SU359824A1 - METHOD OF OBTAINING DIAMIDODIALENES - Google Patents
METHOD OF OBTAINING DIAMIDODIALENESInfo
- Publication number
- SU359824A1 SU359824A1 SU1623004A SU1623004A SU359824A1 SU 359824 A1 SU359824 A1 SU 359824A1 SU 1623004 A SU1623004 A SU 1623004A SU 1623004 A SU1623004 A SU 1623004A SU 359824 A1 SU359824 A1 SU 359824A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- aluminum
- diamidodialenes
- obtaining
- amine
- ethers
- Prior art date
Links
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical class [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N Aluminium hydride Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 150000004985 diamines Chemical class 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 125000004435 hydrogen atoms Chemical class [H]* 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 101700048824 A1H3 Proteins 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- DLFBBZNTWLQIPN-UHFFFAOYSA-N [Al].[AlH2][H] Chemical compound [Al].[AlH2][H] DLFBBZNTWLQIPN-UHFFFAOYSA-N 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000004292 cyclic ethers Chemical class 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000004820 halides Chemical group 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- HPQVWDOOUQVBTO-UHFFFAOYSA-N lithium aluminium hydride Substances [Li+].[Al-] HPQVWDOOUQVBTO-UHFFFAOYSA-N 0.000 description 1
- OCZDCIYGECBNKL-UHFFFAOYSA-N lithium;alumanuide Chemical compound [Li+].[AlH4-] OCZDCIYGECBNKL-UHFFFAOYSA-N 0.000 description 1
- -1 methyl ethyl Chemical group 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000002194 synthesizing Effects 0.000 description 1
Description
Изобретение относитс к новым соединени м алюмини - диамидодиалан.ам, которые благодар ценным свойствам могут найти применение в синтезе полимеров.The invention relates to new aluminum compounds, diamidodialan, which, due to valuable properties, can be used in the synthesis of polymers.
Известен опособ получени аминного комплекса гидрида алюм1ини из алюмини ,, водорода и амина.A method is known for the preparation of the amine complex of aluminum-hydride aluminum from aluminum, hydrogen, and amine.
Предлагаетс способ получени диамидодиаланов общей формулыA method for the preparation of diamidodialanes of the general formula
(X)., А1 - N - R - N - А1 (X).,(X)., A1 - N - R - N - A1 (X).,
где X - водород, галоид или остаток вторичного амина;where X is hydrogen, halide or a residue of a secondary amine;
каждый из R представл ет собой углеводородный радикал «ли вместе образуют цикл; R - ненасыщенный или насыщенный алифатический двухвалентный углеводородный радикал, замещенный или незамещенный цийлоалкильный радикал, замещенный или незамещенный арильный радикал, заключающийс в том, что диамин подвергают взаимодействию с алюминийгидридом в среде органического растворител , с выделением целевого продукта известными приемами.each of R represents a hydrocarbon radical or together forms a cycle; R is an unsaturated or saturated aliphatic bivalent hydrocarbon radical, a substituted or unsubstituted δ-cycloalkyl radical, a substituted or unsubstituted aryl radical, which means that the diamine is reacted with aluminum hydride in an organic solvent medium, and the desired product is isolated using known techniques.
мом азота амина и атомом алюминийгндрида. Процесс осуществл етс при температуре от -20 до +70°С и при да.влении, создаваемом упругостью паров растворител при рабочей температуре.amine nitrogen and an aluminum atom. The process is carried out at a temperature of from -20 to + 70 ° C and at a pressure generated by the elasticity of the solvent vapor at the operating temperature.
В качестве растворител используют простые эфиры, например диметиловый, диэтиловый , метилэтиловый, циклические эфиры и смеси углеводородов с указанными эфирами.As the solvent, ethers, for example dimethyl, diethyl, methyl ethyl, cyclic ethers and mixtures of hydrocarbons with the indicated ethers are used.
Соединени гидрида алюмини выбираютс из групп: MeAlHi, где Me - щелочной металл , предпочтительно литий, «ли А1Нз, причем оба эти соединени представл ют собой эфирные комплексы; AlHgX, представл ющийAluminum hydride compounds are selected from the following groups: MeAlHi, where Me is an alkali metal, preferably lithium, " A1H3, both of which are ester complexes; AlHgX representing
собой эфирный комплекс, где X - атом галоида; H2A1NR2, где R - радикал амина или гетероциклического соединени , св занный с алюминием азотной св зью. В качестве диамина берут М,Ы-диэтилэтилендиамин , или Ы,М-дипропилэтилендиамин, или М,Ы-диэтилгексаметилендиамин, или их хлорпидрат.is an ether complex, where X is a halogen atom; H2A1NR2, where R is an amine or heterocyclic radical bonded to an aluminum by a nitrogen bond. As diamine take M, N-diethylethylenediamine, or N, M-dipropylethylenediamine, or M, N-diethylhexamethylenediamine, or their chloropidrate.
Пример 1. 207 мл 2,97 М раствора гидрида лити -алюмини медленно прибавл ютExample 1. 207 ml of a 2.97 M solution of lithium aluminum hydride are slowly added
к 58,6 г хлоргидрата К,М-диэтилэтилендиамина (молекул рный вес 189), что соответствует 620 мг-атомам азота.to 58.6 g of hydrochloride K, M-diethylethylenediamine (molecular weight 189), which corresponds to 620 mg-nitrogen atoms.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT2175070 | 1970-03-11 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| SU359824A1 true SU359824A1 (en) | |
| SU384207A3 SU384207A3 (en) | 1973-05-23 |
Family
ID=
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