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SU484893A1 - Anode material for electrolytic production of manganese dioxide - Google Patents

Anode material for electrolytic production of manganese dioxide

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Publication number
SU484893A1
SU484893A1 SU1925777A SU1925777A SU484893A1 SU 484893 A1 SU484893 A1 SU 484893A1 SU 1925777 A SU1925777 A SU 1925777A SU 1925777 A SU1925777 A SU 1925777A SU 484893 A1 SU484893 A1 SU 484893A1
Authority
SU
USSR - Soviet Union
Prior art keywords
manganese dioxide
anode material
anode
electrolytic production
manganese
Prior art date
Application number
SU1925777A
Other languages
Russian (ru)
Inventor
Рафаэл Ильич Агладзе
Коба Шалвович Ванидзе
Луиза Арчиловна Зауташвили
Original Assignee
Грузинский Ордена Трудового Красного Знамени Политехнический Институт Им.В.И.Ленина
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Грузинский Ордена Трудового Красного Знамени Политехнический Институт Им.В.И.Ленина filed Critical Грузинский Ордена Трудового Красного Знамени Политехнический Институт Им.В.И.Ленина
Priority to SU1925777A priority Critical patent/SU484893A1/en
Application granted granted Critical
Publication of SU484893A1 publication Critical patent/SU484893A1/en

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  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)

Description

Изобретение относитс  к материалам анодов дл  электролитического получени  двуокиси марганца. Известен материал анода дл  пачученй двуокиси марганца электролизом, содержащий титан. Однако этот материал анода йассивируетс  при увеличении плотности 2 тока выше 0,5 а/дм , С целью устранени  пассивации анода «при повышенных плотност х тока (вьппе 2 Ю,5 а/дьг; ), предлагаетс  матераал анода содержащий т тан, в который введен мартанеП н указанные компоненты вз ты в 1виде сплава при следующем их соотношени вес Марганец6-16 Титаностальное Сплав с содержанием марганца менее 6 вес.% пассивируетс  в растворе серной кислоты, содержащем более ЗО г/л, Н„ Q О. « 4i сплавы же с содержанием марганца более 16 вес.% подвержены интенсивной коррози Пример. Провод т выделение двуокиси марганца на аноде состава, вес.%: Марганец9 Тита остальное Начальна  концентраци  марганца вО г/п, конечна  2О г/п, Като  - свинец. При анодной плотности тока 1 а/дм выход по току MitO составл ет 99,5%. По данным спектрального анализа при- .меси мышь ка, железа, алюмини , хрома и {ннкел  отсутствуют..примеси кальци  соста- /вл ют сотые доли процента, свинца и ма1 |ни  - тыс чные доли процента, меди - R с тичные доли процента. Использованне дл  анода сплава титана iC марганцем указанного состаза позвол ет ,устран ть пассивацию анода. изобретени  Материал анода дл  алектрапитического Палучени  двуокиси марганца, содержащий итан, отличающийс  те, что. - - -- - . 1.Л «.г  л г « , л 1 .jbl J Т I «, с делью устранени  пассивации анода при 34This invention relates to anode materials for the electrolytic production of manganese dioxide. Known anode material for fugging manganese dioxide by electrolysis, containing titanium. However, this anode material is dissiviated when the current density 2 is higher than 0.5 a / dm. In order to eliminate the anode passivation at elevated current densities (2 u, 5 a / dy;), an anode material containing tan The following components were introduced in MartanP in the first type of alloy with the following ratio; with a manganese content of more than 16 wt.% susceptible to intense corrosion Example. Manganese dioxide is precipitated at the anode of the composition, wt.%: Manganese9 Titus Else The initial concentration of manganese is VO g / n, final 2O g / n, Kato is lead. At anode current density of 1 A / dm, the MitO current output is 99.5%. According to the data of spectral analysis, there are no admixtures of arsenic, iron, aluminum, chromium and {nankel). Calcium impurities are / are hundredths of a percent, lead and ma1; nor are percent. The titanium iC alloy used for the anode with manganese of this composition makes it possible to eliminate the anode passivation. of the invention Anode material for aleptic palucine manganese dioxide material containing itan, characterized in that. - - - -. 1. L ". L l g", l 1 .jbl J T I ", with the task of eliminating the passivation of the anode at 34

повышенных плотност х тока, в него вве-вошении, вес.%:increased current density, injected into it, wt.%:

леи марганец и указанные компоненты вэ -Марганец 6-16lei manganese and the indicated components ve-manganese 6-16

ты в виде сплава при следующем их соот-Титаностальноеyou are in the form of an alloy with their next titanium-soot

484893 484893

SU1925777A 1973-05-14 1973-05-14 Anode material for electrolytic production of manganese dioxide SU484893A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
SU1925777A SU484893A1 (en) 1973-05-14 1973-05-14 Anode material for electrolytic production of manganese dioxide

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SU1925777A SU484893A1 (en) 1973-05-14 1973-05-14 Anode material for electrolytic production of manganese dioxide

Publications (1)

Publication Number Publication Date
SU484893A1 true SU484893A1 (en) 1975-09-25

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
SU1925777A SU484893A1 (en) 1973-05-14 1973-05-14 Anode material for electrolytic production of manganese dioxide

Country Status (1)

Country Link
SU (1) SU484893A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2723405A1 (en) * 1976-05-25 1977-12-15 Inst Neorganicheskoi Chimii Ak ELECTROCHEMICAL PROCESS FOR THE PRODUCTION OF MANGANE DIOXIDE
EP0148439A2 (en) * 1983-12-21 1985-07-17 Hoechst Aktiengesellschaft Activated metal anodes and process for their manufacture

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2723405A1 (en) * 1976-05-25 1977-12-15 Inst Neorganicheskoi Chimii Ak ELECTROCHEMICAL PROCESS FOR THE PRODUCTION OF MANGANE DIOXIDE
EP0148439A2 (en) * 1983-12-21 1985-07-17 Hoechst Aktiengesellschaft Activated metal anodes and process for their manufacture

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