SU1761734A1 - Composition for application of glazed coating to ceramic tile - Google Patents
Composition for application of glazed coating to ceramic tile Download PDFInfo
- Publication number
- SU1761734A1 SU1761734A1 SU914899533A SU4899533A SU1761734A1 SU 1761734 A1 SU1761734 A1 SU 1761734A1 SU 914899533 A SU914899533 A SU 914899533A SU 4899533 A SU4899533 A SU 4899533A SU 1761734 A1 SU1761734 A1 SU 1761734A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- electrolyte
- copper
- cadmium
- composition
- plating
- Prior art date
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 10
- 239000011248 coating agent Substances 0.000 title claims abstract description 9
- 239000000203 mixture Substances 0.000 title claims description 13
- 239000000919 ceramic Substances 0.000 title claims description 7
- 238000007747 plating Methods 0.000 claims abstract description 10
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000010949 copper Substances 0.000 claims abstract description 8
- 239000003792 electrolyte Substances 0.000 claims abstract description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052802 copper Inorganic materials 0.000 claims abstract description 7
- 229910052793 cadmium Inorganic materials 0.000 claims abstract description 6
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 5
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 5
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000004927 clay Substances 0.000 claims abstract description 5
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000004576 sand Substances 0.000 claims abstract description 5
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000005246 galvanizing Methods 0.000 claims abstract description 3
- 238000001556 precipitation Methods 0.000 claims description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims 2
- 150000001805 chlorine compounds Chemical class 0.000 claims 2
- 229910052742 iron Inorganic materials 0.000 claims 2
- 229910052708 sodium Inorganic materials 0.000 claims 2
- 239000011734 sodium Substances 0.000 claims 2
- 229910052938 sodium sulfate Inorganic materials 0.000 claims 2
- 235000011152 sodium sulphate Nutrition 0.000 claims 2
- 229910052725 zinc Inorganic materials 0.000 claims 2
- 239000011701 zinc Substances 0.000 claims 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims 1
- 239000004327 boric acid Substances 0.000 claims 1
- 238000001354 calcination Methods 0.000 claims 1
- 235000003891 ferrous sulphate Nutrition 0.000 claims 1
- 239000011790 ferrous sulphate Substances 0.000 claims 1
- 239000003292 glue Substances 0.000 claims 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims 1
- RRIWRJBSCGCBID-UHFFFAOYSA-L nickel sulfate hexahydrate Chemical compound O.O.O.O.O.O.[Ni+2].[O-]S([O-])(=O)=O RRIWRJBSCGCBID-UHFFFAOYSA-L 0.000 claims 1
- 229940116202 nickel sulfate hexahydrate Drugs 0.000 claims 1
- 150000004686 pentahydrates Chemical class 0.000 claims 1
- UOURRHZRLGCVDA-UHFFFAOYSA-D pentazinc;dicarbonate;hexahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[O-]C([O-])=O.[O-]C([O-])=O UOURRHZRLGCVDA-UHFFFAOYSA-D 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 239000011780 sodium chloride Substances 0.000 claims 1
- XXFQGNXPWZSRRK-UHFFFAOYSA-N sodium;n-chlorobenzenesulfonamide Chemical compound [Na+].ClNS(=O)(=O)C1=CC=CC=C1 XXFQGNXPWZSRRK-UHFFFAOYSA-N 0.000 claims 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims 1
- 229910021653 sulphate ion Inorganic materials 0.000 claims 1
- 235000005074 zinc chloride Nutrition 0.000 claims 1
- 239000011592 zinc chloride Substances 0.000 claims 1
- 238000010521 absorption reaction Methods 0.000 abstract description 2
- 239000003086 colorant Substances 0.000 abstract description 2
- 239000000047 product Substances 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 238000009500 colour coating Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000012716 precipitator Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
Landscapes
- Glass Compositions (AREA)
Abstract
Сущность изобретени : шихта содержит силикатную фритту 88-90%, глину2-4%, каолин 2-4%, песок 1-2% и продукт осаждени раствором соды отработанного электролита, выбранного из группы: меднени , цинковани , кадмировани и никелировани 2-5%. Характеристики: покрытие имеет коричневые, голубой и белый цвета, водопоглощение 4.,.6%, термостойкость 150...20°С, морозостойкость 40 циклов. 4 табл.SUMMARY OF THE INVENTION: The charge contains a silicate frit 88-90%, clay 2-4%, kaolin 2-4%, sand 1-2%, and a precipitated product with a solution of soda electrolyte from the group: copper plating, galvanizing, cadmium plating and nickel plating 2-5 % Characteristics: the coating has brown, blue and white colors, water absorption 4.,. 6%, heat resistance 150 ... 20 ° C, frost resistance 40 cycles. 4 tab.
Description
Изобретение относитс к строительной керамике, в частности к составам дл получени цветного глазурованного покрыти на фасадной керамической плитке.The invention relates to building ceramics, in particular, compositions for producing a colored glazed coating on a facade ceramic tile.
Целью изобретени вл етс получение окрашенного покрыти и повышение водостойкости .The aim of the invention is to obtain a colored coating and an increase in water resistance.
Поставленна цель достигаетс тем что состав дл получени глазурованного покрыти , включающий силикатную фритту, глину, каолин и песок, дополнительно содержит продукт осаждени раствором соды отработанного электролита, выбранного из группы меднени , цинковани , кадмировани и никелировани , при следующем соотношении компонентов, мас.%:The goal is achieved by the fact that the composition for producing a glazed coating, including silicate frit, clay, kaolin and sand, additionally contains a precipitation product with a solution of soda electrolyte selected from the group of copper plating, galvanizing, cadmium plating and nickel plating, with the following ratio of components, wt.%:
ФриттаFrit
ГлинаClay
КаолинKaolin
ПесокSand
Указанный продуктSpecified product
осаждени 2...5precipitation 2 ... 5
88...90 2...488 ... 90 2 ... 4
,.4,.four
..2..2
2, 1.2, 1.
Продукт осаждени получают следующим образом.The precipitation product is obtained as follows.
В стакан емкостью 1000 мл, помещенный в термостат и снабженный термометром , мешалкой, барЬотером дл подачи воздуха и дозатором дл подачи осадител , помещают 50 мл раствора отработанного электролита и дозатором прибавл ют стехи- ометрическое количество раствора технической кальцинированной соды с концентрацией 1,05 моль/л. Температуру осаждени поддерживают в пределах 15...45°С. После завершени осаждени суспензию фильтруют, осадок сушат, измельчают и пропускают через сито 10000 отв/см2 до остатка 0,1...0,2%.In a 1000 ml beaker placed in a thermostat and equipped with a thermometer, a stirrer, a barometer for air supply and a dispenser for supplying a precipitator, 50 ml of the spent electrolyte solution are added and a stoichiometric amount of technical soda soda solution with a concentration of 1.05 mol / l The temperature of precipitation is maintained within 15 ... 45 ° C. After the precipitation is complete, the suspension is filtered, the precipitate is dried, ground, and passed through a sieve of 10,000 holes / cm 2 to a residue of 0.1 ... 0.2%.
Услови получени и характеристика полученных продуктов приведены в табл.1.The preparation conditions and the characteristics of the products obtained are given in table 1.
Полученные продукты осаждени используют при приготовлении составов дл получени глазурованного покрыти на фасадной керамической плитке, который гото (ЛThe obtained precipitation products are used in the preparation of compositions for the preparation of a glazed coating on a facade ceramic tile, which is ready (L
СWITH
VI VI
0s0s
xj соxj with
ЈьЈ
в т путем совместного мокрого помола фритты, глины, каолина, песка и продукта осаждени при переработке отработанного электролита.in t by co-grinding of frit, clay, kaolin, sand and product precipitation during the processing of spent electrolyte.
Суспензию состава нанос т на керами- ческую плитку методом полива и обжигают при900...1000°С.The suspension of the composition is applied to a ceramic tile by irrigation and calcined at 900 ... 1000 ° C.
В составе используют фритты производственного состава, сырьевой состав которых приведен в табл.2.In the composition of the use of Frit production composition, the raw material composition of which is given in table 2.
Варианты состава приведены в табл.3, качество полученного покрыти - в табл.4.Variants of the composition are given in Table 3, the quality of the coating obtained is in Table 4.
Из приведенных в таблице результатов испытаний глазурованных покрытий следует , что предложенный состав эффективней известного: водопоглощение снижаетс до 4...6% против 9...12%, а цветное покрытие получают без использовани керамического красител или пигмента.From the test results for glazed coatings shown in the table, it follows that the proposed composition is more effective than the known one: water absorption decreases to 4 ... 6% against 9 ... 12%, and a color coating is obtained without using a ceramic dye or pigment.
Используемый в предложенном составе заменитель красител позвол ет получатьThe dye substitute used in the proposed composition allows to obtain
дефицитные дл промышленного производства окраски бежевых тонов.colors of beige tones, which are scarce for industrial production.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU914899533A SU1761734A1 (en) | 1991-01-03 | 1991-01-03 | Composition for application of glazed coating to ceramic tile |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU914899533A SU1761734A1 (en) | 1991-01-03 | 1991-01-03 | Composition for application of glazed coating to ceramic tile |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU1761734A1 true SU1761734A1 (en) | 1992-09-15 |
Family
ID=21553868
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU914899533A SU1761734A1 (en) | 1991-01-03 | 1991-01-03 | Composition for application of glazed coating to ceramic tile |
Country Status (1)
| Country | Link |
|---|---|
| SU (1) | SU1761734A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2475465C1 (en) * | 2011-10-07 | 2013-02-20 | федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Южно-Российский государственный технический университет (Новочеркасский политехнический институт)" | Glaze |
-
1991
- 1991-01-03 SU SU914899533A patent/SU1761734A1/en active
Non-Patent Citations (1)
| Title |
|---|
| Авторское свидетельство СССР № 1351910,кл. С 04 В 41/86,1985. Е.Л.Рохваргер и др. Справочник Строительна керамика, М., Стройиздат, 1976, с.184-187 (прототип). * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2475465C1 (en) * | 2011-10-07 | 2013-02-20 | федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Южно-Российский государственный технический университет (Новочеркасский политехнический институт)" | Glaze |
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