SU1623952A1 - Process for preparing hexanitroiridates (iii) of alkali metal or ammonium - Google Patents
Process for preparing hexanitroiridates (iii) of alkali metal or ammonium Download PDFInfo
- Publication number
- SU1623952A1 SU1623952A1 SU884377529A SU4377529A SU1623952A1 SU 1623952 A1 SU1623952 A1 SU 1623952A1 SU 884377529 A SU884377529 A SU 884377529A SU 4377529 A SU4377529 A SU 4377529A SU 1623952 A1 SU1623952 A1 SU 1623952A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- alkali metal
- yield
- product
- target product
- ammonium
- Prior art date
Links
- 229910052783 alkali metal Inorganic materials 0.000 title claims abstract 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 title claims 2
- 150000001340 alkali metals Chemical class 0.000 title claims 2
- 238000004519 manufacturing process Methods 0.000 title claims 2
- 238000000034 method Methods 0.000 claims abstract description 12
- 239000000243 solution Substances 0.000 claims abstract description 5
- -1 platinum metals Chemical class 0.000 claims abstract description 4
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 claims abstract description 3
- 239000012047 saturated solution Substances 0.000 claims abstract description 3
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 claims abstract 4
- 230000001376 precipitating effect Effects 0.000 claims abstract 2
- 235000010288 sodium nitrite Nutrition 0.000 claims abstract 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- 101100257999 Danio rerio stambpa gene Proteins 0.000 claims 1
- RBNNPWUKDNRSMD-UHFFFAOYSA-N [Cl].[Ir] Chemical compound [Cl].[Ir] RBNNPWUKDNRSMD-UHFFFAOYSA-N 0.000 claims 1
- 239000000460 chlorine Substances 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- 230000003993 interaction Effects 0.000 claims 1
- KMRZCEMYHNZGFX-UHFFFAOYSA-K sodium lead(2+) trinitrite Chemical compound [Pb+2].N(=O)[O-].[Na+].N(=O)[O-].N(=O)[O-] KMRZCEMYHNZGFX-UHFFFAOYSA-K 0.000 claims 1
- 101150076714 stambp gene Proteins 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 abstract description 2
- 229910052751 metal Inorganic materials 0.000 abstract description 2
- 239000002184 metal Substances 0.000 abstract description 2
- 229910052697 platinum Inorganic materials 0.000 abstract description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052741 iridium Inorganic materials 0.000 abstract 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 abstract 1
- 239000000047 product Substances 0.000 description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 239000003708 ampul Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 229910021591 Copper(I) chloride Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000012716 precipitator Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G55/00—Compounds of ruthenium, rhodium, palladium, osmium, iridium, or platinum
- C01G55/002—Compounds containing ruthenium, rhodium, palladium, osmium, iridium or platinum, with or without oxygen or hydrogen, and containing two or more other elements
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
Изобретение относитс к Heopiа- нической химии, а именно к способам получени комплексных соединений платиновых металлов, Целью изобретени вл етс повышение выхода целевого продукта и сокращение длительности процесса. Поставленна ПРЛЬ достигаетс путем взаимодействи хлорокоуплек- са ириди с нитритом натри и тамк- нутом объеме в присутствии 2 1 - 5-10 М раствора хлористой меди при 120-125°С и осаждени продукта насыщенным раствором соли щелочного металла. По сравнению с прототипом предлагаемый способ позвол ет в 1,5 раза повысить выход целевого продукта, более чем в 20 рач сократит длительность процесса. Кроме того, полученный этим способом продукт не загр з- нен другими комплексными формчни. 1 табл. § (ЛThe invention relates to Heopianic chemistry, in particular to methods for producing complex compounds of platinum metals. The aim of the invention is to increase the yield of the target product and reduce the duration of the process. The delivered RSPP is achieved by reacting the iridium chlorocomplex with sodium nitrite and the volume in the presence of a 2-1-5-10 M solution of copper chloride at 120-125 ° C and precipitating the product with a saturated solution of alkali metal salt. Compared to the prototype, the proposed method allows a 1.5-fold increase in the yield of the target product, will reduce the process time by more than 20 times. In addition, the product obtained in this way is not contaminated by other complex molds. 1 tab. § (L
Description
Изобретение относитс к неорганической химии, а именно к способам получени комплексных соединений платиновых металлов, и может быть использовано в процессах аффинажного производства.The invention relates to inorganic chemistry, namely to methods for producing complex compounds of platinum metals, and can be used in refining processes.
Цель изобретени - повышение выхода целевого продукта и сокращение длительности процесса.The purpose of the invention is to increase the yield of the target product and reduce the duration of the process.
Приме р. В стекл нную ампулу объемом 10 мл помещают 4 мл водного раствора, содержащего Na4IrCl$ с концентрацией М, NaN02 с концентрацией 0,5 м, CuCl с концентрацией 3-10 К. Ампулу запаивают и помещают в термостат при TeMneparypeJPrimer p. In a 10 ml glass vial, 4 ml of an aqueous solution containing Na4IrCl $ with a concentration of M, NaN02 with a concentration of 0.5 m, CuCl with a concentration of 3-10 K are placed. The ampule is sealed and placed in a thermostat at TeMneparypeJ
123°С. Через 30 мин ампулу охлаждают и вскрывают. Реакционную смесь фильтруют и добавл ют 1 мл насыщенного раствора KNOj, выпамший белый осадок отфильтровывают, сушат и взвешивают. Выход целевого продукта 99,510,5%.123 ° C. After 30 minutes, the ampoule is cooled and opened. The reaction mixture is filtered and 1 ml of a saturated solution of KNOj is added, the white precipitate is filtered out, dried and weighed. The yield of the target product 99,510,5%.
Результаты синтезов, проведенных с другими осадител ми и при других концентраци х раствора хлористой ме ди и разных температурах приведены в таблице.The results of the syntheses carried out with other precipitators and at other concentrations of the copper / copper solution and different temperatures are given in the table.
Как следует из таблицы, наибольший выход целевого продукта происходит , когда концентраци раствораAs follows from the table, the highest yield of the target product occurs when the concentration of the solution
N3N3
хлористой меди измен етс в интервале 2 «10 - 5«КГ М при температуре раствора 12(Ы25°С.copper chloride varies in the range of 2 "10 - 5" KG M at a solution temperature of 12 (25 ° C.
ii
По сравнению с прототипом предлагаемый способ позвол ет в 1,5 раза повысить выход целевого продукта, более чем в 20 раз сокращает длительность процесса. По прототипу выход целевого продукта 60-65%, длительность процесса 10-12 ч. Кроме того, полученный предлагаемым способом продукт не загр знен другими комплексными формами.Compared with the prototype, the proposed method allows a 1.5 times increase in the yield of the target product, more than 20 times shortens the process time. In the prototype, the yield of the target product is 60-65%, the duration of the process is 10-12 hours. In addition, the product obtained by the proposed method is not contaminated with other complex forms.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU884377529A SU1623952A1 (en) | 1988-02-15 | 1988-02-15 | Process for preparing hexanitroiridates (iii) of alkali metal or ammonium |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU884377529A SU1623952A1 (en) | 1988-02-15 | 1988-02-15 | Process for preparing hexanitroiridates (iii) of alkali metal or ammonium |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU1623952A1 true SU1623952A1 (en) | 1991-01-30 |
Family
ID=21355324
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU884377529A SU1623952A1 (en) | 1988-02-15 | 1988-02-15 | Process for preparing hexanitroiridates (iii) of alkali metal or ammonium |
Country Status (1)
| Country | Link |
|---|---|
| SU (1) | SU1623952A1 (en) |
-
1988
- 1988-02-15 SU SU884377529A patent/SU1623952A1/en active
Non-Patent Citations (1)
| Title |
|---|
| Синтез комплексных соединений металлов платиновой группы. М.: Наука, 1Q64. с. 209. * |
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