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SU715476A1 - Method of preparing stabilized seed suspension - Google Patents

Method of preparing stabilized seed suspension Download PDF

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Publication number
SU715476A1
SU715476A1 SU782568479A SU2568479A SU715476A1 SU 715476 A1 SU715476 A1 SU 715476A1 SU 782568479 A SU782568479 A SU 782568479A SU 2568479 A SU2568479 A SU 2568479A SU 715476 A1 SU715476 A1 SU 715476A1
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SU
USSR - Soviet Union
Prior art keywords
titanium dioxide
suspension
seed suspension
preparing stabilized
titanium
Prior art date
Application number
SU782568479A
Other languages
Russian (ru)
Inventor
Иван Поликарпович Добровольский
Виктор Петрович Иванов
Раиф Миргаритович Садыков
Стелла Николаевна Лукшина
Владимир Александрович Тюстин
Константин Ульянович Конотопчик
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Предприятие П/Я Г-4855
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Priority to SU782568479A priority Critical patent/SU715476A1/en
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Publication of SU715476A1 publication Critical patent/SU715476A1/en

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Description

(54) СПОСОВ ПОЛУЧЕНИЯ СТАБИЛЬНОЙ ЗАРОДЫШЕВОЙ СУСПЕНЗИИ(54) WAYS OF OBTAINING STABLE EMERGENCY SUSPENSION

1зобретение относитс  к TekHononiH получени  двуокиси титана по сернокислотной схеме, преимушественно может быть использовано при Получении пиг- 5 ментной двуокиси титана рутильной модификации .The invention relates to TekHononiH for the preparation of titanium dioxide according to a sulfuric acid scheme, which can be mainly used for the preparation of pigmental titanium dioxide of rutile modification.

В современном производстве пигментной двуокиси титана рутильной модификации пЬодукт с высокими качественны- ю ми показател ми получают с использованием зародышевой суспензии - кислого , зол  двуокиси титана 1,которкй ввод т в гидратированную двуокись титана перед ее прокалкой или в сер- д нокисльпй раствор титана на стадии его гидролиза 2 . Во всех случа х лучшими технологическими свойствг1ки обладает высокодисперсна  стабильна  зародышева  суспензи , и более 20 высокое качество двуокиси титана достигаетс  при введении ее на стадии гидролиза раствора. Дл  предотвращени  коагул ции и укрупнени  частиц зародышевой суспензии обычно ее 25 стабилизируют органическими соединени ми . . , ,In modern production of pigmentary titanium dioxide, a rutile modification of the product with high quality indicators is obtained using a germ suspension - an acidic, titanium dioxide sol 1, which is introduced into hydrated titanium dioxide before calcining it or in a sulfur-doped titanium solution at the stage its hydrolysis 2. In all cases, the best technological properties of a highly dispersed, stable germinal suspension, and more than 20 high quality titanium dioxide is achieved with the introduction of it at the stage of solution hydrolysis. To prevent coagulation and coarsening of germ suspension particles, it is usually stabilized 25 with organic compounds. . ,,

Наиболее близким к описываемому изобретению по технической сущности и достигаемому результату  вл етс . JQThe closest to the described invention to the technical essence and the achieved result is. Jq

.способ получени  стабильной зародышевой суспензии путем введени  в неё спиртов или водорастворимых полимеров в количестве 1-10 вес.% от содержани  двуокиси титана 3.Однако при использовании зародышевой суспензии с таким содержанием органических стабилизаторов на стадий гидролиза сернокислого раствора титана происходит также стабилизаци  части образующихс  частиц гидратированной двуокиси титана. Эти стабилизированные частицы не удаетс  выделит в осадок ни отстоем , так как они не осаждаютс , ни фильтрацией, так как они проход т через фильтрующий слой вместе с фильтратом. В результате потери двуокиси титана возрастают на 2-5%.A method of obtaining a stable germ suspension by introducing alcohols or water-soluble polymers into it in an amount of 1-10 wt.% based on titanium dioxide content 3. However, when using germinal suspension with this content of organic stabilizers, during the hydrolysis of titanium sulphate a solution also part of the resulting particles is stabilized hydrated titanium dioxide. These stabilized particles are not precipitated as precipitates, as they are not precipitated, or by filtration, as they pass through the filter bed with the filtrate. As a result, the loss of titanium dioxide increases by 2-5%.

Целью изобретени   вл етс  снижение потерь пигмента на стадии фильтрации гидратированной двуокиси титана . , The aim of the invention is to reduce pigment losses in the filtration phase of hydrated titanium dioxide. ,

Поставленна  цель достигаетс  описываемым способом получени  стабильной зародышевой суспензии, включающим введение в кисльлй золь двуокиси титана добавки органического спирта триэтаноламина в смеси с гексаметаThe goal is achieved by the described method of obtaining a stable germ suspension, including the introduction into the acidic sol of titanium dioxide of an additive of organic alcohol triethanolamine in a mixture with hexamet

Claims (1)

Формула изобретенияClaim Способ получения стабильной зародышевой суспензии для производства пигментной двуокиси титана, включающий введение в кислый золь двуокиси титана добавки органического спирта, отличающийся тем, что, с целью снижения потерь пигмента на стадии фильтрации гидг ратированной двуокиси титана, в качестве органического спирта используют триэтаноламин и вводят его в смеси с гексаметофосфатом натрия . в количестве 0,1-1,0 ммоль каждого компонента смеси на 1 моль двуокиси 45 титана в исходном золе.A method of obtaining a stable germ suspension for the production of titanium dioxide pigment, comprising the addition of an organic alcohol to an acid sol of titanium dioxide, characterized in that, in order to reduce pigment losses in the filtration stage of hydrated titanium dioxide, triethanolamine is used as an organic alcohol and introduced into mixtures with sodium hexamethophosphate. in an amount of 0.1-1.0 mmol of each component of the mixture per 1 mol of dioxide of 45 titanium in the initial ash.
SU782568479A 1978-01-13 1978-01-13 Method of preparing stabilized seed suspension SU715476A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
SU782568479A SU715476A1 (en) 1978-01-13 1978-01-13 Method of preparing stabilized seed suspension

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Application Number Priority Date Filing Date Title
SU782568479A SU715476A1 (en) 1978-01-13 1978-01-13 Method of preparing stabilized seed suspension

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5045301A (en) * 1988-07-01 1991-09-03 Rhone-Poulenc Chimie Moldable/extrudable titanium dioxide particulates
US5149519A (en) * 1988-03-30 1992-09-22 Rhone-Poulenc Chimie Preparation of sulfur-free titanium dioxide

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5149519A (en) * 1988-03-30 1992-09-22 Rhone-Poulenc Chimie Preparation of sulfur-free titanium dioxide
US5045301A (en) * 1988-07-01 1991-09-03 Rhone-Poulenc Chimie Moldable/extrudable titanium dioxide particulates
US5100858A (en) * 1988-07-01 1992-03-31 Rhone-Poulenc Chimie Moldable/extrudable titanium dioxide particulates

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