SU433155A1 - METHOD OF PSHGUCHUYI AND PHOSPHOROGENEAL CONNECTIONS - Google Patents
METHOD OF PSHGUCHUYI AND PHOSPHOROGENEAL CONNECTIONSInfo
- Publication number
- SU433155A1 SU433155A1 SU1775103A SU1775103A SU433155A1 SU 433155 A1 SU433155 A1 SU 433155A1 SU 1775103 A SU1775103 A SU 1775103A SU 1775103 A SU1775103 A SU 1775103A SU 433155 A1 SU433155 A1 SU 433155A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- pshguchuyi
- phosphorogeneal
- connections
- alkoxy
- aryl
- Prior art date
Links
Description
1one
I Изобретение относитс к спосЪ бу получени не описанных в литературе фосфорорганических соединений общей фо|зыулыI The invention relates to the method of obtaining organophosphorus compounds of the general phase not described in the literature.
R Pt H CH-N-PRi II , II О (0),R Pt H CH-N-PRi II, II O (0),
где и - алкоксил или арил,where and is alkoxy or aryl,
В - алкил или арил, B is alkyl or aryl,
R - алкил, алкенил или алкоксилR is alkyl, alkenyl or alkoxy
n-0-i.n-0-i.
Эти соединени могут найти применение как потенциальные физиологически активные вещества.These compounds can be used as potential physiologically active substances.
Способ получени фосфорорганических соединений приведенной общей формулы основан на известной реакции получени фосфорилированных амидов, котора однако ранее не примен лась дл синтеза соединений аналогичной структуры.The method of producing organophosphorus compounds of the above general formula is based on the known reaction of obtaining phosphorylated amides, which, however, has not previously been used to synthesize compounds of a similar structure.
Предлагаемый способ заключаетс в том, что хлорангидриды кис|Лот фосфора общей формулы: iThe proposed method consists in the following: acid chlorides Kis | Lot phosphorus of the general formula:
CIPRCIPR
IIII
(0)„(0) „
зПZP
где Д - алкил, алкенил или алкоксил ; П - 0-1,where D is alkyl, alkenyl or alkoxy; P - 0-1,
подвергают взаимодействию с иминами фосфорилированных уксусных альдегидов общей формулыexposed to imine phosphorylated acetaldehyde of the general formula
R2PCH2-CH 1 R,R2PCH2-CH 1 R,
II ОII Oh
где В - алкоксил или арил;where B is alkoxy or aryl;
R - алкил или арил.R is alkyl or aryl.
Процесс провод т в среде четыреххлористого углерода в присутствии акцептора хлористого водорода ,например, тризтиламина.The process is carried out in carbon tetrachloride in the presence of a hydrogen chloride acceptor, for example, triztilamine.
Целевые продукты выдел ют известными приемами. Выход до 65%.Target products are recovered by known techniques. Yield up to 65%.
П Р И М Е Р I. Получение л/фенил (дийзопропоксифосфонил )-виниламида дибутилфосфино|вой кислоты:P I M E R I. Preparation of l / phenyl (diisopropoxyphosphonyl) -vinyl amide dibutylphosphinic acid:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU1775103A SU433155A1 (en) | 1972-04-15 | 1972-04-15 | METHOD OF PSHGUCHUYI AND PHOSPHOROGENEAL CONNECTIONS |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU1775103A SU433155A1 (en) | 1972-04-15 | 1972-04-15 | METHOD OF PSHGUCHUYI AND PHOSPHOROGENEAL CONNECTIONS |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU433155A1 true SU433155A1 (en) | 1974-06-25 |
Family
ID=20511351
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU1775103A SU433155A1 (en) | 1972-04-15 | 1972-04-15 | METHOD OF PSHGUCHUYI AND PHOSPHOROGENEAL CONNECTIONS |
Country Status (1)
| Country | Link |
|---|---|
| SU (1) | SU433155A1 (en) |
-
1972
- 1972-04-15 SU SU1775103A patent/SU433155A1/en active
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