SU1296544A1 - Raw mixture for producing fire-proof reflecting coating - Google Patents
Raw mixture for producing fire-proof reflecting coating Download PDFInfo
- Publication number
- SU1296544A1 SU1296544A1 SU853962088A SU3962088A SU1296544A1 SU 1296544 A1 SU1296544 A1 SU 1296544A1 SU 853962088 A SU853962088 A SU 853962088A SU 3962088 A SU3962088 A SU 3962088A SU 1296544 A1 SU1296544 A1 SU 1296544A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- phosphate
- fight
- coating
- density
- aluminum
- Prior art date
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 21
- 239000011248 coating agent Substances 0.000 title claims abstract description 19
- 239000000203 mixture Substances 0.000 title claims abstract description 15
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 16
- 238000004519 manufacturing process Methods 0.000 claims abstract description 16
- 239000010452 phosphate Substances 0.000 claims abstract description 15
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 14
- 239000002699 waste material Substances 0.000 claims abstract description 11
- 239000005357 flat glass Substances 0.000 claims abstract description 9
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 8
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 8
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000002310 reflectometry Methods 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004615 ingredient Substances 0.000 claims abstract description 4
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 239000003063 flame retardant Substances 0.000 claims abstract 3
- 239000000654 additive Substances 0.000 claims description 7
- 239000002694 phosphate binding agent Substances 0.000 claims description 6
- 239000000853 adhesive Substances 0.000 claims description 4
- 230000001070 adhesive effect Effects 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims 2
- DOEVMNBDNQNWEJ-UHFFFAOYSA-K aluminum;magnesium;phosphate Chemical compound [Mg+2].[Al+3].[O-]P([O-])([O-])=O DOEVMNBDNQNWEJ-UHFFFAOYSA-K 0.000 claims 2
- 239000002775 capsule Substances 0.000 claims 1
- 230000015556 catabolic process Effects 0.000 claims 1
- 238000010304 firing Methods 0.000 claims 1
- 238000005245 sintering Methods 0.000 claims 1
- 230000009970 fire resistant effect Effects 0.000 abstract description 4
- 239000011819 refractory material Substances 0.000 abstract description 3
- 239000011230 binding agent Substances 0.000 abstract description 2
- 229910052751 metal Inorganic materials 0.000 abstract description 2
- 239000002184 metal Substances 0.000 abstract description 2
- 239000002893 slag Substances 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 235000021317 phosphate Nutrition 0.000 description 11
- 238000005516 engineering process Methods 0.000 description 3
- 239000000945 filler Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- VYDNCCLNAHRIST-UHFFFAOYSA-N 13827-38-8 Chemical compound O1P(=O)(O2)O[Si]31OP2(=O)O3 VYDNCCLNAHRIST-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 229910052878 cordierite Inorganic materials 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 239000011381 foam concrete Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- -1 polypropylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/34—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing cold phosphate binders
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/28—Fire resistance, i.e. materials resistant to accidental fires or high temperatures
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
Изобретение относитс к производству огнестойких отражающих покрытий и предназначаетс дл защиты огнеупоров от воздействи агрессивной газомазутной среды, расплавов металлов и шлаков. Целью изобретени вл етс увеличение отражательной способности, повышение адгезионной прочности и плотности покрыти . Сырьева смесь дл изготовлени огнестойкого отражающего покрыти содержит следующие ингредиенты, мас.%: магнийалюмоборфосфатное св зующее 43-51; каолин 18-22; бой листового стекла 1,5-3,0; отходы фосфатного производства 3,0-5,5; капсельный бой 8-13; вода - остальное. 1 табл. (Л ю со О) СП 4 4The invention relates to the production of fire-resistant reflective coatings and is intended to protect refractories from the effects of aggressive gas-oil environment, molten metals and slags. The aim of the invention is to increase the reflectivity, increase the adhesion strength and density of the coating. The raw material mixture for the manufacture of a fire-retardant reflective coating contains the following ingredients, wt%: magnesium-aluminum-peraphosphate binder 43-51; kaolin 18-22; fight sheet glass 1,5-3,0; phosphate production wastes 3.0-5.5; Kapsel fight 8-13; water - the rest. 1 tab. (L u so O) SP 4 4
Description
t12t12
Изобретение относитс к сырьевым смес м дл изготовлени огнестойких отражающих покрытий и предназначено дл защиты огнеупоров от воздействи агрессивной газомазутной среды, расплавов металлов и шлаков.The invention relates to raw materials for the manufacture of fire-resistant reflective coatings and is intended to protect refractories from exposure to aggressive gas-oil environment, metal melts and slags.
Цель изобретени - увеличение отражательной способности, повышение адгезионной прочности и плотности покрыти .The purpose of the invention is to increase the reflectivity, increase adhesion strength and density of the coating.
I Использование в качестве заполнител смеси каолина и капсельного бо содержащего до 30% карборунда, позвол ет создать термостойкую структуру покрыти с повышенной отражательной способностью. Тонкомолотый бой листового стекла активно взаимодействует с МАБФС и формирует низкотемпературную структуру покрыти , а при температурах эксплуатации создает основу стеклофазы покрыти , обеспечивающую повьшенную адгезионную прочность и плотность. Кроме того, соединени магни из св зки с А1,0 образуют высокотемпературоустойчивую фазу - кордиерит,I The use of a mixture of kaolin and cap bole containing up to 30% carborundum as a filler allows the creation of a heat-resistant coating structure with increased reflectivity. Fine-breaking sheet glass actively interacts with MABFS and forms the low-temperature structure of the coating, and at operating temperatures it forms the basis of the glass phase of the coating, which provides enhanced adhesive strength and density. In addition, magnesium compounds from the A1.0 bond form a high temperature resistant phase — cordierite,
Отходы фосфатного производства алюмо- и силикофосфатного состава (накапливающиес при механической обработке фосфатного чеистого бетона, чистке форм, обеспыливании фосфозита и др.) вл ютс материалом, прошедшим предварительную термообработку, и обладают стабильньгм фазовым составом (в основном, А1РО. , тридимит иThe phosphate production wastes of the aluminum and silicophosphate composition (accumulated during the machining of phosphate cellular concrete, cleaning of forms, de-dusting of phosphoxite, etc.) are pre-heat treated materials and have a stable phase composition (mainly A1PO., Tridymite
пирофосфат кремни в высокотемпературной форме) . Они выполн ют роль стабилйзирук цих добавок при формировании фазового состава фосфатных Новообразований и компенсаторов моди фикациомных переходов.silicon pyrophosphate in high temperature form). They perform the role of stabilizers of additives in the formation of the phase composition of phosphate neoplasms and modifiers of modicatory transitions.
Совокупность свойств ингредиентов в указанных пределах и .их специфическое взаимодействие с МАВФС обеспечивают повышенные отражательную способ ность, адгезионную прочность и плотность получаемого огнестойкого отражающего покрыти . IThe combination of the properties of the ingredients within the specified limits and their specific interaction with MAFFS provide enhanced reflectivity, adhesion strength and density of the resulting fire-resistant reflective coating. I
Количественные соотношени МАБФС заполнителей и добавок микропорошков бо стекла и фосфатов обоснованы как достижением полного св зывани в температуроустойчивые формы алюмо The quantitative ratios of the MABPS fillers and additives of micro-powders of glass and phosphates are substantiated as the achievement of complete binding to temperature-resistant forms of aluminum
и силикофосфатов, так и кинетикой ре-55 стве фосфатного св зующего Магнийакции твердени - скорость св зывани скоординирована с процессом структурообразовани . Утилизаци отходов фосфатного производства позвоOand silicophosphates and kinetics of the phosphate binder. Magnesium hardening reaction — the rate of binding is coordinated with the structure formation process. Utilization of phosphate production wastes
л ет создать комплексную безотходную технологию производства фосфатных огнеупорных материалов.It creates an integrated waste-free technology for the production of phosphate refractory materials.
Температура применени предлагаемого покрыти достигает .The application temperature of the proposed coating reaches.
Пример 1. В фарфоровую шаровую мельницу загружают, мас.%: МАБФС 51; каолин 18; капсельньй бой 8; бой листового стекла 1,5; отходы фосфатного производства 3; вода 18,5. Смесь мелют до полного прохождени через сито № 01 (2,5-3 ч), сливают через сетчатый фильтр и нанос т на огнеупорную кладку распылением или 5 кистью. Плотность смеси 1,751 ,80 г/см , в зкость по вискозиметру ВЗ-4 80-90 с. Нанесенное покрытие просушивают при 20-40 С в течение 24 ч, после чего :оно готово к экс-, плуатации.Example 1. In porcelain ball mill load, wt.%: MABFS 51; kaolin 18; kapselny fight 8; fight sheet glass 1.5; phosphate production waste 3; water 18.5. The mixture is ground to complete passage through a No. 01 sieve (2.5-3 hours), drained through a screen filter and applied to the refractory masonry by spraying or 5 with a brush. The density of the mixture is 1.751, 80 g / cm, the viscosity by the OT-4 viscometer is 80-90 s. The applied coating is dried at 20–40 ° C for 24 hours, after which: it is ready for ex- workstation.
П р и м е р 2. Готов т смесь следующего состава, мас.%: МАБФС 47; каолин 20; капсельный бой 11; бой листового стекла 2,5; отходы фосфатного производства 4,5; вода 15.PRI mme R 2. Prepare a mixture of the following composition, wt.%: MABFS 47; kaolin 20; caps fights 11; fight sheet glass 2.5; phosphate production waste 4,5; water 15.
Технологи приготовлени и нанесени покрыти аналогична описанной в примере 1.The technology of preparation and coating is similar to that described in example 1.
П р и м е р 3. Готов т смесь следующего состава, мас.%: МАБФС 43; каолин 22; капсельный бой 13; бой листового стекла 3; отходы фосфатного производства 5,5; вода 13,5.PRI me R 3. A mixture of the following composition is prepared, wt%: MABFS 43; kaolin 22; caps fight 13; fight sheet glass 3; phosphate production waste 5.5; water 13.5.
Технологи приготовлени и нанесе- 35 ни покрыти аналогична описанной в примере 1.The technology of preparation and coating is similar to that described in Example 1.
Основные физико-технические характеристики предлагаемого покрыти и прототипа, приведены в таблице.The main physico-technical characteristics of the proposed coating and prototype are shown in the table.
00
5five
00
Как следует из таблицы, предлагаемое покрытие по всем основным показател м превосходит прототип.As follows from the table, the proposed coverage in all major indicators exceeds the prototype.
45 Формула 45 Formula
изобретени the invention
Сырьева смесь дл изготовлени огнестойкого отражающего покрыти , включающа фосфатное св зующее, каолин , добавки и воду, отличающа с тем, что, с целью увеличени отражательной способности, повышени адгезионной прочности и плот- .кости покрыти , она содержит в качеалюмоборфосфатное св зующее, а в качестве добавок бой листового стекла и отходы фосфатного производства и дополнительно капсельный бой при еледующем соотношении ингредиентов, мас.%:The raw material mixture for the manufacture of a fire-resistant reflective coating, including phosphate binder, kaolin, additives and water, is characterized in that, in order to increase the reflectivity, increase adhesion strength and density of the coating, it contains as a polypropylene binder and as additives, bout of sheet glass and phosphate production wastes and additionally blasted battles with the following ratio of ingredients, wt%:
Термостойкость, количествоHeat resistance, quantity
воздушных теплосмен приair heat changes at
8004 338004 33
Огнеупорность,°СFire resistance, ° С
Бой листового стекла 1,5-3,0 Отходы фосфатногоFight of sheet glass 1,5-3,0 Phosphate waste
30 26 Более 150030 26 Over 1500
2222
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU853962088A SU1296544A1 (en) | 1985-10-04 | 1985-10-04 | Raw mixture for producing fire-proof reflecting coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU853962088A SU1296544A1 (en) | 1985-10-04 | 1985-10-04 | Raw mixture for producing fire-proof reflecting coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU1296544A1 true SU1296544A1 (en) | 1987-03-15 |
Family
ID=21200296
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU853962088A SU1296544A1 (en) | 1985-10-04 | 1985-10-04 | Raw mixture for producing fire-proof reflecting coating |
Country Status (1)
| Country | Link |
|---|---|
| SU (1) | SU1296544A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0911304A1 (en) * | 1997-10-27 | 1999-04-28 | Screg | Reflecting surfaces associated with road traffic or related elements and corresponding composition |
| EP2345042A4 (en) * | 2008-10-06 | 2012-06-27 | Grancrete Inc | Radiation shielding structure composition |
-
1985
- 1985-10-04 SU SU853962088A patent/SU1296544A1/en active
Non-Patent Citations (1)
| Title |
|---|
| Авторское свидетельство СССР № 608784, кл. С 04 В 29/02, 1976. Авторское свидетельство СССР № 1079634, кл. С 04 В 29/02, 1983. * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0911304A1 (en) * | 1997-10-27 | 1999-04-28 | Screg | Reflecting surfaces associated with road traffic or related elements and corresponding composition |
| FR2770213A1 (en) * | 1997-10-27 | 1999-04-30 | Screg | TRAFFIC COVERINGS OR RELATED REFLECTIVE ELEMENTS, AND COMPOSITION THEREOF |
| EP2345042A4 (en) * | 2008-10-06 | 2012-06-27 | Grancrete Inc | Radiation shielding structure composition |
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