮化物。 234.如第233項所述之硬金屬組合物，其中該氮化物包括至少TiN、ZrN、HfN、VN、NbN及 TaN其中之一。 235·如第233項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物。1057D-6939-PF 27 200535255 1 6 9 · The hard metal composition as described in item 168, wherein the g carbide includes at least Tie, ZrC, HfC, VC, NbC, TaC, Cr2C3, Mo2C and we among them one. 170. The hard metal composition according to item 168, wherein the nitride comprises at least one of TiN, ZrN, HfN, VN, NbN, and TaN. 171. The hard metal composition according to item 49, wherein the other elements include Cr, Co, Fe, Al, Ti, Mo, W, Nb, Ta, Hf, Zr, B, C, and Re. Φ 172. The hard metal composition according to item 51, wherein the first material includes a carbide. 173. The hard metal composition according to item 172, wherein the first material further includes a nitride. 174. The hard metal composition according to item 50, wherein the other elements further include Fe, Ti, Hf, C, and Re. 175. The hard metal composition according to item 51, wherein the first material includes a nitride. _ 1 76. The hard metal composition according to item 55, wherein Re accounts for about 0.4% to 1.8% of the total weight of the hard metal composition, and the nickel-based superalloy accounts for about 2.7% to 4.5%, c0 is about 3% to 4.8% of the total weight of the hard metal composition, and the first material containing wc is about 90.4% to 91.5% and Vc accounted for about 0.3% to 0.6% of the total weight of the hard metal composition. 177. The hard metal composition according to item 55, wherein the first material further comprises a nitride. 1057D-6939-PF 28 200535255 17 8. The hard metal composition according to item 55, wherein the first material further comprises a carbide. 179. The hard metal composition according to item 56, wherein the first material further comprises a nitride. 180. The hard metal composition according to item 179, wherein the first material further comprises a carbide 181. The hard metal composition according to item 56, wherein the first material further comprises a carbide . φ 182. The hard metal composition according to item 5, wherein the first material further includes a nitride. 183. The hard metal composition according to item 182, wherein the first material further comprises a carbide. 184. The hard metal composition according to item 57, wherein the first material further comprises a carbide. 185. The hard metal composition according to item 58, wherein the first material further comprises a nitride. • 186. The hard metal composition according to item 185, wherein the first material further comprises a carbide. 187. The hard metal composition according to item 58, wherein the first material further comprises a carbide. 18 8. The hard metal composition according to item 59, wherein the first material further comprises a nitride. 189. The hard metal composition according to item 188, wherein the first material further comprises a carbide. 1057D-6939-PF 29 200535255 190. The hard metal composition according to item 59, wherein the first material further comprises a carbide. 1 9 1 The hard metal composition according to item 60, wherein the first material further comprises a nitride. 192. The hard metal composition according to item 191, wherein the first material further includes a carbide. 193. The hard metal composition according to item 60, wherein the first material further includes a carbide. # 194 The hard metal composition according to item 75, wherein the first material comprises a carbide. 195. The hard metal composition according to item 194, wherein the carbide includes at least one of Tie, ZrC, HfC, VC, NbC, TaC, Cr2C3, Mo2C, and we. 196. The hard metal composition according to item 75, wherein the first material further comprises a nitride. 197. The hard metal composition according to item 196, wherein the nitride # includes at least one of TiN, ZrN, HfN, VN, NbN, and TaN. 198. The hard metal composition according to item 196, wherein the first material further includes a carbide. 199. The hard metal composition according to item 198, wherein the first material includes WC, Tie, TaC, and Mo2C. 200. The hard metal composition according to item 198, wherein the carbide includes at least one of Tie, ZrC, HfC, VC, NbC, TaC, Cr2C3, Mo2C, and WC. 1057D-6939-PF 30 200535255% 201. The hard metal composition according to item 198, wherein the nitride includes at least one of TiN, ZrN, HfN, VN, NbN, and TaN. 202. The hard metal composition according to item 75, wherein the first material further comprises a flank compound. 203. The hard metal composition according to item 202, wherein the first material includes at least one of TiB, ZrB, HfB2, TaB, VB2, MoB2, WB, and W2B. 204. The hard metal composition according to item 75, wherein the first material further includes at least one side compound and at least one carbide. 205. The hard metal composition according to item 204, wherein the first material includes WC, TiC, TaC, and B4C. 206. The hard metal composition according to item 75, wherein the first material comprises a crushed product. 2 0 7 The hard metal composition according to item 75, wherein the petrified compound is one of TaSi2, WSi2, NbSi2, and MoSi2. 208. The hard metal composition according to item 75, wherein Re accounts for about 9.0% to 9.32% of the total weight of the hard metal composition, and the nickel-based superalloy accounts for about the total weight of the hard metal composition 3.53% to 3.64% by weight, and the first material containing WC accounts for about 67.24% to 69.40% of the total weight of the hard metal composition, and TiC accounts for about 6.35% of the total weight of the hard metal composition % To 6.55%, TaC to approximately 6.24% to 6.44% of the total weight of the hard metal composition, TiB2 to approximately 0.40% to 7.39% of the total weight of the hard metal composition, and B4C to approximately the total weight of the hard metal composition 0.22% to 4.25%. 209. The hard metal composition according to item 75, wherein Re accounts for approximately 8.96% to 9_3 7% of the total weight of the 1057D-6939-PF 31 200535255 hard metal composition, and the nickel-based superalloy accounts for approximately the hard metal 3.50% to 3.66% of the total weight of the composition, and the first material containing WC accounts for about 58.8% to 66.67% of the total weight of the hard metal composition, and TiC accounts for about the hard metal composition The total weight is 14.69% to 15.37%, TaC accounts for approximately 6.19% to 6.47% of the total weight of the hard metal composition, and MoC is approximately 0% to 6.15% for the total weight of the hard metal composition. 210. The hard metal composition according to item 75, wherein the binder matrix further comprises Ni. Call 2 11 The hard metal composition according to item 75, wherein the sintering agent matrix further comprises Fe. 2 12 The hard metal composition according to item 75, wherein the binder matrix further comprises Mo. 2 13 The hard metal composition according to item 7.5, wherein the binder matrix further comprises Cr. 214. The hard metal composition according to item 83, wherein the nickel-based superalloy mainly includes nickel and other elements, and the other elements include c0, _Cr, Al, Ti, Mo, Nb, W, Zr and Re. 215. The hard metal composition according to item 91, wherein the first material includes a carbide. 216. The hard metal composition according to item 215, wherein the carbide includes at least one of Tie, ZrC, HfC, VC, NbC, TaC, Cr2C3, Mo2C, and we. 2 1 7 The hard metal composition according to item 9i, wherein the first material further comprises a nitride. 1057D-6939-PF 32 200535255% 218. The hard metal composition according to item 217, wherein the nitride comprises at least one of TiN, ZrN, HfN, VN, NbN, and TaN. 219. The hard metal composition according to item 217, wherein the first material further includes a carbide. 220. The hard metal composition according to item 219, wherein the carbide includes at least one of Tie, ZfC, HfC, VC, NbC, TaC, Cr2C3, Mo2C, and we. 221. The hard metal composition according to item 91, wherein the first material φ further comprises a boride. 222. The hard metal composition according to item 221, wherein the first material includes at least one of TiB2, ZrB2, HfB2, TaB2, VB2, MOB2, WB, and W2B. 223. The hard metal composition according to item 91, wherein the first material further includes at least one sintered compound and at least one carbide. 224. The hard metal composition according to item 223, wherein the first material includes WC, TiC, TaC, and Mo2C. _225. The hard metal composition according to item 91, wherein the first material comprises a silicide. 226. The hard metal composition according to item 225, wherein the silicide includes at least one of TaSi2, WSi2, NbSi2, and MoSi2. 2 2 7 The hard metal composition according to item 91, wherein the binder matrix further comprises Ni. 2 2 8 The hard metal composition according to item 91, wherein the binder matrix further comprises Fe. 1057D-6939-PF 33 200535255 Bird 229. The hard metal composition according to item 91, wherein the binder matrix further comprises Mo. 23 0. The hard metal composition according to item 91, wherein the binder matrix further comprises Cr. 23 1. The hard metal composition according to item 92, wherein the first material further comprises a carbide. 23: 2. The hard metal composition according to item 231, wherein the carbide includes at least one of TiC, ZrC, HfC, VC, NbC, TaC, Cr2C3, Mo2C❿, and we. 23 3. The hard metal composition according to item 92, wherein the first material further comprises a nitride. 234. The hard metal composition according to item 233, wherein the nitride comprises at least one of TiN, ZrN, HfN, VN, NbN, and TaN. 235. The hard metal composition according to item 233, wherein the first material further includes a carbide.

2 3 6 ·如第2 3 5項所述之硬金屬組合物，其中該碳化物 # 包括至少 TiC、ZrC、HfC、VC、NbC、TaC、Cr2C3、Mo2C 及WC其中之一。 237·如第235項所述之硬金屬組合物，其中該氮化物包括至少TiN、ZrN、HfN、VN、NbN及 TaN其中之一。 23 8·如第92項所述之硬金屬組合物，其中該第一材料更進一步包括一硼化物。 239·如第238項所述之硬金屬組合物，其中該第一材料包括至少 TiB2，ZrB2、HfB〗、TaB2、VB〗、M0B2、WB 及 1057D-6939-PF 34 200535255 螓 w2B其中之一。 24〇·如第92項所述之硬金屬組合物，其中該第一材料包括一矽化物。 241.如第92項所述之硬金屬組合物，其中該第一材料包括至少TaSi、Wsi2、NbSi2及MoSi2其中之一。 2 42 ·如第92項所述之硬金屬組合物，其中該第二材料更進一步包括至少Re、Ni、Co、Fe、Mo及Cr其中之一。 243.如第92項所述之硬金屬組合物，其中該第二材 • 料更進一步包括至少另一種不同的鎳基超合金。 244·如第92項所述之硬金屬組合物，其中含wc的 5亥第一材料約佔該硬金屬組合物總重量的9 1.9 %至9 2.5 %、VC約佔該硬金屬組合物總重量的〇·3 %至〇·6%，以及其中該鎳基超合金約佔該硬金屬組合物總重量的人2%至 7.5%。 245·如第92項所述之硬金屬組合物，其中含Tic及 Mc^C的該第一材料分別約佔該硬金屬組合物總重量的 _ 69.44%及16·〇9%，以及其中該鎳基超合金約佔該硬金屬組合物總重量的7.2%至7.5%。 246·如第93項所述之硬金屬組合物，其中該第一材料包括一碳化物。2 3 6 The hard metal composition according to item 2 35, wherein the carbide # includes at least one of TiC, ZrC, HfC, VC, NbC, TaC, Cr2C3, Mo2C, and WC. 237. The hard metal composition according to item 235, wherein the nitride includes at least one of TiN, ZrN, HfN, VN, NbN, and TaN. 23 8. The hard metal composition according to item 92, wherein the first material further comprises a boride. 239. The hard metal composition according to item 238, wherein the first material includes at least one of TiB2, ZrB2, HfB, TaB2, VB, M0B2, WB, and 1057D-6939-PF 34 200535255 螓 w2B. 24. The hard metal composition according to item 92, wherein the first material includes a silicide. 241. The hard metal composition according to item 92, wherein the first material includes at least one of TaSi, Wsi2, NbSi2, and MoSi2. 2 42. The hard metal composition according to item 92, wherein the second material further includes at least one of Re, Ni, Co, Fe, Mo, and Cr. 243. The hard metal composition according to item 92, wherein the second material further comprises at least one different nickel-based superalloy. 244. The hard metal composition according to item 92, wherein the first material containing wc contains about 91.9% to 92.5% of the total weight of the hard metal composition, and VC accounts for about the total weight of the hard metal composition. 0.3% to 0.6% by weight, and wherein the nickel-based superalloy accounts for approximately 2% to 7.5% of the total weight of the hard metal composition. 245. The hard metal composition according to item 92, wherein the first material containing Tic and Mc ^ C respectively accounts for about 69.44% and 16.09% of the total weight of the hard metal composition, and wherein The nickel-based superalloy accounts for approximately 7.2% to 7.5% of the total weight of the hard metal composition. 246. The hard metal composition according to item 93, wherein the first material includes a carbide.

247·如第246項所述之硬金屬組合物，其中該碳化物包括至少 TiC、ZrC、HfC、VC、NbC、TaC、Cr2C3、Mo2C 及wc其中之一。 2 4 8 ·如第9 3項所述之硬金屬組合物，其中該第一材 1057D-6939-PF 35 200535255 碡料包括一氮化物。 249·如第248項所述之硬金屬組合物，其中該氮化物包括至少TiN、ZrN、HfN、VN、NbN及 TaN其中之—。 250·如第249項所述之硬金屬組合物，其中該第一材料更進一步包括一碳化物。247. The hard metal composition according to item 246, wherein the carbide includes at least one of TiC, ZrC, HfC, VC, NbC, TaC, Cr2C3, Mo2C, and wc. 2 4 8 The hard metal composition according to item 93, wherein the first material 1057D-6939-PF 35 200535255 is a nitride. 249. The hard metal composition according to item 248, wherein the nitride includes at least one of TiN, ZrN, HfN, VN, NbN, and TaN. 250. The hard metal composition according to item 249, wherein the first material further includes a carbide.

251.如第250項所述之硬金屬組合物，其中該碳化物包括至少 Tie、ZrC、HfC、VC、NbC、TaC、Cr2C3、Mo2C 及we其中之一。 φ 252·如第25〇項所述之硬金屬組合物，其中該氮化物包括至少TiN、ZrN、HfN、VN、NbN及 TaN其中之一。 253·如第93項所述之硬金屬組合物，其中該第一材料更進一步包括一硼化物。 254.如第253項所述之硬金屬組合物，其中該第一材料包括至少 TiB2, ZrB2、HfB2、TaB2、VB2、MoB2、WB 及 w2b其中之一。 255·如第93項所述之硬金屬組合物，其中該第一材 Φ 料更進一步包括一矽化物。 256·如第93項所述之硬金屬組合物，其中該第一材料包括至少TaSi、Wsi2、NbSi2及MoSi2其中之一。 25 7.如第93項所述之硬金屬組合物，其中該第二材料更進一步包括至少Re、Ni、Co、Fe、Mo及Cr其中之一。 25 8·如第93項所述之硬金屬組合物，其中該第二材料更進一步包括至少另一種不同的鎳基超合金。 259·如第93項所述之硬金屬組合物，其中該鎳基超 1057D-6939-PF 36 .200535255 合金的其他元素更進_步括 Fe、丁a、Hf、B 及厂。 260. —種硬全属鈿 η 屬合物的製造方法，包括·㈣一八屬表面，接著進行一埶喷冷預備孟 Μ ^ ^ # , 、、土氣程將一層硬金屬層塗佈在全屬表面上，其中該硬金屬層包括： ^在金以及具有與第-材料不同之第-材料之的硬粒子’ (binder matrix);其中，弟―材料之—黏結劑基質 μ弟一材料係佔該硬全屬έ日人减體積的3〜40〇/〇 ; 1中，钤私义硬金屬組合物總 ^ φ “點結劑基質包括鍊（Re)元辛，銖兀素係佔該硬金屬組合物绱 ”且勿〜重1的2 5 %以上；苴中，μ 述硬粒子係以實質w的方式散料該黏結劑基質中。紙一種硬金屬組合物的製造方法，包括··預屬表面，接著進行一熱嘴塗f „ 貝土 I耘將一層硬金屬層塗佈在金屬表面々，其中該硬金屬層包括：具有第一材料的硬粒子，其中該第-材料具有至少一下列混合物：⑴wc，Tic與 TaC的混合物’（2)wc，Tic與Nbc的混合物，（3)wc，Tic 與至少TaC與NbC中之一的混合物，（4)wc，Tic與至少 HfC與NbC中之一的混合物；以及具有與第一材料不同之第一材料之一黏結劑基質（binder matrix);其中，該第二材料係佔該硬金屬組合物總體積的3〜40% ;其中，該黏結劑基質包括銖（Re)元素；其中，上述硬粒子係以實質均勻的方式散佈於該黏結劑基質中。 262· —種硬金屬組合物的製造方法，包括：預備一金屬表面，接著進行一熱喷塗製程將一層硬金屬層塗佈在金屬表面上，其中該硬金屬層包括：具有第一材料的硬粒子具有Mo2C及TiC的混和物；以及具有與第一材料不同之 1057D-6939-PF 37 .200535255 第一材料之一黏結劑基質（binder matrix);其中， μ 一 ^ 口义丨丨圓___ 料係佔該硬金屬組合物總體積的3〜40% ; 1中 ^ ，、r，该黏結劑土貝包括鍊（Re)元素；其中，上述硬粒子係以徐、々只貝均勻的方式散佈於該黏結劑基質中。 263· —種硬金屬組合物的製造方法，預備一金屬表面，接著進行一熱喷塗製程將一層硬金屬嘈堂佈在金251. The hard metal composition according to item 250, wherein the carbide includes at least one of Tie, ZrC, HfC, VC, NbC, TaC, Cr2C3, Mo2C, and we. φ 252. The hard metal composition according to item 25, wherein the nitride includes at least one of TiN, ZrN, HfN, VN, NbN, and TaN. 253. The hard metal composition according to item 93, wherein the first material further comprises a boride. 254. The hard metal composition according to item 253, wherein the first material includes at least one of TiB2, ZrB2, HfB2, TaB2, VB2, MoB2, WB, and w2b. 255. The hard metal composition according to item 93, wherein the first material Φ further comprises a silicide. 256. The hard metal composition according to item 93, wherein the first material includes at least one of TaSi, Wsi2, NbSi2, and MoSi2. 25 7. The hard metal composition according to item 93, wherein the second material further comprises at least one of Re, Ni, Co, Fe, Mo, and Cr. 25 8. The hard metal composition according to item 93, wherein the second material further includes at least another different nickel-based superalloy. 259. The hard metal composition according to item 93, wherein the other elements of the nickel-based super 1057D-6939-PF 36 .200535255 alloy further include Fe, D-a, Hf, B, and iron. 260. — A method for manufacturing a hard genus 钿 η genus compound, including: 属 18 genus surface, and then a cold spray preparation M ^ ^ #, a rustic process of coating a hard metal layer on the whole On the surface, the hard metal layer includes: ^ in gold and a binder matrix having a first material that is different from the first material; (wherein the material-the binder matrix-the material system) It accounts for 3 ~ 40 00 / 〇 of the total weight reduction of the hard people. In 1, the total weight of the private hard metal composition ^ φ "The junction agent matrix includes the chain (Re) element, and the element Hard metal composition 绱 "and not more than 25% by weight; in 苴, said hard particles are dispersed in the binder matrix in a substantially w manner. A method for manufacturing a hard metal composition of paper, including: pre-forming the surface, and then performing a hot nozzle coating f „Betu Iyun applies a hard metal layer on the metal surface, wherein the hard metal layer includes: Hard particles of a material, wherein the first material has at least one of the following mixtures: ⑴wc, a mixture of Tic and TaC '(2) wc, a mixture of Tic and Nbc, (3) wc, Tic and at least one of TaC and NbC A mixture of (4) wc, Tic and at least one of HfC and NbC; and a binder matrix having one of the first materials different from the first material; wherein the second material accounts for the 3 ~ 40% of the total volume of the hard metal composition; wherein the adhesive matrix includes Ba (Re) element; wherein the hard particles are dispersed in the adhesive matrix in a substantially uniform manner. 262 · — Hard metal The manufacturing method of the composition includes: preparing a metal surface, and then performing a thermal spraying process to coat a hard metal layer on the metal surface, wherein the hard metal layer includes: hard particles having a first material having Mo2C and TiC Mixed 1057D-6939-PF 37 which is different from the first material; and a binder matrix, which is one of the first materials; where μ ^ 口义丨丨 round ___ material accounts for the hard metal combination 3 ~ 40% of the total volume of the material; 1 ^ ,, r, the binder earth shell includes the chain (Re) element; wherein the hard particles are dispersed in the matrix of the binder in a uniform manner by Xu and Gong shellfish 263 · —A method for manufacturing a hard metal composition, preparing a metal surface, and then performing a thermal spraying process to spread a layer of hard metal in gold

屬表面上，其中該硬金屬層包括：具有第一材料的硬粒· 以及具有與第_材料不同之第二材料之一黏結劑立基子質 (bmder matrix)，該第二材料係包括一鎳基超合金·其中貝上述硬粒子係以實質均勻的方式散佈於該黏結劑基質中。 264· —種硬金屬組合物的製造方法，包 •損備一金屬表面，接著進行一熱喷塗製程將一層硬金屬層塗佈在金屬表面上’其中該硬金屬層包括：具有第一材料的硬粒子包括，其中該第一材料具有TiC與TiN ;以及具有與第一材料不同之第二材料之-黏結劑基質(binder matrix)，該第 -材料^括至少Ni，M。與Μ。，之一；其中，上述硬粒子係以貝貝均勻的方式散佈於該黏結劑基質中。 265· 一種硬金屬組合物的製造方法，包括：預備一金屬表面’接著進行-熱喷塗製程將〆層硬金屬層塗佈在金屬表面上，其中該硬金屬層包括：具有第一材料的硬粒子包括，其中該第一絲社何枓具有至少一下列混合物：（1)wc Tir 與TaC的混合物，· ? I )WC，TiC 與 NbC 的混合物，（3)wc TiC 與至少TaC與Nbr击> ， DL中之一的混合物，（4)WC，TiC盥至少 HfC 與 NbC 中之 _ ^ 勺混合物；以及具有與第一材料不同之On the surface, the hard metal layer includes: hard particles having a first material and a binder matrix having a second material different from the first material, the second material system including a nickel Superalloy-based hard particles are dispersed in the binder matrix in a substantially uniform manner. 264 · —A method for manufacturing a hard metal composition, comprising: preparing a metal surface, and then performing a thermal spraying process to apply a hard metal layer on the metal surface, wherein the hard metal layer includes: a first material The hard particles include, wherein the first material has TiC and TiN; and a binder matrix having a second material different from the first material, the first material including at least Ni, M. With M. , One; wherein the hard particles are dispersed in the adhesive matrix in a uniform manner. 265. A method for manufacturing a hard metal composition, including: preparing a metal surface and then performing a thermal spraying process to coat a hard metal layer on the metal surface, wherein the hard metal layer includes: a first material The hard particles include, wherein the first silk company has a mixture of at least one of the following: (1) a mixture of wc Tir and TaC, · 1) WC, a mixture of TiC and NbC, and (3) wc TiC and at least TaC and Nbr Click >, a mixture of one of DL, (4) WC, TiC, at least a mixture of HfC and NbC, and a material different from the first material

1057D-6939-PF 38 .200535255 弟二材料之一黏結劑基質（binder matrix);其中，該第二材料係佔該硬金屬組合物總體積的3〜40% ;其中，該黏結劑基貝包括鍊（Re)元素，其中’上述硬粒子係以實質均勻的方式散佈於該黏結劑基質中。此外，本應用中第二類288項實施方法敘述如下 1 · 一種硬金屬組合物包括：其中硬粒子包括至少一種碳化物，該碳化物擇自由至少WC、TiC及HfC其中之一；以及一包括Re且用來黏結硬粒子的黏結劑基質，其中該硬 ® 粒子低於該硬金屬組合物總重量的75%，而Re高於該硬金屬組合物總重量的2 5 %。 2·如第1項所述之硬金屬組合物，其中該碳化物為 TiC且高於約該硬金屬組合物總重量的26%，而低於約該硬金屬組合物總重量的74%。 3 ·如第1項所述之硬金屬組合物，其中該碳化物為 WC且高於約該硬金屬組合物總重量的53%，而低於約 ^ 該硬金屬組合物總重量的47%。 4·如第1項所述之硬金屬組合物，其中該碳化物為 HfC且高於約該硬金屬組合物總重量的48%，而低於約該硬金屬組合物總重量的52%。 5 · —種硬金屬組合物包括：包括至少一種碳化物的硬粒子’其中該碳化物擇自由元素週期表中IVb、Vb及VIb 方矢元素所形成的碳化物’不包括WC、Tic及HfC ;以及一黏結硬粒子的黏結劑基質包括Re，其中該硬粒子低於該硬金屬組合物總重量的75%，而Re佔該硬金屬組合物總重 1057D-6939-PF 39 :200535255 量的4%至72%。 6·如第5項所述之硬金屬組合物，其中該碳化物為 ZrC且高於約該硬金屬組合物總重量的3 2%，而Re低於約該硬金屬組合物總重量的6 8 %。 7 ·如第5項所述之硬金屬組合物，其中該碳化物為 VC且咼於約該硬金屬組合物總重量的28%，而Re低於約該硬金屬組合物總重量的72%。 8 ·如第5項所述之硬金屬組合物，其中該碳化物為 NbC且高於約該硬金屬組合物總重量的3，而低於約該硬金屬組合物總重量的64%。 9 ·如第5項所述之硬金屬組合物，其中該碳化物為 TaC且高於約該硬金屬組合物總重量的5丨％，而低於約該硬金屬組合物總重量的49%。1057D-6939-PF 38 .200535255 A binder matrix of one of the second materials; wherein the second material accounts for 3 to 40% of the total volume of the hard metal composition; wherein the binder base comprises Chain (Re) element, in which the above-mentioned hard particles are dispersed in the binder matrix in a substantially uniform manner. In addition, the second type of 288 implementation methods in this application are described as follows: 1. A hard metal composition includes: wherein the hard particles include at least one carbide, and the carbide is selected from at least one of WC, TiC, and HfC; and Re and a binder matrix for bonding hard particles, where the hard® particles are less than 75% of the total weight of the hard metal composition and Re is greater than 25% of the total weight of the hard metal composition. 2. The hard metal composition according to item 1, wherein the carbide is TiC and is greater than about 26% of the total weight of the hard metal composition and less than about 74% of the total weight of the hard metal composition. 3. The hard metal composition according to item 1, wherein the carbide is WC and is higher than about 53% of the total weight of the hard metal composition, and less than about 47% of the total weight of the hard metal composition . 4. The hard metal composition according to item 1, wherein the carbide is HfC and is higher than about 48% of the total weight of the hard metal composition and lower than about 52% of the total weight of the hard metal composition. 5 · A hard metal composition includes: hard particles including at least one carbide 'where the carbide is selected from the carbides formed by IVb, Vb, and VIb square elements in the periodic table of elements' excluding WC, Tic, and HfC And an adhesive matrix that binds hard particles includes Re, wherein the hard particles are less than 75% of the total weight of the hard metal composition, and Re accounts for 1057D-6939-PF 39: 200535255 in the total weight of the hard metal composition. 4% to 72%. 6. The hard metal composition according to item 5, wherein the carbide is ZrC and is higher than about 32% of the total weight of the hard metal composition, and Re is less than about 6 of the total weight of the hard metal composition. 8 %. 7. The hard metal composition according to item 5, wherein the carbide is VC and is less than about 28% of the total weight of the hard metal composition, and Re is less than about 72% of the total weight of the hard metal composition . 8. The hard metal composition according to item 5, wherein the carbide is NbC and is higher than about 3 and about 64% of the total weight of the hard metal composition. 9. The hard metal composition according to item 5, wherein the carbide is TaC and is higher than about 5% of the total weight of the hard metal composition, and less than about 49% of the total weight of the hard metal composition. .

1 〇·如第5項所述之硬金屬組合物，其中該碳化物為 ChC3且高於約該硬金屬組合物總重量的，而以低於約該硬金屬組合物總重量的68%。 11.如第5項所述之硬金屬組合物，其中該碳化物為且高於約該硬金屬組合物總重量的％%，而以低於約該硬金屬組合物總重量的6丨％。 ,· -種硬金屬組合物包括：包括至少一種氮化物的硬粒子’ S中該氮化物擇自由元素週期表中IVb及Vb族 :素所形成的氮化物；以及以及一黏結硬粒子的黏結劑基質包括Re，其中Re約佔該硬金屬組合物總重量的4%至10. The hard metal composition according to item 5, wherein the carbide is ChC3 and is higher than about the total weight of the hard metal composition, and is less than about 68% of the total weight of the hard metal composition. 11. The hard metal composition according to item 5, wherein the carbide is at and above about %% of the total weight of the hard metal composition, and at less than about 6% by weight of the total weight of the hard metal composition. . A hard metal composition includes: hard particles including at least one nitride; the nitride is selected from the group consisting of elements IVb and Vb in the periodic table: element nitrides; and a cohesive bond of hard particles The agent matrix includes Re, wherein Re constitutes about 4% to about 5% by weight of the total weight of the hard metal composition.

72%。 1057D-6939-PF 40 •200535255 鼇 1 3 ·如第12項所述之硬金屬組合物，其中該氮化物為 ZrN且约佔該硬金屬組合物總重量的28%至89%。 14·如第12項所述之硬金屬組合物，其中該氮化物為 ZrN且約佔該硬金屬組合物總重量的34%至92%，而Re 約佔該硬金屬組合物總重量的8%至66%。 1 5 ·如第12項所述之硬金屬纟且合物，其中該氮化物為 HfN且約佔該硬金屬組合物總重量的5〇%至96%，而Re 約佔該硬金屬組合物總重量的4%至5〇%。鲁 16·如第12項所述之硬金屬組合物，其中該氮化物為 VN且約佔該硬金屬組合物總重量的3〇%至91%，而以約佔該硬金屬組合物總重量的9 %至7 〇 %。 17·如第12項所述之硬金屬組合物，其中該氮化物為 NbN且約佔該硬金屬組合物總重量的34%至92%，而^ 約佔該硬金屬組合物總重量的8%至66%。 18. 如第12項所述之硬金屬組合物，其中該氮化物為 • TaN且約佔該硬金屬組合物總重量的51%至96%，而Re 約伯該硬金屬組合物總重量的4%至49%。 19. -種硬金屬組合物包括：包括至少一種氮化物的硬粒子’其中該氮化物擇自由元素週期表中⑽及”族几素所形成#氮化物；以&一黏結硬粒子的黏結劑基質包括鎳基超合金，其中該鎳基超合金約佔該硬金屬組合物總重量的1.7%至50%。 " 20. 如第19項所述之硬金屬組合物，其中該氮化物為 TiN且約佔該硬金屬組合物總重量的5〇%至％%，而該鎳72%. 1057D-6939-PF 40 • 200535255 Ao 1 3 • The hard metal composition according to item 12, wherein the nitride is ZrN and accounts for about 28% to 89% of the total weight of the hard metal composition. 14. The hard metal composition according to item 12, wherein the nitride is ZrN and accounts for about 34% to 92% of the total weight of the hard metal composition, and Re accounts for about 8% of the total weight of the hard metal composition. % To 66%. 1 5. The hard metal complex according to item 12, wherein the nitride is HfN and accounts for about 50% to 96% of the total weight of the hard metal composition, and Re accounts for about the hard metal composition. 4% to 50% of the total weight. Lu 16. The hard metal composition according to item 12, wherein the nitride is VN and accounts for about 30% to 91% of the total weight of the hard metal composition, and accounts for about the total weight of the hard metal composition. 9% to 70%. 17. The hard metal composition according to item 12, wherein the nitride is NbN and accounts for about 34% to 92% of the total weight of the hard metal composition, and ^ accounts for about 8% of the total weight of the hard metal composition. % To 66%. 18. The hard metal composition according to item 12, wherein the nitride is • TaN and accounts for about 51% to 96% of the total weight of the hard metal composition, and Re Job is based on the total weight of the hard metal composition. 4% to 49%. 19. A hard metal composition comprising: hard particles including at least one nitride 'wherein the nitride is selected from the group consisting of ⑽ and "groups of nitrides in the periodic table of the elements" and a bond of & a bonded hard particle The agent matrix includes a nickel-based superalloy, wherein the nickel-based superalloy accounts for about 1.7% to 50% of the total weight of the hard metal composition. &Quot; 20. The hard metal composition according to item 19, wherein the nitride Is TiN and accounts for about 50% to %% of the total weight of the hard metal composition, and the nickel

1057 D-6 93 9-PF 41 :200535255 基超合金約佔該硬金屬組合物總重量的4%至50%。 2 1 ·如第1 9項所述之硬金屬組合物，其中該氮化物為 ZrN且約佔該硬金屬組合物總重量的58%至97%，而該鎳基超合金約佔該硬金屬組合物總重量的3 %至42%。 22.如第19項所述之硬金屬組合物，其中該氮化物為 HfN且約佔該硬金屬組合物總重量的72%至98.2%，而該鎳基超合金約佔該硬金屬組合物總重量的1.8%至28%。 23 ·如第1 9項所述之硬金屬組合物，其中該氮化物為 VN且約佔該硬金屬組合物總重量的53%至96%，而該鎳基超合金約佔該硬金屬組合物總重量的4%至47%。 2 4 ·如弟1 9項所述之硬金屬組合物，其中該氮化物為 NbN且約佔該硬金屬組合物總重量的52%至97%，而該鎳基超合金約佔該硬金屬組合物總重量的3%至42%。 25.如第19項所述之硬金屬組合物，其中該氮化物為 TaN且約佔該硬金屬組合物總重量的73%至98·3%，而該 _ 鎳基超合金約佔該硬金屬組合物總重量的1 · 7 %至2 7 %。 26· —種硬金屬組合物包括：包括至少一種碳化物的硬粒子，其中該碳化物擇自由元素週期表中Ivb、vb及v比族元素所形成的碳化物；以及一黏結硬粒子的黏結劑基質包括Re及鎳基超合金，其中該硬粒子約佔該硬金屬組合物總重量的26.1%至98.4%。 27·如第26項所述之硬金屬組合物，其中該碳化物為 Tic且約佔該硬金屬組合物總重量的261%至95·ι%，心不超過約該硬金屬組合物總重量的73·6%而該鎳基超合^ 1057D-6939-PF 42 200535255 不超過約該硬金屬組合物總重量的5 1.1 %。 28 ·如第26項所述之硬金屬組合物，其中該碳化物為 ZrC且約佔該硬金屬組合物總重量的32%至96%，Re不超過約該硬金屬組合物總重量的67.7%而該鎳基超合金不超過約該硬金屬組合物總重量的44.1 %。 2 9 ·如第2 6項所述之硬金屬組合物，其中該碳化物為 HfC且約佔該硬金屬組合物總重量的47· 7%至98· 1 %，Re 不超過約該硬金屬組合物總重量的52.1%而該鎳基超合金 ® 不超過約該硬金屬組合物總重量的29.2%。 3 0 ·如第2 6項所述之硬金屬組合物，其中該碳化物為 VC且約佔該硬金屬組合物總重量的28.3%至95.6%，Re 不超過約該硬金屬組合物總重量的71.5%而該鎳基超合金不超過約該硬金屬組合物總重量的4 8.4 %。 3 1 ·如第26項所述之硬金屬組合物，其中該碳化物為 NbC且約佔該硬金屬組合物總重量的36%至96 9%，Re φ 等於或低於約該硬金屬組合物總重量的63.8%而該鎳基超合金等於或低於約該硬金屬組合物總重量的39 9%。 32·如第26項所述之硬金屬組合物，其中該碳化物為 TaC且約佔該硬金屬組合物總重量的51%至98 3%，以等於或低於約該硬金屬組合物總重量的48·8%而該錄美赶合金等於或低於約該硬金屬組合物總重量的2 6 5 %。 33·如第26項所述之硬金屬組合物，其中該碳化物為 ChC3且約佔該硬金屬組合物總重量的32.4%至96 4%1057 D-6 93 9-PF 41: 200535255 based super alloy accounts for about 4% to 50% of the total weight of the hard metal composition. 2 1 · The hard metal composition according to item 19, wherein the nitride is ZrN and accounts for about 58% to 97% of the total weight of the hard metal composition, and the nickel-based superalloy accounts for about the hard metal 3% to 42% of the total weight of the composition. 22. The hard metal composition according to item 19, wherein the nitride is HfN and accounts for about 72% to 98.2% of the total weight of the hard metal composition, and the nickel-based superalloy accounts for about the hard metal composition 1.8% to 28% of the total weight. 23. The hard metal composition according to item 19, wherein the nitride is VN and accounts for about 53% to 96% of the total weight of the hard metal composition, and the nickel-based superalloy accounts for about the hard metal combination 4% to 47% of the total weight. 24. The hard metal composition according to item 19, wherein the nitride is NbN and accounts for about 52% to 97% of the total weight of the hard metal composition, and the nickel-based superalloy accounts for about the hard metal 3% to 42% of the total weight of the composition. 25. The hard metal composition according to item 19, wherein the nitride is TaN and accounts for approximately 73% to 98.3% of the total weight of the hard metal composition, and the nickel-based superalloy accounts for approximately the hard 1.7 to 27% of the total weight of the metal composition. 26 · A kind of hard metal composition includes: hard particles including at least one kind of carbide, wherein the carbide is selected from carbides formed by Ivb, vb, and v group elements in the periodic table of elements; and a cohesive bond of hard particles The agent matrix includes Re and nickel-based superalloys, wherein the hard particles account for about 26.1% to 98.4% of the total weight of the hard metal composition. 27. The hard metal composition according to item 26, wherein the carbide is Tic and accounts for about 261% to 95% by weight of the total weight of the hard metal composition, and does not exceed about the total weight of the hard metal composition 73.6% of the nickel-based super-alloy 1057D-6939-PF 42 200535255 does not exceed about 5 1.1% of the total weight of the hard metal composition. 28. The hard metal composition according to item 26, wherein the carbide is ZrC and accounts for about 32% to 96% of the total weight of the hard metal composition, and Re does not exceed about 67.7 of the total weight of the hard metal composition. % And the nickel-based superalloy does not exceed about 44.1% of the total weight of the hard metal composition. 29. The hard metal composition according to item 26, wherein the carbide is HfC and accounts for about 47.7% to 98.1% of the total weight of the hard metal composition, and Re does not exceed about the hard metal. The total weight of the composition is 52.1% and the nickel-based superalloy® does not exceed about 29.2% of the total weight of the hard metal composition. 30. The hard metal composition according to item 26, wherein the carbide is VC and accounts for about 28.3% to 95.6% of the total weight of the hard metal composition, and Re does not exceed about the total weight of the hard metal composition. 71.5% of the nickel-based superalloy does not exceed about 4 8.4% of the total weight of the hard metal composition. 3 1 The hard metal composition according to item 26, wherein the carbide is NbC and accounts for about 36% to 96.9% of the total weight of the hard metal composition, and Re φ is equal to or lower than about the hard metal composition. 63.8% of the total weight of the material and the nickel-based superalloy is equal to or lower than about 39% of the total weight of the hard metal composition. 32. The hard metal composition according to item 26, wherein the carbide is TaC and accounts for about 51% to 98 3% of the total weight of the hard metal composition to be equal to or lower than about the total weight of the hard metal composition. The weight of 48.8% of the alloy is equal to or lower than about 26.5% of the total weight of the hard metal composition. 33. The hard metal composition according to item 26, wherein the carbide is ChC3 and accounts for about 32.4% to 96 4% of the total weight of the hard metal composition

Re等於或低於約該硬金屬組合物總重量的67·3%而該錄美 1057D-6939-PF 43 :200535255 超合金等於或低於約該硬金屬組合物總重量的43 ·6%。 3 4 ·如第2 6項所述之硬金屬組合物，其中該碳化物為 Μοβ且約佔該硬金屬組合物總重量的39.6%至97.3%， Re等於或低於約該硬金屬組合物總重量的60·2%而該鎳基超合金等於或低於約該硬金屬組合物總重量的3 6 · 3 %。 3 5 ·如第2 6項所述之硬金屬組合物，其中該碳化物為 WC且約佔該硬金屬組合物總重量的52.9%至98.4%，Re 等於或低於約該硬金屬組合物總重量的46.9%而該鎳基超 ® 合金等於或低於約該硬金屬組合物總重量的25%。 3 6. —種硬金屬組合物包括··包括至少一種氮化物的硬粒子，其中該氮化物擇自由元素週期表中IVb及Vb族元素所形成的氮化物；以及一黏結硬粒子的黏結劑基質包括Re及鎳基超合金，其中該硬粒子約佔該硬金屬組合物總重量的28%至98.3%。 37.如第36項所述之硬金屬組合物，其中該氮化物為 φ TlN且約佔該硬金屬組合物總重量的28%至95.6%，Re等於或低於約該硬金屬組合物總重量的7丨· 7 %而該錄基超合金等於或低於約該硬金屬組合物總重量的48.7%。 3 8 ·如第3 6項所述之硬金屬組合物，其中該氮化物為 ZrN且約佔該硬金屬組合物總重量的至96.7%，Re 等於或低於約該硬金屬組合物總重量的65·3%而該鎳基超合金等於或低於約該硬金屬組合物總重量的4丨·4%。 3 9 ·如第3 6項所述之硬金屬組合物，其中該氮化物為 HfN且約佔該硬金屬組合物總重量的49 8%至98.2%，Re 1057D-6939-PF 44 ；200535255 等於或低於約該硬金屬組合物總重量的5 0 %而該鎳基超合金等於或低於約該硬金屬組合物總重量的2 7 · 5 %。 40·如第36項所述之硬金屬組合物，其中該氮化物為 VN且約佔該硬金屬組合物總重量的3〇%至96%，Re等於或低於約該硬金屬組合物總重量的69·6%而該鎳基超合金等於或低於約該硬金屬組合物總重量的46.2%。 41 ·如弟3 6項所述之硬金屬組合物，其中該氮化物為 NbN且約佔該硬金屬組合物總重量的34·4%至96.7%，等於或低於约該硬金屬組合物總重量的65·3%而該鎳基超合金等於或低於約該硬金屬組合物總重量的41·5%。 42·如第36項所述之硬金屬組合物，其中該氮化物為 TaN且約佔該硬金屬組合物總重量的5〇7%至98 3%，以等於或低於約該硬金屬組合物總重量的491%而該鎳基超合金等於或低於約該硬金屬組合物總重量的26.8%。 43· —種硬金屬組合物包括··包括至少一種碳化物的 φ硬粒子，其中該碳化物擇自由元素週期表中IVb、Vb及VIb 方矢元素所形成的碳化物；以及一黏結硬粒子的黏結劑基質包括Re及Co ’其中該硬粒子約佔該硬金屬組合物總重量的 26.1% 至 98.2%。 44.如第43項所述之硬金屬組合物，其中該碳化物為 TiC且約佔該硬金屬組合物總重量的26 · 1 %至94 · 6 %，Re 等於或低於約該硬金屬組合物總重量的73.6%而Co等於或低於約該硬金屬組合物總重量的54.1%。 45 ·如第43項所述之硬金屬組合物，其中該；5炭化物為 1057D-6939-PF 45 :200535255Re is equal to or lower than about 67.3% of the total weight of the hard metal composition and the Lumei 1057D-6939-PF 43: 200535255 super alloy is equal to or lower than about 43.6% of the total weight of the hard metal composition. 3 4 · The hard metal composition according to item 26, wherein the carbide is Μοβ and accounts for about 39.6% to 97.3% of the total weight of the hard metal composition, and Re is equal to or lower than about the hard metal composition. The total weight is 60 · 2% and the nickel-based superalloy is equal to or lower than about 36 · 3% of the total weight of the hard metal composition. 35. The hard metal composition according to item 26, wherein the carbide is WC and accounts for about 52.9% to 98.4% of the total weight of the hard metal composition, and Re is equal to or lower than about the hard metal composition. 46.9% of the total weight and the nickel-based super® alloy is equal to or less than about 25% of the total weight of the hard metal composition. 3 6. A kind of hard metal composition includes hard particles including at least one nitride, wherein the nitride is selected from nitrides of elements IVb and Vb in the periodic table of elements; and a binder for binding hard particles The matrix includes Re and a nickel-based superalloy, wherein the hard particles comprise about 28% to 98.3% of the total weight of the hard metal composition. 37. The hard metal composition according to item 36, wherein the nitride is φ TlN and accounts for about 28% to 95.6% of the total weight of the hard metal composition, and Re is equal to or less than about the total of the hard metal composition. 7% by weight and the superalloy is equal to or less than about 48.7% of the total weight of the hard metal composition. 38. The hard metal composition according to item 36, wherein the nitride is ZrN and accounts for about 96.7% of the total weight of the hard metal composition, and Re is equal to or less than about the total weight of the hard metal composition. 65 · 3% and the nickel-based superalloy is equal to or less than about 4% · 4% of the total weight of the hard metal composition. 39. The hard metal composition according to item 36, wherein the nitride is HfN and accounts for about 49 8% to 98.2% of the total weight of the hard metal composition. Re 1057D-6939-PF 44; 200535255 equals Or less than about 50% of the total weight of the hard metal composition and the nickel-based superalloy is equal to or less than about 27.5% of the total weight of the hard metal composition. 40. The hard metal composition according to item 36, wherein the nitride is VN and accounts for about 30% to 96% of the total weight of the hard metal composition, and Re is equal to or lower than about the total weight of the hard metal composition. The weight of 69.6% and the nickel-based superalloy is equal to or less than about 46.2% of the total weight of the hard metal composition. 41. The hard metal composition as described in item 36, wherein the nitride is NbN and accounts for about 34.4% to 96.7% of the total weight of the hard metal composition, which is equal to or lower than the hard metal composition. The total weight is 65 · 3% and the nickel-based superalloy is equal to or lower than about 41 · 5% of the total weight of the hard metal composition. 42. The hard metal composition according to item 36, wherein the nitride is TaN and accounts for about 507% to 983% of the total weight of the hard metal composition, so as to be equal to or lower than about the hard metal composition. The total weight of the nickel-based superalloy is 491% or less than about 26.8% of the total weight of the hard metal composition. 43. A kind of hard metal composition includes φ hard particles including at least one kind of carbide, wherein the carbide is selected from carbides formed by IVb, Vb, and VIb square elements in the periodic table of elements; and a cemented hard particle The binder matrix includes Re and Co 'wherein the hard particles account for about 26.1% to 98.2% of the total weight of the hard metal composition. 44. The hard metal composition according to item 43, wherein the carbide is TiC and accounts for about 26.1% to 94.6% of the total weight of the hard metal composition, and Re is equal to or less than about the hard metal 73.6% of the total weight of the composition and Co is equal to or less than about 54.1% of the total weight of the hard metal composition. 45. The hard metal composition according to item 43, wherein the 5 carbide is 1057D-6939-PF 45: 200535255

ZrC且約佔該硬金屬組合物總重量的32%至96%，Re等於或低於約該硬金屬組合物總重量的67.7%而Co等於或低於約該硬金屬組合物總重量的47.1%。 46·如第43項所述之硬金屬組合物，其中該碳化物為 HfC且約佔該硬金屬組合物總重量的47.6%至97.8%，Re 等於或低於約該硬金屬組合物總重量的5 2.1 %而c 〇等於或低於約該硬金屬組合物總重量的3 1.8 %。 47·如第43項所述之硬金屬組合物，其中該碳化物為 ^ VC且約佔該硬金屬組合物總重量的28.3%至95.1%，Re 等於或低於約該硬金屬組合物總重量的71.4%而Co等於或低於約該硬金屬組合物總重量的5 1 ·5%。 48. 如第43項所述之硬金屬組合物，其中該碳化物為 NbC且約佔該硬金屬組合物總重量的36%至96.5%，Re 等於或低於約該硬金屬組合物總重量的63.8%而co等於或低於約該硬金屬組合物總重量的4 2 · 8 %。 49. 如第43項所述之硬金屬組合物，其中該碳化物為 TaC且約佔該硬金屬組合物總重量的51%至98%，Re等於或低於約該硬金屬組合物總重量的48.8%而Co等於或低於約該硬金屬組合物總重量的28.9%。 5 0.如第43項所述之硬金屬組合物，其中該碳化物為 Cr2C3且約佔該硬金屬組合物總重量的32.4%至96%，Re 等於或低於約該硬金屬組合物總重量的67.3%而Co等於或低於約該硬金屬組合物總重量的46.6%。 5 1 ·如第43項所述之硬金屬組合物，其中該碳化物為 1057D-6939-PF 46 :200535255 m〇2c且約佔該硬金屬組合物總重量# 396%至97%，以等於或低於約該硬金屬組合物總重量白“〇2%而c〇等於或低於約該硬金屬組合物總重量的39 2%。 52.如第43項所述之硬金屬組合物，其中該碳化物為 E且約佔該硬金屬組合物總重量的52 9%至98篇，^ 等於或低於約該硬金屬組合物總重量& 46 9%而c。等於或低於約該硬金屬組合物總重量的27 。ZrC and approximately 32% to 96% of the total weight of the hard metal composition, Re equal to or lower than approximately 67.7% of the total weight of the hard metal composition and Co equal to or lower than approximately 47.1 of the total weight of the hard metal composition %. 46. The hard metal composition according to item 43, wherein the carbide is HfC and accounts for about 47.6% to 97.8% of the total weight of the hard metal composition, and Re is equal to or less than about the total weight of the hard metal composition. Of 5 2.1% and co is equal to or less than about 3 1.8% of the total weight of the hard metal composition. 47. The hard metal composition according to item 43, wherein the carbide is ^ VC and accounts for about 28.3% to 95.1% of the total weight of the hard metal composition, and Re is equal to or lower than about the total of the hard metal composition. 71.4% by weight and Co is equal to or less than about 51.5% of the total weight of the hard metal composition. 48. The hard metal composition according to item 43, wherein the carbide is NbC and accounts for about 36% to 96.5% of the total weight of the hard metal composition, and Re is equal to or less than about the total weight of the hard metal composition. 63.8% and co is equal to or lower than about 4 2 · 8% of the total weight of the hard metal composition. 49. The hard metal composition according to item 43, wherein the carbide is TaC and accounts for about 51% to 98% of the total weight of the hard metal composition, and Re is equal to or lower than about the total weight of the hard metal composition. 48.8% and Co is equal to or less than about 28.9% of the total weight of the hard metal composition. 50. The hard metal composition according to item 43, wherein the carbide is Cr2C3 and accounts for about 32.4% to 96% of the total weight of the hard metal composition, and Re is equal to or lower than about the total weight of the hard metal composition. 67.3% by weight and Co is equal to or less than about 46.6% of the total weight of the hard metal composition. 5 1 · The hard metal composition according to item 43, wherein the carbide is 1057D-6939-PF 46: 200535255 m〇2c and accounts for about 396% to 97% of the total weight of the hard metal composition, which is equal to Or less than about 2% of the total weight of the hard metal composition and c0 is equal to or less than about 39.2% of the total weight of the hard metal composition. 52. The hard metal composition according to item 43, Wherein the carbide is E and accounts for about 52 9% to 98 of the total weight of the hard metal composition, ^ is equal to or lower than the total weight of the hard metal composition & 46 9% and c. Is equal to or lower than about The total weight of the hard metal composition is 27.

53·—種硬金屬組合物包括··包括至少一種氮化物的硬粒子’其中該氮化物擇自由元素週期表巾m及％族元素所形成的氮化物；以及一包括Re及c〇且用來黏結硬粒子的黏結劑基質，其中該硬粒子約佔該硬金屬組合物總重量的28%至98%。 54·如第53項所述之硬金屬組合物，其中該氮化物為 TiN且約佔該硬金屬組合物總重量的28%至95%，Re最高至約該硬金屬組合物總重量的71.6%而Co最高至約該硬金屬組合物總重量的51.7%。 55·如第53項所述之硬金屬組合物，其中該氮化物為 ZrN且約佔該硬金屬組合物總重量的3 4 · 5 %至9 6 · 3 %，Re 最南至約該硬金屬組合物總重量的6 5.3 %而C 〇最高至約該硬金屬組合物總重量的44.4%。 5 6 ·如第5 3項所述之硬金屬組合物，其中該氮化物為 HfN且約佔該硬金屬組合物總重量的49.8%至98%，最局至約該硬金屬組合物總重量的5 0 %而C 〇最而至約該硬金屬組合物總重量的30%。 1057D-6939-PF 47 •200535255 ”·如第53項所述之硬金屬組合物，其中該氮 VN且約佔該硬金屬組合物總重量的 ^ > 〇主最高至約該硬金屬組合物總重量的69 6 〇/ & p η •〇/〇而Co最高至約哕硬金屬組合物總重量的49.3%。 w ，〜〜人义_吸士物，其中該氮化物53. A hard metal composition includes hard particles including at least one nitride 'wherein the nitride is selected from the group consisting of m and% elements of the periodic table of the element; and a nitride including Re and c0 and used An adhesive matrix for bonding hard particles, wherein the hard particles account for about 28% to 98% of the total weight of the hard metal composition. 54. The hard metal composition according to item 53, wherein the nitride is TiN and accounts for about 28% to 95% of the total weight of the hard metal composition, and Re is up to about 71.6% of the total weight of the hard metal composition. % And Co up to about 51.7% of the total weight of the hard metal composition. 55. The hard metal composition according to item 53, wherein the nitride is ZrN and accounts for about 34.5% to 96.3% of the total weight of the hard metal composition, with Re being the southernmost to about the hard The total weight of the metal composition is 6 5.3% and Co is up to about 44.4% of the total weight of the hard metal composition. 5 6 · The hard metal composition according to item 53, wherein the nitride is HfN and accounts for about 49.8% to 98% of the total weight of the hard metal composition, and at most about the total weight of the hard metal composition 50% and C0 up to about 30% of the total weight of the hard metal composition. 1057D-6939-PF 47 • 200535255 "· The hard metal composition as described in item 53, wherein the nitrogen VN and approximately ^ of the total weight of the hard metal composition ^ > 〇 Mainly up to about the hard metal composition The total weight is 69 6 〇 / & p η • 〇 / 〇 and Co is up to about 49.3% of the total weight of the hard metal composition. W, ~~ humane_spirit, wherein the nitride

NbN且約佔該硬金屬組合物總重量的34·4%至％ 3%，# 袁而至約該硬金屬組合物總重量的6 5 1 ρ π 处而Co隶高至約NbN and about 34.4% to 3% of the total weight of the hard metal composition, # Yuan Er to about 6 5 1 ρ π and the total weight of Co hard to about

該硬金屬組合物總重量的44.5%。 59·如第53項所述之硬金屬組合铷甘士斗〆口物，其中該氮化物44.5% of the total weight of the hard metal composition. 59. The hard metal combination (ganshidou) mouthpiece according to item 53, wherein the nitride

TaN且約佔該硬金屬組合物總重量 # 田〆曰1 5〇·7%至98% ，Re 农兩至約該硬金屬組合物總重量的491α/^广π W.1%而Co最高至約該硬金屬組合物總重量的29.2%。 t)U. -禋硬金屬组合物包括：包杠=, _山 I括至少一種碳化物的硬粒子，其中該碳化物擇自由元素週期表中ivb vb& v几族兀素所形成的碳化物；以及-包括鎳基超合金及c〇且用來黏結硬粒子的黏結劑基質，其中該硬粒子約佔該硬金屬組合物總重量的45%至98%。 61·如第60項所述之硬金屬組合物，其中該碳化物為 nc且約佔該硬金屬組合物總重量的45%至，該鎳基超合金最高至約該硬金屬組合物總重量的515%而c〇最南至約該硬金屬組合物總重量的54.5%。 62.如第60項所述之硬金屬組合物，其中該碳化物為 TlC且約佔該硬金屬組合物總重量的52%至96%，該鎳基超合金最高至約該硬金屬組合物總重量的44 4%而C〇最TaN accounts for about the total weight of the hard metal composition. # 田〆说 15.7% to 98%, Re Nongliang to about 491α / ^ Wπ.W.1% of the total weight of the hard metal composition and the highest Co To about 29.2% of the total weight of the hard metal composition. t) U.-禋 Hard metal composition includes: hard particles including at least one carbide, wherein the carbide is selected from the group consisting of ivb vb & v several carbons in the periodic table of elements And-an adhesive matrix including a nickel-based superalloy and co and used to bond hard particles, wherein the hard particles account for about 45% to 98% of the total weight of the hard metal composition. 61. The hard metal composition according to item 60, wherein the carbide is nc and accounts for about 45% of the total weight of the hard metal composition, and the nickel-based superalloy is up to about the total weight of the hard metal composition. 515% of the total and C0 to the south of about 54.5% of the total weight of the hard metal composition. 62. The hard metal composition according to item 60, wherein the carbide is TlC and accounts for about 52% to 96% of the total weight of the hard metal composition, and the nickel-based superalloy is up to about the hard metal composition 44 4% of the total weight

1057D-6939-PF 48 •200535255 € 高至約該硬金屬組合物總重量的47.4%。 63 ·如第60項所述之硬金屬組合物，其中該碳化物為 H fC且約佔該硬金屬組合物總重量的6 8 %至9 8 ’该錄基超合金最高至約該硬金屬組合物總重量的29%而Co最高至約該硬金屬組合物總重量的32%。 64.如第60項所述之硬金屬組合物，其中該碳化物為 V C且約佔該硬金屬組合物總重量的4 8 %至9 6 % ’該鎳基超合金最高至約該硬金屬組合物總重量的49%而Co最高籲至約該硬金屬組合物總重量的52%。 65·如第60項所述之硬金屬組合物，其中該碳化物為 NbC且約佔該硬金屬組合物總重量的5 7%至97 % ’該錄基超合金最高至約該硬金屬組合物總重量的40%而c〇最高至約該硬金屬組合物總重量的43 %。 66. 如第60項所述之硬金屬組合物，其中該碳化物為 TaC且約佔該硬金屬組合物總重量的71%至98%，該鎳基 • 超合金最高至約該硬金屬組合物總重量的27%而Co最高至約該硬金屬組合物總重量的29%。 67. 如第60項所述之硬金屬組合物，其中該碳化物為 Cr2C3且約佔該硬金屬組合物總重量的53%至96%，該鎳基超合金最高至約該硬金屬組合物總重量的67·3 %而Co 最高至約該硬金屬組合物總重量的44%。 6 8 ·如第6 0項所述之硬金屬組合物’其中該碳化物為 Mo2C且約佔該硬金屬組合物總重量的60%至97%，該鎳基超合金最高至約該硬金屬組合物總重量的36.5%而Co 1057D-6939-PF 49 ；200535255 最高至約該硬金屬組合物總重量的39%。 69.如第60項所述之硬金屬組合物，其中該碳化物為 wc且約佔該硬金屬組合物總重量的72%至，該鎳基起a至袁南至約該硬金屬組合物總重量的4 6 · 9 %而C 〇最高至約該硬金屬組合物總重量的27 5%。 7 0 · —種硬金屬組合物包括：包括至少一種氮化物的硬粒子，其中該氮化物擇自由元素週期表中ivb及Vb族元素所形成的氮化物；以及一包括鎳基超合金及Co且用來攀黏結硬粒子的黏結劑基質，其中該硬粒子約佔該硬金屬組合物總重量的47%至98% 71·如第70項所述之硬金屬、纟且合物，其中該氮化物為 ΤιΝ且約佔該硬金屬組合物總重量的47%至％%，該鎳基超合金最高至約該硬金屬組合物總重量的49%而C〇最高至約該硬金屬組合物總重量的52%。 72.如第70項所述之硬金屬紐合物，其中該氮化物為 φ ZrN且約佔該硬金屬組合物總重量的5 5 %至97%，該鎳基超合金最高至約該硬金屬組合物總重量的42%而c〇最高至約該硬金屬組合物總重量的45%。 73 ·如第70項所述之硬金屬、纟且合物，其中該氮化物為 HfN且約佔該硬金屬組合物總重量的7〇%至98%，該鎳基超合金最高至約該硬金屬組合物總重量的3丨％而Co最高至約該硬金屬組合物總重量的27%。 1 74·如第70項所述之硬金屬組合物，其中該氮化物為 VN且約佔該硬金屬組合物總重量的5 〇 %至9 6 %，該鎳基 1057D-6939-PF 50 '200535255 超合金最高至約該硬金屬組合物總重量的5 3 %而Co最g 至約該硬金屬組合物總重量的44%。 75·如第70項所述之硬金屬組合物，其中該氮化物為 NbN且約佔該硬金屬組合物總重量的55%至97%，該錄基超合金最高至約該硬金屬組合物總重量的47%而Co最高至約該硬金屬組合物總重量的4 0 %。 7 6 ·如第7 0項所述之硬金屬組合物，其中該氮化物為 TaN且約佔該硬金屬組合物總重量的7〇%至98%，該錄超合金最高至約該硬金屬組合物總重量的3 〇 %而C 〇最高至約該硬金屬組合物總重量的2 6 %。 77· —種硬金屬組合物包括：包括至少一種碳化物的硬粒子’其中該碳化物擇自由元素週期表中I Vb、Vb及Vlb 族元素所形成的碳化物；以及一包括Re、鎳基超合金及 Co且用來黏結硬粒子的黏結劑基質，其中該硬粒子約佔該硬金屬組合物總重量的26%至98.3%。 φ 78·如第77項所述之硬金屬組合物，其中該碳化物為1057D-6939-PF 48 • 200535255 € Up to about 47.4% of the total weight of the hard metal composition. 63. The hard metal composition according to item 60, wherein the carbide is H fC and accounts for about 68% to 98% of the total weight of the hard metal composition. The total weight of the composition is 29% and Co is up to about 32% of the total weight of the hard metal composition. 64. The hard metal composition according to item 60, wherein the carbide is VC and accounts for about 48% to 96% of the total weight of the hard metal composition. 'The nickel-based superalloy is up to about the hard metal. 49% of the total weight of the composition and Co up to about 52% of the total weight of the hard metal composition. 65. The hard metal composition according to item 60, wherein the carbide is NbC and accounts for about 57% to 97% of the total weight of the hard metal composition. 'The base superalloy is up to about the hard metal combination. 40% of the total weight of the material and c0 up to about 43% of the total weight of the hard metal composition. 66. The hard metal composition according to item 60, wherein the carbide is TaC and accounts for about 71% to 98% of the total weight of the hard metal composition, and the nickel-based superalloy is up to about the hard metal combination 27% of the total weight of the material and Co up to about 29% of the total weight of the hard metal composition. 67. The hard metal composition according to item 60, wherein the carbide is Cr2C3 and accounts for about 53% to 96% of the total weight of the hard metal composition, and the nickel-based superalloy is up to about the hard metal composition. 67.3% of the total weight and Co up to about 44% of the total weight of the hard metal composition. 68. The hard metal composition according to item 60, wherein the carbide is Mo2C and accounts for about 60% to 97% of the total weight of the hard metal composition, and the nickel-based superalloy is up to about the hard metal. 36.5% of the total weight of the composition and Co 1057D-6939-PF 49; 200535255 up to about 39% of the total weight of the hard metal composition. 69. The hard metal composition according to item 60, wherein the carbide is wc and accounts for about 72% of the total weight of the hard metal composition, the nickel group is from a to Yuan Nan to about the hard metal composition 46.9% of the total weight and C0 up to about 275% of the total weight of the hard metal composition. 70. A hard metal composition includes: hard particles including at least one nitride, wherein the nitride is selected from nitrides formed from elements ivb and Vb in the periodic table of elements; and a nickel-based superalloy and Co And a binder matrix for bonding hard particles, wherein the hard particles account for about 47% to 98% of the total weight of the hard metal composition 71. The hard metal and agglomerates according to item 70, wherein the The nitride is TiN and accounts for about 47% to %% of the total weight of the hard metal composition, the nickel-based superalloy is up to about 49% of the total weight of the hard metal composition, and CO is up to about the hard metal composition 52% of total weight. 72. The hard metal conjugate according to item 70, wherein the nitride is φZrN and accounts for about 55 to 97% of the total weight of the hard metal composition, and the nickel-based superalloy is up to about the hard The total weight of the metal composition is 42% and co is up to about 45% of the total weight of the hard metal composition. 73. The hard metal, hafnium complex according to item 70, wherein the nitride is HfN and accounts for about 70% to 98% of the total weight of the hard metal composition, and the nickel-based superalloy is up to about 3% by weight of the total weight of the hard metal composition and Co up to about 27% by weight of the total weight of the hard metal composition. 1 74. The hard metal composition according to item 70, wherein the nitride is VN and accounts for about 50% to 96% of the total weight of the hard metal composition, and the nickel-based 1057D-6939-PF 50 ' 200535255 Superalloys are up to about 53% of the total weight of the hard metal composition and Co is up to about 44% of the total weight of the hard metal composition. 75. The hard metal composition according to item 70, wherein the nitride is NbN and accounts for about 55% to 97% of the total weight of the hard metal composition, and the base superalloy is up to about the hard metal composition. 47% of the total weight and Co up to about 40% of the total weight of the hard metal composition. 76. The hard metal composition according to item 70, wherein the nitride is TaN and accounts for about 70% to 98% of the total weight of the hard metal composition, and the superalloy is up to about the hard metal. 30% of the total weight of the composition and C0 up to about 26% of the total weight of the hard metal composition. 77 · A kind of hard metal composition includes: hard particles including at least one kind of carbide, wherein the carbide is selected from the group consisting of I Vb, Vb and Vlb elements in the periodic table; and A binder matrix of superalloy and Co for bonding hard particles, wherein the hard particles account for about 26% to 98.3% of the total weight of the hard metal composition. φ 78. The hard metal composition according to item 77, wherein the carbide is

TiC且約佔該硬金屬組合物總重量的％%至95%，Re最高至約該硬金屬組合物總重量的73 ·6%，該鎳基超合金最高至約該硬金屬組合物總重量的51.3%而Co最高至約該硬金屬組合物總重量的54.3%。 79.如第77項所述之硬金屬組合物，其中該碳化物為 ZrC且約佔該硬金屬組合物總重量的32%至％%，尺已最高至約該硬金屬組合物總重量的67·7%，該鎳基超合金最高至約該硬金屬組合物總重量的44.2%而c〇最高至約該硬 1057D-6939-PF 51 200535255 金屬組合物總重量的47.2%。 80.如第77項所述之硬金屬組合物，其中該碳化物為 H fC且約佔該硬金屬組合物總重量的4 8 %至9 8 % ’ R e最高至約該硬金屬組合物總重量的52.1%，該鎳基超合金最高至約該硬金屬組合物總重量的2 9 · 3 %而C 〇最高至約該硬金屬組合物總重量的31.8%。 8 1 ·如第77項所述之硬金屬組合物，其中該碳化物為 VC且約佔該硬金屬組合物總重量的28%至96%，Re最高 ^ 至約該硬金屬組合物總重量的71.5%，該鎳基超合金最高至約該硬金屬組合物總重量的48.6%而Co最高至約該硬金屬組合物總重量的51.7%。 82.如第77項所述之硬金屬組合物，其中該碳化物為 NbC且約佔該硬金屬組合物總重量的36%至97%，Re最高至約該硬金屬組合物總重量的63.8%，該鎳基超合金最高至約該硬金屬組合物總重量的40%而Co最高至約該硬 _ 金屬組合物總重量的43%。 83·如第77項所述之硬金屬組合物，其中該碳化物為 TaC且約佔該硬金屬組合物總重量的51%至98.3%，Re 最高至約該硬金屬組合物總重量的48.8%，該鎳基超合金最高至約該硬金屬組合物總重量的26.6%而Co最高至約該硬金屬組合物總重量的29%。 84·如第77項所述之硬金屬組合物，其中該碳化物為 Cr2C〗且約佔該硬金屬組合物總重量的32%至96%，Re最高至約該硬金屬組合物總重量的67.3%，該鎳基超合金最 1057D-6939-PF 52 巍 200535255 高至約該硬金屬組合物總重量的43 ·8%而Co最高至約該硬金屬組合物總重量的46.8%。 85·如第77項所述之硬金屬組合物，其中該碳化物為 Mo2C且約佔該硬金屬組合物總重量的39%至97%，Re最高至約該硬金屬組合物總重量的6 0 · 2 %，該鏢基超合金最高至約該硬金屬組合物總重量的36.4%而Co最高至約該硬金屬組合物總重量的39.3%。 86·如第77項所述之硬金屬組合物，其中該碳化物為 WC且約佔該硬金屬組合物總重量的5 3 %至98 %，Re最高至約該硬金屬組合物總重量的46.9%，該鎳基超合金最高至約該硬金屬組合物總重量的25.1%而Co最高至約該硬金屬組合物總重量的27.5%。 87· —種硬金屬組合物包括：包括至少一種氮化物的硬粒子’其中該氮化物擇自由元素週期表中IVb及Vb族元素所形成的氮化物；以及一包括Re、鎳基超合金及且用來黏結硬粒子的黏結劑基質，其中該硬粒子約佔該硬金屬組合物總重量的28%至98.3%。 88·如第87項所述之硬金屬組合物，其中該氮化物為 ΤιΝ且約佔該硬金屬組合物總重量的28%至96%，Re最高至約該硬金屬組合物總重量的71.6%，該鎳基超合金最高至約該硬金屬組合物總重量的4 8 · 8 %而C 〇最高至約該硬金屬組合物總重量的5 1.9%。 89·如第87項所述之硬金屬組合物，其中該氮化物為 ZrN且約佔該硬金屬組合物總重量的34%至97%，Re最 1057D-6939-PF 53 200535255 毳高至約該硬金屬組合物總重量的65·3%，該鎳基超合金最高至約該硬金屬組合物總重量的41.6%而Co最高至約該硬金屬組合物總重量的4 4.6 %。 90·如第87項所述之硬金屬組合物，其中該氮化物為 HfN且約佔該硬金屬組合物總重量的50%至98%，Re最高至約該硬金屬組合物總重量的50%，該鎳基超合金最高至約該硬金屬組合物總重量的27.5%而Co最高至約該硬金屬組合物總重量的3 0 %。 ^ 91.如第87項所述之硬金屬組合物，其中該氮化物為 VN且約佔該硬金屬組合物總重量的30%至96%，Re最高至約該硬金屬組合物總重量的60%，該鎳基超合金最高至約該硬金屬組合物總重量的46·4%而Co最高至約該硬金屬組合物總重量的49%。 92.如第87項所述之硬金屬組合物，其中該氮化物為 NbN且約佔該硬金屬組合物總重量的34%至97%，Re最鲁高至約該硬金屬組合物總重量的65%，該鎳基超合金最高至約該硬金屬組合物總重量的42%而Co最高至約該硬金屬組合物總重量的45%。 9 3 ·如第8 7項所述之硬金屬組合物，其中該氮化物為 TaN且約佔該硬金屬組合物總重量的51%至98.3%，Re 隶南至約該硬金屬組合物總重量的4 9 %，該鎳基超合金最咼至約該硬金屬組合物總重量的2 7 %而c 〇最高至約該硬金屬組合物總重量的2 9 %。 94. 一種硬金屬組合物包括：包括WC及TiC的硬粒 1057D-6939-PF 54 .200535255 子，其中包括wc的硬粒子約佔該硬金屬組合物總重量的 40%至96% ’而包括TiC的硬粒子約佔該硬金屬組合物總重量的0.3%至21% ;以及一含Re且用來黏結硬粒子的黏結劑基質約佔該硬金屬組合物總重量的4%至54%。 95· ’ 一種硬金屬組合物包括：包括wc及TaC的硬粒子，其中包括WC的硬粒子約佔該硬金屬組合物總重量的 44%至96% ’而包括TaC的硬粒子最高至約該硬金屬組合物總重量的21% ;以及一含Re且用來黏結硬粒子的黏結劑基質約佔該硬金屬組合物總重量的4 %至4 8 %。 96· —種硬金屬組合物包括：包括wc、Tic及TaC的硬粒子，其中包括WC的硬粒子約佔該硬金屬組合物總重量的36%至95%，包括TiC的硬粒子最高至約該硬金屬組合物總重量的22%，而包括TaC的硬粒子最高至約該硬金屬組合物總重1的25% ;以及一含Re用來黏結硬粒子的黏結劑基貝約伯该硬金屬組合物總重量的4 %至5 4 %。 φ 97· 一種硬金屬組合物包括：包括WC及TiC的硬粒子，其中包括WC的硬粒子約佔該硬金屬組合物總重量的 60%至98%，而包括TiC的硬粒子最高至約該硬金屬組合物總重量的25% ;以及一含鎳基超合金且用來黏結硬粒子的黏結劍基貝約佔該硬金屬組合物總重量的^ 5 %至3丨％。 98· —種硬金屬組合物包括··包括wc及TaC的硬粒子，其中包括WC的硬粒子約佔該硬金屬組合物總重量的 63%至98%，而包括Tac的硬粒子最高至約該硬金屬組合物總重量的26% ;以及一含鎳基超合金且用來黏結硬粒子 1057D-6939-PF 55 200535255 的黏結劑基質約佔該硬金屬組合物總重量的1.5%至26%。 99· 一種硬金屬組合物包括：包括wc、TiC及TaC的硬粒子’其中包括W C的硬粒子約佔該硬金屬組合物總重量的51%至98%，包括TiC的硬粒子最高至約該硬金屬組合物總重量的23 %，而包括TaC的硬粒子最高至約該硬金屬組合物總重量的26% ;以及一含鎳基超合金且用來黏結硬粒子的黏結劑基質約佔該硬金屬組合物總重量的丨.5 % 至 26% 〇 100· —種硬金屬組合物包括··包括WC及TiC的硬粒子’其中包括WC的硬粒子約佔該硬金屬組合物總重量的 40/6至98%，而包括TiC的硬粒子最高至約該硬金屬組合物總重量的24% ·，以及一含Re及一含鎳基超合金且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的52%及29%。 101· —種硬金屬組合物包括：包括wc及Tac的硬粒 _ 子，其中包括WC的硬粒子約佔該硬金屬組合物總重量的 44/6至98%，而包括TaC的硬粒子最高至約該硬金屬組合物總重量的24% ;以及一含Re及一含鎳基超合金且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的47%及25%。 102· —種硬金屬組合物包括：包括wc、TiC及TaC 的硬粒子，其中包括WC的硬粒子約佔該硬金屬組合物總重量的40%至98%，包括TiC的硬粒子最高至約該硬金屬組合物總重量的23%，而包括TaC的硬粒子最高至約該硬 1057D-6939-PF 56 .200535255 金屬組合物總重量的26% ;以及一含Re及一含錄基超人金且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的5 3 %及3 0 %。 1 03 · —種硬金屬組合物包括：包括WC及Tic的硬粒子，其中包括WC的硬粒子約佔該硬金屬組合物總重量的 40%至98% ’而包括TiC的硬粒子最高至約該硬金屬組合物總重量的23% ;以及一含Re及一含Co且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的5 3 • %及 31%。 104. —種硬金屬組合物包括：包括WC及TaC的硬粒子，其中包括WC的硬粒子約佔該硬金屬組合物總重量的 44%至98%，而包括TaC的硬粒子最高至約該硬金屬組合物總重量的24% ;以及一含Re及一含c〇且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的47 % 及 28%。TiC and about 5% to 95% of the total weight of the hard metal composition, Re up to about 73.6% of the total weight of the hard metal composition, and up to about total weight of the hard metal composition of the nickel-based superalloy 51.3% and Co up to about 54.3% of the total weight of the hard metal composition. 79. The hard metal composition according to item 77, wherein the carbide is ZrC and accounts for about 32% to %% of the total weight of the hard metal composition, and the ruler is up to about 67 · 7%, the nickel-based superalloy is up to about 44.2% of the total weight of the hard metal composition and c0 is up to about 47.2% of the total weight of the hard 1057D-6939-PF 51 200535255 metal composition. 80. The hard metal composition according to item 77, wherein the carbide is H fC and accounts for about 48% to 98% of the total weight of the hard metal composition 'R e up to about the hard metal composition 52.1% of the total weight, the nickel-based superalloy is up to about 29.3% of the total weight of the hard metal composition and C0 is up to about 31.8% of the total weight of the hard metal composition. 8 1 · The hard metal composition according to item 77, wherein the carbide is VC and accounts for about 28% to 96% of the total weight of the hard metal composition, and Re is up to ^ to about the total weight of the hard metal composition 71.5% of the nickel-based superalloy up to about 48.6% of the total weight of the hard metal composition and Co up to about 51.7% of the total weight of the hard metal composition. 82. The hard metal composition according to item 77, wherein the carbide is NbC and comprises approximately 36% to 97% of the total weight of the hard metal composition, and Re is up to approximately 63.8% of the total weight of the hard metal composition %, The nickel-based superalloy is up to about 40% of the total weight of the hard metal composition and Co is up to about 43% of the total weight of the hard metal composition. 83. The hard metal composition according to item 77, wherein the carbide is TaC and accounts for about 51% to 98.3% of the total weight of the hard metal composition, and Re is up to about 48.8% of the total weight of the hard metal composition. %, The nickel-based superalloy is up to about 26.6% of the total weight of the hard metal composition and Co is up to about 29% of the total weight of the hard metal composition. 84. The hard metal composition according to item 77, wherein the carbide is Cr2C and accounts for about 32% to 96% of the total weight of the hard metal composition, and Re is up to about 30% of the total weight of the hard metal composition. 67.3%, the nickel-based superalloy 1057D-6939-PF 52 is as high as about 43.8% of the total weight of the hard metal composition and Co is up to about 46.8% of the total weight of the hard metal composition. 85. The hard metal composition according to item 77, wherein the carbide is Mo2C and accounts for about 39% to 97% of the total weight of the hard metal composition, and Re is up to about 6% of the total weight of the hard metal composition. 0.2%, the dart-based superalloy is up to about 36.4% of the total weight of the hard metal composition and Co is up to about 39.3% of the total weight of the hard metal composition. 86. The hard metal composition according to item 77, wherein the carbide is WC and accounts for about 53% to 98% of the total weight of the hard metal composition, and Re is up to about 5% of the total weight of the hard metal composition. 46.9%, the nickel-based superalloy up to about 25.1% of the total weight of the hard metal composition and Co up to about 27.5% of the total weight of the hard metal composition. 87 · A kind of hard metal composition includes: hard particles including at least one nitride, wherein the nitride is selected from the group consisting of elements IVb and Vb in the periodic table; and a compound including Re, a nickel-based superalloy, and A binder matrix for bonding hard particles, wherein the hard particles account for about 28% to 98.3% of the total weight of the hard metal composition. 88. The hard metal composition according to item 87, wherein the nitride is TiN and accounts for about 28% to 96% of the total weight of the hard metal composition, and Re is up to about 71.6% of the total weight of the hard metal composition. %, The nickel-based superalloy is up to about 48.8% of the total weight of the hard metal composition and C0 is up to about 51.9% of the total weight of the hard metal composition. 89. The hard metal composition according to item 87, wherein the nitride is ZrN and accounts for about 34% to 97% of the total weight of the hard metal composition. Re 1057D-6939-PF 53 200535255 The total weight of the hard metal composition is 65.3%, the nickel-based superalloy is up to about 41.6% of the total weight of the hard metal composition, and Co is up to about 44.6% of the total weight of the hard metal composition. 90. The hard metal composition according to item 87, wherein the nitride is HfN and accounts for about 50% to 98% of the total weight of the hard metal composition, and Re is up to about 50% of the total weight of the hard metal composition %, The nickel-based superalloy is up to about 27.5% of the total weight of the hard metal composition and Co is up to about 30% of the total weight of the hard metal composition. ^ 91. The hard metal composition according to item 87, wherein the nitride is VN and accounts for about 30% to 96% of the total weight of the hard metal composition, and Re is up to about 30% of the total weight of the hard metal composition. 60%, the nickel-based superalloy up to about 46.4% of the total weight of the hard metal composition and Co up to about 49% of the total weight of the hard metal composition. 92. The hard metal composition according to item 87, wherein the nitride is NbN and accounts for about 34% to 97% of the total weight of the hard metal composition, and Re is up to about the total weight of the hard metal composition. 65% of the nickel-based superalloy up to about 42% of the total weight of the hard metal composition and Co up to about 45% of the total weight of the hard metal composition. 9 3 · The hard metal composition according to item 87, wherein the nitride is TaN and accounts for about 51% to 98.3% of the total weight of the hard metal composition, and Re is about to the total weight of the hard metal composition. 49% by weight of the nickel-based superalloy is up to about 27% of the total weight of the hard metal composition and co is up to about 29% of the total weight of the hard metal composition. 94. A hard metal composition includes: hard particles 1057D-6939-PF 54 .200535255 including WC and TiC, and hard particles including wc account for about 40% to 96% of the total weight of the hard metal composition. TiC hard particles account for about 0.3% to 21% of the total weight of the hard metal composition; and a binder matrix containing Re that is used to bond the hard particles accounts for about 4% to 54% of the total weight of the hard metal composition. 95 · 'A hard metal composition includes: hard particles including wc and TaC, wherein hard particles including WC account for about 44% to 96% of the total weight of the hard metal composition' and hard particles including TaC up to about 21% of the total weight of the hard metal composition; and a binder matrix containing Re and used to bind the hard particles accounts for about 4% to 48% of the total weight of the hard metal composition. 96 · A kind of hard metal composition includes: hard particles including wc, Tic and TaC, among which hard particles including WC account for about 36% to 95% of the total weight of the hard metal composition, and hard particles including TiC are up to about The hard metal composition has a total weight of 22%, and the hard particles including TaC are up to about 25% of the total weight of the hard metal composition; 4% to 54% of the total weight of the metal composition. φ 97 · A hard metal composition includes: hard particles including WC and TiC, where hard particles including WC account for about 60% to 98% of the total weight of the hard metal composition, and hard particles including TiC are up to about 25% by weight of the total weight of the hard metal composition; and a bonding sword-based shell containing a nickel-based superalloy for bonding hard particles accounts for about 5% to 3% of the total weight of the hard metal composition. 98. A kind of hard metal composition includes ... Hard particles including wc and TaC, among which hard particles including WC account for about 63% to 98% of the total weight of the hard metal composition, and hard particles including Tac are up to about 26% of the total weight of the hard metal composition; and a binder matrix containing a nickel-based superalloy for bonding hard particles 1057D-6939-PF 55 200535255 to approximately 1.5% to 26% of the total weight of the hard metal composition . 99. A hard metal composition includes: hard particles including wc, TiC and TaC ', wherein hard particles including WC account for about 51% to 98% of the total weight of the hard metal composition, and hard particles including TiC are up to about The total weight of the hard metal composition is 23%, and the hard particles including TaC are up to about 26% of the total weight of the hard metal composition; and a binder matrix containing a nickel-based superalloy for bonding the hard particles accounts for about 5% to 26% of the total weight of the hard metal composition 〇100 · —A kind of hard metal composition includes hard particles including WC and TiC ', wherein the hard particles including WC account for approximately the total weight of the hard metal composition 40/6 to 98%, and hard particles including TiC up to about 24% of the total weight of the hard metal composition, and a binder matrix containing Re and a nickel-based superalloy for bonding hard particles, respectively Up to about 52% and 29% of the total weight of the hard metal composition. 101 · — A kind of hard metal composition includes: hard particles including wc and Tac, among which hard particles including WC account for about 44/6 to 98% of the total weight of the hard metal composition, and hard particles including TaC have the highest To about 24% of the total weight of the hard metal composition; and a binder matrix containing Re and a nickel-based superalloy for bonding hard particles up to about 47% and 25% of the total weight of the hard metal composition, respectively %. 102 · A kind of hard metal composition includes: hard particles including wc, TiC and TaC, among which hard particles including WC account for about 40% to 98% of the total weight of the hard metal composition, and hard particles including TiC are up to about 23% of the total weight of the hard metal composition, and hard particles including TaC up to about 26% of the total weight of the hard 1057D-6939-PF 56 .200535255 metal composition; and one containing Re and one containing Superman gold The binder matrix used to bind the hard particles is up to about 53% and 30% of the total weight of the hard metal composition, respectively. 1 03 · A kind of hard metal composition includes: hard particles including WC and Tic, wherein hard particles including WC account for about 40% to 98% of the total weight of the hard metal composition, and hard particles including TiC are up to about 23% of the total weight of the hard metal composition; and a binder matrix containing Re and Co that are used to bind hard particles up to about 53% and 31% of the total weight of the hard metal composition, respectively. 104. A kind of hard metal composition includes: hard particles including WC and TaC, wherein hard particles including WC account for about 44% to 98% of the total weight of the hard metal composition, and hard particles including TaC are up to about 24% by weight of the total weight of the hard metal composition; and a binder matrix containing Re and C0 for bonding hard particles up to about 47% and 28% of the total weight of the hard metal composition, respectively.

_ 105· —種硬金屬組合物包括：包括WC、TiC及TaC 的硬粒子，其中包括WC的硬粒子約佔該硬金屬組合物總重量的40%至98%，包括Tic的硬粒子最高至約該硬金屬組合物總重量的23%，而包括TaC的硬粒子最高至約該硬金屬組合物總重量的26% ;以及一含Re及一含c〇且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的53%及33%。 106· —種硬金屬組合物包括：包括WC及TiC的硬粒子，其中包括wc的硬粒子約佔該硬金屬組合物總重量的 1057D-6939-PF 57 200535255 5 8%至98%，而包括TiC的硬粒子最高至約該硬金屬組合物總重量的24% ;以及一含Co及一含鎳基超合金且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的33%及29% ° 107. —種硬金屬組合物包括··包括WC及TaC的硬粒子，其中包括WC的硬粒子約佔該硬金屬組合物總重量的 61%至98%，而包括TaC的硬粒子最高至約該硬金屬組合物總重量的24% ;以及一含Co及一含鎳基超合金且用來 ^ 黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的28%及25%。_ 105 · — A kind of hard metal composition includes: hard particles including WC, TiC, and TaC, and hard particles including WC account for about 40% to 98% of the total weight of the hard metal composition, including Tic hard particles up to About 23% of the total weight of the hard metal composition, and hard particles including TaC up to about 26% of the total weight of the hard metal composition; and a binder containing Re and a containing C0 and used to bond the hard particles The matrix is up to about 53% and 33% of the total weight of the hard metal composition, respectively. 106 · A kind of hard metal composition includes: hard particles including WC and TiC, and hard particles including wc account for about 1057D-6939-PF 57 200535255 5 8% to 98% of the total weight of the hard metal composition, and include TiC hard particles up to about 24% of the total weight of the hard metal composition; and a binder matrix containing Co and a nickel-based superalloy for bonding hard particles up to about the total weight of the hard metal composition, respectively 33% and 29% ° 107. — A kind of hard metal composition includes hard particles including WC and TaC, among which hard particles including WC account for about 61% to 98% of the total weight of the hard metal composition, and include The hard particles of TaC are up to about 24% of the total weight of the hard metal composition; and a binder matrix containing Co and a nickel-based superalloy and used to bond hard particles up to about the total weight of the hard metal composition, respectively. 28% and 25% by weight.

1 〇8· —種硬金屬組合物包括：包括WC、TiC及TaC 的硬粒子，其中包括WC的硬粒子約佔該硬金屬組合物總重量的57%至98%，包括TiC的硬粒子最高至約該硬金屬組合物總重量的23 %，而包括TaC的硬粒子最高至約該硬金屬組合物總重量的26% ;以及一含Co及一含鎳基超合 _ 金且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的33 %及30%。 109· —種硬金屬組合物包括：包括WC及TiC的硬粒子，其中包括WC的硬粒子約佔該硬金屬組合物總重量的 40%至98%，而包括TiC的硬粒子最高至約該硬金屬組合物總重量的24% ;以及一含Co、一含Re及一含鎳基超合金且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的32%、54%及29%。 110. —種硬金屬組合物包括：包括WC及TaC的硬粒 1057D-6939-PF 58 ♦•200535255 子，其中包括wc的硬粒子約佔該硬金屬組合物總重量的 45%至98%，而包括TaC的硬粒子最高至約該硬金屬組合物總重量的24% ;以及一含Co、一含Re及一含鎳基超合金且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的28%、47%及26%。 1 1 1 · 一種硬金屬組合物包括：包括WC、TiC及TaC 的硬粒子，其中包括WC的硬粒子約佔該硬金屬組合物總重量的35%至93%，包括TiC的硬粒子最高至約該硬金屬 _ 組合物總重量的25%，而包括TaC的硬粒子最高至約該硬金屬組合物總重量的2 6 % ;以及一含C 〇、一含R e及一含鎳基超合金且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的44%、65%及41%。 1 12· —種硬金屬組合物包括：包括TiC的硬粒子約佔該硬金屬組合物總重量的1 9 %至8 8 %，而包括Μ 〇 2 C的硬粒子最高至約該硬金屬組合物總重量的3 8 % ;以及一含Re φ 且用來黏結硬粒子的黏結劑基質約佔該硬金屬組合物總重量的9.5%至65%。 1 13 · —種硬金屬組合物包括：包括TiN的硬粒子約佔該硬金屬組合物總重量的21%至89%，而包括Mo2C的硬粒子最高至約該硬金屬組合物總重量的3 6 % ;以及一含Re 且用來黏結硬粒子的黏結劑基質約佔該硬金屬組合物總重量的9%至63%。 1 14· 一種硬金屬組合物包括：包括TiC的硬粒子最高至約該硬金屬組合物總重量的85%，而包括Mo2C的硬粒108. A type of hard metal composition includes hard particles including WC, TiC, and TaC. The hard particles including WC account for about 57% to 98% of the total weight of the hard metal composition. Up to about 23% of the total weight of the hard metal composition, and hard particles including TaC up to about 26% of the total weight of the hard metal composition; and a Co- and Ni-containing super alloy gold for bonding The binder matrix of hard particles is up to about 33% and 30% of the total weight of the hard metal composition, respectively. 109 · A kind of hard metal composition includes: hard particles including WC and TiC, wherein hard particles including WC account for about 40% to 98% of the total weight of the hard metal composition, and hard particles including TiC are up to about 24% of the total weight of the hard metal composition; and a binder matrix containing Co, Re and Ni-based superalloys for bonding hard particles up to about 32% of the total weight of the hard metal composition, 54% and 29%. 110. A kind of hard metal composition includes: hard particles 1057D-6939-PF 58 including WC and TaC, 200535255 particles, in which hard particles including wc account for about 45% to 98% of the total weight of the hard metal composition, Hard particles including TaC are up to about 24% of the total weight of the hard metal composition; and a binder matrix containing Co, Re and Ni-based superalloys for bonding hard particles is up to about 28%, 47% and 26% of the total weight of the hard metal composition. 1 1 1 · A hard metal composition includes: hard particles including WC, TiC, and TaC. The hard particles including WC account for about 35% to 93% of the total weight of the hard metal composition, and the hard particles including TiC are up to About 25% of the total weight of the hard metal composition, and hard particles including TaC up to about 26% of the total weight of the hard metal composition; and one containing C0, one containing Re and one containing nickel-based The binder matrix of the alloy and used to bind the hard particles is up to about 44%, 65% and 41% of the total weight of the hard metal composition, respectively. 1 12 · A kind of hard metal composition includes: hard particles including TiC accounted for about 19% to 88% of the total weight of the hard metal composition, and hard particles including 〇2C up to about the hard metal combination 38% of the total weight of the material; and an adhesive matrix containing Re φ and used to bind hard particles, which accounts for about 9.5% to 65% of the total weight of the hard metal composition. 1 13 · A hard metal composition includes: hard particles including TiN account for about 21% to 89% of the total weight of the hard metal composition, and hard particles including Mo2C up to about 3% of the total weight of the hard metal composition 6%; and a binder matrix containing Re and used to bind hard particles, which accounts for about 9% to 63% of the total weight of the hard metal composition. 1 14 · A hard metal composition includes: hard particles including TiC up to about 85% of the total weight of the hard metal composition, and hard particles including Mo2C

1057D-6939-PF 59 :200535255 子最高至約該硬金屬知人α / 鸯、、且合物總重量的36% ;以及一含Re 且用末黏結硬粒子的京上么士〕點結劑基質約佔該硬金屬組合物總重置的9%至64%。 115· —種硬金屬組合物包括：包括的硬粒子最高至約該硬金屬組合物總重量的83 %，包括㈣的硬粒子最同至約該硬金屬組合物總重量的85%，包括M〇2C的硬粒子最同至約该硬金屬組合物總重量的25%，包括wc的硬 φ 粒子最南至約該硬金屬組合物總重量的39%、包括TaC的硬粒子最咼至約該硬金屬組合物總重量的3〇%，包括vC 的硬粒子隶咼至約該硬金屬組合物總重量的1 1 %，包括 CqC3的硬粒子最高至約該硬金屬組合物總重量的16% ; 以及一含Re且用來黏結硬粒子的黏結劑基質約佔該硬金屬組合物總重量的6%至65%。 116. —種硬金屬組合物包括：包括Tic的硬粒子約佔 «亥硬金屬組合物總重量的3 〇 %至9 〇 %，而包括Μ 〇 2 C的硬 _ 粒子最高至約該硬金屬組合物總重量的40% ;以及一含鎳基超合金且用來黏結硬粒子的黏結劑基質約佔該硬金屬組合物總重量的4%至41%。 11 7· —種硬金屬組合物包括：包括TiN的硬粒子最高至約該硬金屬組合物總重量的9 1 %，而包括Mo2C的硬粒子最高至約該硬金屬組合物總重量的38% ;以及一含鎳基超合金且用來黏結硬粒子的黏結劑基質約佔該硬金屬組合物總重量的4%至38%。 118. —種硬金屬組合物包括··包括TiC的硬粒子最高 601057D-6939-PF 59: 200535255 up to about 36% of the total weight of the hard metal known as α / 鸯, and a compound containing Re and using hard-bonded hard particles to bond] matrix About 9% to 64% of the total reset of the hard metal composition. 115 · A kind of hard metal composition includes: hard particles included up to about 83% of the total weight of the hard metal composition, hard particles including tritium up to about 85% of the total weight of the hard metal composition, including M The hard particles of 〇2C are up to about 25% of the total weight of the hard metal composition, the hard φ particles including wc are the southmost to about 39% of the total weight of the hard metal composition, and the hard particles including TaC are up to about 25%. 30% of the total weight of the hard metal composition, including hard particles of vC to about 11% of the total weight of the hard metal composition, and hard particles including CqC3 up to about 16% of the total weight of the hard metal composition %; And a binder matrix containing Re and used to bind hard particles, which accounts for about 6% to 65% of the total weight of the hard metal composition. 116. A kind of hard metal composition includes: hard particles including Tic account for about 30% to 90% of the total weight of the hard metal composition, and hard particles including M2C up to about the hard metal 40% of the total weight of the composition; and a binder matrix containing a nickel-based superalloy for bonding hard particles to about 4% to 41% of the total weight of the hard metal composition. 11 7 · A hard metal composition includes: hard particles including TiN up to about 91% of the total weight of the hard metal composition, and hard particles including Mo2C up to about 38% of the total weight of the hard metal composition And a binder matrix containing a nickel-based superalloy for bonding hard particles to about 4% to 38% of the total weight of the hard metal composition. 118. A kind of hard metal composition including ... Hard particles including TiC up to 60

1057D-6939-PF 200535255 至約該硬金屬組合物總重量的90%，包括TiN的硬粒子最高至約該硬金屬組合物總重量的9 1 %，包括M〇2C的硬粒子最高至約該硬金屬組合物總重量的38% ;以及一含鎳基超合金且用來黏結硬粒子的黏結劑基質約佔該硬金屬組合物總重量的4%至40%。 119· 一種硬金屬組合物包括··包括Tic的硬粒子最高至約该硬金屬組合物總重量的90%，包括TiN的硬粒子最高至約該硬金屬組合物總重量的90%，包括M〇2c的硬粒子最高至約該硬金屬組合物總重量的25%，包括wc的硬粒子最高至約該硬金屬組合物總重量的42%、包括TaC的硬粒子隶咼至約該硬金屬組合物總重量的36%，包括的硬粒子最高至約該硬金屬組合物總重量的14%，包括 ChC3的硬粒子最高至約該硬金屬組合物總重量的18%; 以及一含鎳基超合金且用來黏結硬粒子的黏結劑基質約佔該硬金屬組合物總重量的2%至40%。 Φ 120· 一種硬金屬組合物包括··包括TiC的硬粒子最高至約該硬金屬組合物總重量的90%，包括TiN的硬粒子最高至約該硬金屬組合物總重量的91%，包括M02C的硬粒子最咼至約該硬金屬組合物總重量的38% ;以及一含Re 及一含鎳基超合金且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的64%及40%。 121· —種硬金屬組合物包括：包括Ti(：的硬粒子最高至約該硬金屬組合物總重量的89%，包括TiN的硬粒子最同至約該硬金屬組合物總重量的9〇%，包括M〇2C的硬粒1057D-6939-PF 200535255 to about 90% of the total weight of the hard metal composition, up to about 9 1% of the total weight of the hard metal composition including TiN, and up to about 90% of the hard particles including Mo 2C 38% of the total weight of the hard metal composition; and a binder matrix containing a nickel-based superalloy for bonding hard particles, which accounts for about 4% to 40% of the total weight of the hard metal composition. 119. A hard metal composition includes hard particles including Tic up to about 90% of the total weight of the hard metal composition, and hard particles including TiN up to about 90% of the total weight of the hard metal composition, including M The hard particles of 〇2c are up to about 25% of the total weight of the hard metal composition, the hard particles including wc are up to about 42% of the total weight of the hard metal composition, and the hard particles including TaC are up to about the hard metal. 36% of the total weight of the composition, including hard particles up to about 14% of the total weight of the hard metal composition, and hard particles including ChC3 up to about 18% of the total weight of the hard metal composition; and a nickel-containing group The binder matrix of the super alloy and used to bind hard particles accounts for about 2% to 40% of the total weight of the hard metal composition. Φ 120. A hard metal composition includes ... Hard particles including TiC up to about 90% of the total weight of the hard metal composition, and hard particles including TiN up to about 91% of the total weight of the hard metal composition, including The hard particles of M02C are up to about 38% of the total weight of the hard metal composition; and a binder matrix containing Re and a nickel-based superalloy for bonding hard particles is up to about the total weight of the hard metal composition, respectively. 64% and 40% by weight. 121. A hard metal composition includes: hard particles including Ti (: up to about 89% of the total weight of the hard metal composition, and hard particles including TiN up to about 9% of the total weight of the hard metal composition. %, Including hard particles of 〇2C

1057D-6939-PF 61 200535255 子最南至約該硬金屬組合物總重量的26%，包括Wc的硬粒子取鬲至約該硬金屬組合物總重量的42%、包括TaC的硬粒子最高至約該硬金屬組合物總重量的33%，包括vc 的硬粒子最高至約該硬金屬組合物總重量的16%，包括 ChC3的硬粒子最高至約該硬金屬組合物總重量的1; 以及一合Re及一含鎳基超合金且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的64%及4〇 2 · 種硬金屬組合物包括：包括T i C的硬粒子最高至約該硬金屬組合物總重量的9〇%，包括TiN的硬粒子最高至約該硬金屬組合物總重量的91%，包括M〇2C的硬粒子最高至約該硬金屬組合物總重量的38% ;以及一含以及έ鎳基超合金且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的64%及42%。 123· —種硬金屬組合物包括··包括Tic的硬粒子最高参至約該硬金屬組合物總重量的89%，包括TiN的硬粒子最咼至約該硬金屬組合物總重量的9〇%，包括M〇2c的硬粒子最高至約該硬金屬組合物總重量的26%，包括wc的硬粒子最高至約該硬金屬組合物總重量的42%、包括的硬粒子最高至約該硬金屬組合物總重量的33%，包括的硬粒子最高至約該硬金屬組合物總重量的1 6 %，包括 CnC3的硬粒子最南至約該硬金屬組合物總重量的1 $ % ; 以及一含Re及一含鎳基超合金且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的64%及竹1057D-6939-PF 61 200535255 Southmost to about 26% of the total weight of the hard metal composition, hard particles including Wc are taken to about 42% of the total weight of the hard metal composition, and hard particles including TaC are up to About 33% of the total weight of the hard metal composition, including hard particles of vc up to about 16% of the total weight of the hard metal composition, and hard particles including ChC3 up to about 1 of the total weight of the hard metal composition; and Yihe Re and a nickel-based superalloy and a binder matrix for bonding hard particles are up to about 64% and 40% of the total weight of the hard metal composition, respectively. · Hard metal compositions include: T i C Up to about 90% of the total weight of the hard metal composition, up to about 91% of the total weight of the hard metal composition including TiN, and up to about 90% of the hard metal including MoC 38% of the total weight of the composition; and a binder matrix containing and nickel-based superalloys for bonding hard particles up to about 64% and 42% of the total weight of the hard metal composition, respectively. 123. A hard metal composition includes hard particles including Tic up to about 89% of the total weight of the hard metal composition, and hard particles including TiN up to about 9% of the total weight of the hard metal composition. %, Hard particles including Mo2c up to about 26% of the total weight of the hard metal composition, hard particles including wc up to about 42% of the total weight of the hard metal composition, and hard particles including up to about 33% of the total weight of the hard metal composition, including hard particles up to about 16% of the total weight of the hard metal composition, including CnC3 south of the hard particles to about 1 $% of the total weight of the hard metal composition; And a binder matrix containing Re and a nickel-based superalloy for bonding hard particles up to about 64% of the total weight of the hard metal composition and bamboo

1057D-6939-PF 62 200535255 %。 I24· —種硬金屬組合物包括：包括TiC的硬粒子最高至約该硬金屬組合物總重量的9〇%，包括TiN的硬粒子最高至約該硬金屬組合物總重量的91%，包括M〇2c的硬粒子隶间至約該硬金屬組合物總重量的3 8 % ;以及一含及一含Co且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的64%及43%。 125. —種硬金屬組合物包括··包括Tic的硬粒子最高至約該硬金屬組合物總重量的89%，包括TiN的硬粒子最高至約該硬金屬組合物總重量的90%，包括M〇2c的硬粒子最高至約該硬金屬組合物總重量的26%，包括wc的硬粒子最高至約該硬金屬組合物總重量的42%、包括TaC的硬粒子最高至約該硬金屬組合物總重量的33 %，包括VC 的硬粒子最高至約該硬金屬組合物總重量的丨6 %，包括 Cr2C3的硬粒子最高至約該硬金屬組合物總重量的18% ; 以及一含Re及一含Co且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的64%及43 % 126. —種硬金屬組合物包括：包括Tic的硬粒子最高至約該硬金屬組合物總重量的90%，包括TiN的硬粒子最高至約該硬金屬組合物總重量的91 %，包括Mo2C的硬粒子最南至約該硬金屬組合物總重量的3 8 % ;以及一含鎳基超合金及一含C 〇且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的40%及43%。 127. —種硬金屬組合物包括：包括TiC的硬粒子最高 1057D-6939-PF 63 ；200535255 至約該硬金屬組合物總重量的89%，包括TiN的硬粒子最同至約該硬金屬組合物總重量的90%，包括Mo2C的硬粒子最南至約該硬金屬組合物總重量的26%，包括WC的硬粒子隶南至約該硬金屬組合物總重量的42%、包括丁ac的硬粒子最高至約該硬金屬組合物總重量的3 3 %，包括Vc 的硬粒子最高至約該硬金屬組合物總重量的丨6 %，包括 ChC3的硬粒子最高至約該硬金屬組合物總重量的ι8% ; 以及一含鎳基超合金及一含C()且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的4〇%及Μ %。 128· —種硬金屬組合物包括··包括Tic的硬粒子最高至約該硬金屬組合物總重量的9〇%，包括TiN的硬粒子最高至約該硬金屬組合物總重量的91%，包括m〇2C的硬粒子最高至約該硬金屬組合物總重量的;以及一含鎳基超。金及含Nl且用來黏結硬粒子的黏結劑基質分別最 •高至約該硬金屬組合物總重量的4〇%及43%。 129· —種硬金屬組合物包括：包括丁丨匚的硬粒子最高至約該硬金屬組合物總重量的89%，包括TiN的硬粒子最高至約該硬金屬組合物總重量的9〇%，包括M〇2C的硬粒子最咼至約該硬金屬組合物總重量的26%，包括wc的硬粒子最高至約該硬金屬組合物總重量的42%、包括Tac的硬粒子最高至約該硬金屬組合物總重量的33%，包括vc 的硬粒子最高至約該硬金屬組合物總重量的16%，包括 Ci*2C3的硬粒子隶咼至約該硬金屬組合物總重量的1 ;1057D-6939-PF 62 200535255%. I24 · A hard metal composition includes: hard particles including TiC up to about 90% of the total weight of the hard metal composition, and hard particles including TiN up to about 91% of the total weight of the hard metal composition, including The hard particles of Mo2c range from about 38% to the total weight of the hard metal composition; and a binder matrix containing and one containing Co and used to bond the hard particles is up to about the total weight of the hard metal composition, respectively. 64% and 43%. 125. A kind of hard metal composition includes hard particles including Tic up to about 89% of the total weight of the hard metal composition, and hard particles including TiN up to about 90% of the total weight of the hard metal composition, including The hard particles of Mo2c are up to about 26% of the total weight of the hard metal composition, the hard particles including wc are up to about 42% of the total weight of the hard metal composition, and the hard particles including TaC are up to about the hard metal. 33% of the total weight of the composition, including hard particles including VC up to about 6% of the total weight of the hard metal composition, and hard particles including Cr2C3 up to about 18% of the total weight of the hard metal composition; Re and a binder matrix containing Co and used to bond hard particles up to about 64% and 43% of the total weight of the hard metal composition, respectively. 126. A hard metal composition includes: Tic hard particles up to about The total weight of the hard metal composition is 90%, and the hard particles including TiN are up to about 91% of the total weight of the hard metal composition. The hard particles including Mo2C are southmost to about 38% of the total weight of the hard metal composition. ; And a nickel-based superalloy and a C-containing and used to Hard knot binder matrix particles were the highest 40% and about 43% of the total weight of the composition of the hard metal. 127. A kind of hard metal composition includes: hard particles including TiC up to 1057D-6939-PF 63; 200535255 to about 89% of the total weight of the hard metal composition, and hard particles including TiN up to about the same hard metal combination 90% of the total weight of the hard material, including the hardest particles of Mo2C, to the south of about 26% of the total weight of the hard metal composition, and hard particles including WC to about 42% of the total weight of the hard metal composition, including diac Up to about 33% of the total weight of the hard metal composition, including Vc up to about 6% of the total weight of the hard metal composition, and up to about 6% of the hard metal composition including ChC3 8% of the total weight of the material; and a nickel-based superalloy and a binder matrix containing C () for bonding hard particles up to about 40% and M% of the total weight of the hard metal composition, respectively. 128. A kind of hard metal composition includes hard particles including Tic up to about 90% of the total weight of the hard metal composition, and hard particles including TiN up to about 91% of the total weight of the hard metal composition, Hard particles including mO2C are up to about the total weight of the hard metal composition; and a nickel-based ultra-fine. Gold and Nl-containing binder matrix used to bind hard particles are up to about 40% and 43% of the total weight of the hard metal composition, respectively. 129 · A kind of hard metal composition includes: hard particles including Ding Xi up to about 89% of the total weight of the hard metal composition, and hard particles including TiN up to about 90% of the total weight of the hard metal composition Hard particles including Mo2C are up to about 26% of the total weight of the hard metal composition, hard particles including wc are up to about 42% of the total weight of the hard metal composition, and hard particles including Tac are up to about The total weight of the hard metal composition is 33%, and the hard particles including vc are up to about 16% of the total weight of the hard metal composition. The hard particles including Ci * 2C3 are included to about 1% of the total weight of the hard metal composition. ;

1057D-6939-PF 64 200535255 以及一含錄基超合金及一含Ni且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的40%及43 %。 13 0. —種硬金屬組合物包括〔包括TiC的硬粒子最高至約該硬金屬組合物總重量的90%，包括TiN的硬粒子最高至約該硬金屬組合物總重量的9 1 %，包括Mo2C的硬粒子最高至約該硬金屬組合物總重量的38% ;以及一含Re、一含鎳基超合金及一含Co且用來黏結硬粒子的黏結劑基 ® 質分別最高至約該硬金屬組合物總重量的64%、40%及42 %。 1 3 1. —種硬金屬組合物包括··包括T i C的硬粒子最高至約該硬金屬組合物總重量的89%，包括TiN的硬粒子最高至約該硬金屬組合物總重量的90%，包括Mo2C的硬粒子最高至約該硬金屬組合物總重量的26%，包括WC的硬粒子最高至約該硬金屬組合物總重量的42%、包括TaC的 • 硬粒子最高至約該硬金屬組合物總重量的33 %，包括VC 的硬粒子最高至約該硬金屬組合物總重量的1 6 %，包括 Cr2C3的硬粒子最高至約該硬金屬組合物總重量的18% ; 以及一含Re、一含鎳基超合金及一含Co且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的63 %、39% 及 42%。 132· —種硬金屬組合物包括··包括TiC的硬粒子最高至約該硬金屬組合物總重量的90%，包括TiN的硬粒子最高至約該硬金屬組合物總重量的91%，包括m〇2C的硬粒 651057D-6939-PF 64 200535255 and a matrix containing a superalloy and a binder containing Ni for bonding hard particles up to about 40% and 43% of the total weight of the hard metal composition, respectively. 13 0. A hard metal composition includes [including hard particles of TiC up to about 90% of the total weight of the hard metal composition, and hard particles including TiN up to about 91% of the total weight of the hard metal composition, Hard particles including Mo2C up to about 38% of the total weight of the hard metal composition; and a binder containing Re, a nickel-based superalloy, and Co containing a binder-based material for bonding hard particles up to about 64%, 40% and 42% of the total weight of the hard metal composition. 1 3 1. A kind of hard metal composition includes hard particles including TiC up to about 89% of the total weight of the hard metal composition, and hard particles including TiN up to about 89% of the total weight of the hard metal composition. 90%, hard particles including Mo2C up to about 26% of the total weight of the hard metal composition, hard particles including WC up to about 42% of the total weight of the hard metal composition, and hard particles including TaC up to about 33% of the total weight of the hard metal composition, including hard particles of VC up to about 16% of the total weight of the hard metal composition, and hard particles including Cr2C3 up to about 18% of the total weight of the hard metal composition; And a binder matrix containing Re, a nickel-based superalloy, and a Co containing binder particles for bonding hard particles up to about 63%, 39%, and 42% of the total weight of the hard metal composition, respectively. 132. A kind of hard metal composition includes ... Hard particles including TiC up to about 90% of the total weight of the hard metal composition, and hard particles including TiN up to about 91% of the total weight of the hard metal composition, including m〇2C of hard particles 65

1057D-6939-PF \200535255 子最高至約該硬金屬組合物總重量的3 8 % ;以及一含Re、一含錄基超合金及一含Ni且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的63 %、40%及42 %。 133· —種硬金屬組合物包括：包括TiC的硬粒子最高至約該硬金屬組合物總重量的89%，包括TiN的硬粒子最高至約該硬金屬組合物總重量的90%，包括m〇2C的硬粒子最高至約該硬金屬組合物總重量的26%，包括WC的硬粒子最高至約該硬金屬組合物總重量的42%、包括TaC的硬粒子最高至約該硬金屬組合物總重量的33%，包括VC 的硬粒子最高至約該硬金屬組合物總重量的1 6 %，包括 cr2C3的硬粒子最高至約該硬金屬組合物總重量的18%; 以及一含Re、一含鎳基超合金及一含Ni且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬组合物總重量的63 %、39% 及 42%。鲁 13 4 · —種硬金屬組合物包括··包括T i C的硬粒子最高至約該硬金屬組合物總重量的90%，包括TiN的硬粒子最南至約該硬金屬組合物總重里的9 1 %，包括]〇 2 C的硬粒子最高至約該硬金屬組合物總重量的3 8 % ;以及一含Re、一含N i及一含C 〇且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的63%、40%及42%。 135. —種硬金屬組合物包括：包括TiC的硬粒子最高至約該硬金屬組合物總重量的89%，包括TiN的硬粒子最高至約該硬金屬組合物總重量的90%，包括Mo2C的硬粒 661057D-6939-PF \ 200535255 up to about 38% of the total weight of the hard metal composition; and a binder matrix containing Re, a superalloy containing Ni, and a binder matrix containing Ni for bonding hard particles, respectively To about 63%, 40% and 42% of the total weight of the hard metal composition. 133 · A hard metal composition includes: hard particles including TiC up to about 89% of the total weight of the hard metal composition, and hard particles including TiN up to about 90% of the total weight of the hard metal composition, including m 〇2C hard particles up to about 26% of the total weight of the hard metal composition, hard particles including WC up to about 42% of the total weight of the hard metal composition, hard particles including TaC up to about the hard metal combination 33% of the total weight of the material, including hard particles including VC up to about 16% of the total weight of the hard metal composition, and hard particles including cr2C3 up to about 18% of the total weight of the hard metal composition; and A nickel-based superalloy and a Ni-containing binder matrix for bonding hard particles up to about 63%, 39%, and 42% of the total weight of the hard metal composition, respectively. Lu 13 4-A hard metal composition includes ... Hard particles including T i C up to about 90% of the total weight of the hard metal composition, and hard particles including TiN to the south of the total weight of the hard metal composition 91%, including hard particles of 〇2C up to about 38% of the total weight of the hard metal composition; and a bond containing Re, Ni and C, and used to bond hard particles The agent base is up to about 63%, 40% and 42% of the total weight of the hard metal composition, respectively. 135. A hard metal composition includes: hard particles including TiC up to about 89% of the total weight of the hard metal composition, and hard particles including TiN up to about 90% of the total weight of the hard metal composition, including Mo2C Durum 66

1057D-6939-PF '200535255 脅子最高至約該硬金屬組合物總重量的26%，包括wc的硬粒子最高至約該硬金屬組合物總重量的42%、包括丁&〔的硬粒子最高至約該硬金屬組合物總重量的33%，包括vc 的硬粒子隶咼至約該硬金屬組合物總重量的1 6 %，包括1057D-6939-PF '200535255 Up to about 26% of the total weight of the hard metal composition, including hard particles of wc up to about 42% of the total weight of the hard metal composition, including hard particles Up to about 33% of the total weight of the hard metal composition, including hard particles including vc, to about 16% of the total weight of the hard metal composition, including

CnC3的硬粒子最高至約該硬金屬組合物總重量的18%; 以及一含Re、一含Ni及一含C〇且用來黏結硬粒子的黏結劑基質分別最尚至約該硬金屬組合物總重量的63 %、42% 及 42%。The hard particles of CnC3 are up to about 18% of the total weight of the hard metal composition; and a binder matrix containing Re, Ni and C0 and used to bond the hard particles, respectively, up to about the hard metal combination. 63%, 42% and 42% of the total weight.

136. -種硬金屬組合物包括：包括沉的硬粒子最高 f約該硬金屬組合物總重量的9〇%，包括雇的硬粒子最高至約該硬金屬組合物總重量的 ^ ’包括Mo2C的硬粒子最高至約該硬金屬組合物總重垔里的38% ;以及一含鎳基起合金、一含Ni及一含Co且用暂八划爭古芬仏外 . 用；黏結硬粒子的黏結劑基 %。〜重篁的40%、42%及43 !嶸金屬組合物包括· a，何·包括TiC的硬粒子最高至約該硬金屬組合物總重量的89 · 古$的兮击ah 0匕括TiN的硬粒子最同至約該硬金屬組合物總重量的 J2! ^ 包括 M〇2C 的硬粒千蚨回至約該硬金屬組合物總重抑工吳一 π从里的26%，包括WC的硬粒子最咼至約該硬金屬組合物碩粉旱爭古石从重里的42%、包括TaC的更粒子取冋至約該硬金屬組合物她的石爭抑；、、心重篁的33%，包括VC 的硬粒子取咼至約該硬金屬組136. A kind of hard metal composition includes: including hard particles up to about 90% of the total weight of the hard metal composition, including hard particles employed up to about ^ 'including the total weight of the hard metal composition ^ including Mo2C The hard particles are up to about 38% of the total weight of the hard metal composition; and a nickel-based alloy, a Ni and a Co containing, and the use of a long-term battle against Guffen. Use; bond hard particles % Binder based. ~ 40%, 42%, and 43% of the weight of the metal composition. The metal composition includes: a, how, and hard particles including TiC up to about 89% of the total weight of the hard metal composition. The hard particles are the same as about 2% of the total weight of the hard metal composition! ^ Hard particles including M02C are returned to about 26% of the total weight of the hard metal composition including WC The hard particles are up to about 42% of the weight of the hard metal composition, and the ancient stones are taken from 42% of the weight, including TaC, and the stone content of the hard metal composition is about 33%. , Including VC hard particles to about the hard metal group

Cr Γ Μ成心v 口物總重量的16%，包括 2C3的硬粒子最高至約該硬金 ίλΆ ^ , 鸯、、且合物總重量的18% ;; 以及一含鎳基超合金、一含Ni 久—含Co且用來黏結硬粒Cr Γ centricity 16% of the total weight of the mouthpiece, including 2C3 hard particles up to about 18% of the total weight of the hard gold ΆλΆ ^, 鸯, and the total weight of the compound; and a nickel-based superalloy, a Ni-containing for a long time-Co-containing and used to bond hard particles

1057D-6939-PF 67 200535255 子的黏結劑基質分別最高至約該硬金屬組合物總重量的4〇 %、42% 及 42% 〇 13 8· —種硬金屬組合物包括：包括Tic的硬粒子最高至約该硬金屬組合物總重量的9〇%，包括TiN的硬粒子最高至約該硬金屬組合物總重量的91%，包括M〇2c的硬粒子最高至約該硬金屬組合物總重量的38% ;以及一含鎳基超合金、一含Νι及一含c〇且用來黏結硬粒子的黏結劑基貝为別最咼至約該硬金屬組合物總重量的4〇%、42%及43 %。1057D-6939-PF 67 200535255 The binder matrix is up to about 40%, 42% and 42% of the total weight of the hard metal composition, respectively. 013. A hard metal composition includes: hard particles including Tic Up to about 90% of the total weight of the hard metal composition, including hard particles of TiN up to about 91% of the total weight of the hard metal composition, and up to about 90% of the total weight of the hard metal composition 38% by weight; and a nickel-based superalloy, a Ni-containing and a C0-based binder used to bond hard particles to a minimum of about 40% of the total weight of the hard metal composition, 42% and 43%.

139· —種硬金屬組合物包括：包括Tic的硬粒子最高至約該硬金屬組合物總重量的89%，包括TiN的硬粒子最高至約該硬金屬組合物總重量的90%，包括M〇2C的硬粒子最高至約該硬金屬組合物總重量的26%，包括wc的硬粒子最高至約該硬金屬組合物總重量的42%、包括丁扎的硬粒子最高至约該硬金屬組合物總重量的33%，包括vc 的硬粒子最高至約該硬金屬組合物總重量的16%，包括 CqC3的硬粒子最高至約該硬金屬組合物總重量的; 以及一含Re、含鎳基超合金、一含Ni及一含c〇且用來黏結硬粒子的黏結劑基質分別最高至約該硬金屬組合物總重量的63%、39%、42%及42%。〜 140· —種硬金屬組合物包括：包括至少一種硼化物的硬粒子，其中該硼化物擇自由元素週期表中ivb、vb及族元素所形成的硼化物；以及一包括Re且用來黏結硬粒子的黏結劑基質，其中Re約佔該硬金屬組合物總重量的々％ 1057D-693 9-PF 68 \200535255 至 76%。 141·如第140項所述之硬金屬組合物，其中該硼化物為TiB2且約佔該硬金屬組合物總重量的24%至87.5%，其中Re約佔該硬金屬組合物總重量的12.5%至76%。 142·如第140項所述之硬金屬組合物，其中該硼化物為ZrB2且約佔該硬金屬組合物總重量的30%至90.5%，其中Re約佔該硬金屬組合物總重量的9.5%至70%。 143·如第140項所述之硬金屬組合物，其中該硼化物春為HfB2且約佔該硬金屬組合物總重量的44.5%至94.5%，其中Re約佔該硬金屬組合物總重量的5.5%至55.5%。 144·如第140項所述之硬金屬組合物，其中該硼化物為VB2且約佔該硬金屬組合物總重量的27%至89%，其中 Re約佔該硬金屬組合物總重量的11 %至73 %。 145·如第140項所述之硬金屬組合物，其中該硼化物為NbB2且約佔該硬金屬組合物總重量的34%至92%，其 0 中Re約佔該硬金屬組合物總重量的8%至66%。 146. 如第140項所述之硬金屬組合物，其中該硼化物為TaB2且約佔該硬金屬組合物總重量的47%至95%，其中Re約佔該硬金屬組合物總重量的5%至53%。 147. 如第140項所述之硬金屬組合物，其中該硼化物為Cr3B2且約佔該硬金屬組合物總重量的30%至90.5%，其中Re約佔該硬金屬組合物總重量的9.5 %至69.5 %。 148. 如第140項所述之硬金屬組合物，其中該硼化物為Μ ο B 2且約佔該硬金屬組合物總重量的3 6 %至9 2.5 %， 1057D-6939-PF 69 .200535255 其中Re約佔該硬金屬組合物總重量的7·5%至64%。 149·如第140項所述之硬金屬組合物，其中該硼化物為WB且約佔該硬金屬組合物總重量的%至％%，其中 Re約佔該硬金屬組合物總重量的4%至47%。 150·如第140項所述之硬金屬組合物，其中該硼化物為W〗B且約佔該硬金屬組合物總重量的53%至96%，其中Re約佔該硬金屬組合物總重量的4%至47%。鲁 1 5 1 · 一種硬金屬組合物包括：包括至少一種梦化物的硬粒子’其中該石夕化物擇自由元素週期表中IVb、vb及VIb 族元素所形成的石夕化物；以及一包括Re且用來黏結硬粒子的黏結劑基質，其中Re約佔該硬金屬組合物總重量的6% 至 77%。 1 5 2 ·如第1 5 1項所述之硬金屬組合物，其中該石夕化物為Ti5Si3且約佔該硬金屬組合物總重量的23%至87%，其中Re約佔該硬金屬組合物總重量的13%至77%。 φ 1 53 ·如第1 5 1項所述之硬金屬組合物，其中該矽化物為Zr6Si5且約佔該硬金屬組合物總重量的28%至90%，其中Re約佔該硬金屬組合物總重量的1 〇%至72%。 1 54·如第1 5 1項所述之硬金屬組合物，其中該矽化物為NbSi2且約佔該硬金屬組合物總重量的3 1 %至9 1 %，其中Re約佔該硬金屬組合物總重量的9%至69%。 1 5 5 ·如第1 5 1項所述之硬金屬組合物，其中該矽化物為TaSi2且約佔該硬金屬組合物總重量的38%至93%，其中Re約佔該硬金屬組合物總重量的7%至62%。 1057D-6939-PF 70 200535255 1 5 6 ·如第1 5 1項所述之硬金屬組合物，其中該矽化物為MoSh且約佔該硬金屬組合物總重量的31%至91%，其中Re約佔該硬金屬組合物總重量的9%至69%。 157·如第151項所述之硬金屬組合物，其中該矽化物為WSh且約佔該硬金屬組合物總重量的40%至94%，其中Re約佔該硬金屬組合物總重量的6%至60%。139 · A hard metal composition includes: hard particles including Tic up to about 89% of the total weight of the hard metal composition, and hard particles including TiN up to about 90% of the total weight of the hard metal composition, including M 〇2C hard particles up to about 26% of the total weight of the hard metal composition, wc hard particles up to about 42% of the total weight of the hard metal composition, and hard particles including dinza up to about the hard metal 33% of the total weight of the composition, including hard particles of vc up to about 16% of the total weight of the hard metal composition, and hard particles including CqC3 up to about the total weight of the hard metal composition; and one containing Re, containing The nickel-based superalloy, a Ni-containing and a C0-containing binder matrix for bonding hard particles are up to about 63%, 39%, 42%, and 42% of the total weight of the hard metal composition, respectively. ~ 140 · —A hard metal composition includes: hard particles including at least one boride, wherein the boride is selected from the group consisting of ivb, vb, and group elements in the periodic table of elements; and a compound including Re and used for bonding A binder matrix of hard particles, in which Re accounts for about 々% of the total weight of the hard metal composition 1057D-693 9-PF 68 \ 200535255 to 76%. 141. The hard metal composition according to item 140, wherein the boride is TiB2 and accounts for about 24% to 87.5% of the total weight of the hard metal composition, wherein Re accounts for about 12.5 of the total weight of the hard metal composition % To 76%. 142. The hard metal composition according to item 140, wherein the boride is ZrB2 and accounts for about 30% to 90.5% of the total weight of the hard metal composition, wherein Re accounts for about 9.5 of the total weight of the hard metal composition % To 70%. 143. The hard metal composition according to item 140, wherein the boride spring is HfB2 and accounts for about 44.5% to 94.5% of the total weight of the hard metal composition, where Re accounts for about the total weight of the hard metal composition. 5.5% to 55.5%. 144. The hard metal composition according to item 140, wherein the boride is VB2 and accounts for about 27% to 89% of the total weight of the hard metal composition, wherein Re accounts for about 11% of the total weight of the hard metal composition % To 73%. 145. The hard metal composition according to item 140, wherein the boride is NbB2 and accounts for about 34% to 92% of the total weight of the hard metal composition, and Re is about 0% of the total weight of the hard metal composition. 8% to 66%. 146. The hard metal composition according to item 140, wherein the boride is TaB2 and accounts for about 47% to 95% of the total weight of the hard metal composition, and Re accounts for about 5% of the total weight of the hard metal composition. % To 53%. 147. The hard metal composition according to item 140, wherein the boride is Cr3B2 and accounts for about 30% to 90.5% of the total weight of the hard metal composition, and Re accounts for about 9.5 of the total weight of the hard metal composition. % To 69.5%. 148. The hard metal composition according to item 140, wherein the boride is Μ B 2 and accounts for about 36 to 9 2.5% of the total weight of the hard metal composition, 1057D-6939-PF 69 .200535255 Among them, Re accounts for about 7.5% to 64% of the total weight of the hard metal composition. 149. The hard metal composition according to item 140, wherein the boride is WB and accounts for about% to %% of the total weight of the hard metal composition, wherein Re accounts for about 4% of the total weight of the hard metal composition To 47%. 150. The hard metal composition according to item 140, wherein the boride is Wb and accounts for approximately 53% to 96% of the total weight of the hard metal composition, wherein Re accounts for approximately the total weight of the hard metal composition 4% to 47%. Lu 1 5 1 · A hard metal composition includes: hard particles including at least one dream compound 'where the stone compound is selected from the group consisting of elements IVb, vb, and VIb in the periodic table of elements; and a compound including Re The binder matrix used to bind hard particles, wherein Re accounts for about 6% to 77% of the total weight of the hard metal composition. 1 5 2 · The hard metal composition according to item 151, wherein the petrified compound is Ti5Si3 and accounts for about 23% to 87% of the total weight of the hard metal composition, wherein Re accounts for about the hard metal composition 13% to 77% of the total weight. φ 1 53. The hard metal composition according to item 151, wherein the silicide is Zr6Si5 and accounts for about 28% to 90% of the total weight of the hard metal composition, and Re accounts for about the hard metal composition. 10% to 72% of the total weight. 1 54. The hard metal composition according to item 151, wherein the silicide is NbSi2 and accounts for about 31% to 91% of the total weight of the hard metal composition, wherein Re accounts for about the hard metal combination. 9% to 69% of the total weight. 1 5 5 The hard metal composition according to item 151, wherein the silicide is TaSi2 and accounts for about 38% to 93% of the total weight of the hard metal composition, wherein Re accounts for about the hard metal composition. 7% to 62% of the total weight. 1057D-6939-PF 70 200535255 1 5 6 · The hard metal composition according to item 1 51, wherein the silicide is MoSh and accounts for about 31% to 91% of the total weight of the hard metal composition, where Re About 9% to 69% of the total weight of the hard metal composition. 157. The hard metal composition according to item 151, wherein the silicide is WSh and accounts for about 40% to 94% of the total weight of the hard metal composition, and Re accounts for about 6% of the total weight of the hard metal composition. % To 60%.

1 5 8 · —種硬金屬組合物包括··硬粒子；以及一包括W 且用來黏結硬粒子的黏結劑基質。 1 5 9 ·如第1 5 8項所述之硬金屬組合物，其中該硬粒子包括至少一種碳化物，其中該碳化物擇自由元素週期表中 IVb、Vb及VIb族元素所形成的碳化物，且其中W約佔該硬金屬組合物總重量的6%至77%。 160.如第159項所述之硬金屬組合物，其中該碳化物為TiC且約佔該硬金屬組合物總重量的28%至89%，其中 W約佔該硬金屬組合物總重量的1 1 %至72%。 1 6 1 ·如第1 5 9項所述之硬金屬組合物，其中該碳化物為ZrC且約佔該硬金屬組合物總重量的34%至92%，其中 W約佔該硬金屬組合物總重量的8%至66%。 1 62·如第1 59項所述之硬金屬組合物，其中該碳化物為HfC且約佔該硬金屬組合物總重量的50%至96%，其中 W約佔該硬金屬組合物總重量的4%至50%。 163·如第159項所述之硬金屬組合物，其中該碳化物為VC且約佔該硬金屬組合物總重量的30%至90%，其中 W約佔該硬金屬組合物總重量的1 〇%至70%。 1057D-6939-PF 71 200535255 1 64·如第1 59項所述之硬金屬組合物，其中該碳化物為NbC且約佔該硬金屬組合物總重量的38%至93%，其中W約佔該硬金屬組合物總重量的7%至62%。 165·如第159項所述之硬金屬組合物，其中該碳化物為TaC且約佔該硬金屬組合物總重量的53%至96%，其中 W約佔該硬金屬組合物總重量的4%至47%。 1 66·如第1 59項所述之硬金屬組合物，其中該碳化物為Ci*2C3且約佔該硬金屬組合物總重量的34%至92%，其中W約佔該硬金屬組合物總重量的8%至66%。 167.如第159項所述之硬金屬組合物，其中該碳化物為M〇2C且約佔該硬金屬組合物總重量的4 1 %至94%，其中W約佔該硬金屬組合物總重量的6%至59%。 1 6 8 ·如第1 5 9項所述之硬金屬組合物，其中該碳化物為WC且約佔該硬金屬組合物總重量的55%至96%，其中 W約佔該硬金屬組合物總重量的4%至45%。 169·如第158項所述之硬金屬組合物，其中該硬粒子包括至少一種氮化物，其中該氮化物擇自由元素週期表中 IVb及Vb族元素所形成的氮化物，且其中w約佔該硬金屬組合物總重量的4%至72%。 170·如第169項所述之硬金屬組合物，其中該氮化物為ΤιΝ且約佔該硬金屬組合物總重量的28%至89%，其中 w約佔該硬金屬組合物總重量的〖丨％至72%。 171.如第169項所述之硬金屬組合物，其中該氮化物為ZrN且約佔該硬金屬組合物總重量的36%至92%，其中1 5 8 A hard metal composition includes ... hard particles; and a binder matrix including W and used to bond the hard particles. 1 5 9 The hard metal composition according to item 158, wherein the hard particles include at least one carbide, and the carbide is selected from the group consisting of carbides of elements IVb, Vb and VIb in the periodic table of elements. And W is about 6% to 77% of the total weight of the hard metal composition. 160. The hard metal composition according to item 159, wherein the carbide is TiC and accounts for about 28% to 89% of the total weight of the hard metal composition, wherein W accounts for about 1% of the total weight of the hard metal composition. 1% to 72%. 1 6 1 · The hard metal composition according to item 159, wherein the carbide is ZrC and accounts for about 34% to 92% of the total weight of the hard metal composition, wherein W accounts for about the hard metal composition 8% to 66% of the total weight. 1 62. The hard metal composition according to item 1 59, wherein the carbide is HfC and accounts for about 50% to 96% of the total weight of the hard metal composition, wherein W accounts for about the total weight of the hard metal composition 4% to 50%. 163. The hard metal composition according to item 159, wherein the carbide is VC and accounts for about 30% to 90% of the total weight of the hard metal composition, wherein W accounts for about 1% of the total weight of the hard metal composition 〇% to 70%. 1057D-6939-PF 71 200535255 1 64 · The hard metal composition according to item 1 59, wherein the carbide is NbC and accounts for about 38% to 93% of the total weight of the hard metal composition, wherein W accounts for about The hard metal composition has a total weight of 7% to 62%. 165. The hard metal composition according to item 159, wherein the carbide is TaC and accounts for about 53% to 96% of the total weight of the hard metal composition, wherein W accounts for about 4% of the total weight of the hard metal composition % To 47%. 1 66. The hard metal composition according to item 1 59, wherein the carbide is Ci * 2C3 and accounts for about 34% to 92% of the total weight of the hard metal composition, wherein W accounts for about the hard metal composition 8% to 66% of the total weight. 167. The hard metal composition according to item 159, wherein the carbide is Mo 2 C and accounts for about 41% to 94% of the total weight of the hard metal composition, wherein W accounts for about the total weight of the hard metal composition 6% to 59% by weight. 1 6 8 · The hard metal composition according to item 159, wherein the carbide is WC and accounts for about 55% to 96% of the total weight of the hard metal composition, wherein W accounts for about the hard metal composition 4% to 45% of the total weight. 169. The hard metal composition according to item 158, wherein the hard particles include at least one nitride, wherein the nitride is selected from the group consisting of nitrides of groups IVb and Vb in the periodic table of elements, and wherein w is approximately 4% to 72% of the total weight of the hard metal composition. 170. The hard metal composition according to item 169, wherein the nitride is TiN and accounts for about 28% to 89% of the total weight of the hard metal composition, wherein w accounts for about 5% of the total weight of the hard metal composition.丨% to 72%. 171. The hard metal composition according to item 169, wherein the nitride is ZrN and comprises about 36% to 92% of the total weight of the hard metal composition, wherein

1057D-6939-PF 72 200535255 W約佔該硬金屬組合物總重量的8%至64% ^ 172·如第169項所述之硬金屬組合物，其中該氮化物為HfN且約佔該硬金屬組合物總重量的52%至96%，其中W約佔該硬金屬組合物總重量的至48%。 173·如第169項所述之硬金屬組合物，其中該氮化物為VN且約佔該硬金屬組合物總重量的3 2 %至9 1 %，其中 W約佔該硬金屬組合物總重量的9%至68%。 174·如第169項所述之硬金屬級合物，其中該氮化物為NbN且約佔該硬金屬組合物總重量的36%至％%，其中W約佔該硬金屬組合物總重量的8%至64%。 175·如第169項所述之硬金屬級合物，其中該氮化物為TaN且約佔該硬金屬組合物總重量的53%至％%，其中W約佔該硬金屬組合物總重量的4%至%。 176·如第158項所述之硬金屬級合物，其中該硬粒子包括至少一種棚化物’其中該棚化物擇自由元素週期表中 IVb及Vb族元素所形成的棚化物，且其中w約佔該硬金屬組合物總重量的3%至74%。 177.如苐176項所述之硬金屬組合物，其中該氮化物為TiB2且約佔該硬金屬組合物總重量的26%至88%，其中W約佔該硬金屬組合物總重量的12%至74%。 1 7 8 ·如第1 7 6項所述之硬金屬組合物，其中該氮化物為ZrB：2且約佔該硬金屬組合物總重量的32%至91%，其中W約、佔該硬金屬組合物總重量的9%至68%。 1 7 9 ·如第1 7 6項所述之硬金屬組合物，其中該氮化物 1057D-6939-PF 73 200535255 為HfB2且約佔該硬金屬組合物總重量的46%至95% ’其中W約佔該硬金屬組合物總重量的5%至54%。 180. 如第176項所述之硬金屬組合物，其中該氮化物為VB2且約佔該硬金屬組合物總重量的28%至90% ’其中 W約佔該硬金屬組合物總重量的1〇%至72%。 181. 如第176項所述之硬金屬組合物，其中該氮化物為NbB2且約佔該硬金屬組合物總重量的36%至92%，其中W約佔該硬金屬組合物總重量的8%至64%。 ⑩ 182.如第176項所述之硬金屬組合物，其中該氮化物為TaB2且約佔該硬金屬組合物總重量的49%至95%，其中W約佔該硬金屬組合物總重量的5%至5 1 %。 183. 如第176項所述之硬金屬組合物，其中該氮化物為C r 3 B 2且約佔該硬金屬組合物總重量的3 2 %至9 1 % ’其中W約佔該硬金屬組合物總重量的9%至68%。 184. 如第176項所述之硬金屬組合物，其中該氮化物 ^ 為MoB2且約佔該硬金屬組合物總重量的38%至93%，其中W約佔該硬金屬組合物總重量的7%至62%。 185·如第176項所述之硬金屬組合物，其中該氮化物為WB且約佔該硬金屬組合物總重量的55%至96%，其中 W約佔該硬金屬組合物總重量的4%至45%。 186.如第176項所述之硬金屬組合物，其中該氮化物為W2B且約佔該硬金屬組合物總重量的56%至97%，其中W約佔該硬金屬組合物總重量的3%至44%。 187·如第158項所述之硬金屬組合物，其中該硬粒子 1057D-6939-PF 74 200535255 包括至少一種矽化物，其中該矽化物擇自由元素週期表中 IVb及Vb族元素所形成的矽化物且其中w約佔該硬金屬組合物總重量的6%至75%。 1 8 8 ·如第1 8 7項所述之硬金屬組合物，其中該矽化物為T i5 S i3且約佔該硬金屬組合物總重量的2 5 %至8 8 %，其中W約佔該硬金屬組合物總重量的1 2 %至7 5 %。 189·如第187項所述之硬金屬組合物，其中該矽化物為 Zr6Si5且約佔該硬金屬組合物總重量的30%至90%，其中 W約佔該硬金屬組合物總重量的1 〇%至70%。 · 1 9 0 ·如第1 8 7項所述之硬金屬組合物，其中該石夕化物為Nb S i2且約佔該硬金屬組合物總重量的3 3 %至91 % ’其中W約佔該硬金屬組合物總重量的9 %至6 7 %。 191·如第187項所述之硬金屬組合物，其中該矽化物為TaSi2且約佔該硬金屬組合物總重量的40%至93%，其中W約佔該硬金屬組合物總重量的7%至60%。 I 192·如第187項所述之硬金屬組合物，其中該矽化物為MoSi2且約佔該硬金屬組合物總重量的3 1 %至9 1 %，其中W約佔該硬金屬組合物總重量的9%至67%。 193·如第187項所述之硬金屬組合物，其中該矽化物為WSi2且約佔該硬金屬組合物總重量的42 %至94%，其中W約佔該硬金屬組合物總重量的6%至58%。 1 94·如第1 5 8項所述之硬金屬組合物’其中黏結劑基質除W之外更進一步包括Re 1 95·如第1 94項所述之硬金屬組合物’其中該硬粒子 1057D-6939-PF 75 200535255 自由元素週期表中且其中Re低於約包括至少一種碳化物，其中該碳化物擇 IVb、Vb及VIb族元素所形成的碳化物該硬金屬組合物總重量的73%而W柄认』w低於約該硬金屬組合物總重量的72%。物，其中該碳化物 42% 至 94% 〇物，其中該碳化物1057D-6939-PF 72 200535255 W approximately 8% to 64% of the total weight of the hard metal composition ^ 172. The hard metal composition according to item 169, wherein the nitride is HfN and approximately accounts for the hard metal 52% to 96% of the total weight of the composition, wherein W accounts for about 48% of the total weight of the hard metal composition. 173. The hard metal composition according to item 169, wherein the nitride is VN and accounts for about 32% to 91% of the total weight of the hard metal composition, wherein W accounts for about the total weight of the hard metal composition 9% to 68%. 174. The hard metal grade according to item 169, wherein the nitride is NbN and accounts for about 36% to %% of the total weight of the hard metal composition, and W accounts for about 36% of the total weight of the hard metal composition. 8% to 64%. 175. The hard metal grade compound according to item 169, wherein the nitride is TaN and accounts for about 53% to %% of the total weight of the hard metal composition, wherein W accounts for about 5% of the total weight of the hard metal composition. 4% to%. 176. The hard metal grade composition according to item 158, wherein the hard particles include at least one kind of shed compound 'wherein the shed compound is selected from the group consisting of elements IVb and Vb in the periodic table of elements, and wherein w is about 3% to 74% of the total weight of the hard metal composition. 177. The hard metal composition according to item 176, wherein the nitride is TiB2 and accounts for about 26% to 88% of the total weight of the hard metal composition, wherein W accounts for about 12% of the total weight of the hard metal composition. % To 74%. 1 7 8 · The hard metal composition as described in item 176, wherein the nitride is ZrB: 2 and approximately 32% to 91% of the total weight of the hard metal composition, wherein W is approximately 9% to 68% of the total weight of the metal composition. 1 7 9 The hard metal composition according to item 176, wherein the nitride 1057D-6939-PF 73 200535255 is HfB2 and accounts for about 46% to 95% of the total weight of the hard metal composition. About 5% to 54% of the total weight of the hard metal composition. 180. The hard metal composition according to item 176, wherein the nitride is VB2 and accounts for about 28% to 90% of the total weight of the hard metal composition 'wherein W accounts for about 1% of the total weight of the hard metal composition 〇% to 72%. 181. The hard metal composition according to item 176, wherein the nitride is NbB2 and accounts for about 36% to 92% of the total weight of the hard metal composition, wherein W accounts for about 8% of the total weight of the hard metal composition % To 64%. 182. The hard metal composition according to item 176, wherein the nitride is TaB2 and accounts for about 49% to 95% of the total weight of the hard metal composition, wherein W accounts for about 5% of the total weight of the hard metal composition. 5% to 51%. 183. The hard metal composition according to item 176, wherein the nitride is C r 3 B 2 and accounts for about 3 2% to 9 1% of the total weight of the hard metal composition 'wherein W accounts for about the hard metal 9% to 68% of the total weight of the composition. 184. The hard metal composition according to item 176, wherein the nitride ^ is MoB2 and accounts for about 38% to 93% of the total weight of the hard metal composition, wherein W accounts for about 38% of the total weight of the hard metal composition. 7% to 62%. 185. The hard metal composition according to item 176, wherein the nitride is WB and accounts for about 55% to 96% of the total weight of the hard metal composition, wherein W accounts for about 4% of the total weight of the hard metal composition % To 45%. 186. The hard metal composition according to item 176, wherein the nitride is W2B and accounts for about 56% to 97% of the total weight of the hard metal composition, wherein W accounts for about 3% of the total weight of the hard metal composition % To 44%. 187. The hard metal composition according to item 158, wherein the hard particles 1057D-6939-PF 74 200535255 include at least one silicide, wherein the silicide is selected from the silicides formed by the elements of the IVb and Vb groups in the periodic table of elements. And wherein w is about 6% to 75% of the total weight of the hard metal composition. 1 8 8 The hard metal composition according to item 1 8 7, wherein the silicide is T i5 S i3 and accounts for about 25% to 88% of the total weight of the hard metal composition, wherein W accounts for about The hard metal composition has a total weight of 12% to 75%. 189. The hard metal composition according to item 187, wherein the silicide is Zr6Si5 and accounts for about 30% to 90% of the total weight of the hard metal composition, wherein W accounts for about 1% of the total weight of the hard metal composition 〇% to 70%. · 19 0 · The hard metal composition according to item 1 8 7, wherein the petrified compound is Nb S i2 and accounts for about 33% to 91% of the total weight of the hard metal composition. 9% to 67% of the total weight of the hard metal composition. 191. The hard metal composition according to item 187, wherein the silicide is TaSi2 and accounts for about 40% to 93% of the total weight of the hard metal composition, wherein W accounts for about 7% of the total weight of the hard metal composition % To 60%. I 192. The hard metal composition according to item 187, wherein the silicide is MoSi2 and accounts for about 31% to 91% of the total weight of the hard metal composition, wherein W accounts for about the total weight of the hard metal composition 9% to 67% by weight. 193. The hard metal composition according to item 187, wherein the silicide is WSi2 and accounts for about 42% to 94% of the total weight of the hard metal composition, wherein W accounts for about 6% of the total weight of the hard metal composition % To 58%. 1 94. The hard metal composition according to item 158, wherein the binder matrix further includes W in addition to W 1 95. The hard metal composition according to item 1 94, wherein the hard particles are 1057D -6939-PF 75 200535255 in the periodic table of free elements and where Re is less than about at least one carbide, wherein the carbide is selected from the group consisting of IVb, Vb and VIb elements 73% of the total weight of the hard metal composition W is considered to be less than about 72% of the total weight of the hard metal composition. Material, wherein the carbide is 42% to 94% 〇 material, wherein the carbide

為 196·如第195項所述之硬金屬組合 T i C且約佔該硬金屬組合物總重量的 197·如第195項所述之硬金屬組合196 The hard metal combination T i C according to item 195 and approximately 197 of the total weight of the hard metal composition 197 The hard metal combination according to item 195

ZrC且約佔該硬金屬組合物總重量的32%至92% 198.如第195項所述之硬金屬組合物，其中該碳化物為H fC且約佔該硬金屬組合物總重量的* § %至9 5 %。 199·如第195項所述之硬金屬組合物，其中該碳化物為VC且約佔該硬金屬組合物總重量的28%至9〇%。 200·如第195項所述之硬金屬組合物，其中該碳化物為NbC且約佔該硬金屬組合物總重量的36%至93%。 201·如第195項所述之硬金屬組合物，其中該碳化物為TaC且約佔該硬金屬組合物總重量的5 1 %至96%。 2 0 2.如第1 9 5項所述之硬金屬組合物，其中該碳化物為ChC3且約佔該硬金屬組合物總重量的32%至92%。 203·如第195項所述之硬金屬組合物，其中該碳化物為Mc^C且約佔該硬金屬組合物總重量的39%至94%。 204·如第195項所述之硬金屬組合物，其中該碳化物為WC且約佔該硬金屬組合物總重量的53%至96%。 205·如第1 94項所述之硬金屬組合物，其中該硬粒子包括至少一種氮化物，其中該氮化物擇自由元素週期表中 1057D-6939-PF 76 200535255 IVb及Vb族元素所形成的氮化物，且其中Re低於約該硬金屬組合物總重量的7 1 %而W低於約該硬金屬組合物總重量的70%。 206·如第205項所述之硬金屬組合物，其中該氮化物為ΤιΝ且約佔該硬金屬組合物總重量的28%至9〇%。 207·如第205項所述之硬金屬組合物，其中該氮化物為ZrN且約佔該硬金屬組合物總重量的34%至。 208·如第205項所述之硬金屬組合物，其中該氮化物為HfN且約佔該硬金屬組合物總重量的5〇%至。 2 0 9 ·如弟2 0 5項所述之硬金屬組合物，其中該氮化物為VN且約佔該硬金屬組合物總重量的川％至9 1 %。 210·如第205項所述之硬金屬組合物，其中該氮化物為NbN且約佔該硬金屬組合物總重量的35%至92%。 2 1 1 ·如第205項所述之硬金屬組合物，其中該氮化物為TaN且約佔該硬金屬組合物總重量的51%至。 φ 212·如第194項所述之硬金屬組合物，其中該硬粒子包括至少一種爛化物，其中該侧化物擇自由元素週期表第 4第、5及第6行元素所形成的硼化物，且其中低於約該硬金屬組合物總重量的75%而W低於約該硬金屬組合物總重量的73%。 213.如第212項所述之硬金屬組合物，其中該硼化物為TiB2且約佔該硬金屬組合物總重量的μ%至μ%。 2 14 ·如第2 12項所述之硬金屬組合物，其中該硼化物為ZrB2且約佔該硬金屬組合物總重量的3 〇%至9 1 %。 1057D-6939-PF 77 2〇0535255 2 1 5 ·如第2 1 2項所述之硬金屬組合物，其中該硼化物為HfB2且約佔該硬金屬組合物總重量的24%至88%。 215A·如第212項所述之硬金屬組合物，其中該硼化物為VB2且約佔該硬金屬組合物總重量的27%至90%。 2 1 6 ·如第2 1 2項所述之硬金屬組合物，其中該硼化物為NbB2且約佔該硬金屬組合物總重量的34%至92%。 217·如第212項所述之硬金屬組合物，其中該硼化物為TaB2且約佔該硬金屬組合物總重量的47%至96%。 218·如第212項所述之硬金屬組合物，其中該硼化物為Cr3B2且約佔該硬金屬組合物總重量的32%至91%。 219·如第212項所述之硬金屬組合物，其中該硼化物為MoB2且約佔該硬金屬組合物總重量的36%至93%。 220.如第212項所述之硬金屬組合物，其中該硼化物為WB且約佔該硬金屬組合物總重量的53%至96%。 22 1 ·如第2 1 2項所述之硬金屬組合物，其中該硼化物為W〗B且約佔該硬金屬組合物總重量的54%至97%。 2 2 2 ·如第1 9 4項所述之硬金屬組合物，其中該硬粒子包括至少一種矽化物，其中該矽化物擇自由元素週期表中 ivb、vb及vib族元素所形成的矽化物，且其中Re低於約該硬金屬組合物總重量的76%而W低於約該硬金屬組合物總重量的74%。為滋如第222項所述之硬金屬組合物，其中該石夕化物 Tissi3且約佔該硬金屬組合物總重量的24%至。其中該矽化物 224·如第222項所述之硬金屬組合物 1057D-6939-PF 78 200535255 為ThSi3且約佔該硬金屬組合物總重量的24%至88%。 2 2 5 ·如弟2 2 2項所述之硬金屬組合物，其中該碎化物為Nb S h且約佔該硬金屬組合物總重量的3 1 %至9 1 %。 226·如第222項所述之硬金屬組合物，其中該矽化物為T a S i2且約佔該硬金屬組合物總重量的3 1 %至9 3 %。 227·如第222項所述之硬金屬組合物，其中該矽化物為MoSh且約佔該硬金屬組合物總重量的3 1 %至91 %。籲、228.如第222項所述之硬金屬組合物，其中該矽化物為NbSi2且約佔該硬金屬組合物總重量的4〇%至94%。 229· —種硬金屬組合物包括：包括至少一種氮化物的硬粒子’其中該氮化物擇自由元素週期表中IVb及vb族元素所形成的氮化物；以及一包括Re及Co且用來黏結硬粒子的黏結劑基質，其中Re低於約該硬金屬組合物總重量的71%而Co低於約該硬金屬組合物總重量的52%。 230·如第229項所述之硬金屬組合物，其中該氮化物鲁為TiN且約佔該硬金屬組合物總重量的28 %至95 %。 23 1 ·如第229項所述之硬金屬組合物，其中該氣化物為ZrN且約佔該硬金屬組合物總重量的34%至96%。 23 2·如第229項所述之硬金屬組合物，其中該氮化物為HfN且約佔該硬金屬組合物總重量的50%至98%。 233·如第229項所述之硬金屬組合物，其中該氮化物為VN且約佔該硬金屬組合物總重量的30%至96%。 23 4·如第229項所述之硬金屬組合物，其中該氮化物為NbN且約佔該硬金屬組合物總重量的34%至96%。 1057D-6939-PF 79 200535255 235·如第229項所述之硬金屬組合物，其中該氮化物為TaN且約佔該硬金屬組合物總重量的5 1 %至98 %。 236· —種硬金屬組合物包括：包括至少一種硼化物的硬粒子，其中該硼化物擇自由元素週期表中IVb、vb及VI b 族元素所形成的硼化物；以及一包括Re& 且用來黏結硬粒子的黏結劑基質，其中Re低於約該硬金屬組合物總重量的75%而Co低於約該硬金屬組合物總重量的。 237.如第236項所述之硬金屬級合物，其中該硼化物為ΤιΒ2且約佔該硬金屬組合物總重量的24%至34%。 238·如第236項所述之硬金屬魬合物，其中該硼化物為ZrB2且約佔该硬金屬組合物總重量的3 %至96%。 239·如第236項所述之硬金屬、纟且合物，其中該硼化物為HfB2且約佔該硬金屬組合物總重量的45%至98%。 240.如第236項所述之硬金屬、纟且合物，其中該硼化物為VB2且約佔該硬金屬組合物總重量的π%至95%。 24 1 ·如第236項所述之硬金屬、纟且合物，其中該棚化物為NbB2且約佔該硬金屬組合物總重量的34%至96%。 242.如第236項所述之硬金屬、纟且合物，其中該硼化物為TaB2且約佔該硬金屬組合物總重量的* 8 %至9 8 %。 243 ·如第236項所述之硬金屬挺合物，其中該糊化物為C r3 B2且約佔該硬金屬組合物總重量的3 〇 %至9 6 %。 244.如第236項所述之硬金屬、纟且合物，其中該棚化物為MoB2且約佔該硬金屬組合物總重量的36%至97%。 2 4 5 ·如第2 3 6項所述之硬金屬、纟且合物，其中該棚化物 l〇57D-6939-PF 80 200535255 為WB且約佔該硬金屬組合物總重量的5 3 %至9 8 %。 246·如第236項所述之硬金屬組合物，其中該硼化物為W2B且約佔該硬金屬組合物總重量的5 5 %至98%。 247. —種硬金屬組合物包括：包括至少一種矽化物的硬粒子’其中該矽化物擇自由元素週期表中IVb及Vb族疋素所形成的矽化物；以及一包括Re及Co且用來黏結硬粒子的黏結劑基質，其中Re低於約該硬金屬組合物總重量 • 的76%而Co低於約該硬金屬組合物總重量的57%。 248. 如第247項所述之硬金屬組合物，其中該矽化物為Ti5Sh且約佔該硬金屬組合物總重量的24%至94%。 249·如第247項所述之硬金屬組合物，其中該石夕化物為Zr0Si3且約佔該硬金屬組合物總重量的28%至95%。 250.如第247項所述之硬金屬組合物，其中該矽化物為NbSk且約佔該硬金屬組合物總重量的31%至96%。 φ 25 1.如第247項所述之硬金屬組合物，其中該矽化物為TaSh且約佔該硬金屬組合物總重量的38%至97%。 252.如第247項所述之硬金屬組合物，其中該石夕化物為Mo Si?且約佔該硬金屬組合物總重量的3 1 %至96%。 253 ·如第247項所述之硬金屬組合物，其中該矽化物為WSi2且約佔該硬金屬組合物總重量的4〇%至97%。 254· —種硬金屬組合物包括··包括至少一種碳化物的硬粒子，其中該碳化物擇自由元素週期表中ivb、Vb及VIb 族元素所形成的碳化物；以及一包括及Mo且用來黏結ZrC and about 32% to 92% of the total weight of the hard metal composition 198. The hard metal composition according to item 195, wherein the carbide is H fC and accounts for about * of the total weight of the hard metal composition * §% to 95%. 199. The hard metal composition according to item 195, wherein the carbide is VC and accounts for about 28% to 90% of the total weight of the hard metal composition. 200. The hard metal composition according to item 195, wherein the carbide is NbC and accounts for about 36% to 93% of the total weight of the hard metal composition. 201. The hard metal composition according to item 195, wherein the carbide is TaC and accounts for about 51 to 96% of the total weight of the hard metal composition. 2 0 2. The hard metal composition according to item 195, wherein the carbide is ChC3 and accounts for about 32% to 92% of the total weight of the hard metal composition. 203. The hard metal composition according to item 195, wherein the carbide is Mc ^ C and accounts for about 39% to 94% of the total weight of the hard metal composition. 204. The hard metal composition according to item 195, wherein the carbide is WC and accounts for about 53% to 96% of the total weight of the hard metal composition. 205. The hard metal composition according to item 1 94, wherein the hard particles include at least one nitride, wherein the nitride is selected from the group consisting of elements 1057D-6939-PF 76 200535255 in the Periodic Table of Freedoms and Group Vb A nitride, and wherein Re is less than about 71% of the total weight of the hard metal composition and W is less than about 70% of the total weight of the hard metal composition. 206. The hard metal composition according to item 205, wherein the nitride is TiN and accounts for about 28% to 90% of the total weight of the hard metal composition. 207. The hard metal composition according to item 205, wherein the nitride is ZrN and accounts for about 34% by weight of the total weight of the hard metal composition. 208. The hard metal composition according to item 205, wherein the nitride is HfN and comprises about 50% to about 50% by weight of the total weight of the hard metal composition. 209. The hard metal composition as described in item 205, wherein the nitride is VN and accounts for approximately 5% to 91% of the total weight of the hard metal composition. 210. The hard metal composition according to item 205, wherein the nitride is NbN and accounts for about 35% to 92% of the total weight of the hard metal composition. 2 1 1 The hard metal composition according to item 205, wherein the nitride is TaN and accounts for about 51% by weight of the total weight of the hard metal composition. φ 212. The hard metal composition according to item 194, wherein the hard particles include at least one rotten compound, and the pendant compound is a boride formed from elements in lines 4, 5, and 6 of the periodic table of elements, And it is less than about 75% of the total weight of the hard metal composition and W is less than about 73% of the total weight of the hard metal composition. 213. The hard metal composition according to item 212, wherein the boride is TiB2 and accounts for about μ% to μ% of the total weight of the hard metal composition. 2 14 · The hard metal composition according to item 2 12 wherein the boride is ZrB2 and accounts for about 30% to 91% of the total weight of the hard metal composition. 1057D-6939-PF 77 205035255 2 1 5 The hard metal composition according to item 2 12 wherein the boride is HfB2 and accounts for about 24% to 88% of the total weight of the hard metal composition. 215A. The hard metal composition according to item 212, wherein the boron compound is VB2 and accounts for about 27% to 90% of the total weight of the hard metal composition. 2 1 6 The hard metal composition according to item 2 12 wherein the boride is NbB2 and accounts for about 34% to 92% of the total weight of the hard metal composition. 217. The hard metal composition according to item 212, wherein the boride is TaB2 and accounts for about 47% to 96% of the total weight of the hard metal composition. 218. The hard metal composition according to item 212, wherein the boride is Cr3B2 and accounts for about 32% to 91% of the total weight of the hard metal composition. 219. The hard metal composition according to item 212, wherein the boride is MoB2 and accounts for about 36% to 93% of the total weight of the hard metal composition. 220. The hard metal composition according to item 212, wherein the boride is WB and accounts for about 53% to 96% of the total weight of the hard metal composition. 22 1 · The hard metal composition according to item 21, wherein the boride is WB and accounts for about 54% to 97% of the total weight of the hard metal composition. 2 2 2 The hard metal composition according to item 194, wherein the hard particles include at least one silicide, and the silicide is selected from silicides formed by elements of the ivb, vb, and vib groups in the periodic table of elements. And wherein Re is less than about 76% of the total weight of the hard metal composition and W is less than about 74% of the total weight of the hard metal composition. For the hard metal composition as described in item 222, wherein the petrified compound Tissi3 is about 24% to the total weight of the hard metal composition. The silicide 224 · The hard metal composition 1057D-6939-PF 78 200535255 according to item 222 is ThSi3 and accounts for about 24% to 88% of the total weight of the hard metal composition. 2 2 5 The hard metal composition according to item 22, wherein the crushed product is NbS h and accounts for about 31% to 91% of the total weight of the hard metal composition. 226. The hard metal composition according to item 222, wherein the silicide is Ta Si 2 and accounts for about 31% to 93% of the total weight of the hard metal composition. 227. The hard metal composition according to item 222, wherein the silicide is MoSh and accounts for about 31% to 91% of the total weight of the hard metal composition. 228. The hard metal composition according to item 222, wherein the silicide is NbSi2 and accounts for about 40% to 94% of the total weight of the hard metal composition. 229 · A hard metal composition includes: hard particles including at least one nitride 'wherein the nitride is selected from the group consisting of IVb and vb elements in the periodic table of elements; and a nitride including Re and Co for bonding A binder matrix of hard particles, where Re is less than about 71% of the total weight of the hard metal composition and Co is less than about 52% of the total weight of the hard metal composition. 230. The hard metal composition according to item 229, wherein the nitride Lu is TiN and accounts for about 28% to 95% of the total weight of the hard metal composition. 23 1 The hard metal composition according to item 229, wherein the gaseous substance is ZrN and accounts for about 34% to 96% of the total weight of the hard metal composition. 23 2. The hard metal composition according to item 229, wherein the nitride is HfN and accounts for about 50% to 98% of the total weight of the hard metal composition. 233. The hard metal composition according to item 229, wherein the nitride is VN and accounts for about 30% to 96% of the total weight of the hard metal composition. 23 4. The hard metal composition according to item 229, wherein the nitride is NbN and accounts for about 34% to 96% of the total weight of the hard metal composition. 1057D-6939-PF 79 200535255 235. The hard metal composition according to item 229, wherein the nitride is TaN and accounts for about 51 to 98% of the total weight of the hard metal composition. 236. A hard metal composition includes: hard particles including at least one boride, wherein the boride is selected from the group consisting of elements IVb, vb, and VI b in the periodic table of elements; and a compound including Re & A binder matrix to bind hard particles, where Re is less than about 75% of the total weight of the hard metal composition and Co is less than about 75% of the total weight of the hard metal composition. 237. The hard metal grade compound according to item 236, wherein the boride is TiB2 and accounts for about 24% to 34% of the total weight of the hard metal composition. 238. The hard metal complex according to item 236, wherein the boride is ZrB2 and accounts for about 3% to 96% of the total weight of the hard metal composition. 239. The hard metal, fluorene complex according to item 236, wherein the boride is HfB2 and accounts for about 45% to 98% of the total weight of the hard metal composition. 240. The hard metal, hafnium complex according to item 236, wherein the boride is VB2 and accounts for about π% to 95% of the total weight of the hard metal composition. 24 1-The hard metal and the complex as described in item 236, wherein the shelf compound is NbB2 and accounts for about 34% to 96% of the total weight of the hard metal composition. 242. The hard metal, fluorene complex according to item 236, wherein the boride is TaB2 and accounts for about 8% to 98% of the total weight of the hard metal composition. 243. The hard metal riser according to item 236, wherein the paste is C r3 B2 and accounts for about 30% to 96% of the total weight of the hard metal composition. 244. The hard metal, fluorene compound as described in item 236, wherein the compound is MoB2 and accounts for about 36% to 97% of the total weight of the hard metal composition. 2 4 5 · The hard metal and the complex as described in item 2 36, wherein the shelf compound 1057D-6939-PF 80 200535255 is WB and accounts for about 53% of the total weight of the hard metal composition To 98%. 246. The hard metal composition according to item 236, wherein the boride is W2B and accounts for about 55 to 98% of the total weight of the hard metal composition. 247. A hard metal composition includes: hard particles including at least one silicide 'wherein the silicide is selected from silicides formed by elements IVb and Vb in the periodic table of elements; and A binder matrix that bonds hard particles, where Re is less than about 76% of the total weight of the hard metal composition and Co is less than about 57% of the total weight of the hard metal composition. 248. The hard metal composition according to item 247, wherein the silicide is Ti5Sh and accounts for about 24% to 94% of the total weight of the hard metal composition. 249. The hard metal composition according to item 247, wherein the petrified compound is Zr0Si3 and accounts for about 28% to 95% of the total weight of the hard metal composition. 250. The hard metal composition according to item 247, wherein the silicide is NbSk and accounts for about 31% to 96% of the total weight of the hard metal composition. φ 25 1. The hard metal composition according to item 247, wherein the silicide is TaSh and accounts for about 38% to 97% of the total weight of the hard metal composition. 252. The hard metal composition according to item 247, wherein the petrified compound is Mo Si? And accounts for about 31% to 96% of the total weight of the hard metal composition. 253. The hard metal composition according to item 247, wherein the silicide is WSi2 and accounts for about 40% to 97% of the total weight of the hard metal composition. 254. A hard metal composition includes hard particles including at least one carbide, wherein the carbide is selected from carbides of elements ivb, Vb and VIb in the periodic table of elements; and To bond

1057D-6939-PF 81 200535255 硬粒子的黏結劑基質，其中Re低於約該硬金屬組合物總重量的74%而Mo低於約該硬金屬組合物總重量的57%。 255·如第254項所述之硬金屬組合物，其中該碳化物為TiC且約佔該硬金屬組合物總重量的26%至94%。 256.如苐254項所述之硬金屬組合物，其中該碳化物為ZrC且約佔該硬金屬組合物總重量的32%至95%。 257·如第254項所述之硬金屬組合物，其中該碳化物 _ 為HfC且約佔該硬金屬組合物總重量的48%至98%。 2 5 8 ·如第2 5 4項所述之硬金屬組合物，其中該碳化物為V C且約佔該硬金屬組合物總重量的2 8 %至9 5 %。 25 9.如第254項所述之硬金屬組合物，其中該碳化物為NbC且約佔該硬金屬組合物總重量的36%至98%。 260·如第254項所述之硬金屬組合物，其中該碳化物為TaC且約佔該硬金屬組合物總重量的5 1 %至98%。 261.如第254項所述之硬金屬組合物，其中該碳化物 _ 為Cr2C3且約佔該硬金屬組合物總重量的32%至95%。 262·如第254項所述之硬金屬組合物，其中該碳化物為Μοβ且約佔該硬金屬組合物總重量的40%至97%。 263·如第254項所述之硬金屬組合物，其中該碳化物為WC且約佔該硬金屬組合物總重量的53%至98%。 264· —種硬金屬組合物包括：包括至少一種碳化物的硬粒子，其中該碳化物擇自由元素週期表中jVb、Vb及vib 族元素所形成的碳化物；以及一包括Re及Ni且用來黏結硬粒子的黏結劑基質，其中Re低於約該硬金屬組合物總重 PF 1057D—6939- 82 200535255 量的74%而Ni低於約該硬金屬組合物總重量的54%。 265. 如第264項所述之硬金屬組合物，其中該碳化物為TiC且約佔該硬金屬組合物總重量的26%至95%。 266. 如第264項所述之硬金屬組合物，其中該碳化物為ZrC且約佔該硬金屬組合物總重量的32%至96%。 267·如第264項所述之硬金屬組合物，其中該碳化物為HfC且約佔該硬金屬組合物總重量的48 %至98 %。 ^ 268 ·如第264項所述之硬金屬組合物，其中該碳化物為VC且約佔該硬金屬組合物總重量的28%至95%。 269.如第264項所述之硬金屬組合物，其中該碳化物為Nbc且約佔該硬金屬組合物總重量的36%至97%。 270·如第264項所述之硬金屬組合物，其中該碳化物為TaC且約佔該硬金屬組合物總重量的5丨％至9 8 %。 271 ·如第264項所述之硬金屬組合物，其中該碳化物為Cr2C3且約佔該硬金屬組合物總重量的至96%。 φ 272·如第264項所述之硬金屬組合物，其中該碳化物為MoC且約佔該硬金屬組合物總重量的至97%。 273.如第264項所述之硬金屬組合物，其中該碳化物為WC且約佔該硬金屬組合物總重量的5 3 %至98 %。1057D-6939-PF 81 200535255 A binder matrix of hard particles in which Re is less than about 74% of the total weight of the hard metal composition and Mo is less than about 57% of the total weight of the hard metal composition. 255. The hard metal composition according to item 254, wherein the carbide is TiC and accounts for about 26% to 94% of the total weight of the hard metal composition. 256. The hard metal composition according to item 254, wherein the carbide is ZrC and accounts for about 32% to 95% of the total weight of the hard metal composition. 257. The hard metal composition according to item 254, wherein the carbide _ is HfC and accounts for about 48% to 98% of the total weight of the hard metal composition. 2 5 8 The hard metal composition according to item 2 54, wherein the carbide is V C and accounts for about 28% to 95% of the total weight of the hard metal composition. 25 9. The hard metal composition according to item 254, wherein the carbide is NbC and accounts for about 36% to 98% of the total weight of the hard metal composition. 260. The hard metal composition according to item 254, wherein the carbide is TaC and accounts for about 51 to 98% of the total weight of the hard metal composition. 261. The hard metal composition according to item 254, wherein the carbide _ is Cr2C3 and accounts for about 32% to 95% of the total weight of the hard metal composition. 262. The hard metal composition according to item 254, wherein the carbide is Μβ and accounts for about 40% to 97% of the total weight of the hard metal composition. 263. The hard metal composition according to item 254, wherein the carbide is WC and accounts for about 53% to 98% of the total weight of the hard metal composition. 264 · A hard metal composition includes: hard particles including at least one carbide, wherein the carbide is selected from carbides formed by elements of the jVb, Vb, and vib groups in the periodic table; The binder matrix to bind hard particles, where Re is less than about 74% of the total weight of the hard metal composition PF 1057D-6939-82 200535255 and Ni is less than about 54% of the total weight of the hard metal composition. 265. The hard metal composition according to item 264, wherein the carbide is TiC and accounts for about 26% to 95% of the total weight of the hard metal composition. 266. The hard metal composition according to item 264, wherein the carbide is ZrC and accounts for about 32% to 96% of the total weight of the hard metal composition. 267. The hard metal composition according to item 264, wherein the carbide is HfC and accounts for about 48% to 98% of the total weight of the hard metal composition. 268. The hard metal composition according to item 264, wherein the carbide is VC and accounts for about 28% to 95% of the total weight of the hard metal composition. 269. The hard metal composition according to item 264, wherein the carbide is Nbc and accounts for about 36% to 97% of the total weight of the hard metal composition. 270. The hard metal composition according to item 264, wherein the carbide is TaC and accounts for about 5 to 98% of the total weight of the hard metal composition. 271. The hard metal composition according to item 264, wherein the carbide is Cr2C3 and accounts for about 96% of the total weight of the hard metal composition. φ 272. The hard metal composition according to item 264, wherein the carbide is MoC and accounts for about 97% of the total weight of the hard metal composition. 273. The hard metal composition according to item 264, wherein the carbide is WC and accounts for about 53% to 98% of the total weight of the hard metal composition.

274· —種硬金屬組合物包括：包括至少一種碳化物的硬粒子，其中該碳化物擇自由元素週期表中j vb、vb及族元素所形成的碳化物；以及一包括以及沁且用來黏結 =粒子的黏結劑基質，其中Re低於約該硬金屬組合物總重量的74%而Cr低於約該硬金屬組合物總重量的。 1057D-6939-PF 83 %\200535255 275·如第274項所述之硬金屬組合物，其中該碳化物為TiC且約佔該硬金屬組合物總重量的26%至96% ° 276·如第264項所述之硬金屬組合物，其中該碳化物為ZrC且約佔該硬金屬組合物總重量的32%至97%。 277.如第264項所述之硬金屬組合物，其中該碳化物為HfC且約佔該硬金屬組合物總重量的48%至98%。 278·如第264項所述之硬金屬組合物，其中該碳化物為VC且約佔該硬金屬組合物總重量的28%至95%。 279·如第264項所述之硬金屬組合物，其中該碳化物為NbC且約佔該硬金屬組合物總重量的36%至97%。 280·如第264項所述之硬金屬組合物，其中該碳化物為TaC且約佔該硬金屬組合物總重量的51%至98%。 28 1 ·如第264項所述之硬金屬組合物，其中該碳化物為ChC3且約佔該硬金屬組合物總重量的32%至97%。 282·如第264項所述之硬金屬組合物，其中該碳化物為M〇2C且約佔該硬金屬組合物總重量的40%至98%。 2 83·如第264項所述之硬金屬組合物，其中該碳化物為WC且約佔該硬金屬組合物總重量的53%至98 6%。 284· —種硬金屬組合物的製造方法，包括：預備一金屬表面’接著進行一熱噴塗製程將一層硬金屬層塗佈在金屬表面上，其中該硬金屬層包括：至少包括碳化物、氮化物、侧化物或矽化物的硬粒子；以及一至少包括Re且用來黏結硬粒子的黏結劑基質。 285 · —種硬金屬組合物的製造方法，包括：預備一金274 · A hard metal composition includes: hard particles including at least one carbide, wherein the carbide is selected from the carbides formed by j vb, vb, and group elements in the periodic table of elements; and Bonding = a binder matrix of particles, where Re is less than about 74% of the total weight of the hard metal composition and Cr is less than about 74% of the total weight of the hard metal composition. 1057D-6939-PF 83% \ 200535255 275. The hard metal composition according to item 274, wherein the carbide is TiC and accounts for about 26% to 96% of the total weight of the hard metal composition. The hard metal composition according to item 264, wherein the carbide is ZrC and accounts for about 32% to 97% of the total weight of the hard metal composition. 277. The hard metal composition according to item 264, wherein the carbide is HfC and accounts for about 48% to 98% of the total weight of the hard metal composition. 278. The hard metal composition according to item 264, wherein the carbide is VC and accounts for about 28% to 95% of the total weight of the hard metal composition. 279. The hard metal composition according to item 264, wherein the carbide is NbC and accounts for about 36% to 97% of the total weight of the hard metal composition. 280. The hard metal composition according to item 264, wherein the carbide is TaC and accounts for about 51% to 98% of the total weight of the hard metal composition. 28 1 The hard metal composition according to item 264, wherein the carbide is ChC3 and accounts for about 32% to 97% of the total weight of the hard metal composition. 282. The hard metal composition according to item 264, wherein the carbide is Mo 2 C and accounts for about 40% to 98% of the total weight of the hard metal composition. 2 83. The hard metal composition according to item 264, wherein the carbide is WC and accounts for about 53% to 986% of the total weight of the hard metal composition. 284 · —A method for manufacturing a hard metal composition, comprising: preparing a metal surface 'followed by a thermal spraying process to coat a hard metal layer on the metal surface, wherein the hard metal layer includes: at least carbide, nitrogen Hard particles of compounds, pendants, or silicides; and a binder matrix including at least Re and used to bond the hard particles. 285 · A method for manufacturing a hard metal composition, including: preparing a gold

1057D-6939--PF 84 200535255 屬表面，接著進行一熱喷塗製程將一層硬金屬層塗佈在金屬表面上，其中該硬金屬層包括：至少包括碳化物、氮化物、棚化物或矽化物的硬粒子；以及一至少包括_錄基超合金且用來黏結硬粒子的黏結劑基質。 286· —種硬金屬組合物的製造方法，包括··預備一金屬表面，接著進行一熱喷塗製程將一層硬金屬層塗佈在金屬表面上，其中該硬金屬層包括：至少包括碳化物、氮化物、删化物或矽化物的硬粒子；以及一至少包括w且用來黏結硬粒子的黏結劑基質。【實施方式】硬金屬材料的組成（c〇mp〇siti〇ns)會直接影響硬金屬的特性與應用成效，當然在製造中的製程條件與設備也會對其特性成效有影響。還有，硬金屬材料的組成也會影響硬金屬原材的成本，並與製造成本相關。因此，找出經濟的硬金屬材料的組成，且又能具有良好的特性，乃是業界 φ亟需努力的課題。本案即提供一種新的硬金屬組合物，其具有特別選擇之黏結劑基質（bindermatrix)材料，並且具有提供優良特性的優點。本案的硬金屬組合物包含各種的硬粒子與各種的黏結片J基貝材料。一般來說，硬粒子可以是週期表巾、Μ 與VIB私之金屬凡素的碳化物，例如ivb之金屬碳化物有 TiC’ ZrC，HfC、VB之今屬石山几仏1057D-6939--PF 84 200535255 metal surface, followed by a thermal spraying process to coat a hard metal layer on the metal surface, where the hard metal layer includes: at least carbide, nitride, shed or silicide Hard particles; and a binder matrix including at least a superalloy and used to bond the hard particles. 286. A method for manufacturing a hard metal composition, including preparing a metal surface and then performing a thermal spraying process to coat a hard metal layer on the metal surface, wherein the hard metal layer includes: Hard particles of silicon, nitrides, compounds or silicides; and a binder matrix including at least w and used to bond the hard particles. [Embodiment] The composition of the hard metal material (c0mp〇sitiOns) will directly affect the properties and application effectiveness of the hard metal, of course, the process conditions and equipment in manufacturing will also affect its performance. In addition, the composition of hard metal materials also affects the cost of hard metal raw materials and is related to manufacturing costs. Therefore, finding out the composition of economic hard metal materials and having good characteristics is an urgent task for the industry. This case provides a new hard metal composition which has a binder matrix material specially selected and has the advantage of providing excellent characteristics. The hard metal composition of the present case contains various hard particles and various adhesive sheet J-based materials. In general, hard particles can be periodic table towels, metal carbides of M and VIB, for example, metal carbides of ivb include TiC ’ZrC, and HfC and VB belong to Shishan Jiuyi.

I 金屬 I化物有 VC，NbC，TaC、VIB 之金屬碳化物有Cr3C2，Mo，C Wr成， ’ 2L，WC。硬粒子也可以是週期表中IVB與VB族之今屬齐| 产、身屬素的氮化物，例如IVB之金屬氮I metal I compounds include VC, NbC, TaC, and VIB metal carbides include Cr3C2, Mo, C, Wr, ′ 2L, WC. Hard particles can also be present in the periodic table of the IVB and the VB group are homogeneous | product, element nitrides, such as the metal nitrogen of IVB

1057D-6939-PF 85 .200535255 化物有TiN，ZrN，HfN、VB之金屬氮化物有VN, NbN, TaN。其中，最被廣泛使用之硬粒子材料係碳化鎢，例如疋早原子〇0110)的Wc。許多氮化物可以與碳化物混合而形成硬粒子。亦即，上述的兩種或兩種以上或其他的碳化物與氮化物可以結合而形成wc基硬金屬或非wc基硬金屬。這裡要提醒的是，本案所述之不同碳化物的混合物係不僅限於wc和Tic的混合物、wc、Tic和TaC的混合物。除了不同的碳化物之外，氮化物碳氮化合物、领化物及石夕化物也可當作硬金屬組合物中的硬粒子，在本應用中會敛述各種不同適合的硬粒子。 ,,關於黏結劑基質的材料組成，除了提供一基質用以與粒子黏結在一起，也能夠有效地影響硬金屬的硬度與耐火性。一般來說’黏結劑基質可以包含_種或多種的週期表中第八列之過渡金屬，例如c〇，Ni，Fe;黏結劑基質也可以包含一種或多種的週期表中第6B列之過渡金屬，例如M。， J。上述的兩種或兩種以上或其他的黏結劑金屬可以混在起使用而形成所需要的黏結劑來黏結適當的硬粒子於一些黏結劑基質，例如使用具㈣與Mo的組合物。里里之Co, Nl 本案所提的硬金屬組合物係基於發 =特別的黏結劑基質材料，而能使本發明的心2 有良好的特性而忽：人隻屬具而付5不同應用之特別需求。特 :提：黏結劑基質材料對於硬金屬的特性有改。’例如彈性⑷aSticity)、剛性（rigidity)與強度參數 l〇57D~6939--pp 86 200535255 (strength parameters ’包含橫切破裂強度、拉伸強度與衝擊強度）。因此，發明者認定本發明所提出之硬金屬組合物中的特別的黏結劑基質材料，能夠改善材料特性而提升硬金屬的特性與效能。更特別的是，上述硬金屬組合物中的特別的黏結劑基質係包含Re、Ni基超合金或一種至少包含沁基超合金和其他黏結劑材料之-的組合物。其他合適的黏結劑材料可籲以f含’尤其是Re或Co。Ni基超合金在相當高溫下係具有高材料強度。由包含有以與Ni基超合金的黏結劑材料所組成之硬金屬“溫下可以具有冑的材料強《，且在高溫下可以展現優良的功效。除此之外，㈣超合金也展現對腐姓與氧化的優良抵抗性，如此，當採用基超合金當作是黏結劑材料時，能夠改善硬金屬的相關抵抗性。’ 本案的硬金屬組合物可以包含黏結劑基質材料係佔該硬金屬組合物總體積的3〜4〇體積％’而其相對應的硬粒子 φ所佔的體積㈣係97〜6G體積％。在上述的體積比率範圍中’黏結劑基質材料—般係佔該硬金屬組合物總體積的 4〜35體積％。最好是，黏結劑基質材料係佔該硬金屬组合物總體積的5〜3G體積^而該黏結劑基f材料佔該硬金屬1057D-6939-PF 85 .200535255 The compounds are TiN, ZrN, HfN, and VB. The metal nitrides are VN, NbN, TaN. Among them, the most widely used hard particle material is tungsten carbide, such as Wc of Isohaya. Many nitrides can be mixed with carbides to form hard particles. That is, the above-mentioned two or more or other carbides and nitrides may be combined to form a wc-based hard metal or a non-wc-based hard metal. It should be reminded here that the mixture of different carbides described in this case is not limited to the mixture of wc and Tic, the mixture of wc, Tic and TaC. In addition to different carbides, nitride carbonitrides, collar compounds, and stone compounds can also be used as hard particles in hard metal compositions. In this application, various suitable hard particles will be summarized. Regarding the material composition of the binder matrix, in addition to providing a matrix for bonding with the particles, it can also effectively affect the hardness and fire resistance of hard metals. Generally, the 'adhesive matrix' can contain one or more transition metals in the eighth column of the periodic table, such as c0, Ni, Fe; the adhesive matrix can also contain one or more transitions in column 6B of the periodic table. Metal, such as M. , J. The above two or more or other binder metals can be mixed and used to form the required binder to bond the appropriate hard particles to some binder matrix, for example, using a combination of rhenium and Mo. Li, Co, Nl The hard metal composition mentioned in this case is based on hair = a special binder matrix material, which can make the heart 2 of the present invention have good characteristics and ignore: people only have equipment and pay 5 different applications. Special needs. Features: Note: The properties of the binder matrix material have changed for hard metals. 'E.g. elasticity (aSticity), rigidity and strength parameters 〇57D ~ 6939--pp 86 200535255 (strength parameters ′ include transverse fracture strength, tensile strength and impact strength). Therefore, the inventors believe that the special binder matrix material in the hard metal composition proposed by the present invention can improve the properties of the material and enhance the properties and performance of the hard metal. More particularly, the particular binder matrix in the hard metal composition described above comprises Re, a Ni-based superalloy, or a composition containing at least one of a Qinky superalloy and other binder materials. Other suitable binder materials may be used to contain ', especially Re or Co. Ni-based superalloys have high material strength at relatively high temperatures. A hard metal composed of a binder material with a Ni-based superalloy "can have a strong material at high temperatures", and can exhibit excellent effects at high temperatures. In addition, rhenium superalloys also exhibit Corrosion resistance and oxidation resistance, so when the base superalloy is used as the binder material, it can improve the resistance of the hard metal. 'The hard metal composition of the present case may include a binder matrix material to account for the hard 3 ~ 40% by volume of the total volume of the metal composition 'and the volume occupied by the corresponding hard particles φ is 97 ~ 6G% by volume. In the above range of volume ratios,' the binder matrix material-generally accounts for the 4 ~ 35% by volume of the total volume of the hard metal composition. Preferably, the binder matrix material accounts for 5 ~ 3G volume of the total volume of the hard metal composition ^ and the binder-based f material accounts for the hard metal

組合物總重量的重晉石公μμ彳备W 里幻I里百刀比係可從該硬金屬組合物的特組合物導出。在許多實施例中，該黏結劑基質主要由Ni基超合金所構成’以及包含具有其他元素（例如Re，co，Ni,Fe,MO*The weight of the total weight of the composition can be derived from the special composition of the hard metal composition. In many embodiments, the binder matrix is mainly composed of a Ni-based superalloy ’and contains other elements such as Re, co, Ni, Fe, MO *

Cr)的仏基超合金的各種組合物。所希望的Ni基超合金除Cr) Various compositions of rhenium-based superalloys. Desired Ni-based superalloys

1057D-6939-PF 87 •200535255 了包含>^與（3〇，〇，八1，丁丨，]\4〇，\¥之外’也可更包含有丁&， Nb，B, Zr與C的其他元素。例如，Ni基超合金可以包含佔有該超合金該硬金屬組合物總重量之重量百分比的構成金屬：Ni 係 30〜70%，Cr 係 10〜30%，Co 係 0〜25%，A1 與 Ti 總量係4〜12%、Mo係〇〜1〇%、W係0〜10%、Ta係0〜10%、 Nb係0〜5%以及Hf係〇〜5%。Ni基超合金可更含有個別或雙方的Re和Hf，例如Re係0〜10%、Hf係0〜5%。具有 Re的Ni基超合金可以在高溫下被應用。Ni基超合金可更 ® 含有其他元素，例如少量的B，Zr與C。在某些應用中，TaC與NbC在一既定量下具有相似之性質，所以在硬金屬組合物中，TaC與NbC可以互相部分或全部取代對方。在某些硬金屬的設計中，HfC與NbC也可以互相部分或全部取代TaC。WC，TiC，TaC可以被單獨或混合地被製造於固溶的型式中。當一混合物被使用時，該混合物係從下列族群中至少選擇一種，即（1 )WC，TiC與 φ TaC的混合物，（2)WC，TiC與NbC的混合物，（3)WC，TiC 與至少TaC與NbC中之一的混合物，（句wc，Tic與至少 HfC與NbC中之一的混合物。多種碳化物的固溶體可以比 -些碳化物的混合物展現更好的特性和效能。因此，硬粒子k下列無群中至少選擇一種，即⑴WC，Tie與丁a。的體（2)WC，TiC與NbC的固溶體，⑺wc，Tic與至少1057D-6939-PF 87 • 200535255 contains> ^ and (3〇, 〇, 八 1, 丁丨,] \ 4〇, \ ¥ 'may also include D &, Nb, B, Zr And other elements of C. For example, a Ni-based superalloy may include a constituent metal occupying a weight percentage of the total weight of the hard metal composition of the superalloy: Ni-based 30 to 70%, Cr-based 10 to 30%, and Co-based 0 to The total amount of A1 and Ti is 4 to 12%, Mo is 0 to 10%, W is 0 to 10%, Ta is 0 to 10%, Nb is 0 to 5%, and Hf is 0 to 5%. Ni-based superalloys can further contain Re and Hf individually or both, for example, Re-based 0 ~ 10%, Hf-based 0 ~ 5%. Ni-based superalloys with Re can be applied at high temperatures. Ni-based superalloys can be more ® Contains other elements, such as a small amount of B, Zr, and C. In some applications, TaC and NbC have similar properties in a given amount, so in hard metal compositions, TaC and NbC can be partially or completely replaced with each other. Each other. In the design of some hard metals, HfC and NbC can also partially or completely replace TaC with each other. WC, TiC, TaC can be manufactured separately or mixed in a solid solution type. When a mixture When used, the mixture is selected from at least one of the following groups: (1) WC, a mixture of TiC and φ TaC, (2) WC, a mixture of TiC and NbC, (3) WC, TiC and at least TaC and NbC One of the mixtures, (sentence wc, a mixture of Tic and at least one of HfC and NbC. A solid solution of multiple carbides can exhibit better characteristics and efficiency than a mixture of some carbides. Therefore, hard particles k Select at least one of the following non-groups, that is, ⑴WC, Tie and Ding a. (2) WC, solid solution of TiC and NbC, ⑺wc, Tic and at least

TaC與NbC中之一的固、玄㉟ U /合體，（4)WC，TiC與至少HfC與One of TaC and NbC is solid or Xuanzang U / combined, (4) WC, TiC and at least HfC and

NbC中之一的固溶體。作為黏結劑材料的Ni基超合金可以是在γ·γ，相中，其One of the solid solutions of NbC. Ni-based superalloys as binder materials can be in the γ · γ phase, which

1057D-6939-PF •200535255 :二：結構的γ，相係與"g混合，且Ni基超在腐银與氧化的抵抗性也有报好的效果 = :分或全部取代在…。基黏結劑組合物中的c。二 Γ:ΓΓ，由於本案的硬金屬中的黏結劑基質中的1057D-6939-PF • 200535255: Two: The structure of γ, the phase system is mixed with " g, and the resistance of Ni-based super has a good effect on the resistance to rotten silver and oxidation =: points or all replaced in…. C in the base adhesive composition. Two Γ: ΓΓ, due to the

At ” 超合金可以有效地提升硬金屬在高溫下的效At ”super alloy can effectively improve the efficiency of hard metals at high temperatures

如由於有低Re的存在而使川基超合金能在較低溫、凡，、。ϋ而使製程能維持在合理的低溫下燒結而對製程有利。除此之外，黏結劑組合物中的相當低含量的Re，可降低黏結劑材料成本，而使這材料具有可行的經濟性。、，相對於黏結劑基質中的特別組成份的所有材料構成，上述Νι基超合金可以佔有數重量百分比到丄⑽重量％。典型的Ni基超合金可以纟γ·γ，相肖強狀態下主要包含錄與其他金屬元素，以致於隨著溫度提升而展現增強的強度。跟一般黏結劑材料Co相比，許多犯基超合金可具有比較低的熔點，該Ni基超合金例如是美國M=ais 公司製造的Rene_95, Udimet-700, Udimet-720，其主要包含 Ni 並結合 Co, Cr, Al，Ti，Mo, Nb，W，B 與 Zr。跟採用 Co 黏結劑的硬金屬比較的話，僅採用上述Ni基超合金的黏結劑材料不會增加所得的硬金屬之熔點。然而’在一實施例中’該Ni基超合金可以使用於黏結劑中而改善硬金屬在高溫下（約5〇〇t或以上）的材料硬度。跟不具有Ni基超合金於黏結劑中的硬金屬相比較，在測試許多試品（samples)之後，證實具有Ni基超合金於黏結 1057D-6939-PF 89 200535255 劑中的硬金屬的材料硬度和強度確實有明顯的改善，例如在低操作溫度下至少有1 〇%的改善。下表係顯示比較具有 Ni基超合金於黏結劑中的試品”P65”與”P46A”以及具有純 Co的黏結劑試品”P49”與” P47A”的硬度參數，其比較結果係顯示於表4。黏結劑中的Ni基超合金(簡稱：NS)的效果試品代號 Co 或 NS 黏結劑在室溫下的硬度 Hv(kg/mm2) 在室溫下的表面破裂韌性Ksc (*106Pa-m2) 比較結果 P49 Co ·' 10vol.% 2186 6.5 P65 NS ： 10vol.% 2532 6.7 Hv値大於P49約 16% P47A Co * 15vol.% 2160 6.4 P46A NS ： 15vol.% 2364 6.4 Ην値大於Ρ47Α約 10% 要注意的是，在500°C以上的操作高溫下，具有Ni基超合金於黏結劑中的硬金屬試品可以展現比不具有Ni基超合金於黏結劑中的硬金屬試品更高的材料硬度。除此之 • 外，跟使用Co作為黏結劑的傳統硬金屬或陶瓷金屬相比較，Ni基超合金的黏結劑材料也可以改善所得之硬金屬或陶甍金屬的对腐#性。For example, due to the presence of low Re, the Sichuan-based superalloy can be used at lower temperatures. ϋ It is beneficial to the process that the process can be sintered at a reasonable low temperature. In addition, the relatively low content of Re in the adhesive composition can reduce the cost of the adhesive material and make this material economically viable. With respect to the composition of all materials with special components in the binder matrix, the above-mentioned Ni-based superalloy can occupy several wt% to 丄 ⑽wt%. Typical Ni-based superalloys can be 纟 γ · γ. In the strong phase, they mainly contain other metal elements, so that they show enhanced strength with increasing temperature. Compared with the common binder material Co, many base-based superalloys can have relatively low melting points. The Ni-based superalloys are, for example, Rene_95, Udimet-700, Udimet-720 manufactured by the US company M = ais. They mainly contain Ni and Combining Co, Cr, Al, Ti, Mo, Nb, W, B and Zr. Compared with a hard metal using a Co binder, the binder material using only the above-mentioned Ni-based superalloy does not increase the melting point of the obtained hard metal. However, in one embodiment, the Ni-based superalloy can be used in a binder to improve the hardness of a hard metal at a high temperature (about 5,000 t or more). Compared with hard metals without Ni-based superalloys in the binder, after testing many samples, it was confirmed that the hardness of the hard metals with Ni-based superalloys in the binder 1057D-6939-PF 89 200535255 And the strength does have a noticeable improvement, such as at least 10% improvement at low operating temperatures. The following table shows the hardness parameters of the test samples "P65" and "P46A" with Ni-based superalloys in the binder and the test samples "P49" and "P47A" with the binder of pure Co. The comparison results are shown in Table 4. The effect of the Ni-based superalloy (abbreviation: NS) in the binder is Co or NS. The hardness Hv (kg / mm2) of the adhesive at room temperature and the surface fracture toughness Ksc (* 106Pa-m2) at room temperature. Comparison result P49 Co · '10vol.% 2186 6.5 P65 NS: 10vol.% 2532 6.7 Hv 値 is about 16% larger than P49 P47A Co * 15vol.% 2160 6.4 P46A NS: 15vol.% 2364 6.4 Ην 値 is larger than P47Α about 10% Note that at operating temperatures above 500 ° C, hard metal samples with Ni-based superalloys in the binder can exhibit higher materials than hard metal samples without Ni-based superalloys in the binder hardness. In addition to this, compared to traditional hard or ceramic metals using Co as a binder, Ni-based superalloy binder materials can also improve the corrosion resistance of the resulting hard or ceramic metals.

Ni基超合金可以獨自使用或與其他元素結合而製作想要的黏結劑基質。上述其他元素例如是Re，Co，Ni，Fe， Mo和Cf。Ni基超合金跟上述其他元素結合而形成之黏結劑基質可以是Ni基超合金、其他之Ni基超合金或非Ni 基超合金。使用Re當作是黏結劑材料，能夠提供硬粒子的強結 1057D-6939-PF 90 '200535255 合強度，特別是可以提供所得之硬金屬材料的高溶點。^ 的熔點係3180X：，遠高於—般使用的c。黏結劑材料。亦即，Re部分地貢獻使用Re當作是黏結劑的硬金屬的優良 f生貝合J如提升所得之硬金屬硬度與在高溫下的強度。以也有黏結劑材料所想要的其他特性。例如，與不具Re黏結劑材料的相似硬金屬相比較，具有Re於黏結劑基質中的硬金屬的硬度、知、切破裂強度、破裂韌性以及熔點能夠有明籲顯的提升。在具有Re於黏結劑基質中的wc基硬金屬，其硬度HV可達2600kg/mm2以上。而一些示範的wc基硬金屬，其熔點（例如燒結溫度）係大於220(rc。與本案比較，在白矣Brookes書中表2.1所示之具有c〇黏結劑的wc基硬金屬’其燒結溫度係於15〇〇。。以下。具有高燒結溫度的硬金屬使得該材料能夠在低於燒結溫度下的高溫下操作。例如由具有含Re的硬金屬材料所構成之工具能夠在高速下操作而減少製程時間而提升效率。 ❿ 使用Re ¥作疋黏結劑材料於硬金屬中，然而在實際Ni-based superalloys can be used alone or combined with other elements to make the desired binder matrix. The other elements mentioned above are, for example, Re, Co, Ni, Fe, Mo and Cf. The binder matrix formed by the combination of the Ni-based superalloy with the other elements mentioned above may be a Ni-based superalloy, other Ni-based superalloys, or a non-Ni-based superalloy. Using Re as a binder material can provide a strong junction of hard particles 1057D-6939-PF 90 '200535255 combined strength, especially the high melting point of the resulting hard metal material. ^ Has a melting point of 3180X :, which is much higher than c, which is generally used. Binder material. That is, Re contributes in part to the excellent properties of hard metals using Re as a binder, such as the hardness of the hard metal obtained and the strength at high temperatures. It also has other properties that are desirable for adhesive materials. For example, compared with similar hard metals without Re binder materials, the hardness, hardness, shear fracture strength, fracture toughness, and melting point of hard metals with Re in the binder matrix can be significantly improved. The wc-based hard metal with Re in the binder matrix has a hardness HV of more than 2600 kg / mm2. And some exemplary wc-based hard metals have melting points (such as sintering temperature) greater than 220 (rc. Compared with the present case, the wc-based hard metals with co adhesives shown in Table 2.1 in the White Book of Brookes' sintering The temperature is below 150 ° C. Below. The hard metal with high sintering temperature enables the material to be operated at a high temperature below the sintering temperature. For example, a tool composed of a hard metal material containing Re can be operated at high speed And reduce the process time and improve efficiency. ❿ Use Re ¥ as 疋 binder material in hard metal, but in practice

製程中可能會有一些限制。例如，以所預期的高溫特性導致製私上而要鬲燒結溫度。然而這需要可以操作更高燒結溫度的爐子來進行此製程，但是這種要能夠在22〇〇艽以上刼作之爐子很貴而並不被廣泛使用。在美國專利第號中，有揭示一種快速全方向壓製（rapid 〇mnidirecti〇nal compaction，R〇c)方法，應用於具有使用6〜_%的純以來當作是黏結劑材料的wc基硬金屬製程，而用來降低製 fD m度而這R〇C製程仍然很貴而不適用於商業製程。 1057D-6939-PF 91 ,200535255 上述硬金屬組合物以及此處所敘述之組成方法的一優點’係可以提供或考慮到—額外的實際製程來製造具有使用Re或Re與其他黏結材料的混合物於黏結劑基質中的硬金屬。特別是，這兩階段步驟可以製造硬金屬，該硬金屬中的Re係佔所得的硬金屬的該硬金一上。如此的具一以…硬金屬;:Ϊ:: 在高溫下具有高硬度與材料強度。使用純Re當作是硬金屬的黏結劑材料的另一限制係There may be some restrictions in the process. For example, sintering temperatures are required due to the expected high temperature characteristics. However, this requires a furnace capable of operating a higher sintering temperature to perform this process, but such a furnace capable of being operated above 2200 ° F is expensive and not widely used. In the U.S. Patent No., a rapid omnidirectional compaction (Roc) method is disclosed, which is applied to wc-based hard metals that have been used as a binder material since 6 to _% pure. Process, which is used to reduce the fDm degree and this ROC process is still expensive and not suitable for commercial processes. 1057D-6939-PF 91, 200535255 An advantage of the above-mentioned hard metal composition and the composition method described herein can be provided or taken into account-an additional practical process to manufacture a mixture with Re or Re and other bonding materials for bonding Hard metal in the agent matrix. In particular, the two-step process can produce a hard metal, and Re in the hard metal accounts for the hard metal of the obtained hard metal. Such a hard metal;: Ϊ :: High hardness and material strength at high temperatures. Another limitation of using pure Re as a binder material for hard metals

Re在35(TC以上的空氣中會嚴重被氧化。這種不良的氧化抵抗性會嚴重影響使用純Re當作黏結劑材料使用於3〇〇1 以上的應用。因為Ni基超合金在1〇〇〇t：以下具有特殊的強度和抗氧化性，因此使用Ni基超合金和Re的混合物當作是黏結劑的話’其中Re係該黏結劑中的支配材： (dominant material)而被用來改善所得的硬金屬的強度和抗氧化性。另一方面，添加額外的Re於只要包含有犯基鲁超合金的黏結劑係能夠增加所得硬金屬的炫點範圍，而二改善Ni基超合金黏結劑的高溫強度和抗潛變性 resistance) ° 一般而言，Re所佔之重量比率係為硬金屬中黏結劑總重的數Wt%〜100wt%。最好是，Re所佔之重量比率係為黏結劑總重的5Wt%以上。在—些實施例中，黏結劑基質^ 的Re係佔所得之硬金屬總重的25wt%以上。具有如此高濃度的Re係、能夠在本案的兩階段製程中以相當低的溫：：製造。Re will be severely oxidized in air above 35 ° C. This poor oxidation resistance will seriously affect the use of pure Re as a binder material for applications above 301. Because Ni-based superalloys are at 1〇〇〇t: The following has special strength and oxidation resistance, so if a mixture of Ni-based superalloy and Re is used as the binder, 'where Re is the dominant material in the binder: (dominant material) is used to Improve the strength and oxidation resistance of the obtained hard metal. On the other hand, the addition of additional Re to the binder system that contains a superalloy can increase the range of dazzling points of the obtained hard metal, and secondly, improve the Ni-based superalloy High-temperature strength and anti-latent resistance of the adhesive) ° Generally speaking, the weight ratio of Re is the number Wt% ~ 100wt% of the total weight of the adhesive in the hard metal. Preferably, the weight ratio of Re is 5 Wt% or more of the total weight of the adhesive. In some embodiments, Re of the binder matrix ^ accounts for more than 25% by weight of the total weight of the obtained hard metal. The Re system with such a high concentration can be manufactured at a relatively low temperature in the two-stage process of this case ::.

1057D-6939-PF 92 200535255 因為Re比其他被使用於硬金屬中的材料貴，所以在設計含Re的黏結劑基質時要考慮成本。部分下列例子中係反映了這成本考量。一般而言，根據一製程形成一種硬金屬且5物其包括：被分散的具有第一材料的硬粒子；以1057D-6939-PF 92 200535255 Because Re is more expensive than other materials used in hard metals, cost must be considered when designing Re-containing binder matrices. Some of the following examples reflect this cost consideration. Generally speaking, a hard metal is formed according to a process and 5 things include: dispersed hard particles with a first material; and

及具有與第一材料不同之第二材料之一黏結劑基質；其 ::該黏結劑基質包含銖(Re)元素，且上述硬粒子係以實貝均勻的方式散佈於該黏結劑基質中。該黏結劑基質可以是Re和其他材料的混合物，用以降低Re的總含量而降低原:料的總成本’並且探測其他黏結劑材料提升該黏結劑基質之效果。例如該黏結劑基質具有Re和其他材料的混合物，該其他材料包含Re與至少一 Ni基超合金的混合物、And a binder matrix having a second material different from the first material; :: The binder matrix contains Ba (Re) elements, and the hard particles are dispersed in the binder matrix in a uniform manner. The adhesive matrix may be a mixture of Re and other materials, so as to reduce the total content of Re and reduce the total cost of raw materials, and detect other adhesive materials to improve the effect of the adhesive matrix. For example, the binder matrix has a mixture of Re and other materials including a mixture of Re and at least one Ni-based superalloy,

Re，Co與至少_ Ni基超合金的混合物、Re，&與其他材料的混合物。表1係列出一些硬金屬組成的例子。在這表中，wc 基組成係被稱為，，硬金屬（hardmetals)”，❿Tic基組成係被 %為’陶究金屬（cermets)，，。傳統上，Tic粒子被Ni與Mo 的此口物或Ni與M〇2C的混合物黏結係被稱為，，陶瓷金屬乂裡的陶瓷金屬可更包括由TiC與TiN的混合物或 TiC、TiN、WC、TaC與Nbc的混合物所構成之粒子，以及由Ni與Mo的混合物或⑽與以。2。的混合物所構成之黏結：基質。對於每一硬金屬組成，係於表中列出三種不同，量百分率的黏結劑材料。當作是一例子，該黏結劑可以是Ni基超合金與c〇的混合物，而該等硬粒子可以是 TiC，TaC與NbC的混合物。在這組成巾，該黏結齊!可以佔A mixture of Re, Co with at least a Ni-based superalloy, a mixture of Re, & with other materials. Table 1 lists some examples of hard metal compositions. In this table, the wc-based composition system is called, “hardmetals”, and the Tic-based composition system is referred to as “cermets.” Traditionally, Tic particles have been described by Ni and Mo. The bonding system of a substance or a mixture of Ni and 〇2C is called, the ceramic metal in the ceramic metal may further include particles composed of a mixture of TiC and TiN or a mixture of TiC, TiN, WC, TaC and Nbc, and Adhesion consisting of a mixture of Ni and Mo or a mixture of rhenium and .2: matrix. For each hard metal composition, three different, percentages of binder materials are listed in the table. As an example The bonding agent can be a mixture of Ni-based superalloy and c0, and the hard particles can be a mixture of TiC, TaC and NbC. In this composition, the bonding is all together! It can account for

1057D-6939-PF 93 •200535255 該硬金屬總重的2〜40wt°/〇。該範圍在許多應用中係被設定於3〜3 5 wt%，而且在其他應用中係被設定於4〜30wt%。表1 (NS : Ni基超合金’ Re :鍊，Co :鈷）黏結劑組成硬粒子組成 1st黏結劑wt.% 範圍 2nd黏結劑wt.% 範圍 3fd黏結劑wt.% 範圍 Re WC 4 to 40 5 to 35 6 to 30 WC-TiC-TaC-NbC 4 to 40 5 to 35 6 to 30 NS WC 2 to 30 3 to 25 4 to 20 WC-TiC-TaC-NbC 2 to 30 3 to 25 4 to 20 硬金屬 NS-Re WC 2 to 40 3 to 35 4 to 30 WC-TiC-TaC-NbC 2 to 40 3 to 35 4 to 30 Re-Co WC 2 to 40 3 to 35 4 to 30 WC-TiC-TaC-NbC 2 to 40 3 to 35 4 to 30 NS-Re-Co WC 2 to 40 3 to 35 4 to 30 WC-TiC-TaC-NbC 2 to 40 3 to 35 4 to 30 NS Mo2C-TiC 5 to 40 6 to 35 8 to 40 Mo2C-TiC-TiN-WC-TaC-NbC 5 to 40 6 to 35 8 to 40 陶瓷金屬 Re Mo2C-TiC 10 to 55 12 to 50 15 to 45 Mo2C-TiC-TiN-WC-TaC-NbC 10 to 55 12 to 50 15 to 45 NS-Re Mo2C-TiC 5 to 55 6 to 50 8 to 45 Mo2C-TiC-TiN-WC-TaC-NbC 5 to 55 6 to 50 8 to 45 製造具有使用Re或Ni基超合金於黏結劑基質的硬金屬可以由下述方法來完成。首先，準備具有所想要的硬粒子的粉末，例如一種或多種的碳化物或碳氮化物。這粉末 # 可以包含不同碳化物的混合物或碳化物與碳氮化物的混合物。然後將這粉末與含有Re或Ni基超合金的適當之黏結劑基質材料混合。除此之外，可添加壓製潤滑劑（例如臘）於上述混合物中。亦即，將上述硬粒子、黏結劑基質材料與潤滑劑藉由輾磨（milling)或研磨（attriting) —段時間（如數小時）而完全地混合，以便使每一硬粒子皆被黏結劑基質材料所被覆，因而促進在後續製程中的硬粒子之結合。上述硬粒子也被潤滑劑所被覆，因而有利於混合製程以及降低或避免硬粒 941057D-6939-PF 93 • 200535255 2 ~ 40wt ° / 〇 of the total weight of the hard metal. This range is set to 3 to 35 wt% in many applications and 4 to 30 wt% in other applications. Table 1 (NS: Ni-based superalloy 'Re: Chain, Co: Cobalt) Binder composition Hard particle composition 1st binder wt.% Range 2nd binder wt.% Range 3fd binder wt.% Range Re WC 4 to 40 5 to 35 6 to 30 WC-TiC-TaC-NbC 4 to 40 5 to 35 6 to 30 NS WC 2 to 30 3 to 25 4 to 20 WC-TiC-TaC-NbC 2 to 30 3 to 25 4 to 20 hard Metal NS-Re WC 2 to 40 3 to 35 4 to 30 WC-TiC-TaC-NbC 2 to 40 3 to 35 4 to 30 Re-Co WC 2 to 40 3 to 35 4 to 30 WC-TiC-TaC-NbC 2 to 40 3 to 35 4 to 30 NS-Re-Co WC 2 to 40 3 to 35 4 to 30 WC-TiC-TaC-NbC 2 to 40 3 to 35 4 to 30 NS Mo2C-TiC 5 to 40 6 to 35 8 to 40 Mo2C-TiC-TiN-WC-TaC-NbC 5 to 40 6 to 35 8 to 40 Ceramic metal Re Mo2C-TiC 10 to 55 12 to 50 15 to 45 Mo2C-TiC-TiN-WC-TaC-NbC 10 to 55 12 to 50 15 to 45 NS-Re Mo2C-TiC 5 to 55 6 to 50 8 to 45 Mo2C-TiC-TiN-WC-TaC-NbC 5 to 55 6 to 50 8 to 45 Manufactured using Re or Ni based The superalloy-to-binder matrix hard metal can be completed by the following method. First, a powder having desired hard particles, such as one or more carbides or carbonitrides, is prepared. This powder # may contain a mixture of different carbides or a mixture of carbides and carbonitrides. This powder is then mixed with a suitable binder matrix material containing Re or Ni-based superalloys. In addition, a press lubricant (such as wax) may be added to the above mixture. That is, the hard particles, the binder matrix material, and the lubricant are completely mixed by milling or attrition for a period of time (such as several hours) so that each hard particle is bound by the binder matrix The material is covered, thus promoting the incorporation of hard particles in subsequent processes. The hard particles mentioned above are also covered by a lubricant, which facilitates the mixing process and reduces or avoids hard particles. 94

1057D-6939-PF 200535255 化。接著，對上述已研磨的混合物連續地進行壓製、 =:成型以及最終燒結製程，而形成所得之硬金屬。數程係一種藉由在硬粒子熔點以下之溫度加熱， :=材料轉變成連續塊狀物，且燒結製程可以在初壓製製程後進行。在此.p_ 王，黏、、、口劑材料會被緻密化而形成一連續的黏結劑基質來黏結硬粒子於其中。之後，1057D-6939-PF 200535255. Then, the above-mentioned milled mixture is continuously subjected to pressing, molding, and final sintering processes to form the obtained hard metal. The number process is a process in which the material is heated to a temperature below the melting point of the hard particles, and the material is transformed into continuous blocks, and the sintering process can be performed after the initial pressing process. Here, p_wang, the viscous, viscous, and oral materials will be densified to form a continuous adhesive matrix to bind the hard particles. after that,

=硬金屬表面上更被覆額外的一或多層塗佈，而提升的效月b。帛1圖係顯示上述製程的流程圖。在Λ〜例中，黏結的碳化物之製程包括溶劑中渴磨^真空乾燥、屡製以及在真空中的液相燒結。液相燒結的溫度係於黏結劑材料的炫點（例如0〇在14价）盘硬金屬混合物的共溶溫度（eutectic temp，例如wc_co在⑽ )門叙而5，黏結的碳化物的燒結溫度係136〇〜148〇 Z之間。對於在黏結劑合金的具有低濃度的Re* Ni基超合金之新材料而言’其製程與傳統的黏結的碳化物製程類似。在真空中的液相燒結原理係被應用於此。所以結溫度係略高於黏結劑合金與碳化物的共熔溫度。例二 (黏、‘Ό 4合金中的Re係25的燒結條件係在直* 以170CTC加熱i小時。第2圖係顯示根據固相燒結的兩階段步驟來製造本發明中各硬金屬的製造流程圖。可以採用兩階段燒結步驟：硬金屬係具有高濃度Re於黏結劑基質中，而不茸、、四TJ Α而要在。狐仃之液相燒結。這兩階段燒結步驟可以在西 (2200°C以下、、隹— 门干又皿下）進仃，因而能夠使用傳統的爐子而不用購置= The hard metal surface is further covered with one or more additional coatings, which improves the efficiency b. Figure 1 shows a flowchart of the above process. In the example, the process of cemented carbides includes thirst in a solvent ^ vacuum drying, repeated production, and liquid phase sintering in a vacuum. The liquid phase sintering temperature is based on the dazzling point of the binder material (for example, 0〇 at 14 valence). The eutectic temp of the hard metal mixture (e.g., wc_co in 门) is listed in Chapter 5. Department between 136〇 ~ 148〇Z. For new materials with low concentrations of Re * Ni-based superalloys in the binder alloy, the process is similar to the traditional cemented carbide process. The principle of liquid-phase sintering in vacuum is applied here. Therefore, the junction temperature is slightly higher than the eutectic temperature of the binder alloy and carbide. Example 2 (The sintering conditions of Re series 25 in viscous and Ό4 alloys were heated at 170 CTC for 1 hour. Figure 2 shows the production of each hard metal in the present invention according to the two-step process of solid phase sintering. Flow chart. Two-stage sintering step can be used: Hard metal system with high concentration of Re in the binder matrix, without velvet, or four TJ Α. The liquid phase sintering of foxtail can be done in the west. (Below 2200 ° C, 隹 —door is dry and under the dish), so you can use a traditional stove without purchasing

1057D-6939-PF 95 \20〇535255 昂貴之高溫設備，所以具有經濟性。由於黏結劑合金和碳化物的高共熔溫度而使液相燒結可能無法實施，所以在上述兩階段步驟係捨棄液相燒結。如上所述，在如此高溫燒結係需要能夠在高溫操作的爐子，因此不合乎經濟效益。上述兩階段步驟的第一步驟係一真空燒結，亦即黏結劑基質和硬粒子之混合物材料係於真空中被燒結。該混合物起初被處理過（例如濕磨、乾燥和壓製），其相似於製作黏結的碳化物之傳統製程。燒結的第一步驟係於低於黏結 ® 劑合金與碳化物的共熔溫度的溫度下進行，所以可忽略之間的多孔性問題（porosity)。第二步驟係在低於共溶溫度進行之固相燒結，而且在一加壓條件下而可忽略在第一步驟後殘留於燒結過的混合物中的殘留孔洞問題。熱均壓（hot iso static pressing，HIP)製程可當作是第二步驟燒結。在燒結過程中，經由熱和壓力施加於該材料而降低製程溫度，這不同於沒有壓力的高溫製程。還有，惰性氣體可加於其 $ 中而傳遞該壓力到該燒結混合物，其壓力可以超過 lOOObar。HIP製程中的壓力可以降低製程溫度以及使其可使用於傳統設備的爐子。用以達成全緻密化的固相燒結和 HIP的溫度通常能顯著地低於液相燒結的溫度。例如，試品P62係使用純Re當作是黏結劑而可以被全緻密化，其條件係在2200°C下進行1〜2小時燒結，之後在2000°C、 30000PSI以及Ar氣氛下進行約1小時的HIP製程。要注意的是，要使用粒徑小於〇. 5 μπι的極微細硬粒子，因而能降低全緻密化該硬金屬的燒結溫度。例如，在製造試品Ρ62, 1057D-6939-PF 96 -200535255 P63時，若使用極微細的wc粒子的話，則燒結温度可降至約2000^。這兩步驟方法比習知美國專利第547653丨號所教導之快速全方向壓製（R〇c)方法來得便宜，而符合經濟效益。下段係敘述一些硬金屬的組成和特性的例子，其各種黏結劑基質材料係包含至少有Re或Ni基超合金。表2係舉出一些試品名稱（或批號），其一些組合物係 _用於形成代表的硬金屬。其中，m代表Re，而Li，L2，L3 係代表三種市面上的Ni基超合金。表3係更列出上述三種代表的Ni基超合金，其各別為udimet 720 (U720)，Rene 95 (R-95)以及Udimet 7〇〇 (U7〇〇)。表4係列出代表的硬合金之組成’亦即針對在黏結劑基質中含有或不含有或犯基超合金。例如，批號P17的材料組成主要包含有88克的 T32(WC)、3 克的 I32(TiC)、3 克的 ASKTaC)、^ 克的 m(Re) 以及4.5克的L2(R_95)當作是黏結劑，還有2克的臘（wax) φ 當作是潤滑劑。批號P58係只有把Ni基超合金L2當作是黏結劑的硬金屬，而不含Re。這些硬金屬係被製造且被測試而敘述有Re與Ni基超合金之一或兩者當作是黏結劑時，其所得之硬金屬的各種特性。表5_8更提供了上述各種不同組成之硬金屬的特性的歸納。第3圖〜第8圖係顯示本案中部分被選擇的試品的量測圖。第3、4圖係顯示測量用於切削鋼等級（steel cutting grade)的一些代表性的硬金屬的韌性和硬度參數。第5、6 圖係顯示測量用於不含鐵切削等級（n〇n-ferr〇us cutting1057D-6939-PF 95 \ 20〇535255 Expensive high temperature equipment, so it is economical. Liquid phase sintering may not be performed due to the high eutectic temperature of the binder alloy and carbides, so liquid phase sintering is discarded in the two-stage step. As described above, sintering at such a high temperature requires a furnace capable of operating at a high temperature, and thus is not economical. The first step of the above two-stage step is a vacuum sintering, that is, a mixture of a binder matrix and hard particles is sintered in a vacuum. The mixture is initially treated (eg, wet-milled, dried, and pressed), similar to the traditional process for making cemented carbides. The first step of sintering is performed at a temperature lower than the eutectic temperature of the bonding agent alloy and the carbide, so the porosity between them can be ignored. The second step is solid phase sintering at a temperature lower than the eutectic temperature, and the problem of residual pores remaining in the sintered mixture after the first step can be ignored under a pressure condition. The hot iso static pressing (HIP) process can be regarded as the second step of sintering. During the sintering process, the process temperature is reduced by applying heat and pressure to the material, which is different from a high temperature process without pressure. Also, an inert gas can be added to it to transfer the pressure to the sintering mixture, and the pressure can exceed 1000 bar. The pressure in the HIP process can reduce the process temperature and make it suitable for furnaces with conventional equipment. The temperatures for solid phase sintering and HIP to achieve full densification are usually significantly lower than those for liquid phase sintering. For example, the test product P62 can be fully densified using pure Re as a binder. The conditions are sintered at 2200 ° C for 1 to 2 hours, and then performed at 2000 ° C, 30000PSI, and Ar for about 1 hour. HIP process for hours. It should be noted that extremely fine hard particles having a particle size of less than 0.5 μm are used, so that the sintering temperature of the hardened metal can be reduced. For example, when producing test samples P62, 1057D-6939-PF 96 -200535255 P63, if extremely fine wc particles are used, the sintering temperature can be reduced to about 2000 ^. The two-step method is cheaper than the fast omnidirectional pressing (ROC) method taught in the conventional U.S. Patent No. 547653 丨, and is economical. The following paragraphs describe some examples of the composition and characteristics of hard metals. The various binder matrix materials include at least Re or Ni-based superalloys. Table 2 lists some sample names (or batch numbers), some of which are used to form representative hard metals. Among them, m represents Re, and Li, L2, and L3 represent three types of Ni-based superalloys on the market. Table 3 further lists the three representative Ni-based superalloys mentioned above, each of which is udimet 720 (U720), Rene 95 (R-95), and Udimet 700 (U700). Table 4 represents the composition of the hard alloys, i.e., for the presence or absence or inclusion of a superalloy in the binder matrix. For example, the material composition of lot P17 mainly contains 88 grams of T32 (WC), 3 grams of I32 (TiC), 3 grams of ASKTaC), ^ grams of m (Re), and 4.5 grams of L2 (R_95) as Binder and 2 grams wax as lubricant. The batch number P58 is only a hard metal that uses Ni-based superalloy L2 as a binder, and does not contain Re. These hard metals are manufactured and tested to describe the various characteristics of the hard metals obtained when one or both of Re and Ni-based superalloys are used as binders. Table 5_8 also provides a summary of the characteristics of the above-mentioned hard metals of different compositions. Figures 3 to 8 are measurement diagrams showing some of the selected samples in this case. Figures 3 and 4 show the measurement of toughness and hardness parameters of some representative hard metals used in steel cutting grades. Figures 5 and 6 show measurements for non-ferrous cutting grades (n〇n-ferr〇us cutting

1057D-6939-PF 97 200535255 grade)的一些代表性的硬金屬的韌性和硬度參數。該等測試係於固相燒結HIP製程前與後所進行，且該等測試資料可建議用於HIP製程而有效改善這些材料的韌性和硬度。第 7圖係顯示一些試品的硬度與溫度之關係圖。當做比較，第7、8圖也顯示在同一測試條件下測量市面的C2與C6 碳化物，其中第7圖係顯示熱硬度Hk和温度之關係，而第 8圖係顯示從室溫到1 000°C的硬度改變狀況。從上述測試圖可清楚發現，根據本發明組合物的硬金屬在高溫硬度方面勝於市販等級材料。這些結果顯示，與Co基黏結劑基質材料比較，有最好效能之黏結劑基質係具有Re與Ni基超合金之一或兩者而當作是黏結劑材料。表21057D-6939-PF 97 200535255 grade) toughness and hardness parameters of some representative hard metals. These tests are performed before and after the solid phase sintering HIP process, and the test data can be recommended for the HIP process to effectively improve the toughness and hardness of these materials. Figure 7 shows the relationship between hardness and temperature of some samples. For comparison, Figures 7 and 8 also show the measurement of C2 and C6 carbides on the market under the same test conditions. Figure 7 shows the relationship between thermal hardness Hk and temperature, and Figure 8 shows the temperature from room temperature to 1,000. Change in hardness at ° C. It is clear from the above test chart that the hard metal of the composition according to the present invention is superior to commercially available grades in terms of high temperature hardness. These results show that, compared with Co-based binder matrix materials, the binder matrix with the best performance is one or both of Re and Ni-based superalloys as the binder material. Table 2

代號 (Code) 粉末組成注釋(Note) T32 wc 粒徑1·5μπι、Alldyne公司製 T35 wc 粒徑1.5μιη、Alldyne公司製 Y20 Mo 粒徑1.7〜2.2μιη、Alldyne公司製 L3 U-700 -325 網目、Special Metal 公司的 Udimet 700 L1 U-720 -325 網目、Special Metal 公司的 Udimet 720 L2 Re-95 -325 網目、Special Metal 公司的 Rene 95 HI Re -325 網目、Rhenium Alloy 公司製 132 TiC AEE公司製的Ti-302 121 TiB2 AEE公司製的Ti-201、1〜5μπι A31 TaC AEE公司製的TA-301 Y31 Mo2C AEE公司製的MO-301 D31 VC AEE公司製的VA-301 B1 Co AEE公司製的CO-101 ΚΙ Ni AEE公司製的Ni-101 1057D-6939-PF 98 .200535255 K2 Ni AEE公司製的Ni-102 113 TiN Cerac公司製的T-1153 C21 ZrB2 Cerac公司製的Z-1031 Y6 Mo AEE公司製的Mo+100、1〜2μπι L6 A1 AEE公司製的Al-100、1〜5μιη R31 b4c AEE 公司製的 Bo-301、3μπι T3.8 wc 粒徑〇.8μηι、Alldyne公司製 T3.4 wc 粒徑〇.4μηι、OMG公司製 T3.2 wc 粒徑0.2μιη、OMG公司製表3Code Note for powder composition (Note) T32 wc particle size 1.5 μm, T35 wc particle size Alldyne 1.5 μm, Y20 Mo particle size 1.7 to 2.2 μm Alldyne, L3 U-700 -325 mesh made by Alldyne , Udimet 700 L1 U-720 -325 mesh of Special Metal, Udimet 720 L2 Re-95 -325 mesh of Special Metal, Rene 95 HI Re -325 mesh of Special Metal, 132 TiC AEE manufactured by Rhenium Alloy Ti-302 121 TiB2 Ti-201 manufactured by AEE Corporation A31 TaC AEE TA-301 Y31 Mo2C AEE Corporation MO-301 D31 VC AEE Corporation VA-301 B1 Co AEE Corporation CO-101 KI Ni-101 1057D-6939-PF 98 Ni 2005 A2 Ni AEE Ni-102 113 TiN Cerac T-1153 C21 ZrB2 Cerac Z-1031 Y6 Mo AEE Mo + 100 manufactured by the company, 1 ~ 2μπι L6 A1 Al-100 manufactured by the company AEE, 1 ~ 5μιη R31 b4c Bo-301 manufactured by the AEE company, 3μπι T3.8 wc particle size 0.8 μηι, T3.4 manufactured by Alldyne Corporation wc particle size 0.4 μm, T3.2 manufactured by OMG, wc particle size 0.2 μm, OMG Ltd. Table 3

Ni Co Cr A1 Ti Mo Nb W Zr B C V R95 61.982 8.04 13.16 3.54 2.53 3.55 3.55 3.54 0.049 0.059 U700 54.331 17.34 15.35 4.04 3.65 5.17 .028 .008 .04 .019 .019 .005 U720 56.334 15.32 16.38 3.06 5.04 3.06 0.01 1.30 .035 .015 .012 .004 表4 批號組成(單位：克） P17 Hl=1.5, L2=4.5,132=3, A31=3, T32=88, Wax=2 P18 Hl=3, L2=3,132=3, A31=3, T32=88? Wax=2 P19 Hl=1.5, L3=4.5,132=3, A31=3, T32=88, Wax=2 P20 Hl=3, L3=3,132=3, A31=3, T32=88, Wax=2 P25 Hl=3.75, L2=2.25,132=3, A31=3, T32=88, Wax=2 P25A Hl=3.75, L2=2.25,132=3, A31=3, T32=88, Wax=2 P31 Hl=3.44, Bl=4.4, T32=92.16, Wax=2 P32 Hl=6.75, Bl=2.88, T32=90.37, Wax=2 P33 Hl=9.93, Bl=1.41, T32=88.66, Wax=2 P34 L2=14.47,132=69.44, Y31=16.09 P35 Hl=8.77, L2=10.27,132=65.73, Y31=15.23 P36 Hl=16.66, L2=6.50,132=62.4, Y31=14.56 P37 Hl=23.80, L2=3.09,132=59.38, Y31=13.76 P38 Kl=15.51,132=68.60, Y31=15.89 P39 K2=15.51,132=68.60, Y31=15.89 P40 Hl=7.57, L2=2.96,132=5.32, A31=5.23, T32=78.92, Wax=2 P40A Hl=7.57, L2=2.96,132=5.32, A31=5.23, T32=78.92, Wax=2 P41 Hl=ll.l, L2=1.45,132=5.20, A31=5.11, T32=77.14, Wax=2 P41A HI=11.1, L2=1.45,132=5.20, A31=5.11, T32=77.14, Wax=2 P42 Hl=9.32, L2=3.64,132=6.55, A31=6.44,121=0.40, R31=4.25, T32=69.40, Wax=2Ni Co Cr A1 Ti Mo Nb W Zr BCV R95 61.982 8.04 13.16 3.54 2.53 3.55 3.55 3.54 0.049 0.059 U700 54.331 17.34 15.35 4.04 3.65 5.17 .028 .008 .04 .019 .019 .005 U720 56.334 15.32 16.38 3.06 5.04 3.06 0.01 1.30. 035 .015 .012 .004 Table 4 Batch number composition (unit: grams) P17 Hl = 1.5, L2 = 4.5,132 = 3, A31 = 3, T32 = 88, Wax = 2 P18 Hl = 3, L2 = 3,132 = 3 , A31 = 3, T32 = 88? Wax = 2 P19 Hl = 1.5, L3 = 4.5,132 = 3, A31 = 3, T32 = 88, Wax = 2 P20 Hl = 3, L3 = 3,132 = 3, A31 = 3 , T32 = 88, Wax = 2 P25 Hl = 3.75, L2 = 2.25,132 = 3, A31 = 3, T32 = 88, Wax = 2 P25A Hl = 3.75, L2 = 2.25,132 = 3, A31 = 3, T32 = 88, Wax = 2 P31 Hl = 3.44, Bl = 4.4, T32 = 92.16, Wax = 2 P32 Hl = 6.75, Bl = 2.88, T32 = 90.37, Wax = 2 P33 Hl = 9.93, Bl = 1.41, T32 = 88.66 , Wax = 2 P34 L2 = 14.47,132 = 69.44, Y31 = 16.09 P35 Hl = 8.77, L2 = 10.27,132 = 65.73, Y31 = 15.23 P36 Hl = 16.66, L2 = 6.50,132 = 62.4, Y31 = 14.56 P37 Hl = 23.80, L2 = 3.09,132 = 59.38, Y31 = 13.76 P38 Kl = 15.51,132 = 68.60, Y31 = 15.89 P39 K2 = 15.51,132 = 68.60, Y31 = 15.89 P40 Hl = 7.57, L2 = 2.96,132 = 5.32 , A31 = 5.23, T32 = 78.92, Wax = 2 P40A Hl = 7.57, L2 = 2.96, 132 = 5.32, A31 = 5.23, T32 = 78.92, Wax = 2 P41 Hl = ll.l, L2 = 1.45,132 = 5.20, A31 = 5.11, T32 = 77.14, Wax = 2 P41A HI = 11.1, L2 = 1.45,132 = 5.20, A31 = 5.11, T32 = 77.14, Wax = 2 P42 Hl = 9.32, L2 = 3.64,132 = 6.55, A31 = 6.44,121 = 0.40, R31 = 4.25, T32 = 69.40, Wax = 2

1057D-6939-PF 99 2005352551057D-6939-PF 99 200535255

P43 Hl=9.04, L2=3.53,132=6.35, A31=6.24,121=7.39, R31=0.22, T32=67.24, Wax=2 P44 Hl-8.96, L2=3.50,132=14.69, A31=6.19, T32=66.67, Wax=2 P45 Hl=9.37, L2-3.66,132=15.37, A31=6.47, Y31=6.51, T32=58.61, Wax=2 P46 Hl=11.40, L2=4.45,132=5.34, A31=5.25, T32-73.55, Wax=2 P46A Hl=11.40, L2=4.45,132=5.34, A31=5.25, T32=73.55, Wax=2 P47 Hl=11.35, Bl=4.88,132=5.32, A31=5.23, T32=73.22, Wax=2 P47A Hl=11.35, Bl=4.88,132=5.32, A31=5.23, T32=73.22, Wax=2 P48 Hl=3.75, L2=2.25,132=5, A31=5, T32=84, Wax=2 P49 H卜7.55, Bl=3.25,132=5.31，A31=5.21, T32=78.68, Wax=2 P50 Hl=4.83, L2=1.89? 132=5.31, A31=5.22, T32=82.75, Wax=2 P51 Hl-7.15, L2=0.93,132=5.23, A31=5.14, T32=81.55, Wax=2 P52 Bl=8, D31=0.6, T3.8=91.4, Wax=2 P53 Bl=8, D31=0.6, T3.4=91.4, Wax=2 P54 Bl=8, D31=0.6, T3.2=91.4, Wax=2 P55 Hl=1.8, Bl=7.2, D31=0.6, T3.4=90.4, Wax=2 P56 Hl=1.8, Bl=7.2, D31=0.6, T3.2=90.4? Wax=2 P56A Hl=1.8, Bl=7.2, D31=0.6, T3.2=90.4, Wax=2 P57 Hl=1.8, Bl=7.2, T3.2=91, Wax=2 P58 L2=7.5, D31=0.6, T3.2=91.9, Wax=2 P59 Hl=0.4, Bl=3, L2=4.5, D31=0.6, T3.2=91.5, Wax=2 P62 Hl=14.48,132=5.09, A31=5.00, T3.2=75.43, Wax=2 P62A Hl=14.48,132=5.09, A31=5.00, T3.2=75.43, Wax=2 P63 Hl=12.47, L2=0.86,132=5.16, A31=5.07, T3.2=76.45, Wax=2 P65 Hl=7.57, L2=2.96,132=5.32, A31=5.23, T3.2=78.92, Wax=2 P65A Hl=7.57, L2=2.96,132=5.32, A31=5.23, T3.2=78.92, Wax=2 P66 Hl=27.92,132-4.91, A31=4.82, T3.2=62.35, Wax=2 P67 Hl=24.37, L3=1.62,132=5.04, A31=4.95, T32=32.01? T33=32.01, Wax=2 P69 L2=7.5, D31=0.4, T3.2=92.1, Wax=2 P70 Ll==7.4, D31=0.3, T3.2=92.3, Wax=2 P71 L3=7.2, D31=0.3, T3.2=92.5, Wax=2 P72 Hl=1.8, Bl=7.2, D31=0.3, T3.2=90.7, Wax=2 P73 Hl=1.8, Bl=4.8, L2=2.7, D31=0.3, T3.2=90.4, Wax=2 P74 Hl=1.8, Bl=3, L2=4.5, D31=0.3, T3.2=90.4, Wax=2 P75 Hl=0.8, Bl=3, L2=4.5, D31=0.3, T3.2=91.4, Wax=2 P76 Hl=0.8, Bl=3, Ll=4.5, D31-0.3, T3.2=91.4, Wax=2 P77 Hl=0.8, Bl=3, L3=4.5, D31=0.3, T3.2=91.4, Wax=2 P78 Hl=0.8, Bl=4.5, Ll=3, D31=0.3, T3.2=91.4, Wax=2 P79 Hl=0.8, Bl=4.5, L3=3.1, D31=0.3, T3.2=91.3, Wax=2 許多代表性種類的硬金屬組成係如下述，用以說明這些硬金屬的設計係包含有Re與Ni基超合金之一或兩者。這些代表性種類的硬金屬組成係基於用於所得硬金屬或陶 100P43 Hl = 9.04, L2 = 3.53,132 = 6.35, A31 = 6.24,121 = 7.39, R31 = 0.22, T32 = 67.24, Wax = 2 P44 Hl-8.96, L2 = 3.50,132 = 14.69, A31 = 6.19, T32 = 66.67, Wax = 2 P45 Hl = 9.37, L2-3.66,132 = 15.37, A31 = 6.47, Y31 = 6.51, T32 = 58.61, Wax = 2 P46 Hl = 11.40, L2 = 4.45,132 = 5.34, A31 = 5.25 , T32-73.55, Wax = 2 P46A Hl = 11.40, L2 = 4.45,132 = 5.34, A31 = 5.25, T32 = 73.55, Wax = 2 P47 Hl = 11.35, Bl = 4.88,132 = 5.32, A31 = 5.23, T32 = 73.22, Wax = 2 P47A Hl = 11.35, Bl = 4.88,132 = 5.32, A31 = 5.23, T32 = 73.22, Wax = 2 P48 Hl = 3.75, L2 = 2.25,132 = 5, A31 = 5, T32 = 84 , Wax = 2 P49 Hb 7.55, Bl = 3.25, 132 = 5.31, A31 = 5.21, T32 = 78.68, Wax = 2 P50 Hl = 4.83, L2 = 1.89? 132 = 5.31, A31 = 5.22, T32 = 82.75, Wax = 2 P51 Hl-7.15, L2 = 0.93,132 = 5.23, A31 = 5.14, T32 = 81.55, Wax = 2 P52 Bl = 8, D31 = 0.6, T3.8 = 91.4, Wax = 2 P53 Bl = 8, D31 = 0.6, T3.4 = 91.4, Wax = 2 P54 Bl = 8, D31 = 0.6, T3.2 = 91.4, Wax = 2 P55 Hl = 1.8, Bl = 7.2, D31 = 0.6, T3.4 = 90.4, Wax = 2 P56 Hl = 1.8, Bl = 7.2, D31 = 0.6, T3.2 = 90.4? Wax = 2 P56A Hl = 1.8, Bl = 7.2, D31 = 0.6, T3.2 = 90.4, Wax = 2 P57 Hl = 1.8 , Bl = 7.2, T3.2 = 91, Wax = 2 P58 L2 = 7.5, D31 = 0.6, T3.2 = 91.9, Wax = 2 P59 Hl = 0.4, Bl = 3, L2 = 4.5, D31 = 0.6, T3.2 = 91.5, Wax = 2 P62 Hl = 14.48, 132 = 5.09, A31 = 5.00, T3.2 = 75.43, Wax = 2 P62A Hl = 14.48,132 = 5.09, A31 = 5.00, T3.2 = 75.43, Wax = 2 P63 Hl = 12.47, L2 = 0.86,132 = 5.16, A31 = 5.07, T3.2 = 76.45, Wax = 2 P65 Hl = 7.57, L2 = 2.96,132 = 5.32, A31 = 5.23, T3.2 = 78.92, Wax = 2 P65A Hl = 7.57, L2 = 2.96,132 = 5.32, A31 = 5.23, T3.2 = 78.92, Wax = 2 P66 Hl = 27.92,132-4.91, A31 = 4.82, T3.2 = 62.35, Wax = 2 P67 Hl = 24.37, L3 = 1.62,132 = 5.04, A31 = 4.95, T32 = 32.01? T33 = 32.01, Wax = 2 P69 L2 = 7.5, D31 = 0.4, T3.2 = 92.1, Wax = 2 P70 Ll == 7.4, D31 = 0.3, T3.2 = 92.3, Wax = 2 P71 L3 = 7.2, D31 = 0.3, T3.2 = 92.5, Wax = 2 P72 Hl = 1.8, Bl = 7.2, D31 = 0.3, T3.2 = 90.7, Wax = 2 P73 Hl = 1.8, Bl = 4.8, L2 = 2.7, D31 = 0.3, T3.2 = 90.4 , Wax = 2 P74 Hl = 1.8, Bl = 3, L2 = 4.5, D31 = 0.3, T3.2 = 90.4, Wax = 2 P75 Hl = 0.8, Bl = 3, L2 = 4.5, D31 = 0.3, T3.2 = 91.4, Wax = 2 P76 Hl = 0.8, Bl = 3, Ll = 4.5, D31-0.3, T3.2 = 91.4, Wax = 2 P77 Hl = 0.8, Bl = 3, L3 = 4.5, D31 = 0.3, T3 .2 = 91.4, Wax = 2 P78 Hl = 0.8, Bl = 4.5, Ll = 3, D31 = 0.3, T3.2 = 91.4, Wax = 2 P79 Hl = 0.8, Bl = 4.5, L3 = 3.1, D31 = 0.3 , T3.2 = 91 .3, Wax = 2 Many representative types of hard metal compositions are described below. The design systems used to illustrate these hard metals include one or both of Re and Ni-based superalloys. These representative types of hard metal composition are based on the

1057D-6939-PF 200535255 一類係使用具有純 Re-Co的黏結劑基瓷金屬之黏結劑基質的組成而定義。第 Re之黏結劑基質，第二類係使用具有結劑基質，而第四基超合金的黏結劑質，第三類係使用具有Ni基超合金的黏類係使用具有結合Re而沒有c〇的Ni 基質。一般來說，用於硬金屬的硬且耐火的粒子係可以包括碳化物、氮化物、碳氮化物、硼化物以及矽化物。其中碳化物例如是 WC，TiC，TaC，Hfc，Nbc，M〇2C，％，z^， B4c與Sic。其中氮化物例如是丁iN，ZrN，HfN，VN，NbN，1057D-6939-PF 200535255 A class is defined using the composition of a binder matrix of pure Re-Co binder-based porcelain metal. For the No. Re binder matrix, the second type uses a binder matrix, and the fourth base superalloy is used as a binder, and the third type uses a Ni based superalloy, which has a binding Re without C. Ni matrix. Generally, hard and refractory particle systems for hard metals can include carbides, nitrides, carbonitrides, borides, and silicides. The carbides are, for example, WC, TiC, TaC, Hfc, Nbc, MoC,%, z ^, B4c, and Sic. Among them, the nitrides are, for example, butyl iN, ZrN, HfN, VN, NbN,

TaN與BN。其中碳氮化物例如是Ti(c，N)，丁a(c，N)，TaN and BN. The carbonitrides are, for example, Ti (c, N), buta (c, N),

Nb(C，N)，V(C，N)，Zr(C，N)。其中硼化物例如是 TiB2, ZrB2,Nb (C, N), V (C, N), Zr (C, N). Where the boride is, for example, TiB2, ZrB2,

HfB2, TaB2, VB2, M〇b2, WB與w2B。其中矽化物例如是HfB2, TaB2, VB2, MoB2, WB and w2B. Where silicide is for example

TaSl2，WSl2, NbSi2與MoSi2。上述四種類的硬金屬或陶瓷金屬也能夠使用這些和其他硬且耐火的粒子。在第一類的使用具有純Re之黏結劑基質的硬金屬或陶瓷金屬中，Re係佔整體硬金屬或陶瓷金屬體積的約 5〜40v〇l·%。例如表4中的批號p62具有以%、Μ。 70vol·/。 TiC 15v〇l·% 以及 Tac 5vol·%，該組成可換算成 Re 14.48wt.%、WC 75.43wt·%、TiC 5.09wt·% 以及 TaC 5.〇Wt.%。在製程中，試片P62-4係以2100t：真空燒結約工小時以及2158t真空燒結約}小時。該材料的密度約係 14.51g/cc，其計算密度（理想密度）係14.5〇g/cc。在室溫下的1〇Kg荷重下测量10次的平均硬度係2627±35Kg/mm2。所測的表面破壞韌性Ksc係約7.4E6Pa.m1/2,其係以在10KgTaSl2, WSl2, NbSi2 and MoSi2. These four kinds of hard metals or ceramic metals can also use these and other hard and refractory particles. In the first type of hard metal or ceramic metal using a binder matrix with pure Re, Re is about 5 to 40 vol.% Of the volume of the entire hard metal or ceramic metal. For example, the batch number p62 in Table 4 has%, M. 70vol · /. TiC 15v〇l ·% and Tac 5vol ·%, the composition can be converted into Re 14.48wt.%, WC 75.43wt ·%, TiC 5.09wt ·%, and TaC 5.〇Wt.%. In the manufacturing process, the test piece P62-4 is 2100t: vacuum sintering for about working hours and 2158t vacuum sintering for about} hours. The density of this material is about 14.51 g / cc, and its calculated density (ideal density) is 14.50 g / cc. The average hardness measured 10 times under a load of 10 Kg at room temperature was 2627 ± 35 Kg / mm2. The measured surface fracture toughness Ksc is about 7.4E6Pa.m1 / 2, which is about 10Kg.

1057D-6939-PF 101 '200535255 荷重下的Palmvist破裂強度而估計而得。在此種類下的另一個例子是表4中的P66。批號P66 的組成具有 Re 20vol·%、WC 60vol·%、TiC 15vol.% 以及 TaC 5vol·%，該組成可換算成 Re 27.92wt %、wC 62.35wt.%、TiC 4.91wt·% 以及 TaC 4.82wt·%。試片 P66-4 係先以2200°C真空燒結約1小時，然後在固相中以HIP製程除去多孔與孔隙。所得之硬金屬的密度約係14.40g/cc， _ 其计异密度係1 5 ·04g/cc。在室溫下的1 OKg荷重下測量7 次的平均硬度係2402士44Kg/mm2。所測的表面破壞韌性Ksc 係約8.1E6Pa.m1/2。試品P66以及在此所述的其他具有高濃度Re(重量百分比大於25%)的組合物，係當作獨一的黏結 4材料或黏結劑中的兩種或多種不同黏結劑材料之一，其能夠用於高操作溫度下的各種應用，以及可基於固相燒結的兩階段製程。硬耐火粒子的與Re多重化合種類的微結構和特性， φ 例如碳化物、氮化物、碳氮化物、矽化物以及主體，係能夠提供比與Re化合的WC材料更多的優點。例如，與 WC-TiC-TaC化合的Re係能夠提供比與wc材料化合的Re 更好的切削鋼的抗坑孔（crater resistance)特性。另一例子係由MhC耐火粒子以及與TiC化合於其中的“黏結劑所構成之材料。關於第二類的具有Re-Co合金之黏結劑基質，該 Rtco合金約佔總體材料組成之5〜40v〇1%。在一些實施例中’黏結劑中的Re/Co之比例係約。跟具有化人 1057D-6939-PF 102 200535255 C〇的硬金屬相比較，含有Re的組合物可以改善所得硬金屬的機械性質，例如在高溫下的硬度、強度和韌性。點結 ^基貝中的Re含量越多的話，則在南溫下的特性越好。此種類的另一個例子是表4中的P3 1。P3 1的組成具有 Re 2.5v〇l.%、c〇 7·5νο1·% 以及 WC 90vol·%，該組成可換异成 Re 3.44wt·%、Co 4_40wt·% 以及 WC 92.12wt·%。在製程中’試片P3U係以1725〇c真空燒結約1小時，在此 • 燒結下有少量的孔洞存在。所得硬金屬的密度約係 15el6g/cc，其計算密度係15.2 7g/cc。在室溫下的l〇Kg荷重下測的平均硬度係1889士 18Kg/mm2。所測的表面破壞韋刃性Ksc係約7 7E6Pa.mi/2。除此之外，在燒結之後，試片 P3 1-1再經過約16〇〇°C /15Ksi之約一小時的HIP處理。該 HIP處理可以實質地消除混合物中的空孔間隙，而增加材料密度。經過HIP處理之後，所測得的密度約是15.25g/cc，其汁异密度係15.27g/cc。在室溫下的10Kg荷重下測的平 φ 均硬度係1 889土 18Kg/mm2。所測的表面破壞韌性Ksc係約 7.6E6Pa m1/2。此種類的另一個例子是表4中的P32。P32的組成具有 Re 5·0νο1·%、Co 5.0vol.% 以及 WC 90vol·%，該組成可換算成 Re 6.75wt·%、Co 2.88wt·%以及 WC 90.38wt·%。在製程中，試片P32_4係以18〇〇它真空燒結約1小時。所得硬金屬的密度約係15.58g/cc，其計算密度係I5.57g/cc。在室溫下的l〇Kg荷重下測的平均硬度係2〇65Kg/mm2。所測的表面破壞韌性Ksc係約5.9E6Pa.m1/2。在燒結之後，試片 1057D-6939-PF 103 200535255 P3 2-4亦再經過約1600°C /15Ksi之約一小時的HIP處理。經過HIP處理之後，所測得的密度約是15.57g/cc，其計算密度係15.57g/cc。在室溫下的l〇Kg荷重下測的平均硬度係 2012±12Kg/mm2。所測的表面破壞韋刃性 Ksc係約 5.8E6Pa-m1/2。第三個例子是表4中的P33°P33的組成具有Re 7·5νο1·%、Co 2·5νο1·% 以及 WC 90vol·%，該組成可換算成 Re 9.93wt·%、Co 1.41wt·%以及 WC 88.66wt.〇/〇。在製程中， ^ 試片P33-7係以1950°C真空燒結約1小時，且仍有孔隙存在。所得硬金屬的密度約係 15.38g/cc，其計算密度係 15.87g/cc。在室溫下的 10Kg荷重下測的平均硬度係 208 1 Kg/mm2。戶斤測的表面破壞韋刃性Ksc係約5.6E6Pa m1/2 〇在燒結之後，試片P3 3-7亦再經過約1600°C/15Ksi之約一小時的HIP處理。經過HIP處理之後，所測得的密度約是 15.82g/cc，其計算密度係I5.87g/cc。在室溫下的10Kg荷 _ 重下測的平均硬度係2039土 18Kg/mm2。所測的表面破壞韌性 Ksc 係約 6.5E6Pa.m1/2。表5化合有Re-Co合金的硬金屬溫度。C 密度g/cc 硬度韌性晶粒尺寸燒結 HIP 計算的測量的 Kg/mm2 xlO6 Pa*m1/2 P55-1 1350 1300 14.77 14.79 2047 8.6 極細 P56-5 1360 1300 14.77 14.72 2133 8.6 極細 P56A-4 1350 1300 14.77 14.71 2108 8.5 極細 P57-1 1350 1300 14.91 14.93 1747 12.3 細表4中的試品P55、P56A以及P57係具有將Re-Co合金1057D-6939-PF 101 '200535255 Palmvist rupture strength under load. Another example in this category is P66 in Table 4. The composition of Lot No. P66 has Re 20vol ·%, WC 60vol ·%, TiC 15vol.% And TaC 5vol ·%. The composition can be converted to Re 27.92wt%, wC 62.35wt.%, TiC 4.91wt ·% and TaC 4.82wt. ·%. The test piece P66-4 was first sintered at 2200 ° C under vacuum for about 1 hour, and then the porosity and pores were removed by a HIP process in the solid phase. The density of the obtained hard metal is about 14.40 g / cc, and the specific density is 1 5 · 04 g / cc. The average hardness measured 7 times under a load of 1 OKg at room temperature is 2402 ± 44Kg / mm2. The measured surface fracture toughness Ksc is about 8.1E6Pa.m1 / 2. Test product P66 and other compositions with a high concentration of Re (greater than 25% by weight) described herein are considered to be one of two or more different adhesive materials among the only adhesive 4 materials, It can be used for a variety of applications at high operating temperatures, as well as a two-stage process that can be based on solid phase sintering. The microstructure and characteristics of multiple refractory compound types of hard refractory particles, such as carbides, nitrides, carbonitrides, silicides, and hosts, can provide more advantages than WC materials compounded with Re. For example, the Re system compounded with WC-TiC-TaC can provide better cracker resistance characteristics of cutting steel than the Re compound compounded with wc material. Another example is a material composed of MhC refractory particles and a "binder" combined with TiC. Regarding the second type of binder matrix with a Re-Co alloy, the Rtco alloy accounts for about 5 to 40v of the overall material composition 〇1%. In some embodiments, the ratio of Re / Co in the binder is about. Compared to hard metals with Huaren 1057D-6939-PF 102 200535255 C〇, the composition containing Re can improve the resulting hard Mechanical properties of metals, such as hardness, strength, and toughness at high temperatures. The more Re content in pits, the better the characteristics at South temperature. Another example of this type is shown in Table 4. The composition of P3 1. The composition of P3 1 has Re 2.5 vol. 1%, co 7 · 5 ν 1 ·%, and WC 90 vol ·%, and the composition can be changed to Re 3.44 wt ·%, Co 4_40 wt ·%, and WC 92.12 wt · %. In the process, 'test piece P3U is sintered at 1725 ° C for about 1 hour. There are a small number of holes under sintering. The density of the obtained hard metal is about 15el6g / cc, and its calculated density is 15.2 7g / cc The average hardness measured under a load of 10Kg at room temperature is 1889 ± 18Kg / mm2. The surface-destroying Ksc system is about 7 7E6Pa.mi / 2. In addition, after sintering, the test piece P3 1-1 is further subjected to HIP treatment at about 1600 ° C / 15Ksi for about one hour. The HIP The treatment can substantially eliminate the void space in the mixture, and increase the material density. After HIP treatment, the measured density is about 15.25g / cc, and its juice density is 15.27g / cc. 10Kg at room temperature The flat φ average hardness measured under load is 1 889 soil 18 Kg / mm2. The measured surface fracture toughness Ksc system is about 7.6E6Pa m1 / 2. Another example of this type is P32 in Table 4. The composition of P32 has Re 5 · 0νο1 ·%, Co 5.0vol.%, And WC 90vol ·%, the composition can be converted into Re 6.75wt ·%, Co 2.88wt ·%, and WC 90.38wt ·%. In the production process, the test piece P32_4 is 18 °. 〇It was sintered in vacuum for about 1 hour. The density of the obtained hard metal was about 15.58 g / cc, and its calculated density was I5.57 g / cc. The average hardness measured under a 10 Kg load at room temperature was 2065 Kg / mm 2 The measured surface fracture toughness Ksc is about 5.9E6Pa.m1 / 2. After sintering, the test piece 1057D-6939-PF 103 200535255 P3 2-4 also passed about 1600 ° C / 15Ksi. HIP treatment is one hour. After the HIP, the measured density is about 15.57g / cc, the density calculated based 15.57g / cc. The average hardness measured under a load of 10Kg at room temperature is 2012 ± 12Kg / mm2. The measured surface-destroying Ksc is about 5.8E6Pa-m1 / 2. The third example is that the composition of P33 ° P33 in Table 4 has Re 7 · 5νο1 ·%, Co 2 · 5νο1 ·%, and WC 90vol ·%. The composition can be converted into Re 9.93wt ·%, Co 1.41wt ·% And WC 88.66 wt. 0 / 〇. During the manufacturing process, the test piece P33-7 was vacuum sintered at 1950 ° C for about 1 hour, and there were still pores. The density of the obtained hard metal was about 15.38 g / cc, and its calculated density was 15.87 g / cc. The average hardness measured under a 10 Kg load at room temperature is 208 1 Kg / mm2. The surface damage measured by the household weight is about 5.6E6Pa m1 / 2. After the sintering, the test piece P3 3-7 is also subjected to HIP treatment at about 1600 ° C / 15Ksi for about one hour. After HIP treatment, the measured density is about 15.82g / cc, and the calculated density is I5.87g / cc. The average hardness measured under a 10Kg load at room temperature is 2039 soil and 18Kg / mm2. The measured surface damage toughness Ksc is about 6.5E6Pa.m1 / 2. Table 5 Temperatures of hard metals combined with Re-Co alloys. C Density g / cc Hardness Toughness Grain size Sintered HIP Calculated measured Kg / mm2 xlO6 Pa * m1 / 2 P55-1 1350 1300 14.77 14.79 2047 8.6 Very fine P56-5 1360 1300 14.77 14.72 2133 8.6 Very fine P56A-4 1350 1300 14.77 14.71 2108 8.5 Ultra-fine P57-1 1350 1300 14.91 14.93 1747 12.3 Samples P55, P56A, and P57 in Table 4 have a Re-Co alloy

1057D-6939-PF 104 200535255 當作黏結劑基質的種類之例子。除了 P57不含VC之外，這些試品係含有Re 1·8°/〇、Co 7.2°/。以及VC 0.6%，其餘是WC。這些不同的組成係用來研究硬金屬的晶粒尺寸對硬度Hv與韌性 Ksc的影響。表6 Ni基超合金，Ni, Re與Co的特性測試溫度 C R-95 U-700 U720 Ni Re Co 密度(g/c.c.) 21 8.2 7.9 8.1 8.9 21 8.9 熔點(°C) 1255 1205 1210 1450 3180 1495 彈性係數(Gpa) 21 30.3 32.4 32.2 207 460 211 最大拉伸強度 (Mp& 21 1620 1410 1570 317 1069 234 760 1170 1035 1455 800 620 870 690 1150 1200 414 0.2% 降伏強度 (Mpa) 21 1310 965 1195 60 760 1100 825 1050 800 870 635 1200 拉伸延長率 (%) 21 15 17 13 30 >15 760 15 20 9 800 5 870 27 1200 2 抗氧化性優優優好差好第三種類係根據具有Ni基超合金的黏結劑基質，其 Ni基超合金係佔所得硬金屬中所有材料的5〜40vol.%。Ni 基超合金係具有γ’強化機制的高溫合金。三種不同的強化合金Rene’95, Udimet 720與Udimet 700係被當作是例子而展現黏結劑強度效應於硬金屬的機械性質。該等Ni基超合金特別在高溫下具有高強度，而且具有良好的環境抵抗 1051057D-6939-PF 104 200535255 is an example of the type of adhesive matrix. Except that P57 does not contain VC, these test lines contain Re 1.8 ° / 〇, Co 7.2 ° /. And VC 0.6%, the rest is WC. These different compositions are used to study the effect of the grain size of hard metals on the hardness Hv and toughness Ksc. Table 6 Characteristics of Ni-based superalloys, Ni, Re and Co. Test temperature C R-95 U-700 U720 Ni Re Co Density (g / cc) 21 8.2 7.9 8.1 8.9 21 8.9 Melting point (° C) 1255 1205 1210 1450 3180 1495 Coefficient of elasticity (Gpa) 21 30.3 32.4 32.2 207 460 211 Maximum tensile strength (Mp & 21 1620 1410 1570 317 1069 234 760 1170 1035 1455 800 620 870 690 1150 1200 414 0.2% Drop strength (Mpa) 21 1310 965 1195 60 760 1100 825 1050 800 870 635 1200 Tensile elongation (%) 21 15 17 13 30 > 15 760 15 20 9 800 5 870 27 1200 2 Excellent oxidation resistance Ni-based superalloys of alloys account for 5 to 40 vol.% Of all materials in the obtained hard metal. Ni-based superalloys are high-temperature alloys with a γ 'strengthening mechanism. Three different strengthening alloys Rene'95, Udimet The 720 and Udimet 700 series are taken as examples to show the mechanical properties of hard metals due to the strength of the binder. These Ni-based superalloys have high strength especially at high temperatures, and have good properties. Environmental resistance 105

1057D-6939-PF •200535255 性，例如抗姓、抗氧化。因此，與化合有C 0的硬金屬相比較，該等Ni基超合金可以增加化合有Ni基超合金的硬金屬之硬度。要注意的是，如表6所示，該等Ni基超合金的拉伸強度遠大於一般黏結劑材料C 〇。這顯示N i基超合金對於硬金屬來說，是一個很好的黏結劑材料。此種類的一例是表4中的 P 5 8。P 5 8的組成具有 Rene，95 7.5wt·%、VC 0.6wt·% 以及 WC 91.9wt·。/。，並與表 4 中的 Co 化合物 P54(8%Co，0.6°/〇VC 與 91.4%WC)比較。 ® 如表7所示，P58的硬度明顯大於P54。表7 P54和:P58的比較燒結 HIP 硬度 (Kg/mm2) 韌性 (xlO6 Pa.m1’2) P54-1 1350〇C /lhr 2094 8.8 P54-2 1380〇C /lhr 2071 7.8 P54-3 1420〇C / lhr 在 Arlhr 下，1305°C， 2107 8.5 P58-1 在 1350, 1380, 1400, 1420, 1450, 1475 的各溫度艺下lhr 15KSI 2322 7.0 P58-3 1450〇C / lhr 2272 7.4 P58-5 1500°C / lhr 2259 7.2 P58-7 1550〇C / lhr 2246 7.3 第四種類係Ni基超合金加上Re而當作是黏結劑基質，其係佔所得硬金屬或陶瓷金屬中所有材料的 5〜40vol.%。因為添加Re可增加上述添加有Re的Ni基超合金的黏結劑的溶點，所以當Re含量增加時，具有上述添加有Re的Ni基超合金的硬金屬的製程溫度就會跟著增加。具有不同Re濃度之各種硬金屬係列於表8中。表9 則顯示列於表8中之硬金屬的所測性質。 1057D-6939-PF 106 '2005352551057D-6939-PF • 200535255, such as anti-surname, anti-oxidation. Therefore, these Ni-based superalloys can increase the hardness of hard metals compounded with Ni-based superalloys compared to hard metals compounded with Co. It should be noted that, as shown in Table 6, the tensile strength of these Ni-based superalloys is much larger than that of the common binder material C0. This shows that Ni-based superalloy is a good binder material for hard metals. An example of this kind is P 5 8 in Table 4. The composition of P 5 8 has Rene, 95 7.5 wt ·%, VC 0.6 wt ·%, and WC 91.9 wt ·. /. And compared with Co compound P54 (8% Co, 0.6 ° / 〇VC and 91.4% WC) in Table 4. ® As shown in Table 7, the hardness of P58 is significantly greater than that of P54. Table 7 Comparative sintered HIP hardness of P54 and P58 (Kg / mm2) Toughness (xlO6 Pa.m1'2) P54-1 1350〇C / lhr 2094 8.8 P54-2 1380〇C / lhr 2071 7.8 P54-3 1420 C / lhr at Arlhr, 1305 ° C, 2107 8.5 P58-1 at various temperatures of 1350, 1380, 1400, 1420, 1450, 1475 lhr 15KSI 2322 7.0 P58-3 1450 ° C / lhr 2272 7.4 P58-5 1500 ° C / lhr 2259 7.2 P58-7 1550 ° C / lhr 2246 7.3 The fourth type is a Ni-based superalloy plus Re as a binder matrix, which accounts for 5% of all materials in the obtained hard or ceramic metal. ~ 40vol.%. Because the addition of Re can increase the melting point of the above-mentioned Re-added Ni-based superalloy binder, when the Re content increases, the process temperature of the hard metal with the above-mentioned Re-added Ni-based superalloy will also increase. Various hard metal series with different Re concentrations are shown in Table 8. Table 9 shows the measured properties of the hard metals listed in Table 8. 1057D-6939-PF 106 '200535255

表8具有Ni基超合金與Re的黏結劑之硬金屬組成，Wt.°/o Re於黏結劑中之比例燒結溫度。C Re Rene95 U-700 U-720 WC TiC TaC P17 1.5 4.5 88 3 3 25% 1600〜1750 P18 3 3.0 88 3 3 50% 1600〜1775 P25 3.75 2.25 88 3 3 62.5% 1650〜1825 P48 3.75 2.25 84 5 5 62.5% 1650〜1825 P50 4.83 1.89 82.75 5.31 5.22 71.9% 1675〜1850 P40 7.57 2.96 78.92 5.32 5.23 71.9% 1675〜1850 P46 11.40 4.45 73.55 5.34 5.24 71.9% 1675-1850 P51 7.15 0.93 81.55 5.23 5.14 88.5% 1700〜1900 P41 11.10 1.45 77.14 5.20 5.11 88.5% 1700〜1900 P63 12.47 0.86 76.45 5.16 5.07 93.6% 1850〜2100 P19 1.5 4.5 88 3 3 25% 1600〜1750 P20 3 3 88 3 3 50% 1600〜1775 P67 24.37 1.62 64.02 5.04 4.95 93.6% 1950〜2300Table 8 Hard metal composition with Ni-based superalloy and Re binder, Wt. ° / o Re to binder ratio Sintering temperature. C Re Rene95 U-700 U-720 WC TiC TaC P17 1.5 4.5 88 3 3 25% 1600 ~ 1750 P18 3 3.0 88 3 3 50% 1600 ~ 1775 P25 3.75 2.25 88 3 3 62.5% 1650 ~ 1825 P48 3.75 2.25 84 5 5 62.5% 1650 ~ 1825 P50 4.83 1.89 82.75 5.31 5.22 71.9% 1675 ~ 1850 P40 7.57 2.96 78.92 5.32 5.23 71.9% 1675 ~ 1850 P46 11.40 4.45 73.55 5.34 5.24 71.9% 1675-1850 P51 7.15 0.93 81.55 5.23 5.14 88.5% 1700 ~ 1900 P41 11.10 1.45 77.14 5.20 5.11 88.5% 1700 ~ 1900 P63 12.47 0.86 76.45 5.16 5.07 93.6% 1850 ~ 2100 P19 1.5 4.5 88 3 3 25% 1600 ~ 1750 P20 3 3 88 3 3 50% 1600 ~ 1775 P67 24.37 1.62 64.02 5.04 4.95 93.6% 1950 ~ 2300

表9具有Ni基超合金與Re的黏結劑之硬金屬的性質溫度。C 密度g/cc 硬度Hv 韌性Ksc 燒結 HIP 計算的測量的 Kg/mm2 xl06Pa.m1/2 P17 1700 14.15 14.18 2120 6.8 P17 1700 1600 14.15 14.21 2092 7.2 P18 1700 14.38 14.47 2168 5.9 P18 1700 1600 14.38 14.42 2142 6.1 P25 1750 14.49 14.41 2271 6.1 P25 1750 1600 14.49 14.48 2193 6.5 P48 1800 1600 13.91 13.99 2208 6.3 P50 1800 1600 13.9 13.78 2321 6.5 P40 1800 13.86 13.82 2343 P40 1800 1600 13.86 13.86 2321 6.3 P46 1800 13.81 13.88 2282 7.1 P46 1800 1725 13.81 13.82 2326 6.7 P51 1800 1600 14.11 13.97 2309 6.6Table 9 Properties and temperatures of hard metals with Ni-based superalloy and Re binders. C Density g / cc Hardness Hv Toughness Ksc Sintered HIP Calculated measured Kg / mm2 xl06Pa.m1 / 2 P17 1700 14.15 14.18 2120 6.8 P17 1700 1600 14.15 14.21 2092 7.2 P18 1700 14.38 14.47 2168 5.9 P18 1700 1600 14.38 14.42 2142 6.1 P25 1750 14.49 14.41 2271 6.1 P25 1750 1600 14.49 14.48 2193 6.5 P48 1800 1600 13.91 13.99 2208 6.3 P50 1800 1600 13.9 13.78 2321 6.5 P40 1800 13.86 13.82 2343 P40 1800 1600 13.86 13.86 13.86 2321 6.3 P46 1800 13.81 13.88 2282 7.1 P46 1800 1725 13.81 13.81 6.7 P51 1800 1600 14.11 13.97 2309 6.6

1057D-6939-PF 107 •2005352551057D-6939-PF 107 • 200535255

一例子係使用5〜40vol·%的黏結劑，該觀 :d係u s Νι基超合金、Re與c〇。包含有化合犯基超口金、Re與C〇的硬金屬之代表組成係列於表1 〇中。合Ni基超合金、Re與co的硬金屬之組成An example is the use of 5 to 40 vol.% Of the binder, the concept: d series u s Ni-based superalloy, Re and co. The representative composition series of the hard metal containing the compound gold, Re and Co is shown in Table 10. Composition of Ni-based superalloy, Re and Co hard metals

測，式一些所選擇的試品而來研究具有川超合金的黏結劑基質的特性。-般來說’ ；^超合金不僅提升高溫下的強度，而且在高溫下有優㈣抗氧純與抗腐錄。见超合金有複雜的微結構和強度機制。-般來說，^超合金主要是〆的析出強化和固溶強化。所以這些測量結輸Ni超合金可以作為具有優良功效之硬金屬的黏結劑材料。表Η係列出一些所選的試品中各組成佔硬金屬總重的重量百分率。其試品中的wc粒子的尺寸係〇 2_。表In order to study the characteristics of the binder matrix with Sichuan superalloy, some selected samples were tested. -Generally speaking; ^ Superalloys not only improve the strength at high temperature, but also have excellent anti-oxidation purity and corrosion resistance at high temperature. See superalloys have complex microstructures and strength mechanisms. -Generally speaking, superalloys are mainly precipitation strengthening and solid solution strengthening of rhenium. Therefore, these measured Ni superalloys can be used as adhesive materials for hard metals with excellent efficacy. Table Η series shows the weight percentages of the components in the selected samples to the total weight of the hard metal. The size of wc particles in the test sample was 0 2_. table

1057D-6939-PF 108 200535255 1 2係列出兩階段製程的條件以及試品的所測密度、硬度參數以及韋刃性參數。表中的Palmqvist破壞勃性Ksc係從 Vicker Indentor公司製造之Palmqvist破裂強度測試機的總破裂強度計算而得，其Ksc = 0.087*(Hv*W)1/2。其推算方式可參閱 Warren and H.Matzke， Proceedings of the International Conference On the Science of Hard Materials,1057D-6939-PF 108 200535255 1 The 2 series shows the conditions of the two-stage process, as well as the measured density, hardness parameters, and edge sharpness parameters of the test sample. The Palmscvist fracture agility Ksc in the table is calculated from the total burst strength of a Palmqvist burst strength tester manufactured by Vicker Indentor, and its Ksc = 0.087 * (Hv * W) 1/2. Its calculation method can be found in Warren and H. Matzke, Proceedings of the International Conference On the Science of Hard Materials,

Jackson，Wyoming，Aug 23-28，1981。硬度 Hv 和破裂長度係在1 OKg荷重下測試1 5秒。在每一測試中，每一試片都有八個壓痕以及用於所列資料之計算結果的平均值。表11Jackson, Wyoming, Aug 23-28, 1981. The hardness Hv and rupture length were tested under a load of 1 OKg for 15 seconds. In each test, each test piece had eight indentations and the average of the calculated results for the listed data. Table 11

重量％體積％ Re Co R-95 WC VC 黏結劑中的Re 黏結劑 P54 0 8 0 91.4 0.6 0 13.13 P58 0 0 7.5 91.9 0.6 0 13.25 P56 1.8 7.2 0 90.4 0.6 20 13.20 P72 1.8 7.2 0 90.7 0.3 20 13.18 P73 1.8 4.8 2.7 90.4 0.3 20 14.00 P74 1.8 3 4.5 90.4 0.3 20 14.24 表12 試品編號燒結條件 HIP條件計算密度 g/c.c. 測量密度g/c.c. 硬度 HvKg/mm2 Palmqvist 韋刃性 Ksc E6Pa -m,/2 P54-5 1360〇C/lhr 14.63 14.58 2062±35 8.9±0.2 1360〇C/lhr 1305〇C/15KSI/lhr 14.55 2090±22 8.5 土 0.2 P58-7 1550〇C/lhr 14.50 14.40 2064土 12 7.9 土 0.2 1550〇C/lhr 1305〇C/15KSI/lhr 14.49 2246±23 7.3 士 0.1 P56-5 1360〇C/lhr 14.77 14.71 2064±23 8.2 士 0.1 1360〇C/lhr 1305〇C/15KSI/lhr 14.72 2133 士 34 8.6±0.2 P72-6 1475〇C/lhr 14.83 14.77 2036士 34 8.5 土 0.6 1475〇C/lhr 1305〇C/15KSI/lhr 14.91 2041士30 9.1 士 0.4 P73-6 1475〇C/lhr 14.73 14.70 2195±23 7.7±0.1 109Weight% Vol% Re Co R-95 WC VC Re Adhesive P54 0 8 0 91.4 0.6 0 13.13 P58 0 0 7.5 91.9 0.6 0 13.25 P56 1.8 7.2 0 90.4 0.6 20 13.20 P72 1.8 7.2 0 90.7 0.3 20 13.18 P73 1.8 4.8 2.7 90.4 0.3 20 14.00 P74 1.8 3 4.5 90.4 0.3 20 14.24 Table 12 Sample number Sintering condition HIP condition Calculated density g / cc Measured density g / cc Hardness HvKg / mm2 Palmqvist Welding edge Ksc E6Pa -m, / 2 P54-5 1360 ° C / lhr 14.63 14.58 2062 ± 35 8.9 ± 0.2 1360 ° C / lhr 1305 ° C / 15KSI / lhr 14.55 2090 ± 22 8.5 soil 0.2 P58-7 1550 ° C / lhr 14.50 14.40 2064 soil 12 7.9 soil 0.2 1550 ° C / lhr 1305 ° C / 15KSI / lhr 14.49 2246 ± 23 7.3 ± 0.1 P56-5 1360 ° C / lhr 14.77 14.71 2064 ± 23 8.2 ± 0.1 1360 ° C / lhr 1305 ° C / 15KSI / lhr 14.72 2133 Taxi 34 8.6 ± 0.2 P72-6 1475 ° C / lhr 14.83 14.77 2036 Tax 34 8.5 Soil 0.6 1475 ° C / lhr 1305 ° C / 15KSI / lhr 14.91 2041 ± 30 9.1 Tax 0.4 P73-6 1475 ° C / lhr 14.73 14.70 2195 ± 23 7.7 ± 0.1 109

1057D-6939-PF 200535255 1475〇C/lhr 1305〇C/15KSI/lhr 14.72 2217士25 8.1 士 0.2 P74-5 1500°C/lhr and 1520〇C/lhr 14.69 14.69 2173士30 7.4 士 0.3 1500o〇C/lhr and 1520〇C/lhr 1305〇C/15KSI/lhr 14.74 2223士 34 7.7±0·1 在這些試品中，試品P54係使用傳統的含Co黏結劑。試品P58係使用Ni超合金來取代P54中的Co而當作是黏結劑。因此，Hv硬度從P54的2090提升到P58的2246。在試品Ρ56中，係使用Re與Co的混合物來取代Co來當作是黏結劑，且其對應的Hv係從P54的2090提升到P56 的2133。試品P72、P73與P74係具有相同含量的Re，但有不同含量之Co與R95。使用於試品P73與P74中的Re， Co與R95混合物，係用來取代試品P72中的當作是黏結劑之Re與Co的混合物。其硬度從2041(P72)到2217(P73)與 2223(P74) ° 表13 重量％體積％ Re R-95 Co TiC TaC WC (2μηι) WC (0.2μιη) 黏結劑中的Re 黏結劑 Ρ17 1.5 4.5 0 3 3 88 0 25 8.78 Ρ18 3 3 0 3 3 88 0 50 7.31 Ρ25 3.75 2.25 0 3 3 88 0 62.5 6.57 Ρ48 3.75 2.25 0 5 5 84 0 62.5 6.3 Ρ50 4.83 1.89 0 5.31 5.22 82.75 0 71.9 6.4 Ρ51 7.15 0.93 0 5.23 5.14 81.55 0 88.5 6.4 Ρ49 7.55 0 3.25 5.31 5.21 78.68 0 69.9 10 Ρ40Α 7.57 2.96 0 5.32 5.23 78.92 0 71.9 10 Ρ63 12.47 0.86 0 5.16 5.07 0 76.45 93.6 101057D-6939-PF 200535255 1475 ° C / lhr 1305 ° C / 15KSI / lhr 14.72 2217 ± 25 8.1 ± 0.2 P74-5 1500 ° C / lhr and 1520 ° C / lhr 14.69 14.69 2173 ± 30 7.4 ± 0.3 1500 ° C / lhr and 1520 ° C / lhr 1305 ° C / 15KSI / lhr 14.74 2223 ± 34 7.7 ± 0.1 In these samples, sample P54 uses a conventional Co-containing binder. Sample P58 used Ni superalloy instead of Co in P54 as a binder. Therefore, the Hv hardness increased from 2090 at P54 to 2246 at P58. In test product P56, a mixture of Re and Co was used instead of Co as a binder, and the corresponding Hv system was increased from 2090 in P54 to 2133 in P56. The samples P72, P73 and P74 have the same content of Re, but different contents of Co and R95. The mixture of Re, Co and R95 in samples P73 and P74 is used to replace the mixture of Re and Co which is used as a binder in sample P72. Its hardness ranges from 2041 (P72) to 2217 (P73) and 2223 (P74) ° Table 13 Weight% Vol% Re R-95 Co TiC TaC WC (2μηι) WC (0.2μιη) Re Adhesive P17 1.5 4.5 0 3 3 88 0 25 8.78 P18 3 3 0 3 3 88 0 50 7.31 P25 3.75 2.25 0 3 3 88 0 62.5 6.57 P48 3.75 2.25 0 5 5 84 0 62.5 6.3 P50 4.83 1.89 0 5.31 5.22 82.75 0 71.9 6.4 P51 7.15 0.93 0 5.23 5.14 81.55 0 88.5 6.4 P49 7.55 0 3.25 5.31 5.21 78.68 0 69.9 10 P40A 7.57 2.96 0 5.32 5.23 78.92 0 71.9 10 P63 12.47 0.86 0 5.16 5.07 0 76.45 93.6 10

110110

1057D-6939-PF 200535255 Ρ62Α 14.48 0 0 5.09 5.00 0 75.43 100 10 Ρ66 27.92 0 0 4.91 4.82 0 62.35 100 20 測試一些所選擇的試品而來研究具有Re的黏結劑基質的特性。表13係所測試的試品。具有2μπι與0·2μπι兩種不同尺寸之WC粒子係被使用。表1 4係列出兩階段製程的條件以及所選之試品的所測密度、硬度參數以及韌性參數0 表141057D-6939-PF 200535255 P62A 14.48 0 0 5.09 5.00 0 75.43 100 10 P66 27.92 0 0 4.91 4.82 0 62.35 100 20 Test some selected samples to study the properties of the binder matrix with Re. Table 13 shows the samples tested. WC particles with two different sizes of 2 μm and 0.2 μm are used. Table 1 The conditions of the two-stage process in the 4 series and the measured density, hardness parameters and toughness parameters of the selected test samples. 0 Table 14

HIP傲牛計算密度g/c.c. 沏盪密度g/c.c. 搬 HvKg/mm2 Palmqvistlffl生 KscE6Pa-m1/2 Ρ17-5 1800°C/lhr 1600〇C/15KSI/lhr 14.15 14.21 2092士 3 7.2±0.1 Ρ18-3 1800°C/lhr 1600〇C/15KSI/lhr 14.38 14.59 2028士88 6.8 士 0.3 Ρ25-3 1750〇C/lhr 1600〇C/15KSI/lhr 14.49 14.48 2193±8 6.5±0.1 Ρ48-1 1800°C/lhr 1600〇C/15KSI/lhr 13.91 13.99 2208±12 6.3±0.4 Ρ50-4 1800°C/lhr 1600t：/15KSI/lhr 13.9 13.8 2294土 20 6.3 士 0.1 Ρ51-1 1800°C/lhr 1600〇C/15KSI/lhr 14.11 13.97 2309士 6 6.6 土 0.1 Ρ40Α-1 1800°C/lhr 1600〇C/15KSI/lhr 13.86 13.86 2321士 10 6.3±0.1 Ρ49-1 1800°C/lhr 1600〇C/15KSI/lhr 13.91 13.92 2186±29 6.5 士 0.2 Ρ62Α-6 2200〇C/lhr 1725〇C/30KSI/lhr 14.5 14.41 2688±22 6.7 士 0.1 Ρ63-5 2200〇C/lhr 1725〇C/30KSI/lhr 14.31 14.37 2562±31 6.7±0.2 Ρ66-4 2200〇C/lhr 15.04 14.40 2402士44 8.2 土 0.4 Ρ66-4 2200〇C/lhr 1725〇C/30KSI/lhr 15.04 14.52 Ρ66-4 2200〇C/lhr 1725〇C/30KSI/lhr +1950〇C/30KSI/lhr 15.04 14.53 2438士47 6.9±0.2 Ρ66-5 2200〇C/lhr 15.04 14.33 2092±23 7.3 土 0.3 Ρ66-5 2200〇C/lhr 1725〇C/30KSI/lhr 15.04 14.63 Ρ66-5 2200〇C/lhr 1725〇C/30KSI/lhr +1850〇C/30KSI/lhr 15.04 14.66 2207士17 7.1 土 0.2 表1 5更顯示出所選試品在各不同溫度下的所測硬度 111HIP Calculated Density g / cc Brew Density g / cc Move HvKg / mm2 Palmqvistlffl Raw KscE6Pa-m1 / 2 P17-5 1800 ° C / lhr 1600 ° C / 15KSI / lhr 14.15 14.21 2092 ± 3 7.2 ± 0.1 P18- 3 1800 ° C / lhr 1600 ° C / 15KSI / lhr 14.38 14.59 2028 ± 88 6.8 ± 0.3 P25-3 1750 ° C / lhr 1600 ° C / 15KSI / lhr 14.49 14.48 2193 ± 8 6.5 ± 0.1 Ρ48-1 1800 ° C / lhr 1600 ° C / 15KSI / lhr 13.91 13.99 2208 ± 12 6.3 ± 0.4 P50-4 1800 ° C / lhr 1600t: / 15KSI / lhr 13.9 13.8 2294 soil 20 6.3 ± 0.1 ρ51-1 1800 ° C / lhr 1600 ° C / 15KSI / lhr 14.11 13.97 2309 ± 6 6.6 Soil 0.1 Ρ40Α-1 1800 ° C / lhr 1600 ° C / 15KSI / lhr 13.86 13.86 2321 ± 10 6.3 ± 0.1 ρ49-1 1800 ° C / lhr 1600 ° C / 15KSI / lhr 13.91 13.92 2186 ± 29 6.5 ± 0.2 P62A-6 2200 ° C / lhr 1725 ° C / 30KSI / lhr 14.5 14.41 2688 ± 22 6.7 ± 0.1 P63-5 2200 ° C / lhr 1725 ° C / 30KSI / lhr 14.31 14.37 2562 ± 31 6.7 ± 0.2 P66-4 2200 ° C / lhr 15.04 14.40 2402 ± 44 8.2 Soil 0.4 P66-4 2200 ° C / lhr 1725 ° C / 30KSI / lhr 15.04 14.52 P66-4 2200 ° C / lhr 1725 ° C / 30KSI / lhr + 1950 ° C / 30KSI / lhr 15.04 14.53 2438 ± 47 6. 9 ± 0.2 P66-5 2200 ° C / lhr 15.04 14.33 2092 ± 23 7.3 Soil 0.3 P66-5 2200 ° C / lhr 1725 ° C / 30KSI / lhr 15.04 14.63 P66-5 2200 ° C / lhr 1725 ° C / 30KSI / lhr + 1850 ° C / 30KSI / lhr 15.04 14.66 2207 ± 17 7.1 Soil 0.2

1057D-6939-PF ，200535255 參數，其中Knoop硬度Hk係藉由Nikon QM hot hardness tester在1公斤荷重下1 5秒而測量，而R係在高溫下所測之Hk相對於在25°C下所測之Hk的比值。C2與C6碳化物的熱硬度試片係購買自 MSC公司（Melville，NY)製造的 inserts SUN434 〇表151057D-6939-PF, 200535255 parameters, where Knoop hardness Hk is measured by Nikon QM hot hardness tester under a load of 1 kg for 15 seconds, and R is measured at high temperature relative to Hk at 25 ° C Measure the ratio of Hk. Hot hardness test strips of C2 and C6 carbides were purchased from inserts SUN434 manufactured by MSC Corporation (Melville, NY). Table 15

批號 !1試溫度。C 25 400 500 600 700 800 900 Hv @25° 1880 1720 1653 1553 1527 2092 P17-5 Hk, Kg/mm2 士 10 土 17 士 25 士 29 士 6 士 3 R，％ 100 91 88 83 81 1773 1513 1467 1440 1340 2028 P18-3 Hk, Kg/mm2 士 32 士 12 ±21 土 10 士 16 士 88 R,% 100 85 83 81 76 1968 1813 1710 1593 2193 P25-3 Hk, Kg/mm2 ±45 士 12 ±0 ±5 士 8 R,% 100 92 87 81 2000 1700 1663 1583 1540 2321 P40A-1 Hk, Kg/mm2 ±35 土 17 土 12 土21 ±35 土 10 R,% 100 85 83 79 77 1925 1613 1533 1477 1377 2208 P48-1 Hk, Kg/mm2 ±25 士 15 ±29 ±6 士 15 土 12 R，％ 100 84 80 77 72 2023 1750 1633 1600 2186 Hk, Kg/mm2 P49-1 土 32 ±0 土 6 ±17 ±29 R,% 100 87 81 79 2057 1857 1780 1713 1627 2294 Hk, Kg/mm2 P50-4 ±25 土 15 ±20 土 6 士 40 土 20 R, % 100 90 87 83 79 2050 1797 1743 1693 1607 2309 Hk, Kg/mm2 P51-1 士 26 土 6 ±35 ±15 土 15 ±6 112Lot number! 1 Test temperature. C 25 400 500 600 700 800 900 Hv @ 25 ° 1880 1720 1653 1553 1527 2092 P17-5 Hk, Kg / mm2 1010 1717 2525 2929 66 33 R,% 100 91 88 83 81 1773 1513 1467 1440 1340 2028 P18-3 Hk, Kg / mm2 ± 32 ± 12 ± 21 ± 10 ± 16 ± 88 R,% 100 85 83 81 76 1968 1813 1710 1593 2193 P25-3 Hk, Kg / mm2 ± 45 ± 12 ± 0 ± 5 ± 8 R,% 100 92 87 81 2000 1700 1663 1583 1540 2321 P40A-1 Hk, Kg / mm2 ± 35 soil 17 soil 12 soil 21 ± 35 soil 10 R,% 100 85 83 79 77 1925 1613 1533 1477 1377 2208 P48-1 Hk, Kg / mm2 ± 25 ± 15 ± 29 ± 6 ± 15 ± 12 ± 12 R,% 100 84 80 77 72 2023 1750 1633 1600 2186 Hk, Kg / mm2 ± 49 ± 6 ± 17 ± 29 R,% 100 87 81 79 2057 1857 1780 1713 1627 2294 Hk, Kg / mm2 P50-4 ± 25 soil 15 ± 20 soil 6 ± 40 soil 20 R,% 100 90 87 83 79 2050 1797 1743 1693 1607 2309 Hk, Kg / mm2 P51-1 ± 26 ± 6 ± 35 ± 15 ± 15 ± 6 112

1057D—6939—PF 200535255 R, % 100 88 85 83 78 2228 2063 1960 1750 2688 Hk, Kg/mm2 P62A-6 ±29 ±25 士 76 ±0 士 22 R, % 100 93 88 79 1887 1707 1667 1633 1603 2562 Hk, Kg/mm2 P63-5 ±6 ±35 土 15 ±6 ±25 士31 R,% 100 1503 988 711 584 1685 Hk, Kg/mm2 C2靴物 ±38 士 9 士 0 士 27 士 16 R,% 100 66 47 39 1423 1127 1090 1033 928 1576 Hk, Kg/mm2 C6靴物 ±23 士 25 ±10 ±23 ±18 士 11 R,% 100 79 77 73 65 硬金屬中的含有Re的黏結劑基質係提升了含有 Co-Re，Ni超合金- Re，Ni超合金- Re-Co的黏結劑合金之溶點。例如，P63的熔點遠大於被使用於固相燒結製程的2200 °C。具有Re於黏結劑（例如P17至P63)中的該硬金屬的熱硬度值遠大於傳統的含Co硬金屬（C2與C6碳化物）。特別是，上述測量結果顯示增加黏結劑中的Re濃度係能夠增加 # 在高溫下的硬度。在該等試品中，具有純Re當作是黏結劑的P62A係具有最高的硬度。具有94%Re與6%Ni基超合金R95當作是黏結劑組成的P63係具有第二高的硬度。接著是 P40A(71.9%Re-29.1%R95)、P49(69.9%Re-30.1%R95)、 P51(88.5%Re-11.5%R95)與 P50(71.9%Re-28.1 %R95)。具有 62.5%Re-37.5%R95的黏結劑的試品P48，在這些試品中的硬度是最低的，其原因是因為Re的含量最少。在另一種類中，硬金屬或陶瓷金屬可以包含與TiC和 TiN化合於具有Ni，Mo或Mo2C之黏結劑基質中。陶瓷金 l〇57D-6939-PF 113 200535255 屬中的黏結劑Ni可以被Re，Re-Co, Ni基超合金，Re-Ni基超合金或Re-Co-Ni基超合金部分或全部取代。例如，P3 8 和P39係典型的化合有Ni的陶瓷金屬。而P34係化合有 Rene95 的陶瓷金屬。P35，P36，P37與 P45係化合有 Re-Rene95 的陶瓷金屬 °P34, P35, P36, P37, P38, P39 與 P45 的組成係列於表1 6中。表16 P34至P39的組成重量％ Re Rene95 Nil Ni2 TiC Mo2C WC TaC P34 14.47 69.44 16.09 P35 8.77 10.27 65.37 15.23 P36 16.6 6.50 62.40 14.46 P37 23.8 3.09 59.38 13.76 P38 15.51 68.60 15.89 P39 15.51 68.60 15.89 P45 9.37 3.66 15.37 6.51 58.6 6.47 表17-29列出額外三種組成範圍。表17利用純Re當作黏結劑來黏結由元素週期表中IVb、Vb及VIb族元素所形成的碳 0 化物或由元素週期表中IVb及Vb族元素所形成的氮化物組成範圍1 組成範圍2 組成範圍3 估算熔點。 c 體積％重量% 體積％重量% 體積％重量％ Re黏結 Re 7.25 to 40 25 to 74 7.25 to 35 25 to 70 7.25 to 30 25 to 65 3000 to 3200 TiC TiC 60 to 92.75 26 to 75 65 to 92.75 30 to 75 70 to 92.75 35 to 75 Re黏結 Re 3 to 40 9 to 68 4 to 35 12 to 63 5 to 30 14 to 58 3000 to 3200 ZrC ZrC 60 to 97 32 to 93 65 to 96 37 to 88 70 to 95 42 to 86 Re黏結 Re 16.75 to 40 25 to 52 16.75 to 35 25 to 47 16.75 to 30 25 to 42 3000 to 3200 HfC HfC 60 to 83.25 48 to 75 65 to 83.25 53 to 75 70 to 83.25 58 to 75 Re黏結 Re 3 to 40 11 to 72 4 to 35 14 to 67 5 to 30 17 to 62 2700 to 3100 VC VC 60 to 97 28 to 89 65 to 96 33 to 86 70 to 95 38 to 83 Re黏結 Re 3 to 40 8 to 64 4 to 35 10 to 59 5 to 30 12 to 54 3000 to 3200 1141057D—6939—PF 200535255 R,% 100 88 85 83 78 2228 2063 1960 1750 2688 Hk, Kg / mm2 P62A-6 ± 29 ± 25 ± 76 ± 0 ± 22 R,% 100 93 88 79 1887 1707 1667 1633 1603 2562 Hk, Kg / mm2 P63-5 ± 6 ± 35 ± 15 ± 6 ± 25 ± 31 ± 31 ± R 100% H3, Kg / mm2 C2 boots ± 38 ± 9 ± 0 ± 27 ± 16 R,% 100 66 47 39 1423 1127 1090 1033 928 1576 Hk, Kg / mm2 C6 boots ± 23 ± 25 ± 10 ± 23 ± 18 ± 11 R,% 100 79 77 73 65 Re-based binder matrix in hard metals improves The melting point of the binder alloy containing Co-Re, Ni superalloy-Re, Ni superalloy-Re-Co is shown. For example, the melting point of P63 is much higher than 2200 ° C used in the solid phase sintering process. The hard metal with Re in the binder (such as P17 to P63) has a thermal hardness value much larger than that of conventional Co-containing hard metals (C2 and C6 carbides). In particular, the above measurement results show that increasing the Re concentration in the binder can increase the hardness at high temperatures. Among these samples, the P62A series with pure Re as a binder has the highest hardness. The P63 series with 94% Re and 6% Ni-based super alloy R95 as a binder has the second highest hardness. This is followed by P40A (71.9% Re-29.1% R95), P49 (69.9% Re-30.1% R95), P51 (88.5% Re-11.5% R95), and P50 (71.9% Re-28.1% R95). The test product P48 with a binder of 62.5% Re-37.5% R95 had the lowest hardness among these test products because the Re content was the lowest. In another category, hard or ceramic metals may be combined with TiC and TiN in a binder matrix with Ni, Mo or Mo2C. Ceramic gold 057D-6939-PF 113 200535255 can be partially or completely replaced by Re, Re-Co, Ni-based superalloy, Re-Ni-based superalloy, or Re-Co-Ni-based superalloy. For example, P3 8 and P39 are typical Ni-containing ceramic metals. The P34 series is a ceramic metal with Rene95. The series of P35, P36, P37 and P45 ceramics with Re-Rene95 ° P34, P35, P36, P37, P38, P39 and P45 are shown in Table 16. Table 16 Composition weight% of P34 to P39 Re Rene95 Nil Ni2 TiC Mo2C WC TaC P34 14.47 69.44 16.09 P35 8.77 10.27 65.37 15.23 P36 16.6 6.50 62.40 14.46 P37 23.8 3.09 59.38 13.76 P38 15.51 68.60 15.89 P39 15.51 68.60 15.89 P45 9.37 3.66 15.37 6.37 6.47 Table 17-29 lists three additional composition ranges. Table 17 uses pure Re as a binder to bond carbides formed by elements of Groups IVb, Vb, and VIb in the periodic table or nitrides formed by elements of Groups IVb and Vb in the periodic table. Composition range 1 Composition range 2 Composition range 3 Estimated melting point. c vol% wt% vol% wt% vol% wt Re Rebond Re 7.25 to 40 25 to 74 7.25 to 35 25 to 70 7.25 to 30 25 to 65 3000 to 3200 TiC TiC 60 to 92.75 26 to 75 65 to 92.75 30 to 75 70 to 92.75 35 to 75 Rebond Re 3 to 40 9 to 68 4 to 35 12 to 63 5 to 30 14 to 58 3000 to 3200 ZrC ZrC 60 to 97 32 to 93 65 to 96 37 to 88 70 to 95 42 to 86 Re Bond Re 16.75 to 40 25 to 52 16.75 to 35 25 to 47 16.75 to 30 25 to 42 3000 to 3200 HfC HfC 60 to 83.25 48 to 75 65 to 83.25 53 to 75 70 to 83.25 58 to 75 Re bond Re 3 to 40 11 to 72 4 to 35 14 to 67 5 to 30 17 to 62 2700 to 3100 VC VC 60 to 97 28 to 89 65 to 96 33 to 86 70 to 95 38 to 83 Rebond Re 3 to 40 8 to 64 4 to 35 10 to 59 5 to 30 12 to 54 3000 to 3200 114

1057D-6939-PF "2005352551057D-6939-PF " 200535255

NbC NbC 60 to 97 36 to 92 65 to 96 41 to 90 70 to 95 46 to 88 Re黏結 Re 3 to 40 4 to 49 4 to 35 6 to 44 5 to 30 7 to 38 3000 to 3200 TaC TaC 60 to 97 51 to 96 65 to 96 56 to 94 70 to 95 62 to 93 Re黏結 Re 3 to 40 9 to 68 4 to 35 12 to 63 5 to 30 14 to 57 1700 to 1900 Cr2C3 Cr2C3 60 to 97 32 to 91 65 to 96 37 to 88 70 to 95 43 to 86 Re黏結 Re 3 to 40 7 to 61 4 to 35 9 to 55 5 to 30 11 to 50 2300 to 2600 Mo2C Mo2C 60 to 97 39 to 93 65 to 96 45 to 91 70 to 95 50 to 89 Re黏結 Re 20 to 40 25 to 47 20 to 35 25 to 42 20 to 30 25 to 37 2700 to 2900 WC WC 60 to 80 53 to 75 65 to 80 58 to 75 70 to 80 63 to 75 Re黏結 Re 3 to 40 11 to 72 4 to 35 14 to 68 5 to 30 17 to 62 2900 to 3100 TiN TiN 60 to 97 28 to 89 65 to 96 32 to 86 70 to 95 38 to 83 Re黏結 Re 3 to 40 8 to 66 4 to 35 11 to 61 5 to 30 13 to 55 2900 to 3100 ZrN ZrN 60 to 97 34 to 92 65 to 96 39 to 89 70 to 95 45 to 87 Re黏結 Re 3 to 40 4 to 50 4 to 35 6 to 45 5 to 30 7 to 39 3000 to 3200 HfN HfN 60 to 97 50 to 96 65 to 96 55 to 94 70 to 95 61 to 93 Re黏結 Re 3 to 40 9 to 70 4 to 35 13 to 65 5 to 30 16 to 62 2100 to 2300 VN VN 60 to 97 30 to 91 65 to 96 35 to 87 70 to 95 38 to 84 Re黏結 Re 3 to 40 8 to 66 4 to 35 11 to 61 5 to 30 13 to 55 2300 to 2500 NbN NbN 60 to 97 34 to 92 65 to 96 39 to 89 70 to 95 45 to 87 Re黏結 Re 3 to 40 4 to 49 4 to 35 6 to 44 5 to 30 7 to 39 3000 to 3200 TaN TaN 60 to 97 51 to 96 65 to 96 56 to 94 70 to 95 61 to 93NbC NbC 60 to 97 36 to 92 65 to 96 41 to 90 70 to 95 46 to 88 Rebond Re 3 to 40 4 to 49 4 to 35 6 to 44 5 to 30 7 to 38 3000 to 3200 TaC TaC 60 to 97 51 to 96 65 to 96 56 to 94 70 to 95 62 to 93 Rebond Re 3 to 40 9 to 68 4 to 35 12 to 63 5 to 30 14 to 57 1700 to 1900 Cr2C3 Cr2C3 60 to 97 32 to 91 65 to 96 37 to 88 70 to 95 43 to 86 Rebond Re 3 to 40 7 to 61 4 to 35 9 to 55 5 to 30 11 to 50 2300 to 2600 Mo2C Mo2C 60 to 97 39 to 93 65 to 96 45 to 91 70 to 95 50 to 89 Re Bonding Re 20 to 40 25 to 47 20 to 35 25 to 42 20 to 30 25 to 37 2700 to 2900 WC WC 60 to 80 53 to 75 65 to 80 58 to 75 70 to 80 63 to 75 Re Bonding Re 3 to 40 11 to 72 4 to 35 14 to 68 5 to 30 17 to 62 2900 to 3100 TiN TiN 60 to 97 28 to 89 65 to 96 32 to 86 70 to 95 38 to 83 Rebond Re 3 to 40 8 to 66 4 to 35 11 to 61 5 to 30 13 to 55 2900 to 3100 ZrN ZrN 60 to 97 34 to 92 65 to 96 39 to 89 70 to 95 45 to 87 Rebond Re 3 to 40 4 to 50 4 to 35 6 to 45 5 to 30 7 to 39 3000 to 3200 HfN HfN 60 to 97 50 to 96 65 to 96 55 to 94 70 to 95 61 to 93 Rebond Re 3 to 40 9 to 70 4 to 35 13 to 65 5 to 30 16 to 62 2100 to 2300 VN VN 60 to 97 30 to 91 65 to 96 35 to 87 70 to 95 38 to 84 Rebond Re 3 to 40 8 to 66 4 to 35 11 to 61 5 to 30 13 to 55 2300 to 2500 NbN NbN 60 to 97 34 to 92 65 to 96 39 to 89 70 to 95 45 to 87 Rebond Re 3 to 40 4 to 49 4 to 35 6 to 44 5 to 30 7 to 39 3000 to 3200 TaN TaN 60 to 97 51 to 96 65 to 96 56 to 94 70 to 95 61 to 93

表18在黏結劑中利用鎳基超合金來黏結由元素週期表中IVb及Vb族元素所形成的氮化物組成範圍1 組成範圍2 組成範圍3 體積％重量％體積％重量％體積％重量％ NBSA- NBSA 3 to 40 4 to 50 4 to 35 6 to 44 5 to 30 7 to 39 TiN TiN 60 to 97 50 to 96 65 to 96 56 to 94 70 to 95 61 to 93 NBSA- NBSA 3 to 40 3 to 42 4 to 35 4 to 37 5 to 30 5 to 32 ZrN ZrN 60 to 97 58 to 97 65 to 96 63 to 96 70 to 95 68 to 95 NBSA- NBSA 3 to 40 1.8 to 28 4 to 35 2.4 to 24 5 to 30 3 to 19 HfN HfN 60 to 97 72 to 98.2 65 to 96 76 to 97.6 70 to 95 81 to 97 NBSA- NBSA 3 to 40 4 to 47 4 to 35 5 to 42 5 to 30 7 to 36 VN VN 60 to 97 53 to 96 65 to 96 58 to 95 70 to 95 64 to 93 115TABLE 18 Ni-based superalloys are used in the binder to bond nitrides formed from elements of the IVb and Vb groups in the periodic table. Composition range 1 Composition range 2 Composition range 3 vol.% Wt. -NBSA 3 to 40 4 to 50 4 to 35 6 to 44 5 to 30 7 to 39 TiN TiN 60 to 97 50 to 96 65 to 96 56 to 94 70 to 95 61 to 93 NBSA- NBSA 3 to 40 3 to 42 4 to 35 4 to 37 5 to 30 5 to 32 ZrN ZrN 60 to 97 58 to 97 65 to 96 63 to 96 70 to 95 68 to 95 NBSA- NBSA 3 to 40 1.8 to 28 4 to 35 2.4 to 24 5 to 30 3 to 19 HfN HfN 60 to 97 72 to 98.2 65 to 96 76 to 97.6 70 to 95 81 to 97 NBSA- NBSA 3 to 40 4 to 47 4 to 35 5 to 42 5 to 30 7 to 36 VN VN 60 to 97 53 to 96 65 to 96 58 to 95 70 to 95 64 to 93 115

1057D-6939-PF 200535255 NBSA - NBSA 3 to 40 3 to 42 4 to 35 4 to 37 5 to 30 5 to 32 NbN NbN 60 to 97 52 to 97 65 to 96 33 to 96 70 to 95 68 to 95 NBSA- NBSA 3 to 40 1.7 to 27 4 to 35 2.3 to 23 5 to 30 3 to 19 TaN TaN 60 to 97 73 to 98.3 65 to 96 77 to 97.7 70 to 95 81 to 97 表19在黏結記中利用Re及鎳基超合金來黏結由元素週期表中IVb、Vb及VIb族元素所形成的碳化物或由元素週期表中IVb及Vb族元素所形成的氮化物，其中黏結劑組成比例範圍由1% Re+99%鎳基超合金至99%Re+l%鎳基超合金1057D-6939-PF 200535255 NBSA-NBSA 3 to 40 3 to 42 4 to 35 4 to 37 5 to 30 5 to 32 NbN NbN 60 to 97 52 to 97 65 to 96 33 to 96 70 to 95 68 to 95 NBSA- NBSA 3 to 40 1.7 to 27 4 to 35 2.3 to 23 5 to 30 3 to 19 TaN TaN 60 to 97 73 to 98.3 65 to 96 77 to 97.7 70 to 95 81 to 97 Table 19 uses Re and nickel-based Alloys to bond carbides formed from Group IVb, Vb, and VIb elements in the periodic table or nitrides formed from Group IVb and Vb elements in the periodic table, in which the binder composition ratio ranges from 1% Re + 99% Nickel-based superalloy to 99% Re + l% nickel-based superalloy

材料組成範圍1 組成範圍2 組成範圍3 體積％重量％體積％重量％ mm % 重量％ (Re+NBSA) Re 0.03 to 39.6 0.13 to 73.6 0.04 to 34.7 0.17 to 69.3 0.05 to 29.7 0.21 to 64.3 - NBSA 0.03 to 39.6 0.04 to 51.1 0.04 to 34.7 0.06 to 45.9 0.05 to 29.7 0.07 to 40.4 TiC TiC 60 to 97 26.1 to 95.1 65 to 96 30.5 to 93.6 70 to 95 35.5 to 92 (Re+NBSA) Re 0.03 to 39.6 0.09 to 67.7 0.04 to 34.7 0.13 to 62.9 0.05 to 29.7 0.16 to 57.5 - NBSA 0.03 to 39.6 0.03 to 44.1 0.04 to 34.7 0.05 to 39.0 0.05 to 29.7 0.06 to 33.8 ZrC ZrC 60 to 97 32 to 96 65 to 96 37 to 95 70 to 95 42 to 94 (Re+NBSA) Re 0.03 to 39.6 0.05 to 52.1 0.04 to 34.7 0.07 to 46.8 0.05 to 29.7 0.08 to 41.2 - NBSA 0.03 to 39.6 0.02 to 29.2 0.04 to 34.7 0.025 to 25 0.05 to 29.7 0.03 to 21 HfC HfC 60 to 97 47.7 to 98.1 65 to 96 53 to 97.4 70 to 95 58.6 to 96.7 (Re+NBSA) Re 0.03 to 39.6 0.11 to 71.5 0.04 to 34.7 0.15 to 67.0 0.05 to 29.7 0.19 to 61.8 - NBSA 0.03 to 39.6 0.04 to 48.4 0.04 to 34.7 0.05 to 43.3 0.05 to 29.7 0.06 to 37.9 VC VC 60 to 97 28.3 to 95.6 65 to 96 32.8 to 94.2 70 to 95 38 to 92.8 (Re+NBSA) Re 0.03 to 39.6 0.08 to 63.8 0.04 to 34.7 0.1 to 58.7 0.05 to 29.7 0.13 to 53.1 - NBSA 0.03 to 39.6 0.03 to 39.9 0.04 to 34.7 0.04 to 35 0.05 to 29.7 0.05 to 30 NbC NbC 60 to 97 36 to 96.9 65 to 96 41 to 95.8 70 to 95 46.6 to 94.8 (Re+NBSA) Re 0.03 to 39.6 0.04 to 48.8 0.04 to 34.7 0.06 to 43.5 0.05 to 29.7 0.07 to 38 - NBSA 0.03 to 39.6 0.016 to 26.5 0.04 to 34.7 0.02 to 22.6 0.05 to 29.7 0.03 to 18.9 TaC TaC 60 to 97 51 to 98.3 65 to 96 56.3 to 97.7 70 to 95 61.8 to 97.1 (Re+NBSA) Re 0.03 to 39.6 0.09 to 67.3 0.04 to 34.7 0.12 to 62.5 0.05 to 29.7 0.16 to 57.0 - NBSA 0.03 to 39.6 0.03 to 43.6 0.04 to 34.7 0.04 to 38.6 0.05 to 29.7 0.05 to 33.4 Cr2C3 Cr2C3 60 to 97 32.4 to 96.4 65 to 96 37.3 to 95.2 70 to 95 42.8 to 94.0 (Re+NBSA) Re 0.03 to 39.6 0.07 to 60.2 0.04 to 34.7 0.1 to 55 0.05 to 29.7 0.12 to 49.3 - NBSA 0.03 to 39.6 0.025 to 36.3 0.04 to 34.7 0.03 to 31.6 0.05 to 29.7 0.04 to 26.9 Mo2C Mo2C 60 to 97 39.6 to 97.3 65 to 96 44.8 to 96.4 70 to 95 50.5 to 95.5 (Re+NBSA) Re 0.03 to 39.6 0.04 to 46.9 0.04 to 34.7 0.05 to 41.7 0.05 to 29.7 0.07 to 36.3 - NBSA 0.03 to 39.6 0.015 to 25 0.04 to 34.7 0.02 to 21.3 0.05 to 29.7 0.025 to 17.8 wc WC 60 to 97 52.9 to 98.4 65 to 96 58.2 to 97.9 70 to 95 63.6 to 97.3 (Re+NBSA) Re 0.03 to 39.6 0.1 to 71.7 0.04 to 34.7 0.15 to 67.2 0.05 to 29.7 0.19 to 62 - NBSA 0.03 to 39.6 0.04 to 48.7 0.04 to 34.7 0.05 to 43.5 0.05 to 29.7 0.06 to 38 116Material composition range 1 Composition range 2 Composition range 3 vol% wt% vol% wt% mm% wt% (Re + NBSA) Re 0.03 to 39.6 0.13 to 73.6 0.04 to 34.7 0.17 to 69.3 0.05 to 29.7 0.21 to 64.3-NBSA 0.03 to 39.6 0.04 to 51.1 0.04 to 34.7 0.06 to 45.9 0.05 to 29.7 0.07 to 40.4 TiC TiC 60 to 97 26.1 to 95.1 65 to 96 30.5 to 93.6 70 to 95 35.5 to 92 (Re + NBSA) Re 0.03 to 39.6 0.09 to 67.7 0.04 to 34.7 0.13 to 62.9 0.05 to 29.7 0.16 to 57.5-NBSA 0.03 to 39.6 0.03 to 44.1 0.04 to 34.7 0.05 to 39.0 0.05 to 29.7 0.06 to 33.8 ZrC ZrC 60 to 97 32 to 96 65 to 96 37 to 95 70 to 95 42 to 94 (Re + NBSA) Re 0.03 to 39.6 0.05 to 52.1 0.04 to 34.7 0.07 to 46.8 0.05 to 29.7 0.08 to 41.2-NBSA 0.03 to 39.6 0.02 to 29.2 0.04 to 34.7 0.025 to 25 0.05 to 29.7 0.03 to 21 HfC HfC 60 to 97 47.7 to 98.1 65 to 96 53 to 97.4 70 to 95 58.6 to 96.7 (Re + NBSA) Re 0.03 to 39.6 0.11 to 71.5 0.04 to 34.7 0.15 to 67.0 0.05 to 29.7 0.19 to 61.8-NBSA 0.03 to 39.6 0.04 to 48.4 0.04 to 34.7 0.05 to 43.3 0.05 to 29.7 0.06 to 37.9 VC VC 60 to 97 28.3 to 95.6 65 to 96 32.8 to 94.2 70 to 95 38 to 92.8 (Re + NBSA) Re 0.03 to 39.6 0.08 to 63.8 0.04 to 34.7 0.1 to 58.7 0.05 to 29.7 0.13 to 53.1 -NBSA 0.03 to 39.6 0.03 to 39.9 0.04 to 34.7 0.04 to 35 0.05 to 29.7 0.05 to 30 NbC NbC 60 to 97 36 to 96.9 65 to 96 41 to 95.8 70 to 95 46.6 to 94.8 (Re + NBSA) Re 0.03 to 39.6 0.04 to 48.8 0.04 to 34.7 0.06 to 43.5 0.05 to 29.7 0.07 to 38-NBSA 0.03 to 39.6 0.016 to 26.5 0.04 to 34.7 0.02 to 22.6 0.05 to 29.7 0.03 to 18.9 TaC TaC 60 to 97 51 to 98.3 65 to 96 56.3 to 97.7 70 to 95 61.8 to 97.1 (Re + NBSA) Re 0.03 to 39.6 0.09 to 67.3 0.04 to 34.7 0.12 to 62.5 0.05 to 29.7 0.16 to 57.0-NBSA 0.03 to 39.6 0.03 to 43.6 0.04 to 34.7 0.04 to 38.6 0.05 to 29.7 0.05 to 33.4 Cr2C3 60 to 97 32.4 to 96.4 65 to 96 37.3 to 95.2 70 to 95 42.8 to 94.0 (Re + NBSA) Re 0.03 to 39.6 0.07 to 60.2 0.04 to 34.7 0.1 to 55 0.05 to 29.7 0.12 to 49.3-NBSA 0.03 to 39.6 0.025 to 36.3 0.04 to 34.7 0.03 to 31.6 0. 05 to 29.7 0.04 to 26.9 Mo2C Mo2C 60 to 97 39.6 to 97.3 65 to 96 44.8 to 96.4 70 to 95 50.5 to 95.5 (Re + NBSA) Re 0.03 to 39.6 0.04 to 46.9 0.04 to 34.7 0.05 to 41.7 0.05 to 29.7 0.07 to 36.3 -NBSA 0.03 to 39.6 0.015 to 25 0.04 to 34.7 0.02 to 21.3 0.05 to 29.7 0.025 to 17.8 wc WC 60 to 97 52.9 to 98.4 65 to 96 58.2 to 97.9 70 to 95 63.6 to 97.3 (Re + NBSA) Re 0.03 to 39.6 0.1 to 71.7 0.04 to 34.7 0.15 to 67.2 0.05 to 29.7 0.19 to 62-NBSA 0.03 to 39.6 0.04 to 48.7 0.04 to 34.7 0.05 to 43.5 0.05 to 29.7 0.06 to 38 116

1057D-6939-PF .2005352551057D-6939-PF .200535255

TiN TiN 60 to 97 28 to 95.6 65 to 96 32.6 to 94.1 70 to 95 37.8 to 92.7 (Re+NBSA) Re 0.03 to 39.6 0.09 to 65.3 0.04 to 34.7 0.1 to 60.3 0.05 to 29.7 0.14 to 54.8 - NBSA 0.03 to 39.6 0.03 to 41.4 0.04 to 34.7 0.04 to 36.5 0.05 to 29.7 0.05 to 31.4 ZrN ZrN 60 to 97 34.5 to 96.7 65 to 96 39.4 to 95.6 70 to 95 45 to 94.5 (Re+NBSA) Re 0.03 to 39.6 0.05 to 50 0.04 to 34.7 0.06 to 44.7 0.05 to 29.7 0.08 to 39.2 - NBSA 0.03 to 39.6 0.017 to 27.5 0.04 to 34.7 0.02 to 23.5 0.05 to 29.7 0.03 to 19.6 HfN HfN 60 to 97 49.8 to 98.2 65 to 96 55.1 to 97.6 70 to 95 60.7 to 97 (Re+NBSA) Re 0.03 to 39.6 0.1 to 69.6 0.04 to 34.7 0.14 to 65 0.05 to 29.7 0.17 to 59.6 - NBSA 0.03 to 39.6 0.04 to 46.2 0.04 to 34.7 0.05 to 41.1 0.05 to 29.7 0.06 to 35.8 VN VN 60 to 97 30 to 96 65 to 96 35 to 94.7 70 to 95 40 to 93.3 (Re+NBSA) Re 0.03 to 39.6 0.09 to 65.3 0.04 to 34.7 0.1 to 60.4 0.05 to 29.7 0.14 to 54.9 - NBSA 0.03 to 39.6 0.03 to 41.5 0.04 to 34.7 0.04 to 36.5 0.05 to 29.7 0.05 to 31.5 NbN NbN 60 to 97 34.4 to 96.7 65 to 96 39.4 to 95.6 70 to 95 45 to 94.5 (Re+NBSA) Re 0.03 to 39.6 0.04 to 49.1 0.04 to 34.7 0.06 to 43.8 0.05 to 29.7 0.08 to 38.3 - NBSA 0.03 to 39.6 0.017 to 26.8 0.04 to 34.7 0.02 to 22.8 0.05 to 29.7 0.027 to 19 TaN TaN 60 to 97 50.7 to 98.3 65 to 96 56 to 97.7 70 to 95 61.5 to 97TiN TiN 60 to 97 28 to 95.6 65 to 96 32.6 to 94.1 70 to 95 37.8 to 92.7 (Re + NBSA) Re 0.03 to 39.6 0.09 to 65.3 0.04 to 34.7 0.1 to 60.3 0.05 to 29.7 0.14 to 54.8-NBSA 0.03 to 39.6 0.03 to 41.4 0.04 to 34.7 0.04 to 36.5 0.05 to 29.7 0.05 to 31.4 ZrN ZrN 60 to 97 34.5 to 96.7 65 to 96 39.4 to 95.6 70 to 95 45 to 94.5 (Re + NBSA) Re 0.03 to 39.6 0.05 to 50 0.04 to 34.7 0.06 to 44.7 0.05 to 29.7 0.08 to 39.2-NBSA 0.03 to 39.6 0.017 to 27.5 0.04 to 34.7 0.02 to 23.5 0.05 to 29.7 0.03 to 19.6 HfN HfN 60 to 97 49.8 to 98.2 65 to 96 55.1 to 97.6 70 to 95 60.7 to 97 (Re + NBSA) Re 0.03 to 39.6 0.1 to 69.6 0.04 to 34.7 0.14 to 65 0.05 to 29.7 0.17 to 59.6-NBSA 0.03 to 39.6 0.04 to 46.2 0.04 to 34.7 0.05 to 41.1 0.05 to 29.7 0.06 to 35.8 VN VN 60 to 97 30 to 96 65 to 96 35 to 94.7 70 to 95 40 to 93.3 (Re + NBSA) Re 0.03 to 39.6 0.09 to 65.3 0.04 to 34.7 0.1 to 60.4 0.05 to 29.7 0.14 to 54.9-NBSA 0.03 to 39.6 0.03 to 41.5 0.04 to 34.7 0.04 to 36.5 0.05 to 29.7 0.05 to 31.5 NbN NbN 60 to 97 34.4 to 96.7 65 to 96 39.4 to 95.6 70 to 95 45 to 94.5 (Re + NBSA) Re 0.03 to 39.6 0.04 to 49.1 0.04 to 34.7 0.06 to 43.8 0.05 to 29.7 0.08 to 38.3-NBSA 0.03 to 39.6 0.017 to 26.8 0.04 to 34.7 0.02 to 22.8 0.05 to 29.7 0.027 to 19 TaN TaN 60 to 97 50.7 to 98.3 65 to 96 56 to 97.7 70 to 95 61.5 to 97

表20在黏結劑中利用Re及Co(Re+Co)來黏結由元素週期表中IVb、Vb及VIb族元素所形成的碳化物或由元素週期表中IVb及Vb族元素所形成的氮化物，其中黏結劑組成比例範圍由1 %Re+99%Co 至 99%Re+l%Co 材料組成範圍1 組成範圍2 組成範圍3 mm % 重量％ mm % 重量% 體積％重量％ (Re+Co) Re 0.03 to 39.6 0.13 to 73.6 0.04 to 34.7 0.17 to 69.3 0.05 to 29.7 0.20 to 64.3 - Co 0.03 to 39.6 0.05 to 54.1 0.04 to 34.7 0.07 to 48.9 0.05 to 29.7 0.08 to 43.3 TiC TiC 60 to 97 26.1 to94.6 65 to 96 30.4 to 92.8 70 to 95 35.5 to 91 (Re+Co) Re 0.03 to 39.6 0.09 to 67.7 0.04 to 34.7 0.13 to 62.9 0.05 to 29.7 0.16 to 57.5 - Co 0.03 to 39.6 0.04 to 47.1 0.04 to 34.7 0.05 to 42.0 0.05 to 29.7 0.06 to 36.6 ZrC ZrC 60 to 97 32 to 96 65 to 96 37 to 95 70 to 95 42 to 93 (Re+Co) Re 0.03 to 39.6 0.05 to 52.1 0.04 to 34.7 0.07 to 46.8 0.05 to 29.7 0.08 to 41.2 Co 0.03 to 39.6 0.02 to 31.8 0.04 to 34.7 0.028 to 27 0.05 to 29.7 0.035 to 23 HfC HfC 60 to 97 47.6 to 97.8 65 to 96 53 to 97.1 70 to 95 58.6 to 96.3 (Re+Co) Re 0.03 to 39.6 0.11 to 71.4 0.04 to 34.7 0.15 to 67.0 0.05 to 29.7 0.19 to 61.8 - Co 0.03 to 39.6 0.05 to 51.5 0.04 to 34.7 0.06 to 46.3 0.05 to 29.7 0.07 to 40.8 VC VC 60 to 97 28.3 to 95.1 65 to 96 32.8 to 93.5 70 to 95 38 to 92 (Re+Co) Re 0.03 to 39.6 0.08 to 63.8 0.04 to 34.7 0.1 to 58.7 0.05 to 29.7 0.13 to 53.1 - Co 0.03 to 39.6 0.03 to 42.8 0.04 to 34.7 0.04 to 37.8 0.05 to 29.7 0.05 to 32.6 NbC NbC 60 to 97 36 to 96.5 65 to 96 41 to 95.4 70 to 95 46.6 to 94.2 (Re+Co) Re 0.03 to 39.6 0.04 to 48.8 0.04 to 34.7 0.06 to 43.5 0.05 to 29.7 0.07 to 38 - Co 0.03 to 39.6 0.018 to 28.9 0.04 to 34.7 0.024 to 24.8 0.05 to 29.7 0.03 to 20.8 TaC TaC 60 to 97 51 to 98 65 to 96 56.3 to 97.4 70 to 95 61.8 to 96.8 (Re+Co) Re 0.03 to 39.6 0.09 to 67.3 0.04 to 34.7 0.12 to 62.5 0.05 to 29.7 0.15 to 57.0 117Table 20 uses Re and Co (Re + Co) in the binder to bond carbides formed by elements of Group IVb, Vb and VIb in the periodic table or nitrides formed by elements of Group IVb and Vb in the periodic table , Where the composition ratio of the binder ranges from 1% Re + 99% Co to 99% Re + l% Co material composition range 1 composition range 2 composition range 3 mm% weight% mm% weight% volume% weight% (Re + Co) Re 0.03 to 39.6 0.13 to 73.6 0.04 to 34.7 0.17 to 69.3 0.05 to 29.7 0.20 to 64.3-Co 0.03 to 39.6 0.05 to 54.1 0.04 to 34.7 0.07 to 48.9 0.05 to 29.7 0.08 to 43.3 TiC TiC 60 to 97 26.1 to 94.6 65 to 96 30.4 to 92.8 70 to 95 35.5 to 91 (Re + Co) Re 0.03 to 39.6 0.09 to 67.7 0.04 to 34.7 0.13 to 62.9 0.05 to 29.7 0.16 to 57.5-Co 0.03 to 39.6 0.04 to 47.1 0.04 to 34.7 0.05 to 42.0 0.05 to 29.7 0.06 to 36.6 ZrC ZrC 60 to 97 32 to 96 65 to 96 37 to 95 70 to 95 42 to 93 (Re + Co) Re 0.03 to 39.6 0.05 to 52.1 0.04 to 34.7 0.07 to 46.8 0.05 to 29.7 0.08 to 41.2 Co 0.03 to 39.6 0.02 to 31.8 0.04 to 34.7 0.028 to 27 0.05 to 29.7 0.035 to 23 H fC HfC 60 to 97 47.6 to 97.8 65 to 96 53 to 97.1 70 to 95 58.6 to 96.3 (Re + Co) Re 0.03 to 39.6 0.11 to 71.4 0.04 to 34.7 0.15 to 67.0 0.05 to 29.7 0.19 to 61.8-Co 0.03 to 39.6 0.05 to 51.5 0.04 to 34.7 0.06 to 46.3 0.05 to 29.7 0.07 to 40.8 VC VC 60 to 97 28.3 to 95.1 65 to 96 32.8 to 93.5 70 to 95 38 to 92 (Re + Co) Re 0.03 to 39.6 0.08 to 63.8 0.04 to 34.7 0.1 to 58.7 0.05 to 29.7 0.13 to 53.1-Co 0.03 to 39.6 0.03 to 42.8 0.04 to 34.7 0.04 to 37.8 0.05 to 29.7 0.05 to 32.6 NbC NbC 60 to 97 36 to 96.5 65 to 96 41 to 95.4 70 to 95 46.6 to 94.2 (Re + Co) Re 0.03 to 39.6 0.04 to 48.8 0.04 to 34.7 0.06 to 43.5 0.05 to 29.7 0.07 to 38-Co 0.03 to 39.6 0.018 to 28.9 0.04 to 34.7 0.024 to 24.8 0.05 to 29.7 0.03 to 20.8 TaC TaC 60 to 97 51 to 98 65 to 96 56.3 to 97.4 70 to 95 61.8 to 96.8 (Re + Co) Re 0.03 to 39.6 0.09 to 67.3 0.04 to 34.7 0.12 to 62.5 0.05 to 29.7 0.15 to 57.0 117

1057D-6939-PF 200535255 - Co 0.03 to 39.6 0.04 to 46.6 0.04 to 34.7 0.05 to 41.5 0.05 to 29.7 0.06 to 36.1 Cr2C3 Cr2C3 60 to 97 32.4 to 96 65 to 96 37.3 to 94.6 70 to 95 42.7 to 93.3 (Re+Co) Re 0.03 to 39.6 0.07 to 60.2 0.04 to 34.7 0.1 to 55 0.05 to 29.7 0.12 to 49.3 - Co 0.03 to 39.6 0.03 to 39.2 0.04 to 34.7 0.04 to 34.3 0.05 to 29.7 0.05 to 29.4 Mo2C Mo2C 60 to 97 39.6 to 97 65 to 96 44.8 to 96 70 to 95 50.5 to 95 (Re+Co) Re 0.03 to 39.6 0.04 to 46.9 0.04 to 34.7 0.05 to 41.7 0.05 to 29.7 0.07 to 36.3 - Co 0.03 to 39.6 0.017 to 27.4 0.04 to 34.7 0.023 to 23.4 0.05 to 29.7 0.028 to 19.6 WC WC 60 to 97 52.9 to98.2 65 to 96 58.2 to 97 70 to 95 63.6 to 97 (Re+Co) Re 0.03 to 39.6 0.1 to 71.6 0.04 to 34.7 0.15 to 67.1 0.05 to 29.7 0.19 to 62 - Co 0.03 to 39.6 0.05 to 51.7 0.04 to 34.7 0.06 to 46.5 0.05 to 29.7 0.07 to 41 TiN TiN 60 to 97 28 to 95 65 to 96 32.6 to 93.4 70 to 95 37.8 to 92 (Re+Co) Re 0.03 to 39.6 0.09 to 65.3 0.04 to 34.7 0.11 to 60.3 0.05 to 29.7 0.14 to 54.8 - Co 0.03 to 39.6 0.035 to 44.4 0.04 to 34.7 0.046 to 39.3 0.05 to 29.7 0.056 to 34 ZrN ZrN 60 to 97 34.5 to 96.3 65 to 96 39.4 to 95 70 to 95 45 to 93.8 (Re+Co) Re 0.03 to 39.6 0.05 to 50 0.04 to 34.7 0.06 to 44.7 0.05 to 29.7 0.08 to 39.2 - Co 0.03 to 39.6 0.02 to 30 0.04 to 34.7 0.026 to 25.7 0.05 to 29.7 0.03 to 21.6 HfN HfN 60 to 97 49.8 to 98 65 to 96 55.1 to 97.3 70 to 95 60.7 to 96.6 (Re+Co) Re 0.03 to 39.6 0.1 to 69.6 0.04 to 34.7 0.14 to 65 0.05 to 29.7 0.17 to 59.6 - Co 0.03 to 39.6 0.04 to 49.3 0.04 to 34.7 0.055 to 44 0.05 to 29.7 0.067 to 38.6 VN VN 60 to 97 30 to 95.5 65 to 96 35 to 94 70 to 95 40 to 92.6 (Re+Co) Re 0.03 to 39.6 0.09 to 65.3 0.04 to 34.7 0.11 to 60.4 0.05 to 29.7 0.14 to 54.8 - Co 0.03 to 39.6 0.035 to 44.5 0.04 to 34.7 0.046 to 39.4 0.05 to 29.7 0.057 to 34.1 NbN NbN 60 to 97 34.4 to 96.3 65 to 96 39.4 to 95 70 to 95 45 to 93.8 (Re+Co) Re 0.03 to 39.6 0.04 to 49.1 0.04 to 34.7 0.06 to 43.8 0.05 to 29.7 0.075 to 38.3 - Co 0.03 to 39.6 0.019 to 29.2 0.04 to 34.7 0.025 to 25 0.05 to 29.7 0.03 to 21 TaN TaN 60 to 97 50.7 to 98 65 to 96 56 to 97.4 70 to 95 61.5 to 96.71057D-6939-PF 200535255-Co 0.03 to 39.6 0.04 to 46.6 0.04 to 34.7 0.05 to 41.5 0.05 to 29.7 0.06 to 36.1 Cr2C3 Cr2C3 60 to 97 32.4 to 96 65 to 96 37.3 to 94.6 70 to 95 42.7 to 93.3 (Re + Co ) Re 0.03 to 39.6 0.07 to 60.2 0.04 to 34.7 0.1 to 55 0.05 to 29.7 0.12 to 49.3-Co 0.03 to 39.6 0.03 to 39.2 0.04 to 34.7 0.04 to 34.3 0.05 to 29.7 0.05 to 29.4 Mo2C Mo2C 60 to 97 39.6 to 97 65 to 96 44.8 to 96 70 to 95 50.5 to 95 (Re + Co) Re 0.03 to 39.6 0.04 to 46.9 0.04 to 34.7 0.05 to 41.7 0.05 to 29.7 0.07 to 36.3-Co 0.03 to 39.6 0.017 to 27.4 0.04 to 34.7 0.023 to 23.4 0.05 to 29.7 0.028 to 19.6 WC WC 60 to 97 52.9 to 98.2 65 to 96 58.2 to 97 70 to 95 63.6 to 97 (Re + Co) Re 0.03 to 39.6 0.1 to 71.6 0.04 to 34.7 0.15 to 67.1 0.05 to 29.7 0.19 to 62- Co 0.03 to 39.6 0.05 to 51.7 0.04 to 34.7 0.06 to 46.5 0.05 to 29.7 0.07 to 41 TiN TiN 60 to 97 28 to 95 65 to 96 32.6 to 93.4 70 to 95 37.8 to 92 (Re + Co) Re 0.03 to 39.6 0.09 to 65.3 0.04 to 34.7 0.11 to 60.3 0.05 to 29.7 0.14 to 54.8 -Co 0.03 to 39.6 0.035 to 44.4 0.04 to 34.7 0.046 to 39.3 0.05 to 29.7 0.056 to 34 ZrN ZrN 60 to 97 34.5 to 96.3 65 to 96 39.4 to 95 70 to 95 45 to 93.8 (Re + Co) Re 0.03 to 39.6 0.05 to 50 0.04 to 34.7 0.06 to 44.7 0.05 to 29.7 0.08 to 39.2-Co 0.03 to 39.6 0.02 to 30 0.04 to 34.7 0.026 to 25.7 0.05 to 29.7 0.03 to 21.6 HfN HfN 60 to 97 49.8 to 98 65 to 96 55.1 to 97.3 70 to 95 60.7 to 96.6 (Re + Co) Re 0.03 to 39.6 0.1 to 69.6 0.04 to 34.7 0.14 to 65 0.05 to 29.7 0.17 to 59.6-Co 0.03 to 39.6 0.04 to 49.3 0.04 to 34.7 0.055 to 44 0.05 to 29.7 0.067 to 38.6 VN VN 60 to 97 30 to 95.5 65 to 96 35 to 94 70 to 95 40 to 92.6 (Re + Co) Re 0.03 to 39.6 0.09 to 65.3 0.04 to 34.7 0.11 to 60.4 0.05 to 29.7 0.14 to 54.8-Co 0.03 to 39.6 0.035 to 44.5 0.04 to 34.7 0.046 to 39.4 0.05 to 29.7 0.057 to 34.1 NbN NbN 60 to 97 34.4 to 96.3 65 to 96 39.4 to 95 70 to 95 45 to 93.8 (Re + Co) Re 0.03 to 39.6 0.04 to 49.1 0.04 to 34.7 0.06 to 43.8 0.05 to 29.7 0.075 to 38.3-Co 0.03 to 39.6 0.019 t o 29.2 0.04 to 34.7 0.025 to 25 0.05 to 29.7 0.03 to 21 TaN TaN 60 to 97 50.7 to 98 65 to 96 56 to 97.4 70 to 95 61.5 to 96.7

表21在黏結劑中利用鎳基超合金及Co來黏結由元素週期表中IVb、Vb及VIb族元素所形成 # 的碳化物或由元素週期表中IVb及Vb族元素所形成的氮化物，其中黏結劑組成比例範圍由1 %鎳基超合金+99%Co至99%鎳基超合金+l%Co 材料組成範圍1 組成範圍2 組成範圍3 體積％重量％體積％ mm% 體積％重量％ (NBSA+Co) NBSA 0.03 to 39.6 0.05 to 51.5 0.04 to 34.7 0.06 to 46.2 0.05 to 29.7 0.08 to 40.6 - Co 0.03 to 39.6 0.05 to 54.5 0.04 to 34.7 0.07 to 49.2 0.05 to 29.7 0.09 to 43.6 TiC TiC 60 to 97 45 to 95 65 to 96 50 to 93.6 70 to 95 56 to 92 (NBSA+Co) NBSA 0.03 to 39.6 0.04to 44.4 0.04 to 34.7 0.05 to 39.2 0.05 to 29.7 0.06 to 57.5 - Co 0.03 to 39.6 0.04 to 47.4 0.04 to 34.7 0.05 to 42 0.05 to 29.7 0.07 to 34 ZrC ZrC 60 to 97 52 to 96 65 to 96 57 to 95 70 to 95 63 to 94 (NBSA+Co) NBSA 0.03 to 39.6 0.02 to 29 0.04 to 34.7 0.026 to 25 0.05 to 29.7 0.03 to 21 - Co 0.03 to 39.6 0.02 to 32 0.04 to 34.7 0.03 to 27.5 0.05 to 29.7 0.036 to 23 HfC HfC 60 to 97 68 to 98 65 to 96 72 to 97.4 70 to 95 77 to 96.8 (NBSA+Co) NBSA 0.03 to 39.6 0.04 to 49 0.04 to 34.7 0.06 to 44 0.05 to 29.7 0.07 to 38 118Table 21 uses nickel-based superalloys and Co to bond carbides formed by elements IVb, Vb, and VIb in the periodic table of the elements or nitrides formed by elements IVb and Vb in the periodic table, The bonding agent composition ratio ranges from 1% nickel-based superalloy + 99% Co to 99% nickel-based superalloy + l% Co material composition range 1 composition range 2 composition range 3 volume% weight% volume% mm% volume% weight% (NBSA + Co) NBSA 0.03 to 39.6 0.05 to 51.5 0.04 to 34.7 0.06 to 46.2 0.05 to 29.7 0.08 to 40.6-Co 0.03 to 39.6 0.05 to 54.5 0.04 to 34.7 0.07 to 49.2 0.05 to 29.7 0.09 to 43.6 TiC TiC 60 to 97 45 to 95 65 to 96 50 to 93.6 70 to 95 56 to 92 (NBSA + Co) NBSA 0.03 to 39.6 0.04 to 44.4 0.04 to 34.7 0.05 to 39.2 0.05 to 29.7 0.06 to 57.5-Co 0.03 to 39.6 0.04 to 47.4 0.04 to 34.7 0.05 to 42 0.05 to 29.7 0.07 to 34 ZrC ZrC 60 to 97 52 to 96 65 to 96 57 to 95 70 to 95 63 to 94 (NBSA + Co) NBSA 0.03 to 39.6 0.02 to 29 0.04 to 34.7 0.026 to 25 0.05 to 29.7 0.03 to 21-Co 0.03 to 39.6 0.02 to 32 0.04 to 34.7 0.03 to 27.5 0.05 to 29.7 0.036 to 23 HfC HfC 60 to 97 68 to 98 65 to 96 72 to 97.4 70 to 95 77 to 96.8 (NBSA + Co) NBSA 0.03 to 39.6 0.04 to 49 0.04 to 34.7 0.06 to 44 0.05 to 29.7 0.07 to 38 118

1057D-6939-PF 2005352551057D-6939-PF 200535255

- Co 0.03 to 39.6 0.05 to 52 0.04 to 34.7 0.06 to 47 0.05 to 29.7 0.08 to 41 VC VC 60 to 97 48 to 96 65 to 96 53 to 93.5 70 to 95 59 to 93 (NBSA+Co) NBSA 0.03 to 39.6 0.03 to 40 0.04 to 34.7 0.04 to 35 0.05 to 29.7 0.05 to 30 - Co 0.03 to 39.6 0.035 to 43 0.04 to 34.7 0.046 to 38 0.05 to 29.7 0.06 to 33 NbC NbC 60 to 97 57 to 97 65 to 96 62 to 96 70 to 95 67 to 95 (NBSA+Co) NBSA 0.03 to 39.6 0.017 to 27 0.04 to 34.7 0.022 to 23 0.05 to 29.7 0.03 to 19 - Co 0.03 to 39.6 0.02 to 29 0.04 to 34.7 0.025 to 25 0.05 to 29.7 0.03 to 21 TaC TaC 60 to 97 71 to 98 65 to 96 75 to 97.8 70 to 95 79 to 97 (NBSA+Co) NBSA 0.03 to 39.6 0.09 to 67.3 0.04 to 34.7 0.12 to 62.5 0.05 to 29.7 0.15 to 57.0 - Co 0.03 to 39.6 0.04 to 44 0.04 to 34.7 0.05 to 39 0.05 to 29.7 0.06 to 34 Cr2C3 Cr2C3 60 to 97 53 to 96 65 to 96 58 to 95 70 to 95 63 to 94 (NBSA+Co) NBSA 0.03 to 39.6 0.026 to 36.5 0.04 to 34.7 0.035 to 32 0.05 to 29.7 0.044 to 27 - Co 0.03 to 39.6 0.03 to 39 0.04 to 34.7 0.04 to 34 0.05 to 29.7 0.05 to 30 Mo2C Mo2C 60 to 97 60 to 97 65 to 96 65 to 96 70 to 95 70 to 95.6 (NBSA+Co) NBSA 0.03 to 39.6 0.04 to 46.9 0.04 to 34.7 0.05 to 41.7 0.05 to 29.7 0.07 to 36.3 - Co 0.03 to 39.6 0.018 to 27.5 0.04 to 34.7 0.024 to 23.5 0.05 to 29.7 0.03 to 19.7 wc WC 60 to 97 72 to98 65 to 96 76 to 98 70 to 95 80 to 97 (NBSA+Co) NBSA 0.03 to 39.6 0.4 to 49 0.04 to 34.7 0.06 to 44 0.05 to 29.7 0.07 to 38 - Co 0.03 to 39.6 0.05 to 52 0.04 to 34.7 0.065 to 47 0.05 to 29.7 0.08 to 41 TiN TiN 60 to 97 47 to 96 65 to 96 53 to 94 70 to 95 58 to 93 (NBSA+Co) NBSA 0.03 to 39.6 0.03 to 42 0.04 to 34.7 0.04 to 37 0.05 to 29.7 0.05 to 32 - Co 0.03 to 39.6 0.04 to 45 0.04 to 34.7 0.05 to 40 0.05 to 29.7 0.06 to 34 ZrN ZrN 60 to 97 55 to 97 65 to 96 60 to 96 70 to 95 65 to 95 (NBSA+Co) NBSA 0.03 to 39.6 0.02 to 31 0.04 to 34.7 0.027 to 27 0.05 to 29.7 0.03 to 22 Co 0.03 to 39.6 0.02 to 27 0.04 to 34.7 0.024 to 23 0.05 to 29.7 0.03 to 20 HfN HfN 60 to 97 70 to 98 65 to 96 74 to 97.6 70 to 95 78 to 97 (NBSA+Co) NBSA 0.03 to 39.6 0.045 to 53 0.04 to 34.7 0.06 to 47 0.05 to 29.7 0.07 to 41 - Co 0.03 to 39.6 0.04 to 44 0.04 to 34.7 0.055 to 40 0.05 to 29.7 0.066 to 34 VN VN 60 to 97 50 to 96 65 to 96 55 to 95 70 to 95 61 to 93 (NBSA+Co) NBSA 0.03 to 39,6 0.04 to 47 0.04 to 34.7 0.05 to 41 0.05 to 29.7 0.06 to 36 - Co 0.03 to 39.6 0.03 to 40 0.04 to 34.7 0.04 to 35 0.05 to 29.7 0.05 to 30 NbN NbN 60 to 97 55 to 97 65 to 96 60 to 96 70 to 95 65 to 95 (Re+Co) NBSA 0.03 to 39.6 0.02 to 30 0.04 to 34.7 0.026 to 26 0.05 to 29.7 0.032 to 22 - Co 0.03 to 39.6 0.017 to 26 0.04 to 34.7 0.023 to 23 0.05 to 29.7 0.03 to 19 TaN TaN 60 to 97 70 to 98 65 to 96 75 to 97.7 70 to 95 79 to 97 表22 在黏結劑中利用Re、鎳基超合金及Co來黏結由元素週期表中IVb、Vb及VIb族元素所形成的碳化物或由元素週期表中IVb及Vb族元素所形成的氮化物，其中黏結劑組成比例範圍由0.5%+0.5%Co+99%鎳基超合金至0.5%Re+99%Co+0.5%鎳基超合金材料組成範圍1 組成範圍2 組成範圍3 體積％重量％體積％重量°/〇體積％重量％ 119-Co 0.03 to 39.6 0.05 to 52 0.04 to 34.7 0.06 to 47 0.05 to 29.7 0.08 to 41 VC VC 60 to 97 48 to 96 65 to 96 53 to 93.5 70 to 95 59 to 93 (NBSA + Co) NBSA 0.03 to 39.6 0.03 to 40 0.04 to 34.7 0.04 to 35 0.05 to 29.7 0.05 to 30-Co 0.03 to 39.6 0.035 to 43 0.04 to 34.7 0.046 to 38 0.05 to 29.7 0.06 to 33 NbC NbC 60 to 97 57 to 97 65 to 96 62 to 96 70 to 95 67 to 95 (NBSA + Co) NBSA 0.03 to 39.6 0.017 to 27 0.04 to 34.7 0.022 to 23 0.05 to 29.7 0.03 to 19-Co 0.03 to 39.6 0.02 to 29 0.04 to 34.7 0.025 to 25 0.05 to 29.7 0.03 to 21 TaC TaC 60 to 97 71 to 98 65 to 96 75 to 97.8 70 to 95 79 to 97 (NBSA + Co) NBSA 0.03 to 39.6 0.09 to 67.3 0.04 to 34.7 0.12 to 62.5 0.05 to 29.7 0.15 to 57.0-Co 0.03 to 39.6 0.04 to 44 0.04 to 34.7 0.05 to 39 0.05 to 29.7 0.06 to 34 Cr2C3 Cr2C3 60 to 97 53 to 96 65 to 96 58 to 95 70 to 95 63 to 94 (NBSA + Co) NBSA 0.03 to 39.6 0.026 to 36.5 0.04 to 34.7 0.035 to 32 0.05 to 29.7 0.044 to 27-Co 0.03 to 39.6 0.03 to 39 0.04 to 34.7 0.04 to 34 0.05 to 2 9.7 0.05 to 30 Mo2C Mo2C 60 to 97 60 to 97 65 to 96 65 to 96 70 to 95 70 to 95.6 (NBSA + Co) NBSA 0.03 to 39.6 0.04 to 46.9 0.04 to 34.7 0.05 to 41.7 0.05 to 29.7 0.07 to 36.3-Co 0.03 to 39.6 0.018 to 27.5 0.04 to 34.7 0.024 to 23.5 0.05 to 29.7 0.03 to 19.7 wc WC 60 to 97 72 to 98 65 to 96 76 to 98 70 to 95 80 to 97 (NBSA + Co) NBSA 0.03 to 39.6 0.4 to 49 0.04 to 34.7 0.06 to 44 0.05 to 29.7 0.07 to 38-Co 0.03 to 39.6 0.05 to 52 0.04 to 34.7 0.065 to 47 0.05 to 29.7 0.08 to 41 TiN TiN 60 to 97 47 to 96 65 to 96 53 to 94 70 to 95 58 to 93 (NBSA + Co) NBSA 0.03 to 39.6 0.03 to 42 0.04 to 34.7 0.04 to 37 0.05 to 29.7 0.05 to 32-Co 0.03 to 39.6 0.04 to 45 0.04 to 34.7 0.05 to 40 0.05 to 29.7 0.06 to 34 ZrN ZrN 60 to 97 55 to 97 65 to 96 60 to 96 70 to 95 65 to 95 (NBSA + Co) NBSA 0.03 to 39.6 0.02 to 31 0.04 to 34.7 0.027 to 27 0.05 to 29.7 0.03 to 22 Co 0.03 to 39.6 0.02 to 27 0.04 to 34.7 0.024 to 23 0.05 to 29.7 0.03 to 20 HfN HfN 60 to 97 70 to 98 65 to 96 74 to 97.6 70 to 95 78 to 97 (NBSA + Co) NBSA 0.03 to 39.6 0.045 to 53 0.04 to 34.7 0.06 to 47 0.05 to 29.7 0.07 to 41-Co 0.03 to 39.6 0.04 to 44 0.04 to 34.7 0.055 to 40 0.05 to 29.7 0.066 to 34 VN VN 60 to 97 50 to 96 65 to 96 55 to 95 70 to 95 61 to 93 (NBSA + Co) NBSA 0.03 to 39,6 0.04 to 47 0.04 to 34.7 0.05 to 41 0.05 to 29.7 0.06 to 36-Co 0.03 to 39.6 0.03 to 40 0.04 to 34.7 0.04 to 35 0.05 to 29.7 0.05 to 30 NbN NbN 60 to 97 55 to 97 65 to 96 60 to 96 70 to 95 65 to 95 (Re + Co) NBSA 0.03 to 39.6 0.02 to 30 0.04 to 34.7 0.026 to 26 0.05 to 29.7 0.032 to 22-Co 0.03 to 39.6 0.017 to 26 0.04 to 34.7 0.023 to 23 0.05 to 29.7 0.03 to 19 TaN TaN 60 to 97 70 to 98 65 to 96 75 to 97.7 70 to 95 79 to 97 Table 22 In the binder, Re, nickel-based superalloy and Co are used to bond the carbides formed by the IVb, Vb and VIb elements in the periodic table or the nitrides formed by the IVb and Vb elements in the periodic table. The binder composition ratio ranges from 0.5% + 0.5% Co + 99% nickel-based superalloy to 0.5% Re + 99% Co + 0.5% nickel-based superalloy Feed composition range of a composition range of 2% by weight of the composition range of 3 vol% vol% wt ° / square wt% vol% 119

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(Re+Co Re 0.015 to 39.6 0.06 to 73.6 0.02 to 34.65 0.08 to 69.3 0.025 to 29.7 0.1 to 64.3 +NBSA) NBSA 0.015 to 39.6 0.02 to 51.3 0.02 to 34.65 0.03 to 46.0 0.025 to 29.7 0.035 to 40.5 - Co 0.015 to 39.6 0.03 to 54.3 0.02 to 34.65 0.036 to 49.0 0.025 to 29.7 0.045 to 43.5 TiC TiC 60 to 97 26 to 95 65 to 96 30 to 94 70 to 95 35 to 92 (Re+Co Re 0.015 to 39.6 0.05 to 67.7 0.02 to 34.65 0.06 to 62.9 0.025 to 29.7 0.08 to 57.5 +NBSA) NBSA 0.015 to 39.6 0.017 to 44.2 0.02 to 34.65 0.022 to 39.1 0.025 to 29.7 0.028 to 33.9 - Co 0.015 to 39.6 0.02 to 47.2 0.02 to 34.65 0.027 to 42.0 0.025 to 29.7 0.034 to 36.7 ZrC ZrC 60 to 97 32 to 96 65 to 96 37 to 95 70 to 95 43 to 94 (Re+Co Re 0.015 to 39.6 0.025 to 52.1 0.02 to 34.65 0.034 to 46.8 0.025 to 29.7 0.042 to 41.2 +NBSA) NBSA 0.015 to 39.6 0.009 to 29.3 0.02 to 34.65 0.012 to 25.1 0.025 to 29.7 0.015 to 21 - Co 0.015 to 39.6 0.01 to 31.8 0.02 to 34.65 0.014 to 27.4 0.025 to 29.7 0.018 to 23.1 HfC HfC 60 to 97 48 to 98 65 to 96 53 to 97.4 70 to 95 59 to 96.8 (Re+Co Re 0.015 to 39.6 0.06 to 71.5 0.02 to 34.65 0.08 to 67 0.025 to 29.7 0.09 to 61.8 +NBSA) NBSA 0.015 to 39.6 0.02 to 48.6 0.02 to 34.65 0.026 to 43.4 0.025 to 29.7 0.032 to 38 - Co 0.015 to 39.6 0.024 to 51.7 0.02 to 34.65 0.032 to 46.4 0.025 to 29.7 0.04 to 40.9 VC VC 60 to 97 28 to 96 65 to 96 33 to 94 70 to 95 38 to 93 (Re+Co Re 0.015 to 39.6 0.04 to 63.8 0.02 to 34.65 0.05 to 58.7 0.025 to 29.7 0.07 to 53.1 +NBSA) NBSA 0.015 to 39.6 0.015 to 40 0.02 to 34.65 0.02 to 35 0.025 to 29.7 0.024 to 30 - Co 0.015 to 39.6 0.017 to 43 0.02 to 34.65 0.023 to 37.9 0.025 to 29.7 0.03 to 32.7 NbC NbC 60 to 97 36 to 97 65 to 96 41 to 96 70 to 95 47 to 95 (Re+Co Re 0.015 to 39.6 0.02 to 48.8 0.02 to 34.65 0.03 to 43.5 0.025 to 29.7 0.04 to 38 +NBSA) NBSA 0.015 to 39.6 0.008 to 26.6 0.02 to 34.65 0.011 to 22.6 0.025 to 29.7 0.013 to 18.9 - Co 0.015 to 39.6 0.01 to 29 0.02 to 34.65 0.013 to 24.8 0.025 to 29.7 0.016 to 20.8 TaC TaC 60 to 97 51 to 98.3 65 to 96 56 to 97.7 70 to 95 61.8 to 97.2 (Re+Co Re 0.015 to 39.6 0.05 to 67.3 0.02 to 34.65 0.06 to 62.5 0.025 to 29.7 0.08 to 57 +NBSA) NBSA 0.015 to 39.6 0.017 to 43.8 0.02 to 34.65 0.022 to 38.7 0.025 to 29.7 0.027 to 33.5 - Co 0.015 to 39.6 0.02 to 46.8 0.02 to 34.65 0.027 to 41.6 0.025 to 29.7 0.033 to 36.2 Cr2C3 Cr2C3 60 to 97 32 to 96 65 to 96 37 to 95 70 to 95 43 to94 (Re+Co Re 0.015 to 39.6 0.03 to 60.2 0.02 to 34.65 0.05 to 55 0.025 to 29.7 0.06 to 49 +NBSA) NBSA 0.015 to 39.6 0.013 to 36.4 0.02 to 34.65 0.017 to 31.7 0.025 to 29.7 0.02 to 27 - Co 0.015 to 39.6 0.015 to 39.3 0.02 to 34.65 0.02 to 34 0.025 to 29.7 0.025 to 29 Mo2C Mo2C 60 to 97 39 to 97 65 to 96 45 to 96 70 to 95 50 to 95.6 (Re+Co Re 0.015 to 39.6 0.02 to 46.9 0.02 to 34.65 0.027 to 41.7 0.025 to 29.7 0.034 to 36.3 +NBSA) NBSA 0.015 to 39.6 0.008 to 25.1 0.02 to 34.65 0.01 to 21.3 0.025 to 29.7 0.013 to 17.8 - Co 0.015 to 39.6 0.009 to 27.5 0.02 to 34.65 0.012 to 23.5 0.025 to 29.7 0.015 to 19.6 WC WC 60 to 97 53 to 98 65 to 96 58 to 97.8 70 to 95 64 to 97.4 材针組成範圍1 組成範圍2 組成範圍3 體積％重量％體積％重量％體積％重量％ (Re+Co Re 0.015 to 39.6 0.06 to 71.6 0.02 to 34.65 0.08 to 67.2 0.025 to 29.7 0.1 to 62 +NBSA) NBSA 0.015 to 39.6 0.02 to 48.8 0.02 to 34.65 0.027 to 43.6 0.025 to 29.7 0.032 to 38.2 - Co 0.015 to 39.6 0.025 to 51.9 0.02 to 34.65 0.03 to 46.6 0.025 to 29.7 0.04 to 41(Re + Co Re 0.015 to 39.6 0.06 to 73.6 0.02 to 34.65 0.08 to 69.3 0.025 to 29.7 0.1 to 64.3 + NBSA) NBSA 0.015 to 39.6 0.02 to 51.3 0.02 to 34.65 0.03 to 46.0 0.025 to 29.7 0.035 to 40.5-Co 0.015 to 39.6 0.03 to 54.3 0.02 to 34.65 0.036 to 49.0 0.025 to 29.7 0.045 to 43.5 TiC TiC 60 to 97 26 to 95 65 to 96 30 to 94 70 to 95 35 to 92 (Re + Co Re 0.015 to 39.6 0.05 to 67.7 0.02 to 34.65 0.06 to 62.9 0.025 to 29.7 0.08 to 57.5 + NBSA) NBSA 0.015 to 39.6 0.017 to 44.2 0.02 to 34.65 0.022 to 39.1 0.025 to 29.7 0.028 to 33.9-Co 0.015 to 39.6 0.02 to 47.2 0.02 to 34.65 0.027 to 42.0 0.025 to 29.7 0.034 to 36.7 ZrC ZrC 60 to 97 32 to 96 65 to 96 37 to 95 70 to 95 43 to 94 (Re + Co Re 0.015 to 39.6 0.025 to 52.1 0.02 to 34.65 0.034 to 46.8 0.025 to 29.7 0.042 to 41.2 + NBSA) NBSA 0.015 to 39.6 0.009 to 29.3 0.02 to 34.65 0.012 to 25.1 0.025 to 29.7 0.015 to 21-Co 0.015 to 39.6 0.01 to 31.8 0.02 to 34.65 0.014 to 27.4 0.025 to 29.7 0.018 to 23.1 HfC HfC 60 to 97 48 to 98 65 to 96 53 to 9 7.4 70 to 95 59 to 96.8 (Re + Co Re 0.015 to 39.6 0.06 to 71.5 0.02 to 34.65 0.08 to 67 0.025 to 29.7 0.09 to 61.8 + NBSA) NBSA 0.015 to 39.6 0.02 to 48.6 0.02 to 34.65 0.026 to 43.4 0.025 to 29.7 0.032 to 38-Co 0.015 to 39.6 0.024 to 51.7 0.02 to 34.65 0.032 to 46.4 0.025 to 29.7 0.04 to 40.9 VC VC 60 to 97 28 to 96 65 to 96 33 to 94 70 to 95 38 to 93 (Re + Co Re 0.015 to 39.6 0.04 to 63.8 0.02 to 34.65 0.05 to 58.7 0.025 to 29.7 0.07 to 53.1 + NBSA) NBSA 0.015 to 39.6 0.015 to 40 0.02 to 34.65 0.02 to 35 0.025 to 29.7 0.024 to 30-Co 0.015 to 39.6 0.017 to 43 0.02 to 34.65 0.023 to 37.9 0.025 to 29.7 0.03 to 32.7 NbC NbC 60 to 97 36 to 97 65 to 96 41 to 96 70 to 95 47 to 95 (Re + Co Re 0.015 to 39.6 0.02 to 48.8 0.02 to 34.65 0.03 to 43.5 0.025 to 29.7 0.04 to 38 + NBSA) NBSA 0.015 to 39.6 0.008 to 26.6 0.02 to 34.65 0.011 to 22.6 0.025 to 29.7 0.013 to 18.9-Co 0.015 to 39.6 0.01 to 29 0.02 to 34.65 0.013 to 24.8 0.025 to 29.7 0.016 to 20.8 TaC TaC 60 to 97 51 to 98.3 65 to 9 6 56 to 97.7 70 to 95 61.8 to 97.2 (Re + Co Re 0.015 to 39.6 0.05 to 67.3 0.02 to 34.65 0.06 to 62.5 0.025 to 29.7 0.08 to 57 + NBSA) NBSA 0.015 to 39.6 0.017 to 43.8 0.02 to 34.65 0.022 to 38.7 0.025 to 29.7 0.027 to 33.5-Co 0.015 to 39.6 0.02 to 46.8 0.02 to 34.65 0.027 to 41.6 0.025 to 29.7 0.033 to 36.2 Cr2C3 Cr2C3 60 to 97 32 to 96 65 to 96 37 to 95 70 to 95 43 to94 (Re + Co Re 0.015 to 39.6 0.03 to 60.2 0.02 to 34.65 0.05 to 55 0.025 to 29.7 0.06 to 49 + NBSA) NBSA 0.015 to 39.6 0.013 to 36.4 0.02 to 34.65 0.017 to 31.7 0.025 to 29.7 0.02 to 27-Co 0.015 to 39.6 0.015 to 39.3 0.02 to 34.65 0.02 to 34 0.025 to 29.7 0.025 to 29 Mo2C Mo2C 60 to 97 39 to 97 65 to 96 45 to 96 70 to 95 50 to 95.6 (Re + Co Re 0.015 to 39.6 0.02 to 46.9 0.02 to 34.65 0.027 to 41.7 0.025 to 29.7 0.034 to 36.3 + NBSA) NBSA 0.015 to 39.6 0.008 to 25.1 0.02 to 34.65 0.01 to 21.3 0.025 to 29.7 0.013 to 17.8-Co 0.015 to 39.6 0.009 to 27.5 0.02 to 34.65 0.012 to 23.5 0.025 to 29.7 0.015 to 19.6 WC WC 60 to 97 53 to 98 65 to 96 58 to 97.8 70 to 95 64 to 97.4 needle composition range 1 composition range 2 composition range 3 vol% vol% vol% vol% vol% wt% (Re + Co Re 0.015 to 39.6 0.06 to 71.6 0.02 to 34.65 0.08 to 67.2 0.025 to 29.7 0.1 to 62 + NBSA) NBSA 0.015 to 39.6 0.02 to 48.8 0.02 to 34.65 0.027 to 43.6 0.025 to 29.7 0.032 to 38.2-Co 0.015 to 39.6 0.025 to 51.9 0.02 to 34.65 0.03 to 46.6 0.025 to 29.7 0.04 to 41

1057D-6939-PF 120 2005352551057D-6939-PF 120 200535255

TiN TiN 60 to 97 28 to 96 65 to 96 33 to 94 70 to 95 38 to 93 (Re+Co Re 0.015 to 39.6 0.04 to 65.3 0.02 to 34.65 0.06 to 60.3 0.025 to 29.7 0.07 to 54.8 +NBSA) NBSA 0.015 to 39.6 0.016 to 41.6 0.02 to 34.65 0.02 to 36.6 0.025 to 29.7 0.025 to 31.5 - Co 0.015 to 39.6 0.02 to 44.6 0.02 to 34.65 0.025 to 40 0.025 to 29.7 0.03 to 34 ZrN ZrN 60 to 97 34 to 97 65 to 96 39 to 96 70 to 95 45 to 95 Re+Co Re 0.015 to 39.6 0.02 to 50 0.02 to 34.65 0.03to 45 0.025 to 29.7 0.04 to 39 +NBSA NBSA 0.015 to 39.6 0.009 to 27.5 0.02 to 34.65 0.011 to 23.5 0.025 to 29.7 0.014 to 20 - Co 0.015 to 39.6 0.01 to 30 0.02 to 34.65 0.013 to 25.8 0.025 to 29.7 0.017 to 22 HfN HfN 60 to 97 50 to 98 65 to 96 55 to 97.6 70 to 95 61 to 97 Re+Co Re 0.015 to 39.6 0.05 to 60 0.02 to 34.65 0.07 to 65 0.025 to 29.7 0.09 to 60 +NBSA NBSA 0.015 to 39.6 0.02 to 46.4 0.02 to 34.65 0.024to41.2 0.025 to 29.7 0.03 to 36 - Co 0.015 to 39.6 0.02 to 49 0.02 to 34.65 0.03 to 44 0.025 to 29.7 0.04 to 39 VN VN 60 to 97 30 to 96 65 to 96 35 to 95 70 to 95 40 to 93 Re+Co Re 0.015 to 39.6 0.04 to 65 0.02 to 34.65 0.06 to 60 0.025 ίο 29.7 0.07 to 55 +NBSA NBSA 0.015 to 39.6 0.016to42 0.02 to 34.65 0.02 to 37 0.025 to 29.7 0.025 to 32 - Co 0.015 to 39.6 0.02 to 45 0.02 to 34.65 0.025 to 39.5 0.025 to 29.7 0.03 to 34 NbN NbN 60 to 97 34to 97 65 to 96 39 to 96 70 to 95 45 to 95 Re+Co Re 0.015 to 39.6 0.02 to 49 0.02 to 34.65 0.03 to 44 0.025 to 29.7 0.04 to 38 +NBSA NBSA 0.015 to 39.6 0.008 to 27 0.02 to 34.65 0.011 to 23 0.025 to 29.7 0.014 to 19 - Co 0.015 to 39.6 0.01 to 29 0.02 to 34.65 0.013 to 25 0.025 to 29.7 0.016 to 21 TaN TaN 60 to 97 51 to 98.3 65 to 96 56 to 97.7 70 to 95 61.5 to 97.1TiN TiN 60 to 97 28 to 96 65 to 96 33 to 94 70 to 95 38 to 93 (Re + Co Re 0.015 to 39.6 0.04 to 65.3 0.02 to 34.65 0.06 to 60.3 0.025 to 29.7 0.07 to 54.8 + NBSA) NBSA 0.015 to 39.6 0.016 to 41.6 0.02 to 34.65 0.02 to 36.6 0.025 to 29.7 0.025 to 31.5-Co 0.015 to 39.6 0.02 to 44.6 0.02 to 34.65 0.025 to 40 0.025 to 29.7 0.03 to 34 ZrN ZrN 60 to 97 34 to 97 65 to 96 39 to 96 70 to 95 45 to 95 Re + Co Re 0.015 to 39.6 0.02 to 50 0.02 to 34.65 0.03to 45 0.025 to 29.7 0.04 to 39 + NBSA NBSA 0.015 to 39.6 0.009 to 27.5 0.02 to 34.65 0.011 to 23.5 0.025 to 29.7 0.014 to 20-Co 0.015 to 39.6 0.01 to 30 0.02 to 34.65 0.013 to 25.8 0.025 to 29.7 0.017 to 22 HfN HfN 60 to 97 50 to 98 65 to 96 55 to 97.6 70 to 95 61 to 97 Re + Co Re 0.015 to 39.6 0.05 to 60 0.02 to 34.65 0.07 to 65 0.025 to 29.7 0.09 to 60 + NBSA NBSA 0.015 to 39.6 0.02 to 46.4 0.02 to 34.65 0.024 to 41.2 0.025 to 29.7 0.03 to 36-Co 0.015 to 39.6 0.02 to 49 0.02 to 34.65 0.03 to 44 0.025 to 29.7 0.04 to 39 VN VN 60 to 97 30 to 96 65 to 96 35 to 95 70 to 95 40 to 93 Re + Co Re 0.015 to 39.6 0.04 to 65 0.02 to 34.65 0.06 to 60 0.025 ί 29.7 0.07 to 55 + NBSA NBSA 0.015 to 39.6 0.016 to 42 0.02 to 34.65 0.02 to 37 0.025 to 29.7 0.025 to 32-Co 0.015 to 39.6 0.02 to 45 0.02 to 34.65 0.025 to 39.5 0.025 to 29.7 0.03 to 34 NbN NbN 60 to 97 34to 97 65 to 96 39 to 96 70 to 95 45 to 95 Re + Co Re 0.015 to 39.6 0.02 to 49 0.02 to 34.65 0.03 to 44 0.025 to 29.7 0.04 to 38 + NBSA NBSA 0.015 to 39.6 0.008 to 27 0.02 to 34.65 0.011 to 23 0.025 to 29.7 0.014 to 19-Co 0.015 to 39.6 0.01 to 29 0.02 to 34.65 0.013 to 25 0.025 to 29.7 0.016 to 21 TaN TaN 60 to 97 51 to 98.3 65 to 96 56 to 97.7 70 to 95 61.5 to 97.1

表23利用Re來黏結WC+TiC或WC+TaC或WC+TiC+TaC的組成材料組成範圍1 組成範圍2 組成範圍3 mm% 重量％體積％重量％體積％重量％ Re Re 3 to 40 4 to 54 4 to 35 5 to 49 5 to 30 7 to 43 - WC 40 to 96 40 to 96 43 to 94.5 44 to 94 45 to 93 48 to 93 WC+TiC TiC 1 to 48 0.3 to 21 1.5 to 43 0.5 to 19 2 to 45 0.6 to 18 Re Re 3 to 40 4 to 48 4 to 35 5 to 42 5 to 30 7 to 37 - WC 50 to 96.5 44 to 96 55 to 95 49 to 94 60 to 93.5 55 to 92 WC+TaC TaC 0.5 to 24 0.5 to 21 1 to 22 1 to 19 1.5 to 18 1.5tol8 Re Re 3 to 40 4 to 48 4 to 35 5 to 43 5 to 30 7 to 38 - WC 40 to 95.5 36 to 95 45 to 93 41 to 93 50 to 90 48 to 90 WC+TiC TiC 1 to 48 0.3 to 22 2 to 45 0.6 to 20 3 to 42 0.9 to 18 +TaC TaC 0.5 to 20 0.5 to 25 1 to 18 0.8 to 22 2 to 15 2 to 17 表24利用鎳基超合金來黏結WC+TiC或WC+TaC或WC+TiC+TaC的組成材料組成範圍1 組成範圍2 組成範圍3 體積％重量％體積％重量％體積％重量％ NBSA NBSA 3 to 40 1.5 to 31 4 to 35 2 to 26 5 to 30 3 to 23 121Table 23 Composition materials for bonding WC + TiC or WC + TaC or WC + TiC + TaC using Re Composition range 1 Composition range 2 Composition range 3 mm% wt% vol% wt% vol% wt% Re Re 3 to 40 4 to 54 4 to 35 5 to 49 5 to 30 7 to 43-WC 40 to 96 40 to 96 43 to 94.5 44 to 94 45 to 93 48 to 93 WC + TiC TiC 1 to 48 0.3 to 21 1.5 to 43 0.5 to 19 2 to 45 0.6 to 18 Re Re 3 to 40 4 to 48 4 to 35 5 to 42 5 to 30 7 to 37-WC 50 to 96.5 44 to 96 55 to 95 49 to 94 60 to 93.5 55 to 92 WC + TaC TaC 0.5 to 24 0.5 to 21 1 to 22 1 to 19 1.5 to 18 1.5 tol8 Re Re 3 to 40 4 to 48 4 to 35 5 to 43 5 to 30 7 to 38-WC 40 to 95.5 36 to 95 45 to 93 41 to 93 50 to 90 48 to 90 WC + TiC TiC 1 to 48 0.3 to 22 2 to 45 0.6 to 20 3 to 42 0.9 to 18 + TaC TaC 0.5 to 20 0.5 to 25 1 to 18 0.8 to 22 2 to 15 2 to 17 Table 24 Ni-based superalloys are used to bond WC + TiC or WC + TaC or WC + TiC + TaC. Composition range 1 Composition range 2 Composition range 3 vol% wt% vol% wt% vol% wt% NBSA NBSA 3 to 40 1.5 to 31 4 t o 35 2 to 26 5 to 30 3 to 23 121

1057D-6939-PF •200535255 - WC 40 to 96 60 to 98 43 to 94.5 63 to 97 45 to 93 66 to 96.5 WC+TiC TiC 1 to 48 0.3 to 25 1.5 to 43 0.5 to 22 2 to 45 0.6 to 20 NBSA NBSA 3 to 40 1.5 to 26 4 to 35 2 to 22 5 to 30 3 to 18 - WC 50 to 96. 5 63 to 98 55 to 95 67 to 97 60 to 93.5 71 to 96 WC+TaC TaC 0.5 to 24 0.5 to 26 1 to 22 1 to 23 1.5 to 18 1.5 to 21 NBSA NBSA 3 to 40 1.5 to 26 4 to 35 2 to 22 5 to 30 3 to 19 - WC 40 to 95.5 51 to 98 45 to 93 56 to 96 50 to 90 61 to 94 WC+TiC TiC 1 to 48 0.4 to 23 2 to 45 0.8 to 21 3 to 42 1 to 19 +TaC TaC 0.5 to 20 0.6 to 26 1 to 18 1 to 23 2 to 15 2 to 18 表25利用Re及鎳基超合金來黏結WC+TiC或WC+TaC或WC+TiC+TaC的組成材料組成範圍1 組成範圍2 組成範圍3 mm% 重量％體積％重量0/〇 mm% 重量％ (Re+ Re 0.03 to 39-6 0.04 to 52 0.04 to 34.65 0.06 to 48 0.05 to 29.7 0.07 to 45 NBSA) NBSA 0.03 to 39.6 0.015 to 29 0.04 to 34.65 0.02 to 26 0.05 to 29.7 0.026 to 23 - WC 40 to 96 40 to 98 43 to 94.5 44 to 97 45 to 93 48 to 96.6 WC+TiC TiC 1 to 48 0.3 to 24 1.5 to 45 0.5 to 22 2 to 42 0.6 to 21 (Re+ Re 0.03 to 39.6 0.04 to 47 0.04 to 34.65 0.055 to 42 0.05 to 29.7 0.07 to 37 NBSA) NBSA 0.03 to 39.6 0.015 to 25 0.04 to 34.65 0.02 to 22 0.05 to 29.7 0.025 to 18 - WC 50 to 96.5 44 to 98 55 to 95 50 to 97 60 to 93 55 to 95.5 WC+TaC TaC 0.5 to 22 0.5 to 24 1 to 20 1 to 21.5 2 to 18 2 to 19 (Re+ Re 0.03 to 39.6 0.04 to 53 0.04 to 34.65 0.06 to 47 0.05 to 29.7 0.07 to 41 NBSA) NBSA 0.03 to 39.6 0.015 to 30 0.04 to 34.65 0.02 to 25 0.05 to 29.7 0.026 to 21 - WC 40 to 95.5 40 to 98 45 to 93 46 to 96 50 to 90 51 to 94 WC+TiC TiC 1 to 48 0.3 to 23 2 to 45 0.6 to 21 3 to 42 0.9 to 19 +TaC TaC 0.5 to 20 0.4 to 26 1 to 18 0.8 to 23 2 to 15 2 to 181057D-6939-PF • 200535255-WC 40 to 96 60 to 98 43 to 94.5 63 to 97 45 to 93 66 to 96.5 WC + TiC TiC 1 to 48 0.3 to 25 1.5 to 43 0.5 to 22 2 to 45 0.6 to 20 NBSA NBSA 3 to 40 1.5 to 26 4 to 35 2 to 22 5 to 30 3 to 18-WC 50 to 96. 5 63 to 98 55 to 95 67 to 97 60 to 93.5 71 to 96 WC + TaC TaC 0.5 to 24 0.5 to 26 1 to 22 1 to 23 1.5 to 18 1.5 to 21 NBSA NBSA 3 to 40 1.5 to 26 4 to 35 2 to 22 5 to 30 3 to 19-WC 40 to 95.5 51 to 98 45 to 93 56 to 96 50 to 90 61 to 94 WC + TiC TiC 1 to 48 0.4 to 23 2 to 45 0.8 to 21 3 to 42 1 to 19 + TaC TaC 0.5 to 20 0.6 to 26 1 to 18 1 to 23 2 to 15 2 to 18 Table 25 uses Re And nickel-based superalloys to bond WC + TiC or WC + TaC or WC + TiC + TaC. Composition range 1 Composition range 2 Composition range 3 mm% wt% vol% wt 0 / 0mm% wt% (Re + Re 0.03 to 39-6 0.04 to 52 0.04 to 34.65 0.06 to 48 0.05 to 29.7 0.07 to 45 NBSA) NBSA 0.03 to 39.6 0.015 to 29 0.04 to 34.65 0.02 to 26 0.05 to 29.7 0.026 to 23-WC 40 to 96 40 to 98 43 to 94.5 44 to 97 45 to 93 48 to 96.6 WC + TiC TiC 1 to 48 0.3 to 24 1.5 to 45 0.5 to 22 2 to 42 0.6 to 21 (Re + Re 0.03 to 39.6 0.04 to 47 0.04 to 34.65 0.055 to 42 0.05 to 29.7 0.07 to 37 NBSA) NBSA 0.03 to 39.6 0.015 to 25 0.04 to 34.65 0.02 to 22 0.05 to 29.7 0.025 to 18-WC 50 to 96.5 44 to 98 55 to 95 50 to 97 60 to 93 55 to 95.5 WC + TaC TaC 0.5 to 22 0.5 to 24 1 to 20 1 to 21.5 2 to 18 2 to 19 (Re + Re 0.03 to 39.6 0.04 to 53 0.04 to 34.65 0.06 to 47 0.05 to 29.7 0.07 to 41 NBSA) NBSA 0.03 to 39.6 0.015 to 30 0.04 to 34.65 0.02 to 25 0.05 to 29.7 0.026 to 21-WC 40 to 95.5 40 to 98 45 to 93 46 to 96 50 to 90 51 to 94 WC + TiC TiC 1 to 48 0.3 to 23 2 to 45 0.6 to 21 3 to 42 0.9 to 19 + TaC TaC 0.5 to 20 0.4 to 26 1 to 18 0.8 to 23 2 to 15 2 to 18

表26利用Re及Co來黏結WC+TiC或WC+TaC或WC+TiC+TaC的組成材料組成範圍1 組成範圍2 組成範圍3 體積％重量％體積％重量％體積％重量％ (Re+ Re 0.03 to 39.6 0.04 to 53 0.04 to 34.65 0.055 to 48 0.05 to 29.7 0.07 to 43 Co) Co 0.03 to 39.6 0.017to31 0.04 to 34.65 0.023 to 28 0.05 to 29.7 0.03 to 26 - WC 40 to 96 40 to 98 43 to 94.5 44 to 97 45 to 93 48 to 96 WC+TiC TiC 1 to 48 0.3 to 23 1.5 to 45 0.5 to 22 2 to 42 0.6 to 21 (Re+ Re 0.03 to 39.6 0.04 to 47 0.04 to 34.65 0.055 to 42 0.05 to 29.7 0.07 to 37 Co) CO 0.03 to 39.6 0.017 to 28 0.04 to 34.65 0.023 to 24 0.05 to 29.7 0.03 to 20 - WC 50 to 96.5 44 to 98 55 to 95 50 to 97 60 to 93 55 to 95 WC+TaC TaC 0.5 to 22 0.5 to 24 1 to 20 1 to 21 2 to 18 2 to 19 (Re+ Re 0.03 to 39.6 0.04 to 53 0.04 to 34.65 0.06 to 47 0.05 to 29.7 0.07 to 41 Co) Co 0.03 to 39.6 0.017 to 33 0.04 to 34.65 0.023 to 28 0.05 to 29.7 0.03 to 23 - WC 40 to 95.5 40 to 98 45 to 93 46 to 96 50 to 90 51 to 94 WC+TiC TiC 1 to 48 0.3 to 23 2 to 45 0.6 to 21 3 to 42 0.9 to 19 122Table 26 Composition materials for bonding WC + TiC or WC + TaC or WC + TiC + TaC using Re and Co Composition range 1 Composition range 2 Composition range 3 vol% wt% vol% wt% vol% wt% 39.6 0.04 to 53 0.04 to 34.65 0.055 to 48 0.05 to 29.7 0.07 to 43 Co) Co 0.03 to 39.6 0.017 to 31 0.04 to 34.65 0.023 to 28 0.05 to 29.7 0.03 to 26-WC 40 to 96 40 to 98 43 to 94.5 44 to 97 45 to 93 48 to 96 WC + TiC TiC 1 to 48 0.3 to 23 1.5 to 45 0.5 to 22 2 to 42 0.6 to 21 (Re + Re 0.03 to 39.6 0.04 to 47 0.04 to 34.65 0.055 to 42 0.05 to 29.7 0.07 to 37 Co ) CO 0.03 to 39.6 0.017 to 28 0.04 to 34.65 0.023 to 24 0.05 to 29.7 0.03 to 20-WC 50 to 96.5 44 to 98 55 to 95 50 to 97 60 to 93 55 to 95 WC + TaC TaC 0.5 to 22 0.5 to 24 1 to 20 1 to 21 2 to 18 2 to 19 (Re + Re 0.03 to 39.6 0.04 to 53 0.04 to 34.65 0.06 to 47 0.05 to 29.7 0.07 to 41 Co) Co 0.03 to 39.6 0.017 to 33 0.04 to 34.65 0.023 to 28 0.05 to 29.7 0.03 to 23-WC 40 to 95.5 40 to 98 45 to 93 46 to 96 50 to 90 51 to 94 WC + TiC T iC 1 to 48 0.3 to 23 2 to 45 0.6 to 21 3 to 42 0.9 to 19 122

1057D-6939-PF ^ 200535255 +TaC TaC 0.5 to 20 0.4 to 26 1 to 18 0.8 to 23 2 to 15 2 to 18 表27利用Co及鎳基超合金來黏結WC+TiC或WC+TaC或WC+TiC+TaC的組成材料組成範圍1 組成範圍2 組成範圍3 體積％重量％體積％重量％體積％重量％ (Co+ Co 0.03 to 39.6 0.018 to 33 0.04 to 34.65 0.024 to 29 0.05 to 29.7 0.03 to 25 NBSA) NBSA 0.03 to 39.6 0.015 to 29 0.04 to 34.65 0.02 to 26 0.05 to 29.7 0.03 to 23 - WC 40 to 96 58 to 98 43 to 94.5 6! to 97 45 to 93 64 to 96.7 WC+TiC TiC 1 to 48 0.3 to 24 1.5 to 45 0.5 to 22 2 to 42 0.7 to 21 (Co+ Co 0.03 to 39.6 0.018 to 28 0.04 to 34.65 0.024 to 24 0.05 to 29.7 0.03 to 20 NBSA) NBSA 0.03 to 39.6 0.015 to 25 0.04 to 34.65 0.02 to 22 0.05 to 29.7 0.025 to 18 - WC 50 to 96.5 61 to 98 55 to 95 65 to 97 60 to 93 69 to 95 WC+TaC TaC 0.5 to 22 0.5 to 24 1 to 20 1 to 21.5 2 to 18 2 to 19 (Co+ Co 0.03 to 39.6 0.018 to 33 0.04 to 34.65 0.024 to 28 0.05 to 29.7 0.03 to 23 NBSA) NBSA 0.03 to 39.6 0.015 to 30 0.04 to 34.65 0.02 to 25 0.05 to 29.7 0.026 to 21 - WC 40 to 95.5 57 to 98 45 to 93 62 to 96 50 to 90 67 to 94 WC+TiC TiC 1 to 48 0.4 to 23 2 to 45 0.7 to 21 3 to 42 1 to 19 +TaC TaC 0.5 to 20 0.6 to 26 ltol8 1 to 23 2 to 15 2 to 181057D-6939-PF ^ 200535255 + TaC TaC 0.5 to 20 0.4 to 26 1 to 18 0.8 to 23 2 to 15 2 to 18 Table 27 Bonding WC + TiC or WC + TaC or WC + TiC using Co and nickel-based superalloy + TaC composition material composition range 1 composition range 2 composition range 3 vol% wt% vol% wt% vol% wt (Co + Co 0.03 to 39.6 0.018 to 33 0.04 to 34.65 0.024 to 29 0.05 to 29.7 0.03 to 25 NBSA) NBSA 0.03 to 39.6 0.015 to 29 0.04 to 34.65 0.02 to 26 0.05 to 29.7 0.03 to 23-WC 40 to 96 58 to 98 43 to 94.5 6! To 97 45 to 93 64 to 96.7 WC + TiC TiC 1 to 48 0.3 to 24 1.5 to 45 0.5 to 22 2 to 42 0.7 to 21 (Co + Co 0.03 to 39.6 0.018 to 28 0.04 to 34.65 0.024 to 24 0.05 to 29.7 0.03 to 20 NBSA) NBSA 0.03 to 39.6 0.015 to 25 0.04 to 34.65 0.02 to 22 0.05 to 29.7 0.025 to 18-WC 50 to 96.5 61 to 98 55 to 95 65 to 97 60 to 93 69 to 95 WC + TaC TaC 0.5 to 22 0.5 to 24 1 to 20 1 to 21.5 2 to 18 2 to 19 (Co + Co 0.03 to 39.6 0.018 to 33 0.04 to 34.65 0.024 to 28 0.05 to 29.7 0.03 to 23 NBSA) NBSA 0.03 to 39.6 0.015 to 3 0 0.04 to 34.65 0.02 to 25 0.05 to 29.7 0.026 to 21-WC 40 to 95.5 57 to 98 45 to 93 62 to 96 50 to 90 67 to 94 WC + TiC TiC 1 to 48 0.4 to 23 2 to 45 0.7 to 21 3 to 42 1 to 19 + TaC TaC 0.5 to 20 0.6 to 26 ltol8 1 to 23 2 to 15 2 to 18

表28 利用Re、鎳基超合金及Co來黏結WC+TiC或WC+TaC或WC+TiC+TaC的組成，其中黏結劑組成比例範圍由〇.5%Re+99.5%鎳基超合金至99.5%Re+0.5%鎳基超合金至0.5 %Re+0.5%鎳基超合金+99%Co 材料組成範圍1 組成範圍2 組成範圍3 體積％重量％體積％重量％ mm% 重量％ (Re+Co Re 0.015 to 39.8 0.02 to 54 0.02 to 34.8 0.027 to 48 0.025 to 29.9 0.035 to 43 NBSA) NBSA 0.015 to 39.8 0.008 to 29 0.02 to 34.8 0.01 to 26 0.025 to 29.9 0.13 to 24 Co 0 to 39.6 0 to 32 0 to 34.7 Oto 29 0 to 29.8 0 to 26 - WC 40 to 96 40 to 98 43 to 94.5 44 to 97 45 to 93 48 to 96 WC+TiC TiC 1 to 48 0.3 to 24 1.5 to 45 0.5 to 22 2 to 42 0.6 to 21 (Re+Co Re 0.015 to 39.8 0.02 to 47 0.02 to 34.8 0.027 to 42 0.025 to 29.9 0.034 to 37 +NBSA) NBSA 0.015 to 39.8 0.008 to 26 0.02 to 34.8 0.01 to 22 0.025 to 29.9 0.13 to 18 - Co 0 to 39.6 Oto 28 0 to 34.7 Oto 24 0 to 29.8 Oto 20 WC 50 to 96.5 45 to 98 55 to 95 50 to 97 60 to 93 55 to 95 WC+TaC TaC 0.5 to 22 0.5 to 24 1 to 20 0.9 to 21 2 to 18 1.8tol9 (Re+ Re 0.015 to 39.8 0.02 to 65 0.02 to 34.8 0.027 to 58 0.025 to 29.9 0.034 to 51 NBSA NBSA 0.015 to 39.8 0.008 to41 0.02 to 34.8 0.01 to 34 0.025 to 29.9 0.13 to 28 +Co) Co 0 to 39.6 0 to 44 0 to 34.7 Oto 37 0 to 29.8 Oto 31 - WC 35 to 85 35 to 93 40 to 80 41 to 88 40 to 75 47 to83 WC+TiC TiC 1 to 50 0.3 to 25 2 to 45 0.6 to 22 3 to 40 0.9 to 18 123Table 28 Composition of WC + TiC or WC + TaC or WC + TiC + TaC using Re, nickel-based superalloy, and Co to bond the composition ratio of the binder from 0.5% Re + 99.5% nickel-based superalloy to 99.5 % Re + 0.5% nickel-based superalloy to 0.5% Re + 0.5% nickel-based superalloy + 99% Co Material composition range 1 composition range 2 composition range 3 vol% wt% vol% wt% mm% wt% (Re + Co Re 0.015 to 39.8 0.02 to 54 0.02 to 34.8 0.027 to 48 0.025 to 29.9 0.035 to 43 NBSA) NBSA 0.015 to 39.8 0.008 to 29 0.02 to 34.8 0.01 to 26 0.025 to 29.9 0.13 to 24 Co 0 to 39.6 0 to 32 0 to 34.7 Oto 29 0 to 29.8 0 to 26-WC 40 to 96 40 to 98 43 to 94.5 44 to 97 45 to 93 48 to 96 WC + TiC TiC 1 to 48 0.3 to 24 1.5 to 45 0.5 to 22 2 to 42 0.6 to 21 (Re + Co Re 0.015 to 39.8 0.02 to 47 0.02 to 34.8 0.027 to 42 0.025 to 29.9 0.034 to 37 + NBSA) NBSA 0.015 to 39.8 0.008 to 26 0.02 to 34.8 0.01 to 22 0.025 to 29.9 0.13 to 18-Co 0 to 39.6 Oto 28 0 to 34.7 Oto 24 0 to 29.8 Oto 20 WC 50 to 96.5 45 to 98 55 to 95 50 to 97 60 to 93 55 to 95 WC + TaC TaC 0.5 to 22 0.5 to 24 1 to 20 0.9 to 21 2 to 18 1.8tol9 (Re + Re 0.015 to 39.8 0.02 to 65 0.02 to 34.8 0.027 to 58 0.025 to 29.9 0.034 to 51 NBSA NBSA 0.015 to 39.8 0.008 to 41 0.02 to 34.8 0.01 to 34 0.025 to 29.9 0.13 to 28 + Co) Co 0 to 39.6 0 to 44 0 to 34.7 Oto 37 0 to 29.8 Oto 31-WC 35 to 85 35 to 93 40 to 80 41 to 88 40 to 75 47 to 83 WC + TiC TiC 1 to 50 0.3 to 25 2 to 45 0.6 to 22 3 to 40 0.9 to 18 123

1057D-6939-PF 200535255 +TaC TaC 0.5 to 25 0.4 to 26 1 to 22 0.8 to 24 2 to 20 1.6 to 21 | 表29額外材料及其組成批號組成重量％ Re R95 Co U700 U720 Ni wc Tie TaC VC M02C TiN P80 0 0 14.28 74.15 5.835 5.733 P81 0.736 0 13.904 73.84 5.811 5.709 P82 0.707 6.026 7.3694 74.31 5.847 5.744 P83 0.679 12.82 0 74.83 5.889 5.785 P84 1.45 5.903 7.1237 73.98 5.822 5.719 P85 3.06 5.532 6.7027 73.27 5.766 5.665 P86 1.45 5.903 7.1237 36.99 5.822 5.719 P87 1.063 4.126 5.4174 78.14 5.676 5.576 P88 1.861 7.57 9.1372 69.59 5.974 5.869 P89 1.368 5.572 6.7242 80.31 3.004 3.023 P99 0 0 5.5 15 29 10 9.5 20 P100 4.8 4.65 14.5 28.1 9.7 9.5 19.4 P101 4.8 4.65 14.5 28.1 9.7 9.5 19.4 P102 4.8 10 14.5 28.1 9.7 9.5 19.4 P103 9.6 20 11.25 21.65 7.5 7.1 14.9 P104 7.2 15 12.8 25 8.6 8.1 17.3 P105 15 7.5 13.6 26.35 9.05 8.9 18.1 P106 14.49 0 0 74.415 5.092 6.003 P107 15.101 0 0 66.875 7.076 10.95 P108 11.796 0.7485 0.437 75.727 5.182 6.109 P109 12.303 0.7807 0.456 68.105 7.206 11.15 P110 9.5724 1.4017 0.761 76.812 5.256 6.196 Pill 9.9896 1.4628 0.794 69.124 7.314 11.32 P112 6.9929 2.1369 1.16 78.07 5.342 6.298 P113 14.131 4.3182 2.343 67.447 5.398 6.363 P114 21.418 6.545 3.552 56.602 5.454 6.43 P115 3.8745 3.0258 1.642 79.591 5.446 6.421 P116 7.988 6.2383 3.385 70.155 5.614 6.619 P117 12.363 9.6552 5.24 60.119 5.793 6.829 P118 1.8824 3.5833 1.961 80.561 5.513 6.499 P119 2.8849 5.4917 3.006 76.345 5.632 6.64 P120 5.0264 9.5681 5.237 67.339 5.888 6.941 P121 13.157 0.5708 0 75.078 5.138 6.057 P122 5.294 2.0672 0 81.057 5.316 6.2661057D-6939-PF 200535255 + TaC TaC 0.5 to 25 0.4 to 26 1 to 22 0.8 to 24 2 to 20 1.6 to 21 | Table 29 Additional materials and their composition Batch number Composition weight% Re R95 Co U700 U720 Ni wc Tie TaC VC M02C TiN P80 0 0 14.28 74.15 5.835 5.733 P81 0.736 0 13.904 73.84 5.811 5.709 P82 0.707 6.026 7.3694 74.31 5.847 5.744 P83 0.679 12.82 0 74.83 5.889 5.785 P84 1.45 5.903 7.1237 73.98 5.822 5.719 P85 3.06 5.532 6.7027 73.27 5.766 5.665 5.86 P237 1.45 5.99 5.99 P87 1.063 4.126 5.4174 78.14 5.676 5.576 P88 1.861 7.57 9.1372 69.59 5.974 5.869 P89 1.368 5.572 6.7242 80.31 3.004 3.023 P99 0 0 5.5 15 29 10 9.5 20 P100 4.8 4.65 14.5 28.1 9.7 9.5 19.4 P101 4.8 4.65 14.5 28.1 9.7 9.5 19.4 P102 4.8 10 28.1 9.7 9.5 19.4 P103 9.6 20 11.25 21.65 7.5 7.1 14.9 P104 7.2 15 12.8 25 8.6 8.1 17.3 P105 15 7.5 13.6 26.35 9.05 8.9 18.1 P106 14.49 0 0 74.415 5.092 6.003 P107 15.101 0 0 66.8 75 7.076 10.95 P108 11.796 0.7485 0.437 75.727 5.182 6.109 P109 12.303 0.7807 0.456 68.105 7.206 11.15 P110 9.5724 1.4017 0.761 76.812 5.256 6.196 Pill 9.9896 1.4628 0.794 69.124 7.314 11.32 P112 6.9929 2.1369 1.16 78.07 5.342 6.298 P113 14.131 4.3182 2.3.5 67.447 5.398 6.363 5.398 6.363 5.114 6.363 5.418 6.363 5.114 6.363 5.114 6.363 6.654 6.363 5.654 6.63 5.447 6.398 5.654 6.63 6.447 5.398 6.654 6.363 6.144 5.639 6.65 6.65 6.65 3.11 3.10 3.10 6.89 5.89 6.38 5.38 3.11 6.36 5.454 6.43 P115 3.8745 3.0258 1.642 79.591 5.446 6.421 P116 7.988 6.2383 3.385 70.155 5.614 6.619 P117 12.363 9.6552 5.24 60.119 5.793 6.829 P118 1.8824 3.5833 1.961 80.561 5.513 6.499 P119 2.8849 5.4917 3.006 76.345 5.632 6.64 P120 5.0264 9.5681 5.138 67.339 67.339 67.339 6.878 6.057 P122 5.294 2.0672 0 81.057 5.316 6.266

124124

1057D-6939-PF 2005352551057D-6939-PF 200535255

重量％ Re R95 Co U700 U720 Ni WC TiC TaC VC Mo2C TiN P123 19.908 5.9798 1.976 60.41 5.382 6.344 P124 20.68 9.9386 2.736 54.464 5.59 6.59 P125 1.5492 3.0246 0.833 82.731 5.444 6.418 P126 8.4621 13.217 3.639 61.723 5.948 7.011 P127 12.191 13.964 3.844 61.702 3.808 4.49 P128 11.906 0.5166 0 86.99 0.604 P129 1.6752 2.0169 1.9524 93.77 0.599 P130 11.97 8.0334 8.085 71.33 0.6 P131 1.4372 3.8162 3.7765 90.39 0.596 P132 6.6223 1.3705 1.3191 90.1 0.605 P133 5.505 1.7196 1.6331 90.55 0.609 P134 11.43 5.0212 4.8443 78.11 0.613 P135 1.644 2.3344 2.571 79.98 3.151 10.32 P136 3.6545 5.1371 5.657 73.439 0 12.11 P137 4.4642 6.3916 7.039 69.776 0 12.33 P138 4.899 6.5757 7.241 69.279 1.435 10.57 P139 6.5381 7.902 8.702 64.651 1.459 10.75 P140 3.0601 5.5324 6.703 73.274 5.766 5.665 P141 2.9261 5.2902 6.409 71.233 3.308 10.83 P142 5.0649 6.1371 7.419 67.113 3.337 10.93 A 13.853 0.2847 0.314 74.887 5.125 5.538 B 2.7327 5.0305 0 81.358 5.488 5.391 C 3.0601 5.5324 6.703 73.274 5.766 5.665 D 1.8803 3.5793 1.988 81.637 5.507 5.41 E 7.7737 9.4819 0 71.578 5.633 5.534 P144 0.6786 12.821 0 74.827 5.889 5.785 P145 0.6437 5.663 0 80.041 3.194 10.46 P146 1.8837 5.3941 0 81.786 5.517 5.42 P147 2.3479 5.1953 0 81.552 5.501 5.404 P148 1.5479 8.462 0 76.038 3.264 10.69 P149 1.6376 15.347 0 68.255 3.453 11.31 J 25.75 2.5 14.5 24.1 8.5 8 16.65 K 11.671 0.4143 0.3935 0 0 86.92 0.605 L 2.6826 5.5683 0 0 0 91.32 0.43 M 3.5669 0 14.235 0 0 81.75 0.452 N 0 7.5039 0 0 0 92.06 0.44 0 12.515 0 0 0 0.2541 86.63 0.601 P 1.7969 0 0 6.9309 90.68 0.597 Q 0 0 0 7.4214 91.98 0.602Weight% Re R95 Co U700 U720 Ni WC TiC TaC VC Mo2C TiN P123 19.908 5.9798 1.976 60.41 5.382 6.344 P124 20.68 9.9386 2.736 54.464 5.59 6.59 P125 1.5492 3.0246 0.833 82.731 5.444 6.418 P126 8.4621 13.217 3.639 61.128 5.948 7.011 P127 12.191 3.808 3.844 61 11.906 0.5166 0 86.99 0.604 P129 1.6752 2.0169 1.9524 93.77 0.599 P130 11.97 8.0334 8.085 71.33 0.6 P131 1.4372 3.8162 3.7765 90.39 0.596 P132 6.6223 1.3705 1.3191 90.1 0.605 P133 5.505 1.7196 1.6331 90.55 0.609 P134 11.43 5.0212 4.8443 78.11 3.6151 2.136 P135 1.644 1.136 5.1371 5.657 73.439 0 12.11 P137 4.4642 6.3916 7.039 69.776 0 12.33 P138 4.899 6.5757 7.241 69.279 1.435 10.57 P139 6.5381 7.902 8.702 64.651 1.459 10.75 P140 3.0601 5.5324 6.703 73.274 5.766 5.665 P141 2.9261 5.2902 6.409 71.233 3.308 10.83 P142 67.113 6.419 7.6.1 7. .337 10.93 A 13.853 0.2847 0.314 74.887 5.125 5.538 B 2.7327 5.0305 0 81.358 5.488 5.391 C 3.0601 5.5324 6.703 73.274 5.766 5.665 D 1.8803 3.5793 1.988 81.637 5.507 5.41 E 7.7737 9.4819 0 71.578 5.633 5.534 P144 0.6786 12.821 0 74.827 5.889 5.785 P145 0.6041 5.663 0 3.194 10.46 P146 1.8837 5.3941 0 81.786 5.517 5.42 P147 2.3479 5.1953 0 81.552 5.501 5.404 P148 1.5479 8.462 0 76.038 3.264 10.69 P149 1.6376 15.347 0 68.255 3.453 11.31 J 25.75 2.5 14.5 24.1 8.5 8 16.65 K 11.671 0.4143 0.3935 0 0 86.92 0.605 L 2.6826 5.5683 0 0 0 91.32 0.43 M 3.5669 0 14.235 0 0 81.75 0.452 N 0 7.5039 0 0 0 92.06 0.44 0 12.515 0 0 0.2541 86.63 0.601 P 1.7969 0 0 6.9309 90.68 0.597 Q 0 0 7.4214 91.98 0.602

1057D-6939-PF 125 ^ 200535255 s 8.371 0 0 5.3814 85.67 0.579 τ 1.6967 0 4.681 0 92.98 0.645 υ 3.9002 0 0 3.8684 91.6 0.636 Ρ150 0 0 14.847 84.68 0.469 Ρ151 0 3.2554 11.851 84.38 0.51 重量％ Re R95 Co U700 U720 Ni WC TiC TaC VC Μ〇2〇 TiN Ρ152 1.5219 3.225 11.153 83.59 0.505 Ρ153 12.451 1.2899 4.6957 81.09 0.478 Ρ154 2.6486 2.9933 7.6052 54.464 0.509 Ρ155 0 0 11.55 82.731 0.414 Ρ156 1.1019 3.5804 6.2338 61.723 0.671 Ρ157 0 3.761 6.5607 86.24 0.675 Ρ158 0 0 9.9898 88.04 0.512 Ρ159 0.9437 3.0766 5.5161 88.41 0.502 Ρ160 0 3.0946 5.9144 89 0.505 Ρ161 0 0 8.7552 89.5 0.506 Ρ162 2.967 5.6892 0.6379 0.654 89.817 0.2346 Ρ163 0.581 8.1942 0.9297 0.8972 89.156 0.2413 Ρ164 2.16 7.569 0.8669 0.8333 88.331 0.2391 Ρ165 2.801 6.7279 1.976 2.026 86.226 0.2422 Ρ166 2.797 8.3834 1.2603 1.2361 86.082 0.2418 Ρ167 2.789 11.13 0 0 85.84 0.24111057D-6939-PF 125 ^ 200535255 s 8.371 0 0 5.3814 85.67 0.579 τ 1.6967 0 4.681 0 92.98 0.645 υ 3.9002 0 0 3.8684 91.6 0.636 P150 0 0 14.847 84.68 0.469 P151 0 3.2554 11.851 84.38 0.51 wt% Re R95 Co U700 U720 Ni WC TiC TaC VC Mo2〇TiN P152 1.5219 3.225 11.153 83.59 0.505 P153 12.451 1.2899 4.6957 81.09 0.478 P154 2.6486 2.9933 7.6052 54.464 0.509 P155 0 0 11.55 82.731 0.414 P156 1.1019 3.5804 6.2338 61.723 0.671 P157 0 3.761 6.59.9 86158.86 6.548 P159 0.9437 3.0766 5.5161 88.41 0.502 P160 0 3.0946 5.9144 89 0.505 P161 0 0 8.7552 89.5 0.506 P162 2.967 5.6892 0.6379 0.654 89.817 0.2346 P163 0.581 8.1942 0.9297 0.8972 89.156 0.2413 P164 2.16 7.569 0.8669 0.8333 88.331 0.2391 P165 2.801 2.6 2.786 2.6279 1.622 0.626 1.834 6.226 1.2361 86.082 0.2418 P167 2.789 11.13 0 0 85.84 0.2411

3 0-41列出金屬陶瓷組成物的組成範圍。 • 表 30 利用 Re 爲黏結劑來黏結 TiC+Mo2C 或 TiN+Mo2C 或 TiC+TiN+Mo2C 或 TiC+TiN+Mo2C +WC+TaC+VC+Cr2C3 林料組成範圍1 組成範圍2 組成範圍3 體積％重量％體積％重量％ mm % 重量％ Re Re 3 to 30 9.5 to 65 4 to 27 13 to 60 5 to 25 15 to 58 - TiC 43 to 97 19 to 88 48 to 92 23 to 79 51 to 90 25 to 75 TiC+Mo2C Mo2C Oto 27 0 to 38 Oto 26 Oto 36 Oto 24 Oto 33 Re Re 3 to 30 9 to 63 4 to 27 12 to 58 5 to 25 15 to 56 - TiN 43 to 97 21 to 89 48 to 92 25 to 81 51 to 90 27 to 76 TiN+Mo2C Mo2C Oto 27 0 to 36 Oto 26 Oto 34 Oto 24 Oto 31 Re Re 3 to 30 9 to 64 4 to 27 12 to 60 5 to 25 15 to 58 - TiC 0.3 to 93.7 0.2 to 84 0.4 to 91.6 0.3 to 79 0.5 to 89.5 0.35 to 74 TiC+TiN TiN 0.3 to 93.7 0.3 to 85 0.4 to 91.6 0.4 to 80 0.5 to 89.5 0.5 to 76 +M02C Mo2C Oto 27 0 to 36 Oto 26 Oto 34 Oto 24 Oto 31 1263 0-41 lists the composition range of the cermet composition. • Table 30 Use Re as a binder to bond TiC + Mo2C or TiN + Mo2C or TiC + TiN + Mo2C or TiC + TiN + Mo2C + WC + TaC + VC + Cr2C3 Forest material composition range 1 composition range 2 composition range 3 vol% % By weight% by weight mm% by weight Re Re 3 to 30 9.5 to 65 4 to 27 13 to 60 5 to 25 15 to 58-TiC 43 to 97 19 to 88 48 to 92 23 to 79 51 to 90 25 to 75 TiC + Mo2C Mo2C Oto 27 0 to 38 Oto 26 Oto 36 Oto 24 Oto 33 Re Re 3 to 30 9 to 63 4 to 27 12 to 58 5 to 25 15 to 56-TiN 43 to 97 21 to 89 48 to 92 25 to 81 51 to 90 27 to 76 TiN + Mo2C Mo2C Oto 27 0 to 36 Oto 26 Oto 34 Oto 24 Oto 31 Re Re 3 to 30 9 to 64 4 to 27 12 to 60 5 to 25 15 to 58-TiC 0.3 to 93.7 0.2 to 84 0.4 to 91.6 0.3 to 79 0.5 to 89.5 0.35 to 74 TiC + TiN TiN 0.3 to 93.7 0.3 to 85 0.4 to 91.6 0.4 to 80 0.5 to 89.5 0.5 to 76 + M02C Mo2C Oto 27 0 to 36 Oto 26 Oto 34 Oto 24 Oto 31 126

1057D-6939-PF 2005352551057D-6939-PF 200535255

Re Re 3 to 30 6 to 65 4 to 27 9 to 61 5 to 25 11 to 65 TiC 0.3 to 93.5 0.1 to 83 0.4 to 91.3 0.2 to 78 0.5 to 89.1 0.3 to 74 - TiN 0.3 to 93.5 0.15 to 85 0.4 to 91.3 0.2 to 80 0.5 to 89.1 0.3 to 76 Mo2C 0 to 28 Oto 25 0 to 26 Oto 25 Oto 24 Oto 24 TiC+TiN WC 0.1 to 20 0.15 to 39 0.15 to 15 0.25 to 32 0.2 to 12 0.35 to 28 +Mo2C TaC 0.1 to 15 0.15 to 30 0.15 to 12 0.25 to 25 0.2 to 10 0.3 to 22 +WC+TaC VC Oto 15 Oto 11 Oto 12 Oto 10 Oto 10 0 to 9 +VC+Cr2C3 Cr2C3 Oto 15 Oto 16 Oto 12 Oto 14 Oto 10 0tol2 表31利用鎳基超合金爲黏結劑來黏結TiC+Mo2C或TiN+Mo2C或TiC+TiN+Mo2C或TiC+TiN +Mo2C+WC+TaC+VC+Cr2C3Re Re 3 to 30 6 to 65 4 to 27 9 to 61 5 to 25 11 to 65 TiC 0.3 to 93.5 0.1 to 83 0.4 to 91.3 0.2 to 78 0.5 to 89.1 0.3 to 74-TiN 0.3 to 93.5 0.15 to 85 0.4 to 91.3 0.2 to 80 0.5 to 89.1 0.3 to 76 Mo2C 0 to 28 Oto 25 0 to 26 Oto 25 Oto 24 Oto 24 TiC + TiN WC 0.1 to 20 0.15 to 39 0.15 to 15 0.25 to 32 0.2 to 12 0.35 to 28 + Mo2C TaC 0.1 to 15 0.15 to 30 0.15 to 12 0.25 to 25 0.2 to 10 0.3 to 22 + WC + TaC VC Oto 15 Oto 11 Oto 12 Oto 10 Oto 10 0 to 9 + VC + Cr2C3 Cr2C3 Oto 15 Oto 16 Oto 12 Oto 14 Oto 10 0tol2 Table 31 Adhesive TiC + Mo2C or TiN + Mo2C or TiC + TiN + Mo2C or TiC + TiN + Mo2C + WC + TaC + VC + Cr2C3

材料組成範圍1 組成範圍2 組成範圍3 mm% 重量％體積％重量％體積％重量％ NBSA NBSA 3 to 30 4 to 41 4 to 27 5 to 37 5 to 25 6 to 34 - TiC 43 to 94 30 to 90 48 to 92 35 to 87 51 to 90 37 to 84 TiC+Mo2C Mo2C 3 to 27 4 to 40 4 to 26 6 to 39 5 to 24 8 to 36 NBSA NBSA 3 to 30 4 to 38 4 to 27 5 to 34 5 to 25 6 to 32 - TiN 43 to 94 32 to 91 48 to 92 37 to 88 51 to 90 40 to 85 TiN+Mo2C Mo2C 3 to 27 4 to 38 4 to 26 6 to 37 5 to 24 7 to 34 NBSA NBSA 3 to 30 4 to 40 4 to 27 5 to 36 5 to 25 6 to 34 - TiC 0.3 to 93.7 0.2 to 90 0.4 to 91.6 0.3 to 86 0.5 to 89.5 0.4 to 83 TiC+TiN TiN 0.3 to 93.7 0.3 to 91 0.4 to 91.6 0.4 to 88 0.5 to 89.5 0.5 to 85 +M〇2〇 Mo2C 3 to 27 4 to 38 4 to 26 6 to 37 5 to 24 8 to 34 NBSA NBSA 3 to 30 2 to 40 4 to 27 4 to 36 5 to 25 5 to 34 TiC 0.3 to 93.3 0.15 to 90 0.4 to 91.3 0.2 to 86 0.5 to 89.3 0.3 to 83 - TiN 0.3 to 93.3 0.25 to 90 0.4 to 91.3 0.35 to 87 0.5 to 89.3 0.45 to 84 Mo2C 3 to 27 4 to 25 4 to 26 6 to 26 5 to 24 8 to 25.5 TiC+TiN WC 0.1 to 20 0.25 to 42 0.15 to 15 0.4 to 34 0.2 to 12 0.5 to 29 +M02C TaC 0.1 to 15 0.25 to 36 0.15 to 12 0.4 to 30 0.2 to 10 0.5 to 26 +WC+TaC VC Oto 15 Oto 14 Oto 12 Oto 12 Oto 10 Oto 10 +VC+Cr2C3 Cr2C3 Oto 15 Oto 18 Oto 12 Oto 15 Oto 10 0tol3 表32利用Re及鎳基超合金爲黏結劑來黏結TiC+M〇2C或TiN+Mo2C或TiC+TiN+Mo2C或 TiC+TiN+Mo2C+WC+TaC+VC+Cr2C3 材料組成範圍1 組成範圍2 組成範圍3 體積0/〇重量％體積％重量％體積％重量〇/〇 (Re+NBSA) Re 0.03 to 29.7 0.1 to 64 0.04 to 26.73 0.13 to 60 0.05 to 24.75 0.16 to 57 - NBSA 0.03 to 29.7 0.03 to 40 0.04 to 26.73 0.05 to 36 0.05 to 24.75 0.06 to 34 TiC+TiN TiC 0 to 94 Oto 90 Oto 92 Oto 87 0 to 90 0 to 84 127Material composition range 1 Composition range 2 Composition range 3 mm% wt% vol% wt% vol% wt% NBSA NBSA 3 to 30 4 to 41 4 to 27 5 to 37 5 to 25 6 to 34-TiC 43 to 94 30 to 90 48 to 92 35 to 87 51 to 90 37 to 84 TiC + Mo2C Mo2C 3 to 27 4 to 40 4 to 26 6 to 39 5 to 24 8 to 36 NBSA NBSA 3 to 30 4 to 38 4 to 27 5 to 34 5 to 25 6 to 32-TiN 43 to 94 32 to 91 48 to 92 37 to 88 51 to 90 40 to 85 TiN + Mo2C Mo2C 3 to 27 4 to 38 4 to 26 6 to 37 5 to 24 7 to 34 NBSA NBSA 3 to 30 4 to 40 4 to 27 5 to 36 5 to 25 6 to 34-TiC 0.3 to 93.7 0.2 to 90 0.4 to 91.6 0.3 to 86 0.5 to 89.5 0.4 to 83 TiC + TiN TiN 0.3 to 93.7 0.3 to 91 0.4 to 91.6 0.4 to 88 0.5 to 89.5 0.5 to 85 + M〇2〇Mo2C 3 to 27 4 to 38 4 to 26 6 to 37 5 to 24 8 to 34 NBSA NBSA 3 to 30 2 to 40 4 to 27 4 to 36 5 to 25 5 to 34 TiC 0.3 to 93.3 0.15 to 90 0.4 to 91.3 0.2 to 86 0.5 to 89.3 0.3 to 83-TiN 0.3 to 93.3 0.25 to 90 0.4 to 91.3 0.35 to 87 0.5 to 89.3 0.45 to 84 Mo2C 3 to 27 4 to 25 4 to 26 6 to 26 5 to 24 8 to 25.5 TiC + TiN WC 0.1 to 20 0.25 to 42 0.15 to 15 0.4 to 34 0.2 to 12 0.5 to 29 + M02C TaC 0.1 to 15 0.25 to 36 0.15 to 12 0.4 to 30 0.2 to 10 0.5 to 26 + WC + TaC VC Oto 15 Oto 14 Oto 12 Oto 12 Oto 10 Oto 10 + VC + Cr2C3 Cr2C3 Oto 15 Oto 18 Oto 12 Oto 15 Oto 10 0tol3 TiN + Mo2C or TiC + TiN + Mo2C or TiC + TiN + Mo2C + WC + TaC + VC + Cr2C3 material composition range 1 composition range 2 composition range 3 volume 0 / 〇wt% vol% wt% vol% wt 0 / 〇 ( Re + NBSA) Re 0.03 to 29.7 0.1 to 64 0.04 to 26.73 0.13 to 60 0.05 to 24.75 0.16 to 57-NBSA 0.03 to 29.7 0.03 to 40 0.04 to 26.73 0.05 to 36 0.05 to 24.75 0.06 to 34 TiC + TiN TiC 0 to 94 Oto 90 Oto 92 Oto 87 0 to 90 0 to 84 127

1057D-6939-PF 200535255 +M02C TiN 0 to 94 Oto 91 Oto 92 0 to 88 0 to 90 0 to 85 Mo2C 3 to 27 3 to 38 4 to 26 4 to 37 5 to 24 5 to 34 (Re+NBSA) Re 0.03 to 29.7 0.06 to 64 0.04 to 26.73 0.1 to 60 0.05 to 24.75 0.12 to 57 - NBSA 0.03 to 29.7 0.02 to 40 0.04 to 26.73 0.03 to 36 0.05 to 24.75 0.04 to 34 TiC+TiN TiC 0.3 to 93.5 0.15 to 89 .40 to 91.3 0.2 to 86 0.5 to 89.1 0.3 to 83 +M02C TiN 0.3 to 93.5 0.15 to 90 .40 to 91.3 0.2 to 87 0.5 to 89.1 0.3 to 84 +WC+TaC Mo2C 3 to 28 3 to 26 4 to 26 4 to 26 5 to 24 5 to 25.5 +VC+Cr2C3 WC 0.1 to 20 0.15 to 42 0.15 to 15 0.25 to 35 0.2 to 12 0.35 to 29 TaC 0.1 to 15 0.15 to 33 0.15 to 12 0.25 to 28 0.2 to 10 0.3 to 24 VC Oto 15 Oto 16 Oto 12 Oto 13 Oto 10 Oto 11 Cr2C3 Oto 15 Oto 18 Oto 12 Oto 15 Oto 10 Oto 13 表33利用Re及Ni爲黏結劑來黏結TiC+Mo2C或TiN+Mo2C或TiC+TiN+Mo2C或 TiC+TiN+Mo2C+WC+TaC+VC+Cr2C3 材料組成範圍1 組成範圍2 組成範圍3 體積％重量0/〇體積％重量％體積0/〇重量％ (Re+Ni) Re 0.03 to 29.7 0.1 to 64 0.04 to 26.73 0.13 to 60 0.05 to 24.75 0.16 to 57 - Ni 0.03 to 29.7 0.04 to 42 0.04 to 26.73 0.05 to 38 0.05 to 24.75 0.06 to 36 TiC+TiN TiC 0 to 94 Oto 90 Oto 92 Oto 87 0 to 90 Oto 83 +M02C TiN 0 to 94 0 to 91 Oto 92 0 to 88 0 to 90 0 to 85 Mo2C 3 to 27 3 to 38 4 to 26 4 to 37 5 to 24 5 to 34 (Re+Ni) Re 0.03 to 29.7 0.06 to 64 0.04 to 26.73 0.1 to 60 0.05 to 24.75 0.12 to 57 - Ni 0.03 to 29.7 0.03 to 42 0.04 to 26.73 0.04 to 39 0.05 to 24.75 0.05 to 36 TiC+TiN TiC 0.3 to 93.5 0.15 to 89 .40 to 91.3 0.2 to 85 0.5 to 89.1 0.3 to 82 +Mo2C TiN 0.3 to 93.5 0.15 to 90 .40 to 91.3 0.2 to 87 0.5 to 89.1 0.3 to 83 +WC+TaC Mo2C 3 to 28 3 to 26 4 to 26 4 to 26 5 to 24 5 to 25.5 +VC+Cr2C3 WC 0.1 to 20 0.15 to 42 0.15 to 15 0.25 to 35 0.2 to 12 0.35 to 29 TaC 0.1 to 15 0.15 to 33 0.15 to 12 0.25 to 28 0.2 to 10 0.3 to 24 VC Oto 15 Oto 16 Oto 12 Oto 13 Oto 10 Oto 11 Cr2C3 Oto 15 Oto 18 Oto 12 Oto 15 Oto 10 0tol31057D-6939-PF 200535255 + M02C TiN 0 to 94 Oto 91 Oto 92 0 to 88 0 to 90 0 to 85 Mo2C 3 to 27 3 to 38 4 to 26 4 to 37 5 to 24 5 to 34 (Re + NBSA) Re 0.03 to 29.7 0.06 to 64 0.04 to 26.73 0.1 to 60 0.05 to 24.75 0.12 to 57-NBSA 0.03 to 29.7 0.02 to 40 0.04 to 26.73 0.03 to 36 0.05 to 24.75 0.04 to 34 TiC + TiN TiC 0.3 to 93.5 0.15 to 89 .40 to 91.3 0.2 to 86 0.5 to 89.1 0.3 to 83 + M02C TiN 0.3 to 93.5 0.15 to 90 .40 to 91.3 0.2 to 87 0.5 to 89.1 0.3 to 84 + WC + TaC Mo2C 3 to 28 3 to 26 4 to 26 4 to 26 5 to 24 5 to 25.5 + VC + Cr2C3 WC 0.1 to 20 0.15 to 42 0.15 to 15 0.25 to 35 0.2 to 12 0.35 to 29 TaC 0.1 to 15 0.15 to 33 0.15 to 12 0.25 to 28 0.2 to 10 0.3 to 24 VC Oto 15 Oto 16 Oto 12 Oto 13 Oto 10 Oto 11 Cr2C3 Oto 15 Oto 18 Oto 12 Oto 15 Oto 10 Oto 13 + TiN + Mo2C + WC + TaC + VC + Cr2C3 material composition range 1 composition range 2 composition range 3 vol.% Weight 0 / 〇vol.% Weight% vol.0 / 〇weight% (Re + Ni ) Re 0.03 to 29.7 0.1 to 64 0.04 to 26.73 0.13 to 60 0.05 to 24.75 0.16 to 57-Ni 0.03 to 29.7 0.04 to 42 0.04 to 26.73 0.05 to 38 0.05 to 24.75 0.06 to 36 TiC + TiN TiC 0 to 94 Oto 90 Oto 92 Oto 87 0 to 90 Oto 83 + M02C TiN 0 to 94 0 to 91 Oto 92 0 to 88 0 to 90 0 to 85 Mo2C 3 to 27 3 to 38 4 to 26 4 to 37 5 to 24 5 to 34 (Re + Ni) Re 0.03 to 29.7 0.06 to 64 0.04 to 26.73 0.1 to 60 0.05 to 24.75 0.12 to 57-Ni 0.03 to 29.7 0.03 to 42 0.04 to 26.73 0.04 to 39 0.05 to 24.75 0.05 to 36 TiC + TiN TiC 0.3 to 93.5 0.15 to 89 .40 to 91.3 0.2 to 85 0.5 to 89.1 0.3 to 82 + Mo2C TiN 0.3 to 93.5 0.15 to 90 .40 to 91.3 0.2 to 87 0.5 to 89.1 0.3 to 83 + WC + TaC Mo2C 3 to 28 3 to 26 4 to 26 4 to 26 5 to 24 5 to 25.5 + VC + Cr2C3 WC 0.1 to 20 0.15 to 42 0.15 to 15 0.25 to 35 0.2 to 12 0.35 to 29 TaC 0.1 to 15 0.15 to 33 0.15 to 12 0.25 to 28 0.2 to 10 0.3 to 24 VC Oto 15 Oto 16 Oto 12 Oto 13 Oto 10 Oto 11 Cr2C3 Oto 15 Oto 18 Oto 12 Oto 15 Oto 10 0tol3

表34利用Re及Co爲黏結劑來黏結TiC+Mo2C或TiN+Mo2C或TiC+TiN+Mo2C或TiC+TiN +Mo2C+WC+TaC+VC+Cr2C3 材料組成範圍1 組成範圍2 組成範圍3 體積0/〇重量％體積％重量0/〇體積〇/〇重量％ Re+Co Re 0.03 to 29.7 0.1 to 64 0.04 to 26.73 0.13 to 60 0.05 to 24.75 0.16 to 57 Co 0.03 to 29.7 0.04 to 43 0.04 to 26.73 0.05 to 39 0.05 to 24.75 0.06 to 36 - TiC 0 to 94 Oto 90 Oto 92 Oto 87 Oto 90 Oto 83 TiC+TiN TiN 0 to 94 Oto 91 Oto 92 0 to 88 0 to 90 0 to 85 +M02C Mo2C 3 to 27 3 to 38 4 to 26 4 to 37 5 to 24 5 to 34 128Table 34 Adhesive TiC + Mo2C or TiN + Mo2C or TiC + TiN + Mo2C or TiC + TiN + Mo2C + WC + TaC + VC + Cr2C3 using Re and Co as binders. Material composition range 1 composition range 2 composition range 3 volume 0 / 〇wt% vol% wt 0 / 〇vol 〇 / 〇wt% Re + Co Re 0.03 to 29.7 0.1 to 64 0.04 to 26.73 0.13 to 60 0.05 to 24.75 0.16 to 57 Co 0.03 to 29.7 0.04 to 43 0.04 to 26.73 0.05 to 39 0.05 to 24.75 0.06 to 36-TiC 0 to 94 Oto 90 Oto 92 Oto 87 Oto 90 Oto 83 TiC + TiN TiN 0 to 94 Oto 91 Oto 92 0 to 88 0 to 90 0 to 85 + M02C Mo2C 3 to 27 3 to 38 4 to 26 4 to 37 5 to 24 5 to 34 128

1057D-6939-PF .2005352551057D-6939-PF .200535255

Re+Co Re 0.03 to 29.7 0.06 to 64 0.04 to 26.73 0.1 to 60 0.05 to 24.75 0.12 to 57 Co 0.03 to 29.7 0.03 to 43 0.04 to 26.73 0.04 to 39 0.05 to 24.75 0.05 to 36 - TiC 0.3 to 93.5 0.15 to 89 .40 to 91.3 0.2 to 85 0.5 to 89.1 0.3 to 82 TiN 0.3 to 93.5 0.15 to 90 .40 to 91.3 0.2 to 87 0.5 to 89.1 0.3 to 83 TiC+TiN Mo2C 3 to 28 3 to 26 4 to 26 4 to 26 5 to 24 5 to 25.5 +Mo2C WC 0.1 to 20 0.15 to 42 0.15 to 15 0.25 to 34 0.2 to 12 0.35 to 29 +WC+TaC TaC 0.1 to 15 0.15 to 32 0.15 to 12 0.25 to 27 0.2 to 10 0.3 to 24 +VC+Cr2C3 VC Oto 15 Oto 16 Oto 12 Oto 13 Oto 10 Oto 11 Cr2C3 Oto 15 Oto 18 Oto 12 Oto 15 Oto 10 0tol3 表35利用鎳基超合金及Co爲黏結劑來黏結TiC+Mo2C或TiN+Mo2C或TiC+TiN+Mo2C或 TiC+TiN+Mo2C+WC+TaC+VC+Cr2C3Re + Co Re 0.03 to 29.7 0.06 to 64 0.04 to 26.73 0.1 to 60 0.05 to 24.75 0.12 to 57 Co 0.03 to 29.7 0.03 to 43 0.04 to 26.73 0.04 to 39 0.05 to 24.75 0.05 to 36-TiC 0.3 to 93.5 0.15 to 89. 40 to 91.3 0.2 to 85 0.5 to 89.1 0.3 to 82 TiN 0.3 to 93.5 0.15 to 90 .40 to 91.3 0.2 to 87 0.5 to 89.1 0.3 to 83 TiC + TiN Mo2C 3 to 28 3 to 26 4 to 26 4 to 26 5 to 24 5 to 25.5 + Mo2C WC 0.1 to 20 0.15 to 42 0.15 to 15 0.25 to 34 0.2 to 12 0.35 to 29 + WC + TaC TaC 0.1 to 15 0.15 to 32 0.15 to 12 0.25 to 27 0.2 to 10 0.3 to 24 + VC + Cr2C3 VC Oto 15 Oto 16 Oto 12 Oto 13 Oto 10 Oto 11 Cr2C3 Oto 15 Oto 18 Oto 12 Oto 15 Oto 10 0tol3 + TiN + Mo2C or TiC + TiN + Mo2C + WC + TaC + VC + Cr2C3

材料組成範圍1 組成範圍2 組成範圍3 體積％ mm% 體積0/〇重量％體積％重量％ (NBSA+Co) NBSA 0.03 to 29.7 0.04 to 40 0.04 to 26.73 0.05 to 37 0.05 to 24.75 0.06 to 34 - Co 0.03 to 29.7 0.04 to 43 0.04 to 26.73 0.06 to 39 0.05 to 24.75 0.07 to 37 TiC+TiN TiC 0 to 94 0 to 90 Oto 92 Oto 87 0 to 90 0 to 84 +M02C TiN 0 to 94 Oto 91 Oto 92 0 to 88 0 to 90 0 to 86 Mo2C 3 to 27 4 to 38 4 to 26 6 to 37 5 to 24 7 to 34 (NBSA+Co) NBSA 0.03 to 29.7 0.02 to 40 0.04 to 26.73 0.03 to 36 0.05 to 24.75 0.05 to 34 - Co 0.03 to 29.7 0.03 to 43 0.04 to 26.73 0.04 to 39 0.05 to 24.75 0.05 to 36 TiC+TiN TiC 0.3 to 93.5 0.15 to 89 .40 to 91.3 0.2 to 86 0.5 to 89.1 0.3 to 83 +Mo2C TiN 0.3 to 93.5 0.25 to 90 .40 to 91.3 0.35 to 87 0.5 to 89.1 0.45 to 84 +WC+TaC Mo2C 3 to 28 4 to 26 4 to 26 6 to 26 5 to 24 7 to 25.5 +VC+Cr2C3 WC 0.1 to 20 0.25 to 42 0.15 to 15 0.38 to 35 0.2 to 12 0.5 to 29 TaC 0.1 to 15 0.23 to 33 0.15 to 12 0.35 to 28 0.2 to 10 0.47 to 24 VC Oto 15 Oto 16 Oto 12 Oto 13 Oto 10 Oto 11 Cr2C3 Oto 15 Oto 18 Oto 12 Oto 15 Oto 10 0tol3 表36 36利用鎳基超合金及Ni爲黏結劑來黏結TiC+M〇2C或TiN+Mo2C或TiC+TiN+ Mo2C 或 TiC+TiN+Mo2C+WC+TaC+VC+Cr2C3 材料組成範圍1 組成範圍2 組成範圍3 體積％重量％體積％重量％體積％重量％ (NBSA+Ni) NBSA 0.03 to 29.7 0.04 to 40 0.04 to 26.73 0.05 to 37 0.05 to 24.75 0.06 to 34 - Ni 0.03 to 29.7 0.04 to 43 0.04 to 26.73 0.055 to 39 0.05 to 24.75 0.07 to 36 TiC+TiN TiC 0 to 94 0 to 90 Oto 92 0 to 88 0 to 90 Oto 85 +M02C TiN Oto 94 Oto 91 Oto 92 Oto 89 0 ΐο 90 0 to 86 Mo2C 3 to 27 4 to 38 4 to 26 6 to 37 5 to 24 7 to 34 (NBSA+Ni) NBSA 0.03 to 29.7 0.02 to 40 0.04 to 26.73 0.035 to 36 0.05 to 24.75 0.05 to 34 - Ni 0.03 to 29.7 0.03 to 43 0.04 to 26.73 0.04 to 39 0.05 to 24.75 0.05 to 36 129Material composition range 1 Composition range 2 Composition range 3 vol% mm% vol 0 / 〇wt% vol% wt% (NBSA + Co) NBSA 0.03 to 29.7 0.04 to 40 0.04 to 26.73 0.05 to 37 0.05 to 24.75 0.06 to 34-Co 0.03 to 29.7 0.04 to 43 0.04 to 26.73 0.06 to 39 0.05 to 24.75 0.07 to 37 TiC + TiN TiC 0 to 94 0 to 90 Oto 92 Oto 87 0 to 90 0 to 84 + M02C TiN 0 to 94 Oto 91 Oto 92 0 to 88 0 to 90 0 to 86 Mo2C 3 to 27 4 to 38 4 to 26 6 to 37 5 to 24 7 to 34 (NBSA + Co) NBSA 0.03 to 29.7 0.02 to 40 0.04 to 26.73 0.03 to 36 0.05 to 24.75 0.05 to 34 -Co 0.03 to 29.7 0.03 to 43 0.04 to 26.73 0.04 to 39 0.05 to 24.75 0.05 to 36 TiC + TiN TiC 0.3 to 93.5 0.15 to 89 .40 to 91.3 0.2 to 86 0.5 to 89.1 0.3 to 83 + Mo2C TiN 0.3 to 93.5 0.25 to 90 .40 to 91.3 0.35 to 87 0.5 to 89.1 0.45 to 84 + WC + TaC Mo2C 3 to 28 4 to 26 4 to 26 6 to 26 5 to 24 7 to 25.5 + VC + Cr2C3 WC 0.1 to 20 0.25 to 42 0.15 to 15 0.38 to 35 0.2 to 12 0.5 to 29 TaC 0.1 to 15 0.23 to 33 0.15 to 12 0.35 to 28 0.2 to 10 0.47 to 24 VC Oto 15 Oto 16 Oto 12 Oto 13 Oto 10 Oto 11 Cr2C3 Oto 15 Oto 18 Oto 12 Oto 15 Oto 10 0tol3 TiN + Mo2C or TiC + TiN + Mo2C + WC + TaC + VC + Cr2C3 Material composition range 1 Composition range 2 Composition range 3 vol% wt% vol% wt% vol% wt% (NBSA + Ni) NBSA 0.03 to 29.7 0.04 to 40 0.04 to 26.73 0.05 to 37 0.05 to 24.75 0.06 to 34-Ni 0.03 to 29.7 0.04 to 43 0.04 to 26.73 0.055 to 39 0.05 to 24.75 0.07 to 36 TiC + TiN TiC 0 to 94 0 to 90 Oto 92 0 to 88 0 to 90 Oto 85 + M02C TiN Oto 94 Oto 91 Oto 92 Oto 89 0 ΐο 90 0 to 86 Mo2C 3 to 27 4 to 38 4 to 26 6 to 37 5 to 24 7 to 34 (NBSA + Ni) NBSA 0.03 to 29.7 0.02 to 40 0.04 to 26.73 0.035 to 36 0.05 to 24.75 0.05 to 34-Ni 0.03 to 29.7 0.03 to 43 0.04 to 26.73 0.04 to 39 0.05 to 24.75 0.05 to 36 129

1057D-6939-PF ^ 2005352551057D-6939-PF ^ 200535255

TiC+TiN TiC 0.3 to 93.5 0.15 to 89 .40 to 91.3 0.2 to 86 0.5 to 89.1 0.3 to 83 +Μ〇2〇 TiN 0.3 to 93.5 0.25 to 90 .40 to 91.3 0.35 to 87 0.5 to 89.1 0.45 to 84 +WC+TaC Mo2C 3 to 28 4 to 26 4 to 26 6 to 26 5 to 24 7 to 25.5 +VC+Cr2C3 WC 0.1 to 20 0.25 to 42 0.15 to 15 0.38 to 35 0.2 to 12 0.5 to 29 TaC 0.1 to 15 0.23 to 33 0.15 to 12 0.35 to 28 0.2 to 10 0.47 to 24 VC Oto 15 Oto 16 Oto 12 Oto 13 Oto 10 Oto 11 O2C3 Oto 15 Oto 18 Oto 12 Oto 15 Oto 10 0tol3 表37利用Re、Co及鎳基超合金爲黏結劑來黏結TiC+Mo2C或TiN+M〇2C或TiC+TiN+Mo2C 或 TiC+TiN+Mo2C+WC+TaC+VC+Cr2C3TiC + TiN TiC 0.3 to 93.5 0.15 to 89 .40 to 91.3 0.2 to 86 0.5 to 89.1 0.3 to 83 + Μ〇2〇 TiN 0.3 to 93.5 0.25 to 90 .40 to 91.3 0.35 to 87 0.5 to 89.1 0.45 to 84 + WC + TaC Mo2C 3 to 28 4 to 26 4 to 26 6 to 26 5 to 24 7 to 25.5 + VC + Cr2C3 WC 0.1 to 20 0.25 to 42 0.15 to 15 0.38 to 35 0.2 to 12 0.5 to 29 TaC 0.1 to 15 0.23 to 33 0.15 to 12 0.35 to 28 0.2 to 10 0.47 to 24 VC Oto 15 Oto 16 Oto 12 Oto 13 Oto 10 Oto 11 O2C3 Oto 15 Oto 18 Oto 12 Oto 15 Oto 10 0tol3 Table 37 uses Re, Co, and nickel-based superalloys as Adhesive to bond TiC + Mo2C or TiN + M〇2C or TiC + TiN + Mo2C or TiC + TiN + Mo2C + WC + TaC + VC + Cr2C3

材料組成範圍1 組成範圍2 組成範圍3 體積％重量％體積％重量％體積％重量％ (Re+NBSA Re 0.03 to 29.4 0.1 to 64 0.04 to 26.46 0.13 to 60 0.05 to 24.5 0.16 to 57 +Co) NBSA 0.03 to 29.4 0.035 to 40 0.04 to 26.46 0.045 to 36 0.05 to 24.5 0.055 to 34 - Co 0.03 to 29.4 0.04 to 42 0.04 to 26.46 0.05 to 39 0.05 to 24.5 0.06 to 36 TiC+TiN TiC 0 to 94 0 to 90 0 to 92 0 to 88 0 to 90 0 to 84 +M02C TiN 0 to 94 Oto 91 Oto 92 0 to 88 0 to 90 0 to 85 Mo2C 3 to 27 3 to 38 4 to 26 4 to 37 5 to 24 5 to 34 (Re+NBSA Re 0.03 to 29.4 0.06 to 63 0.04 to 26.46 0.1 to 60 0.05 to 24.5 0.13 to 57 +Co) NBSA 0.03 to 29.4 0.02 to 39 0.04 to 26.46 0.03 to 36 0.05 to 24.5 0.04 to 33 - Co 0.03 to 29.4 0.03 to 42 0.04 to 26.46 0.04 to 39 0.05 to 24.5 0.05 to 36 TiC 0.3 to 93.5 0.15 to 89 0.4 to 91.3 0.2 to 86 0.5 to 89.1 0.3 to 83 TiC+TiN TiN 0.3 to 93.5 0.15 to 90 0.4 to 91.3 0.2 to 87 0.5 to 89.1 0.3 to 84 +M02C Mo2C 3 to 28 3 to 26 4 to 26 4 to 26 5 to 24 5 to 25.5 +WC+TaC WC 0.1 to 20 0.15 to 42 0.15 to 15 0.25 to 35 0.2 to 12 0.35 to 29 +VC+Cr2C3 TaC 0.1 to 15 0.15 to 33 0.15 to 12 0.25 to 28 0.2 to 10 0.3 to 24 VC Oto 15 Oto 16 Oto 12 Oto 13 Oto 10 Oto 11 Cr2C3 Oto 15 Oto 18 Oto 12 Oto 15 Oto 10 Oto 13 表38利用Re、Ni及鎳基超合金爲黏結劑來黏結TiC+Mo2C或TiN+Mo2C或TiC+TiN+M〇2C 或 TiC+TiN+Mo2C+WC+TaC+VC+Cr2C3 材料組成範圍1 組成範圍2 組成範圍3 體積％重量％體積％重量％ mm% 重量％ (Re+NBSA Re 0.03 to 29.4 0.1 to 63 0.04 to 26.46 0.13 to 60 0.05 to 24.5 0.16 to 57 +Ni) NBSA 0.03 to 29.4 0.035 to 40 0.04 to 26.46 0.045 to 36 0.05 to 24.5 0.055 to 33 - Ni 0.03 to 29.4 0.04 to 42 0.04 to 26.46 0.05 to 38 0.05 to 24.5 0.06 to 36 TiC+TiN TiC 0 to 94 0 to 90 0 to 92 Oto 87 0 to 90 0 to 84 +Mo2C TiN 0 to 94 Oto 91 Oto 92 Oto 88 0 to 90 0 to 85 Mo2C 3 to 27 3 to 38 4 to 26 4 to 37 5 to 24 5 to 34 (Re+NBSA Re 0.03 to 29.4 0.06 to 63 0.04 to 26.46 0.1 to 60 0.05 to 24.5 0.13 to 57 130Material composition range 1 Composition range 2 Composition range 3 Vol% wt% Vol% wt% Vol% wt% (Re + NBSA Re 0.03 to 29.4 0.1 to 64 0.04 to 26.46 0.13 to 60 0.05 to 24.5 0.16 to 57 + Co) NBSA 0.03 to 29.4 0.035 to 40 0.04 to 26.46 0.045 to 36 0.05 to 24.5 0.055 to 34-Co 0.03 to 29.4 0.04 to 42 0.04 to 26.46 0.05 to 39 0.05 to 24.5 0.06 to 36 TiC + TiN TiC 0 to 94 0 to 90 0 to 92 0 to 88 0 to 90 0 to 84 + M02C TiN 0 to 94 Oto 91 Oto 92 0 to 88 0 to 90 0 to 85 Mo2C 3 to 27 3 to 38 4 to 26 4 to 37 5 to 24 5 to 34 (Re + NBSA Re 0.03 to 29.4 0.06 to 63 0.04 to 26.46 0.1 to 60 0.05 to 24.5 0.13 to 57 + Co) NBSA 0.03 to 29.4 0.02 to 39 0.04 to 26.46 0.03 to 36 0.05 to 24.5 0.04 to 33-Co 0.03 to 29.4 0.03 to 42 0.04 to 26.46 0.04 to 39 0.05 to 24.5 0.05 to 36 TiC 0.3 to 93.5 0.15 to 89 0.4 to 91.3 0.2 to 86 0.5 to 89.1 0.3 to 83 TiC + TiN TiN 0.3 to 93.5 0.15 to 90 0.4 to 91.3 0.2 to 87 0.5 to 89.1 0.3 to 84 + M02C Mo2C 3 to 28 3 to 26 4 to 26 4 to 26 5 to 24 5 to 25.5 + WC + TaC WC 0.1 to 20 0.15 to 42 0.15 to 15 0.25 to 35 0.2 to 12 0.35 to 29 + VC + Cr2C3 TaC 0.1 to 15 0.15 to 33 0.15 to 12 0.25 to 28 0.2 to 10 0.3 to 24 VC Oto 15 Oto 16 Oto 12 Oto 13 Oto 10 Oto 11 Cr2C3 Oto 15 Oto 18 Oto 12 Oto 15 Oto 10 Oto 13 M〇2C or TiC + TiN + Mo2C + WC + TaC + VC + Cr2C3 Material composition range 1 Composition range 2 Composition range 3 vol% wt% vol% wt% mm% wt% (Re + NBSA Re 0.03 to 29.4 0.1 to 63 0.04 to 26.46 0.13 to 60 0.05 to 24.5 0.16 to 57 + Ni) NBSA 0.03 to 29.4 0.035 to 40 0.04 to 26.46 0.045 to 36 0.05 to 24.5 0.055 to 33-Ni 0.03 to 29.4 0.04 to 42 0.04 to 26.46 0.05 to 38 0.05 to 24.5 0.06 to 36 TiC + TiN TiC 0 to 94 0 to 90 0 to 92 Oto 87 0 to 90 0 to 84 + Mo2C TiN 0 to 94 Oto 91 Oto 92 Oto 88 0 to 90 0 to 85 Mo2C 3 to 27 3 to 38 4 to 26 4 to 37 5 to 24 5 to 34 (Re + NBSA Re 0.03 to 29.4 0.06 to 63 0.04 to 26.46 0.1 to 60 0.05 to 24.5 0.13 to 57 130

1057D-6939-PF .'200535255 +Ni) NBSA 0.03 to 29.4 0.02 to 39 0.04 to 26.46 0.03 to 36 0.05 to 24.5 0.04 to 33 - Ni 0.03 to 29.4 0.03 to 42 0.04 to 26.46 0.04 to 38 0.05 to 24.5 0.05 to 36 TiC+TiN TiC 0.3 to 93.5 0.15 to 89 0.4 to 91.3 0,2 to 86 0.5 to 89.1 0.3 to 83 +Μ〇2〇 TiN 0.3 to 93.5 0.15 to 90 0.4 to 91.3 0.2 to 87 0.5 to 89.1 0.3 to 84 +WC+TaC Mo2C 3 to 28 3 to 26 4 to 26 4 to 26 5 to 24 5 to 25.5 +VC+Cr2C3 we 0.1 to 20 0.15 to 42 0.15 to 15 0.25 to 35 0.2 to 12 0.35 to 29 TaC 0.1 to 15 0.15 to 33 0.15 to 12 0.25 to 28 0.2 to 10 0.3 to 24 VC Oto 15 Oto 16 Oto 12 Oto 13 Oto 10 Oto 11 Cr2C3 Oto 15 Oto 18 0 to 12 Oto 15 Oto 10 Oto 13 表39利用Re、Ni及Co爲黏結劑來黏結TiC+Mo2C或TiN+Mo2C或TiC+TiN+Mo2C或TiC+ TiN+Mo2C+WC+TaC+VC+Cr2C31057D-6939-PF .'200535255 + Ni) NBSA 0.03 to 29.4 0.02 to 39 0.04 to 26.46 0.03 to 36 0.05 to 24.5 0.04 to 33-Ni 0.03 to 29.4 0.03 to 42 0.04 to 26.46 0.04 to 38 0.05 to 24.5 0.05 to 36 TiC + TiN TiC 0.3 to 93.5 0.15 to 89 0.4 to 91.3 0, 2 to 86 0.5 to 89.1 0.3 to 83 + Μ〇2〇 TiN 0.3 to 93.5 0.15 to 90 0.4 to 91.3 0.2 to 87 0.5 to 89.1 0.3 to 84 + WC + TaC Mo2C 3 to 28 3 to 26 4 to 26 4 to 26 5 to 24 5 to 25.5 + VC + Cr2C3 we 0.1 to 20 0.15 to 42 0.15 to 15 0.25 to 35 0.2 to 12 0.35 to 29 TaC 0.1 to 15 0.15 to 33 0.15 to 12 0.25 to 28 0.2 to 10 0.3 to 24 VC Oto 15 Oto 16 Oto 12 Oto 13 Oto 10 Oto 11 Cr2C3 Oto 15 Oto 18 0 to 12 Oto 15 Oto 10 Oto 13 Table 39 Adhesion using Re, Ni, and Co Agent to bond TiC + Mo2C or TiN + Mo2C or TiC + TiN + Mo2C or TiC + TiN + Mo2C + WC + TaC + VC + Cr2C3

材料組成範圍1 組成範圍2 組成範圍3 體積％重量％體積％重量％體積％重量°/〇 (Re+Ni Re 0.03 to 29.4 0.1 to 63 0.04 to 26.46 0.13 to 60 0.05 to 24.5 0.16 to 57 +Co) Ni 0.03 to 29.4 0.04 to 42 0.04 to 26.46 0.05 to 38 0.05 to 24.5 0.06 to 36 - Co 0.03 to 29.4 0.04 to 42 0.04 to 26.46 0.05 to 39 0.05 to 24.5 0.06 to 36 TiC+TiN TiC 0 to 94 0 to 90 Oto 92 Oto 87 0 to 90 Oto 83 +Mo2C TiN 0 to 94 Oto 91 Oto 92 0 to 88 0 to 90 0 to 85 Mo2C 3 to 27 3 to 38 4 to 26 4 to 37 5 to 24 5 to 34 (Re+Ni Re 0.03 to 29.4 0.06 to 63 0.04 to 26.46 0.1 to 60 0.05 to 24.5 0.13 to 57 +Co) Ni 0.03 to 29.4 0.025 to 42 0.04 to 26.46 0.04 to 38 0.05 to 24.5 0.05 to 36 - Co 0.03 to 29.4 0.03 to 42 0.04 to 26.46 0.04 to 39 0.05 to 24.5 0.05 to 36 TiC 0.3 to 93.5 0.15 to 89 0.4 to 91.3 0.2 to 85 0.5 to 89.1 0.3 to 82 TiC+TiN TiN 0.3 to 93.5 0.15 to 90 0.4 to 91.3 0.2 to 87 0.5 to 89.1 0.3 to 83 +M02C Mo2C 3 to 28 3 to 26 4 to 26 4 to 26 5 to 24 5 to 25.5 +WC+TaC WC 0.1 to 20 0.15 to 42 0.15 to 15 0.25 to 35 0.2 to 12 0.35 to 29 +VC+Cr2C3 TaC 0.1 to 15 0.15 to 33 0.15 to 12 0.25 to 28 0.2 to 10 0.3 to 24 VC Oto 15 Oto 16 Oto 12 Oto 13 Oto 10 Oto 11 Cr2C3 Oto 15 Oto 18 Oto 12 Oto 15 Oto 10 Oto 13 表40利用Co、Ni及鎳基超合金爲黏結劑來黏結TiC+M〇2C或TiN+M〇2C或TiC+TiN+Mo2C 或 TiC+TiN+Mo2C+WC+TaC+VC+Cr2C3 材料組成範圍1 組成範圍2 組成範圍3 體積％重量％體積％重量％體積％雷量％ (NBSA+Ni NBSA 0.03 to 29.4 0.04 to 40 0.04 to 26.46 0.5 to 36 0.05 to 24.5 0.06 to 34 +Co) Ni : 0.03 to 29.4 0.04 to 42 0.04 to 26.46 0.055 to 39 0.05 to 24.5 0.07 to 37 - Co 0.03 to 29.4 0.04 to 43 0.04 to 26.46 0.055 to 39 0.05 to 24.5 0.07 to 36 TiC+TiN TiC 0 to 94 Oto 90 Oto 92 Oto 87 0 to 90 0 to 84 +M02C TiN 0 to 94 Oto 91 Oto 92 Oto 88 0 to 90 Oto 85 131Material composition range 1 Composition range 2 Composition range 3 vol% wt% vol% wt% vol% wt ° / 〇 (Re + Ni Re 0.03 to 29.4 0.1 to 63 0.04 to 26.46 0.13 to 60 0.05 to 24.5 0.16 to 57 + Co) Ni 0.03 to 29.4 0.04 to 42 0.04 to 26.46 0.05 to 38 0.05 to 24.5 0.06 to 36-Co 0.03 to 29.4 0.04 to 42 0.04 to 26.46 0.05 to 39 0.05 to 24.5 0.06 to 36 TiC + TiN TiC 0 to 94 0 to 90 Oto 92 Oto 87 0 to 90 Oto 83 + Mo2C TiN 0 to 94 Oto 91 Oto 92 0 to 88 0 to 90 0 to 85 Mo2C 3 to 27 3 to 38 4 to 26 4 to 37 5 to 24 5 to 34 (Re + Ni Re 0.03 to 29.4 0.06 to 63 0.04 to 26.46 0.1 to 60 0.05 to 24.5 0.13 to 57 + Co) Ni 0.03 to 29.4 0.025 to 42 0.04 to 26.46 0.04 to 38 0.05 to 24.5 0.05 to 36-Co 0.03 to 29.4 0.03 to 42 0.04 to 26.46 0.04 to 39 0.05 to 24.5 0.05 to 36 TiC 0.3 to 93.5 0.15 to 89 0.4 to 91.3 0.2 to 85 0.5 to 89.1 0.3 to 82 TiC + TiN TiN 0.3 to 93.5 0.15 to 90 0.4 to 91.3 0.2 to 87 0.5 to 89.1 0.3 to 83 + M02C Mo2C 3 to 28 3 to 26 4 to 26 4 to 26 5 to 24 5 to 25.5 + WC + TaC W C 0.1 to 20 0.15 to 42 0.15 to 15 0.25 to 35 0.2 to 12 0.35 to 29 + VC + Cr2C3 TaC 0.1 to 15 0.15 to 33 0.15 to 12 0.25 to 28 0.2 to 10 0.3 to 24 VC Oto 15 Oto 16 Oto 12 Oto 13 Oto 10 Oto 11 Cr2C3 Oto 15 Oto 18 Oto 12 Oto 15 Oto 10 Oto 13 Table 40 uses Co, Ni, and nickel-based superalloys as binders to bond TiC + M〇2C or TiN + M〇2C or TiC + TiN + Mo2C or TiC + TiN + Mo2C + WC + TaC + VC + Cr2C3 material composition range 1 composition range 2 composition range 3 vol% wt% vol% wt% vol% lightning amount% (NBSA + Ni NBSA 0.03 to 29.4 0.04 to 40 0.04 to 26.46 0.5 to 36 0.05 to 24.5 0.06 to 34 + Co) Ni: 0.03 to 29.4 0.04 to 42 0.04 to 26.46 0.055 to 39 0.05 to 24.5 0.07 to 37-Co 0.03 to 29.4 0.04 to 43 0.04 to 26.46 0.055 to 39 0.05 to 24.5 0.07 to 36 TiC + TiN TiC 0 to 94 Oto 90 Oto 92 Oto 87 0 to 90 0 to 84 + M02C TiN 0 to 94 Oto 91 Oto 92 Oto 88 0 to 90 Oto 85 131

1057D-6939-PF ‘2005352551057D-6939-PF ‘200535255

Mo2C 3 to 27 4 to 38 4 to 26 5 to 37 5 to 24 7 to 34 (NBSA+Ni NBSA 0.03 to 29.4 0.025 to 40 0.04 to 26.46 0.035 to 36 0.05 to 24.5 0.05 to 33 +Co) Ni 0.03 to 29.4 0.025 to 42 0.04 to 26.46 0.04 to 38 0.05 to 24.5 0.05 to 36 - Co 0.03 to 29.4 0.03 to 42 0.04 to 26.46 0.04 to 39 0.05 to 24.5 0.05 to 36 TiC 0.3 to 93.5 0.15 to 89 0.4 to 91.3 0.2 to 86 0.5 to 89.1 0.3 to 83 TiC+TiN TiN 0.3 to 93.5 0.25 to 90 0.4 to 91.3 0.35 to 87 0.5 to 89.1 0.45 to 84 +M02C Mo2C 3 to 28 4 to 26 4 to 26 6 to 26 5 to 24 7 to 25.5 +WC+TaC WC 0.1 to 20 0.25 to 42 0.15 to 15 0.35 to 35 0.2 to 12 0. 5 to 29 +VC+Cr2C3 TaC 0.1 to 15 0.25 to 33 0.15 to 12 0.35 to 28 0.2 to 10 0.45 to 24 VC Oto 15 Oto 16 Oto 12 Oto 13 0 to 10 Oto 11 Cr2C3 Oto 15 Oto 18 Oto 12 Oto 15 Oto 10 Oto 13 表41利用Re、Ni、Co及鎳基超合金爲黏結劑來黏結TiC+Mo2C或TiN+Mo2C或TiC+TiN+ Mo2C 或 TiC+TiN+Mo2C+WC+TaC+VC+Cr2C3 材料組成範圍1 組成範圍2 組成範圍3 體積％重量％體積％重量％體積％重量〇/〇 (Re+NBSA+Ni Re 0.03 to 29.1 0.1 to 63 0.04 to 26.19 0.13 to 59 0.05 to 24.25 0.16 to 57 +Co) NBSA 0.03 to 29.1 0.035 to 39 0.04 to 26.19 0.45 to 36 0.05 to 24.25 0.055 to 33 - Ni 0.03 to 29.1 0.04 to 42 0.04 to 26.19 0.05 to 38 0.05 to 24.25 0.06 to 36 TiC+TiN Co 0.03 to 29.1 0.04 to 42 0.04 to 26.19 0.5 to 38 0.05 to 24.25 0.06 to 36 +Mo2C TiC 0 to 94 0 to 90 Oto 92 Oto 87 0 to 90 0 to 84 TiN 0 to 94 Oto 91 Oto 92 0 to 88 0 to 90 0 to 85 Mo2C 3 to 27 3 to 38 4 to 26 4 to 37 5 to 24 5 to 34 (Re+NBSA+Ni Re 0.03 to 29.1 0.06 to 63 0.04 to 26.19 0.1 to 59 0.05 to 24.25 0.12 to 56 +Co) NBSA 0.03 to 29.1 0.02 to 39 0.04 to 26.19 0.03 to 35 0.05 to 24.25 0.04 to 33 - Ni 0.03 to 29.1 0.025 to 42 0.04 to 26.19 0.035 to 38 0.05 to 24.25 0.05 to 35 Co 0.03 to 29.1 0.025 to 42 0.04 to 26.19 0.03 to 38 0.05 to 24.25 0.05 to 36 TiC+TiN TiC 0.3 to 93.5 0.15 to 89 0.4 to 91.3 0.2 to 86 0.5 to 89.1 0.3 to 83 +Mo2C TiN 0.3 to 93.5 0.15 to 90 0.4 to 91.3 0.2 to 87 0.5 to 89.1 0.3 to 84 +WC+TaC Mo2C 3 to 28 3 to 26 4 to 26 4 to 26 5 to 24 5 to 25.5 +VC+Cr2C3 WC 0.1 to 20 0.15 to 42 0.15 to 15 0.25 to 35 0.2 to 12 0.3 to 29 TaC 0.1 to 15 0.15 to 33 0.15 to 12 0.2 to 28 0.2 to 10 0.3 to 24 VC Oto 15 Oto 16 Oto 12 Oto 13 Oto 10 Oto 11 1 Cr2C3 Oto 15 Oto 18 Oto 12 Oto 15 0 to 10 Oto 13Mo2C 3 to 27 4 to 38 4 to 26 5 to 37 5 to 24 7 to 34 (NBSA + Ni NBSA 0.03 to 29.4 0.025 to 40 0.04 to 26.46 0.035 to 36 0.05 to 24.5 0.05 to 33 + Co) Ni 0.03 to 29.4 0.025 to 42 0.04 to 26.46 0.04 to 38 0.05 to 24.5 0.05 to 36-Co 0.03 to 29.4 0.03 to 42 0.04 to 26.46 0.04 to 39 0.05 to 24.5 0.05 to 36 TiC 0.3 to 93.5 0.15 to 89 0.4 to 91.3 0.2 to 86 0.5 to 89.1 0.3 to 83 TiC + TiN TiN 0.3 to 93.5 0.25 to 90 0.4 to 91.3 0.35 to 87 0.5 to 89.1 0.45 to 84 + M02C Mo2C 3 to 28 4 to 26 4 to 26 6 to 26 5 to 24 7 to 25.5 + WC + TaC WC 0.1 to 20 0.25 to 42 0.15 to 15 0.35 to 35 0.2 to 12 0.5 to 29 + VC + Cr2C3 TaC 0.1 to 15 0.25 to 33 0.15 to 12 0.35 to 28 0.2 to 10 0.45 to 24 VC Oto 15 Oto 16 Oto 12 Oto 13 0 to 10 Oto 11 Cr2C3 Oto 15 Oto 18 Oto 12 Oto 15 Oto 10 Oto 13 Table 41 Adhesive TiC + Mo2C or TiN + Mo2C or TiC + TiN + Mo2C or TiC + TiN + Mo2C + WC + TaC + VC + Cr2C3 Material composition range 1 Composition range 2 Composition range 3 vol% wt% vol% wt% Product weight 〇 / 〇 (Re + NBSA + Ni Re 0.03 to 29.1 0.1 to 63 0.04 to 26.19 0.13 to 59 0.05 to 24.25 0.16 to 57 + Co) NBSA 0.03 to 29.1 0.035 to 39 0.04 to 26.19 0.45 to 36 0.05 to 24.25 0.055 to 33-Ni 0.03 to 29.1 0.04 to 42 0.04 to 26.19 0.05 to 38 0.05 to 24.25 0.06 to 36 TiC + TiN Co 0.03 to 29.1 0.04 to 42 0.04 to 26.19 0.5 to 38 0.05 to 24.25 0.06 to 36 + Mo2C TiC 0 to 94 0 to 90 Oto 92 Oto 87 0 to 90 0 to 84 TiN 0 to 94 Oto 91 Oto 92 0 to 88 0 to 90 0 to 85 Mo2C 3 to 27 3 to 38 4 to 26 4 to 37 5 to 24 5 to 34 (Re + NBSA + Ni Re 0.03 to 29.1 0.06 to 63 0.04 to 26.19 0.1 to 59 0.05 to 24.25 0.12 to 56 + Co) NBSA 0.03 to 29.1 0.02 to 39 0.04 to 26.19 0.03 to 35 0.05 to 24.25 0.04 to 33-Ni 0.03 to 29.1 0.025 to 42 0.04 to 26.19 0.035 to 38 0.05 to 24.25 0.05 to 35 Co 0.03 to 29.1 0.025 to 42 0.04 to 26.19 0.03 to 38 0.05 to 24.25 0.05 to 36 TiC + TiN TiC 0.3 to 93.5 0.15 to 89 0.4 to 91.3 0.2 to 86 0.5 to 89.1 0.3 to 83 + Mo2C TiN 0.3 to 93.5 0.15 to 90 0.4 to 91.3 0.2 to 87 0.5 to 89.1 0.3 to 84 + WC + TaC Mo2C 3 to 28 3 to 26 4 to 26 4 to 26 5 to 24 5 to 25.5 + VC + Cr2C3 WC 0.1 to 20 0.15 to 42 0.15 to 15 0.25 to 35 0.2 to 12 0.3 to 29 TaC 0.1 to 15 0.15 to 33 0.15 to 12 0.2 to 28 0.2 to 10 0.3 to 24 VC Oto 15 Oto 16 Oto 12 Oto 13 Oto 10 Oto 11 1 Cr2C3 Oto 15 Oto 18 Oto 12 Oto 15 0 to 10 Oto 13

表42-5 1列出額外不同組成物的組成範圍，與上述部分組成物類似，在表42-51中的一些組成可應用在高溫下，其應用溫度顯示在表格最後一列估算溶點中。如以上所述，帶有Re、鎳基超合金或兩者的結合可加強 132Table 42-5 1 lists the composition range of additional different compositions, similar to some of the above-mentioned components. Some of the compositions in Table 42-51 can be applied at high temperatures. The application temperature is shown in the estimated column in the last column of the table. As mentioned above, with Re, nickel-based superalloy, or a combination of both

1057D-6939-PF ‘200535255 在高溫下材料的性質。通常利用w在不同的硬粒子中例如：碳化物、氮化物、碳氮化合物、化物或^夕化物當作組成元素。當用來作黏結劑基質時無論是單獨使用或連同其他金屬皆可大幅提高硬金屬材料的熔點至2500°C至3500t：，因此以W基黏結劑基質可在高溫下應用。，在表43-48中明顯地顯示以W 為基底的黏結劑基質熔點約3500°C。表47中以Re及Co來黏結氮化物的組成物，其中硬金屬組合物中氮化物可由氮化物及碳化物的結合物來取 ® 代。此硬金屬組合物包括至少一種由元素週期表中IVb及 Vb族元素所形成的氮化物及一種由元素週期表中IVb、Vb 及VIb族元素所形成的碳化物，以及一包含Re及Co用來黏結硬粒子的黏結劑基質。表42 Re黏結由元素週期表中IVb、Vb及VIb族元素所形成的硼化物或由元素週期表中IVb、 Vb及VIb族元素所形成的矽化物組成範圍1 組成範圍2 組成範圍3 估算熔點體積％重量％ mm% 重量％體積％重量％ °C Re黏結 Re 3 to 40 12.5 to 76 4 to 35 16 to 71 5 to 30 20 to 67 2700 to TiB2 TiB2 60 to 97 24 to 87.5 65 to 96 29 to 84 70 to 95 33 to 80 3000 Re黏結 Re 3 to 40 9.5 to 70 4 to 35 12.5 to 65 5 to 30 15 to 60 2800 to ZrB2 ZrB2 60 to 97 30 to 90.5 65 to 96 35 to 87.5 70 to 95 40 to 85 3000 Re黏結 Re 3 to 40 5.5 to 55.5 4 to 35 7 to 50 5 to 30 9 to 44.5 3000 to HfB2 HiB2 60 to 97 44.5 to 94.5 65 to 96 50 to 93 70 to 95 55.5 to 91 3200 Re黏結 Re 3 to 40 11 to 73 4 to 35 14.5 to 69 5 to 30 18 to 64 2000 to vb2 vb2 60 to 97 27 to 89 65 to 96 31 to 85.5 70 to 95 36 to 82 2500 Re黏結 Re 3 to 40 8 to 66 4 to 35 11 to 61 5 to 30 13 to 55.5 2800 to NbB2 NbB2 60 to 97 34 to 92 65 to 96 39 to 89 70 to 95 44.5 to 87 3100 Re黏結 Re 3 to 40 5 to 53 4 to 35 6.5 to 47 5 to 30 8 to 42 3000 to TaB2 TaB2 60 to 97 47 to 95 65 to 96 53 to 93.5 70 to 95 58 to 92 3200 Re黏結 Re 3 to 40 9.5 to 69.5 4 to 35 12.5 to 65 5 to 30 15 to 60 1800 to Cr3B2 Cr3B2 60 to 97 30.5 to 90.5 65 to 96 35 to 87.5 70 to 95 40 to 85 2200 Re黏結 Re 3 to 40 7.5 to 64 4 to 35 10 to 59 5 to 30 12.5 to 54 2000 to1057D-6939-PF ‘200535255 Properties of materials at high temperatures. Generally, w is used as a constituent element in different hard particles such as carbides, nitrides, carbonitrides, compounds or compounds. When used as an adhesive matrix, whether used alone or in combination with other metals, can significantly increase the melting point of hard metal materials to 2500 ° C to 3500t: Therefore, W-based adhesive matrix can be used at high temperatures. Tables 43-48 clearly show that the melting point of the W-based adhesive matrix is about 3500 ° C. In Table 47, the composition of nitrides is bonded with Re and Co. The nitrides in the hard metal composition can be replaced by a combination of nitrides and carbides. The hard metal composition includes at least one nitride formed from elements of Groups IVb and Vb in the periodic table of the elements, and a carbide formed of elements of Groups IVb, Vb, and VIb of the Periodic Table of Elements, and a compound containing Re and Co. A binder matrix to bind hard particles. Table 42 Re-bonded boride formed from elements IVb, Vb, and VIb in the periodic table or silicide formed from elements IVb, Vb, and VIb in the periodic table. Composition range 1 Composition range 2 Composition range 3 Estimated melting point Vol% wt% mm% wt% vol% wtC Rebond Re 3 to 40 12.5 to 76 4 to 35 16 to 71 5 to 30 20 to 67 2700 to TiB2 TiB2 60 to 97 24 to 87.5 65 to 96 29 to 84 70 to 95 33 to 80 3000 Rebond Re 3 to 40 9.5 to 70 4 to 35 12.5 to 65 5 to 30 15 to 60 2800 to ZrB2 ZrB2 60 to 97 30 to 90.5 65 to 96 35 to 87.5 70 to 95 40 to 85 3000 Re Bonding Re 3 to 40 5.5 to 55.5 4 to 35 7 to 50 5 to 30 9 to 44.5 3000 to HfB2 HiB2 60 to 97 44.5 to 94.5 65 to 96 50 to 93 70 to 95 55.5 to 91 3200 Re bonding Re 3 to 40 11 to 73 4 to 35 14.5 to 69 5 to 30 18 to 64 2000 to vb2 vb2 60 to 97 27 to 89 65 to 96 31 to 85.5 70 to 95 36 to 82 2500 Rebond Re 3 to 40 8 to 66 4 to 35 11 to 61 5 to 30 13 to 55.5 2800 to NbB2 NbB2 60 to 97 34 to 92 65 to 96 39 to 89 70 to 95 44.5 to 87 3100 Rebond Re 3 to 40 5 to 53 4 to 35 6.5 to 47 5 to 30 8 to 42 3000 to TaB2 TaB2 60 to 97 47 to 95 65 to 96 53 to 93.5 70 to 95 58 to 92 3200 Re bond Re 3 to 40 9.5 to 69.5 4 to 35 12.5 to 65 5 to 30 15 to 60 1800 to Cr3B2 Cr3B2 60 to 97 30.5 to 90.5 65 to 96 35 to 87.5 70 to 95 40 to 85 2200 Rebond Re 3 to 40 7.5 to 64 4 to 35 10 to 59 5 to 30 12.5 to 54 2000 to

133133

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MoB2 60 to 97 36 to 92.5 65 to 96 41 to 90 70 to 95 46 to 87.5 Re黏結 Re 3 to 40 4 to 47 4 to 35 5 to 41 5 to 30 6.5 to 36 2700 to WB WB 60 to 97 53 to 96 65 to 96 59 to 95 70 to 95 64 to 93.5 3000 Re黏結 Re 3 to 40 4 to 47 4 to 35 5 to 41 5 to 30 6.5 to 36 2600 to W2B W2B 60 to 97 53 to 96 65 to 96 59 to 95 70 to 95 64 to 93.5 2900 Re黏結 Re 3 to 40 13 to 77 4 to 35 17 to 72 5 to 30 20 to 68 2000 to Ti5Si3 Ti5Si3 60 to 97 23 to 87 65 to 96 28 to 83 70 to 95 32 to 80 2400 Re黏結 Re 3 to 40 10 to 72 4 to 35 14 to 67 5 to 30 17 to 62 2100 to Zr6Si5 Zr6Si5 60 to 97 28 to 90 65 to 96 33 to 86 70 to 95 38 to 83 2500 Re黏結 Re 3 to 40 9 to 69 4 to 35 12 to 64 5 to 30 15 to 59 1800 to NbSi2 NbSi2 60 to 97 31 to 91 65 to 96 36 to 88 70 to 95 41 to 85 2200 Re黏結 Re 3 to 40 7 to 62 4 to 35 9 to 57 5 to 30 12 to 51 2200 to TaSi2 TaSi2 60 to 97 38 to 93 65 to 96 43 to 91 70 to 95 49 to 88 2600 Re黏結 Re 3 to 40 9 to 69 4 to 35 12 to 64 5 to 30 15 to 59 1800 to MoSi2 MoSi2 60 to 97 31 to 91 65 to 96 36 to 88 70 to 95 41 to 85 2200 Re黏結 Re 3 to 40 6 to 60 4 to 35 9 to 55 5 to 30 11 to 49 1800 to WSi2 WSi2 60 to 97 40 to 94 65 to 96 45 to 91 70 to 95 51 to 89 2200MoB2 60 to 97 36 to 92.5 65 to 96 41 to 90 70 to 95 46 to 87.5 Rebond Re 3 to 40 4 to 47 4 to 35 5 to 41 5 to 30 6.5 to 36 2700 to WB WB 60 to 97 53 to 96 65 to 96 59 to 95 70 to 95 64 to 93.5 3000 Rebond Re 3 to 40 4 to 47 4 to 35 5 to 41 5 to 30 6.5 to 36 2600 to W2B W2B 60 to 97 53 to 96 65 to 96 59 to 95 70 to 95 64 to 93.5 2900 Rebond Re 3 to 40 13 to 77 4 to 35 17 to 72 5 to 30 20 to 68 2000 to Ti5Si3 Ti5Si3 60 to 97 23 to 87 65 to 96 28 to 83 70 to 95 32 to 80 2400 Re bonding Re 3 to 40 10 to 72 4 to 35 14 to 67 5 to 30 17 to 62 2100 to Zr6Si5 Zr6Si5 60 to 97 28 to 90 65 to 96 33 to 86 70 to 95 38 to 83 2500 Re bonding Re 3 to 40 9 to 69 4 to 35 12 to 64 5 to 30 15 to 59 1800 to NbSi2 NbSi2 60 to 97 31 to 91 65 to 96 36 to 88 70 to 95 41 to 85 2200 Rebond Re 3 to 40 7 to 62 4 to 35 9 to 57 5 to 30 12 to 51 2200 to TaSi2 TaSi2 60 to 97 38 to 93 65 to 96 43 to 91 70 to 95 49 to 88 2600 Rebond Re 3 to 40 9 to 69 4 to 35 12 to 64 5 to 30 15 to 59 1800 to MoSi2 M oSi2 60 to 97 31 to 91 65 to 96 36 to 88 70 to 95 41 to 85 2200 Rebond Re 3 to 40 6 to 60 4 to 35 9 to 55 5 to 30 11 to 49 1800 to WSi2 WSi2 60 to 97 40 to 94 65 to 96 45 to 91 70 to 95 51 to 89 2200

表43 W S占結由元素週期表中IVb、Vb及VIb族元素所形成的碳化物或由元素週期表中 IVb及Vb族元素所形成的氮化物組成範圍1 組成範圍2 組成範圍3 估算熔點體積％重量％ mm% 重量％體積％重量％ °C w黏結 w 3 to 40 11 to 72 4 to 35 25.02 to 70 5 to 30 25.02 to 65 3000 to 3300 TiC TiC 60 to 97 28 to 89 65 to 96 30 to 74.98 70 to 95 35 to 74.98 w黏結 W 3 to 40 8 to 66 4 to 35 11 to 61 5 to 30 13 to 56 3200 to 3500 ZrC ZrC 60 to 97 34 to 92 65 to 96 39 to 89 70 to 95 44 to 87 w黏結 W 3 to 40 4 to 50 4 to 35 6 to 45 5 to 30 7 to 40 3300 to 3500 HfC HfC 60 to 97 50 to 96 65 to 96 55 to 64 70 to 95 60 to 93 w黏結 W 3 to 40 10 to 70 4 to 35 13 to 65 5 to 30 16 to 60 2700 to 3300 VC VC 60 to 97 30 to 90 65 to 96 35 to 87 70 to 95 40 to 84 W黏結 W 3 to 40 7 to 62 4 to 35 9 to 57 5 to 30 11 to 51 3000 to 3500 NbC NbC 60 to 97 38 to 93 65 to 96 43 to 91 70 to 95 49 to 89 W黏結 W 3 to 40 4 to 47 4 to 35 5 to 42 5 to 30 7 to 36 3300 to 3500 TaC TaC 60 to 97 53 to 96 65 to 96 58 to 95 70 to 95 64 to 93 w黏結 W 3 to 40 8 to 66 4 to 35 11 to 61 5 to 30 13 to 55 1700 to 2100 Cr2C3 Cr2C3 60 to 97 34 to 92 65 to 96 39 to 89 70 to 95 45 to 87 W黏結 W 3 to 40 6 to 59 4 to 35 8 to 53 5 to 30 10 to 48 2400 to 2600 Mo2C Mo2C 60 to 97 41 to 94 65 to 96 47 to 93 70 to 95 52 to 90 W黏結 W 3 to 40 4 to 45 4 to 35 5 to 40 5 to 30 6 to 35 2800 to 3000 wc WC 60 to 97 55 to 96 65 to 96 60 to 95 70 to 95 65 to 94 W黏結 W 3 to 40 11 to 72 4 to 35 14 to 68 5 to 30 16 to 60 2800 to 3300 134Table 43 WS accounts for carbides formed from elements of Groups IVb, Vb and VIb in the periodic table or nitrides formed from elements of Groups IVb and Vb of the periodic table Composition range 1 Composition range 2 Composition range 3 Estimated melting volume % Wt% mm% wt% vol% wt% ° C w Bonding w 3 to 40 11 to 72 4 to 35 25.02 to 70 5 to 30 25.02 to 65 3000 to 3300 TiC TiC 60 to 97 28 to 89 65 to 96 30 to 74.98 70 to 95 35 to 74.98 w Bonding W 3 to 40 8 to 66 4 to 35 11 to 61 5 to 30 13 to 56 3200 to 3500 ZrC ZrC 60 to 97 34 to 92 65 to 96 39 to 89 70 to 95 44 to 87 w Bonding W 3 to 40 4 to 50 4 to 35 6 to 45 5 to 30 7 to 40 3300 to 3500 HfC HfC 60 to 97 50 to 96 65 to 96 55 to 64 70 to 95 60 to 93 w Bonding W 3 to 40 10 to 70 4 to 35 13 to 65 5 to 30 16 to 60 2700 to 3300 VC VC 60 to 97 30 to 90 65 to 96 35 to 87 70 to 95 40 to 84 W Bonding W 3 to 40 7 to 62 4 to 35 9 to 57 5 to 30 11 to 51 3000 to 3500 NbC NbC 60 to 97 38 to 93 65 to 96 43 to 91 70 to 95 49 to 89 W Bonding W 3 to 40 4 to 47 4 to 35 5 to 4 2 5 to 30 7 to 36 3300 to 3500 TaC TaC 60 to 97 53 to 96 65 to 96 58 to 95 70 to 95 64 to 93 w Bonding W 3 to 40 8 to 66 4 to 35 11 to 61 5 to 30 13 to 55 1700 to 2100 Cr2C3 Cr2C3 60 to 97 34 to 92 65 to 96 39 to 89 70 to 95 45 to 87 W Bonding W 3 to 40 6 to 59 4 to 35 8 to 53 5 to 30 10 to 48 2400 to 2600 Mo2C Mo2C 60 to 97 41 to 94 65 to 96 47 to 93 70 to 95 52 to 90 W Bonding W 3 to 40 4 to 45 4 to 35 5 to 40 5 to 30 6 to 35 2800 to 3000 wc WC 60 to 97 55 to 96 65 to 96 60 to 95 70 to 95 65 to 94 W Bonding W 3 to 40 11 to 72 4 to 35 14 to 68 5 to 30 16 to 60 2800 to 3300 134

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TiN TiN 60 to 97 28 to 89 65 to 96 32 to 86 70 to 95 40 to 84 W黏結 W 3 to 40 8 to 64 4 to 35 10 to 59 5 to 30 12 to 53 2900 to 3300 ZrN ZrN 60 to 97 36 to 92 65 to 96 41 to 90 70 to 95 47 to 88 W黏結 W 3 to 40 4 to 48 4 to 35 6 to 43 5 to 30 7 to 37 3200 to 3500 HfN HfN 60 to 97 52 to 96 65 to 96 57 to 94 70 to 95 63 to 93 W黏結 W 3 to 40 9 to 68 4 to 35 12 to 63 5 to 30 15 to 58 2000 to 2400 VN VN 60 to 97 32 to 91 65 to 96 37 to 88 70 to 95 42 to 85 W黏結 W 3 to 40 8 to 64 4 to 35 10 to 59 5 to 30 12 to 53 2200 to 2600 NbN NbN 60 to 97 36 to 92 65 to 96 41 to 90 70 to 95 47 to 88 W黏結 W 3 to 40 4 to 47 4 to 35 5 to 42 5 to 30 7 to 37 3000 to 3500 TaN TaN 60 to 97 53 to 96 65 to 96 58 to 95 70 to 95 63 to 93 表44 W黏結由元素週期表中IVb、Vb及VIb族元素所形成的硼化物或由元素週期表中 IVb、Vb及VIb族元素所形成的矽化物TiN TiN 60 to 97 28 to 89 65 to 96 32 to 86 70 to 95 40 to 84 W Bonding W 3 to 40 8 to 64 4 to 35 10 to 59 5 to 30 12 to 53 2900 to 3300 ZrN ZrN 60 to 97 36 to 92 65 to 96 41 to 90 70 to 95 47 to 88 W Bonding W 3 to 40 4 to 48 4 to 35 6 to 43 5 to 30 7 to 37 3200 to 3500 HfN HfN 60 to 97 52 to 96 65 to 96 57 to 94 70 to 95 63 to 93 W Bonding W 3 to 40 9 to 68 4 to 35 12 to 63 5 to 30 15 to 58 2000 to 2400 VN VN 60 to 97 32 to 91 65 to 96 37 to 88 70 to 95 42 to 85 W bonding W 3 to 40 8 to 64 4 to 35 10 to 59 5 to 30 12 to 53 2200 to 2600 NbN NbN 60 to 97 36 to 92 65 to 96 41 to 90 70 to 95 47 to 88 W bonding W 3 to 40 4 to 47 4 to 35 5 to 42 5 to 30 7 to 37 3000 to 3500 TaN TaN 60 to 97 53 to 96 65 to 96 58 to 95 70 to 95 63 to 93 Table 44 W bonding by IVb in the periodic table Borides formed by Groups, Vb, and VIb elements or silicides formed by Group IVb, Vb, and VIb elements in the periodic table

組成範圍1 組成範圍2 組成範圍3 估算熔點體積％重量％體積％重量％體積％ MM% °C w黏結 w 3 to 40 12 to 74 4 to 35 15 to 70 5 to 30 18 to 65 2700 to TiB2 TiB2 60 to 97 26 to 88 65 to 96 30 to 85 70 to 95 35 to 82 3000 w黏結 W 3 to 40 9 to 68 4 to 35 12 to 63 5 to 30 14 to 58 2800 to ZrB2 ZrB2 60 to 97 32 to 91 65 to 96 37 to 88 70 to 95 42 to 86 3000 w黏結 W 3 to 40 5 to 54 4 to 35 7 to 48 5 to 30 8 to 42 3000 to HfB2 HfB2 60 to 97 46 to 95 65 to 96 52 to 93 70 to 95 58 to 92 3400 w黏結 W 3 to 40 10 to 72 4 to 35 14 to 67 5 to 30 17 to 62 2000 to vb2 vb2 60 to 97 28 to 90 65 to 96 33 to 86 70 to 95 38 to 83 2500 W黏結 W 3 to 40 8 to 64 4 to 35 10 to 59 5 to 30 12 to 53 2900 to NbB2 NbB2 60 to 97 36 to 92 65 to 96 41 to 90 70 to 95 47 to 88 3400 w黏結 W 3 to 40 5 to 51 4 to 35 6 to 45 5 to 30 7 to 40 3100 to TaB2 TaB: 60 to 97 49 to 95 65 to 96 55 to 94 70 to 95 60 to 93 3400 w黏結 w 3 to 40 9 to 68 4 to 35 12 to 63 5 to 30 14 to 58 1800 to Cr3B2 Cr3B2 60 to 97 32 to 91 65 to 96 37 to 88 70 to 95 42 to 86 2200 w黏結 W 3 to 40 7 to 62 4 to 35 9 to 57 5 to 30 12 to 52 2000 to MoB2 MoB2 60 to 97 38 to 93 65 to 96 43 to 91 70 to 95 48 to 88 2400 W黏結 W 3 to 40 4 to 45 4 to 35 5 to 39 5 to 30 6 to 34 2700 to WB WB 60 to 97 55 to 96 65 to 96 61 to 95 70 to 95 66 to 94 3000 W黏結 W 3 to 40 3 to 44 4 to 35 5 to 38 5 to 30 6 to 33 2600 to w2b w2b 60 to 97 56 to 97 65 to 96 62 to 95 70 to 95 67 to 94 2900 W黏結 W 3 to 40 12 to 75 4 to 35 16 to 71 5 to 30 19 to 66 2000 to Ti5Si3 Ti5Si3 60 to 97 25 to 88 65 to 96 29 to 84 70 to 95 34 to 81 2400 W黏結 w 3 to 40 10 to 70 4 to 35 13 to 65 5 to 30 16 to 60 2100 to Zr6Si5 Zr6Si5 60 to 97 30 to 90 65 to 96 35 to 87 70 to 95 40 to 84 2500 W黏結 w 3 to 40 9 to 67 4 to 35 11 to 62 5 to 30 14 to 57 1800 toComposition range 1 Composition range 2 Composition range 3 Estimated melting point volume% weight% volume% weight% volume% MM% ° C w bonding w 3 to 40 12 to 74 4 to 35 15 to 70 5 to 30 18 to 65 2700 to TiB2 TiB2 60 to 97 26 to 88 65 to 96 30 to 85 70 to 95 35 to 82 3000 w Bonding W 3 to 40 9 to 68 4 to 35 12 to 63 5 to 30 14 to 58 2800 to ZrB2 ZrB2 60 to 97 32 to 91 65 to 96 37 to 88 70 to 95 42 to 86 3000 w Bonding W 3 to 40 5 to 54 4 to 35 7 to 48 5 to 30 8 to 42 3000 to HfB2 HfB2 60 to 97 46 to 95 65 to 96 52 to 93 70 to 95 58 to 92 3400 w Bonding W 3 to 40 10 to 72 4 to 35 14 to 67 5 to 30 17 to 62 2000 to vb2 vb2 60 to 97 28 to 90 65 to 96 33 to 86 70 to 95 38 to 83 2500 W Bonding W 3 to 40 8 to 64 4 to 35 10 to 59 5 to 30 12 to 53 2900 to NbB2 NbB2 60 to 97 36 to 92 65 to 96 41 to 90 70 to 95 47 to 88 3400 w Bonding W 3 to 40 5 to 51 4 to 35 6 to 45 5 to 30 7 to 40 3100 to TaB2 TaB: 60 to 97 49 to 95 65 to 96 55 to 94 70 to 95 60 to 93 3400 w Bonding w 3 to 40 9 to 68 4 to 35 12 to 63 5 to 30 14 to 58 1800 to Cr3B2 Cr3B2 60 to 97 32 to 91 65 to 96 37 to 88 70 to 95 42 to 86 2200 w Bonding W 3 to 40 7 to 62 4 to 35 9 to 57 5 to 30 12 to 52 2000 to MoB2 MoB2 60 to 97 38 to 93 65 to 96 43 to 91 70 to 95 48 to 88 2400 W Bonding W 3 to 40 4 to 45 4 to 35 5 to 39 5 to 30 6 to 34 2700 to WB WB 60 to 97 55 to 96 65 to 96 61 to 95 70 to 95 66 to 94 3000 W Bonding W 3 to 40 3 to 44 4 to 35 5 to 38 5 to 30 6 to 33 2600 to w2b w2b 60 to 97 56 to 97 65 to 96 62 to 95 70 to 95 67 to 94 2900 W Bonding W 3 to 40 12 to 75 4 to 35 16 to 71 5 to 30 19 to 66 2000 to Ti5Si3 Ti5Si3 60 to 97 25 to 88 65 to 96 29 to 84 70 to 95 34 to 81 2400 W bonding w 3 to 40 10 to 70 4 to 35 13 to 65 5 to 30 16 to 60 2100 to Zr6Si5 Zr6Si5 60 to 97 30 to 90 65 to 96 35 to 87 70 to 95 40 to 84 2500 W bonding w 3 to 40 9 to 67 4 to 35 11 to 62 5 to 30 14 to 57 1800 to

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NbSi2 NbSi2 60 to 97 33 to 91 65 to 96 38 to 89 70 to 95 43 to 86 2200 W黏結 W 3 to 40 7 to 60 4 to 35 9 to 55 5 to 30 11 to 49 2200 to TaSi2 TaSi2 60 to 97 40 to 93 65 to 96 45 to 91 70 to 95 51 to 89 2600 W黏結 W 3 to 40 9 to 67 4 to 35 11 to 62 5 to 30 14 to 57 1800 to MoSi2 MoSi2 60 to 97 31 to 91 65 to 96 38 to 89 70 to 95 43 to 86 2200 w黏結 W 3 to 40 6 to 58 4 to 35 8 to 53 5 to 30 10 to 47 1800 to WSi2 WSi2 60 to 97 42 to 94 65 to 96 47 to 92 70 to 95 43 to 90 2200NbSi2 NbSi2 60 to 97 33 to 91 65 to 96 38 to 89 70 to 95 43 to 86 2200 W Bonding W 3 to 40 7 to 60 4 to 35 9 to 55 5 to 30 11 to 49 2200 to TaSi2 TaSi2 60 to 97 40 to 93 65 to 96 45 to 91 70 to 95 51 to 89 2600 W Bonding W 3 to 40 9 to 67 4 to 35 11 to 62 5 to 30 14 to 57 1800 to MoSi2 MoSi2 60 to 97 31 to 91 65 to 96 38 to 89 70 to 95 43 to 86 2200 w Bonding W 3 to 40 6 to 58 4 to 35 8 to 53 5 to 30 10 to 47 1800 to WSi2 WSi2 60 to 97 42 to 94 65 to 96 47 to 92 70 to 95 43 to 90 2200

表45 Re及W(Re+W)黏結由元素週期表中IVb、Vb及VIb族元素所形成的碳化物或由元素週期表中IVb及Vb族元素所形成的氮化物，其中黏結劑組成範圍由l%Re+99%W至 99%Re+l%W 組成範圍1 組成範圍2 組成範圍3 估算熔點體積％重量％體積％重量％體積％重量％ °C Re +W Re 0.03 to 39.6 0.12 to 73 0.04 to 34.7 0.15 to 69 0.05 to 29.7 0.19 to 64 2900 黏結 W 0.03 to 39.6 0.1 to 72 0.04 to 34.7 0.14 to 67 0.05 to 29.7 0.17 to 62 to TiC TiC 60 to 97 26 to 89 65 to 96 30 to 86 70 to 95 35 to 83 3300 Re +W Re 0.03 to 39.6 0.09 to 67 0.04 to 34.7 0.12 to 63 0.05 to 29.7 0.15 to 57 3000 黏結 W 0.03 to 39.6 0.08 to 66 0.04 to 34.7 0.11 to 61 0.05 to 29.7 0.13 to 55 to ZrC ZrC 60 to 97 32 to 92 65 to 96 37 to 89 70 to 95 42 to 87 3400 Re+W Re 0.03 to 39.6 0.05 to 52 0.04 to 34.7 0.07 to 47 0.05 to 29.7 0.08 to 41 3100 黏結 W 0.03 to 39.6 0.05 to 50 0.04 to 34.7 0.06 to 45 0.05 to 29.7 0.07 to 39 to HfC HfC 60 to 97 48 to 95 65 to 96 53 to 94 70 to 95 58 to 93 3500 Re+W Re 0.03 to 39.6 0.11 to 71 0.14 to 67 0.15 to 67.0 0.17 to 62 0.19 to 61.8 2700 黏結 W 0.03 to 39.6 0.1 to 69 0.13 to 65 0.06 to 46.3 0.15 to 60 0.07 to 40.8 to VC VC 60 to 97 28 to 90 33 to 87 32.8 to 93.5 70 to 95 38 to 84 3000 Re + W Re 0.03 to 39.6 0.08 to 64 0.04 to 34.7 0.1 to 59 0.05 to 29.7 0.13 to 53 3200 黏結 W 0.03 to 39.6 0.07 to 56 0.04 to 34.7 0.09 to 56 0.05 to 29.7 0.11 to 51 to NbC NbC 60 to 97 36 to 93 65 to 96 41 to 91 70 to 95 47 to 88 3500 Re + W Re 0.03 to 39.6 0.04 to 49 0.04 to 34.7 0.06 to 43 0.05 to 29.7 0.07 to 38 3100 黏結 W 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.05 to 41 0.05 to 29.7 0.07 to 36 to TaC TaC 60 to 97 51 to 96 65 to 96 56 to 95 70 to 95 62 to 93 3500 Re + W Re 0.03 to 39.6 0.09 to 67 0.04 to 34.7 0.12 to 62 0.05 to 29.7 0.14 to 57 1700 黏結 W 0.03 to 39.6 0.08 to 65 0.04 to 34.7 0.11 to 60 0.05 to 29.7 0.13 to 55 to Cr2C3 Cr2C3 60 to 97 32 to 92 65 to 96 37 to 89 70 to 95 43 to 87 1900 Re + W Re 0.03 to 39.6 0.07 to 60 0.04 to 34.7 0.09 to 55 0.05 to 29.7 0.11 to 49 2400 黏結 W 0.03 to 39.6 0.06 to 58 0.04 to 34.7 0.08 to 53 0.05 to 29.7 0.1 to 47 to Mo2C Mo2C 60 to 97 39 to 94 65 to 96 45 to 92 70 to 95 50 to 90 2600 Re + W Re 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.05 to 42 0.05 to 29.7 0.07 to 36 2700 黏結 W 0.03 to 39.6 0.04 to 45 0.04 to 34.7 0.05 to 40 0.05 to 29.7 0.06 to 34 to wc WC 60 to 97 53 to 96 65 to 96 58 to 95 70 to 95 63 to 94 2900Table 45 Re and W (Re + W) bonding Carbides formed from Group IVb, Vb, and VIb elements in the periodic table or nitrides formed from Group IVb and Vb elements in the periodic table, in which the composition of the binder ranges From 1% Re + 99% W to 99% Re + l% W Composition range 1 Composition range 2 Composition range 3 Estimated melting volume% by weight% by volume% by weight% by volume% by weight ° C Re + W Re 0.03 to 39.6 0.12 to 73 0.04 to 34.7 0.15 to 69 0.05 to 29.7 0.19 to 64 2900 Bonding W 0.03 to 39.6 0.1 to 72 0.04 to 34.7 0.14 to 67 0.05 to 29.7 0.17 to 62 to TiC TiC 60 to 97 26 to 89 65 to 96 30 to 86 70 to 95 35 to 83 3300 Re + W Re 0.03 to 39.6 0.09 to 67 0.04 to 34.7 0.12 to 63 0.05 to 29.7 0.15 to 57 3000 Bonding W 0.03 to 39.6 0.08 to 66 0.04 to 34.7 0.11 to 61 0.05 to 29.7 0.13 to 55 to ZrC ZrC 60 to 97 32 to 92 65 to 96 37 to 89 70 to 95 42 to 87 3400 Re + W Re 0.03 to 39.6 0.05 to 52 0.04 to 34.7 0.07 to 47 0.05 to 29.7 0.08 to 41 3100 Bonding W 0.03 to 39.6 0.05 to 50 0.04 to 34.7 0.06 to 45 0.05 to 29.7 0.07 to 39 to HfC HfC 60 to 97 48 to 95 65 to 96 53 to 94 70 to 95 58 to 93 3500 Re + W Re 0.03 to 39.6 0.11 to 71 0.14 to 67 0.15 to 67.0 0.17 to 62 0.19 to 61.8 2700 Bonding W 0.03 to 39.6 0.1 to 69 0.13 to 65 0.06 to 46.3 0.15 to 60 0.07 to 40.8 to VC VC 60 to 97 28 to 90 33 to 87 32.8 to 93.5 70 to 95 38 to 84 3000 Re + W Re 0.03 to 39.6 0.08 to 64 0.04 to 34.7 0.1 to 59 0.05 to 29.7 0.13 to 53 3200 Bond W 0.03 to 39.6 0.07 to 56 0.04 to 34.7 0.09 to 56 0.05 to 29.7 0.11 to 51 to NbC NbC 60 to 97 36 to 93 65 to 96 41 to 91 70 to 95 47 to 88 3500 Re + W Re 0.03 to 39.6 0.04 to 49 0.04 to 34.7 0.06 to 43 0.05 to 29.7 0.07 to 38 3100 Bonding W 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.05 to 41 0.05 to 29.7 0.07 to 36 to TaC TaC 60 to 97 51 to 96 65 to 96 56 to 95 70 to 95 62 to 93 3500 Re + W Re 0.03 to 39.6 0.09 to 67 0.04 to 34.7 0.12 to 62 0.05 to 29.7 0.14 to 57 1700 Bonding W 0.03 to 39.6 0.08 to 65 0.04 to 34.7 0.11 to 60 0.05 to 29.7 0.13 to 55 to Cr2C3 Cr2C3 60 to 97 32 to 92 65 to 96 37 to 89 70 to 95 43 to 87 1900 Re + W Re 0.03 to 39.6 0.07 to 60 0.04 to 34.7 0.09 to 55 0.05 to 29.7 0.11 to 49 2400 Bonding W 0.03 to 39.6 0.06 to 58 0.04 to 34.7 0.08 to 53 0.05 to 29.7 0.1 to 47 to Mo2C Mo2C 60 to 97 39 to 94 65 to 96 45 to 92 70 to 95 50 to 90 2600 Re + W Re 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.05 to 42 0.05 to 29.7 0.07 to 36 2700 Bonding W 0.03 to 39.6 0.04 to 45 0.04 to 34.7 0.05 to 40 0.05 to 29.7 0.06 to 34 to wc WC 60 to 97 53 to 96 65 to 96 58 to 95 70 to 95 63 to 94 2900

136136

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Re +W Re 0.03 to 39.6 0.1 to 71 0.04 to 34.7 0.14 to 67 0.05 to 29.7 0.17 to 62 2900 黏結 W 0.03 to 39.6 0.1 to 70 0.04 to 34.7 0.13 to 65 0.05 to 29.7 0.16 to 60 to TiN TiN 60 to 97 28 to 90 65 to 96 32 to 87 70 to 95 38 to 84 3200 Re +W Re 0.03 to 39.6 0.08 to 65 0.04 to 34.7 0.11 to 60 0.05 to 29.7 0.13 to 55 2900 黏結 W 0.03 to 39.6 0.08 to 63 0.04 to 34.7 0.1 to 58 0.05 to 29.7 0.12 to 53 to ZrN ZrN 60 to 97 34 to 92 65 to 96 39 to 90 70 to 95 45 to 88 3200 Re +W Re 0.03 to 39.6 0.05 to 50 0.04 to 34.7 0.06 to 45 0.05 to 29.7 0.08 to 39 3100 黏結 W 0.03 to 39.6 0.04 to 48 0.04 to 34.7 0.06 to 43 0.05 to 29.7 0.07 to 37 to HiN HfN 60 to 97 50 to 96 65 to 96 55 to 95 70 to 95 61 to 93 3400 Re +W Re 0.03 to 39.6 0.1 to 69 0.04 to 34.7 0.13 to 65 0.05 to 29.7 0.16 to 59 2100 黏結 W 0.03 to 39.6 0.09 to 67 0.04 to 34.7 0.12 to 63 0.05 to 29.7 0.14 to 57 to VN VN 60 to 97 30 to 91 65 to 96 35 to 88 70 to 95 40 to 86 2300 Re +W Re 0.03 to 39.6 0.08 to 65 0.04 to 34.7 0.11 to 60 0.05 to 29.7 0.13 to 55 2300 黏結 W 0.03 to 39.6 0.08 to 63 0.04 to 34.7 0.1 to 58 0.05 to 29.7 0.12 to 53 to NbN NbN 60 to 97 35 to 92 65 to 96 39 to 90 70 to 95 45 to 88 2500 Re +W Re 0.03 to 39.6 0.04 to 49 0.04 to 34.7 0.06 to 44 0.05 to 29.7 0.07 to 38 2900 黏結 W 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.05 to 42 0.05 to 29.7 0.07 to 36 to TaN TaN 60 to 97 51 to 96 65 to 96 56 to 95 70 to 95 61 to 93 3400Re + W Re 0.03 to 39.6 0.1 to 71 0.04 to 34.7 0.14 to 67 0.05 to 29.7 0.17 to 62 2900 Bonding W 0.03 to 39.6 0.1 to 70 0.04 to 34.7 0.13 to 65 0.05 to 29.7 0.16 to 60 to TiN TiN 60 to 97 28 to 90 65 to 96 32 to 87 70 to 95 38 to 84 3200 Re + W Re 0.03 to 39.6 0.08 to 65 0.04 to 34.7 0.11 to 60 0.05 to 29.7 0.13 to 55 2900 Bond W 0.03 to 39.6 0.08 to 63 0.04 to 34.7 0.1 to 58 0.05 to 29.7 0.12 to 53 to ZrN ZrN 60 to 97 34 to 92 65 to 96 39 to 90 70 to 95 45 to 88 3200 Re + W Re 0.03 to 39.6 0.05 to 50 0.04 to 34.7 0.06 to 45 0.05 to 29.7 0.08 to 39 3100 Bonding W 0.03 to 39.6 0.04 to 48 0.04 to 34.7 0.06 to 43 0.05 to 29.7 0.07 to 37 to HiN HfN 60 to 97 50 to 96 65 to 96 55 to 95 70 to 95 61 to 93 3400 Re + W Re 0.03 to 39.6 0.1 to 69 0.04 to 34.7 0.13 to 65 0.05 to 29.7 0.16 to 59 2100 Bonding W 0.03 to 39.6 0.09 to 67 0.04 to 34.7 0.12 to 63 0.05 to 29.7 0.14 to 57 to VN VN 60 to 97 30 to 91 65 to 96 35 to 88 70 to 95 40 to 86 2300 Re + W Re 0.03 to 39.6 0.08 to 65 0.04 to 34.7 0.11 to 60 0.05 to 29.7 0.13 to 55 2300 Bonding W 0.03 to 39.6 0.08 to 63 0.04 to 34.7 0.1 to 58 0.05 to 29.7 0.12 to 53 to NbN NbN 60 to 97 35 to 92 65 to 96 39 to 90 70 to 95 45 to 88 2500 Re + W Re 0.03 to 39.6 0.04 to 49 0.04 to 34.7 0.06 to 44 0.05 to 29.7 0.07 to 38 2900 Bonding W 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.05 to 42 0.05 to 29.7 0.07 to 36 to TaN TaN 60 to 97 51 to 96 65 to 96 56 to 95 70 to 95 61 to 93 3400

表46 Re及W(Re+W)黏結由元素週期表中IVb、Vb及VIb族元素所形成的硼化物或由元素週期表中IVb及Vb族元素所形成的矽化物，其中黏結劑組成範圍由l%Re+99%W至 99%Re+l%W 組成範圍1 組成範圍2 組成範圍3 估算熔點體積0/〇重量％體積0/〇重量％體積％重量0/〇 °C Re+W Re 0.03 to 39.6 0.13 to 75 0.04 to 34.7 0.16 to 71 0.05 to 29.7 0.2 to 66 2900 黏結 W 0.03 to 39.6 0.12 to 73 0.04 to 34.7 0.15 to 69 0.05 to 29.7 0.18 to 64 to || TiB2 TiB2 60 to 97 24 to 88 65 to 96 29 to 85 70 to 95 33 to 82 3100 Re + W Re 0.03 to 39.6 0.1 to 69 0.04 to 34.7 0.13 to 64 0.05 to 29.7 0.16 to 59 2900 黏結 W 0.03 to 39.6 0.09 to 67 0.04 to 34.7 0.12 to 63 0.05 to 29.7 0.14 to 57 to ZrB2 ZrB2 60 to 97 30 to 91 65 to 96 35 to 88 70 to 95 40 to 86 3100 Re+W Re 0.03 to 39.6 0.05 to 54 0.04 to 34.7 0.07 to 50 0.05 to 29.7 0.09 to 44 3100 黏結 W 0.03 to 39.6 0.05 to 53 0.04 to 34.7 0.07to 48 0.05 to 29.7 0.08to 42 to HfB2 HfB2 60 to 97 44 to 95 65 to 96 50〇93 70 to 95 55 to 92 3300 Re+W Re 0.03 to 39.6 0.11 to 73 0.14 to 67 0.15 to 68 0.17 to 62 0.18 to 63 2000 黏結 W 0.03 to 39.6 0.1 to 71 0.13 to 65 0.13 to 66 0.15 to 60 0.16 to 61 to vb2 vb2 60 to 97 27 to 90 33 to 87 31 to 86 70 to 95 36 to 84 2200 Re + W Re 0.03 to 39.6 0.08 to 65 0.04 to 34.7 0.1 to 61 0.05 to 29.7 0.13 to 55 2900 黏結 W 0.03 to 39.6 0.08 to 63 0.04 to 34.7 0.1 to 58 0.05 to 29.7 0.12 to 53 to NbB2 NbB2 60 to 97 34 to 92 65 to 96 39 to 90 70 to 95 44 to 88 3100 Re + W Re 0.03 to 39.6 0.05 to 52 0.04 to 34.7 0.07 to 47 0.05 to 29.7 0.08 to 41 3100 黏結 W 0.03 to 39.6 0.05 to 50 0.04 to 34.7 0.06 to 39 0.05 to 29.7 0.07 to 39 to 137Table 46 Re and W (Re + W) bonding Borides formed from elements of Groups IVb, Vb, and VIb in the periodic table or silicides formed from elements of Groups IVb and Vb in the periodic table, in which the composition of the binder ranges From 1% Re + 99% W to 99% Re + l% W Composition range 1 Composition range 2 Composition range 3 Estimated melting volume 0 / 〇wt% Volume 0 / 〇wt% Vol% wt 0 / 〇 ° C Re + W Re 0.03 to 39.6 0.13 to 75 0.04 to 34.7 0.16 to 71 0.05 to 29.7 0.2 to 66 2900 Bonding W 0.03 to 39.6 0.12 to 73 0.04 to 34.7 0.15 to 69 0.05 to 29.7 0.18 to 64 to || TiB2 TiB2 60 to 97 24 to 88 65 to 96 29 to 85 70 to 95 33 to 82 3100 Re + W Re 0.03 to 39.6 0.1 to 69 0.04 to 34.7 0.13 to 64 0.05 to 29.7 0.16 to 59 2900 Bonding W 0.03 to 39.6 0.09 to 67 0.04 to 34.7 0.12 to 63 0.05 to 29.7 0.14 to 57 to ZrB2 ZrB2 60 to 97 30 to 91 65 to 96 35 to 88 70 to 95 40 to 86 3100 Re + W Re 0.03 to 39.6 0.05 to 54 0.04 to 34.7 0.07 to 50 0.05 to 29.7 0.09 to 44 3100 Bonding W 0.03 to 39.6 0.05 to 53 0.04 to 34.7 0.07 to 48 0.05 to 29.7 0.08 to 42 to HfB2 HfB2 60 to 97 44 to 95 65 to 96 50〇93 70 to 95 55 to 92 3300 Re + W Re 0.03 to 39.6 0.11 to 73 0.14 to 67 0.15 to 68 0.17 to 62 0.18 to 63 2000 Bond W 0.03 to 39.6 0.1 to 71 0.13 to 65 0.13 to 66 0.15 to 60 0.16 to 61 to vb2 vb2 60 to 97 27 to 90 33 to 87 31 to 86 70 to 95 36 to 84 2200 Re + W Re 0.03 to 39.6 0.08 to 65 0.04 to 34.7 0.1 to 61 0.05 to 29.7 0.13 to 55 2900 Bonding W 0.03 to 39.6 0.08 to 63 0.04 to 34.7 0.1 to 58 0.05 to 29.7 0.12 to 53 to NbB2 NbB2 60 to 97 34 to 92 65 to 96 39 to 90 70 to 95 44 to 88 3100 Re + W Re 0.03 to 39.6 0.05 to 52 0.04 to 34.7 0.07 to 47 0.05 to 29.7 0.08 to 41 3100 Bonding W 0.03 to 39.6 0.05 to 50 0.04 to 34.7 0.06 to 39 0.05 to 29.7 0.07 to 39 to 137

1057D-6939-PF •2005352551057D-6939-PF • 200535255

TaB2 TaB2 60 to 97 47 to 96 65 to 96 53 to 94 70 to 95 58 to 93 3300 Re +W Re 0.03 to 39.6 0.1 to 69 0.04 to 34.7 0.13 to 64 0.05 to 29.7 0.16 to 59 1900 黏結 W 0.03 to 39.6 0.09 to 67 0.04 to 34.7 0.12 to 62 0.05 to 29.7 0.14 to 57 to Cr3B2 Cr3B2 60 to 97 32 to 91 65 to 96 35 to 88 70 to 95 40 to 86 2100 Re + W Re 0.03 to 39.6 0.08 to 64 0.04 to 34.7 0.1 to 59 0.05 to 29.7 0.13 to 53 2000 黏結 W 0.03 to 39.6 0.07 to 62 0.04 to 34.7 0.09 to 57 0.05 to 29.7 0.11 to 51 to MoB2 MoB2 60 to 97 36 to 93 65 to 96 41 to 91 70 to 95 46 to 88 2200 Re + W Re 0.03 to 39.6 0.04 to 46 0.04 to 34.7 0.05 to 41 0.05 to 29.7 0.07 to 36 2800 黏結 W 0.03 to 39,6 0.04 to 44 0.04 to 34.7 0.05 to 39 0.05 to 29.7 0.06 to 34 to WB WB 60 to 97 53 to 96 65 to 96 57 to 95 70 to 95 64 to 94 2900 Re + W Re 0.03 to 39.6 0.04 to 45 0.04 to 34.7 0.05 to 40 0.05 to 29.7 0.06 to 35 2700 黏結 W 0.03 to 39.6 0.03 to 43 0.04 to 34.7 0.05 to 38 0.05 to 29.7 0.06 to 33 to w2b W2B 60 to 97 54 to 97 65 to 96 60 to 95 70 to 95 65 to 94 2900 Re + W Re 0.03 to 39.6 0.13 to 76 0.04 to 34.7 0.17 to 72 0.05 to 29.7 0.21 to 67 2000 1黏結 W 0.03 to 39.6 0.12 to 74 0.04 to 34.7 0.16 to 70 0.05 to 29.7 0.19 to 65 to Ti5Si3 Ti5Si3 60 to 97 24 to 88 65 to 96 28 to 84 70 to 95 32 to 81 2200 Re + W Re 0.03 to 39.6 0.11 to 71 0.04 to 34.7 0.14 to 67 0.05 to 29.7 0.17 to 61 2100 黏結 W 0.03 to 39.6 0.1 to 69 0.04 to 34.7 0.13 to 65 0.05 to 29.7 0.15 to 59 to Zr6Si5 Zr6Si5 60 to 97 28 to 90 65 to 96 33 to 87 70 to 95 38 to 84 2400 Re + W Re 0.03 to 39.6 0.09 to 68 0.04 to 34.7 0.12 to 64 0.05 to 29.7 0.15 to 58 1900 黏結 W 0.03 to 39.6 0.09 to 66 0.04 to 34.7 0.11 to 62 0.05 to 29.7 0.14 to 56 to NbSi2 NbSi2 60 to 97 31 to 91 65 to 96 36 to 89 70 to 95 41 to 86 2100 Re + W Re 0.03 to 39.6 0.07 to 62 0.04 to 34.7 0.09 to 57 0.05 to 29.7 0.12 to 51 2300 黏結 W 0.03 to 39.6 0.07 to 60 0.04 to 34.7 0.09 to 54 0.05 to 29.7 0.11 to 49 to TaSi2 TaSi2 60 to 97 38 to 93 65 to 96 43 to 91 70 to 95 49 to 89 2500 Re + W Re 0.03 to 39.6 0.1 to 69 0.04 to 34.7 0.12 to 64 0.05 to 29.7 0.15 to 58 1900 黏結 W 0.03 to 39.6 0.09 to 67 0.04 to 34.7 0.11 to 62 0.05 to 29.7 0.14 to 56 to | MoSi2 MoSi2 60 to 97 31 to 91 65 to 96 36 to 89 70 to 95 41 to 86 2100 Re + W Re 0.03 to 39.6 0.07 to 60 0.04 to 34.7 0.09 to 54 0.05 to 29.7 0.11 to 49 1900 黏結 W 0.03 to 39.6 0.06 to 58 0.04 to 34.7 0.08 to 52 0.05 to 29.7 0.1 to 47 to WSi2 WSi2 60 to 97 40 to 94 65 to 96 45 to 92 70 to 95 51 to 90 2100 表47 Re及Co(Re+Co)黏結由元素週期表中IVb、Vb及VIb族元素所形成的碳化物或由元素週期表中IVb及Vb族元素所形成的氮化物，其中黏結劑組成範圍由l%Re+99%C〇至 99%Re+l%Co 組成範圍1 組成範圍2 組成範圍3 估算熔點體積％重量％體積％重量％體積％重量％ °C Re +Co Re 0.03 to 39.6 0.12 to 74 0.04 to 34.7 0.17 to 69 0.05 to 29.7 0.2 to 64 1400 黏結 Co 0.03 to 39.6 0.05 to 54 0.04 to 34.7 0.07 to 49 0.05 to 29.7 0.08 to 43 to TiC TiC 60 to 97 26 to 95 65 to 96 30 to 93 70 to 95 35 to 91 3200 Re +Co Re 0.03 to 39.6 0.09 to 68 0.04 to 34.7 0.13 to 63 0.05 to 29.7 0.16 to 57 1400 138TaB2 TaB2 60 to 97 47 to 96 65 to 96 53 to 94 70 to 95 58 to 93 3300 Re + W Re 0.03 to 39.6 0.1 to 69 0.04 to 34.7 0.13 to 64 0.05 to 29.7 0.16 to 59 1900 Bonding W 0.03 to 39.6 0.09 to 67 0.04 to 34.7 0.12 to 62 0.05 to 29.7 0.14 to 57 to Cr3B2 Cr3B2 60 to 97 32 to 91 65 to 96 35 to 88 70 to 95 40 to 86 2100 Re + W Re 0.03 to 39.6 0.08 to 64 0.04 to 34.7 0.1 to 59 0.05 to 29.7 0.13 to 53 2000 Bonding W 0.03 to 39.6 0.07 to 62 0.04 to 34.7 0.09 to 57 0.05 to 29.7 0.11 to 51 to MoB2 MoB2 60 to 97 36 to 93 65 to 96 41 to 91 70 to 95 46 to 88 2200 Re + W Re 0.03 to 39.6 0.04 to 46 0.04 to 34.7 0.05 to 41 0.05 to 29.7 0.07 to 36 2800 Bonding W 0.03 to 39,6 0.04 to 44 0.04 to 34.7 0.05 to 39 0.05 to 29.7 0.06 to 34 to WB WB 60 to 97 53 to 96 65 to 96 57 to 95 70 to 95 64 to 94 2900 Re + W Re 0.03 to 39.6 0.04 to 45 0.04 to 34.7 0.05 to 40 0.05 to 29.7 0.06 to 35 2700 Bonding W 0.03 to 39.6 0.03 to 43 0.04 to 34.7 0.05 to 38 0.05 to 29.7 0.06 to 33 to w2b W2B 60 to 97 54 to 97 65 to 9 6 60 to 95 70 to 95 65 to 94 2900 Re + W Re 0.03 to 39.6 0.13 to 76 0.04 to 34.7 0.17 to 72 0.05 to 29.7 0.21 to 67 2000 1 Bonding W 0.03 to 39.6 0.12 to 74 0.04 to 34.7 0.16 to 70 0.05 to 29.7 0.19 to 65 to Ti5Si3 Ti5Si3 60 to 97 24 to 88 65 to 96 28 to 84 70 to 95 32 to 81 2200 Re + W Re 0.03 to 39.6 0.11 to 71 0.04 to 34.7 0.14 to 67 0.05 to 29.7 0.17 to 61 2100 Bonding W 0.03 to 39.6 0.1 to 69 0.04 to 34.7 0.13 to 65 0.05 to 29.7 0.15 to 59 to Zr6Si5 Zr6Si5 60 to 97 28 to 90 65 to 96 33 to 87 70 to 95 38 to 84 2400 Re + W Re 0.03 to 39.6 0.09 to 68 0.04 to 34.7 0.12 to 64 0.05 to 29.7 0.15 to 58 1900 Bonding W 0.03 to 39.6 0.09 to 66 0.04 to 34.7 0.11 to 62 0.05 to 29.7 0.14 to 56 to NbSi2 NbSi2 60 to 97 31 to 91 65 to 96 36 to 89 70 to 95 41 to 86 2100 Re + W Re 0.03 to 39.6 0.07 to 62 0.04 to 34.7 0.09 to 57 0.05 to 29.7 0.12 to 51 2300 Bonding W 0.03 to 39.6 0.07 to 60 0.04 to 34.7 0.09 to 54 0.05 to 29.7 0.11 to 49 to TaSi2 TaSi2 60 to 97 38 to 93 65 to 96 43 to 91 70 to 95 49 to 89 2500 Re + W Re 0.03 to 39.6 0.1 to 69 0.04 to 34.7 0.12 to 64 0.05 to 29.7 0.15 to 58 1900 Bonding W 0.03 to 39.6 0.09 to 67 0.04 to 34.7 0.11 to 62 0.05 to 29.7 0.14 to 56 to | MoSi2 MoSi2 60 to 97 31 to 91 65 to 96 36 to 89 70 to 95 41 to 86 2100 Re + W Re 0.03 to 39.6 0.07 to 60 0.04 to 34.7 0.09 to 54 0.05 to 29.7 0.11 to 49 1900 Bonding W 0.03 to 39.6 0.06 to 58 0.04 to 34.7 0.08 to 52 0.05 to 29.7 0.1 to 47 to WSi2 WSi2 60 to 97 40 to 94 65 to 96 45 to 92 70 to 95 51 to 90 2100 Table 47 Re and Co (Re + Co) bonding by the element cycle The carbides formed by Group IVb, Vb, and VIb elements in the table or the nitrides formed by Group IVb and Vb elements in the Periodic Table of Elements, wherein the binder composition ranges from 1% Re + 99% C0 to 99% Re + l% Co Composition range 1 Composition range 2 Composition range 3 Estimated melting point vol% wt% vol% wt% vol% wt% ° C Re + Co Re 0.03 to 39.6 0.12 to 74 0.04 to 34.7 0.17 to 69 0.05 to 29.7 0.2 to 64 1400 Bonding Co 0.03 to 39.6 0.05 to 54 0.04 to 34.7 0.07 to 49 0.05 to 29. 7 0.08 to 43 to TiC TiC 60 to 97 26 to 95 65 to 96 30 to 93 70 to 95 35 to 91 3200 Re + Co Re 0.03 to 39.6 0.09 to 68 0.04 to 34.7 0.13 to 63 0.05 to 29.7 0.16 to 57 1400 138

1057D-6939-PF .200535255 黏結 Co 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.05 to 42 0.05 to 29.7 0.06 to 37 to ZrC ZrC 60 to 97 32 to 96 65 to 96 37 to 95 70 to 95 42 to 93 3200 Re +Co Re 0.03 to 39.6 0.05 to 52 0.04 to 34.7 0.07 to 47 0.05 to 29.7 0.08 to 41 1400 黏結 Co 0.03 to 39.6 0.02 to 32 0.04 to 34.7 0.03 to 27 0.05 to 29.7 0.04 to 23 to HfC HfC 60 to 97 48 to 98 65 to 96 53 to 97 70 to 95 59 to 96 3200 Re+Co Re 0.03 to 39.6 0.11 to 71 0.14 to 67 0.15 to 67.0 0.17 to 62 0.19 to 62 1400 黏結 Co 0.03 to 39.6 0.05 to 51 0.13 to 65 0.06 to 46 0.15 to 60 0.07 to 41 to VC VC 60 to 97 28 to 95 33 to 87 33 to 94 70 to 95 38 to 92 2900 Re + Co Re 0.03 to 39.6 0.08 to 64 0.04 to 34.7 0.1 to 59 0.05 to 29.7 0.13 to 53 1400 黏結 Co 0.03 to 39.6 0.03 to 43 0.04 to 34.7 0.04 to 38 0.05 to 29.7 0.05 to 33 to NbC NbC 60 to 97 36 to 97 65 to 96 41 to 95 70 to 95 47 to 94 3200 Re H- Co Re 0.03 to 39.6 0.04 to 49 0.04 to 34.7 0.06 to 43 0.05 to 29.7 0.07 to 38 1400 黏結 Co 0.03 to 39.6 0.02 to 29 0.04 to 34.7 0.024 to 25 0.05 to 29.7 0.03 to 21 to TaC TaC 60 to 97 51 to 98 65 to 96 56 to 97 70 to 95 62 to 97 3200 1 Re+Co Re 0.03 to 39.6 0.09 to 67 0.04 to 34.7 0.12 to 62 0.05 to 29.7 0.15 to 57 1400 黏結 Co 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.05 to 41 0.05 to 29.7 0.06 to 36 to Cr2C3 Cr2〇3 60 to 97 32 to 96 65 to 96 37 to 95 70 to 95 43 to 93 1900 Re + Co Re 0.03 to 39.6 0.07 to 60 0.04 to 34.7 0.09 to 55 0.05 to 29.7 0.11 to 49 1400 黏結 Co 0.03 to 39.6 0.03 to 39 0.04 to 34.7 0.04 to 34 0.05 to 29.7 0.05 to 29 to Mo2C Mo2C 60 to 97 40 to 97 65 to 96 45 to 96 70 to 95 50 to 95 2600 Re + Co Re 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.05 to 42 0.05 to 29.7 0.07 to 36 1400 黏結 Co 0.03 to 39.6 0.017 to 27 0.04 to 34.7 0.023 to 23 0.05 to 29.7 0.028 to 20 to WC WC 60 to 97 53 to 96 65 to 96 58 to 95 70 to 95 63 to 94 2900 Re + Co Re 0.03 to 39.6 0.11 to 71 0.04 to 34.7 0.15 to 67 0.05 to 29.7 0.19 to 62 1400 黏結 Co 0.03 to 39.6 0.05 to 52 0.04 to 34.7 0.06 to 46 0.05 to 29.7 0.07 to 41 to TiN TiN 60 to 97 28 to 95 65 to 96 33 to 93 70 to 95 38 to 92 3200 Re + Co Re 0.03 to 39.6 0.08 to 65 0.04 to 34.7 0.11 to 60 0.05 to 29.7 0.14 to 55 1400 ^黏結 Co 0.03 to 39.6 0.04 to 44 0.04 to 34.7 0.05 to 39 0.05 to 29.7 0.06 to 34 to ZrN ZrN 60 to 97 34 to 96 65 to 96 39 to 95 70 to 95 45 to 94 3200 Re + Co Re 0.03 to 39.6 0.05 to 50 0.04 to 34.7 0.06 to 45 0.05 to 29.7 0.08 to 39 1400 黏結 Co 0.03 to 39.6 0.019 to 30 0.04 to 34.7 0.026 to 26 0.05 to 29.7 0.032 to 22 to HfN HfN 60 to 97 50 to 98 65 to 96 55 to 97 70 to 95 61 to 97 3200 Re + Co Re 0.03 to 39.6 0.1 to 70 0.04 to 34.7 0.14 to 65 0.05 to 29.7 0.17 to 60 1400 黏結 Co 0.03 to 39.6 0.04 to 49 0.04 to 34.7 0.05 to 44 0.05 to 29.7 0.07 to 39 to VN VN 60 to 97 30 to 96 65 to 96 35 to 94 70 to 95 40 to 93 2300 Re + Co Re 0.03 to 39.6 0.08 to 65 0.04 to 34.7 0.11 to 60 0.05 to 29.7 0.14 to 55 1400 黏結 Co 0.03 to 39.6 0.04 to 45 0.04 to 34.7 0.05 to 39 0.05 to 29.7 0.06 to 34 to NbN NbN 60 to 97 34 to 96 65 to 96 39 to 95 70 to 95 45 to 94 2500 Re + Co . Re 0.03 to 39.6 0.04 to 49 0.04 to 34.7 0.06 to 44 0.05 to 29.7 0.07 to 38 1400 黏結 Co 0.03 to 39.6 0.02 to 29 0.04 to 34.7 0.025 to 25 0.05 to 29.7 0.03 to 21 to TaN TaN 60 to 97 51 to 98 65 to 96 56 to 97 70 to 95 62 to 98 3200 1391057D-6939-PF .200535255 Bonding Co 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.05 to 42 0.05 to 29.7 0.06 to 37 to ZrC ZrC 60 to 97 32 to 96 65 to 96 37 to 95 70 to 95 42 to 93 3200 Re + Co Re 0.03 to 39.6 0.05 to 52 0.04 to 34.7 0.07 to 47 0.05 to 29.7 0.08 to 41 1400 Bonding Co 0.03 to 39.6 0.02 to 32 0.04 to 34.7 0.03 to 27 0.05 to 29.7 0.04 to 23 to HfC HfC 60 to 97 48 to 98 65 to 96 53 to 97 70 to 95 59 to 96 3200 Re + Co Re 0.03 to 39.6 0.11 to 71 0.14 to 67 0.15 to 67.0 0.17 to 62 0.19 to 62 1400 Bonding Co 0.03 to 39.6 0.05 to 51 0.13 to 65 0.06 to 46 0.15 to 60 0.07 to 41 to VC VC 60 to 97 28 to 95 33 to 87 33 to 94 70 to 95 38 to 92 2900 Re + Co Re 0.03 to 39.6 0.08 to 64 0.04 to 34.7 0.1 to 59 0.05 to 29.7 0.13 to 53 1400 Bonding Co 0.03 to 39.6 0.03 to 43 0.04 to 34.7 0.04 to 38 0.05 to 29.7 0.05 to 33 to NbC NbC 60 to 97 36 to 97 65 to 96 41 to 95 70 to 95 47 to 94 3200 Re H- Co Re 0.03 to 39.6 0.04 to 49 0.04 to 34.7 0.06 to 43 0.05 to 29.7 0.07 to 38 1400 Bonding Co 0.03 to 39.6 0.02 to 29 0.04 to 34.7 0.024 to 25 0.05 to 29.7 0.03 to 21 to TaC TaC 60 to 97 51 to 98 65 to 96 56 to 97 70 to 95 62 to 97 3200 1 Re + Co Re 0.03 to 39.6 0.09 to 67 0.04 to 34.7 0.12 to 62 0.05 to 29.7 0.15 to 57 1400 Bonding Co 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.05 to 41 0.05 to 29.7 0.06 to 36 to Cr2C3 Cr2〇3 60 to 97 32 to 96 65 to 96 37 to 95 70 to 95 43 to 93 1900 Re + Co Re 0.03 to 39.6 0.07 to 60 0.04 to 34.7 0.09 to 55 0.05 to 29.7 0.11 to 49 1400 Bonding Co 0.03 to 39.6 0.03 to 39 0.04 to 34.7 0.04 to 34 0.05 to 29.7 0.05 to 29 to Mo2C Mo2C 60 to 97 40 to 97 65 to 96 45 to 96 70 to 95 50 to 95 2600 Re + Co Re 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.05 to 42 0.05 to 29.7 0.07 to 36 1400 Bonding Co 0.03 to 39.6 0.017 to 27 0.04 to 34.7 0.023 to 23 0.05 to 29.7 0.028 to 20 to WC WC 60 to 97 53 to 96 65 to 96 58 to 95 70 to 95 63 to 94 2900 Re + Co Re 0.03 to 39.6 0.11 to 71 0.04 to 34.7 0.15 to 67 0.05 to 29.7 0.19 to 62 1400 Bonding Co 0.03 to 39.6 0.05 to 5 2 0.04 to 34.7 0.06 to 46 0.05 to 29.7 0.07 to 41 to TiN TiN 60 to 97 28 to 95 65 to 96 33 to 93 70 to 95 38 to 92 3200 Re + Co Re 0.03 to 39.6 0.08 to 65 0.04 to 34.7 0.11 to 60 0.05 to 29.7 0.14 to 55 1400 ^ Cohesion Co 0.03 to 39.6 0.04 to 44 0.04 to 34.7 0.05 to 39 0.05 to 29.7 0.06 to 34 to ZrN ZrN 60 to 97 34 to 96 65 to 96 39 to 95 70 to 95 45 to 94 3200 Re + Co Re 0.03 to 39.6 0.05 to 50 0.04 to 34.7 0.06 to 45 0.05 to 29.7 0.08 to 39 1400 Bonding Co 0.03 to 39.6 0.019 to 30 0.04 to 34.7 0.026 to 26 0.05 to 29.7 0.032 to 22 to HfN HfN 60 to 97 50 to 98 65 to 96 55 to 97 70 to 95 61 to 97 3200 Re + Co Re 0.03 to 39.6 0.1 to 70 0.04 to 34.7 0.14 to 65 0.05 to 29.7 0.17 to 60 1400 Bonding Co 0.03 to 39.6 0.04 to 49 0.04 to 34.7 0.05 to 44 0.05 to 29.7 0.07 to 39 to VN VN 60 to 97 30 to 96 65 to 96 35 to 94 70 to 95 40 to 93 2300 Re + Co Re 0.03 to 39.6 0.08 to 65 0.04 to 34.7 0.11 to 60 0.05 to 29.7 0.14 to 55 1400 Bonding Co 0.03 to 39.6 0.04 to 45 0.04 to 34.7 0.05 to 39 0 .05 to 29.7 0.06 to 34 to NbN NbN 60 to 97 34 to 96 65 to 96 39 to 95 70 to 95 45 to 94 2500 Re + Co. Re 0.03 to 39.6 0.04 to 49 0.04 to 34.7 0.06 to 44 0.05 to 29.7 0.07 to 38 1400 Bonding Co 0.03 to 39.6 0.02 to 29 0.04 to 34.7 0.025 to 25 0.05 to 29.7 0.03 to 21 to TaN TaN 60 to 97 51 to 98 65 to 96 56 to 97 70 to 95 62 to 98 3200 139

1057D-6939-PF 200535255 表48 Re及C〇(Re+C〇)黏結由元素週期表中IVb、Vb及VIb族元素所形成的硼化物或由元素週期表中IVb及Vb族元素所形成的矽化物，其中黏結劑組成範圍由l%Re+99%Co 至 99%Re+l%Co 組成範圍1 組成範圍2 組成範圍3 估算熔點 Volume % Weight % Volume % Weight % Volume % Weight % °C Re +Co Re 0.03 to 39.6 0.13 to 75 0.04 to 34.7 0.18 to 71 0.05 to 29.7 0.22 to 66 1400 黏結 Co 0.03 to 39.6 0.05 to 56 0.04 to 34.7 0.07 to 51 0.05 to 29.7 0.08 to 45 to TiB2 TiB2 60 to 97 24 to 34 65 to 96 29 to 92 70 to 95 34 to 90 3100 Re + Co Re 0.03 to 39.6 0.1 to 69 0.04 to 34.7 0.13 to 64 0.05 to 29.7 0.17 to 59 1400 黏結 Co 0.03 to 39.6 0.04 to 49 0.05 to 34.7 0.05 to 44 0.05 to 29.7 0.07 to 38 to ZrB2 ZrB2 60 to 97 30 to 96 65 to 96 35 to 94 70 to 95 40 to 93 3100 Re +Co Re 0.03 to 39.6 0.06 to 55 0.04 to 34.7 0.08 to 50 0.05 to 29.7 0.09 to 44 1400 黏結 Co 0.03 to 39.6 0.2 to 34 0.04 to 34.7 0.03 to 30 0.05 to 29.7 0.04 to 25 to ψ HfB2 HfB2 60 to 97 45 to 98 65 to 96 50〇97 70 to 95 56 to 96 3200 Re +Co Re 0.03 to 39.6 0.12 to 73 0.14 to 67 0.16 to 69 0.17 to 62 0.2 to 63 1400 黏結 Co 0.03 to 39.6 0.05 to 53 0.13 to 65 0.06 to 48 0.15 to 60 0.08 to 42 to vb2 vb2 60 to 97 27 to 95 33 to 87 31 to 93 70 to 95 36 to 91 2200 Re + Co Re 0.03 to 39.6 0.09 to 66 0.04 to 34.7 0.12 to 61 0.05 to 29.7 0.14 to 55 1400 黏結 Co 0.03 to 39.6 0.04 to 45 0.04 to 34.7 0.05 to 40 0.05 to 29.7 0.06 to 34 to NbB2 NbB2 60 to 97 34 to 96 65 to 96 39 to 95 70 to 95 45 to 94 3100 Re + Co Re 0.03 to 39.6 0.05 to 52 0.04 to 34.7 0.07 to 47 0.05 to 29.7 0.08 to 41 1400 黏結 Co 0.03 to 39.6 0.02 to 32 0.04 to 34.7 0.03 to 27 0.05 to 29.7 0.035 to 23 to TaB2 TaB2 60 to 97 48 to 98 65 to 96 53 to 97 70 to 95 58 to 96 3300 Re + Co Re 0.03 to 39.6 0.1 to 69 0.04 to 34.7 0.13 to 65 0.05 to 29.7 0.17 to 59 1400 黏結 Co 0.03 to 39.6 0.04 to 49 0.04 to 34.7 0.05 to 44 0.05 to 29.7 0.07 to 38 to Cr3B2 60 to 97 30 to 96 65 to 96 35 to 93 70 to 95 41 to 93 2100 ^Re +Co Re 0.03 to 39.6 0.08 to 64 0.04 to 34.7 0.1 to 59 0.05 to 29.7 0.13 to 53 1400 丨酽黏結 Co 0.03 to 39.6 0.03 to 43 0.04 to 34.7 0.04 to 38 0.05 to 29.7 0.05 to 33 to MoB2 MoB2 60 to 97 36 to 97 65 to 96 41 to 95 70 to 95 46 to 94 2200 Re + Co Re 0.03 to 39.6 0.04 to 46 0.04 to 34.7 0.05 to 41 0.05 to 29.7 0.07 to 36 1400 黏結 Co 0.03 to 39.6 0.017 to 27 0.04 to 34.7 0.022 to 23 0.05 to 29.7 0.028 to 19 to WB WB 60 to 97 53 to 98 65 to 96 59 to 98 70 to 95 64 to 97 2900 Re + Co Re 0.03 to 39.6 0.04 to 45 0.04 to 34.7 0.05 to 40 0.05 to 29.7 0.06 to 35 1400 黏結 Co 0.03 to 39.6 0.016 to 26 0.04 to 34.7 0.021 to 22 0.05 to 29.7 0.027 to 19 to W2B W2B 60 to 97 55 to 98 65 to 96 60 to 98 70 to 95 65 to 97 2900 Re +Co Re 0.03 to 39.6 0.14 to 76 0.04 to 34.7 0.18 to 72 0.05 to 29.7 0.23 to 67 1400 黏結 Co 0.03 to 39.6 0.06 to 57 0.04 to 34.7 0.07 to 52 0.05 to 29.7 0.09 to 47 to Ti5Si3 Ti5Si3 60 to 97 24 to 94 65 to 96 28 to 92 70 to 95 32 to 90 2200 Re + Co Re 0.03 to 39.6 0.11 to 71 0.04 to 34.7 0.15 to 67 0.05 to 29.7 0.19 to 62 1400 黏結 Co 0.03 to 39.6 0.05 to 51 0.04 to 34.7 0.06 to 46 0.05 to 29.7 0.07 to 41 to Zr6Si5 ZrN 60 to 97 28 to 95 65 to 96 33 to 94 70 to 95 38 to 92 2400 1401057D-6939-PF 200535255 Table 48 Re and C〇 (Re + C〇) bonding Boride formed by elements of Group IVb, Vb and VIb in the periodic table or formed by elements of Group IVb and Vb of the periodic table Silicide, where the composition of the binder ranges from 1% Re + 99% Co to 99% Re + l% Co Composition range 1 Composition range 2 Composition range 3 Estimated melting point Volume% Weight% Volume% Weight% Volume% Weight% ° C Re + Co Re 0.03 to 39.6 0.13 to 75 0.04 to 34.7 0.18 to 71 0.05 to 29.7 0.22 to 66 1400 Bonding Co 0.03 to 39.6 0.05 to 56 0.04 to 34.7 0.07 to 51 0.05 to 29.7 0.08 to 45 to TiB2 TiB2 60 to 97 24 to 34 65 to 96 29 to 92 70 to 95 34 to 90 3100 Re + Co Re 0.03 to 39.6 0.1 to 69 0.04 to 34.7 0.13 to 64 0.05 to 29.7 0.17 to 59 1400 Bonding Co 0.03 to 39.6 0.04 to 49 0.05 to 34.7 0.05 to 44 0.05 to 29.7 0.07 to 38 to ZrB2 ZrB2 60 to 97 30 to 96 65 to 96 35 to 94 70 to 95 40 to 93 3100 Re + Co Re 0.03 to 39.6 0.06 to 55 0.04 to 34.7 0.08 to 50 0.05 to 29.7 0.09 to 44 1400 Bonding Co 0.03 to 39.6 0.2 to 34 0.04 to 34.7 0.03 to 30 0.05 to 2 9.7 0.04 to 25 to ψ HfB2 HfB2 60 to 97 45 to 98 65 to 96 50〇97 70 to 95 56 to 96 3200 Re + Co Re 0.03 to 39.6 0.12 to 73 0.14 to 67 0.16 to 69 0.17 to 62 0.2 to 63 1400 Bonding Co 0.03 to 39.6 0.05 to 53 0.13 to 65 0.06 to 48 0.15 to 60 0.08 to 42 to vb2 vb2 60 to 97 27 to 95 33 to 87 31 to 93 70 to 95 36 to 91 2200 Re + Co Re 0.03 to 39.6 0.09 to 66 0.04 to 34.7 0.12 to 61 0.05 to 29.7 0.14 to 55 1400 Bonding Co 0.03 to 39.6 0.04 to 45 0.04 to 34.7 0.05 to 40 0.05 to 29.7 0.06 to 34 to NbB2 NbB2 60 to 97 34 to 96 65 to 96 39 to 95 70 to 95 45 to 94 3100 Re + Co Re 0.03 to 39.6 0.05 to 52 0.04 to 34.7 0.07 to 47 0.05 to 29.7 0.08 to 41 1400 Bonding Co 0.03 to 39.6 0.02 to 32 0.04 to 34.7 0.03 to 27 0.05 to 29.7 0.035 to 23 to TaB2 TaB2 60 to 97 48 to 98 65 to 96 53 to 97 70 to 95 58 to 96 3300 Re + Co Re 0.03 to 39.6 0.1 to 69 0.04 to 34.7 0.13 to 65 0.05 to 29.7 0.17 to 59 1400 Bonding Co 0.03 to 39.6 0.04 to 49 0.04 to 34.7 0.05 to 44 0.05 to 29.7 0.07 to 38 to Cr3B2 60 t o 97 30 to 96 65 to 96 35 to 93 70 to 95 41 to 93 2100 ^ Re + Co Re 0.03 to 39.6 0.08 to 64 0.04 to 34.7 0.1 to 59 0.05 to 29.7 0.13 to 53 1400 丨 Cohesive Co 0.03 to 39.6 0.03 to 43 0.04 to 34.7 0.04 to 38 0.05 to 29.7 0.05 to 33 to MoB2 MoB2 60 to 97 36 to 97 65 to 96 41 to 95 70 to 95 46 to 94 2200 Re + Co Re 0.03 to 39.6 0.04 to 46 0.04 to 34.7 0.05 to 41 0.05 to 29.7 0.07 to 36 1400 Bonding Co 0.03 to 39.6 0.017 to 27 0.04 to 34.7 0.022 to 23 0.05 to 29.7 0.028 to 19 to WB WB 60 to 97 53 to 98 65 to 96 59 to 98 70 to 95 64 to 97 2900 Re + Co Re 0.03 to 39.6 0.04 to 45 0.04 to 34.7 0.05 to 40 0.05 to 29.7 0.06 to 35 1400 Bonding Co 0.03 to 39.6 0.016 to 26 0.04 to 34.7 0.021 to 22 0.05 to 29.7 0.027 to 19 to W2B W2B 60 to 97 55 to 98 65 to 96 60 to 98 70 to 95 65 to 97 2900 Re + Co Re 0.03 to 39.6 0.14 to 76 0.04 to 34.7 0.18 to 72 0.05 to 29.7 0.23 to 67 1400 Bonding Co 0.03 to 39.6 0.06 to 57 0.04 to 34.7 0.07 to 52 0.05 to 29.7 0.09 to 47 to Ti5Si3 Ti5Si3 60 to 97 24 to 9 4 65 to 96 28 to 92 70 to 95 32 to 90 2200 Re + Co Re 0.03 to 39.6 0.11 to 71 0.04 to 34.7 0.15 to 67 0.05 to 29.7 0.19 to 62 1400 Bonding Co 0.03 to 39.6 0.05 to 51 0.04 to 34.7 0.06 to 46 0.05 to 29.7 0.07 to 41 to Zr6Si5 ZrN 60 to 97 28 to 95 65 to 96 33 to 94 70 to 95 38 to 92 2400 140

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Re + Co Re 0.03 to 39.6 0.1 to 69 0.04 to 34.7 0.13 to 64 0.05 to 29.7 0.16 to 58 1400 黏結 Co 0.03 to 39.6 0.04 to 48 0.04 to 34.7 0.05 to 43 0.05 to 29.7 0.06 to 37 to NbSi2 NbSi2 60 to 97 31 to 96 65 to 96 36 to 94 70 to 95 41 to 93 2100 Re + Co Re 0.03 to 39.6 0.07 to 62 0.04 to 34.7 0.1 to 57 0.05 to 29.7 0.12 to 51 1400 黏結 Co 0.03 to 39.6 0.03 to 41 0.04 to 34.7 0.04 to 36 0.05 to 29.7 0.05 to 31 to TaSi2 TaSi2 60 to 97 38 to 97 65 to 96 43 to 96 70 to 95 49 to 95 2500 Re + Co Re 0.03 to 39.6 0.1 to 69 0.04 to 34.7 0.13 to 64 0.05 to 29.7 0.16 to 59 1400 黏結 Co 0.03 to 39.6 0.04 to 48 0.04 to 34.7 0.05 to 43 0.05 to 29.7 0.07 to 38 to MoSi2 MoSi2 60 to 97 31 to 96 65 to 96 36 to 94 70 to 95 41 to 93 2100 Re +Co Re 0.03 to 39.6 0.07 to 60 0.04 to 34.7 0.09 to 55 0.05 to 29.7 0.11 to 49 1400 黏結 Co 0.03 to 39.6 0.03 to 39 0.04 to 34.7 0.04 to 34 0.05 to 29.7 0.046 to 29 to WSi2 WSi2 60 to 97 40 to 97 65 to 96 45 to 96 70 to 95 51 to 95 2100Re + Co Re 0.03 to 39.6 0.1 to 69 0.04 to 34.7 0.13 to 64 0.05 to 29.7 0.16 to 58 1400 Bonding Co 0.03 to 39.6 0.04 to 48 0.04 to 34.7 0.05 to 43 0.05 to 29.7 0.06 to 37 to NbSi2 NbSi2 60 to 97 31 to 96 65 to 96 36 to 94 70 to 95 41 to 93 2100 Re + Co Re 0.03 to 39.6 0.07 to 62 0.04 to 34.7 0.1 to 57 0.05 to 29.7 0.12 to 51 1400 Bonding Co 0.03 to 39.6 0.03 to 41 0.04 to 34.7 0.04 to 36 0.05 to 29.7 0.05 to 31 to TaSi2 TaSi2 60 to 97 38 to 97 65 to 96 43 to 96 70 to 95 49 to 95 2500 Re + Co Re 0.03 to 39.6 0.1 to 69 0.04 to 34.7 0.13 to 64 0.05 to 29.7 0.16 to 59 1400 Bonding Co 0.03 to 39.6 0.04 to 48 0.04 to 34.7 0.05 to 43 0.05 to 29.7 0.07 to 38 to MoSi2 MoSi2 60 to 97 31 to 96 65 to 96 36 to 94 70 to 95 41 to 93 2100 Re + Co Re 0.03 to 39.6 0.07 to 60 0.04 to 34.7 0.09 to 55 0.05 to 29.7 0.11 to 49 1400 Bonding Co 0.03 to 39.6 0.03 to 39 0.04 to 34.7 0.04 to 34 0.05 to 29.7 0.046 to 29 to WSi2 WSi2 60 to 97 40 to 97 65 to 96 45 to 96 70 to 95 51 to 95 2100

表49 Re及Mo(Re+Mo)黏結由元素週期表中IVb、Vb及VIb族元素所形成的碳化物，其中黏結劑組成範圍由l%Re+99%Mo至99%Re+l%Mo 組成範圍1 組成範圍2 組成範圍3 估算熔點體積％重量％體積％重量％體積0/〇重量％ °C Re +Mo Re 0.03 to 39.6 0.12 to 74 0.04 to 34.7 0.16 to 69 0.05 to 29.7 0.2 to 64 2600 黏結 Mo 0.03 to 39.6 0.06 to 57 0.04 to 34.7 0.07 to 52 0.05 to 29.7 0.09 to 46 to TiC TiC 60 to 97 26 to 94 65 to 96 30 to 92 70 to 95 35 to 90 3200 Re +Mo Re 0.03 to 39.6 0.09 to 68 0.04 to 34.7 0.13 to 63 0.05 to 29.7 0.16 to 57 2600 黏結 Mo 0.03 to 39.6 0.04 to 50 0.04 to 34.7 0.06 to 45 0.05 to 29.7 0.07 to 39 to ZrC ZrC 60 to 97 32 to 95 65 to 96 37 to 94 70 to 95 42 to 92 3200 Re +Mo Re 0.03 to 39.6 0.05 to 52 0.04 to 34.7 0.07 to 47 0.05 to 29.7 0.08 to 41 2600 黏結 Mo 0.03 to 39.6 0.02 to 34 0.04 to 34.7 0.03 to 30 0.05 to 29.7 0.04 to 25 to HfC HfC 60 to 97 48 to 98 65 to 96 53 to 97 70 to 95 59 to 96 3200 +Mo Re 0.03 to 39.6 0.11 to 71 0.14 to 67 0.15 to 67.0 0.17 to 62 0.18 to 62 2600 ，黏結 Mo 0.03 to 39.6 0.05 to 55 0.13 to 65 0.07 to 49 0.15 to 60 0.08 to 44 to VC VC 60 to 97 28 to 95 33 to 87 33 to 93 70 to 95 38 to 91 2900 Re + Mo Re 0.03 to 39.6 0.08 to 64 0.04 to 34.7 0.1 to 59 0.05 to 29.7 0.13 to 53 2600 黏結 Mo 0.03 to 39.6 0.04 to 46 0.04 to 34.7 0.05 to 41 0.05 to 29.7 0.06 to 35 to NbC NbC 60 to 97 36 to 96 65 to 96 41 to 95 70 to 95 47 to 94 3200 Re + Mo Re 0.03 to 39.6 0.04 to 49 0.04 to 34.7 0.06 to 43 0.05 to 29.7 0.07 to 38 2600 黏結 Mo 0.03 to 39.6 0.02 to 31 0.04 to 34.7 0.028 to 27 0.05 to 29.7 0.03 to 22 to TaC TaC 60 to 97 51 to 98 65 to 96 56 to 97 70 to 95 62 to 96 3200 Re +Mo Re 0.03 to 39.6 0.09 to 67 0.04 to 34.7 0.12 to 62 0.05 to 29.7 0.15 to 57 1700 黏結 Mo 0.03 to 39.6 0.04 to 50 0.04 to 34.7 0.06 to 45 0.05 to 29.7 0.07 to 39 to Cr2C3 Cr2C3 60 to 97 32 to 95 65 to 96 37 to 94 70 to 95 43 to 92 1900 Re + Mo Re 0.03 to 39.6 0.07 to 60 0.04 to 34.7 0.09 to 55 0.05 to 29.7 0.11 to 49 2500 黏結 Mo 0.03 to 39.6 0.03 to 42 0.04 to 34.7 0.04 to 37 0.05 to 29.7 0.05 to 32 to Mo2C Mo2C 60 to 97 40 to 97 65 to 96 45 to 96 70 to 95 50 to 95 2600 141Table 49 Re and Mo (Re + Mo) bonding carbides formed from elements of Groups IVb, Vb, and VIb in the periodic table of elements, in which the binder composition ranges from 1% Re + 99% Mo to 99% Re + l% Mo Composition range 1 Composition range 2 Composition range 3 Estimated melting volume% by weight% by volume% by weight% by volume 0 / 〇% by weight ° C Re + Mo Re 0.03 to 39.6 0.12 to 74 0.04 to 34.7 0.16 to 69 0.05 to 29.7 0.2 to 64 2600 Bonding Mo 0.03 to 39.6 0.06 to 57 0.04 to 34.7 0.07 to 52 0.05 to 29.7 0.09 to 46 to TiC TiC 60 to 97 26 to 94 65 to 96 30 to 92 70 to 95 35 to 90 3200 Re + Mo Re 0.03 to 39.6 0.09 to 68 0.04 to 34.7 0.13 to 63 0.05 to 29.7 0.16 to 57 2600 Bonding Mo 0.03 to 39.6 0.04 to 50 0.04 to 34.7 0.06 to 45 0.05 to 29.7 0.07 to 39 to ZrC ZrC 60 to 97 32 to 95 65 to 96 37 to 94 70 to 95 42 to 92 3200 Re + Mo Re 0.03 to 39.6 0.05 to 52 0.04 to 34.7 0.07 to 47 0.05 to 29.7 0.08 to 41 2600 Bonding Mo 0.03 to 39.6 0.02 to 34 0.04 to 34.7 0.03 to 30 0.05 to 29.7 0.04 to 25 to HfC HfC 60 to 97 48 to 98 65 to 96 53 to 97 70 to 95 59 to 96 3200 + Mo Re 0.03 to 39.6 0.11 to 71 0.14 to 67 0.15 to 67.0 0.17 to 62 0.18 to 62 2600, bonding Mo 0.03 to 39.6 0.05 to 55 0.13 to 65 0.07 to 49 0.15 to 60 0.08 to 44 to VC VC 60 to 97 28 to 95 33 to 87 33 to 93 70 to 95 38 to 91 2900 Re + Mo Re 0.03 to 39.6 0.08 to 64 0.04 to 34.7 0.1 to 59 0.05 to 29.7 0.13 to 53 2600 Bonding Mo 0.03 to 39.6 0.04 to 46 0.04 to 34.7 0.05 to 41 0.05 to 29.7 0.06 to 35 to NbC NbC 60 to 97 36 to 96 65 to 96 41 to 95 70 to 95 47 to 94 3200 Re + Mo Re 0.03 to 39.6 0.04 to 49 0.04 to 34.7 0.06 to 43 0.05 to 29.7 0.07 to 38 2600 Bonding Mo 0.03 to 39.6 0.02 to 31 0.04 to 34.7 0.028 to 27 0.05 to 29.7 0.03 to 22 to TaC TaC 60 to 97 51 to 98 65 to 96 56 to 97 70 to 95 62 to 96 3200 Re + Mo Re 0.03 to 39.6 0.09 to 67 0.04 to 34.7 0.12 to 62 0.05 to 29.7 0.15 to 57 1700 Bonding Mo 0.03 to 39.6 0.04 to 50 0.04 to 34.7 0.06 to 45 0.05 to 29.7 0.07 to 39 to Cr2C3 Cr2C3 60 to 97 32 to 95 65 to 96 37 to 94 70 to 95 43 to 92 1900 Re + Mo Re 0.03 to 39.6 0.07 to 60 0.04 to 34.7 0.09 to 55 0.05 to 29.7 0.11 to 49 2500 Bonding Mo 0.03 to 39.6 0.03 to 42 0.04 to 34.7 0.04 to 37 0.05 to 29.7 0.05 to 32 to Mo2C Mo2C 60 to 97 40 to 97 65 to 96 45 to 96 70 to 95 50 to 95 2600 141

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Re + Mo Re 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.05 to 42 0.05 to 29.7 0.07 to 36 2600 黏結 Mo 0.03 to 39.6 0.019 to 30 0.04 to 34.7 0.026 to 26 0.05 to 29.7 0.032 to 22 to WC WC 60 to 97 53 to 98 65 to 96 58 to 97 70 to 95 64 to 97 2900 表50 Re及Ni(Re+Ni)黏結由元素週期表中IVb、Vb及VIb族元素所形成的碳化物，其中黏結劑組成範圍由l%Re+99%Ni至99%Re+l%Ni 組成範圍1 組成範圍2 組成範圍3 估算熔點體積％重量％體積％重量％體積％重量％ °C Re+Ni Re 0.03 to 39.6 0.12 to 74 0.04 to 34.7 0.17 to 69 0.05 to 29.7 0.2 to 64 1400 黏結 Ni 0.03 to 39.6 0.05 to 54 0.04 to 34.7 0.06 to 49 0.05 to 29.7 0.08 to 43 to TiC TiC 60 to 97 26 to 95 65 to 96 30 to 93 70 to 95 35 to 91 3200 Re+Ni Re 0.03 to 39.6 0.09 to 68 0.04 to 34.7 0.13 to 63 0.05 to 29.7 0.16 to 57 1400 黏結 Ni 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.05 to 42 0.05 to 29.7 0.06 to 36 to ψ ZrC ZrC 60 to 97 32 to 96 65 to 96 37 to 95 70 to 95 42 to 93 3200 Re+Ni Re 0.03 to 39.6 0.05 to 52 0.04 to 34.7 0.07 to 47 0.05 to 29.7 0.08 to 41 1400 黏結 Co 0.03 to 39.6 0.02 to 31 0.04 to 34.7 0.027 to 27 0.05 to 29.7 0.034 to 23 to HfC HfC 60 to 97 48 to 98 65 to 96 53 to 97 70 to 95 59 to 96 3200 Re+Ni Re 0.03 to 39.6 0.11 to 71 0.14 to 67 0.15 to 67.0 0.17 to 62 0.19 to 62 1400 黏結 Ni 0.03 to 39.6 0.04 to 51 0.13 to 65 0.06 to 46 0.15 to 60 0.07 to 40 to VC VC 60 to 97 28 to 95 33 to 87 33 to 94 70 to 95 38 to 92 2900 Re + Ni Re 0.03 to 39.6 0.08 to 64 0.04 to 34.7 0.1 to 59 0.05 to 29.7 0.13 to 53 1400 黏結 Ni 0.03 to 39.6 0.03 to 43 0.04 to 34.7 0.04 to 37 0.05 to 29.7 0.05 to 32 to NbC NbC 60 to 97 36 to 97 65 to 96 41 to 95 70 to 95 47 to 94 3200 Re + Ni Re 0.03 to 39.6 0.04 to 49 0.04 to 34.7 0.06 to 43 0.05 to 29.7 0.07 to 38 1400 黏結 Ni 0.03 to 39.6 0.018 to 29 0.04 to 34.7 0.024 to 25 0.05 to 29.7 0.03 to 21 to TaC TaC 60 to 97 51 to 98 65 to 96 56 to 97 70 to 95 62 to 97 3200 W Re+Ni Re 0.03 to 39.6 0.09 to 67 0.04 to 34.7 0.12 to 62 0.05 to 29.7 0.15 to 57 1400 ，黏結 Ni 0.03 to 39.6 0.04 to 46 0.04 to 34.7 0.05 to 41 0.05 to 29.7 0.06 to 36 to Cr2C3 Cr2C3 60 to 97 32 to 96 65 to 96 37 to 95 70 to 95 43 to 93 1900 Re + Ni Re 0.03 to 39.6 0.07 to 60 0.04 to 34.7 0.09 to 55 0.05 to 29.7 0.11 to 49 1400 黏結 Ni 0.03 to 39.6 0.03 to 39 0.04 to 34.7 0.04 to 34 0.05 to 29.7 0.05 to 29 to Mo2C Mo2C 60 to 97 40 to 97 65 to 96 45 to 96 70 to 95 50 to 95 2600 Re + Ni Re 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.06 to 42 0.05 to 29.7 0.07 to 36 1400 黏結 Ni 0.03 to 39.6 0.017 to 27 0.04 to 34.7 0.022 to 23 0.05 to 29.7 0.028 to 19 to WC WC 60 to 97 53 to 98 65 to 96 58 to 98 70 to 95 64 to 97 2900 表51 Re及Cr(Re+Cr)黏結由元素週期表中IVb、Vb及VIb族元素所形成的碳化物，其中黏結劑組成範圍由l%Re+99%Cr至99%Re+l%CrRe + Mo Re 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.05 to 42 0.05 to 29.7 0.07 to 36 2600 Bonding Mo 0.03 to 39.6 0.019 to 30 0.04 to 34.7 0.026 to 26 0.05 to 29.7 0.032 to 22 to WC WC 60 to 97 53 to 98 65 to 96 58 to 97 70 to 95 64 to 97 2900 Table 50 Re and Ni (Re + Ni) bonding formed by carbides of Group IVb, Vb, and VIb elements in the periodic table of elements, in which the range of binder composition is l% Re + 99% Ni to 99% Re + l% Ni Composition range 1 Composition range 2 Composition range 3 Estimated melting point volume% weight% volume% weight% volume% weight% ° C Re + Ni Re 0.03 to 39.6 0.12 to 74 0.04 to 34.7 0.17 to 69 0.05 to 29.7 0.2 to 64 1400 Bonding Ni 0.03 to 39.6 0.05 to 54 0.04 to 34.7 0.06 to 49 0.05 to 29.7 0.08 to 43 to TiC TiC 60 to 97 26 to 95 65 to 96 30 to 93 70 to 95 35 to 91 3200 Re + Ni Re 0.03 to 39.6 0.09 to 68 0.04 to 34.7 0.13 to 63 0.05 to 29.7 0.16 to 57 1400 Bonded Ni 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.05 to 42 0.05 to 29.7 0.06 to 36 to ψ ZrC ZrC 60 to 97 32 to 96 65 to 96 37 to 95 70 to 95 42 to 93 3200 R e + Ni Re 0.03 to 39.6 0.05 to 52 0.04 to 34.7 0.07 to 47 0.05 to 29.7 0.08 to 41 1400 Bonding Co 0.03 to 39.6 0.02 to 31 0.04 to 34.7 0.027 to 27 0.05 to 29.7 0.034 to 23 to HfC HfC 60 to 97 48 to 98 65 to 96 53 to 97 70 to 95 59 to 96 3200 Re + Ni Re 0.03 to 39.6 0.11 to 71 0.14 to 67 0.15 to 67.0 0.17 to 62 0.19 to 62 1400 Bonded Ni 0.03 to 39.6 0.04 to 51 0.13 to 65 0.06 to 46 0.15 to 60 0.07 to 40 to VC VC 60 to 97 28 to 95 33 to 87 33 to 94 70 to 95 38 to 92 2900 Re + Ni Re 0.03 to 39.6 0.08 to 64 0.04 to 34.7 0.1 to 59 0.05 to 29.7 0.13 to 53 1400 Bonding Ni 0.03 to 39.6 0.03 to 43 0.04 to 34.7 0.04 to 37 0.05 to 29.7 0.05 to 32 to NbC NbC 60 to 97 36 to 97 65 to 96 41 to 95 70 to 95 47 to 94 3200 Re + Ni Re 0.03 to 39.6 0.04 to 49 0.04 to 34.7 0.06 to 43 0.05 to 29.7 0.07 to 38 1400 Bonded Ni 0.03 to 39.6 0.018 to 29 0.04 to 34.7 0.024 to 25 0.05 to 29.7 0.03 to 21 to TaC TaC 60 to 97 51 to 98 65 to 96 56 to 97 70 to 95 62 to 97 3200 W Re + Ni Re 0.03 to 39.6 0.09 to 67 0.0 4 to 34.7 0.12 to 62 0.05 to 29.7 0.15 to 57 1400, bonding Ni 0.03 to 39.6 0.04 to 46 0.04 to 34.7 0.05 to 41 0.05 to 29.7 0.06 to 36 to Cr2C3 Cr2C3 60 to 97 32 to 96 65 to 96 37 to 95 70 to 95 43 to 93 1900 Re + Ni Re 0.03 to 39.6 0.07 to 60 0.04 to 34.7 0.09 to 55 0.05 to 29.7 0.11 to 49 1400 Bonded Ni 0.03 to 39.6 0.03 to 39 0.04 to 34.7 0.04 to 34 0.05 to 29.7 0.05 to 29 to Mo2C Mo2C 60 to 97 40 to 97 65 to 96 45 to 96 70 to 95 50 to 95 2600 Re + Ni Re 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.06 to 42 0.05 to 29.7 0.07 to 36 1400 Bonding Ni 0.03 to 39.6 0.017 to 27 0.04 to 34.7 0.022 to 23 0.05 to 29.7 0.028 to 19 to WC WC 60 to 97 53 to 98 65 to 96 58 to 98 70 to 95 64 to 97 2900 Table 51 Re and Cr (Re + Cr) bonding by element cycle The carbides formed by Group IVb, Vb and VIb elements in the table. The binder composition ranges from 1% Re + 99% Cr to 99% Re + l% Cr.

組成範圍1 組成範圍2 組成範圍3 估算熔點體積％重量％體積％重量％體積％重量％ °C 142Composition range 1 Composition range 2 Composition range 3 Estimated melting point% by volume% by weight% by weight %% by weight %% by weight ° C 142

1057D-6939-PF *2005352551057D-6939-PF * 200535255

Re +Cr Re 0.03 to 39.6 0.13 to 74 0.04 to 34.7 0.17 to 69 0.05 to 29.7 0.2 to 64 1800 黏結 Cr 0.03 to 39.6 0.04 to 48 0.04 to 34.7 0.05 to 43 0.05 to 29.7 0.06 to 39 to TiC TiC 60 to 97 26 to 96 65 to 96 30 to 94 70 to 95 36 to 93 3200 Re +Cr Re 0.03 to 39.6 0.1 to 68 0.04 to 34.7 0.13 to 63 0.05 to 29.7 0.16 to 57 1800 黏結 Cr 0.03 to 39.6 0.03 to 41 0.04 to 34.7 0.04 to 36 0.05 to 29.7 0.05 to 32 to ZrC ZrC 60 to 97 32 to 97 65 to 96 37 to 95 70 to 95 42 to 94 3200 Re +Cr Re 0.03 to 39.6 0.05 to 52 0.04 to 34.7 0.07 to 47 0.05 to 29.7 0.09 to 41 1800 黏結 Cr 0.03 to 39.6 0.017 to 27 0.04 to 34.7 0.022 to 23 0.05 to 29.7 0.027 to 19 to HfC HfC 60 to 97 48 to 98 65 to 96 53 to 98 70 to 95 59 to 97 3200 Re +Cr Re 0.03 to 39.6 0.11 to 71 0.14 to 67 0.15 to 67.0 0.17 to 62 0.19 to 62 1800 黏結 Cr 0.03 to 39.6 0.04 to 46 0.13 to 65 0.05 to 41 0.15 to 60 0.06 to 35 to VC VC 60 to 97 28 to 96 33 to 87 33 to 95 70 to 95 38 to 93 2900 Re + Cr Re 0.03 to 39.6 0.08 to 64 0.04 to 34.7 0.1 to 59 0.05 to 29.7 0.13 to 53 1800 黏結 Cr 0.03 to 39.6 0.026 to 37 0.04 to 34.7 0.034 to 33 0.05 to 29.7 0.04 to 28 to m NbC NbC 60 to 97 36 to 97 65 to 96 41 to 96 70 to 95 47 to 95 3200 Re + Cr Re 0.03 to 39.6 0.04 to 49 0.04 to 34.7 0.06 to 43 0.05 to 29.7 0.07 to 38 1800 黏結 Cr 0.03 to 39.6 0.015 to 25 0.04 to 34.7 0.019 to 21 0.05 to 29.7 0.024 to 17 to TaC TaC 60 to 97 51 to 98 65 to 96 56 to 98 70 to 95 62 to 97 3200 Re +Cr Re 0.03 to 39.6 0.09 to 67 0.04 to 34.7 0.12 to 62 0.05 to 29.7 0.16 to 57 1800 黏結 Cr 0.03 to 39.6 0.03 to 41 0.04 to 34.7 0.04 to 36 0.05 to 29.7 0.05 to 31 to Cr2C3 Cr2C3 60 to 97 32 to 97 65 to 96 37 to 96 70 to 95 43 to 95 1900 Re + Cr Re 0.03 to 39.6 0.07 to 60 0.04 to 34.7 0.09 to 55 0.05 to 29.7 0.11 to 49 1800 黏結 Cr 0.03 to 39.6 0.023 to 34 0.04 to 34.7 0.03 to 29 0.05 to 29.7 0.037 to 25 to Mo2C Mo2C 60 to 97 40 to 98 65 to 96 45 to 97 70 to 95 50 to 96 2600 Re + Cr Re 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.05 to 42 0.05 to 29.7 0.07 to 36 1800 黏結 Cr 0.03 to 39.6 0.014 to 23 0.04 to 34.7 0.018 to 20 0.05 to 29.7 0.023 to 16 to WC WC 60 to 97 53 to 98.6 65 to 96 58 to 98 70 to 95 64 to 97.6 2900 具面，例如用於含有由元件可入物被硬金屬具、切有上述組成之硬金屬或陶瓷金屬可以應用在很多方如，可應用於用來除去目標物材質的耐磨元件，例切削工具、磨輪、鑽具中的财磨元件。該工具可以其他不同材料製成的支撐元件，例如鋼。這些耐磨以鑲於支撐元件中。該工具可以設計成包含多種嵌鑲於支撐元件中。例如許多礦業用的鑽具包含許多材料所構成之小釦子。當然可應用的工具包括鑽削工具、磨具、刀具、鋸子等等各式各樣的需要耐 143Re + Cr Re 0.03 to 39.6 0.13 to 74 0.04 to 34.7 0.17 to 69 0.05 to 29.7 0.2 to 64 1800 Bonded Cr 0.03 to 39.6 0.04 to 48 0.04 to 34.7 0.05 to 43 0.05 to 29.7 0.06 to 39 to TiC TiC 60 to 97 26 to 96 65 to 96 30 to 94 70 to 95 36 to 93 3200 Re + Cr Re 0.03 to 39.6 0.1 to 68 0.04 to 34.7 0.13 to 63 0.05 to 29.7 0.16 to 57 1800 Bonded Cr 0.03 to 39.6 0.03 to 41 0.04 to 34.7 0.04 to 36 0.05 to 29.7 0.05 to 32 to ZrC ZrC 60 to 97 32 to 97 65 to 96 37 to 95 70 to 95 42 to 94 3200 Re + Cr Re 0.03 to 39.6 0.05 to 52 0.04 to 34.7 0.07 to 47 0.05 to 29.7 0.09 to 41 1800 Bonded Cr 0.03 to 39.6 0.017 to 27 0.04 to 34.7 0.022 to 23 0.05 to 29.7 0.027 to 19 to HfC HfC 60 to 97 48 to 98 65 to 96 53 to 98 70 to 95 59 to 97 3200 Re + Cr Re 0.03 to 39.6 0.11 to 71 0.14 to 67 0.15 to 67.0 0.17 to 62 0.19 to 62 1800 Bonded Cr 0.03 to 39.6 0.04 to 46 0.13 to 65 0.05 to 41 0.15 to 60 0.06 to 35 to VC VC 60 to 97 28 to 96 33 to 87 33 to 95 70 to 95 38 to 93 2900 Re + Cr Re 0.03 to 39.6 0.08 to 64 0.04 to 34.7 0.1 to 59 0.05 to 29.7 0.13 to 53 1800 Bonded Cr 0.03 to 39.6 0.026 to 37 0.04 to 34.7 0.034 to 33 0.05 to 29.7 0.04 to 28 to m NbC NbC 60 to 97 36 to 97 65 to 96 41 to 96 70 to 95 47 to 95 3200 Re + Cr Re 0.03 to 39.6 0.04 to 49 0.04 to 34.7 0.06 to 43 0.05 to 29.7 0.07 to 38 1800 Bonded Cr 0.03 to 39.6 0.015 to 25 0.04 to 34.7 0.019 to 21 0.05 to 29.7 0.024 to 17 to TaC TaC 60 to 97 51 to 98 65 to 96 56 to 98 70 to 95 62 to 97 3200 Re + Cr Re 0.03 to 39.6 0.09 to 67 0.04 to 34.7 0.12 to 62 0.05 to 29.7 0.16 to 57 1800 Bonded Cr 0.03 to 39.6 0.03 to 41 0.04 to 34.7 0.04 to 36 0.05 to 29.7 0.05 to 31 to Cr2C3 Cr2C3 60 to 97 32 to 97 65 to 96 37 to 96 70 to 95 43 to 95 1900 Re + Cr Re 0.03 to 39.6 0.07 to 60 0.04 to 34.7 0.09 to 55 0.05 to 29.7 0.11 to 49 1800 Bonded Cr 0.03 to 39.6 0.023 to 34 0.04 to 34.7 0.03 to 29 0.05 to 29.7 0.037 to 25 to Mo2C Mo2C 60 to 97 40 to 98 65 to 96 45 to 97 70 to 95 50 to 96 2600 Re + Cr Re 0.03 to 39.6 0.04 to 47 0.04 to 34.7 0.05 t o 42 0.05 to 29.7 0.07 to 36 1800 Bonded Cr 0.03 to 39.6 0.014 to 23 0.04 to 34.7 0.018 to 20 0.05 to 29.7 0.023 to 16 to WC WC 60 to 97 53 to 98.6 65 to 96 58 to 98 70 to 95 64 to 97.6 2900 surface, for example, for hard metal or ceramic metal containing the above-mentioned composition, which can be used to remove the target material. Grinding elements in cutting tools, grinding wheels, drilling tools. The tool can be a support element made of different materials, such as steel. These are wear-resistant to be embedded in the support element. The tool can be designed to include a variety of inserts in the support element. For example, many mining drills contain small clasps made of many materials. Of course, the applicable tools include drilling tools, grinding tools, knives, saws, etc.

1057D-6939-PF 200535255 而作成環境下磨耗之工具。除此之外，可根據元件的特別需要，構造用的外罩、外表面或一些層來配合元件在某也的操作應用。特別的是，上述的硬金屬可以用來製作切削工呈，而能對金屬、合金、複合物、塑膠、木頭以及其他材料進行機械加工。這些切削工具可以包含用來旋轉、磨、鑽的鑲嵌物，還有鑽孔器、鉸刀、錢床、栓頭、套子與研磨具等等。由於上述的工具在切削時會達到50(rc的高溫，所以本案之適用於高溫之硬金屬材料非常適用於上述工具，因而有特別之功效。例如，可增加工具壽命以及可藉由增加切削速度而改善切削品質。本發明的硬金屬材料除了可應用於抽線（wire drawing)、擠製（extrusion)、鍛造以及冷加工之外，也能用於粉末製程中的模具和衝頭。還有，也可用於礦業的耐磨元件。本發明的硬金屬材料除了可製造成塊材的形式也可塗佈在金屬表面上。本發明硬金屬材料的塗佈有助於在金屬表面形成一硬金屬層來達到下部金屬材料所難以達到的高硬度值。以本發明組成所製成的金屬塊材成本相當昂貴，因此利用塗佈的方式將本發明之硬金屬塗佈在價格低廉且硬度較低的金屬材料上，可有效降低成本且提升所需的硬度。多種用來製造商用硬金屬的粉末製程也可用來製造本發明的硬金屬。例如，一 Re含量超過總重量8 5 %的黏 1057D-6939-PF 144 200535255 結劑基質可用固態燒結製程來製造以消除多孔性，接著以熱均壓（hot 1S0Static pressing，HIP)製程取代液相燒結第9圖顯示多種上述硬金屬組合物材料及結=造方法的流程圖，如圖所示，可以一濕式的混合製程利用液體輾磨’將黏結劑的合金粉末與硬粒子粉末混合，其中輕磨製程中可添加潤滑劑（例如：蠟）來減低摩擦。第9圖中左手邊的製造流程為利用含潤滑劑的濕式輾磨來製造硬金屬。利用真空乾燥法（vacuum drying)或噴霧乾燥法㈣^ ㈣ng)將混合物作第-次乾燥來製造經過潤滑的粉末，接著將該經過潤滑的粉末藉由衝壓、擠製材及成形。冷均壓製程是利用均勻的厂堅力使粉末成形的塊材透過多種加熱過程以除去潤滑劑，例如可將加壓成形的塊材在真空或氫氣氣氛下利用液相燒結，接著更進一步利用熱均壓製程來形成最後的硬金屬塊材。若黏結劑合金粉末與硬粒子粉末混合時未使用潤滑劑，則該未經潤滑的粉末在乾燥製程後可經由兩種不同的方法來製造最後的硬金屬組合物。第一種方法是利用轨衝壓，第二種方法是利用熱喷塗法在真空中將粉末形成在金屬基材上’接著將金屬基材移除使完成最後單獨存在的硬金屬。除此之外，要可再利用—熱均壓製程來降低多孔性。在金屬表面形成硬金屬塗層的過程中，可利用一熱噴塗製程在真空條件下將硬金屬塗佈在金屬表面上。例：可在鋼鐵表面或工具表面塗佈一硬金屬層來提高其硬度以增 1057D-693 9-PF 145 ‘200535255 加性此。第1 〇圖顯示熱喷塗製程實施例的流程圖。有多種已知的熱喷塗製程可用來在金屬表面進行塗佈製程，例如ASM手冊第7冊（P408, 1998)中描述熱噴塗製程如同一種能夠將金屬、陶瓷、介金屬化合物，複合材料以及局分子形成塗佈層或獨立的結構的微粒結合製程。在喷塗製程中可將粉末、金屬線材或條狀金屬材料置入燃燒或以電弧加熱（arc-heated)的喷射器中，經過加熱、熔化或軟化、加速再經由控制喷塗至表面或基板上。在噴塗衝擊 •的過程中，微粒快速固化、冷卻、收縮以及逐漸累積成一沈積物於表面。在沈積過程中薄塗佈層經過一超過ι〇1/δ 的高冷卻速率。一熱噴塗製程可利用化學能或電能來加熱填入噴射器中材料，形成一熔化的流體經過加速在基材表面完成塗佈。不同的熱噴塗製程顯示在ASM手冊第7冊p4〇9_4i() 中第3及第4圖。不同熱噴塗製程細節詳述在分別刊載於 ASM手冊第7冊p〇wer⑽_ APPliCati〇n(1998)中 P396-407 及 P4〇8-419 中 Lawley 以吐的 “spray f0rming，，以及 Knight et al 的“丁⑹⑽！ s㈣^1057D-6939-PF 200535255 and the tool for abrasion in the environment. In addition, according to the special needs of the component, the construction cover, outer surface or some layers can be used to match the application of the component in a certain operation. In particular, the above-mentioned hard metals can be used to make cutting tools, but can be used to machine metals, alloys, composites, plastics, wood, and other materials. These cutting tools can include inserts for rotation, grinding, and drilling, as well as drills, reamers, coin beds, bolts, sleeves, and abrasive tools. Since the above-mentioned tool can reach a high temperature of 50 (rc) during cutting, the hard metal material suitable for high temperature in this case is very suitable for the above-mentioned tool, and therefore has a special effect. For example, it can increase the tool life and can increase the cutting speed by Improve the cutting quality. In addition to the wire drawing, extrusion, forging, and cold working, the hard metal material of the present invention can also be used in dies and punches in the powder manufacturing process. Also, It can also be used in abrasion-resistant components in the mining industry. The hard metal material of the present invention can be coated on metal surfaces in addition to being made into a block. The coating of the hard metal material of the present invention helps to form a hard metal on the metal surface. Layer to achieve a high hardness value that is difficult to achieve for the lower metal material. The metal block made of the composition of the present invention is quite expensive, so the hard metal of the present invention is coated at a low price and low hardness by means of coating. Metal materials can effectively reduce the cost and increase the required hardness. A variety of powder processes used to make commercial hard metals can also be used to make this Invented hard metal. For example, a viscous 1057D-6939-PF 144 200535255 with a Re content exceeding 85% by weight can be manufactured by a solid state sintering process to eliminate porosity, and then hot isostatic pressing (HIP) ) The process replaces liquid phase sintering. Figure 9 shows a flow chart of a variety of the above-mentioned hard metal composition materials and junction manufacturing methods. As shown in the figure, a wet mixing process can be performed by liquid milling to mix the alloy powder of the binder with Hard particle powder mixing, in which a lubricant (such as wax) can be added during the light grinding process to reduce friction. The manufacturing process on the left-hand side of Figure 9 is to use hard grinding with lubricant to produce hard metal. Vacuum drying (Vacuum drying) or spray drying method (^ ㈣ ng) The mixture is first-dried to produce a lubricated powder, and the lubricated powder is then punched, extruded, and formed. The cold equalizing process is to use uniform plant strength to make powder-shaped blocks through various heating processes to remove lubricants. For example, press-shaped blocks can be sintered in a liquid phase under a vacuum or hydrogen atmosphere, and then further utilized. Hot homogenization process to form the final hard metal block. If the binder alloy powder is mixed with the hard particle powder without using a lubricant, the non-lubricated powder can be manufactured into the final hard metal composition by two different methods after the drying process. The first method is to use rail stamping, and the second method is to use thermal spraying method to form powder on a metal substrate in a vacuum 'followed by removing the metal substrate to complete the final hard metal which exists alone. In addition, it should be reusable—hot soaking to reduce porosity. In the process of forming a hard metal coating on a metal surface, a thermal spray coating process can be used to coat the hard metal on the metal surface under vacuum. Example: A hard metal layer can be coated on the surface of steel or tools to increase its hardness to increase 1057D-693 9-PF 145 ‘200535255. FIG. 10 shows a flowchart of an embodiment of a thermal spraying process. There are many known thermal spraying processes that can be used to coat metal surfaces. For example, the ASM Handbook, Volume 7 (P408, 1998) describes thermal spraying processes as a method that combines metals, ceramics, intermetallic compounds, composite materials, and Local molecules form a coating layer or an independent structure of a microparticle bonding process. In the spraying process, powder, metal wire or strip metal material can be placed in a burner or arc-heated injector, heated, melted or softened, accelerated, and then sprayed to the surface or substrate through control. on. During the spraying shock, particles rapidly solidify, cool, shrink, and gradually accumulate into a deposit on the surface. During the deposition process, the thin coating layer undergoes a high cooling rate in excess of ι1 / 1 / δ. A thermal spray process can use chemical energy or electrical energy to heat the material filled in the ejector to form a molten fluid that is accelerated to complete the coating on the surface of the substrate. The different thermal spray processes are shown in Figures 3 and 4 of the ASM Handbook, Volume 7, p4009_4i (). The details of the different thermal spraying processes are detailed in Laws P396-407 and P408-419 published in ASM Handbook Volume 7 pοwer⑽_ APPliCatione (1998), and "spray f0rming", and Knight et al. "Ding Yan! s㈣ ^

Forming Of Material”。雖然本發明已以較佳實施例揭露如上，然其並非用以限定本發明，任何熟習此技藝者，在不脫離本發明之精神和範圍内，當可作些許之更動與潤飾，因此本發明之保護Forming Of Material ". Although the present invention has been disclosed as above with preferred embodiments, it is not intended to limit the present invention. Anyone skilled in this art can make some changes and modifications without departing from the spirit and scope of the present invention. Retouching and therefore protection of the present invention

範圍¥視後附之申請專利範圍所界定者為準。 1057D-6939-PF 146 200535255 【圖式簡單說明】第1圖是顯示根據一方法來製造本發明硬金屬的一典型製造流程圖。第2圖是顯示在固態下根據兩階段燒結步驟來製造本發明硬金屬的一典型製造流程圖。第3、4、5、6、7與8圖係顯示所選擇的代表性的硬金屬之一些測定性質。第9及第1 0圖係說明熱喷塗的方法。 • 【主要元件符號說明】無The scope ¥ is subject to the definition of the scope of the attached patent application. 1057D-6939-PF 146 200535255 [Brief description of the drawings] FIG. 1 is a typical manufacturing flowchart showing a method for manufacturing the hard metal according to the present invention. Fig. 2 is a typical manufacturing flow chart showing the production of the hard metal according to the present invention by a two-stage sintering step in a solid state. Figures 3, 4, 5, 6, 7, and 8 show some of the measured properties of the selected representative hard metal. Figures 9 and 10 illustrate the thermal spraying method. • [Description of main component symbols] None

1057D-6939-PF 1471057D-6939-PF 147

Claims

-200535255 X. Patent application scope I. A material, including: a plurality of hard particles, including at least one carbide, wherein the carbide is free of at least one of Wc, TiC and HfC; and a binder matrix, including Re And used to bond the plurality of hard particles, wherein the plurality of hard particles is less than 75% of the total weight of the material, and Re is greater than 25% of the total weight of the material. I 2 · —a type of material, including: a plurality of hard particles, including at least one carbide, wherein the carbide is selected from carbides formed by elements IVb, vb & VIb in the periodic table of the element, but excluding WC, TiC and HfC; and a binder matrix, including Re and used to bond a plurality of hard particles, wherein the plurality of hard particles is less than 75% of the total weight of the material, and k accounts for about 4% to 72% of the total weight of the material; 3. · A kind of material, including ·· 纟 several hard particles' including at least one nitride, wherein the nitride is selected from the group consisting of elements of the IVMVb group in the periodic table of the elements; To bind the plurality of hard particles. 4. The material as described in item 3 of the Chinese Patent Application ranges from 4% to 72% by weight. 5 ~ —materials, including: a plurality of hard particles, including at least one self-propelled material, the carbide is selected from the carbides formed by IVb, Vb, and 7L-free elements in the periodic table; 1057D -6939-PF 148 .200535255 and-a binder matrix including Re and a nickel-based superalloy and used to bond the plurality of hard particles. 6. The material according to item 5 of the scope of patent application, wherein the plurality of hard particles account for about 26.1% to 98.4% of the total weight of the material. 7 · A kind of material, including: a plurality of hard particles, including at least one kind of carbide, wherein the carbide selects the free element period | medium! Carbides formed by elements of the Vb and VbAVIb groups; and viscous, fluorene-based alloys, including a nickel-based superalloy and co, and used to bond the plurality of hard particles. 8. The material according to item 7 of the scope of patent application, wherein the plurality of hard particles make up about 45% to about the total weight of the material. 9. A material comprising: a plurality of hard particles, including at least one carbide, wherein the carbide is selected from carbides of elements lvb, vb and VIb in the periodic table of elements; and a binder matrix including Re, A nickel-based superalloy and co are used to bond the plurality of hard particles. 10. The material as described in item 9 of the scope of the patent application, wherein the plurality of hard particles account for about 26% to 98.4% of the total weight of the material. 11 · A material comprising: a plurality of hard particles including WC and Tic; and 1057D-6939-PF 149 .200535255 a binder matrix including a core and a nickel-based superalloy for bonding the plurality of hard particles. '° ~ 12. The material as described in item u of the patent application range, wherein about 40% to 92% of the total weight of the material, and TiC up to about 24% of the total weight of the material, and in the adhesive matrix ^ And the nickel-based superalloy are up to two to about 52% and 29% of the total weight of the material, respectively. 13 · A material, including: a plurality of hard particles, including WC and TaC; and _-a binder matrix, including and-a nickel-based superalloy and used to bond the plurality of hard particles. 14 · The material described in item 13 of the scope of patent application, wherein WC accounts for about 44% to 98% of the total weight of the material, and Tac is up to about 24% of the total weight of the material, and in the adhesive matrix, Re And the nickel-based superalloy is up to about 47% and 24% of the total weight of the material, respectively. 1 5 · A type of material, including: ❿ a plurality of hard particles, including WC, TiC, and TaC; and a binder matrix, including Re and a nickel-based superalloy, for bonding the plurality of hard particles. 1 6 · The material described in item 5 of Shenjing's patent scope, which accounts for about 40% to 98% of the total weight of the material, Tic is up to about 5% of the total weight of the material, and TaC is up to about the total weight of the material 26% by weight, and in the binder matrix, Re and the nickel-based superalloy are up to about 53% and 30% of the total weight of the material, respectively. 〇17 ·-materials' include: 1057D-6939-PF 150. * 200535255 a plurality of hard particles including WC and TiC; and-a binder matrix including Co and a nickel-based superalloy and used to bond the plurality of hard particles. 18. The material described in item 17 of the scope of patent application, wherein wc accounts for about 58% to 98% of the total weight of the material, and Tic is up to about 24% of the total weight of the material, and in the adhesive matrix, and The nickel-based superalloys are up to about 33% and 29% of the total weight of the material, respectively. 19. A material, including: ® a plurality of hard particles, including WC and TaC; and a viscous, w-based substrate, including Co and a nickel-based superalloy, and used to bond the plurality of hard particles. 20. The material described in item 19 of the scope of patent application, wherein wc accounts for about 61% to 98% of the total weight of the material, and TaC is up to about ⑽ ′ of the total weight of the material, and in the adhesive matrix, c 〇 and the base superalloy up to about 28% and 25% of the total weight of the material, respectively. A 2 1 · — a kind of material, including a plurality of hard particles a binder matrix a plurality of hard particles. Including WC, TiC, and TaC; and materials including Co and a nickel-based superalloy for bonding the 22 · The material described in item 21 of the patent application scope, wherein wc accounts for about 57% to 98% of the total weight of the material, TiC Up to about 23% of the total weight of the material 'TaC up to about 26% of the total weight of the material, and Co and the nickel-based superalloy in the binder matrix up to about 33% of the total weight of the material and 30% 〇1057D-6939-PF 151, 200535255 2 3-a kind of material, including a plurality of hard particles, including WC and Tie; and-a binder matrix, including Co and a nickel-based superalloy and used to bond the A plurality of hard particles. 24. The material described in item 23 of the scope of patent application, wherein about 40% to 98% of the total weight of the material 'and TiC is up to about 24% of the total weight of the material, and in the adhesive matrix, "and The nickel-based superalloy is southmost to about 54% and 29% of the total weight of the material, respectively. 25 ·-materials, including a plurality of hard particles, including WC and TaC; and a binder matrix, including Co, Re and a Nickel-based superalloys are used to bond the plurality of hard particles. 26. The material described in item 25 of the scope of patent application, wherein wc accounts for about 45% to 98% of the total weight of the material, and TaC is up to about the total weight of the material 24%, TaC up to about 26% of the total weight of the material, and C0, Re and the nickel-based superalloy in the binder matrix up to about 28%, 47%, and 26% of the total amount of the material, respectively. %. 27 · —Materials' include: a plurality of hard particles, including WC, Tic, and TaC; and a binder matrix, including Co, Re, and a nickel-based superalloy, and are used to bond the plurality of hard particles. 28. As described in the patent application No. 27, Wc accounts for about 35% to 93% of the total weight of the material, TiC Up to about 25% of the total weight of the material 'TaC up to about 26% of the total weight of the material, and Co, Re and the nickel-based superalloy in the matrix 1057D-6939-PF 152 .-200535255 respectively Up to about 44%, 65% and 41% of the total weight of the material. 2 9 · — materials including a number of hard particles including TiC and Mo2C; and a binder matrix including Re and used to bond the plurality 30. The material as described in item 29 of the scope of patent application, wherein Tic accounts for about 19% to 88% of the total weight of the material, and MoC is up to about 38% of the total weight of the material; and Re accounts for about 95% to 65% of the total weight of the material. _ 31 · — a variety of materials, including: a plurality of hard particles, including TiC and Mo2C; and a binder matrix, including Re and used to bond the plurality of hard 32. The material as described in item 31 of the scope of the patent application, wherein Ding Yao accounts for about 21% to 89% of the total weight of the material, and MhC is up to about 36% of the total weight of the material; and Re accounts for about 36% of the total weight of the material; 9% to 63% of the total weight of the material. 33 · — a variety of materials, including: _ a number of hard particles, including Ti C, TiN, and Mo2C; and a binder matrix, including Re and used to bond the plurality of hard particles. 34. The material described in item 33 of the scope of patent application, wherein Tic is up to about 84% of the total weight of the material And TiN is up to about 85% of the total weight of the material, and Μοβ is up to about 36% of the total weight of the material; and Re is about 9% to 64% of the total weight of the material. 3 5 · — a variety of materials, including: a plurality of hard particles, including TiC, TiN, Mo2C, WC, TaC, vc and Cr2C3; and 1057D-6939-PF 153. * 200535255-a matrix of 1 agent, including Re and used to Bonding the plurality of hard particles. 36. The material described in item 35 of the scope of the patent application, ... to about 83% of the total weight of the material, and, taking a range of oc / o / n / 〇TlN to about 85% of the total weight of the material, Mo2C is up to about 25% of the material, and WC is up to 39% of the total weight of the material. TaC # 古本 From Douchong TaC is up to about 30% of the total weight of the material. The highest VC is about 11% of the material, and the maximum Cr2c3 is about 16% of the total weight of the material, and the maximum weight of the material is 6%, and the force is 6% of the total weight of the material. % To 65% 〇

37 · —A kind of material, including: a plurality of hard particles, including TiC and Μοβ; and a binder matrix, including a nickel alloy and a human body ^ super gold and used to bond the plurality of hard particles. 38. The material described in item 37 of the scope of the patent application, wherein Job Shen: 30% to 90% of the total weight of the material, and a maximum of about 40% of the total weight of the material; and the base superalloy accounts for approximately $ To 65% of the total weight of the material 〇39 ·· materials, including ... a plurality of hard particles, including TiN and m02C; and a yttrium-based matrix, including a nickel-based superalloy and used to bond the plurality of Hard particles. 40. The material described in item 37 of the scope of patent application, wherein TiN is up to 91% of the total weight of the material, and Mg2C is up to about 38% of the total weight of the material; and the nickel-based superalloy is about 4% to 38% of the total weight of the material ° ^ 〇57d ~ 6939 ~ PF 154 .200535255 4 1 · A material comprising: a plurality of hard particles 'including TiC, TiN and Mo 2C; and a binder matrix' including _ Nickel-based superalloys are used to bond the plurality of hard particles. 42. The material described in item 41 of the scope of Shenying's patent, in which the Ding and Mo2C knives are southmost to about the total weight of the material, M% and; and the nickel-based superalloy accounts for about the total weight of the material. to. 43 · —materials, including: _ a plurality of hard particles, including TiC, TiN, Mo2C, WC, TaC, VC, and Cr2C3; and a binder matrix ′ includes a nickel-based superalloy and is used to bond the plurality of hard particles. 44. The material according to item 43 of the scope of patent application, wherein TiC is up to about 90% of the total weight of the material, TiN is up to about 90% of the total weight of the material, and Mow is up to about 25% of the total weight of the material. %, Wc up to about φ 〇 42% of the total weight of the material, hC up to about 36% of the total weight of the material, VC up to about 14% of the total weight of the material and cr2c3 up to about 1% of the weight of the material 8%; and the nickel-based superalloy accounts for about 2% to 40% of the total weight of the material. 4 5 · A type of material, including a plurality of hard particles, including TiC, TiN, and MoC; and a binder matrix including Re and a nickel-based superalloy for bonding the plurality of hard particles. 1057D-6939-PF 155 '-200535255 46. According to the materials described in the 45th, +, — &J; of the scope of patent application, Tic is up to about 90% of the total weight of the material, and Ding _ ^ Take flN to about 91% of the total weight of the material, and Mo2C up to about 91% of the material, and more to 38%; and Re and the nickel-based superalloy up to about 哕 J and the total weight of the material, respectively. 64% and 40%. 4 7 · — a variety of materials, including: 袓 several hard particles, including TiC, Ding M ^ llN, Mo2C, wc, TaC, VC and Cr2C3; and a binder matrix, including Re and-nickel-based superalloys and used To bind the plurality of hard particles. 48. The material described in item 47 of the scope of patent application, wherein Tic is up to about 89% of the total weight of the material, and TiN is up to about 90/6 M0C of the total weight of the material. , The maximum range is up to about 42% of the total weight of the material, the TaC is up to about M% of the total weight of the material, the VC is up to about 16% of the total weight of the material, and cr2c3 is up to about 18% of the total weight of the material. %; And the nickel-based superalloy up to about 64% and 40% of the total weight of the material. 49 · A material comprising: a plurality of hard particles, including TiC, TiN, and Mo2C; and a binder matrix, including RelCo, used to bond the plurality of hard particles 50. The material as described in item 49 of the scope of patent application , Where TiC is up to about 90% of the total weight of the material, and TiN is up to about 91% of the total weight of the material 1057D-6939-PF 156 • 200535255 ', and Μοβ is up to about 38% of the total weight of the material; and Re And Co up to about 64% and 43% of the total weight of the material, respectively. 5 1 · A kind of material, including: a plurality of hard particles, including TiC, TiN, Mo2C, WC, TaC, VC, and Cr2c3; and a binder matrix, including Re and Co, which are used to bond the plurality of hard particles. 52. The material described in item 51 of the scope of patent application, wherein TlC is up to about 89% of the total weight of the material, and TiN is up to about 90% of the total weight of the material; m2C is up to about the total weight of the material %% by weight, wc up to about 42% of the total weight of the material, TaC up to about 32% of the total weight of the material, VC up to about 16% of the total weight of the material and cr2c3 up to about the total weight of the material 18%; and Re and Co up to about 64% and 43% of the total weight of the material. 53 · —A kind of material, including: a plurality of hard particles, including TiC, TiN, and Mo2C; and _ a binder matrix including a nickel-based superalloy and Co and used to bond the plurality of hard particles. 54. The material described in item 53 of the patent application scope, wherein Tic is up to about 90% of the total weight of the material, TiN is up to about 91% of the total weight of the material, and m02C is up to about the total weight of the material. 38% by weight; and the nickel-based superalloy and C0, respectively, up to about 40% and 43% of the total weight of the material. 55 · — a variety of materials, including: 1057D-6939-PF 157 ', 200535255 a plurality of hard particles, including TiC, TiN, Mo2C, WC, TaC, VC and Cr2C3; and a binder matrix, including a nickel-based superalloy and c0 and used to bond the plurality of hard particles. 56. The material described in claim 55, wherein Tic is up to about 89% of the total weight of the material, TiN is up to about 90% of the total weight of the material, and MoC is up to about 90% of the total weight of the material. 26%, WC up to about 42% of the total weight of the material, TaC up to about 33% of the total weight of the material, VC up to about 16% of the total weight of the material and Cr2c3 up to about the total weight of the material 18%; and up to about 40% and 43% of the total weight of the nickel-based superalloy and co. 57 · — a variety of materials, including: a number of hard particles, including Tic, TiN and Mo2C; and a binder matrix, including Re, a nickel-based superalloy and. And used to bond the plurality of hard particles. 58. The material described in item 57 of the scope of patent application, wherein μ is up to about 90% of the total weight of the material, TiN is up to about 91% of the total weight of the material, and m02C is up to about the total weight of the material. 38% by weight: and the nickel-based superalloy and Co up to about ⑽, 40%, and 42% of the total weight of the material, respectively. 5 · 9 materials, including ... a plurality of hard particles, including T彳 ρ, Ti · XΓ χ > Γ] 丁祜 m, TiN, Mo2c, wc, TaC, VC, and Cr2C3; and 1057D-6939-PF 158. * 200535255 a binder matrix, including Re, a nickel-based ultra-thin The alloy and co are used to bond the plurality of hard particles. 60. The material as described in item 59 of the% patent application range, wherein the maximum amount of Ding c is about 89% of the total weight of the material, the maximum of TiN is about 90% of the total weight of the material, and the maximum amount of Mo 2C is About 26% of the total weight of the material, Wc up to about 42% of the total weight of the material, TaC up to about 33% of the total weight of the material, VC up to about 16% of the total weight of the material and Cr2c3 up to about 18% of the total weight of the material; and Re, the nickel-based superalloy, and up to about 63%, 40%, and 43% of the total weight of the material. 61. A material comprising: a plurality of hard particles including at least one boride formed from elements of the ivb, Vb and vib groups in the periodic table; and a binder matrix including Re and used to bond the plurality of hard particles particle. 62. The material according to item 61 of the scope of patent application, wherein about 4% to 76% of the total weight of the material. 63. A kind of material includes: # hard particles include at least one silicide formed from elements of the Periodic Table I, Vb and Vib groups; and-a binder If, including Re and used to bond the plurality of hard particles particle. 64. The material described in item 63 of the scope of patent application has a center of approximately 6% to 77% of the total weight of the material. / 6 5 · — a material including: a plurality of hard particles; and a binder matrix including a plurality of hard particles for bonding. 1057D-6939-PF 159 • 200535255 66. The material as described in item 65 of the scope of patent application, wherein the plurality of hard particles include at least one carbide formed from elements IVb, Vb and VIb in the periodic table, W About 4% to 72% of the total weight of the material. 67. The material as described in item 65 of the scope of patent application, wherein the plurality of hard particles include at least one kind of hard particles of nitrides formed from elements of groups IVb, Vb and VIb in the periodic table, and W accounts for about 4% to 72% of the total weight of the material. 68. The material as described in item 65 of the scope of patent application, wherein the plurality of # hard particles include at least one boride formed from elements of Groups IVb, Vb and VIb in the periodic table of elements, and W accounts for about 3% to 74%. 69. The material as described in item 65 of the scope of patent application, wherein the plurality of hard particles include at least one silicide formed from elements IVb, Vb and VIb in the periodic table of elements, and W accounts for about 6% of the total weight of the material % To 75%. 70. The material as described in claim 66, wherein the adhesive matrix further comprises Re. 71. The material described in item 70 of the scope of patent application, wherein the plurality of _ hard particles include at least one carbide formed from Group IVb, Vb and VIb elements in the periodic table of elements, and Re is less than the total of the material 73% by weight, W is less than 72% of the total weight of the material. 72. The material according to item 70 of the scope of patent application, wherein the plurality of hard particles include at least one carbide formed from elements of Groups IVb, Vb and VIb in the periodic table, and Re is less than the total weight of the material 71%, W is less than 70% of the total weight of the material. 1057D-6939-PF 160

• 200535255 3 · The material described in Item 70 of the declared patent scope, wherein the plurality of hard particles include at least one boride formed from elements of Groups ivb, vb and VIb in the periodic table, and Re is less than that 75% of the total weight of the hard metal composition is less than about 73% of the total weight of the material. 74. The material as described in item 70 of the scope of the patent application, wherein the plurality of hard particles include at least one silicide formed by elements yb, vb, and vib in the periodic table of elements, and Re is less than about 76% of the total weight of the material, w is less than about 74% of the total weight of the material. 75 · —a material comprising: a plurality of hard particles including at least one nitride formed from elements ivb, Vb and Vib in the periodic table of elements; and a binder matrix including Re & Co for bonding the plurality Hard particles. 76. The material described in item 75 of the scope of patent application, wherein ^ is less than about 71% of the total weight of the material, and ⑽ is less than 52% of the total weight of the material. 77. A material comprising: a plurality of hard particles including at least one boride formed from elements ivb, Vb and Vib in the periodic table of elements; and a binder matrix including Re and Co for bonding the plurality of Hard particles. 78. The material as described in item 77 of the scope of patent application, wherein "about 75% of the total weight of the material 'and Co is less than the total weight of the material. 79.-A kind of material, including: 1057D-6939- PF 161 '200535255 A plurality of hard particles, including at least one of the silicides formed by IVb and savanin in the periodic table of Vb and VIb 旄 -epidin; and a binder matrix, including Re and Co, used for plaque. ^ Knot the plurality of hard granules 80. As described in the scope of the patent application, the poor auntie oblique tongue, "Re, is less than °," "76% of weight 1, and c. Less than 57% of the total weight of the material & general material 81 81.-a kind of material, including: a plurality of hard particles, including Vb ^ VTh ^-^ including a small number of elements in the Periodic Table IVb, Carbide formed by Bioss 70; and a binder. A binder matrix, including ReAM, is used to persuade the plurality of hard granules = the material described in item 81 of the patent scope, where Re is about It is less than 74% of the weight of the material, and M. It is less than ㈣ of the total weight of the material. 83 ·-a kind of material, including: a plurality of hard particles , Including a dagger to v kinds of carbides formed from elements IVb, Vb and VIb in the periodic table; and M matrix, including Re & Ni, used to bond the plurality of hard particles. The material described in item 83 of the range has a total weight of 740 / _ of the material, and Νι is less than about 54% of the total weight of the material. 85 ·-a kind of material, including: a number of hard teachings; 1. A carbide formed from IVb, Vb & VIb & TLf in the periodic table of elements; and a cement, which includes clear earth shells, including Re and Cr, and is used to bond the plurality of hard particles 1057D-6939-PF 162 .200535255 86. The material described in item 85 of the scope of patent application, wherein Re is less than 74% of the total weight of the material, and Cr is less than 48% of the total weight of the material. 87. A manufacturing method, The method comprises the following steps: providing a metal surface; performing a thermal spraying process to coat a hard metal on the metal surface, wherein the hard metal includes: a plurality of hard particles, at least of carbides, nitrides, pendants, or Fragments formed; and a binder matrix Comprising Re, or a nickel-base superalloy w, for the plurality of hard knot clay particles.

1057D-6939-PF 163