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SG10202101020PA - Silyl-bridged bis-biphenyl-phenoxy catalysts for olefin polymerization - Google Patents

Silyl-bridged bis-biphenyl-phenoxy catalysts for olefin polymerization

Info

Publication number
SG10202101020PA
SG10202101020PA SG10202101020PA SG10202101020PA SG10202101020PA SG 10202101020P A SG10202101020P A SG 10202101020PA SG 10202101020P A SG10202101020P A SG 10202101020PA SG 10202101020P A SG10202101020P A SG 10202101020PA SG 10202101020P A SG10202101020P A SG 10202101020PA
Authority
SG
Singapore
Prior art keywords
silyl
biphenyl
olefin polymerization
bridged bis
phenoxy
Prior art date
Application number
SG10202101020PA
Inventor
Hien Q Do
Philip P Fontaine
Andrew J Young
Susan G Brown
Johnathan E Delorbe
Tulaza Vaidya
Zach T Rickaway
Amy E Floeck
Chunming Zhang
Ruth Figueroa
Jerzy Klosin
Original Assignee
Dow Global Technologies Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Llc filed Critical Dow Global Technologies Llc
Publication of SG10202101020PA publication Critical patent/SG10202101020PA/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/64003Titanium, zirconium, hafnium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/64168Tetra- or multi-dentate ligand
    • C08F4/64186Dianionic ligand
    • C08F4/64193OOOO
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/01High molecular weight, e.g. >800,000 Da.
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/03Narrow molecular weight distribution, i.e. Mw/Mn < 3
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/08Low density, i.e. < 0.91 g/cm3
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12Melt flow index or melt flow ratio
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/582Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
SG10202101020PA 2016-07-29 2017-07-28 Silyl-bridged bis-biphenyl-phenoxy catalysts for olefin polymerization SG10202101020PA (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US201662368706P 2016-07-29 2016-07-29

Publications (1)

Publication Number Publication Date
SG10202101020PA true SG10202101020PA (en) 2021-03-30

Family

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Family Applications (2)

Application Number Title Priority Date Filing Date
SG11201900653RA SG11201900653RA (en) 2016-07-29 2017-07-28 Silyl-bridged bis-biphenyl-phenoxy catalysts for olefin polymerization
SG10202101020PA SG10202101020PA (en) 2016-07-29 2017-07-28 Silyl-bridged bis-biphenyl-phenoxy catalysts for olefin polymerization

Family Applications Before (1)

Application Number Title Priority Date Filing Date
SG11201900653RA SG11201900653RA (en) 2016-07-29 2017-07-28 Silyl-bridged bis-biphenyl-phenoxy catalysts for olefin polymerization

Country Status (7)

Country Link
US (1) US11111318B2 (en)
EP (1) EP3491034A1 (en)
KR (1) KR102423018B1 (en)
CN (1) CN109476783B (en)
BR (1) BR112019001111B1 (en)
SG (2) SG11201900653RA (en)
WO (1) WO2018022975A1 (en)

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EP3491034A1 (en) 2016-07-29 2019-06-05 Dow Global Technologies, LLC Silyl-bridged bis-biphenyl-phenoxy catalysts for olefin polymerization
JP7460602B2 (en) * 2018-08-30 2024-04-02 ダウ グローバル テクノロジーズ エルエルシー Bis-phenyl-phenoxy polyolefin procatalysts having two anthracenyl ligands
SG11202110593WA (en) * 2019-03-31 2021-10-28 Dow Global Technologies Llc Methods for preparing catalyst precursor materials
WO2021128128A1 (en) 2019-12-26 2021-07-01 Dow Global Technologies Llc Ethylene/alpha-olefin interpolymer based compositions with improved balance of cure and processability
WO2021128126A1 (en) * 2019-12-26 2021-07-01 Dow Global Technologies Llc Alpha-olefin interpolymers with improved molecular design for photovoltaic encapsulants
WO2021155168A1 (en) * 2020-01-31 2021-08-05 Dow Global Technologies Llc Polymerization processes that include group iii and lanthanide bis-phenyl-phenoxy metal-ligand complexes and chain transfer agents
EP4097151A1 (en) * 2020-01-31 2022-12-07 Dow Global Technologies LLC Group iii and lanthanide bis-phenyl-phenoxy metal-ligand complexes
US20230146294A1 (en) * 2020-02-24 2023-05-11 Dow Global Technologies Llc Non-cryogenic synthesis of heteroatom-bridge precursors of metal-ligand complex catalysts
CN115461351A (en) * 2020-04-23 2022-12-09 埃克森美孚技术与工程公司 High-yield synthesis of metal-organic frameworks
BR112022023905A2 (en) * 2020-05-29 2022-12-27 Dow Global Technologies Llc PROCESS FOR PRODUCING AN ETHYLENE-BASED COPOLYMER
KR20230017245A (en) 2020-05-29 2023-02-03 다우 글로벌 테크놀로지스 엘엘씨 Attenuated post-metallocene catalyst
CA3172236A1 (en) 2020-05-29 2021-12-02 Rhett A. BAILLIE Attenuated post-metallocene catalysts
JP2023527125A (en) 2020-05-29 2023-06-27 ダウ グローバル テクノロジーズ エルエルシー damped hybrid catalyst
US20230203216A1 (en) * 2020-05-29 2023-06-29 Dow Global Technologies Llc Catalyst systems and processes for producing polyethylene using the same
US20230242695A1 (en) 2020-05-29 2023-08-03 Dow Global Technologies Llc Chemically converted catalysts
WO2022015369A1 (en) 2020-07-17 2022-01-20 Dow Global Technologies Llc Hydrocarbyl-modified methylaluminoxane cocatalysts for bis-phenylphenoxy metal-ligand complexes
US20240010770A1 (en) 2020-07-17 2024-01-11 Dow Global Technologies Llc Hydrocarbyl-modified methylaluminoxane cocatalysts for bis-phenylphenoxy metal-ligand complexes
KR20230039687A (en) 2020-07-17 2023-03-21 다우 글로벌 테크놀로지스 엘엘씨 Hydrocarbyl-modified methylaluminoxane cocatalyst for bis-phenylphenoxy metal-ligand complexes
WO2022173915A1 (en) 2021-02-15 2022-08-18 Dow Global Technologies Llc Method for making a poly(ethylene-co-1-alkene) copolymer with reverse comonomer distribution
KR20230163474A (en) 2021-03-31 2023-11-30 다우 글로벌 테크놀로지스 엘엘씨 Method and catalyst system for the production of isotactic polypropylene
CN115433221A (en) * 2021-06-03 2022-12-06 中国科学院化学研究所 Bis (alkoxyalkyl) silane external electron donor, preparation method thereof and application thereof in olefin polymerization
CN115433296B (en) * 2021-06-03 2024-04-05 中国科学院化学研究所 A catalyst composition and its application in olefin polymerization
CN117916307A (en) 2021-09-27 2024-04-19 陶氏环球技术有限责任公司 Thermoplastic polyolefin compositions with reactive compatibilization
CN114133409B (en) * 2021-11-17 2023-09-19 万华化学集团股份有限公司 Triazine structure-containing IVB metal ligand, catalyst system thereof and production method of polyolefin elastomer
US20250051495A1 (en) * 2021-11-23 2025-02-13 Dow Global Technologies Llc Supported catalyst systems containing a silocon bridged, anthracenyl substituted bis-biphenyl-phenoxy organometallic compound for making polyethylene and polyethylene copolymer resins in a gas phase polymerization reactor
KR20240128314A (en) * 2023-02-17 2024-08-26 주식회사 엘지화학 Transition metal compound, and catalystic composition comprising the same

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CA2652551A1 (en) 2006-05-17 2007-11-29 Dow Global Technologies Inc. Polyolefin solution polymerization process and polymer
US7528203B2 (en) * 2006-09-14 2009-05-05 Exxonmobil Chemical Patents Inc. Cyclic olefin copolymers, and methods of making the same
JP5767318B2 (en) 2010-05-17 2015-08-19 ダウ グローバル テクノロジーズ エルエルシー Method for selectively polymerizing ethylene and catalyst therefor
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WO2014105412A1 (en) * 2012-12-27 2014-07-03 Dow Global Technologies Llc An ethylene based polymer
BR112015015550B1 (en) 2012-12-27 2021-05-11 Dow Global Technologies Llc polymerization process for the production of ethylene-based polymers
CN104870489B (en) 2012-12-27 2018-03-09 陶氏环球技术有限责任公司 Antigravity system for olefinic polymerization
ES2750524T3 (en) * 2012-12-27 2020-03-26 Dow Global Technologies Llc Procedure for the polymerization of ethylene and octene
CN105283474A (en) 2013-06-28 2016-01-27 陶氏环球技术有限责任公司 Molecular weight control of polyolefins using halogenated bis-phenylphenoxy catalysts
CN111620976B (en) 2014-06-30 2023-11-17 陶氏环球技术有限责任公司 Process for the polymerization of olefins
ES2796870T3 (en) * 2014-06-30 2020-11-30 Dow Global Technologies Llc Catalytic systems for olefin polymerization
US10870713B2 (en) * 2015-09-30 2020-12-22 Dow Global Technologies Llc Procatalyst and polymerization process using the same
EP3491034A1 (en) 2016-07-29 2019-06-05 Dow Global Technologies, LLC Silyl-bridged bis-biphenyl-phenoxy catalysts for olefin polymerization

Also Published As

Publication number Publication date
US11111318B2 (en) 2021-09-07
SG11201900653RA (en) 2019-02-27
US20200247917A1 (en) 2020-08-06
CN109476783B (en) 2022-11-01
WO2018022975A1 (en) 2018-02-01
EP3491034A1 (en) 2019-06-05
KR20190036535A (en) 2019-04-04
BR112019001111B1 (en) 2022-08-23
CN109476783A (en) 2019-03-15
KR102423018B1 (en) 2022-07-21
BR112019001111A2 (en) 2019-04-30

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