SU475792A3 - Composition for treatment of linen after washing - Google Patents

Description

dodecyl, tetradecyl, hexadecyl and octadecyl. Deputy Rs is a methyl radical.

The ammonium compounds of formula 1 used can be converted to salts with various anions X, for example, sulfates, borates, phosphates or salts of organic acids.

The ammonium compounds of the formula 1 are, at normal temperature, solid, waxy or melted. They can be easily soluble or dispersed in cold water; they are readily soluble in lower alcohols, methanol, ethanol, isonronanol.

They are obtained by the exchange decomposition reaction of dicarboxylic acid HOOC - (СНОН) - (СВ2) p - COOH and the tertiary amine of the formula NRiRaRs, where n. B, Ri, R2 and Rj are as defined above, with ennchlorohydrin or enibromohydrin, preferably in the presence of a solvent, moreover, in order to avoid the formation of by-products, the tertiary amine is used in slightly smaller amounts in relation to zylohaline.

Decomposition of drains: 60–70 ° C; practically quantitative decomposition under these conditions usually takes about 25 hours. The products are obtained after distillation of the solvent and, if necessary, unreacted starting materials.

The target product is purified with the aid of, over-treatment or recrystallization, and, for example, in lower alcohols, aetone, acetic acid ester, gasoline with active carbon or other adsorption agents.

In a mixture of 0.30 mol of dicarboxylic acid and 0.30 mol of epichlorohydrin in 250 ml of isonropanol, at a temperature of 60-65 ° C, 0.27 mol of tertiary amine is stirred in to stir. Additionally stir at 65 ° C for 30 hours, then the solvent is distilled off and the residue is in a high vacuum at 70 ° C, freed from traces of unreacted starting materials. Get monoammonium salts. Similarly, using appropriate amounts of raw materials, get ammonium salts. The components of the composition are used as follows: eat ratio, weight,%:

Dispersant0.5-3

Organic solvent1-15

Additives0,3-7,5

Fabric softener5-15

WaterUnder 100

Additives consist mainly of optical brighteners, antimicrobial active substances, acidic additional substances, fragrances and dyes and are part of the composition at the following ratio of components, weight. %: Antimicrobial active substance 0.2-3.0

Acidic additional substances 0,2-6,0. Cotton Brightener 0.01-0.5

Nolamide 0,01-0,5 clarifier

Perfume 0,01-0,5

Dye0,00001-0.05

Non-ionic surface-active substances are used as dispersants. These include products with hydrophilic properties due to the presence of nonether ethers, amino oxide, sulfoxide or phosphoxyoxide groups, alkylolamide groups, and also generally due to the accumulation of hydroxyl groups. Such compounds contain at least one hydrophobic radical with 8-26 carbon atoms and at least one non-non-group.

The nascent hydrophobic radical is usually aliphatic, sometimes alicyclic.

It can be through media or through intermediate groups associated with groups

giving water solubility. Intermediate groups may be, for example, benzene rings, carbopic or ester carbonate groups, ether and complex esters of polyvalent alcohols, for example ethylene glycol, propylene glycol, glycerin or the corresponding polyether radicals.

Special practical iptres have compounds obtained by npredneni

ethnlenoxide and (or) glycide to fatty alcohols, alkylphenols, fatty acids, fatty amines, amides of the fatty or sulfonic acid, and these non-ionic substances may contain 6-100, unfortunately

8-40 or 8-20 ether radicals per molecule, especially ethylene glycol ether radicals. In addition, propylene or butylene glycol ether radicals can be found in these polyester chains or at their ends.

In addition, the so-called "Pluronic n" Teironic products are used. They are obtained from water-insoluble polypropylene glycol or water-soluble propoxylated lower aliphatic alcohols,

containing 1-8, preferably 3-6 carbon atoms, or water-soluble propoxylated alkandiamines. These water-insoluble (i.e. hydrophobic) propylene oxide derivatives are converted to non-ionic

substances by ethoxylation to solubility in water. As non-ionic substances, also known as "Ucon-Fluid", water-soluble reaction products of the above aliphatic alcohols with propylene oxide can be used as non-ionic substances.

Non-neoprene substances used also include fatty or sulphonic acid alkylolamides, which are derived from mono- or diethanolamine, dhydroxypropylamine, or other polyhydroxyalkylamines, for example, clay-nityum. They can be replaced by amides of higher primary or secondary alkylamines and polyhydroxycarboxylic acids.

Kaniline-active amine oxides include, for example, products derived from higher tertiary aiMnnoB, containing one hydrophobic alkyl radical and two short alkyl radicals and / or alkyl tin radicals each having up to 4 carbon atoms. In addition to water-soluble iosurfactants, bruises are used as non-ionic dispersants, also water-soluble or emulsifiable or dispersible compounds that either have no hydrophobic radicals, or their nature or the number of hydrophilic groups is not sufficient to achieve complete solubility in water. The former include, for example, solid or liquid polyethylene glycols, addition products of ethylene oxide and glycerol and other polyalcohols, etc. The latter include, for example, partial glycerides of fatty acid, water-soluble alkoxylation products, for example, having 2- 5 ethylene glycol ether radicals in the molecule.

Lower alcohols with 1-5 carbon atoms are used as water-soluble organic solvents, for example, methanol, ethanol, propanol, isopropanol, butanol, amyl alcohol, and lower ketops — acetone, methyl plastic, and ethylene and dethylene glycol and their mono- or polyethylene glycol. dimethyl or ethyl ether. Isopropanol is of particular interest. Inorganic and peraperive actinic organic acids with 2-8 carbon atoms, for example, amidosulfonic acid, urinary compounds of orthophosphoric acid, boric acid, oxalic acid, lactic acid, glycol, citric acid, citric acid, benzoic acid, phthalic acid, gluconic acid, vinegar propionic acid, are used as acidic substances. and also benzene, toluene or xylosulfonic, sulfoacetic or sulfobenzoic acid or alkali metal salts of these acids.

The clarifiers used are usually derivatives of amyostilbensulfonic acid or diaminostilbendisulfopic acid, diarylpyrazole, carbostyril 1,2-di- (2-benzoxazolyl) or 1,2-di- (2-beisimidazolyl) ethylene, bezoxazoltiophene, and temsoxazolthiophene and acetone, and 1,2-di- (2-beisimidazolyl) ethylene, bezoxazolthiophene, and besoxazolthiophene and acetone, and 1,2-di- (2-beisimidazolyl) ethylene, bezoxazolthiophene, and besoxazole thiophene;

Examples of a clarifier of the class of diamipostilbepdisulfonic acid derivatives are compounds of formula II

(

W K

S-tlr

AND,

Have

I

ii

IT formulas RI and R2 are alkoxy groups, amino groups or radicals of aliphatic, aromatic or heterocyclic, ihervich or secondary amines, as well as amiposulfonic radicals

acids, moreover, the aliphatic radicals in the aboveiiiiijx groups preferably contain C, -; atom, while heterocyclic ring systems are usually 5 or 6 membered rings. Aro.matical radicals can be radicals of aniline, nitrate acid or aiylsulfonic acid. Brighteners obtained from dnaimolepdnsulfonic acid are usually used as clarifiers.

To the clarifier of polyamide OTOS TC diarnlirovolny formula P1 n IV

31

Ne

,

 Ar,

Ag

In the formula, Ks and Rs are hydrogen atoms, sometimes substituted by carboxyl, carbonamide or ester groups, alkyl or arylo radicals;

R4 and Rs are hydrogen or a short-chained alkyl radical, Agch-aryl radicals such as fennl, diphenyl or Japhyl, which may contain a substituent, and for example hydroxyl, alkoxy, hydroxyalkyl, amioalkylamino, acyl-amino, carboxyl groups, carbonic ester groups acids, sulfonic acids, sulfonamide n sulfopic group; h or halogen atoms.

The clarifying agent of polypamide also includes aliphatic or aromatic substituted amide, Cl-1, Py, ipprpmer, 4-methyl-7-d, 1-methylamino or 4-methyl-7-diethylaminocupine. In addition, compounds of 1- (2-benzimidazol1 l) -2- (1-hydroxyethyl-2-benznimidazolyl) ethylene and 1-ethyl-3-phenyl-7-diethylaminocarboethnrnl can be used as clarifiers of polyamide. As a clarifier of polyester fibers and amide floor, also used are types of 2,5-dn- (2-benzoxacholyl) -tofen, 2- (2-bepsoxazolyl) -naphtho- 2, 3-b-tnofen n, 2-dp- (5 -me-tpl-2-benzoxazoln) -ethnlen.

The antimicrobial agents are bactericidal or bacteriostatic, fuigtsidno-il1 fuggistatically active. Oii can be used in the form of their salts. The anti active substances are generally quaternary compounds of almopps, which, along with one long chain aliphatic and two short-chain aliphatic carbon radicals, contain in the molecule an aromatic radical bound to the nitrogen atom through an aliphatic carbon atom or one aliphatic carbon radical or one aliphatic carbon radical or one aliphatic carbon radical attached to the nitrogen atom through an aliphatic carbon atom or one aliphatic carbon radical. double bonds. Examples of such aitimikrobiyh quaternary ammonium compounds are the following: dimetilbenzildodetsilammoniyhlorid, dimetilbenziltetradetsilammoiiyhlorid, dimethyl - (ethylbenzyl) - dodetsilammoniyhlorid, dimetilbenzildetsilammoniybromid, dietilbenzildodetsilammoniyhlorid, dietilbenziloktilammoniyhlorid, dibutilallilmetiletilbenzil, and etiltsiklogeksilallil etilkrotildietilaminoetildodetsilammoniyhlorid. Antimicrobial agents are lower bile or diols with 3–5 carbon atoms substituted by both bromine and nitro groups, for example, compounds 2-bromo-2-nitro-pro-1, 3-diol, 1-bromo-1-nitro-3, 3, 3-trichloro-2-ironanol, 2-bromo-2-nitrobutaiol, phenolic compounds such as halogenated phenols, for example chlorinated phenols; alkyl-, cycloalkyl-, aralkyl- and phenylphenols with 1-12 carbon atoms in the alkyl radicals and with 1-4 halogen atoms in the molecule; alkylene bisphenols, for example, derivatives substituted with 2-6 halogen atoms or lower alkyl or trifluoromethyl groups, with one alkylene bridging unit consisting of 1-10 carbon atoms; hydroxybenzoic acids or their esters and amides, anilides, which in the benzoic acid radical and (or) aniline, can be replaced by two or three halogen atoms and (or) trifluoromethyl groups; orthophenoxyphenols, which can be substituted by 1-7 halogen atoms and (or) hydroxyl, cyano, carbomethoxy carboxyl group or lower alkklom; preferred derivatives of orthophenoxyphenol are 2-hydroxy-2, 4,4-trichlorodiphenyl ether. The washing after washing can be carried out in different ways, depending on the method of drying. If dried in a hot air dryer, the laundry may be directly sprayed with a dispersion of a softener, or the active substance with a carrier may be applied to the laundry, for example by spraying the inner walls of the dryer with a dispersion of the active substance before loading the appliance with laundry. a dispersion-impregnated active ingredient, wherein the softener of textiles is transferred to the laundry during the drying process. Nowadays, the laundry is mostly dried in the hanging position, therefore, the softener is advantageously used in the last rinsing of the washing process for hand or machine washing. The active ingredient of the formula 1 is applied in the rinsing solution in amounts from 0.1 to 2.0, preferably 0.2-1.0 g / l. Obtained by the method described above and used to treat the linen after washing. Example 1. Use the following honeycomb,%: 3,3-Tartaroyldioxibis- (2-oxnpropylmethyltetradecylammonium chloride) 5.0 The addition product of coconut alcohol (Ci2-GIS) to 4 moles of ethylene oxide1.0 Pzonpropyl alcohol1.0 Cotton lighter0.1 Fragrant substance 0 cotton substance 0,010. 2 Dye 0.05 Water Residue Example 2. The following is used:% 3,3-Succinyldioxibis- (2-hydroxypropylmethyltetradecyl ammonium chloride) 5.0 Adduct of nonylphenol to 9.5 mol of ethylene oxide1.0 Ethylene glycol1 Glycolic acid 5.0 Perfume 0.4 Water Residue Example 3. The following honeycomb is used c,%: 3,3-Oxalyldioxibis- (2-hydroxypropylmethyl ditertonyl ammonium chloride 15.0 Adduct of oleyl and cetyl is reduced to 10 mol of ethylene oxide3.0 Pzopropyl alcohol7.5 Methyl ethyl ketone7.5 Cotton clarifier0.2 Fragrance0.3 WaterWaterOcttect 300% WaterOstattect0.3% Next coav,%: 3,3-Oxalyldioxy- (2-hydroxypropylmethyl) Tradecylammonium chloride) 7 Odyl acetyl alcohol product from 10 oleyl acetyl alcohol combined with citric acid 1 Water 90 Example 5. The following coav,%: 3,3-Malonyl dioxybis-2 (hydroxypropyl hydroxypropyl) (2-hydroxypropylpropyl) (2-hydroxypropyl), 2-hydroxypropylamine; chloride 7 Adduct from oleyl acetyl alcohol 5 mol of ethylene oxide Glycolic acid 1 Water 90 Example 6. Use the following soav,%: 3,3-Succinyldioxy- (2-hydroxypropylmethyl tetradecylammonyl chloride 7) The co-product of the cobalt compound (CI-I-GI) I i'm I am not already at work, I have 4, 3% sucrosenyldioxy- (2-hydroxypropylmethyltetradecylmonium nitride) 7 the cobalt nitrite (Ci2-GI) I and I I have I, I, I, I, I, I, I, I, I, I, I, I, I use 3% sucrotic acid) EXAMPLE 7 The following composition is used, ° C: 3,3-Tartaroyl dioxibis- (2-hydroxypropylmethyltetradecylammonium chloride 7 Nonylpepol addition product 9.5 mol of ethylene oxide 2 Tartaric acid 1 Water 90 Example 8. The following is used with% 3%: , 3-Oxalild ioxibis- (2-hydroxypropylmethyltetradecyl ammonium chloride7 Isopropyl alcohol 6 Adduct from coking alcohol (Ci2-Cis) and 4 mol of ethylene oxide 2 Tartaric acid1 Water 89 Example 9, 3- Succinyldioxibis- (2-hydroxypropylmethyltetradetracyl ammonium chloride7 Isopropyl alcohol2 Adduct of cetyl olel alcohol and 10 moles of ethylene oxide 2 Sodium acetate 1 Water 88 Example 10. The following is used with%; 3,3-Maloyldioxibis- (2-hydroxypropylmethylditetradecyl ammonium chloride 7 Isopropyl alcohol 10 Addition product from cetyl olel alcohol and 4 mol of ethylene oxide 2 Citric acid 2 Water 79 Example I. The following is used,%: 3,3Tartaroyl dioxybis is a challenge for 2% of the same level as for non-adult The addition product from nonylphenol and 60 mol of ethylene oxide 2 Glycolic acid 1 Water 80 Example 12. The following is used,%: 3,3-Lowioxy dioxybis- (2-hydroxypropylmethyltetradecyl ammonium chloride7 Addition product from cetyl olel alcohol and 5 mol of ethylene oxide 2 Cotton clarifier of formula II, where RI is aniline radical and Ra-dihydroxyethylamino radical 0.1 Water 90.9 Example 13. The following is used with% 3,3-Tartaroyl dioxybis- (2-hydroxypropylmethyldidetradecyl ammonium chloride 7 Cetyl olel alcohol and 10 mol of ethylene oxide 2 Tartaric acid1 Cotton clarifier of formula II, in which RI is an alkylene radical and R2-dihydroxyethylamino radical, 2 Water8 9.8 Example 14. The following co is used,%: 3,3-Malonyldioxybis- (2-hydroxypropylmethlptic jcl Products lrisoedppapp pz coconut alcohol (Ci2-Cis) and 4 moles of ethylene oxide2 Citric acid2 Clonium clarifier of the formula II, in which RI is aniline radical of the R2-dihydroxyethylmineradical0, 2 Water88.8 Example 15. Use the following co. 3,3-0-0 gd. - (2-hydroxypropyl methyl methyl ditetradecyl ammonium chloride7 Isopropyl alcohol6 The product is added from coconut alcohol (Ci2-GIS) and 3 mol of ethylene oxide2 Tartaric acid1 Cotton clarifier of the formula I, in which RI is aniline radical and 1 -dihydroxyethylethyliamyrocalcate hydrochloride is alkaloacylated hydrochloride; 16. Used with co-soav,%: 3,3-Oxalildioxybis- (2-hydroxylpropylmethyltetradecyl ammonium chloride 7 Isopropyl alcohol6 Coconut alcohol (Ci2-Cis) and 4 moles of ethylene oxide 2 Wine acid1 Cotton bleach of the formula I, in which R means aniline radical and R2-glyph-edelemidyl ehydrogen e-2) Tartaric acid1 Cotton brightener of formula I, in which R means aniline radical and R2-glyph-edelemyl ehydrogenyl2 tartaric acid 2 -Benzyl-T-dodecyl-N, N-dimethylammonium chloride 1 Water 82.8 Example 17. The following covol,% are used: 3-x Malo-oxy-2-hydroxypropylmethylditetradecylammonium chloride7 The adhesion product from coconut alcohol (Ci2-Cis) and 3 mole of ethylene 2 -2-o2-2-2 o -2-2-o -2-2-o -2-2-o -2-2-o -2-2-hydroxyethylmonium chloride 7 Adduct from coconut alcohol (Ci2-Cis) and 3 mol of 2ya2-a2-2 o -2 o -2-2-hydroxyethylmonium chloride; Example 18. Use The following is compiled,%: H-Malonoxy-2-hydroxypropylmethyltetradecylammonium chloride Adhesion product from nonylphenol and 9.5 mol of ethylene oxide2 Isopropyl distilled10 Tartaric acid2 Water79 Example 19. The following is used: 7o: H-Maloxy-2-hydroxypropylmethylamine and hydrogen; coconut alcohol (Ci2-C4) and 4 moles of ethylene oxide2 Isopropyl alcohol4 Wine acid2 Cotton bleach formula II, in which RI means anilino radical and Ng-morpholino radical 0.2 Water84.8 Example 20 H-Maloxy-2-hydroxypropylmethyldite Adecylammonium chloride7 Addition product of coconut alcohol (Ci2-Cu) and 4 moles of ethylene oxide2 Isopropyl alcohol6 Glycolic acid2 Cotton bleach of the formula II, in which RI is an anilino radical, Cg-morpholino radical 0.2 Water Hydro.8.8 The composition of the data was given by mol glymete 80 g with an organic solvent and with other additives it is melted at 50-60 ° C into a homogenous alloy. The acid and optical brightener are dissolved in water and the aqueous solution is intensively stirred, added to the alloy. Blending substances, stains and dyes can be added to the preparations. The determination of the effect of the softener is carried out with one dispersion of the preparation. One-shot processing of hardened tissue samples leads to a soft-touch fabric. The feeding ability, expressed in%, has a value of 91.1 to 55.5%, compared to 20% when using a known fabric softener. The subject of the invention: A composition for treating linen after a cloth based on an aqueous solution of an organic solvent with the addition of a dissneror, fabric softener and additives, characterized in that, in order to increase the softening effect of the absorption capacity of cans, a compound of the general formula II® is introduced as a softener with Oi-0- {M1.g-L10H- (H2-K-K2X (OIOI) ", Ks (V,) n I GO-0-A. t 0-4; P O-4, and, t + p not more than 4; RI and R2 alkyl Ci-C24; Rs alkyl Ci-C4; XQ anion, for example, -C1, -Gr; BH or, at m 0,, -SPz or C2H5; AH or radical. © C -Ci: -, - CIIOIi-CH-NR, R, R., X where RI R2 and RS have the above 5-15 wt.% based on the weight of the composition.