SE7502921L - KIT FOR CATALYTIC HYDRODE SULFURATION OF VANADIN AND NICKEL CONTAINING RESIDUAL PISTON OILS. - Google Patents
KIT FOR CATALYTIC HYDRODE SULFURATION OF VANADIN AND NICKEL CONTAINING RESIDUAL PISTON OILS.Info
- Publication number
- SE7502921L SE7502921L SE7502921A SE7502921A SE7502921L SE 7502921 L SE7502921 L SE 7502921L SE 7502921 A SE7502921 A SE 7502921A SE 7502921 A SE7502921 A SE 7502921A SE 7502921 L SE7502921 L SE 7502921L
- Authority
- SE
- Sweden
- Prior art keywords
- catalyst
- catalysts
- combination
- weight
- requirement
- Prior art date
Links
- 239000003921 oil Substances 0.000 title abstract 3
- 230000003197 catalytic effect Effects 0.000 title abstract 2
- 238000005987 sulfurization reaction Methods 0.000 title 1
- 239000003054 catalyst Substances 0.000 abstract 37
- 239000011148 porous material Substances 0.000 abstract 3
- 239000004215 Carbon black (E152) Substances 0.000 abstract 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 2
- 239000005864 Sulphur Substances 0.000 abstract 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 abstract 2
- 229930195733 hydrocarbon Natural products 0.000 abstract 2
- 150000002430 hydrocarbons Chemical class 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 239000000969 carrier Substances 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 239000000295 fuel oil Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 239000000395 magnesium oxide Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229910052750 molybdenum Inorganic materials 0.000 abstract 1
- 239000011733 molybdenum Substances 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- HBVFXTAPOLSOPB-UHFFFAOYSA-N nickel vanadium Chemical compound [V].[Ni] HBVFXTAPOLSOPB-UHFFFAOYSA-N 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 150000003568 thioethers Chemical class 0.000 abstract 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 abstract 1
- 229910052721 tungsten Inorganic materials 0.000 abstract 1
- 239000010937 tungsten Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Abstract
1504586 Hydrodesulphurization of heavy oils SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ BV 13 March 1975 [11 April 1974] 10508/75 Heading C5E In a process for the catalytic hydrodesulphurization of vanadium- and nickel-containing residual hydrocarbon oils without catalyst replenishment, the hydrocarbon oil is consecutively contacted with a catalyst I and a catalyst II which satisfy the requirements: (a) each of the individual catalysts of which the combination of catalyst I and catalyst II is composed has a total pore volume in excess of 0À30 ml./g. of which less than 10% is present as pores having a diameter in excess of 100 nm., (b) catalyst II has a specific average pore diameter (p) and a specific average particle diameter (d) such that the quotient p/(d)<SP>0À9</SP> of catalyst II satisfies the requirement where P H2 is the hydrogen partial pressure applied, (c) when the combination of catalyst I and catalyst II is composed of two catalysts, catalyst I has a p and d such that the quotient p/(d)<SP>0.9</SP> of catalyst I satisfies the requirement while when the combination of catalyst I and catalyst II is composed of more than two catalysts, the above requirement in respect of [p/(d)<SP>0À9</SP>]cat.I applies to the average p/(d)<SP>0À9</SP> of catalyst I determined as the weight average of the values of p/(d)<SP>0À9</SP> of each of the individual catalysts of which catalyst I is composed, (d) the percentage of the total catalyst volume which is taken up by catalyst II is between 10 and 90% and satisfies the requirement: Sf representing the sulphur content of the feed and Sp the sulphur content of the desulphurized product, and (e) when the combination of catalyst I and catalyst II is composed of more than two catalysts, each of the individual catalysts of which catalyst I is composed has a p and d such that the quotient p/(d)<SP>0À9</SP> of each of these catalysts is greater than [p/(d)<SP>0À9</SP>]cat.II, p being in nm., d in mm., P H2 in bar and Sp and Sf in weight per cent. The designation catalyst II is defined as being the second catalyst when a combination of two catalysts is used and as being the final catalyst when using a combination of more than two catalysts, the designation catalyst I being defined as being the first catalyst when two catalysts are used and all but the last catalyst when more than two are used. The catalysts used preferably contain 0À5 to 20 parts by weight of nickel and/or cobalt and 2À5 to 60 parts by weight of molybdenum and/or tungsten per 100 parts by weight of carrier, the metals being present on the carrier in metallic form or in the form of their oxides or sulphides, suitable carriers being the oxides of elements of Groups II, III and IV of the periodic system, e.g. silica, alumina, magnesia, zirconia and mixtures thereof.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NLAANVRAGE7404948,A NL187641C (en) | 1974-04-11 | 1974-04-11 | PROCESS FOR CATALYTIC HYDROGENIZING DESULFULIFYING WITHOUT CATALYST REPLACEMENT OF RESIDUAL HYDROCARBON OILS. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| SE7502921L true SE7502921L (en) | 1975-10-13 |
| SE408431B SE408431B (en) | 1979-06-11 |
Family
ID=19821155
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SE7502921A SE408431B (en) | 1974-04-11 | 1975-03-14 | SET OF CATALYTIC HYDRODE SULFURATION OF VANADIN AND NICKEL CONTAINING RESIDUAL CARBON OILS, WHERE THE CARBON OIL AFTER EVERY NIGHT IS CARRIED OUT WITH TWO DIFFERENT CATALYSTS, WHERE TO PECVEL SPEC |
Country Status (13)
| Country | Link |
|---|---|
| JP (1) | JPS6027714B2 (en) |
| BE (1) | BE827492A (en) |
| CA (1) | CA1060370A (en) |
| DE (1) | DE2512294A1 (en) |
| DK (1) | DK129375A (en) |
| ES (1) | ES435948A1 (en) |
| FR (1) | FR2267359B1 (en) |
| GB (1) | GB1504586A (en) |
| IT (1) | IT1034407B (en) |
| NL (1) | NL187641C (en) |
| NO (1) | NO144424C (en) |
| SE (1) | SE408431B (en) |
| ZA (1) | ZA751655B (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6215231U (en) * | 1985-07-11 | 1987-01-29 | ||
| JPH0311812U (en) * | 1989-06-21 | 1991-02-06 | ||
| US5492684A (en) * | 1993-07-06 | 1996-02-20 | Mobil Oil Corporation | Graded-bed system for improved separations |
| JP3802106B2 (en) | 1995-06-08 | 2006-07-26 | 日本ケッチェン株式会社 | Hydrocarbon oil hydrotreating catalyst, production method thereof and activation method thereof |
| US12025435B2 (en) | 2017-02-12 | 2024-07-02 | Magēmã Technology LLC | Multi-stage device and process for production of a low sulfur heavy marine fuel oil |
| US20190233741A1 (en) | 2017-02-12 | 2019-08-01 | Magēmā Technology, LLC | Multi-Stage Process and Device for Reducing Environmental Contaminates in Heavy Marine Fuel Oil |
| US11788017B2 (en) | 2017-02-12 | 2023-10-17 | Magëmã Technology LLC | Multi-stage process and device for reducing environmental contaminants in heavy marine fuel oil |
| US10604709B2 (en) | 2017-02-12 | 2020-03-31 | Magēmā Technology LLC | Multi-stage device and process for production of a low sulfur heavy marine fuel oil from distressed heavy fuel oil materials |
| US12071592B2 (en) | 2017-02-12 | 2024-08-27 | Magēmā Technology LLC | Multi-stage process and device utilizing structured catalyst beds and reactive distillation for the production of a low sulfur heavy marine fuel oil |
-
1974
- 1974-04-11 NL NLAANVRAGE7404948,A patent/NL187641C/en not_active IP Right Cessation
-
1975
- 1975-02-24 CA CA220,643A patent/CA1060370A/en not_active Expired
- 1975-03-13 GB GB10508/75A patent/GB1504586A/en not_active Expired
- 1975-03-13 NO NO750853A patent/NO144424C/en unknown
- 1975-03-14 SE SE7502921A patent/SE408431B/en not_active IP Right Cessation
- 1975-03-18 IT IT21422/75A patent/IT1034407B/en active
- 1975-03-18 ZA ZA00751655A patent/ZA751655B/en unknown
- 1975-03-20 DE DE19752512294 patent/DE2512294A1/en active Granted
- 1975-03-24 ES ES435948A patent/ES435948A1/en not_active Expired
- 1975-03-26 FR FR7509481A patent/FR2267359B1/fr not_active Expired
- 1975-03-26 DK DK129375A patent/DK129375A/da not_active IP Right Cessation
- 1975-04-02 JP JP50039308A patent/JPS6027714B2/en not_active Expired
- 1975-04-03 BE BE1006570A patent/BE827492A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE2512294C2 (en) | 1987-08-27 |
| SE408431B (en) | 1979-06-11 |
| NO144424B (en) | 1981-05-18 |
| NO750853L (en) | 1975-10-14 |
| NL7404948A (en) | 1975-10-14 |
| DK129375A (en) | 1975-10-12 |
| NO144424C (en) | 1981-08-26 |
| CA1060370A (en) | 1979-08-14 |
| AU7921175A (en) | 1976-09-23 |
| ZA751655B (en) | 1976-02-25 |
| ES435948A1 (en) | 1976-12-16 |
| FR2267359A1 (en) | 1975-11-07 |
| JPS50136302A (en) | 1975-10-29 |
| BE827492A (en) | 1975-10-03 |
| FR2267359B1 (en) | 1982-03-19 |
| JPS6027714B2 (en) | 1985-07-01 |
| IT1034407B (en) | 1979-09-10 |
| DE2512294A1 (en) | 1975-10-23 |
| NL187641C (en) | 1991-12-02 |
| GB1504586A (en) | 1978-03-22 |
| NL187641B (en) | 1991-07-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| NUG | Patent has lapsed |
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