SU580797A3 - Herbicide - Google Patents
HerbicideInfo
- Publication number
- SU580797A3 SU580797A3 SU7401991123A SU1991123A SU580797A3 SU 580797 A3 SU580797 A3 SU 580797A3 SU 7401991123 A SU7401991123 A SU 7401991123A SU 1991123 A SU1991123 A SU 1991123A SU 580797 A3 SU580797 A3 SU 580797A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- compounds
- cyanophenyl
- herbicide
- plants
- oxime
- Prior art date
Links
- 230000002363 herbicidal effect Effects 0.000 title description 11
- 239000004009 herbicide Substances 0.000 title description 5
- 239000000203 mixture Substances 0.000 description 13
- 150000001875 compounds Chemical class 0.000 description 12
- 241000196324 Embryophyta Species 0.000 description 6
- -1 2,4-dichlorophenoxy Chemical group 0.000 description 5
- 125000001931 aliphatic group Chemical group 0.000 description 5
- 229910052736 halogen Inorganic materials 0.000 description 4
- 150000002367 halogens Chemical class 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- JUUJGJKBAHKKSW-UHFFFAOYSA-N (2-cyanophenyl) hydrogen carbonate Chemical class OC(=O)OC1=CC=CC=C1C#N JUUJGJKBAHKKSW-UHFFFAOYSA-N 0.000 description 2
- 235000007866 Chamaemelum nobile Nutrition 0.000 description 2
- 241000287828 Gallus gallus Species 0.000 description 2
- 244000042664 Matricaria chamomilla Species 0.000 description 2
- 235000007232 Matricaria chamomilla Nutrition 0.000 description 2
- 244000062793 Sorghum vulgare Species 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 2
- 235000019713 millet Nutrition 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 229940087195 2,4-dichlorophenoxyacetate Drugs 0.000 description 1
- 241000219310 Beta vulgaris subsp. vulgaris Species 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 241000131095 Oniscidea Species 0.000 description 1
- 235000021536 Sugar beet Nutrition 0.000 description 1
- PXAJQJMDEXJWFB-UHFFFAOYSA-N acetone oxime Chemical compound CC(C)=NO PXAJQJMDEXJWFB-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 229940125782 compound 2 Drugs 0.000 description 1
- CLDLHEOVBBBZAF-UHFFFAOYSA-N cyano phenyl carbonate Chemical compound N#COC(=O)OC1=CC=CC=C1 CLDLHEOVBBBZAF-UHFFFAOYSA-N 0.000 description 1
- 229960003887 dichlorophen Drugs 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 150000002923 oximes Chemical class 0.000 description 1
- BSCCSDNZEIHXOK-UHFFFAOYSA-N phenyl carbamate Chemical compound NC(=O)OC1=CC=CC=C1 BSCCSDNZEIHXOK-UHFFFAOYSA-N 0.000 description 1
- 238000013379 physicochemical characterization Methods 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/06—Oxygen or sulfur directly attached to a cycloaliphatic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/34—Nitriles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
- A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N39/00—Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
- A01N39/02—Aryloxy-carboxylic acids; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N39/00—Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
- A01N39/02—Aryloxy-carboxylic acids; Derivatives thereof
- A01N39/04—Aryloxy-acetic acids; Derivatives thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
- A01N47/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing —O—CO—O— groups; Thio analogues thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/30—Derivatives containing the group >N—CO—N aryl or >N—CS—N—aryl
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N2300/00—Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Dentistry (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Medicines Containing Plant Substances (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
(54) ГЕРБИЦИДНЫЙ СОСТАВ(54) HERBICIDE STRUCTURE
1one
Изобретение относитс к химическим средствам дл борьбы с нежелательной растительностью в посевах возделываемых культур.This invention relates to chemical agents for controlling undesirable vegetation in crops of cultivated crops.
Широко известен гербицидный состав на основе О-(М-фенилкарбамоил) ацетоноксима и изопропил-К фенилкарбамата 1 .A herbicidal composition based on O- (M-phenylcarbamoyl) acetone oxime and isopropyl-K phenylcarbamate 1 is widely known.
Известен также гербицидный состав на основе (2,6-дийод-4-циано} фенилкарбоната 2.Also known herbicide composition based on (2,6-diyod-4-cyano} phenylcarbonate 2.
Однако известные гербицидные составы недостаточно избирательны в посевах злаковых культур и. малоэффективны в отношен однодольных сорных растений Ef- посевах сахарной свеклы.However, the known herbicidal compositions are not sufficiently selective in crops of cereals and. ineffective against monocotyledonous weed plants Ef- crops of sugar beet.
С целью усилени гербицидной активности и избирательности действи и расширени ассортимента гербицидов, предлагаетс гербицидный состав, включающий в качест ве производных О-(феноксиацил) - оксима соединени общей формулыFor the purpose of enhancing herbicidal activity and selectivity of action and expanding the range of herbicides, a herbicidal composition is proposed, which includes, as derivatives of O- (phenoxyacyl) - oxime, a compound of the general formula
/R2 / R2
А V o-СН-СО-о-N-сAnd V o-CH-CO-about-N
/Ч./ H
где RI и R2 одинаковые или различные и означают незамещенный или замещенный одним или несклькими заместител ми ароматический , Vалифатический, циклоалифатичео5 кий, арилалифатическийИли гетероцикличеокий углеводородный остаток, Rj и - со&местно с атомом углерода образуют цшшоалифатический углеводородный остаток, РЭ- водород шш низший алкил,where RI and R2 are the same or different and mean unsubstituted or substituted by one or several substituents aromatic, aliphatic, cycloaliphatic, arylaliphatic, or heterocyclic hydrocarbon residue, Rj and, with the carbon atom, form the aliphatic, the ally, the ally, the hydrocarbon, the ally, the alter,
10X - водород и/или низщий алкил,10X is hydrogen and / or lower alkyl,
и/или галоген,and / or halogen,
h - целое число 1-3, a в качеств 1производных цианфенипкарбойата состав содержит соединени общей формулыh is an integer of 1-3, and as 1-derivative of cyanopheniparbomate, the composition contains compounds of the general formula
ХX
гg
/t-N-o-d/o/ t-o-d / o
11eleven
гдеЯ{)1.Р2- одинаковые или различные и означают незамещенный или замещенный одним или несколькими заместител ми алифатический углеводородныйОстаток,where I {) 1.P2 are the same or different and mean an aliphatic hydrocarbon residue unsubstituted or substituted by one or more substituents,
ХиУ - одинаковые и различные и оэиачают галоген, причем состав содержит 4О-5р вес, ч. производных О-{феноксиацил -юксима и 5-10 вер. ч. прхэиаводных цианфенилкарбоната , в также 51-35 вес. ч. Езофорона в качестве растворител и 4-5 вес. ч. поверхностно-активного вещества. В табл. 1 дана физико-химическа характеристика («гпытанных в качестве гербицида соединений. Приме р 1. Растени звездчатки, росички, ленчицы, паслёна, мокрицы высотой 1О-14 см обрабатывали в дозе 0,1 и 0,5 кг/га соединени ми № 1, 2,3, 4, 5, в, 7, 8 и смесью, соединени ; каждьш из соединений. Спуст 2 нед. проводили учет гербицид ной активности и избирательности действи по 10О-баплыюй шкале; О - полна гибе растений, 1ОО - нет Повреждений. Результаты испытаний представлены в табл. 2. The chiU is the same and different, and it is halogen, and the composition contains 4O-5p weight, including derivatives of O- {phenoxyacyl-yuxima and 5-10 ver. including preyavodnyh cyanophenyl carbonate, also 51-35 weight. h. Ezoforona as a solvent and 4-5 weight. including surfactants. In tab. 1 is given a physico-chemical characterization ("tested as a herbicide of compounds. Example 1. Plants of sprocket, rosichki, lechitsy, hairy, woodlice with a height of 1 ~ 14 cm were treated at a dose of 0.1 and 0.5 kg / ha with compounds No. 1 , 2,3, 4, 5, в, 7, 8 and a mixture of compounds; each of the compounds. After 2 weeks, we carried out an account of the herbicidal activity and selectivity of action on a 10O-scale, O is full of the death of plants, 1OO is not Damage The test results are presented in Table 2.
1Изоп{)Ьшшиденамино-2,6-дийод-4-цианфенил- карбонат1Isop {) shshidenamino-2,6-diiodo-4-cyanophenyl carbonate
2.« Ацетоноксик 2- (2,4-дихлорфенокси)-пропиона т2. "Acetonoxy 2- (2,4-dichlorophenoxy) -propion t
(3,5,)- Триметил-3-циклогексаноноксим)2- (2-метил-4-хл рфенокси)-пропионат(3,5,) - Trimethyl-3-cyclohexanone oxime) 2- (2-methyl-4-chlorophenoxy) propionate
(3,5,5-Триметш1-2-циклогексаноноксим)-2- (2,4-дихлорфенок си )-проаиона т(3,5,5-Trimetsh1-2-cyclohexanonoxime) -2- (2,4-dichlorophene si) -proaion t
5. Ацётофеноноксим-2-.4 2,4-ч1ихлорфенокси)-пропионат5. Atsetophenone-2-.4 2,4-h1-chlorophenoxy) -propionate
6, Метилизобутилкетоксим-2-(2,4-диxлopфeнoкcи)-пpoш oнaт6, Methylisobutyl ketoxim-2- (2,4-dichlorophenoxy) -product one
7. (3-Нитробешзальдоксим)-2- (2,4-дихлорфенокси )-пропионат7. (3-Nitrobeshzaloxime) -2- (2,4-dichlorophenoxy) propionate
8 Бензрфенонокси -2-(2,4-дихлорфенокси) -пропиоиат8 Benzrphenonoxy -2- (2,4-dichlorophenoxy) propionate
9 Ацетоноксик -2-(2-метил-4-хлорфенокси)-пропионат9 Acetonoxy-2- (2-methyl-4-chlorophenoxy) propionate
10Адетонокснм-2,4-дихлорфеноксиацетат10Adetonum-2,4-dichlorophenoxyacetate
11Ацетоноксим- 2,4,5-;трихпорфеноксиацетат11Acetonoxime-2,4,5-; trichpophenoxyacetate
167-168 (разложение) . 1,5390167-168 (decomposition). 1.5390
1,5418 1,55711.5418 1.5571
1,56281.5628
1,52451.5245
1,6ОО51.6OO5
1,52481.5248
81 83 П р и м е р 2, Растени звездчатки, сыти, ромашки, плевела, росички, куриного проса в стадии 4-5 листьев обрабатывали соединени ми № 1, 2, 8, 9, 10, 11, 12, а также их смес ми, включающими соединение № 1 с каждым из соединений (2-12) последовательно в дозе 0,1 к 0,5 кг/га. Результаты испытаний учитывали через 2 нед,,по 100 - балльной шкале. Они представлены в табл. 3, П р и м е р 3. Растени ромашки, плевела , ленчицы, куриного проса в стадии 4-5 листьев обрабатывали в дозе 0,1 и 0,5кг/ге соединени ми № 2, i, 8, 14, 15, 16, а также смесью соединени 2 с каждым из соединений с 1-16 последовательно. Спуст 14 дней определ ли сырой вес свежесрезанных растений в сравнении с контролем (без обработки), Результаты приведены в табл. 4 Таблица 1 12Ацетоноксим-2-мегил-4-хлорфеноксиацегат 13Ацетоноксим-2-( 2,4,5-трихаорфеноксй )пропионаг 141-вгор-Бугилэ.хилиденаминог-(2,6-дийод 4-цианфенил )«арбонаг 151-Этилэгилиденамино-(2,6-дийод-4-цианфенил )-карбонат 161-Изопропилэтилиденамино-( 2,6-дийод-4-цианфенил ) 171-Мегилпропилиденамино-(2,6-дибром-4-цианфенил )-карбонаг81 83 PRI me R 2, Sprocket plants, seedlings, chamomile, chaff, rosichki, chicken millet in the 4-5 leaf stage were treated with compounds nos. 1, 2, 8, 9, 10, 11, 12, as well as their mixtures comprising compound No. 1 with each of the compounds (2-12) sequentially in a dose of 0.1 to 0.5 kg / ha. The test results were taken into account after 2 weeks, on a 100 - point scale. They are presented in Table. 3, Example 3: Chamomile, chaff, lenchitsa, chicken millet plants in a 4-5 leaf stage were treated at a dose of 0.1 and 0.5 kg / he with compounds No. 2, i, 8, 14, 15, 16, as well as a mixture of compound 2 with each of the compounds from 1-16 successively. After 14 days, the fresh weight of freshly cut plants was determined in comparison with the control (without treatment). The results are shown in Table. 4 Table 1 12Acetonexime-2-megyl-4-chlorophenoxyacetate 13Acetoneoxime-2- (2,4,5-trichorofenoxy) propionag 141-vgor-Bougilee.hilidenamine- (2,6-diiodo 4-cyanophenyl) arbonec 151-Ethylegylidene (2,6-diyod-4-cyanophenyl) -carbonate 161-isopropylethylideneamino- (2,6-diiodo-4-cyanophenyl) 171-megylpropylideneamino- (2,6-dibromo-4-cyanophenyl) -carbonyl
Продолжение табл. 1 58 1,5620 107-1О8 (разложение) 115-117 6&-7ОContinued table. 1 58 1.5620 107-1О8 (decomposition) 115-117 6 & -7O
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Формула иаобрегени Гербицидный состав, включающий цействующее начало на основе производных 0-(фен оксиацил)-оксима и цианфенилкарбонага, а также добавку, выбранную из группы - раст воригель, эмульгатор, диспергагор, отличающийс тем, что, с целью усилени гербицидной активности и избирательности действи , состав содержит в качестве О-(феноксиацил)-оксима соединение общей формулыHerbicidal composition, including a active principle based on the derivatives of 0- (phenoxyacyl) -oxime and cyanophenylcarbonag, as well as an additive selected from the group of diluent, emulsifier, dispersant, characterized in that, in order to enhance the herbicidal activity and selectivity , the composition contains as O- (phenoxyacyl) -oxime compound of the general formula
И AND
0-(iH-(l,0-0-N-(.C0- (iH- (l, 0-0-N - (. C
где - одинаковые или различные и означают незамещенный или замещенный одним или несколькими заместител ми ароматический , алифатический, циклоалифагинеский, арилалифатический или гетероциклический углеводородный остаток, RjjRj - совместно с атомом углерода образуют циклоалифатический углеводородный остаток,where is the same or different and means unsubstituted or substituted by one or more substituents aromatic, aliphatic, cycloaliphage, aryl aliphatic or heterocyclic hydrocarbon residue, RjjRj - together with the carbon atom form a cycloaliphatic hydrocarbon residue,
. - водород или низший алкил, X - водород и/или низший алкил, и/или галоген.. is hydrogen or lower alkyl; X is hydrogen and / or lower alkyl and / or halogen.
П целое число 1-3,P is an integer of 1-3,
а в качестве производных цианфенилкарбоната состав содержит соединени общей формулыand as derivatives of cyanophenyl carbonate, the composition contains compounds of the general formula
-лl
N -О-СО -f N -O-CO -f
CNCN
где , Cj - одинаковые или различные и означают незамещенный или замешенный одним или нескольким заместител ми алифатический углеводородный остаток,where Cj is the same or different and means an aliphatic hydrocarbon residue unsubstituted or substituted by one or more substituents,
X и V - одинаковые или различные и X and V are the same or different and
л 4 означают галогеи, пр чем состав содержит 4О-50 вес. ч. производных 0-{феноксиацил)оксима и 5-10 вес. ч. производных цианфенилкарбоната , а также 51-35 вас.ч. изофорона в качестве растворител и 4-5 вес.ч, поверхностно-активного вещества.l 4 means halogen, and the composition contains 4O-50 weight. including derivatives of 0- (phenoxyacyl) oxime and 5-10 weight. including derivatives of cyanophenyl carbonate, as well as 51-35 vas.h. isophorone as a solvent; and 4-5 ppmw, a surfactant.
Источники информации, прин тые во внимание при экспертизе:Sources of information taken into account in the examination:
1.Патент Англии № 116522О,кл.А5 Е, 1970.1.Patent of England No. 116522O, class A5 E, 1970.
2.Патент Англии № 1221840,кл.АсЕ, 966.2. The patent of England No. 1221840, kl. ASE, 966.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2303336A DE2303336A1 (en) | 1973-01-20 | 1973-01-20 | HERBICIDAL MIXTURES |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU580797A3 true SU580797A3 (en) | 1977-11-15 |
Family
ID=5869802
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU7401991123A SU580797A3 (en) | 1973-01-20 | 1974-01-18 | Herbicide |
| SU752126029A SU667094A3 (en) | 1973-01-20 | 1975-04-18 | Herbicide composition |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU752126029A SU667094A3 (en) | 1973-01-20 | 1975-04-18 | Herbicide composition |
Country Status (28)
| Country | Link |
|---|---|
| JP (1) | JPS49102842A (en) |
| AR (1) | AR216883A1 (en) |
| AT (1) | AT331555B (en) |
| BE (1) | BE809928A (en) |
| BG (2) | BG21180A3 (en) |
| BR (1) | BR7400375D0 (en) |
| CA (1) | CA1013961A (en) |
| CH (1) | CH584505A5 (en) |
| CS (2) | CS178442B2 (en) |
| DD (1) | DD107571A5 (en) |
| DE (1) | DE2303336A1 (en) |
| DK (1) | DK137421C (en) |
| FI (1) | FI56472C (en) |
| FR (1) | FR2214407B1 (en) |
| GB (1) | GB1460663A (en) |
| HU (1) | HU170900B (en) |
| IE (1) | IE38761B1 (en) |
| IL (1) | IL44031A (en) |
| IT (1) | IT1049215B (en) |
| LU (1) | LU69116A1 (en) |
| NL (1) | NL7400739A (en) |
| NO (1) | NO141777C (en) |
| PL (2) | PL91646B1 (en) |
| RO (2) | RO69339A (en) |
| SE (1) | SE401075B (en) |
| SU (2) | SU580797A3 (en) |
| TR (1) | TR18484A (en) |
| ZA (1) | ZA74396B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3426719A1 (en) * | 1984-07-20 | 1986-01-23 | Hoechst Ag, 6230 Frankfurt | PLANT PROTECTIVE AGENTS BASED ON OXIMESTERS |
-
1973
- 1973-01-20 DE DE2303336A patent/DE2303336A1/en not_active Withdrawn
- 1973-11-22 DK DK631173A patent/DK137421C/en active
- 1973-12-03 DD DD175058*A patent/DD107571A5/xx unknown
- 1973-12-10 CS CS5704A patent/CS178442B2/cs unknown
- 1973-12-10 CS CS8535A patent/CS178438B2/cs unknown
- 1973-12-12 TR TR18484A patent/TR18484A/en unknown
- 1973-12-14 NO NO4775/73A patent/NO141777C/en unknown
-
1974
- 1974-01-04 LU LU69116A patent/LU69116A1/xx unknown
- 1974-01-10 PL PL1974168032A patent/PL91646B1/pl unknown
- 1974-01-16 FI FI115/74A patent/FI56472C/en active
- 1974-01-17 AR AR251980A patent/AR216883A1/en active
- 1974-01-17 IE IE99/74A patent/IE38761B1/en unknown
- 1974-01-18 NL NL7400739A patent/NL7400739A/xx not_active Application Discontinuation
- 1974-01-18 SU SU7401991123A patent/SU580797A3/en active
- 1974-01-18 BG BG28742A patent/BG21180A3/xx unknown
- 1974-01-18 BR BR375/74A patent/BR7400375D0/en unknown
- 1974-01-18 CH CH70774A patent/CH584505A5/xx not_active IP Right Cessation
- 1974-01-18 IT IT19558/74A patent/IT1049215B/en active
- 1974-01-18 RO RO7484790A patent/RO69339A/en unknown
- 1974-01-18 HU HU74SC00000459A patent/HU170900B/en unknown
- 1974-01-18 BE BE139973A patent/BE809928A/en unknown
- 1974-01-18 ZA ZA740396A patent/ZA74396B/en unknown
- 1974-01-18 FR FR7401727A patent/FR2214407B1/fr not_active Expired
- 1974-01-18 BG BG25536A patent/BG22055A3/xx unknown
- 1974-01-18 SE SE7400666A patent/SE401075B/en unknown
- 1974-01-18 RO RO7477325A patent/RO68496A/en unknown
- 1974-01-20 IL IL44031A patent/IL44031A/en unknown
- 1974-01-21 CA CA190,523A patent/CA1013961A/en not_active Expired
- 1974-01-21 GB GB272674A patent/GB1460663A/en not_active Expired
- 1974-01-21 AT AT46674*#A patent/AT331555B/en not_active IP Right Cessation
- 1974-01-21 JP JP49009177A patent/JPS49102842A/ja active Pending
- 1974-08-10 PL PL1974184009A patent/PL92143B1/pl unknown
-
1975
- 1975-04-18 SU SU752126029A patent/SU667094A3/en active
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