SU771034A1 - Enamel - Google Patents
Enamel Download PDFInfo
- Publication number
- SU771034A1 SU771034A1 SU782727365A SU2727365A SU771034A1 SU 771034 A1 SU771034 A1 SU 771034A1 SU 782727365 A SU782727365 A SU 782727365A SU 2727365 A SU2727365 A SU 2727365A SU 771034 A1 SU771034 A1 SU 771034A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- glaze
- bao
- cao
- mgo
- zro
- Prior art date
Links
- 210000003298 dental enamel Anatomy 0.000 title 1
- 239000000203 mixture Substances 0.000 description 6
- 239000005995 Aluminium silicate Substances 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Description
1one
Изобретение относитс к составам глазурей и может быть использовано в производстве керамических облицовочных плиток.The invention relates to glaze compositions and can be used in the manufacture of ceramic tiles.
Известна глазурь, включающа еле- 5 дующие компоненты, вес.%: SiO 36,0i«5 ,8; , 2,0-8,33; , t,,0; CaO 2,53-6,53; MgO 0,15-1,50; ZnO 0,15-1,50; SrO 5,30-n. BaO 0,502 ,60; NajO 1,13-5,13; ZrO, 7,50-17,5210Known glaze, including the following components, wt.%: SiO 36.0i 5, 8; , 2.0-8.33; , t ,, 0; CaO 2.53-6.53; MgO 0.15-1.50; ZnO 0.15-1.50; SrO 5.30-n. BaO 0.502, 60; NajO 1.13-5.13; ZrO, 7.50-17,5210
Недостатками данной глазури вл етс высока стоимость из-за большого содержани борного ангидрида (до 40%). Кроме того, известно, что уве- 15 личение содержани . снижает химическую устойчивость глазурных фритт, л введение ,, в глазурь в количествах , превышающих 30%, способствует вскипанию глазури, а также образова- 20 нию наколов.The disadvantages of this glaze are the high cost due to the high content of boric anhydride (up to 40%). In addition, it is known that the increase in content. reduces the chemical resistance of glazing frites, l introduction, into the glaze in quantities exceeding 30%, contributes to the boiling up of the glaze, as well as the formation of pricks.
Увеличение содержани ZrO,3i( 1 5-1 7) ведет к увеличению в зкости известной глазури и ухудшает ее разлив.Increasing the content of ZrO, 3i (1 5-1 7) leads to an increase in the viscosity of the known glaze and worsens its spreading.
Глазурь имеет белизну 84-86%. 25Glaze has a whiteness of 84-86%. 25
Наиболее близкой к изобретению по составу вл етс глазурь, включающа следующие компоненты, вес.%: Si Oj i59,79-61 ,06; . .10 , 22-1 О ,«7 ; CaO .10,36-10,6); MgO 1,53-2,06; ZrOaClosest to the invention in composition is glaze, comprising the following components, wt.%: Si Oj i59.79-61, 06; . .10, 22-1 O, “7; CaO .10.36-10.6); MgO 1.53-2.06; ZrOa
10,03-10,85; Na/iO 1,53-1,60; КлО 1 ,16-1 ,22; BaO 3,63-,06 2 .10.03-10.85; Na / iO 1.53-1.60; CLO 1, 16-1, 22; BaO 3.63-, 06 2.
Недостатком указанной глазури вл етс невысока белизна 78-80%.The disadvantage of this glaze is a low whiteness of 78-80%.
Целью изобретени вл етс повышение белизны.The aim of the invention is to increase the whiteness.
Достигаетс это тем, что глазурь, включающа SiO., ZrOi,°CaO, Al20j, , BaO, MgO, , дополнительно содержит при следующем соотношении компонентов, вес.%:This is achieved by the fact that the glaze, including SiO., ZrOi, ° CaO, Al20j,, BaO, MgO,, additionally contains, in the following ratio of components, wt.%:
40,5-51,540,5-51,5
,0-12,0, 0-12,0
ZrO,ZrO,
5,0- 7,05.0-7.0
CaOCao
3,0- 6,03.0-6.0
3,0- 6,03.0-6.0
N37.0N37.0
2,0- 7,02.0-7.0
BaOBaO
0,5- 2,00.5-2.0
MgOMgO
0,5- 2,0 0.5-2.0
20,0-25,0 20.0-25.0
i S состав фритты следующий.The composition of the frit is the following.
ВЫЙYOU
Шихтов вес.%:Weight%
Песок 17-32 Сода 4-10 Поташ 1- 4 Углекислый барий 2- 7 Каолин 10-15 Мел 4- 8 Доломит 1- 3Sand 17-32 Soda 4-10 Potash 1- 4 Barium carbonate 2- 7 Kaolin 10-15 Chalk 4- 8 Dolomite 1- 3
БорныйBoric
ангидрид 15-20anhydride 15-20
Циркон 10-17 Перемешенную шихту пропускают через сито с 36 ртв./см . Варкуфритты рсущестззл ют во вращающейс печи в соличестве 400 кг в течение 4,5 ч Ьри 1350-1380 0. Помол фритты осу- . ществл ют в шаровых мельницах следующего , мельничного состава, %: Фритты 95, каолина 5, NaCl .0,35, КМЦ 0,02. Влажность шликера составл ет 40-42% при плотности 1,60 г/см по ареометру , текучести 5 с. Помол глазури производ т до остатк а на сите 0056 до 0,07%. Глазурь нанос т на утильныеZircon 10-17 The mixed mixture is passed through a sieve with 36 Ht / cm. Cooking efftorescence in a rotary kiln in the amount of 400 kg for 4.5 hours. We reached 1350-1380 0. Grinding of the frits is carried out. They are found in ball mills of the following, mill composition,%: Fritts 95, kaolin 5, NaCl .0.35, CMC 0.02. The moisture of the slurry is 40-42% with a density of 1.60 g / cm by hydrometer, a yield strength of 5 s. The grinding of the glaze is carried out to a residue on a 0056 sieve to 0.07%. Glaze is applied to scrap materials.
плитки поливом. Расход глазури на одну плитку составл ет 18 г.tile watering. The glaze consumption per tile is 18g.
Политой обжиг плиток производ т в роликовой печи при продолжительностью 26 мин.Poured tiles are baked in a roller oven for 26 minutes.
Начало разм гчени глазури 770°С, конец разм гчени 880®С, т.е. интервал разм гчени .The beginning of softening of the glaze is 770 ° С, the end of softening is 880®С, i.e. softening interval.
Коэффициент термического расширени глазури в интервале 20-400 0 равен 6,0810 1/град.The coefficient of thermal expansion of the glaze in the range of 20-400 0 is 6.0810 1 / degree.
Термостойкость глазури - 170с.Heat resistance glaze - 170s.
В табл. 1 даны составы глазурей.In tab. 1 given the compositions of the glazes.
В табл. 2 даны физико-химическиеIn tab. 2 given the physico-chemical
ТаблицаTable
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU782727365A SU771034A1 (en) | 1978-12-26 | 1978-12-26 | Enamel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU782727365A SU771034A1 (en) | 1978-12-26 | 1978-12-26 | Enamel |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU771034A1 true SU771034A1 (en) | 1980-10-15 |
Family
ID=20811316
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU782727365A SU771034A1 (en) | 1978-12-26 | 1978-12-26 | Enamel |
Country Status (1)
| Country | Link |
|---|---|
| SU (1) | SU771034A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2394009C1 (en) * | 2009-04-16 | 2010-07-10 | Юлия Алексеевна Щепочкина | Glase |
-
1978
- 1978-12-26 SU SU782727365A patent/SU771034A1/en active
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2394009C1 (en) * | 2009-04-16 | 2010-07-10 | Юлия Алексеевна Щепочкина | Glase |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| SU1178718A1 (en) | Glaze | |
| SU771034A1 (en) | Enamel | |
| SU1636361A1 (en) | Opaque glaze | |
| SU1268523A1 (en) | Glaze | |
| SU1477705A1 (en) | Composition for producing translucent glaze | |
| SU1698204A1 (en) | Glaze | |
| RU2018493C1 (en) | Glaze frit | |
| SU1291563A1 (en) | Glaze | |
| SU1544750A1 (en) | Ceramic composition for making porcelain | |
| SU1362720A1 (en) | Glaze | |
| SU1414813A1 (en) | Glaze | |
| SU1119991A1 (en) | Opacified glaze | |
| SU1198031A1 (en) | Glaze | |
| SU1609754A1 (en) | Glaze | |
| SU1030368A1 (en) | Glaze | |
| SU1102777A1 (en) | Glaze | |
| SU1673571A1 (en) | Non-fritted glaze | |
| SU1706980A1 (en) | Zirconless opaque glaze | |
| SU1730066A1 (en) | Glaze | |
| SU1386598A1 (en) | Transparent glaze | |
| SU1104119A1 (en) | Glaze | |
| SU1668348A1 (en) | Non-fritted glaze | |
| SU1470683A1 (en) | Translucent glaze composition | |
| RU2140405C1 (en) | Ceramic body for manufacturing insulators | |
| SU1620424A1 (en) | Glaze |