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SG11201811669UA - Noble metal hydrogenation catalysts and aromatic saturation methods - Google Patents

Noble metal hydrogenation catalysts and aromatic saturation methods

Info

Publication number
SG11201811669UA
SG11201811669UA SG11201811669UA SG11201811669UA SG11201811669UA SG 11201811669U A SG11201811669U A SG 11201811669UA SG 11201811669U A SG11201811669U A SG 11201811669UA SG 11201811669U A SG11201811669U A SG 11201811669UA SG 11201811669U A SG11201811669U A SG 11201811669UA
Authority
SG
Singapore
Prior art keywords
international
hydrogenation
road
catalysts
pct
Prior art date
Application number
SG11201811669UA
Inventor
Michael Lanci
Stuart Soled
Javier Guzman
Sabato Miseo
Thomas Green
Joseph Baumgartner
Lei Zhang
Christine Kliewer
Lukasz Koziol
Kanmi Mao
Tracie Owens
Gary Schleicher
Original Assignee
Exxonmobil Res & Eng Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US15/198,346 external-priority patent/US10227539B2/en
Application filed by Exxonmobil Res & Eng Co filed Critical Exxonmobil Res & Eng Co
Publication of SG11201811669UA publication Critical patent/SG11201811669UA/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
    • C10G65/043—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps at least one step being a change in the structural skeleton
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/638—Pore volume more than 1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/44—Hydrogenation of the aromatic hydrocarbons
    • C10G45/46—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used
    • C10G45/52—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used containing platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/12—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including cracking steps and other hydrotreatment steps
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/10—Lubricating oil

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property 1111111011110111010101111101 1101001111011111100110111101M10 ill OEN Organization International Bureau (10) International Publication Number (43) International Publication Date .....0\"\"1 WO 2018/005094 Al 04 January 2018 (04.01.2018) W I PO I PCT (51) International Patent Classification: 08867 (US). GREEN, Thomas, E.; 708 Nottinghill Lane, ClOG 65/04 (2006.01) ClOG 65/12 (2006.01) Hamilton, NJ 08619 (US). BAUMGARTNER, Joseph, B01J 23/40 (2006.01) E.; 179 Raritan River Road, Califon, NJ 07830 (US). (21) International Application Number: ZHANG, Lei; 9 Tartan Drive, Basking Ridge, NJ 07920 (US). KLIEWER, Christine, E.; 5 Austin Hill Road, Clin- PCT/US2017/037416 ton, NJ 08809 (US). KOZIOL, Lukasz; 13 Franklin Place, (22) International Filing Date: #7E, Morristown, NJ 07960 (US). MAO, Kanmi; 5 Arbor 14 June 2017 (14.06.2017) Court, Clinton, NJ 08809 (US). OWENS, Tracie, L.; 1121 Nadine Street, Houston, TX 77009 (US). SCHLEICHER, (25) Filing Language: English Gary, P.; 7 Meadow Run Road, Milford, NJ 08848 (US). (26) Publication Language: English (74) Agent: YARNELL, Scott, F. et al.; Exxonmobil Research (30) Priority Data: and Engineering Company, 1545 Route 22 East, P. 0. Box 15/198,346 30 June 2016 (30.06.2016) US 900, Annandale, NJ 08801-0900 (US). (71) Applicant: EXXONMOBIL RESEARCH AND EN- (81) Designated States (unless otherwise indicated, for every GINEERING COMPANY [US/US]; 1545 Route 22 East, kind of national protection available): AE, AG, AL, AM, P.O. Box 900, Annandale, NJ 08801-0900 (US). AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, (72) Inventors: LANCI, Michael, P.; 18 Hickory Trail, Flem-DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, ington, NJ 08822 (US). SOLED, Stuart, L.; 21 Cooks HR, HU, ID, IL, IN, IR, IS, JO, JP, KE, KG, KH, KN, KP, — Cross Road, Pittstown, NJ 08867 (US). GUZMAN, Javier; KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, 25202 Hobsons Corner Drive, Kingwood, TX 77365 (US). MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, MISEO, Sabato; 770 Country Road 579, Pittstown, NJ OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, = = (54) Title: NOBLE METAL HYDROGENATION CATALYSTS AND AROMATIC SATURATION METHODS Activity per Pt site for Toluene Hydrogenation with a Sulfur-containing feed = = = 18000 . 1 .0, 16984 = 16000 cl 14000 co i I 1 p ii = _ = 0 u_ 12000 i--- i 0.5, 9409 _ _ ' 5- 10000 - ,.... en n 8000 2.1, 5609 .5, 9110 = — — = = E 1 a 6000 -1 3.0, 6007 16.8, 971 = _ a i • = N 4000 - • • 8.8, 2809 = i — 2000 -1 0, 275 _ 0 1 1-1 0 5 10 15 20 % A1 2 0 3 Added by I.W. ii. cr, © FIG. 8 kr) 0 0 ---- (57) : Methods are provided for modifying hydrogenation catalysts having silica supports (or other non-alumina supports) with GC additional alumina, and using such catalysts to achieve unexpectedly superior hydrogenation of feedstocks. The modified hydrogenation 1-1 © catalysts can have a relatively low cracking activity while providing an increased activity for hydrogenation. ei O [Continued on next page] WO 2018/005094 Al MIDEDIMOMMIDIREEMOMIIMINIMMOHMEHOIS SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (84) Designated States (unless otherwise indicated, for every kind of regional protection available): ARIPO (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG). Declarations under Rule 4.17: — as to applicant's entitlement to apply for and be granted a patent (Rule 4.17(11)) — as to the applicant's entitlement to claim the priority of the earlier application (Rule 4.17(iii)) Published: — with international search report (Art. 21(3))
SG11201811669UA 2016-06-30 2017-06-14 Noble metal hydrogenation catalysts and aromatic saturation methods SG11201811669UA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US15/198,346 US10227539B2 (en) 2014-06-09 2016-06-30 Noble metal hydrogenation catalysts and aromatic saturation methods
PCT/US2017/037416 WO2018005094A1 (en) 2016-06-30 2017-06-14 Noble metal hydrogenation catalysts and aromatic saturation methods

Publications (1)

Publication Number Publication Date
SG11201811669UA true SG11201811669UA (en) 2019-01-30

Family

ID=59315698

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11201811669UA SG11201811669UA (en) 2016-06-30 2017-06-14 Noble metal hydrogenation catalysts and aromatic saturation methods

Country Status (4)

Country Link
EP (1) EP3478799B1 (en)
CA (1) CA3029555C (en)
SG (1) SG11201811669UA (en)
WO (1) WO2018005094A1 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110237867A (en) * 2019-05-28 2019-09-17 天津大学 A kind of platinum nanoparticle liquid with oxidase activity and preparation method thereof

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5198203A (en) 1990-01-25 1993-03-30 Mobil Oil Corp. Synthetic mesoporous crystalline material
US5102643A (en) 1990-01-25 1992-04-07 Mobil Oil Corp. Composition of synthetic porous crystalline material, its synthesis
US6106802A (en) * 1997-01-31 2000-08-22 Intevep, S.A. Stable synthetic material and method for preparing same
FI102730B (en) 1997-06-16 1999-02-15 Neste Oy Hydration catalyst with good sulfur resistance
US6569312B1 (en) 1998-09-29 2003-05-27 Exxonmobil Research And Engineering Company Integrated lubricant upgrading process
FR2874837B1 (en) * 2004-09-08 2007-02-23 Inst Francais Du Petrole DOPE CATALYST AND IMPROVED PROCESS FOR TREATING HYDROCARBON LOADS
JP6095234B2 (en) * 2011-03-31 2017-03-15 シェブロン ユー．エス．エー． インコーポレイテッド Novel process and catalyst system for improving dewaxing catalyst stability and lubricant yield
CA2848343A1 (en) * 2011-10-24 2013-05-02 Total Raffinage France Process for preparing a mesoporized catalyst, catalyst thus obtained and use thereof in a catalytic process

Also Published As

Publication number Publication date
CA3029555A1 (en) 2018-01-04
EP3478799B1 (en) 2021-04-28
WO2018005094A1 (en) 2018-01-04
CA3029555C (en) 2023-12-12
EP3478799A1 (en) 2019-05-08

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