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SU504715A1 - Glass - Google Patents

Glass

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Publication number
SU504715A1
SU504715A1 SU2045683A SU2045683A SU504715A1 SU 504715 A1 SU504715 A1 SU 504715A1 SU 2045683 A SU2045683 A SU 2045683A SU 2045683 A SU2045683 A SU 2045683A SU 504715 A1 SU504715 A1 SU 504715A1
Authority
SU
USSR - Soviet Union
Prior art keywords
glass
thermal expansion
chemical resistance
coefficient
cao
Prior art date
Application number
SU2045683A
Other languages
Russian (ru)
Inventor
Лия Павловна Кручинина
Иван Федорович Худяков
Юрий Дмитриевич Кручинин
Ольга Васильевна Кузнецова
Original Assignee
Уральский ордена Трудового Красного Знамени политехнический институт им.С.М.Кирова
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Уральский ордена Трудового Красного Знамени политехнический институт им.С.М.Кирова filed Critical Уральский ордена Трудового Красного Знамени политехнический институт им.С.М.Кирова
Priority to SU2045683A priority Critical patent/SU504715A1/en
Application granted granted Critical
Publication of SU504715A1 publication Critical patent/SU504715A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/083—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound
    • C03C3/085—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal
    • C03C3/087—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal containing calcium oxide, e.g. common sheet or container glass

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Compositions (AREA)

Description

Изобретение относитс  к высокожелезистым стеклам, используемым в качестве облицовочного и химически стойко.го материала.FIELD OF THE INVENTION The present invention relates to high iron glasses used as a lining and chemically resistant material.

Известны высокожелезистые стекла, содержащие SiOz, АЬОз, РеаОз, FeO, СаО, MgO, КгО. Однако дл  известного стекла характерна недостаточна  химичеока  стойкость, ограничивающа  его применение.High-iron glasses containing SiOz, AO3, ReaO3, FeO, CaO, MgO, CgO are known. However, the known glass is characterized by insufficient chemical resistance, limiting its use.

Цель изобретени  - повысить химическую стойкость и снизить коэффициент термического расширени  высокожелезистых стекол.The purpose of the invention is to increase chemical resistance and reduce the coefficient of thermal expansion of high-iron glasses.

Это достигаетс  тем, что стекло содержит компоненты в следующих количествах, вес. %: SiOs54-60This is achieved in that the glass contains components in the following amounts, weight. %: SiOs54-60

АЬОз4-5ALO4-5

Ре2Оз+РеО19-22Pe2Oz + PeO19-22

MgO8,8-10MgO8,8-10

СаО6-7CaO6-7

NazO2-2,1NazO2-2,1

Дл  /получени  стекла данного состава беретс  шихта, состо ща  из 100 вес. ч. шлака никелевого производства, 20-40 вес. ч. кварцевого песка и 6-7 вес. ч. сульфата натри . Варка стекла проводитс  при 1400-1420°С, формование изделий - при 1250-1300°С и отжиг -при 600°С.In order to obtain glass of this composition, a charge consisting of 100 wt. including slag nickel production, 20-40 weight. including quartz sand and 6-7 wt. including sodium sulfate. Glass melting is carried out at 1400-1420 ° C, products are molded at 1250-1300 ° C and annealed at 600 ° C.

Полученное стекло обладает следующими сзойствамк: Химическа  стойкость по отношению:The resulting glass has the following properties: Chemical resistance against:

к концентрированной H2SO4, % 100,0 к 35%-ному NaOH, %91,0-94,0to concentrated H2SO4,% 100.0 to 35% NaOH,% 91.0-94.0

Мнкротвердость при нагревании 50 г, КГ/ММ2680-690 Коэффициент термического расширени  (100-600°С) а-Ю-, 1/град 37,0-55,0Mn-hardness when heated 50 g, KG / MM2680-690 Thermal expansion coefficient (100-600 ° C) a-Yu-, 1 / deg 37,0-55,0

Наиболее существенные положительные признаки предлагаемого стекла по сравнению с известными: данное стекло ирактически ие реагирует с серной кислотой и обладает высокой щелочеустойчивостью с одновременно низким коэффнциенто.м термического расширени .The most significant positive signs of the proposed glass are compared with the known ones: this glass reacts in a practical way with sulfuric acid and has a high alkali resistance and at the same time a low coefficient of thermal expansion.

Конкретные составы стекол (вес. %) лриведепы в табл. 1.Specific formulations of glasses (wt.%) Lryvedeps in table. one.

Свойства составов приведены в табл. 2.The properties of the compositions are given in table. 2

Предлагаемое стекло может быть использовано как химически стойкий облицовочный материал, а также как высококачественный панолнитель кислотоупорных замазок.The offered glass can be used as a chemically resistant facing material, as well as a high-quality pannolnik acid-resistant putties.

Таблица 2table 2

Форм у л а изобретени Formula inventions

Стекло, включающее Si02, AbOj, Ре2Оз, FeO, CaO, MgO и ЫазО, отличающеес  тем, что, с целью повышени  химической стойкости и снижени  коэффициента термического .расширени , оно в следующих количествGlass including Si02, AbOj, Pe2Oz, FeO, CaO, MgO and LazO, characterized in that, in order to increase chemical resistance and reduce the coefficient of thermal expansion, it is in the following amounts

SiOsSiOs

АЬОзAoz

РезОз-ЬРеОRESOZREO

MgOMgO

СаОCao

NaaONaaO

SU2045683A 1974-07-16 1974-07-16 Glass SU504715A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
SU2045683A SU504715A1 (en) 1974-07-16 1974-07-16 Glass

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SU2045683A SU504715A1 (en) 1974-07-16 1974-07-16 Glass

Publications (1)

Publication Number Publication Date
SU504715A1 true SU504715A1 (en) 1976-02-28

Family

ID=20591541

Family Applications (1)

Application Number Title Priority Date Filing Date
SU2045683A SU504715A1 (en) 1974-07-16 1974-07-16 Glass

Country Status (1)

Country Link
SU (1) SU504715A1 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4764487A (en) * 1985-08-05 1988-08-16 Glass Incorporated International High iron glass composition
US5558942A (en) * 1993-11-12 1996-09-24 Asahi Glass Company Ltd. Ultraviolet ray absorbent colored glass
US5897956A (en) * 1994-10-26 1999-04-27 Asahi Glass Company Ltd. Glass having low solar radiation and ultraviolet ray transmittance

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4764487A (en) * 1985-08-05 1988-08-16 Glass Incorporated International High iron glass composition
US5558942A (en) * 1993-11-12 1996-09-24 Asahi Glass Company Ltd. Ultraviolet ray absorbent colored glass
US5897956A (en) * 1994-10-26 1999-04-27 Asahi Glass Company Ltd. Glass having low solar radiation and ultraviolet ray transmittance

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