TW200530296A - Metal chelate polymer solution and its application - Google Patents

Abstract

This invention is related to a metal chelate polymer solution and its application. The metal chelate polymer solution comprises one or more than one kind of metal chelate polymers. The metal chelate polymer is formed by evenly mixing R-COOH and/or a carbohydrate dissolved by an inorganic acid and/or a polymer with hydroxyl group and/or carboxyl group and/or carbohydrate, metal salt solution and ammonia or substances like amine according to the normal methods. The metal chelate polymer solution brought up in this invention is extensively applied on areas of technology like oxidation reaction, condensation reaction, decomposition reaction, oxidative condensation reaction, gas detection, artificial chitosan solution, artificial amino-glucose, bactericide, biochemical reaction for fermentation, biological protein and purification of its metabolite, gene engineering, bacteria conserving system, culture medium for cell proliferation, medical treatment, oil products, plants, semiconductor, nano-filtration, manufacture of nano-material, nano-ceramic, nano-plastic, nano spinning and weaving, generation of electric power, liquid crystal display and biochips. The metal chelate polymer solution proposed in this invention exhibits effects like chemical engineering, gas removing, processing waste solvent solution. This is the metal chelate polymer solution and its application.

Description

200530296

[Technical field to which the invention belongs] The present invention relates to a metal polymer solution and its application, and in particular, to a metal complex polymer solution regarding a condensation reaction solution, an oxidative condensation reaction solution, and other reaction solutions, and an application thereof. The metal complex polymer solution is used in various catalyst reactions, fungicides, artificial glucosamine, biochemical reactions for fermentation, purification of biological proteins and their metabolites, genetic engineering, bacteria preservation system, culture medium for cell proliferation, medical treatment, and plants , Semiconductors, nanofiltration, nanofabrication, nanoceramics, nanoplastics, nanotextile industry, power generation, liquid crystal, biochip applications, and various chemical fields, or go to excess organic solvent gases and other gases And in the treatment of waste solvent liquids. [Previous technology] In general, condensation reaction is an important unit of the chemical process. It is well known that styrene gas becomes polystyrene solid and monomer gas becomes solid polymer. Both are condensation polymerization reactions, but the polymerization reaction Sometimes it is necessary to match the initial reaction (local oxidation reaction) to make the reaction successful. The catalyst structure of the early condensation reaction is very complicated, and the initial reaction (local oxidation reaction) and the condensation reaction are separated. Unlike the present invention, the oxidative condensation can be reacted together. Some reactions can be achieved together, and some of them can be achieved under high temperature and high pressure. The cost of investment, financial resources and material resources can be imagined, but the present invention can be achieved simply. Furthermore, catalyst reagents and carriers with condensation reactions and oxidative condensation reactions and other reactive properties for treating organic solvent gases and other gases are also rare. In the early days, only carriers that adsorbed and neutralized acid-base gas frameworks were not directly available. Handle solvent gas

Page 6 200530296 V. Description of the invention (2) The carrier of the body 'Early reaction of methyl ethyl cellulose and other special JC short-lived', but now it is infinitely extended due to C, and the physiologically active lifespan of this substrate However, it can be developed into a chitosan solution containing metal ions, which becomes a highly efficient, artificial ions into a carrier of imitation. The use of metal complexes to gather human, high activity, long-lived antenatal bacteria is fixed and preserved: η ”system and enzyme fixation system. And purification is not easy, often stored for a long time, and it is imitation Chitin ===: This ... base f can be used without considering the specific binding of basal substance or humic acid. Nutrition, original metabolism issues. Instead of the old old culture medium 'to make bacteria and enzymes and nucleic acid and cell body strong and Powerful cultivation. After drying and drying, it is generally only in the range of 10-6 meters (I $ Μ 拖 A = 2? ®-9 meters), and it is generally converted to organic by the sol-gel method. Metal can only be achieved, and the chemical process is also very difficult. 3 'Erjin Misu new glue in the fermentation system can achieve nanochemical and nano ί V right two Λ, / ... card textile applications. Waste solvent liquid The treatment is the same, because of the rapid shrinkage at room temperature; 5 places such as the number of people ~ human K ^ ^ — condensation. Reaction and emulsification condensation reaction, unprecedented, non-τ 仃 waste solvent treatment can be processed. It can be seen that there are still many shortcomings in the existing technologies mentioned above. Urgent present Minga to further = feed in order to solve the existing technical defects, the firms did not dare seek a solution, but a long time -.! Straight no applicable design is the development of yuan into, this is obviously related businesses eager to solve the problem.

200530296

-It is generally known that & propylmethylcellulose is a cellulose widely present in plants and woods, and is a natural fiber polymer. In nature, the physiological activity of hydroxypropylphosphonium cellulose has functional properties, non-toxic and non-irritating allergic reactions to the human body, good biocompatibility with the human body, no antibody response, and is used in chemically compatible heavy metals and Many-valent, divalent, or trivalent metal ions, most people only know the application of additives and additives, but they do not know the proper proportion of monovalent, bivalent, or trivalent metal ions. Chemical gas undergoes oxidative cracking and condensation polymerization of organic solvents, as well as detection of gases, artificial imitation of glucosamine, fungicides, medical treatments, biochemistry, nanometers, plants, semiconductors, power generation, liquid crystal, and biochips. application. If it is chitin, it is considered that it is necessary to cooperate with other media (such as carbon tetracarbonate or sodium sulfate) to initiate the condensation reaction, or that it only generates a neutralization reaction to acid and alkaline gases, but it is unknown that the precise dose-controlled oxidation reaction solution is dried. The film will produce a continuous flow of oxygen and negative ions due to the friction of air lice. In view of the shortcomings of the existing technologies described above, the present invention is based on many years of practical experience and professional knowledge in the design and manufacture of such products, and actively researches and innovates in order to create a new type of metal complex polymer solution and its application, which can improve general Existing conventional technologies on the market make it more practical. After continuous research, design, and repeated trial and error to make samples and improvements, the invention of stomach-exporting that has practical value is finally created. [Summary of the Invention] The purpose of the present invention is to overcome the shortcomings of the existing technology and provide a new metal complex polymer solution. The main technical problems to be solved

200530296 V. Description of the invention (4) It has good oxidation, cracking, condensation and oxidative condensation ability. Another object of the present invention is to provide a metal complex polymer solution. The technical problem to be solved is to make it widely used in the field of chemical industry, to detect gases, artificially imitate glucosamine, biocides, biochemical reactions for fermentation, and biological proteins. And its metabolites purification, genetic engineering, bacteria preservation system, cell proliferation medium, medical, oil, plant, semiconductor, nanofiltration, and manufacturing nano, nano ceramic, nano plastic, nano textile, power generation, Technical field of liquid crystal and biochip. Yet another object of the present invention is to provide a metal complex polymer solution. The technical problem to be solved is to make it more practical, and it can improve economic benefits. It has an improved effect on the whole, and has industrial advantages. The use of compensation. The object of the present invention and the solution of its main technical problems are achieved by the following technical solutions. A metal complex polymer solution according to the present invention includes one or more metal complex polymers. The objective of the present invention and the solution of its technical problems can be achieved by the following techniques. The aforementioned metal complex polymer solution, wherein the metal complex polymer solution is a polymer in which saccharide molecules (including glucosamine) are dissolved by R-C00H and / or an inorganic acid and / or a polymer having a radical and / or a saccharide is used. And the metal salt solution are mixed uniformly according to a conventional method. The metal complex polymer solution described in the above article, wherein the metal complex polymer solution is a polymer in which R-C00H and / or an inorganic acid dissolves a sugar molecule and / or a hydroxyl group and / or a bile, and then adds a metal The salt solution and ammonia or amines are made by mixing according to conventional methods. The metal complex polymer solution just described, wherein the metal complex is polymerized

200530296 V. Description of the invention (5) The product solution is R-C00H and / or inorganic acid dissolved with sugar molecules and / or monosaccharide-containing bimolecules', and then the metal salt solution and ammonia or amines are added and mixed according to conventional methods Made evenly. … The aforementioned metal complex polymer solution, wherein the metal complex polymer solution is an acid of R-C00H carboxyl group and / or alkaline saponification R-c00H having R having two or more hydrocarbon groups such as Fatty acid and / or carbohydrate molecules, and then adding a metal salt solution and ammonia or amines, and mixing them according to conventional methods. In the foregoing metal complex polymer solution, the metal salt solution is one or more monovalent, divalent, or trivalent metal salt solutions, and the mass percentage of the metal complex solution accounts for 0% of the mass of the metal complex polymer solution. 〇1〜20 ％. In the foregoing metal complex polymer solution, the metal salt is beryllium, magnesium, calcium, gill, barium, radium, nickel, chromium, lead, copper, iron, zinc, titanium, manganese, cobalt, silver, gold, Platinum, Palladium, Pickaxe, Lithium, Rubidium, Cesium, Mercury, Tin, Zirconium, Aluminum, Sharp, Antimony, M, Bi, Gallium, Surface, Tungsten, Krypton, Silver, Silver, Rhenium, Thorium, Ruthenium, Baht, Vanadium , Indium, manganese, lanthanide, and actinide metal salt solutions f The foregoing metal complex polymer solution, wherein the ^ CD⑽ or inorganic acid is one or more, and its mass percentage accounts for the mass of the metal complex polymer solution 0.01 ~ 20% of which is a hydrocarbyl group. The aforementioned metal complex polymer solution, wherein the R-COOH is monocarboxylic acid%, dicarboxylic acid, tricarboxylic acid, acetic acid, citric acid, vitamin C, salicylic acid, oxalic acid, formic acid, propionic acid, Malonic acid, lactic acid, malic acid, berberic acid, maleic acid, fumaric acid, n-acid, oxalic acid, lauric acid, adipic acid, tartaric acid, medlar acid, humic acid, humic acid, fatty acids, plants OPINES, carboxyl-rich acid fibers, and styrenic resins such as

Page 10 200530296 V. Description of the invention (6)

Amberlite IRC-50, wherein the inorganic acids are hydrochloric acid, dishic acid, lithocholic acid, and sulfuric acid. The foregoing metal complex polymer solution, wherein the mass percentage of the audible molecule and / or the polymer having a hydroxyl group and / or a carboxyl group and / or a saccharide accounts for 0.01 to 20 of the mass of the metal complex polymer solution. %, The molecules and / or polymers having hydroxyl and / or carboxyl groups and / or sugars are: sucrose, maltose, lactose, trehalose, disaccharides, monosaccharides (containing gas-based glucose); cracked oils; Or artificially synthesized chitin, chitin; seaweed cell wall (containing calcium without metal salts); plants such as rice (existing calcium without metal salts) or monosaccharides such as cytokinin-0-glucosides, namely cytokinin ( Cytokinin) and glucose (glucose) combined substances can promote cytoplasmic division, and at the same time have physiological effects similar to kinetin (kinin). Temporary materials · Erzhuang silk, Bingjian 97 substances, or with ammonia ( Amines), polyvinyl alcohol or polyvinyl alcohol; or humic enzymes that do not require acid to dissolve; oxygen (or humic or humic acid nitrated humic acid, peat or terminalized or 0 · 1 ~ 6 % Hydroxypropyl methylcellulose Sin or 〇 ″ ~ _ via propylmethyl fiber = :: monochitin; · or X synthetic chitin with ammonia (or amine) substances, or hydroxypropyl methylcellulose; propyl 曱Cellulose; or a mixture of the above having a hydroxyl group and / or a carboxyl group and / or one or more of the above with an oil or with a sugar. 3 Carbohydrate polymer polymer The aforementioned low-molecular metal complex polymerization (containing glucosamine) or a monosaccharide-containing disaccharide Eight a liquid, which is characterized by a monosaccharide molecule 77 metal metal polymer solution

200530296 V. Description of the invention (7) ii not having a bridging linking agent and / or an inorganic polymer carrier and / or fiber,) / fiber containing carboxylic acid though carboxyl group or modified carboxylic acid rich in carboxylic group: ί f The non-metallic person is a right-misplex polymer solution, wherein the metal complex polymer solution contains / does not contain a hygroscopic agent bound to the complex. "The aforementioned metal complex polymer tincture or the combination with the complex; the polymer bridge described in U is connected to a white enzyme or a bacterium or a Γϊ: physical solution, characterized in that it contains / does not contain eggs. The metal complex is assembled in a factory and / or a sub-product of a polymer with a warp group. The valley is a polymer solution of rice powder. The polymer contains / does not contain silicic acid and / or Nai Metal complexes are mixed together. 4. The hafnium solution is used in the manufacture of nanomaterials. It is characterized in that the metal complex polymers are used in the gas, liquid _ = benamic ceramics or nanoplastics or nanoweavers, hydrogen peroxide, nitrogen, if, The body contains ozone, strong oxygen 〇-2 or 〇2-, acid, boric acid, sulfuric acid, sulfuric acid: sulfur and sulfur gas, phosphoric acid, hydrochloric acid, hydrofluoric acid, phthalic acid, and lycoic acid. Human chlorine Acid, digas acetic acid, m-benzene, the aforementioned metal complex polymer,: J black, bone, pearl, dental braces. "Liquid in nano plastic or Nile = 'It is characterized in that the metal complex polymer dissolves the aforementioned Metal complexes, plastic or rubber polymers in the application. , Characterized in that the plastic polyaniline, polystyreneamine, polyethene, polyethene, polyoxyethylene, epoxy resin, epoxy resin, polybutadiene styrene, -oxygen described in Yin Shuyue Yue, ㈣ Resin, Polyester, Polyacrylamide, Page 12 200530296 V. Description of the Invention (8) Polyacrylate, polyester, polyurethane, polyolefin, polyvinyl butyral, Ishiba , Merging. E.p.Q resin (p N 0), rubber, butadiene rubber, silicone rubber, polyethylene. 0 burned ketone, etc. or its precursors or their homologues or modified or blended above. The metal complex polymer solution described above is characterized in that the metal complex polymer f solution generates oxygen anions in the oxidation reaction, condensation reaction, oxidation condensation reaction, biochemical reaction for fermentation, purification of biological proteins and their metabolites, bacteria Health protection subsystem, genes and vectors, cell proliferation medium, detection gas', metal enzyme biocatalyst, oil products, fermented nanomaterials, = ceramics, nanoplastics, nanotextile industry, liquid crystal manufacturing, Production of chemical substances in plants, nano inorganics, 物: The application of enzymes to increase activity, biochips, treatment of waste solvent liquids, and removal of winter agent oxygen contains chitosan metal complexes. The purpose of the present invention and its main technical problems are solved by using the following method. The present invention has obvious advantages compared with the prior art. The advantages and benefits of the present invention have been achieved. The main technical contents of the present invention are as follows. ^ A metal complex polymer solution proposed by the present invention, saccharose, or maltose; or lactose; or seaweed Sugar; or disaccharides; or cracked oils; or synthetic chitin; crustaceans' early mornings; numbers or monosaccharides such as cytokinin-〇-glucosides · plants such as rice or polyvinyl alcohol solution must be combined with ammonia (Or amines) substances such as poly peat, humic acid, humic acid solution must be combined with ^ ethyl hydric alcohol; no need to dissolve or nitrate humic acid, humic acid; (or amines) or other polymers (Chemical-OH) n's functional group solution should be mixed with helium (or

200530296 V. Description of the invention (9) Amine); ίΐϊϊΓ ~ sub-chemicals—OH functional solution of the functional group itself has already been taught; 30% 4% mixed with hydroxypropyl methyl cellulose ; Or artificially synthesized chitin 1 ~ 4% mixed with 0.1 ~ 6% of hydroxypropyl methylcellulose; or hydroxypropyl methylcellulose must be combined with ammonia (or amine) substances; or, standing Propylmethyl cellulose (when it is a cleavage reaction solution, it does not need to be compounded with amino or ammonia or amines); or most of the above-mentioned compounds have a high molecular weight or oil or sugar; It dissolves with acids (including organic and inorganic acids such as acids with _COOH group) and water, and then adds acidification or gasification or hydroxide (referred to when nitrate sodium humate) or inorganic monomolecular, bivalent Or trivalent metal ions (can mix two or more divalent metal ions), mainly bivalent metal ions, other ions can be achieved by heating, or the following methods, such as heating and mixing uniformly; or metal with a small radius Ions must be mixed with other metal ions and added to the "or, after the amount of iron ions are semi-fermented, and then Add metal ions that are difficult to bind to make it / ferment; or adjust the pH value to make the wrong combination, the structure tends to be stable, etc., f Add the above 1 ~ 4% ammonia (or amine) substances, and the existing ammonia ; Base (such as = or mixed with chitin) need not be added, uniformly mixed or searched out at high speed, condensation reaction solution or tritiated condensation reaction solution (local or separate Qin mixed ° gasification or hydrogenation (referring to When nitric acid sodium humate) or inorganic high-acid acidified ions have the ability to oxidize the gas), stirring will produce sufficient bivalent iron to stabilize it. This reaction solution can be sealed in a closed space with Pan's knot #state mode straight

Page 14 200530296 V. Description of the invention (10) Ceramic structure with pVA — SI— M crossbody (see ###) as the catalyst carrier, which will be condensed by spraying the processing gas or mining inorganic polymer. The reaction solution or oxidative condensation reaction solution or other reaction solution is added with PVP K-30 with a content of 0-1 to 3%, in order not to affect the reaction solution of the complex body, but to combine with the complex body ^ Hygroscopic agent, to promote the complex body The hygroscopicity is different from the single mixed type hygroscopicity, because the mixed-type hygroscopicity cannot make the wrong body enter the liquid phase reaction immediately. Without any hygroscopic agent as follows: Polymers with hydroxyl or amino groups are a mixture of 1 ~ 4% chitin and hydroxypropylmethylcellulose of 0 ~ 6%, and work into chitin 1 ~ 4% with The mixed cellulose of propylmethylcellulose of 1 to 6 ° must be compounded with a small amount of ammonia (or amine) substances, and independent hydroxypropylmethylcellulose. i agent search and mix evenly, then cover this solution with soak. This soaked pottery can be used to dry and remove water. It has a volatility of ^ i or more, or becomes a ceramic catalyst in a dry state. It has a molecular weight similar to that of condensation solvents at room temperature. It has a molecular weight similar to that of oxygen organic solvents =: 3 organic solvents. And other gases and

Become a waste solvent processor. Each agent of the machine is condensed into a solid state of the clay, and in addition, the chitosan (chitosan, chitosan) and artificial complexes referred to in the present invention also include chitin (also known as shell-form chitin), which is commercially available from shrimp. 2. Crab shells Page 15 200530296 V. Description of the invention (11) Extraction preparation and artificially synthesized products. The main f quantity of raw material chitin is deducted from k, such as water and color damage, gray damage, degree of point, dissolvability, etc. The preparation of the condensation reaction solution or the oxidation condensation reaction solution and the sensitivity of the reaction solution are closely related. Therefore, the present invention requires that the raw material chitinous corpse: The water content < 20% 'ash < 10%, than The thick logarithmic viscosity is ~ 5.5, and it is required to have good solubility; the concentration of chitin in the condensation or oxidation reaction liquid prepared by this method is generally 0.1 ~ 10%, and the preferred concentration is a chemical state with the same chitin and Functional chemical combination containing hydroxypropyl methylcellulose (HPMC) and amino group: substance, 5 ΐΪϋΪ: when the medium? Gold ion catalyst 5 ^, so that propyl methyl cellulose can be mixed with ΝΗ3 When hydroxypropyl methylcellulose (HPMC)] ^ 01! Functional Group, in which hydrogen is dehydrogenated by metal and dehydrated NH 2 can be combined with propyl methyl cellulose (HpMc) to form r 1 m when “chitin? Solution and chemical state and chemical molecules, = body support. The artificially imitation chitin solution is converted to %%, so that: Further fermentation causes the metal to bite into the liquid phase, or burn or carbonize, and so on. 'Nanometallic liquid crystals belong to oxides, and j fermentation systems can also be developed. Are similar to the above principle, regardless of whether the large and low molecular polymers or disaccharides or monosaccharides or monosaccharide bimolecules are 2 gold

200530296

It is a fermenting system with low and medium metal polymers and metal complexes produced by the combination of a salt and a combination of a stilbene and an amino group. Application of fermentation system to biocides, artificial imitation of glucosamine, biochemical and original fermentation, purification of biological proteins and their metabolites, genetic engineering, culture medium for anti-cell proliferation of bacteria preservation, medical treatment, oil products, nanofiltration, Manufacturing Qi, materials, nano-ceramics, nano-plastics, nano-textiles, artificial imitation nail materials, metal enzyme biocatalysts, plants, semiconductors, power generation, and * chips. The concentration of the above-mentioned hydroxypropylmethylcellulose leaching solution in the Japanese biological field is 0, and its application: acetic acid or other acid: hydroxypropylmethylcellulose or other (chemical, Real — H) n polymer: acidified or gasified monovalent, two things according to 97: 1 · ι · 14 „0. Belle monovalent metal ions 1 · 1 · 1 and 88: 4 ·· 4: 4 Intervals are prepared in proportions, and then ammonia (or amines) is added. Those who already have amino groups are added in steps to add bacteria or enzymes or smaller nucleic acids or parts. With the addition, you can: the yeast grows to 1 in biochemical Compared with the traditional technology, the present invention has the advantages of faster reaction speed to the solvent gas or liquid compared with the traditional technology. Compared with the traditional technology, the present invention can be used at normal temperature without any large financial and material resources. Beiyingyinggao invention has high safety, no need to set fire, no industrial safety for a long time, no issue: long storage period, not easy to be damaged, service life is not ϊΣ 、 4, there is anxiety because of contact with the media. The long question, Fafayue solves the problem of organic solvent treatment and the fermented field surface decides the chemical industry Oxidation, condensation capacity of the fermentation gas

200530296 V. Description of the invention (13) Various problems of reaction bottle tightness such as force and cracking ability. 5. The present invention creates a chitin solution artificially imitated with metal ions, which increases the source of chitin and multiple applications. 6. The present invention creates detection gas, artificial imitation glucosamine, fungicides, biochemical reactions for fermentation, purification of biological proteins and their metabolites, genetic engineering, bacteria preservation systems, medicine, oil products, plants, semiconductors, and applications. New medium for cell proliferation. ‘7. The present invention creates new technologies for nanofiltration, nanomaterials, nanoceramics, nanoplastics, and nanotextile manufacturing. 8. The invention is a good metal enzyme biocatalyst. 9. The present invention creates new technologies for power generation, liquid crystal materials, and biochips. In summary, the metal complex polymer solution of the special architecture of the present invention has many of the above advantages and practical values, and there is no similar architecture design published or used in similar products. It is indeed an innovation. There are great improvements in architecture or function, great progress in technology, and easy-to-use and practical effects, and it has a number of improved functions over the existing metal complex polymer solutions, so it is even more It is suitable for practical use and has extensive industrial use value. It is a new, progressive and practical new design. • The above description is only an overview of the technical solution of the present invention. In order to be able to understand the technical means of the present invention more clearly, and can be implemented according to the content of the description-the implementation of the preferred embodiment of the present invention in conjunction with the drawings will be described in detail later. . The specific implementation mode of the present invention is given in detail by the following embodiments and the accompanying drawings. [Embodiment]

200530296 V. Description of the invention (14) --- To further elaborate on the technical means and effects adopted by the present invention to achieve the intended purpose of the invention, the following is a combination of the drawings and preferred embodiments for the metal complex according to the present invention. The polymer solution and its application, the specific implementation mode architecture, characteristics, and effects are described in detail below. Refer to FIG. 1 for a schematic diagram of the structure of RMNH2 used in the present invention, that is, the hydroxyl group of hydroxypropyl methylcellulose (HPMC) is dehydrated with a metal, and R − is inserted after the amino group is inserted. Please refer to FIG. 2, which is a structural diagram of the core 2_ used in the present invention, that is, the chitin and the metal solution are directly reacted.丨 »Please refer to FIG. 3, which is a process of forming an amino-containing polymer metal complex and an amino-containing polymer metal enzyme complex in the polymer metal complex of the present invention, that is, firstly polymerizing low, medium and high polymer React with the metal ion to obtain a polymer metal complex, and the polymer metal complex further reacts with an amino group to obtain an amino-containing polymer metal complex, the amino-containing polymer metal complex having a -C00H carboxyl group Further fermentation with protein enzymes to obtain amino acid-containing polymer metal enzyme complex. Refer to FIG. 4 for a schematic diagram of the structure of the "bow" arrangement of maltose in the present invention after adding a carboxyl group of an organic acid, a metal salt, and an amino group. • Please refer to FIG. 5, which is an example of the monosaccharide disaccharide contained in the plant before Cytokinins (Cytokinin) in the present invention before the monosaccharide-containing bimolecular organic acid, metal salt and amino group without carboxyl group is added. A series of molecular schematic diagrams. Please refer to FIG. 6, which is an infrared photocurrent generation mechanism in the oxidation reaction semi-guide film of the biomass energy generation of the present invention. The preparation of the polymer complex structure formation solution proposed in the present invention includes the following steps: Page 19 200530296 V. Description of the invention (15) Steps: 1. Use organic compounds containing 1 ~ 10% acetic acid or other acids (including acids with -c00Η carboxyl group) And inorganic acid) as the solvent, after stirring and dissolving at a high temperature or room temperature or below room temperature for a certain period of time; 2. Formulated with 0.1 to 10% or sucrose, or maltose, or lactose, or Trehalose, or disaccharides, or monosaccharides, or cracked oils, or synthetic chitin, chitin, or. Ya 1: 〇1 ^ 11111-〇1111. 〇31 (165 (.71: 〇1 ^ 11: 1113 refers to 〇71: 〇1 ^ 11111 is a substance that binds to glucose, which can promote cytokinesis and few cytokiniesis :), and has similar physiological effects as kinetin) Sugar bimolecules, or polyvinyl alcohol solution should be mixed with ammonia (or amines) substances or polyvinyl alcohol, or nitrated humic acid or humic acid solution should be mixed with ammonia (or amines) substances, or dissolved in humic acid, or humic acid,% Or other polymer (chemical-OH) η functional group solution with ammonia (or knee substance, ― class) or other polymer (chemical-〇Η) η functional group solution itself already has—NΗ2 ammonia or chitin 1 Mixture of ~ 4% and hydroxypropylmethylcellulose from 0.1 to 6%. Based on artificial or synthetic chitin 1 ~ 4% and hydroxypropylmethyl hydrazone to α '• Materials, raw materials, or hydroxypropyl methylcellulose must be combined with ammonia (or amine) substances, or independent hydroxypropyl methyl cellulose (when it is a cracking reaction solution, it does not need to be equipped with amino or ammonia Or amines), or most of the above mixed slurry; ΰ 3, and then add 1 to 4% acidification or gasification or hydroxide (Refers to nitrification humus

200530296 V. Description of the invention (16) ------- When sodium ions) or inorganic polymer monovalent, divalent or trivalent metal ions (can be more than two divalent metal ions); mainly divalent metal ions The compound mouth can be supplemented by heating, or using the following methods, such as heating and mixing sentences; or metal ions with a small ion radius must be mixed with other metals; or semi-fermented with a small amount of iron ions, and then Add hard-to-combine gold to make it continue to ferment; or adjust the PH value to combine with the wrong body to separate from malaria, ancient soil and soil. 4. Add the above 1 ~ 4% ammonia (or amine) substance. Generally speaking, ammonia is the main ingredient. If ammonia is not available, ethylenediamine or other amines can be used to supplement the existing amino groups (such as chitin or mixed with chitin). Do not add. Mix evenly or at high speed. Stir and mix to form: a condensation reaction solution b oxidation condensation reaction solution: locally (mixed with iron ions and other metal ions) or separately add the aforementioned metal ions 0 · 1 ~ 3% of 0 · 1 ~ 100% acidified, or gasified or Hydroxide (referring to sodium nitrate humate) Complementary or inorganic polymer divalent iron ions have the ability to oxidize the gas, and fierce ions can also be oxidative condensation reaction liquid. C The more oxidation solution is added, the stronger the oxidizing capacity, and finally the oxidation reaction liquid is generally an ideal upper limit It is 100%, because the chitin is positively charged if it is an existing amino group. The composite metal iron ion (a mixture of iron ions and other metal ions) can induce reverse push-pull to generate negative electricity in the reaction gas during chelation oxidation. An oxidation reaction occurs on board. Negative ions are generated on oxygen and oxygen negative ions are generated. At this time, there is a complex metal iron ion state when the main body is chitin or humic acid, so

200530296 V. Description of the invention (17) The carrier made without the need of %%, chapter sword 5, and then the remaining eight Λ dry type sensitivity is high, you can use it. # ϋ $ U 醢 0 reaction solution or oxidative condensation reaction solution or oxidative reaction / combination or decompression, and intersperse ΛΛτ. 伊 ee and; s your content ο · 1 ~ 3% ρνρ κ—30, is not The shadower 2 times ..., the hygroscopic agents dissolve evenly with each other. Or do not use any hygroscopic agent. 5: 1 ~ 4% of oyster is mixed with hydroxypropyl methyl cellulose of 0.1 ~ 6%, I ,. 1 ~ 4% of chitin and 01 ~ 6% of hydroxypropyl methylcellulose J Ξ The methyl cellulose must be mixed with a small amount of ammonia (or amine) substances, j ► independent hydroxypropyl methyl cellulose Cellulose. Then confiscate this liquid, Fen λ, * τ-M for the county, and participate in the secondary transparent coated nano-inorganic polymer 'present PVA one * eight 41 people, see the latter paragraph for details): the architecture In the body, Taumann and the reaction solution "then dry the coal" to strengthen the anchoring force by the viscosity of PVP K-30, and the wet deliquescence makes the carrier easy to absorb moisture. When the carrier is dried in the wind by anti-gas field, Due to the non-high sensitivity of the condensation reaction liquid in the liquid phase (aqueous) reaction, the sensitivity in the anhydrous dry state reaction is very poor, but the reaction sensitivity in the anhydrous dry state is very high as described above. Because chitin is charged with JL, mixed hydroxypropyl fluorenyl cellulose is pulled by metal ions [['It will tend to absorb the chitin's amino group and lead to electron free, so the sensitivity will increase to' No water or gas is needed. Synthetic chitin, chitin, or polyvinyl alcohol solution should be mixed with ammonia (or amine) substances, or humus, and the solution should be mixed with ammonia (or amine) substances, or two other molecules (chemical -OH) n functional group solution mixed with ammonia (or amine

Page 22, 200530296 V. Description of the invention (Class 18)), the functional group solution itself already has -NH2 ammonia or other polymer (chemical-0! 1) 〇 groups need water vapor, or as the case may be (When, the official produces deargonization so that the dehydration reaction is coordinated-NH2 and metal ions metal complex (for organic solvent gases), or the body :::::: oxidative cracking and condensation polymerization reaction, so there is 30 in the liquid solution. Deliquescence and high humidity (aqueous), or == K- This removes the carrier gas of the organic solvent gas to operate and break for _ months or even-more than a long time; = often smooth, can last ^ need fermentation Add bacteria or enzymes or nucleic acid or cell body carrier for various uses. The above-mentioned functional solutions of PVA or other polymers (chemicals-0H) n, or functional solutions of other amidine molecules (chemicals-0H) n Already-NH2 amino, or methyldegradation, or humic acid, or hydroxypropyl methylcellulose have the following fermentation (the first three are not necessarily or fermentation depends on the addition of sugars as accelerators, if its (R- 〇H) n is an approximate carbohydrate structure. In the structure of the metal complex, there is coordination of amino groups, the molecular chain contains non-faced atoms, and has a special helix phenomenon, which can be fermented. The composition of methyl methyl cellulose (HpMC) combined with metal ions and amino groups has high efficiency and long-term stable fermentation characteristics. When metal ions are used as a medium to pull, hydroxypropyl methyl cellulose can be mixed with NH3. R—OH functional group of hydroxypropyl methylcellulose, hydrogen is dehydrogenated by metal ions and combined with dehydration to form R-M: 200530296 V. Description of the invention (19) a When the amount of metal ion reaction is small ϋρι # c: Read the structure Not tight, when the amount of free radicals of metal ions is equivalent, the degree of dislocation is relatively increased, and the oxidative condensation characteristic 4 is increased by two, and the catalyst is sensitive. B When the metal ion reaction is quite far away, the etiquette structure is tight. When the amount of base reaction is equal, the error is c. When the amount of metal ion reaction is too high, and the number of reactions between the two groups is equal, then there is precipitation. With amino, It can make the free electron A birch, e Λ pass; for ^ ^ Tunding eight increase to the oxidation reaction, it will generate negative ions on oxygen and produce oxygen negative ions., So that NH 2 can be combined with hydroxypropylmethyl_dimensional preparation仏 人 r. ^ Τ 丞 Cellulose scaffolds are semi-bound to R-M-NH2 3 amino groups. When the reaction amount is not too much with the (metal) ion reaction amount, many metal ions half-bridge one -R body, which is connected to the hole. Migration of the free electrons of the other side is a cleavage reaction and a PVA complex, the degree of polymerization increases, there is a tendency to kneel, the adsorption structure is relatively increased, and high temperature carbonization can be used as an adsorbent; b amino groups together with the amount of metal ions when the reaction is small At the same time, NH2 exhibits the phenomenon of bridging on the polymer metal complex (free beating). At this time, the sensitivity of the condensation reaction is greatly increased, and the dry reaction can be performed. C When the amino group has a small reaction amount and the metal ion reaction amount is small, the R- Gold 1-NH2 cannot be stabilized to form a reaction mechanism, and the two will jump around to form a slow condensation reaction. When the number of bases is equivalent, the stability of lysobacteria and enzymes is high. nitrogen. In addition, when the amino reaction amount is equivalent, it means that the main R-0H can be ionized by metal.

Page 24 200530296 V. Explanation of the invention (20) The dehydrogenation and dehydration of the ions into R-NH2 or the same as (the body itself already) amino-NH2; (Metal ion) When the reaction amount is equivalent, the main impurity R-0H is borrowed. When metal ions are dehydrogenated and dehydrated to form a stable polymer metal complex, too few metal ions will cause the complex to be unstable. Too many metal ions will generate excessively complex precipitates. It is known from this that the number of metal ions and the number of amino coordinations cause a distorted shape of the sample, so that the push-pull electron flows to the reaction mode of the moving catalyst to the gas or chemical substance. These reaction mechanisms due to the wrong structure, push and pull electrons are both electron acceptors or donors, not hydrogen ion acceptors or donors, and they are not several reactions in the neutral state, but the catalyst state. Unlimited reactions. At this time, it is the same as the chitin chemical solution and the chemical state and chemical molecular structure. It is a polymer complex and becomes an artificial f-formic salty solution containing metal ions. Then, after adding bacteria or enzymes or more Tiny nucleic acids or 4 viable cell bodies do not need to consider their nutritional sources and metabolic issues. After a period of time (time is determined by the size of the reaction tank, usually two weeks), the enzymes excited by metal ions are shaken after Activity, NH2 tail is connected with white enzyme, (amino polysaccharide) is like molasses, fast fermentation 2 ultra-high concentration of highly active cell body or bacteria or enzyme or nucleic acid is immobilized into a biochemical solution with cell body or bacteria or enzyme or nucleic acid. Whereas the solution of chitin made in hydroxypropyl methylcellulose =, the stability of bacteria or enzymes is high, the life is long, and it is not tolerated; when the sub-quantity is lower, such as below CPS400: Chitin — # 'easier to saccharify' into glucan, the bacteria are not easy to be permanent, life expectancy is about -years, -normally normal pure crustacean · zymase brother life is very short, but now after adding metal ions, the life is also

200530296 V. Description of the invention (21) -____ For one year, humic acid can be added to metal ions for a long time. But hydroxypropyl methylcellulose CPS400 life can also grow very common chitin-comparison of compatibility with the human body: into imitation solution 'eg: when the body is stable, it can be suitable for the human body Above CPS400 ... Such as medical gauze; and if CPS750 00, the higher the CPS, the degree of disorganized polymerization a dissolves in water with dispersibility, but the life is infinite and permanent • tends to pro-free or enzyme or nucleic acid storage system 、 Replication system: Synthetic cells, biochemistry, agriculture, fisheries, animal products, etc. 曱 :: 2 :: Erzhuang Factory 翌 considers the biodiversity environment, including: solutions can be used. It is used in the state of "main or two enzymes below PS400" or "enzyme state", and some of them are recommended to use UCPS400 for the following years. If they are not dried by freezing and spray-dried into solid, do chitin application processing. From 7 :: ：：： The higher the wrong body, the longer the stability and stability of the bacteria, the lower the amount of the wrong body, the lower the stability and stability of the bacteria, because the molecular weight is higher than the wrong body, the electrons in the wrong body have more free space, hands and feet The pitching (electron) force is larger, the contact frequency is shorter, the molecular weight is lower, the free space of electrons is smaller in the wrong body, and the hand-foot pitching (electron) force is smaller. There are more cheek rates. Each has its own advantages. Hand-foot ball (electronic) force is greater, the frequency is shorter, the person with lower frequency has stronger shrinking and aggregation ability, hand-foot ball (electronic) force is lower, the frequency is more numerous, and the oxidative cracking ability is stronger, which can be understood from the experience of the examples. @ From the above, it is known that from the condensation reaction to the oxidative condensation reaction to the negative reaction, the conductivity is different after the reaction solution is formed into a thin film at each stage.

Page 26 200530296 V. Description of the invention (22) Low electrical conductivity in the combined reaction, high electrical conductivity in the oxidative condensation reaction, medium electrical resistance, moderate friction during the oxidation reaction (clean gas transmission), high negative ion conductivity and low electrical resistance ( Normal film is non-conductive), so we use different reactions at different stages with different adaptation gases and different resistance areas. When reacting with polluted gas, 'different reactions at different stages have different resistance floats. When the condensation reaction is made into a dry adsorption reagent, When the air suction tube has a fixed weight and fixed resistance value, the air exposure of the air suction tube is started. The solvent gas is sucked and reacts to form suspended colloidal particles to be fixed on the adsorbent. The resistance value of this straw increases, the higher the concentration of the solvent gas, the more the quality of the solvent gas inhalation becomes more suspended gel. The higher the resistance value, we use the mode of how much the resistance value is increased to compare the increased mass. , And then calculate how much concentration (in the case of a single medium molecular gas, The body to the level of awareness with THC). The oxidative condensation reaction is the same as above (a single medium-molecular gas, high stability gas' has no free radicals, and when it is first oxidized and condensed, the similar composite gas is recognized by the total hydrocarbon level). Negative ions are generated during the oxidation reaction. When the film is formed with friction (clean gas permeates), negative ions are generated. The conductivity is large. The resistance is small. When a contaminated gas is reacted and the negative ions are consumed, the conductivity is small. If you increase it, you will know how much the concentration disappears. 'When the clean gas passes through, the concentration value will be zero. When you consume it, you will know the concentration. (When using a single low-molecular gas, the same complex gas is recognized by the total hydrocarbon level.) For example, the molecular weights of the hydroxypropylmethyl cellulose systems cps75000 and cps400 in Example 5 are of different viscosities, resulting in larger molecular weight complexes and molecules.

Page 27 200530296 V. Description of the invention (23) Small amount of wrong body 'both condensation reaction and oxidative condensation reaction, in which the metal salt uses copper sulfate to increase the conductivity, and under the same formula, the resistance curves of different reactions are arranged. 'It is more necessary to use instruments to correct the relative relationship between resistance and mass increase and gas concentration', and then microcomputer calculations show the correct data. The negative ion generated in the oxidation reaction was used as a probe in Example 丨, similarly as above. For different types of f-combined gases (referring to medium-molecular solvent gases and low-molecular gases such as SOx and NOx), the application of Example 2 oxidation reaction to generate negative ions can be used as a probe to generate negative ions for the friction of its film against low molecular gases. In addition, there is also an emulsification condensation reaction for the characteristics of medium molecular gases, and its own electricity 'and ::, can detect the concentration of total hydrocarbon consumption of different types of composite gases, such test polymer gases such as plastic, polymer The gas needs to be strong, and then the gas is removed by oxidative condensation reaction. To deal with the resistance curve and concentration relationship of the trowel knife milk, another set of applications for measuring the carcass concentration is needed. The sensitivity of the gas resistance can make the chemical gas more clear. @ Further, fermented on the polymer metal complex, developed into a metal enzyme Ϊ = system metal enzyme is a fermented enzyme compound plus ΐΐΐΐ, brother life is limited, but high The fermenting enzymes of molecular metals (such as via the two-methylcellulose system) have an infinitely long life and activity. It is a high-efficiency and high-level gold-containing compound> 1 Biocatalyst. Various reaction solutions are specially made of metal-containing biocatalysts according to the reaction mode. The catalysts have the opposite effect on gas or chemical substance treatment. This solution can be added with other precipitants or alkali. , Or add an excess of metal to precipitate, or add an adsorbent to promote precipitation and turn it into a solid state enzyme biocatalyst. Page 28 200530296 V. Description of the invention (24) It is known from the above that the content of -C00H Carboxylic acid dissolves chitin or hydroxypropyl methylcellulose or if humic acid already has a carboxyl group, and R — NH2 contains an amino group, so the entire solution has both amino (basic) and carboxyl (acid groups). The so-called positive and negative molecules' drive the thixotropy of the entire solution. In the formation of dislocations, the negative molecules and adjacent positive molecules gradually develop into dozens or hundreds of units of dislocation tissue, just like the organization of proteins. Amino acids also have amino (basic) and carboxyl (acid groups). The connection line is a straight line, and the chain formed is rolled into a circle, forming a unique form of each protein. There is a great compatibility between the complex solution and the positive and negative forms of protein tissue, and it develops into a carrier of protein materials such as cells, bacteria, enzymes, nucleic acids, DNA, RNA, etc. When chitin (the one with an amino group) is bonded as R-NH2- (metal ion) complex structure 'Humic acid and hydroxypropyl methylcellulose (-0H-based dehydrated) are bonded to R-metal ion-NH2 complex structure, and the electron migration and flow direction of the two are different. Causes the catalyst reaction and sensitivity to be different. The compatibility of proteins is best if the potentials of the proteins are compatible with each other. @If the solution is not dissolved by a carboxylic acid and a fatty acid is the main component, a micrometal complex containing amino groups is formed. That ’s not suitable for bacterial protein growth. It has the function of inhibiting bacteria and develops into a fourth-order ammonia salt. It is suitable for killing Qi. Take butter as an example. After saponified butter, it becomes sodium salt, and trace metal ions. Under the traction of the amino group, it becomes a complex body, and becomes a complex body salt with multiple functional groups. Under the strong traction of NH2, it becomes a strong agent. 'Supplemented with dilute sulfuric acid as a penetrant, it can be made into a paste, a liquid agent, and an office agent. ^ Skin treatment Treatment, environmental purification. This amino-containing fungicide is reported to be easy to attract bacterial proteins, but bacteria without carboxyl groups cannot replicate and are polar. Page 29 200530296 V. Description of the invention (25) ^, will stabilize the bond strength of the protein configuration such as hydrogen bonding, Ionic bonds, hydrophobins, watts, and other secondary bonds are destroyed by the bond strength: make good fungicides. S Natural, Xiao Mi ', so it is a non- @ Other polymer (chemical-0H) n functional group solution ^ Physics-GH) _ The functional group itself already exists, the base is a sugar structure such as chitin, Humic acid can only be fermented with the aid of hearing aids. It is not a carbohydrate structure. Iii. There is a special helix phenomenon. Fermentation of 3 asymmetric carbon atoms. "Yes, you can add monosaccharides with" nt ". Both disaccharides have a small amount of sarcosinate, which is the most qualitative and has the longest life span. Such as PVA itself ΐ = =:,! Add some cool acid into it, then add gold in the aqueous solution, and then add sugars such as ϊ =: = add, ammonia water to make the nucleic acid or part of the wrong body is more feasible%: after the second species, add bacteria or enzymes or structure Presented as follows: PVA Dingjin vM = can be preserved and grown, its immobilized M-NH2- proteinase __, Lilang 2 a proteinase-cool, that is, R-PVA has no asymmetric carbon, and the bacteria have a long shelf life. 'For the life of the above-mentioned bacteria with asymmetric carbon, there is no very good replication ability. Another example is Gao Bazi's "can save the life of bacteria" also added acetic acid, pure water, monounsaturated fatty acids, for example, this oil man bacteria or enzymes or even smaller: U water, monosaccharide mixed after sentence ： Cheng, its immobilized architecture shows ^ or 部 # feasible cells Zhao Jiu can ferment Changku's structural bacteria such as preserved fatty acids-M — NH2_ protein enzymes have a long life, in fact, the carboxyl group of fatty acids and 200530296 V. Explanation of the invention (26) Metal ion dissociation, immobilized protein, and the resulting dislocation structure 'can also be used to ferment organic acids. If there is no fatty acid, R' contains other high-carbon molecules. Basal body. In fact, the fatty acid M ^ u multi-carbon R 'cannot dominate the tissue to produce a copy of the tissue M ~ NH2 ~ proteinase-sugar. Such structures are the food source of cells and human body, and account for r & mass (source of amino group). , Fatty acids), minerals (metal ions), proteins (organic acids of the carboxyl group such as Λ enzyme, hearing (rice, noodles), source of acidic cells, all kinds of lemons of the human body), these substances constitute the human body >, Embryonic stem cells, various cells such as neural stem cells, skin stem cells, etc., are matched with the development of different cells in the body, such as acid cells, acids, 2 ~ proteinases-listen to this type of structure to reach = deliberately lack of several bases The acidic substances are then two: the symptom expansion in the body also slows down the cell synthesis in the body. At this time, eat L: to inhibit the development of germs, taking AIDS as an example, long-term treatment control, germ reduction, long-term auxiliary In order to supplement the body's enzymes in the central phase f, the enzymes in AIDS patients are much larger than those in AIDS, and f: f is slowly disappeared from the body during metabolism. Regarding the recovery of kidney cells to talk about I f row or not, and then control it with the above dietary methods, remember to eat carbohydrates, supplemented with enzymes in the kidney cells to treat, slowly recover and become better, so you can use Application in medicine. To give another example, & in terms of seed development, seeds contain lipids (fatty acids), quality (sources of amino groups), starches (sugars), fertilized ovules (nucleic acid white and minerals from the soil ( Metal ions) and acids (with carboxyl groups)

200530296 V. Description of the invention (27) Organic acid), only after the seed germinates and grows up, after growing slowly, the tumor in the plant is an minerals substance, which contains Octopine Family or Nopaiine Family 'as the intermediate carbon (hydrocarbon-based) diene acid It also constitutes the structure of r — μ —nh2-protease-sugar, which enables cells to continue to divide, and can even create important chemicals such as Cytok in in and auxin, and monosaccharide-containing bimolecules, allowing plants to grow endlessly. @ Another industrial oil product contains 0H groups, among which the fatty acid industrial oil is based on the above-mentioned fatty acid-M-NH2 -proteinase-listening structure, among which various types of metal ions are the most safe. The protein fermentation is made into an oily state, which can be mixed with gasoline or fuel oil as an additive. Among them, the fermentation protein is mainly able to promote the burning or decomposition of the oil, and the ions have been nanometerized in the fermentation process. When the engine deflagrates, this fermented protein and instantaneous combustion become nano # 5 'It will completely burn the oil and exhaust gas, increase horsepower and reduce pollution' This nano calcium will decompose the exhaust gas, but will not harm the human body. In terms of lubricating oil, oil-emulsified substances such as fatty acid-M-NH2-proteinase-sugar can also be added, which are compatible with the lubricating oil as an additive. When the cylinder wall requires a layer of nano metal, With the above formula engine, the cylinder wall can be coated with nano metal at high heat. The fermented protein is mainly able to promote slip or loose metal. The metal ion becomes nano metal. It is made of Shao, gold, tin, etc. metal. In addition, food waste oil is used as the engine fuel, as long as fat-fatty acid-M-heart 2_proteinase-sugar is an emulsified oil, among which enzymes can change the volatility of food waste oil and make hydrocarbons compress in the engine. It is more volatile than the medium and then mixed with food waste oil and used as fuel oil. Or if you want to produce special industrial and commercial oils or special function food-grade oils, you can also page ~ "Lai 200530296 V. Description of the invention (28) in a similar way Pan 0

In this way, the above solutions are widely used in oil products. Take oligomeric disaccharides such as carbohydrate as an example. This sucrose is added with _ acid, pure water, metal salt, ammonia water, and mixed with bacteria or enzymes or smaller. Nucleic acids or some viable cell bodies can be fermented to grow. Its immobilized architecture is as follows: sucrose-M-NH 2-proteinase. This type of architecture does not require auxiliary sugars, because it is already a sucrose 'bacteria. For a long time, another protection mode of sucrose is to cut the whole dried cane into small pieces, and the bagasse is not separated. This cane juice will not be damaged, that is, it is protected by the combination of dry cane fiber, and then used acetic acid, water, metal salts, Ammonia is mixed evenly, and it can be fermented by adding bacteria or enzymes or smaller nucleic acids or some viable cell bodies. The immobilized structure is as follows: R-sucrose-M-NH2-proteinase, where r refers to dry cane Fiber (vegetable fiber). If monosaccharides, acetic acid, pure water, metal salts, and ammonia are mixed uniformly, 'does not present macromolecular complexes, only small molecular complexes with a single scattered distribution' cannot be connected into an entire block, and the stability of fermentation is long-lasting. It has very limited properties, and can be used to achieve metal nanofermentation, because the overall current is not pulling each other. The metal nanoforming effect is not good. If you use polymer bridging agent or polymer fiber or inorganic polymer carrier (including inorganic and organic Cross-linking inorganic polymer or nano-inorganic polymer), imitating the principle of dry cane fiber, connecting the small molecular complexes of the branch 'the fermentation and metal nano-metalysis is not good: it can improve the presence of monosaccharides, acetic acid, Pure water, metal salt ammonia liquid bridge linker or plant fiber or inorganic polymer carrier can also be transferred to the formula. R_monosaccharide_Μ_ΝΗ2_proteinase is a polymer bridge linker which is linear and can be used. Online

200530296

If the volume of diglucose is compared with the artificial imitation chitin, it can also become artificial imitation glucosamine. In R-glucose M-nH2, R refers to dry cane fiber and / or coconut fiber and / or palm fiber (plant fiber and / or containing Carboxylic acid fiber) Μ 疋 trace of calcium, remove R, and turn into glucose-trace μ-N mouth H2, micro ㈣ glucosamine, can be used for food health care, cosmetics, emulsification and other functions. @ ί, there is another mode of f. Monosaccharide and single molecule are combined to form a monosaccharide with a single sugar, and then kneaded. Then, it is mixed with acetic acid, pure water, metal salt, and ammonia water. Smaller nucleic acids or partially viable cells have been grown, and their immobilization architecture is as follows: It contains a monosaccharide bimolecule-white enzyme, and the bacteria have a long life span, which can be used to achieve gold nanofaction. The nutrient sources in the matter are light, water, minerals and broken organic hydrocarbons and free ammonia nitrogen in the soil, carbon dioxide in the air, plants will synthesize and carboxyl-containing acids. 0 ^ 1: 〇1 ^ 1 ^ 11- ^ glucosides, the above scheme plus special MA and RNA of plants can produce photosynthesis of plants or conduct electricity (instead of light) to produce a large number of unique plants 2 chemical substances or non-conductive production (It is necessary to change the DNA vector and the adaptive reaction system). Different DNA and RNA in plants use different photosynthetic processes to produce different chemicals. Now we can control the plant ’s DNA and NA, the plant ’s carrier, and the plant. Source of nutrition for photosynthesis mechanism, Plants can produce specific chemical substances. Take a fermentation tank as an example, light, water, minerals, and fragmented organic hydrocarbons and free ammonia nitrogen and carbon dioxide can be controlled according to plant production conditions. DNA and RNA immobilized carriers can also cultivate chemicals in the required plants.

200530296 V. Description of the invention (30) @ In addition, the fiber with carboxyl-rich acid or modified fiber is used to make the fiber with carboxyl-rich acid or resin containing carboxyl such as Amberli te IRC-50, pure water, plant valley such as rice grain The ammonia and water are mixed uniformly, and it can present a polymer complex to ferment. The crushed rice paddy contains glycan material and calcium. The glycan material-calcium-NH2-proteinase 'is R-rice-NH2-proteinase, R It refers to the fiber that has been broken up with carboxylic acid rich in carboxyl (vegetable fiber or carboxyl-containing resin such as Amber 1 i te IRC-50). It does not need to add acetic acid, and the stability and durability of fermentation are very good. The liquid is the carrier-free protease, which is not easy to be stained without purification. It is easy to obtain high-purity and high-yield cells or bacterial solutions or enzymes. The vaccine can be used to achieve the purification and purification of various biological protein enzymes. In addition, R-seaweed cell wall (containing calcium) -NH2 proteinase can also be purified in the manner described above to purify high-purity cells or bacteria liquids or enzymes or vaccines, but complete sterilization measures should be taken beforehand. The other is! ^ —Peat—Calcium-NH2—protein π sugar-calcium binding will not be precipitated, and peat has humic acid ... Upper = characteristic of enzyme-based acid 'so the other one is to complete the sterilization measures of disney coal in advance . Re-I white enzyme, wheat field soil methyl cellulose and humic acid and calcium-NΗ2-egg precipitation and consumption of cellulose and humic acid and calcium mixed into a solid solid after acid-base balance, filtered out and mixed with ammonia After fermenting into hydroxypropyl methylamine in a certain degree in winter, there is a ^ ^ -like structure and R (carboxy calcium-NH2_ proteinase which can also be obtained = fiber or " based resin), the yield of the cell is between the purity and the yield. Or bacterial solution or enzyme or vaccine, another r_

Page 35 200530296 V. Description of the invention (31) Chitin and calcium-NH2-protein high-yield cells or bacterial liquids can be purified by purifying high-purity carriers in the manner described above. No enzymes or vaccines are used. Enzymes to be used The liquid is active, especially some vaccines 2 are put back into the carrier system to bridge the storage of the enzyme solution. The carrier system is accompanied by the entry of nutrients = used for humans and animals. It does not need to be a kind of metal cross-purity purification method, which is the most suitable. This application in culture purification. In the case of biological cells or bacteria or protein enzymes, the oral solution uses the above-mentioned carrier technology β in the case of biological cells or cobalt for non-protein such as bacterial metabolism T. The product culture is the culture and purification of bacterial liquid and materials. The metabolites required for metabolizing growth have a life bacteriostatic Hi 2 contained in the Zhao system, the combination and quantity of the system is the control system, all the way to the situation-different metabolic needs suitable for different carrier systems. Control the growth rate of bacteria, control the nutrients required for metabolism: Thanks to products, such as more carriers, more bacteria will be predatory ^ material is suitable for culture, bacteria is suitable for culture, antibiotic synthesis, = less carrier, less bacteria, nutrition Too much, the metabolic growth is stable, and the output 2 is stable. The half-life cycle achieved by the carrier system of the above technology is not long, and there is almost no limitation. It is a bioreactor that can be separated by a continuous flow 1 stirred reactor or fixed bed reactor or a washing bed reactor or ultrafiltration membrane. Bioreactor for biotransformation, and metabolites are easily depleted from them; the bacteria can be isolated in a micro-transition or sterilization method or other ways to purify metabolites, the other is fatty acid-M-NH2_proteinase- Cool gelatinous semi-solid (liquid with carboxyl group-containing acid) has been mixed with R (carboxyl group-containing acid 200530296 V. The fiber of the invention (32) or Wei-group-containing resin), imitating human or animal cell tissue The concentrated dense bridge is fixed in the interlayer like the internal organs. At this time, the nutrient solution is slowly circulated, and then specific metabolites are cultivated. The above is a metal complex polymer solution in biological cells or bacteria or proteinases and their metabolites. Application in culture purification. @ Another ^ Mixing disaccharide, acetic acid, pure water, metal salt, and ammonia water uniformly can present macromolecular complexes, and the stability and durability of fermentation are very good, which can be used to achieve metal nano-ization. Maltose with no asymmetric carbon has a bow-shaped arrangement of the entire molecule due to the short chain _〇H symmetrical connection. Its "bow" -shaped row can be staggered like a filter cloth and has a strong tension solution. With warp and weft threads, its fine pores can filter nano-elements, and the liquid is dipped in the cloth to form a film and dried to become a nano-filter cloth. This "Bow" series is suitable for those with a smaller atomic radius than J. The formation space of the body is very tight, and the atomic radius is less than that, and the bacteria can not even be accommodated. Other polymer metal complexes can also be used. However, they are less regular, and there are no striped and woven fabrics. In the application of this fermentation series in genetic engineering, because NA-RNA can be copied quickly, unlike many previous complex steps to cultivate DNA * rna, the above eight fermentation systems each have different interfaces. When two different cultivation interfaces are used, DNA and RNA will mutate during replication. Observing the variation 1 'can understand the adaptability of DNA and RNA in different culture tissues, and then understand the adaptability of different DNA and RNA in various cell tissues. In nature, human DNA and RNA are suitable for human cell tissues. Animals have animals that are suitable for plants and plants, and special species that are suitable for specific species. So they can be used for DNA and RNA replication and mutation research. ^ Special page 37 ---- 200530296 V. Description of the invention (33) Gene-cell organization. In terms of the human epidermal cell tissue, external bites, new protein enzymes are injected, and swelling occurs. This is where the performance of genetic insects changes, the size of enzymes, stability or not, and cell% somatic response. The external expression of genes is involved, so that special applications of basal cell tissues can be developed. ® 1 Tian @ chitin exists in nature, repairing body tissues like cells in the human body, such as glycosaminoglycan-protein exists in human tissues > Supplementing metal-containing imitation chitin solution, also It can imitate human tissues, and cell culture, nucleic acid, DNA, and RNA replication. For example, humic acid is more rapid and robust when it develops (inorganic salts) with amino groups than plants without amino groups; such as injured puppy legs Large bones have been exposed, but chitin and metal trace elements are better than chitin alone. Soon, the long meat and long tendons of ancient nails have been restored. 'For example, the cultivation of hydroxypropyl methylcellulose, In the cultivation of single-cell cyanobacteria or yeast, there is no problem. Using insect, acid, bacteria and enzyme solutions to break the insect eggs into the solution, the grown MA and RNA can be reproduced and cultured on it. : Bacteria and enzymes are clearly distinguished. It is proved that this series of solutions can be used to develop various tissue culture techniques. The above-mentioned vertebrate tissue culture medium is comparable to the fermented cell culture without cell populations. This system, Rondi: f;:, can be established without purification Salts (single addition) a 1 丨 After mixing with various inorganic materials, the roots of plants will be moved to hair two. The needs are determined. The cells use the cells to copy the nutrients, the cultivation medium has been cultivated, and the animals are removed. To animal culture, the solution can be mixed with nutrient solution, then the cell tissue

200530296

The fatty acid _M-NH2-proteinase ’is equipped with the enzymes in the chicken body, which will not have any side effects. And stem cell technology and asexual replication technology continue to develop on top of it. Take chicken breeding as an example. A chicken feed agent developed with a framework such as sugar. This chicken can grow in 4 to 5 days, so it can develop a large number of animal and plant proliferation technology. 0 ® In the age of nanotechnology, metal soluble rice must be changed to a level of 10-9 meters, which can usually only be achieved by organometals. Nowadays, chemically produced protein enzymes are almost similar to nanometer or hydroxypropyl methyl cellulose fermentation system enzymes. The state is pulling each other. In the staggered system, it becomes an organic metal, and the (negative) attraction continuously shifts to each other, and it becomes a nanometer grade. This technology is used to achieve a variety of special applications. Generally, the number of metal nanometers is also large. Numerous small and small nucleic acids are even smaller. Metal nano-protease will have different metal crystals. P 'can also create a special crystal phase structure. The lower the wrong body, the higher the yield of nano-metals for bacterial fermentation. It can be maximized by adding about 10% or adding 10% ferment to the amount of metal ions to prevent precipitation. After the reaction solution is dried, it is usually only in 10-6. After the sol-gel method is used, the drag process is also very complicated. However, in the other fermentation systems mentioned above, the R-metal ion-NH2-protein is due to the protein. Enzyme fermentation enters the metal solution into the positive attraction and the reverse to make the metal ions smaller. It can also make various metal ions nanometer. The number of proteinases is relatively small. The number of proteinases is small, and the number of nanometers becomes It can be set that there is a pain & phase, and an egg that specifically eats heavy metals; = the structure of the crystal phase obtained by the higher molecular weight complex and the molecular b is not the same. If you want to add metal ions to the fermentation system, add some metal ions after fermentation.

200530296 V. Description of the invention (35) Those who cannot combine can be heated and mixed; or ionic radius ions must be mixed with other metal ions and added; or a small amount of iron ion should be added first to add difficult metal ions to make it continue to ferment Shape and burn the iron and the metal you want, and then use the magnet to purify the iron and the metal. Or adjust the PH value to combine the wrong body, and the structure tends to be stable. After the flame spraying, the high temperature kills the protease, the mist is dry-refined * ,, and the organic matter is removed by anaerobic carbonization during solution or fire or sintering ::: semi-combustion into nanometer film; becomes metal carbide or oxidized or Decompose by heating in an aqueous solution, and then add the precipitate or liquid in the vacuum to evaporate the compound < = dissolve the compound metal gas, then condense it back or add it after thermal decomposition in an oil pan, or oxidant, 〇__2 " Water cooling precipitation recovery to fly away as CO2, H20, N2 gas. Hydrocarbons and amino groups are decomposed, and finally only nano metal particles or too oxides are left. When composite metals are needed, nanometer metal particles can be further applied or the nanometer oxide powder has the following characteristics: ancient materials, such as degassing function; characteristics, good absorption of solvents: = Gao Zhaoji makes the pore distribution high in the diphtheria: a case 'when sulfuric acid converges and has: J solution :: the medium solution is a prime, and the amino group is made into a catalyst to dissolve the hydroxypropylmethyl fiber to form a button fermentation and the titanium ion reaches Nano Page 40 200530296 V. Description of the invention (36) After coating, the Ti compound in the composite is semi-combustible and tends to form a titanium dioxide powder film. @Metal complex polymer solution added silicic acid in advance, designed as PVA-silicic acid-metal M-NH2-proteinase-sugar, which is silicic acid ~ M-NH2-proteinase-sugar, -0H group of R and silicic acid Co-contamination with metal M, after fermentation, the metal reaches nanometerization, and silicon followers can also be nanometerized, which can extend silicon nitride, carbonization, and dreaming of composite metal nanometerization, and use heat treatment or ceramics in the manufacture of nanometer materials. In the sintering reaction process, nitrogen or hypoxia is added or mixed with other nano-metal staggered polymer solutions to achieve the output of nano-silicide or directly mixed into the ceramic process to produce nano-age composite ceramic materials. Another example is that after fermenting the metal complex polymer solution, the metal is fermented to nanometer, and the fermented metal complex polymer / cereal is directly mixed into the ceramic process during the sintering process to obtain the nano composite ceramic material. How to mix the nano powder evenly in it or want to get pure nano powder? Ί ΐPrecisely study, then heat or sinter and mix evenly, or: The gas should be obtained in the air to get the nano metal oxide 'or add nitrogen to the reaction, just like phosphoric acid According to the metal, fluoric acid can be added to obtain fluorinated metal, and it can be added or mixed directly with Tao Yidao to separate out or crystallize it to produce fermented agricultural nano composite ceramic materials. Nano-re-dispersion process ^ Already powdered = mixed polymer solution (can be mixed in many kinds) is in use, borrowed from a Zhao mill, and hydrated, and then mechanically dispersed and stabilized cellulose Polyvinyl alcohol; Li Tongzhong; fermented husk or hydroxypropyl Yin powder mixed with more stable and stable, Tongbai has the characteristics of a knotting agent, so that points. Illegal forming (pressure forming, casting, casting, and sintering), and sintering, or 200530296 V. Description of the invention (37) Shaped sintering is performed at the same time. The sintered metal body is gathered during sintering. The six liquids will be carbonized, just like the carbon black package combustion. During the heat treatment, the carbon is accumulated & A, and the pressure and temperature are important to control during sintering. The sintering is anti-deer = junction, atmosphere sintering, hot-pressing sintering, and electric discharge. Pulp sintering, ultra-high pressure g fiber hot isostatic sintering, high-pressure gas-phase reaction sintering, etc. If you want to get together, the structure and product must match the suitable sintering mode listed above. The most important thing is that the rice frame must have agglomeration and Grain growth and coarse graining, to obtain a high-quality nano-ceramic metal disorganized polymer solution without fermentation of titanium oxide (fermented by ^ ^ vitamin element system) dried at 50 ° C and 60% relative humidity Geomethyl Ⅰϊϊϋ: Gel is obtained by washing and molding of titanium oxide, ΐϊ surname, # π i-titanite phase to rutile phase transition temperature, that is, the calcination density is> 99% at 600 ° c, and the grain size is only —Nami. Under the condition of 60ηο /, the densification temperature of nanometer is between 800 ~ 1 000 ° C. At 60 ° C, the surname silk contains «. It belongs to the complex polymorphism, which makes full use of the gold in the phase transition: = The function of the liquid, although the temperature is lower at 6 ° 0 ° c, but due to rice ceramics. This promotes the sintering process, and still obtains a dense nano-L solution (all have fallen asleep, polymer solutions or a variety of nano-metal complex polymers. Polyethylene is dispersed into plastic knees or rubber polymers. In the case of polyamine,; substrate = tree: scattered down: etc. as the substrate or co-state plastic G ί: ί Ξ; jy is a polymer liquid and liquid plastic or powder *, including mechanical force dispersion

200530296 V. Description of the invention (38) Method dispersion. Dispersion of mechanical force: Colloidal film is dispersed and stirred at high speed. With the help of mechanochemical action and heating and evaporation, the metal is dissociated and combined with the plastic polymer. Ultrasound dispersion: Ultrasound will destroy the enzyme and dislocation structure of nano metal disorganized polymer solution, so that the strip metal is fully combined with the plastic polymer. 0 High-energy processing method: stir in the colloid or monomer dispersion, with the help of electricity Halo, microwave, plasma, ultraviolet radiation and other radiative chemical action (some can promote fermentation) and heating and evaporation, so that the metal staggered with plastic polymers or polycondensation at the same time. Dispersion by chemical method: add surface chemical modifier or acid gas solution and mix it into nano metal complex polymer solution and plastic polymer to dissociate metal complex and combine with plastic polymer. In the other mode, the nano-metal germanium-rhenium polymer solution and the monomers of the plastic polymer are stirred and combined, and then subjected to addition polymerization reaction or condensation polymerization reaction or cross-linking curing, and then heated and evaporated to make it into a synthetic type. The other mode is to mix the individual original mixture and plastic polymer (or resin containing ammonium group such as Amberlite IRC- or its monomers) of the nano-metal cross-staggered polymer solution before fermentation, and then use fermentation and the above-mentioned feasible dispersion method. (Send privately without interference) or ferment and add polymerization or condensation polymerization K curing (referring to fermentation without interference) 'and heat and evaporate to mix it in another mode nano metal complex polymer solution and polymer The latex particles of Renheru rubber latex are dispersed, and then added:

Page 43 200530296

5. Description of the invention (39) Co-precipitation of the 39 systems, centrifugation or removal of water ', heating, drying and evaporation. However, these all consider the stabilization design of nanocomposite materials. Based on the chemical structure of the polymer and the surface charge of the nanoparticle with broken residual bonds, covalent, ionic, coordination, Or affinity. Select systems with chitin or hydroxypropyl methylcellulose or disaccharides or monosaccharides, or cracking oils or polyvinyl alcohol or humic acid or mixed or other nano metal complex polymer system solutions to promote the reaction, especially Some plastics add some fatty acid-M-NH2-protease-sugar. This system cooperates with other systems to promote fusion. When the polymer is carboxyl, the entire solution has both amino (basic) mixtures to obtain organic amino acids, and then it can be polymerized with plastic or rubber. The above dispersion method can be used alone or in combination with other hot melt extrusion molding. Heating polymer combination, molding methods can be divided into nano-materials such as parting, injection molding, injection molding, etc. The above needs to be thermally resistant to oxidized metal, or anoxic to be mixed with nano-nitrogen metal, and phosphoric acid can be added. Miphos plastic polymer. In addition, R-NH2 contains an amino group, so it has a carboxyl group (acid group), and it is easy to combine with organic clay of clay. At this time, fermentation can also combine with the compound, which has multiple compatibility. It can be mixed and used. The above heating and evaporation or evaporation disintegrates the metal body and presses, plasticizes, and extrudes with plastic. The above-mentioned dispersion method can also be used to produce nano-silicon carbide or nitrogen in the reaction, adding fluoric acid, and nano-fluorinated acidified metal, which can be directly mixed into white enzyme Metal complex poly-composite rubber is made of humic acid-metal compound-NH2-eggrate solution in composite rubber by using mechanical filling example

200530296 V. Description of invention (40) Fully scattered method. The humic acid-zinc_NH2_ protease exists in the form of a rubber matrix, and t plays a role of enhancing the crosslinking. The humic acid-zinc-NH2-proteinases that reinforce the rubber with naphthalene have several characteristics, have certain compatibility with the aggregates, have appropriate reactivity with the rubber, and have the ability to set polymer and ionomer. Homopolymers have better cohesive energy. In order to improve the crosslinking efficiency (including the speed of crosslinking), the structure of the bond.丨 enter more ionic cross-linking bonds), on the one hand, it will be connected and cross-linked with oak, and then heated and evaporated in the mixing and stirring. F surplus is for it to play a reaction. High temperature means that the reaction is already fast enough to high temperature, low is not visible, and / or the remaining nano zinc or zinc oxide is combined in it. The mechanical properties of Ash I, which makes it carbonized, especially the tensile strength, are also high. The zinc-filled rubber is filled with about 10% of nano-zinc, and its vulcanizate is stretched with a strong zeta rubber. Right, this is the highest height except for short-fiber composite rubber. The strength of the solution in nanotextiles. We add nano metal complex polymer solution (granular application, nano-fibrous fiber, and coating treatment, as well as the functional polymer solution extension technology of reed spinning to dye and print. Granulation method using metal disintegration: adding the metal disintegration polymer solution 1 slice ^ " in the process after adding polycondensation-granulation slice-drying-screw spinning-injection method: in the spinning process, use Processing ~ business solution is added to the polyester melt to make the metal complex polymer solution dried in a syringe. The secret method is to inject the metal when the screw is spinning, and the polyester is cut.

Page 45 200530296 V. Description of the invention (41) Sheet-drying-screw spinning ~ post-winding processing-Luyuan. Solution spinning: The substrates used for solution spinning are mostly poly, complex polymer solutions that are directly added to the spinning solution φ / usually the gold can disperse the ceramic inorganic salt into chitin or _ its, Tian, and 1 body Blended 'also fermented in the metal complex polymer solution again, i tt soil patch •, Viking system implantation treatment method: the use of natural fiber surface micro? [Shi, into the spinning solution. Among the fibers, the pores of these micropores have a lot of different colors. The team is different. The surface-treated fibers and inorganic nanometer knots are not large. The polymer solution's activity and natural fiber production are physical, coating methods: the metal complex polymer solution is uniformly applied in the sky # dimensional% ^ ° to become a thick coating film, and then dried and necessary Various functional natural fibers are processed on the surface of heat, fiber, and fibers. ',,,' Can be dyed and printed ... A monosaccharide system of the metal complex polymer solution is R — monosaccharide-M-NH2-proteinase, where R refers to plant fiber or inorganic polymer carrier (including inorganic and Inorganic south molecules or nano-inorganic polymers with frame bridges) have become nano-sized after fermentation. When R (referring to plant fibers or carboxyl-rich acid fibers or inorganic polymer carriers) is missing, it is a monosaccharide-M -ΝΗ2-proteinase. At this time, the protease has a short life span and is less stable. After simple drying and sterilization, the monosaccharide -M-ΝΗ2 is removed. At this time, the M metal has been converted to amino-containing amino acids. The metal substance is in a polar state. It is similar to the azo dye developer ^ -NΗ2 'combined with the base of the azo dye to perform a coupling reaction. The nano metal substance can be firmly fixed on the fiber without any harm to the human body. . For example, the metal complex polymer solution of the monosaccharide system is placed in a carrier filled with plant fibers (which can be bridged). After fermentation, the metal has become nanometer.

200530296 V. Description of the invention (42) The complex polymer solution is extruded from plant fibers under pressure, and the squeezed metal complex polymer solution is at 80. c. Drying with ultraviolet light to sterilize, and then perform nano metal dyeing and printing. The primer in the dyeing is dissolved in water, the fiber is immersed in it to absorb the primer, and then the developer r — NH2 and nano monosaccharide are used. UH2 is mixed with each other to carry out the diazotization reaction to make the organic nanometer metal function and color can be revealed. This is the application of metal complex polymer solution in the nanotextile industry. @The above reaction liquid is a new type of polymer liquid crystal material. This kind of biological liquid crystal has the fluidity of liquid and the order of crystal structure. People_ have found many ribonucleic acids, DNA, proteins, lipids, lipids. Protein, poly = and other biological macromolecules, and all have liquid crystal properties. It is a series of fluorene (such as propyl methylcellulose) with a single-helix, double-helix structure, and double-helix structure ($ 疋) The unfermented complex structure is a single-helix structure. This water-soluble single-helix structure can be used as a liquid crystal, and then t = after fermentation, the protein enzyme is added to the double-helix structure.) In order to be stable, this double-helix architecture does not need to be dissolved, so it is more developmental. This solution is mixed with silver sulfate to make silver nanometer to obtain a liquid crystal liquid with high transmittance and lower resistance in the visible first region, or dried into a thin film. This nano liquid crystal and liquid crystal film Γ electrode can be used in flat display. Yingye is a new type of semiconductor element material. It can be made of natural electronic elements made of protein elements. For example, dna of plants = in the early sugar fermentation system, containing the monosaccharide bimolecule _m_nh2-proteinase, monosaccharide-M. -NH2-Protein-Polymer Crosslinker for Photosynthesis in Plants

200530296 V. Description of the invention (43) The characteristics used to develop organic EL (0rganic Electroluminescence). The enzymes of these two major systems are not so tightly fixed. Enzyme activity can only be enhanced by external forces. Therefore, it is necessary for plants to receive light. Bioelectron reaction 2 grows. If you do n’t give light directly to the electron reaction, the surrounding growth elements must control the dagger to generate a light source for the reverse reaction. This is 70 semiconductors of organic L. In addition, protein wafers are made of materials such as protein molecules, such as the protein enzyme system of polyvinyl alcohol, and the laminated structure of the diaphragm structure is prepared through a special process. For example, the protein is prepared into an appropriate concentration layer, and 'made to develop into a monomolecular layer film on the water surface, and then placed on the quartz rice tin, the same method is used to prepare an organic thin film' can obtain hundreds of nanometer thin Glandular membrane. This film is composed of two organic thin films. When a liter of about 42 ethin of the protease system was irradiated with ultraviolet light, the resistance was inserted, and then left and right, and when it was irradiated with visible light, it returned to its original state. The other protease system to the ultraviolet light Γ is not affected by visible light ’, but its resistance is reduced by about 7% when it is photographed by a complex. A biomaterial combination of two different protein enzyme systems using different metals in a sigma solution was developed in one step. A new type of switching element that can be light-controlled was developed. This kind of thin film is used for the development of semiconductor electronic components, and has been used in semiconductors. . ® Gene and / or "疋 A new type of biomass energy generating material, capable of conducting electricity with a specific interruption. The enzyme must receive light or other stimuli, internally generate electrons to react without electricity, or 'ϊ can form electron accumulation and generate electromotive force Therefore, for example, the enzymes used in plants to generate electricity and slow the fish's internal power generation system to develop power generation 'Zhongshou alfalfa bud seeds are dormant and give radiation such as red

Page 48 200530296 V. Description of the invention (44) Outside light, alfalfa buds germinate. Similarly, we have extracted the genes and enzymes that have just germinated from this alfalfa bud and used it in chitin-NH 2-M-proteinase (for) The oxidation reaction produces negative ions on the system, and it is dry-coated on the electrode plate after fermentation. The electrode plate is coated with a coating that emits infrared light. The other side of the electrode plate is PVA-metal M-NH2-proteinase-sugar system (when conducting Dielectric film), in which the metal is Ru (2) as the sensitizer, followed by the electrolyte, which contains 0.04mol / L 12 and 0.5mol / L Lil, and the other end of the electrolyte is a pt electrode. The infrared light hv excites the alfalfa bud genes and / or enzymes on the chitin system with an oxidation reaction to produce negative ions: the alfalfa bud genes and / or enzyme levels are increased, there is a germination situation, and the effect of the synthetic reaction has holes The oxidation reaction of the chitin system can release negative ions (electron e), and the energy level h is passed through the sensitizer of the PVA system in the electrolyte and the pt electrode for the primary oxidation and reduction reactions, and it accumulates in the semiconductor with the oxidation reaction. The electrons on the nanocrystals of the electrode film are collected on the surface of the transmissive electrode and transmitted to the counter electrode through an external circuit. @ A new type of carrier material automatic fermentation method. The natural inorganic carrier honeycomb hole material can grow a lot of bacteria and organisms. Because there are many minerals and rot free media in the inorganic matter, the new carrier material is made according to the above principle and becomes an inorganic material. The biggest advantage of the polymer carrier containing polymer metal is 1 water. As an example, 7 kg of PV A powder is hydrolyzed into water with 15 kg of dream acid solution and 6 kg of metal brews. The carrier material, the carrier material is dried slowly, and sintered into a ceramic shape. At this time, the structure is PVA-SI-M metal, and an acid chitin aqueous solution containing a soaking group is added to the Taoman carrier material, and a small amount of the chitin aqueous solution is added. Bacteria, slowly knot each other,

200530296 V. Description of the invention (45) PVA-SI-M-chitin, then the bacteria will slowly and automatically secrete ^ ^ ^ So it is fermented on the entire carrier material and becomes PVA-SI-M-chitin-proteinase, At this time, it is the bacteria-containing carrier of the inorganic polymer metal complex. With the inorganic system, it can be used to develop inorganic and organic related applications. PVA plus Shi Xi 酴 ηυ dehydration caused PVA-SI-M-NH 2-proteinase-sugar linker drag ^ ^. In addition, proteolytic enzymes used protein enzymes that can break down sugar, sterilized with alcohol, it is easy to disperse After solution or heating, drying and sterilization, they are all shaped as nano-inorganic high-scoring dm films. -SI-M, there will be no response to silicon precipitation, where si and M are both Fengzhi, τ, and meters. PVA can be changed to other The coating layer of R (polymer) containing -0Η presents the wrong body frame = two pieces: Fu Li, which is a good nano inorganic carrier. It is also made into nano paint, and nano particles are put into this carrier or paint. It is a very reactive reaction structure, so the silicic acid fermented after metal complex is a very good inorganic ^ / nano-molecular polymer developed by nano metal complex polymer solution (fermented). , Hole carriers, spheres are more functional than without nanometers. PVA-SI-Ca is used for stabilization, and PVA-SI-other metals are used for function. This is a metal complex polymer solution in nanometer inorganic substances. Application. 3 @ A method to promote the increase of protein enzyme activity in the dry type. Generally, bacteria and enzymes are in an aqueous solution or a liquid state, and their activity is only manifested, and the response is good. The f energy can be expressed, but in the dry type, the bacteria and enzymes, Either it is dead or dormant, or its activity declines, it cannot respond, and its functions cannot be expressed. The reason why bacteria and enzymes can exhibit activity and function in aqueous solution or liquid is because the medium of water is the living carrier of bacteria and enzymes, and the conductive ions in water. It is a buffer pool for the electronic activity of bacteria and enzymes, so bacteria and enzymes in the liquid have the power. At present, there is a dry system of bacteria and enzymes that can give good results. Page 50 200530296 V. Description of the invention (46). When the above series of reaction solutions have an oxidative condensation reaction, the reaction structure is R-M-NH2, where The amount of (M metal) is trace. In this case, the structure of the protease's bridge is R-a small amount of M-NH2-proteinase, (because) the relationship of a small amount of M is not stable, resulting in the metal μ in each ΝΗ2- Protease (free) beating 'Although it is a dry structure at this time, because the free beating of the metal moves like conductive ions in the entire complex, as in water, the activity can be shown in the dry form, the reaction is good, and the function can be expressed. come out. For example, hydroxypropyl methylcellulose is dissolved in vitamin c. With a small amount of metal salts and a normal amount of amino groups, after adding protease, the activity and function of protease in the stem are still shown. From this space of application of protease It is greatly increased, and it can only react in liquid phase, but now it becomes gas phase and = phase, and it can be reacted. Among them, vitamin C and iron ions play the role of reduction and oxidation. The subflow, too much vitamin C, the valence iron ions cannot be oxidized and changed parameters: nowadays, it tends to condense, because vitamin C has too strong antioxidant power, and vitamin = Too little, the valence iron ions cannot be reduced after the valence is changed, and the oxidizing power is weak, so there is a linkage relationship between the two and the entire complex. @ 液 一 都 种 //// Application of polymer solutions in biochips, the above-mentioned solvents and organic molecules (including without 1% bridge I: ί, Ϊ: ί: or nano inorganic high Molecule) or polymer activity. Through the protein chip technology, you can ::: The physical and chemical properties and protein information in the body, it is a proteome to obtain a large number of biological chips and protein chips. Medium and cold method for the manufacture of metal complex polymer ridge solution printing / jet printing probes and microelectronics industry

Page 51 200530296 V. Description of the invention (47) '---- Microfabrication technology. Such as Xiansha Qiru Xiandai #, ^ m / micro printing, piezoelectric printing (such as inkjet printers, engraving technology, reactive ion etching, micro-injection casting and ^ membrane washing scale method, etc., ^ ^ ^ ^ Micron-sized micro-structures reacted by the substrate from polymer carriers and other substrates. Compared to polymer carriers coated with a layer of plastic insulation film, ^ electric ^ extremely narrow beam controlled by electric machine Focused X-ray beams or electrons are drawn with stripes parallel to each other on the plastic insulating film. =, · The width of the text is several tens of nanometers, and the distance between the stripes is 200-25 nm.塑胶 The part of the plastic irradiated by the beam is dissolved, and the U-meter inorganic polymer is exposed from the gap. At this time, the monosaccharide--NH2-DNA (fermented from plant fibers) is "grafted". Then wash off the place where j glue, edge film and monosaccharide-M-NH2_DNA are attached. If necessary according to the design, then M on monosaccharide-M-NH2-DNA is the metal needed to transmit Denshi f ( (Such as silver). This is the biomass circuit. ^ Microfluidic electricity produced by nano-inorganic polymers as a substrate Wafer. Use the optical f technology to etch the designed flow path, and add the sample to be measured in the microchannel: test, reagent, and protein adsorption surface in the microfluidic wafer increase, the sense of analysis, and the two detection time is less. Protein chips can already fix a variety of active proteins on the carrier; protein engineering has obtained a large number of recombinant high-conductivity proteins for wafer manufacturing. If fermented chitin or propyl isomethylcellulose is used, The production of biochips by the rice system is suitable for micro-printing and waste printing. If DNA conductive strands are to be obtained, the highly distorted body formed by DNA and metal ions exhibits molecular wire behavior, and when the surface of DNA is covered with more metal ions, Is R-monosaccharide-M — NH2-DNA, where R is the nano inorganic high score

200530296

5. Description of the invention (48) The daughter membrane becomes a conductive DNA strand and can be used in nano biological circuits. In order to obtain active proteins, the metal complex polymer solution must be used to make biochips in a dry way to increase the activity of white enzymes. For example, R—Sam_ $ M-NH2-DNA combined with vitamin C and iron metal or other The acid and silver and gold are used to design the biochip. The plant fiber-monosaccharide-M-NH2-DNA (fermented) is used as an intermediate process, and then the monosaccharide-M-NH2-DNA is extruded and printed on the rice inorganic On the polymer membrane, it is changed to a nano-inorganic polymer membrane-monosaccharide __M ^ ^ DNA bridge structure, so that the biochip can promote the activity of protein enzymes in dry mode, and play the biochip in biomedical testing and various aspects. Its application. The nano-inorganic polymer membrane-monosaccharide-Ca —NH2 —DNA on the φδπ biochip is in this state. The metal ion is Ca or a complex Ca metal. The protein enzyme on the chip must have water or be energized to increase activity. The level of proteinase activity on the wafer can be controlled. @ Reactive carrier material, which has been coated with nano-inorganic polymers, has a ceramic structure of PVA-SI &M; 0.3% PVPK—30 is homogeneous to the condensation reaction solution or the oxidative condensation reaction solution, and is injected into the carrier material with the above medicine solution ^ fully absorbed and saturated, and then dried to remove water, drying temperature 9 〇〇c lasts for 40 minutes. It is immobilized for storage. There is no time limit for its preservation effect, and it will not absorb other odors in the free air. The condensation reaction will occur when the organic solvent gas passes through the carrier material. The reaction conditions are that organic solvents or petroleum-based gases or organic solvents have similar molecular weight and similar structure gases, and can react at normal temperature, and can be used with humid (water-containing) or dry air. Another mode of waste solvent gas treatment is to use the condensation reaction chemical solution

200530296 V. Description of the invention (49) or oxidation condensation reaction solution, the size of the gas-liquid compatible reaction washing tower is determined according to the amount of waste solvent gas to be processed, and the solvent waste gas treatment is determined by the reaction temperature of the chemical liquid at normal temperature and the gas-liquid ratio of the washing tower. For example, the 3501 condensation reaction liquid is used as an example. The washing tower water tank has a circular capacity of 500L. The speed of the pump is 20 1 per minute. The washing tower is closed. Only the solvent gas is added and exited. The solvent gas will The reaction shrinks into a plastic film, which finally turns into fine cement, mixed into the liquid or floated around the reaction tank, and the side of the tank is attached with a medicinal solution to wash the reaction transition system, so that the reaction cement can be discharged. The discharged cement can be recovered as a solid fuel. Use, so that is a set of solvent gas treatment methods. > The waste solvent treatment mode is to use the condensation reaction chemical solution or the oxidative condensation reaction solution to determine the size of the reaction tank according to the amount of the waste solvent solution to be processed, and the normal temperature reaction rate of the chemical solution to determine the amount of solvent waste liquid to be added. As an example, the chemical reaction solution of the L condensation reaction has a circular tank capacity of 500L. The mixer rotates at a speed of five hundred revolutions per minute, so that the upper cover of the tank is closed, leaving only the shaft hole of the mixer and the solvent dosing port. Chemical liquid reaction filtration system, so that the cement can be discharged. For example, the amount of solvent waste liquid is 150cc per minute. Dosing is performed by a quantitative dosing machine. The reaction liquid is slowly added in a high-speed stirring tank. The stirring speed is 100 ~ 5 thousand revolutions per minute. The liquid solvent will shrink into a plastic film, and finally become fine cement, mixed into the liquid or floated around the reaction tank, and the cement is discharged through the filtration system. It can be added slowly, and the discharged cement can be recycled as a solid fuel. This is a set of waste solvent treatment methods. The embodiment proposed by the present invention: 1 to 4% of a powder of hydroxypropyl methylcellulose having a viscosity CPS of 75000, and containing 1 to 4% acetic acid or other acids (including having-

Page 54 200530296 V. Description of the invention (50) C00H carboxylic acid and other organic and inorganic acids) and ~ rq〇 /, at the time of ，, made into a transparent solution ^ and a solution and bu 4 «into chlorinated or Gas oxidation of nail polish. Add this, inorganic polymer-valence, divalent or trivalent metal (Kb rot ...) or metal ions or more, locally or separately add the former two kinds of bivalent ~ 80% acidified or chlorinated or chlorinated or Nitrification or inorganic ions 1 ~ 3% of 〇1. Preparation of a few painful virgins, Liu Yulian, early iron ions have oxidative anti-U on the gas The solution and the oxidative condensation react with each other, and the reaction solution and other reaction liquids are converted to 1%. The following are the formulas of various reaction solutions. Example 1 The mass composition of the application of the film after air oxidation to produce negative ions after drying the oxidation reaction solution is: Μ vinegar 1.30% chitin powder 1.30% water 90.6% copper sulfate 3.40% sulfuric acid Iron 3.40% In the above formula, the chitin must be between CPS 100 and CPS 240. In the case of high molecular complexes produced by lower molecular complexes, only negative ions will be produced by empty friction, which is detected by the detector. Contains 0-2 oxygen anions. In this age square, copper ions and iron ions are mixed together, and iron ions are oxygen in the complex, and copper ions are reduced in the complex state. There are many metal ions half-bridged by the left-over flow, The main body of R is, so the electricity τ in the wrong body is always greater than the hole, and electrons and negative ions can be generated continuously.

Page 55 200530296 V. Description of the invention (51) Example 2 (Alkaline system with existing carboxyl group) After the oxidation reaction solution is dried, the film is rubbed with air to produce negative ions. The mass composition of the application is = nitrate sodium humate 100 ml of copper hydroxide 2 grams of ferric hydroxide 2 grams of ethylenediamine 0.3% Negative ions are generated by air friction. Detectors are detected to contain 0-2 oxygen negative ions. Example 3 The mass percentage composition of the M solution is: 94% water, 2% vinegar, and hydroxypropyl. Methylcellulose 2% Magnesium Sulfate 3% Prepare the reaction solution (K 05cc acetone drips and expands on the surface of the reaction solution, the surface of the acetone expansion in about 20 seconds is cracked into a fine film, and acetone is gone. The same is true for the same continuous action The reaction time is long due to the generation of holes, and the chemical state of acetone gradually collapses. Example 4 The mass percentage composition of the application of organic solvents (also fermentable, nano applications) in the reaction solution is 2% vinegar 曱Chitin powder 2% sterile water 94%

Page 56 200530296 V. Description of the invention (52) 2% 0. 396 05cc Acetone drips and expands on the surface of the reaction solution, and shrinks into a fine film about 10 seconds, and the acetone is gone. Continue to do the same with the zinc chloride PVP K-30. Example 5 The mass percentage composition of the application (also fermentable, nano application) that can dry organic solvents in the condensation reaction solution in a dry state (without water) is: sterile water 93% citric acid or carboxylic acid containing 2% hydroxy Propyl methylcellulose 2% (cps7500 0 viscosity) Magnesium sulfate or copper sulfate 2% Ammonia water 1% Prepare the reaction solution to drip and expand on the dry surface of the reaction solution with 0.05cc acetone, and the surface expanded by acetone in about 10 seconds will become fine The film, acetone, is gone. Same goes for continuous. When using hydroxypropylmethylcellulose with cps400 viscosity and the above formula, it is found that the structure is a complex structure with a smaller molecular weight, which tends to have oxidative condensation characteristics. It is no longer a simple condensation reaction, but an oxidative condensation reaction. Example 6 ^ The mass percentage of the condensation reaction solution (also fermentable, nano application) is difficult * is: humic acid 100 ml

Page 57 200530296 V. Description of the invention (53) 0.35 g 0.05 g 0.3 ° / 0 copper sulfide ferric sulfate ammonium hydroxide solution The reaction solution is prepared by dripping and expanding on the surface of the reaction solution with 0.05 cc toluene, about After 10 seconds of toluene expansion, the surface was oxidized and condensed to form a finely dispersed film, but then it was not visible, and the toluene was missing. The same is true for consecutive movements. Example 7 • The application of the organic solvent treatment in the condensation reaction solution has a mass percentage composition of m. Polyvinyl alcohol 44 g of water 7 2 1 ml of heat and stir to dissolve and then add copper sulfate 4 4 g of ammonia 2 6. 2 ml to complete the reaction 0.05cc of acetone was dripped and expanded on the surface of the reaction solution, and the surface of the acetone expansion in about 10 seconds shrank into a fine adhesive film, and the acetone was gone. The same is true for consecutive movements. % Example 8 The biochemical solution for fermentation is also a metal enzyme biocatalyst, and it is also an artificial imitation chitin solution. Its mass percentage composition is: sterile water 94% vinegar or acid containing carboxyl 2%

Page 58 200530296 V. Description of the invention (54) After propyl methylcellulose 2% magnesium sulfate or calcium sulfate 2% ammonia 2%, the amount of fermentation bacteria should be stored for more than several years after fermentation. Effectiveness Example 9 Fungicide solution, its quality Percent group of sterile water 94% fatty acid sodium 3% sulfuric acid 0.01% ammonia water or urea 3% Take Hong Kong foot fungus as an example and apply the above-mentioned germicidal solution to the affected area for half a day to completely eliminate it. Example 1 Application of nanometers), its application in mass chloroplast storage system (also can be stored as: sterile water 82% vinegar or carboxyl-containing acid 2% polyvinyl alcohol 4% > magnesium sulfate or sulfuric acid Calcium 4% Ammonia 3% Carbohydrates (monosaccharides or disaccharides) 5% A small amount of bacteria can be stored for more than one year after storage, the efficacy still exists

Page 59 200530296 V. Description of the invention (55) Example 11 In the application of food health care (also fermentable, nano applications), its mass percentage is 90% sterile water, vinegar or carboxylic acid containing 2% fatty acids (cracked Over oil) 1% calcium sulfate and various inorganic salts (single addition) 2% ammonia or protein 2% carbohydrates (monosaccharides or disaccharides) 4% Ji The amount of fermentation enzymes in the body makes the fermentation in the body vigorous, and the cells Often updated and alive. Example 1 2 Application in oil products (also fermentable, nano applications), its quality is 100%: sterile water 30% carboxylic acid containing 10% fatty acids (cracked industrial oil) 2 0 % Calcium sulfate or metal salt 10% Ammonia water 10% * Carbohydrate (monosaccharide or disaccharide) 20% Oil Special purpose fermentation enzyme Trace oil emulsified substance After water evaporation or dehydration treatment, it is added with various types of oil as additives Auxiliaries. Example 1 3

Page 60 200530296 V. Description of the invention (56) Production and application of chemical substances in plants (fermentable, nano applications), its mass percentage is: sterile water 90% vinegar or carboxyl-containing acid 2% cytokinin-0-glucosides 2% Calcium sulfate and various inorganic salts (single addition) 2% Ammonia 2% Plant-specific DNA, RNA, and / or enzymes. Micro-analogs are the same as those in plant cells and tissues or in plants ► Fatty acid-M-NH2- Protease-sugar carriers develop together. Example 1 4 The mass percentage composition of the cell proliferation medium is: 94% sterile water, 2% vinegar or carboxyl-containing acid, 2% hydroxypropyl methylcellulose, 2% magnesium sulfate, and various inorganic salts. % Ammonia water 2% Cell body traces Purified cell lines beforehand. • Example 1 Application of 5 nanometer filtration system (also fermentable, manufactured by nanometer (maltose cannot be used by nanometer)), its mass percentage composition is: sterile water 92% vinegar or acid containing carboxyl 2%

Page 61 200530296 Description of the invention (57) Maltose or other disaccharides 2% Sulfate or sulfuric acid 2 ° / 〇 Ammonia 2% Fermenting bacteria (not used for maltose) Nano-sized filter cloth (membrane) is made in a small amount, under microscopic , See the repossession. Example 16 The mass percentage composition of a 6 nanometer manufacturing liquid is: sterile water 88.89% vinegar or carboxyl-containing acid 1.3% • hydroxypropyl methylcellulose 1.3% ammonium sulfate 7.21% ammonia water 1.3% fermentation bacteria micro-full fermentation coating After the second half of combustion, a nano titanium dioxide fine particle film was obtained. Or the titanium dioxide particles are compounded with the PVA-SI-M nano inorganic polymer film. PVA (polyvinyl alcohol) is organic, silicic acid and M are inorganic. The two are combined together. It is neither an organic porous adsorbent nor an inorganic porous ceramic, but a nano inorganic polymer film. Inorganic nano-complex. Example 17 Application in 7% rice ceramics, the mass percentage composition of which is: sterile water 86% vinegar or carboxyl-containing acid 2% hydroxypropyl methylcellulose 2% ammonium sulfate 10%

Page 62 200530296 V. Description of the invention (58) Ammonia 2% Fermentation bacteria A trace amount of the fermented nano metal complex polymer solution above is melted into a gel state, cast into a titanium oxide blank, and sintered at 600 ° C . Example 1 The mass percentage composition of the application of 8 nano plastics is ... Humic acid 90 ml zinc sulfide 10 g ► Ammonia 0.3% Fermentative bacteria ferment the above fermented nano metal complex polymer solution 50% butyl rubber 50% 1 The nano-rubber is gradually heated and evaporated during the mixing and stirring. Example 1 9 The application in the nano-textile industry (also fermentable, nano-application), its mass percentage is: 90% sterilized water, vinegar or acid containing quatyl 2% glucose or monosaccharide 2% zinc sulfate or titanium sulfate or aluminum sulfate 2% ammonia 2%

Page 63 200530296 V. Description of the invention (59) The single complex fluid and plant recognition or inorganic polymer carrier mentioned above, produce macromolecular complexes and then add bacteria to ferment the nano. It is extruded from plant fibers or inorganic polymer carriers, and the extruded metal complex polymer solution is dried and sterilized by ultraviolet light. It is R-NH2, which is neric monosaccharide-M-NH2 for dyeing and printing. Example 2 The mass percentage composition of 0 nanometer liquid crystal is: sterile water 92 ° / 〇 vinegar or carboxylic acid containing 2% via propyl methyl cellulose 2% silver sulfate 0.4% ammonia water 2% nucleic acid trace amount of liquid crystal and After the full fermentation coating, the nano-crystalline liquid-crystal conductive film is obtained by semi-combustion. Example 2 1 Application of organic EL in semiconductors (also fermentable, nano applications), its mass percentage is: sterile water 90% vinegar or carboxyl-containing acid 2% glucose or monosaccharide 2% iridium sulfate or platinum sulfate 0. 4% ammonia 2% polymer bridging linker such as PVP 0.03% special DNA or RNA (such as photosynthesis mechanism) trace example 22

Page 64 200530296 V. Description of the invention (60) Application of biomass energy power generation, its mass percentage composition is: sterile water 90.6% vinegar 1.30% chitin powder 1.30% copper sulfate 3. 40% iron sulfate 3.40% PVP K- 30 0.01% Alfalfa buds have just germinated by gene and enzyme fermentation, combined with infrared light coating and PVA system sensitizer. Example 2 3 Mass percentage of nano-inorganic polymer metal composite carrier material (fermentable, nano-application): Water 8 3% Silicic acid 3.75% Polyvinyl alcohol 1.75% Rhenium sulfate or Luic acid # 5 1.5% After thermal dissolution Soak the carrier material and dry it slowly, sintered into a ceramic-like vinegar or carboxyl-containing acid 2% chitin 2% ® sterile water 96% Fermentation bacteria are slowly and automatically fermented on the entire carrier Example 24 Nano inorganic polymer film , Hole carrier, sphere material application, its quality is one hundred

Page 65 200530296 Description of the invention (61) The ratio is: sterile water 87% cetulonic acid 3. 75% polyvinyl alcohol 1. 75% vinegar or carboxyl-containing acid 2% metal sulfate or calcium sulfate 1. 5% glucose or Monosaccharide 2% Ammonia 2% Sugar-dissolving fermenting bacteria become nano-scale PVA-metal M-NH2-proteinase-sugar system , Hole carrier, spheres are PVA-SI-M. Example 2 5 In a dry method (in a state without water), a method and an application for promoting the increase of proteinase activity, the mass percentage composition of which is: sterile water 94% vitamin C 2% hydroxypropyl methylcellulose 2% iron sulfate or sulfuric acid Calcium 0.4% Ammonia 2% Fermentation bacteria It was found that the activity of the bacteria in the dry type was still strong and there was no time limit. Example 2 6

Page 66 200530296 V. Description of the invention (62) The method and application of promoting the activity of protein enzymes in dry type (without water), its mass percentage composition is: sterile water 94% vitamin C 2% chitin 2% iron sulfate Or calcium sulfate 0.4% ammonia water 2% Fermentation bacteria found that the activity of bacteria in the dry type is still strong and there is no time limit. Example 2 of jif application in biochip (state without water), its mass percentage composition is: sterile water 94% vitamin C 2% glucose or monosaccharide 2% iron sulfate 0.4% ammonia water 2 ° / 〇 DNA is used first Plant fiber is used as carrier to ferment% plant fiber is extruded and printed on nano-inorganic polymer film. When the carrier wafer has both polymer R and R. Example 2 8 The application of artificial imitation glucosamine, its mass percentage composition is: water 94%

Page 67 200530296 V. Description of the invention (63) Glucose 3% Calcium sulfate 0.01% Ammonia or urea 3 ° / 〇 Use plant fiber as a carrier to promote the reaction, and squeeze out from the fiber into glucose-trace calcium-NH2, which can be used in food Health care, cosmetics, emulsification and other functions. When coconut fiber and / or brown fiber (fibers rich in fatty acids or carboxylic acids) are used as the carrier to react with urea, it will become quaternary ammonia • salt cation after extrusion from the fiber. The liquid can be used for baby shampoo and sterilization. Example 2 9 Application in the cultivation and purification of biological cells or bacteria or protein enzymes, the mass percentage composition of which is: 90% sterile water, minced rice (glycan material and calcium) 7% ammonia, 3% ammonia, 3% fermented bacteria, minced Plant fibers (fibers rich in carboxyl acids) are fermented to promote the reaction when the carrier is cultured in suspension to become R-rice-NH2-proteinase. After filtering and extruding from the fiber and rice, it is used to purify biological cells or bacteria or protease ^ ° Example 30 0. The application of biological cells or bacteria or protein enzymes in culture and purification, the mass percentage composition is: * sterilized peat 5% sulfuric acid about 2%

Page 68 V. Description of the invention (64) (Add a small amount of sterile water) The dry-drying of sulfuric acid radicals to become the above-mentioned two, uniformly penetrate and solidify peat-calcium 90% 3% sterile water ammonia water cut with Λ body two Zhiwei (fiber rich in carboxyl acid) promotes the reaction when it is loaded or not fermented, and becomes R-peat-calcium-NΗ2- Extrusion :, is peat (containing calcium, amino bridges in it), filtered and squeezed After the exit, it is a purified biological cell or bacteria or protease. Example 3 1 The ratio of biological cells or bacteria or protein is: Application in enzyme culture and purification, its mass percentage is vinegar chitin (the higher the CPS, the better) sulfuric acid is about 2% 4% 3% 92% of the above two The mixed homogeneous substance was acid-tested to solidify the solids and filtered out (there is no longer the source of chitin acetate-calcium balance: precipitation and conversion). Drying and blowing off the sulfate radicals into sterile water ammonia water 90% 3% 200530296 V. Invention Note (65) Trace amounts of fermenting bacteria and carboxyl-containing resins such as Amberlite IRC-50 or chopped plant fibers ^ (carboxyl-rich acid fibers) become R-chitin and calcium-NH 2- when the carrier is cultured in suspension The protease enzyme is filtered and extruded from the fiber and chitin (containing calcium, amino bridged in it), and is used to purify biological cells or bacteria or protease enzymes. It is only a preferred embodiment of the present invention, not Restriction on the invention = in any form 'Although this issue has been disclosed in the preferred embodiment as #, it is not intended to limit the invention. Any person skilled in the art should be within the scope of the invention ... Utilizing the above disclosed embodiments, However, any changes or modifications made to the above embodiments without departing from the technical solution of the invention f of the invention are still modifications and equivalents of the technical solution of the invention.

200530296

[Schematic description] Please refer to FIG. 1, which is a schematic diagram of the R-MNH2 used in the present invention, that is, the hydroxyl group of hydroxypropyl methylcellulose (HPMC) is dehydrated with a metal, and the amino group is R- M-NH2. Please refer to FIG. 2, which is a structural diagram of R-NH2_M applied in the present invention, that is, directly obtained by the reaction of chitin and a metal solution. Please refer to FIG. 3, which shows the process of forming amino polymer-containing polymer metal complexes and amino-containing polymer metal enzyme complexes in the polymer metal complexes of the present invention. React with metal ions (except, get erbium molecular metal complex, the polymer metal complex is further reacted with amino group to obtain amino-containing polymer metal complex, the amino-containing polymer metal complex contains -C00H The carboxyl group is further fermented with protease to obtain an amino-containing polymer metal enzyme complex. Please refer to FIG. 4, which is formed by adding maltose in the present invention by adding a carboxyl organic acid, a metal salt, and an amino group. " Schematic diagram of the structure of the font arrangement. Please refer to FIG. 5, which is a monosaccharide bimolecular organic acid, metal salt, and amino group without carboxyl group in the present invention. For example, Cytokinins (cell division in plants) A series of schematic diagrams of a series of monosaccharide bimolecules. Please refer to FIG. 6, which shows the mechanism of infrared photocurrent generation in the half-body film of the oxidation reaction of biomass energy generation according to the present invention. Symbol Description】

Claims (1)

200530296 6. Scope of patent application 1. A metal complex polymer solution, which is characterized in that it comprises one or more metal complex polymers. 2. The metal complex polymer solution according to claim 1, characterized in that the metal complex polymer solution is a solution of saccharide molecules (containing glucosamine) and / or Or a polymer having a hydroxyl group and / or a saccharide (without chitosan) and a metal salt solution are uniformly mixed according to a conventional method to obtain 0 3. The metal complex polymer solution according to claim 1, characterized in that Metal complex polymer solution is a polymer that dissolves saccharide molecules and / or hydroxyl and / or saccharides (without chitosan) by R-COOH and / or inorganic acid, and then adds a metal salt solution and Ammonia or amines, and mixed according to conventional methods. 4. The metal complex polymer solution according to claim 丨, characterized in that the metal complex polymer solution is dissolved into sugar molecules and / or monosaccharide-containing bimolecules by R-C00H and / or inorganic acid, and then Add metal salt solution and ammonia or amines, and mix according to conventional methods. 5. The metal complex polymer solution according to claim 1, wherein the metal complex polymer solution is dissolved in R-CD⑽ carboxylic acid and / or basic information, and r ~ c00h has a medium-high level. The amount of hydrocarbon groups such as fatty acids and / or sugar knives is then added by adding a metal salt solution and ammonia or amines, and mixing them according to conventional methods. The metal complex polymer solution according to claim 2 or 3 or 4 or 5, wherein the metal salt solution is one or more valent, divalent, or trivalent metal salt solutions, and The mass percentage accounts for 0.01 to 20% of the mass of the polymer solution. 7. The metal complex polymer solution according to claim 2 or 3 or 4 or 5, wherein the metal salt solution is beryllium, magnesium, calcium, strontium, barium, radium, nickel, chromium, lead , Copper, iron, zinc, titanium, manganese, cobalt, silver, gold, beginning, handle, record, chain, # σ, absolutely, mining, tin, record, inscription, inscription, record, silk, error, record, turn, Crane, Ji, Lu, Qian, Table, Samarium, Ruthenium, Baht, Vanadium, Indium, Lanthanide and Actinide metal salt solutions. 8. The metal complex polymer solution according to claim 2 or 3 or 4 or 5, characterized in that the R-COOH and / or inorganic acid is one or more than one, and the mass percentage thereof accounts for the metal complex The mass of polymer solution is 0.01 to 20%, where R is a hydrocarbon group. 9. The metal complex polymer solution according to claim 2 or 3 or 4 or 5, characterized in that the R-COOH is mono-chinic acid, dicarboxylic acid, tricarboxylic acid, acetic acid, citric acid, Vitamin C, salicylic acid, oxalic acid, formic acid, propionic acid, malonic acid, lactic acid, malic acid, succinic acid, adipic acid, maleic acid, fumaric acid, orthoic acid, oxalic acid, lauric acid, tartaric acid, Lycium acid, humic acid, nitro-humic acid, fatty acids, plantes in plants, fibers rich in carboxylic acids, resins containing carboxyl groups such as Amberlite IRC-50, where the inorganic acids are hydrochloric acid, filling acid, nitric acid, sulfuric acid . 10. The metal complex polymer solution according to claim 3 or 4 or 5, characterized in that the saccharide molecules and / or have hydroxyl and / or carboxyl groups and / or saccharides (without chitosan) The polymer content percentage is 0.01 to 20% of the mass of the metal complex polymer solution. The saccharide molecule and / or the polymer having a radical and / or a radical and / or a saccharide is one of the following substances. : 200530296 6. Scope of patent application Sucrose; maltose; lactose; seaweed seeding. Glucose); cracking oils; seaweed fine and disaccharides; monosaccharides (containing amino salts); May not add metal 0-glucosides and other monosaccharide-containing bimolecules without adding metal salts); cytokinin-or to be taken with ammonia (or amines) substances ^ or ammonia (or amines) substances vinyl alcohol or separately polymerized Vinyl alcohol; phytic acid, peat; and acid-dissolved humic acid, nitro-humic acid or humic acid alone, nitro-humic acid or 0.1-1% hydroxypropylmethyl fiber ',! _0 · 1 ~ 6% Hydroxypropylmethyl fiber to remove 1 乂 of chitin; ；; prime and 1 ~ 4% artificially synthesized chitin or to be combined with ammonia (or amine) substances or hydroxypropylmethyl cellulose; bismuth Propyl methylcellulose; or the above-mentioned polymer having a hydroxyl group and / or a carboxyl group and / or a polymer or mixed with oil or sugar or a sugar (without chitosan) with a high score of 11. The metal oblique lies in that the metal polymer is a monosaccharide 3 == two ===, its characteristics Molecule of metal or saccharide polymer (3 into gas-based glucose) or monosaccharide molecular bridging linking agent and / formula toxin / body polymer solution, which contains high L · t ^ A ^ or ... Child carrier and / or plant fiber (including Γ2 fiber or modified fiber rich in endogenous acid). The metal complex is a metal complex polymer solution as described in claim 1, wherein the compound solution contains t Hygroscopic agent with complex structure. The metal complex polymer solution according to claim 13, claim 11, or claim 12, characterized in that the polymer bridging linking agent or hygroscopic structure with hygroscopicity is incorporated therein. Page 74 200530296 VI. Scope of patent application The agent is PVP and polyethylene; 14. The metal complex polymer solution according to claim 1, characterized in that it contains protein enzymes or bacteria or cells. 15. The metal complex polymer solution according to claim 1, characterized in that the metal complex polymer solution and / or the polymer having a hydroxyl group contain oxalic acid and / or nano powder. 16. The metal complex polymer solution according to claim 1, characterized in that the metal complex polymer solution is used in the manufacture of nano-materials, nano-ceramics, nano-plastics or nano-textile industries from gas, liquid to solid Contains oxygen, strong oxygen 0-2 or 02-, hydrogen peroxide and nitrogen), ammonia and ammonia, sulfur and sulfur, phosphoric acid, hydrochloric acid, hydrofluoric acid, boric acid, sulfuric acid, carbonic acid, sulfonic acid, hypogas acid, trichloride Acetic acid, isophthalic acid, phthalic acid, graphite, carbon black, bone, pearl, tooth enamel. 17. The metal complex polymer solution according to claim 1, characterized in that the metal complex polymer solution contains a plastic or rubber polymer in nano plastic or nano textile industry applications. 18. The metal complex polymer solution according to claim 17, wherein the plastic or rubber polymer is polyamine, polyimide, polyethylene, polyethylene gas, polyaniline, polyphenylene Ethylene, poly (p-phenylenevinylene), propylene N-butadiene styrene, polyethylene oxide, epoxy resin, phenolic resin, polycarbonate, polypropylene, polyacrylate, polyester, polyurethane, polyolefin, polyethylene Butyric acid, polyoxymethylene, poly (phenylene oxide). Qin resin (PN0), rubber, butadiene rubber, silicone rubber, polyvinyl ketone, etc. or its precursor or its oligomer or the above-mentioned modified and blended. Page 75 200530296 6. Application patent scope 19. The metal complex polymer solution according to claim 1, characterized in that the metal complex polymer solution generates oxygen anions in the oxidation reaction, the organic solvent is treated by condensation reaction, and the oxidative condensation is performed. Reactions, biochemical reactions for fermentation, purification of biological proteins and their metabolites, bacterial cell preservation systems, genes and vectors, cell proliferation media, detection of gas concentrations, metal enzyme biocatalysts, oil products, nanomaterials for fermentation, nano Ceramics, nano plastics, nano textile industry, manufacture of liquid crystals, semiconductors, production of chemical substances in plants, nano inorganics, power generation, promoting proteinase activity increase in dry processes, biochips, treatment of waste solvent liquids and removal of solvent gases Contains ¥ chitosan metal complex polymer solution. 20. Application of a metal complex polymer solution to generate oxygen anions in an oxidation reaction. 21. Application of a metal complex polymer solution in a cracking reaction. 22. Application of a metal complex polymer solution in a condensation reaction. 23. Application of a metal complex polymer solution in an oxidative condensation reaction. 24. Application of a metal complex polymer solution in artificial imitation chitin. 25. Application of a metal complex polymer solution in a biochemical reaction for fermentation. 6. Application of a metal complex polymer solution in detecting gas concentration. 27. Application of a metal complex polymer solution in a metal enzyme biocatalyst. 28. Application of a metal complex polymer solution in a fungicide. 29. Application of a metal complex polymer solution in a bacterial cell preservation system. Page 76 200530296 VI. Scope of patent application 30. Application of a metal complex polymer solution in food medical care. 3 1. Application of a metal complex polymer solution in oil products. 32. The application of a metal complex polymer solution in the production of chemical substances in plants. 33. Application of a metal complex polymer solution in genes and vectors. 34. Application of a metal complex polymer solution in a cell proliferation medium. 35. Application of a metal complex polymer solution in a nanofiltration system. 36. Application of a metal complex polymer solution in the manufacture of nanomaterials by fermentation. 37. Application of a metal complex polymer solution in nano-ceramics. 38. Application of a metal complex polymer solution in nanoplastics. 39. Application of a metal complex polymer solution in the nano-textile industry. 40. Application of a metal complex polymer solution in manufacturing liquid crystal. 41. Application of a metal complex polymer solution in semiconductors. 42. Application of a metal complex polymer solution in power generation. 43. Application of a metal complex polymer solution in a nano inorganic substance. 44. The application of a metal complex polymer solution in dry mode to promote the increase of protease. 5. Application of a metal complex polymer solution in a biochip. 46. Application of a metal complex polymer solution in the treatment of waste solvent liquids and removal of organic gases. 47. Application of a metal complex polymer solution in artificial imitation of glucosamine. Page 77 200530296 Page 78