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SE537606C2 - Method and apparatus for producing sugar, protein and ethanol from ensiled legumes - Google Patents

Method and apparatus for producing sugar, protein and ethanol from ensiled legumes Download PDF

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SE537606C2
SE537606C2 SE1100706A SE1100706A SE537606C2 SE 537606 C2 SE537606 C2 SE 537606C2 SE 1100706 A SE1100706 A SE 1100706A SE 1100706 A SE1100706 A SE 1100706A SE 537606 C2 SE537606 C2 SE 537606C2
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protein
fibers
sugar
separated
liquid
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SE1100706A
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SE1100706A1 (en
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Jan Lundh
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Jan Lundh
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Priority to SE1100706A priority Critical patent/SE537606C2/en
Priority to PCT/SE2012/000148 priority patent/WO2013048299A1/en
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Publication of SE537606C2 publication Critical patent/SE537606C2/en

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    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12PFERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00Preparation of oxygen-containing organic compounds
    • C12P7/02Preparation of oxygen-containing organic compounds containing a hydroxy group
    • C12P7/04Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
    • C12P7/06Ethanol, i.e. non-beverage
    • C12P7/08Ethanol, i.e. non-beverage produced as by-product or from waste or cellulosic material substrate
    • C12P7/10Ethanol, i.e. non-beverage produced as by-product or from waste or cellulosic material substrate substrate containing cellulosic material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L5/00Solid fuels
    • C10L5/40Solid fuels essentially based on materials of non-mineral origin
    • C10L5/44Solid fuels essentially based on materials of non-mineral origin on vegetable substances
    • C10L5/445Agricultural waste, e.g. corn crops, grass clippings, nut shells or oil pressing residues
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01FPROCESSING OF HARVESTED PRODUCE; HAY OR STRAW PRESSES; DEVICES FOR STORING AGRICULTURAL OR HORTICULTURAL PRODUCE
    • A01F29/00Cutting apparatus specially adapted for cutting hay, straw or the like
    • A01F29/005Cutting apparatus specially adapted for cutting hay, straw or the like for disintegrating and cutting up bales of hay, straw or fodder
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65BMACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
    • B65B69/00Unpacking of articles or materials, not otherwise provided for
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    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12PFERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P21/00Preparation of peptides or proteins
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01BSOIL WORKING IN AGRICULTURE OR FORESTRY; PARTS, DETAILS, OR ACCESSORIES OF AGRICULTURAL MACHINES OR IMPLEMENTS, IN GENERAL
    • A01B79/00Methods for working soil
    • A01B79/02Methods for working soil combined with other agricultural processing, e.g. fertilising, planting
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01DHARVESTING; MOWING
    • A01D87/00Loaders for hay or like field crops
    • A01D87/12Loaders for sheaves, stacks or bales
    • A01D87/127Apparatus for handling, loading or unrolling round bales
    • A01D2087/128Devices for unrolling or breaking round bales
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/02Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/02Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by distillation
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L2290/00Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/02Combustion or pyrolysis
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10L2290/00Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/06Heat exchange, direct or indirect
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10L2290/00Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/08Drying or removing water
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    • C10L2290/00Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/24Mixing, stirring of fuel components
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10L2290/00Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
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    • C10L2290/46Compressors or pumps
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel

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  • Molecular Biology (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Distillation Of Fermentation Liquor, Processing Of Alcohols, Vinegar And Beer (AREA)

Abstract

Sammandrag: En metod aft utvinna protein och etanol fran ensilerade baljvaxter kraver en ekoreaktor som separerar en grOda fbretradesvis en baljvdxt i starkelse och socker, lignin och eellulosa samt protein. Processen inleds med aft langa fibrer separeras mekaniskt fran proteiner och efter rening och mekanisk torkning fors ur processen. Efter detta separeras resterande material tillsammans med det utvunna proteinet av en transfervatska som bildas i processen. Det separerade materiaiet bestar ena sidan av starkelse som skall hydrolyseras till socker och protein som skall avforas fran processen for kommersialisering. Den hydrolyserade fraktionen jases under rorelse i ett jastorn dar den fermenterande vatskan matas in underifran av en pump och sugs upp av undertrycket i den nastkommande destillatorn. Destillatom fungerar med hjalp av vdrme och undertryck som far den jasta vatskan aft avge sin alkohol i gasform, med hjalp av ovan tva faktorer kan destillationen goras mycket exakt. Efter fcirgasningen sammanpressas sedan gasen sa aft varmen stiger i gasen av komprimeringen, bortfors och anvands pa andra stallen i ekoreaktorn. Efter komprimering mot ett munstycke har gasen kallnat och kondenserats. Vatskan bestaende av ren alkohol samlas in i en tank av lamplig storlek och material. Ecoreaktorn dr till stora delar fciretradesvis tillverkad i plast. Summary: A method of extracting protein and ethanol from ensiled legumes requires an ecoreactor that separates a crop, preferably a legume in starch and sugar, lignin and cellulose, and protein. The process begins with long fibers separated mechanically from proteins and after purification and mechanical drying removed from the process. After this, the remaining material is separated together with the recovered protein by a transfer liquid formed in the process. The separated matter consists on one side of starch to be hydrolyzed to sugar and protein to be removed from the process of commercialization. The hydrolyzed fraction is stirred under agitation in a fermentation tower where the fermenting broth is fed from below by a pump and sucked up by the negative pressure in the next distiller. The distiller works with the help of heat and negative pressure which causes the fermenting liquid to give off its alcohol in gaseous form, with the help of the above two factors the distillation can be done very precisely. After the pre-gasification, the gas is then compressed so that the heat rises in the gas from the compaction, is removed and used in other places in the eco-reactor. After compression against a nozzle, the gas has cooled and condensed. The liquid consisting of pure alcohol is collected in a tank of suitable size and material. The Ecoreactor dr is largely made of plastic.

Description

537 606 Metod och anordning for att framstalla socker, protein och etanol Iran ensilerade baljvaxter. 537 606 Method and apparatus for producing sugar, protein and ethanol Iran ensiled legumes.

Bakgrund: Behovet av fornyelsebar och koldioxidnegativ energi ar stort och vi behover aterga till vara 'guar och finna ett satt alt utvinna energi bade fir vara kroppar, vara fordon och varma vara hus. Vi behover aven kunna producera elstrom tillsammans med detta. For alt minska energiatgangen till transporter Ors denna anlaggning i ett format som lampar sig fdr storre gardsniva eller kooperativ. Background: The need for renewable and carbon dioxide-negative energy is great and we need to return to being 'guar' and find a way to extract energy both for our bodies, our vehicles and our warm homes. We also need to be able to produce electricity together with this. In order to reduce energy access to transport Ors this facility in a format that is suitable for larger farm levels or cooperatives.

Importen av proteiner är mycket stor och kommer i form av sojamjol framst fran Brasilien dar den är ett stort miljo och klimatproblem dá den tar regnskogsmark i ansprak. Odling av sojabonor i Brasilien är den enskilt storsta anledningen till avskogningen i varlden och sker med hjalp av svedjebruk. Delta är ocksa ett stort socialt problem da sma jordbrukare forlorar sin mark och utkomst. The import of proteins is very large and comes in the form of soybean meal mainly from Brazil as it is a large environment and climate problem as it uses rainforest land. Soybean cultivation in Brazil is the single biggest reason for deforestation in the world and is done with the help of swede farming. Delta is also a major social problem as small farmers lose their land and livelihoods.

Anvandningen av handelsgodsel har okat de senaste 50 aren och sedan djurjordbruken separerades frail spannmalsodlingen har en obalans skapats. Jordarna dar endast spannmal odlas har ftirlorat mycket av sift organiska material i form av humus (mull) och djurgardarna far ofta ett Overskott av kvave som ofta resulterar i lackage till vattendrag, sjoar och hay. The use of commercial goods has increased in the last 50 years and since animal farms were separated from grain cultivation, an imbalance has been created. The soils where only cereals are grown have lost a lot of sift organic material in the form of humus (soil) and the zoos often get an excess of nitrogen which often results in varnishing to streams, lakes and hay.

Det atgar stora mangder energi aft tillverka kvavegodning, stora delar av den energi som utvinns fran akrarna forbrukas vid tillverkning av syntetiskt kvave, men da anvands fossil olja eller gas. It takes large amounts of energy to produce nitrogen fertilizer, large parts of the energy extracted from the fields are consumed in the production of synthetic nitrogen, but then fossil oil or gas is used.

Behovet av en kvavefixerande fcirfruktsgroda i vaxtftiljden i vaxelbruk med spannmal och raps är mycket stort. Detta tillsammans med minskad plojning kan restaurera bade jorden och luften. The need for a nitrogen-fixing forage frog in the plant environment in crop rotation with cereals and rapeseed is very great. This together with reduced plowing can restore both the soil and the air.

Del finns aven en marknad for langa fibrer, bade som fast bransle (ved, briketter och pellets) och som ramaterial till byggskivor. There is also a market for long fibers, both as a solid industry (wood, briquettes and pellets) and as a raw material for building boards.

De vanligaste arterna av baljvaxter som odlas pa vara breddgrader forutom Findusartan och Bruna honor är vanlig foderarta och akerbona. The most common species of legumes grown in latitudes besides Findusartan and Brown females are common fodder species and field beans.

De innehaller stora mangder Protein och Starkelse, resten är vaxtfibrer och sma mangder mineraler och fosfor som efter aft de Onskade materialen utvunnits aterfors jorden. They contain large amounts of Protein and Starch, the rest are plant fibers and small amounts of minerals and phosphorus which, after the desired materials have been extracted, are returned to the soil.

Som forfruktsgroda har bagge var sift problem: Artan drabbas latt av art-rot rota och kan bara odlas vart sjunde ar, Akerbonan kan odlas oftare men har en langre odlingstid och troskas ofta i oktober-november. For aft optimera produktionen av energi, protein och fibrer har en 1 537 606 ekoreaktor utvecklats som kan forkorta akerbonans odlingstid genom aft helskorda den rá for ensilering. As a forage frog, ram has every sift problem: Artan is easily affected by art-root rot and can only be grown every seven years, Akerbonan can be grown more often but has a longer cultivation time and is often trodden in October-November. In order to optimize the production of energy, protein and fiber, a 1,537,606 eco-reactor has been developed which can shorten the akerbonan's cultivation time by completely cutting it raw for ensilage.

Beskrivning: Metoden är en rationell kontinuerlig teknik som syftar till aft ta vara pd hela vaxten bade stdrkelse, glukos, maltodextriner, cellulosa, hemicellulosa, socker, lignin och protein. Description: The method is a rational continuous technique which aims to take advantage of the whole plant both starch, glucose, maltodextrins, cellulose, hemicellulose, sugar, lignin and protein.

Vaxten, ravaran är foretradesvis en baljvaxt ensam eller i kombination med strasad. Baljvdxtens foretrdden är dess egenskap aft kunna fixera kvdve fran luften till jorden medan den vaxer, samt aft den dven skapar en gynnsam struktur i jorden. Detta beror delvis pa eft okat kolinnehall (humus)detta kallas forfruktseffekt. The plant, the raw material, is preferably a legume alone or in combination with strasad. The advantage of baljvdxten is its ability to fix nitrogen from the air to the soil while it is growing, and because it also creates a favorable structure in the soil. This is partly due to increased carbon content (humus) this is called the pre-fruiting effect.

Kvdvefixeringen är mycket anvandbar cla baljvaxten inte behover kvavegodslas och aven lamnar 30 — 50 kg kvave/Ha i jorden till ndsta groda i samband med odling. The quince fixation is very useful cla the legume does not need to be nitrogen fertilized and also leaves 30 - 50 kg nitrogen / Ha in the soil for the next frog in connection with cultivation.

Baljvdxten skapar ocksa en mycket positiv struktur for jorden vilket resulterar i skordeokningar for ndstkommande groda foretradesvis hostsadda grodor. Koldioxid insamlas ocksa fran luften och tillsammans med Vate fran vattnet kan vaxten bilda en mangd anvandbara anmen sasom korta kolhydrater (socker och Starkelse m.m.) T.ex. monosackarider i olika former som glukos och aminosyror som är en forening av Kvave, Vdte, Syre och Kol (endast tva av de 20 existerande Aminosyrorna innehaller ocksa ett ensamt Svavel). Aminosyrorna kan sedan bilda mycket stora mangder olika sorters proteiner. Fibrer r ocksa kolhydrater i langa kedjor i antingen 5 eller 6 Kols struktur, vilka ocksa är C, H och 0 kombinationer. The baljvdxten also creates a very positive structure for the soil, which results in yield increases for the next frog, preferably hosted frogs. Carbon dioxide is also collected from the air and together with Vate from the water, the plant can form a number of useful substances such as short carbohydrates (sugar and starch, etc.). monosaccharides in various forms such as glucose and amino acids which are a combination of Kvave, Vdte, Oxygen and Carbon (only two of the 20 existing Amino Acids also contain a single Sulfur). The amino acids can then form very large amounts of different kinds of proteins. Fibers are also long chain carbohydrates in either the 5 or 6 Carbon structure, which are also C, H and 0 combinations.

Baljvdxten innehaller stora mangder protein uppbyggt av tidigare namnda Aminosyror som ir uppbyggligt for bade manniskor och djur. The baljvdxten contains large amounts of protein made up of previously mentioned Amino acids which are edifying for both humans and animals.

Aven kolhydrat finns tillgangligt i form av socker, maltodextrin, stdrkelse, cellulosa, hemicellulosa och lignin. Vilket gör aft detta är en vdrdefull del i processen. Carbohydrates are also available in the form of sugar, maltodextrin, starch, cellulose, hemicellulose and lignin. Which makes this a valuable part of the process.

Resultatet är aft allt som utvinns kommer fran luften och vattnet. Peas on Earth-konceptet anvander vaxten och jorden bara som yard i processen men bortfOr ingenting, ddremot berikas jorden med kvave som godning och kol i form av humus fran luften sa att halten CO2 minskar i atmosfdren. The result is that everything that is extracted comes from the air and the water. The Peas on Earth concept uses the plant and the soil only as a yard in the process but removes nothing, on the other hand, the soil is enriched with nitrogen as a fertilizer and carbon in the form of humus from the air so that the CO2 content decreases in the atmosphere.

Tekniken är kontinuerlig och ravaran är torr, halvtorr, ensilerad, hosilerad eller rã, Ms eller i bal. The technique is continuous and the raw material is dry, semi-dry, ensiled, hosylated or raw, Ms or in bale.

Ravaran är foretradesvis ensilerad. 2 537 606 Produktionen sker i en ekoreaktor ddr bade energi, ravaror och halvfabrikat (transferprodukter) anvands som katalysatorer i processen som borjar med att vaxtfibrerna separeras ut och renas. Detta Ors foretradesvis ur en farsk eller ensilerat fardigvuxen groda. Pa detta sat forkortas vaxtperioden sa att nastkommande groda kan insas tidig host. Med hjalp av krossning och valsning pa ett sadant sat att fibrema inte bryts. rensas pa detta satt fibrema i stjalkarna fran jasbara kolhydrater sasom ovan namnda starkelse, socker och dextriner. The raw material is preferably ensiled. 2,537,606 Production takes place in an eco-reactor where both energy, raw materials and semi-finished products (transfer products) are used as catalysts in the process that begins with the plant fibers being separated out and purified. This Ors is preferably from a fresh or ensiled ready-grown frog. In this way, the growing period is shortened so that the next frog can be seen early in the autumn. By means of crushing and rolling in such a way that the fibers are not broken. In this way, the fibers in the stems are cleansed of fermentable carbohydrates such as the above-mentioned starch, sugar and dextrins.

Valsningen är konstruerad sa att man forst pa en upprullare i form av ett transportband (1.a) repar och trtiskar grodan sa att fri5na frilaggs och avskiljs, detta Ors med hjalp av en roterande repa (1.b) bade repar ur frona och kastar fibrema till ett annat transportband som rotsig med hogre hastighet sit att materialet i rullen blir tunnare. FrOna hamnar i uppsamlaren (1.c). Vidare fors grodan in mellan tva gangade valsar (1.d) som sprider fibrerna jamnt mot underlaget sit att en grovseparering mellan fibrema sker fran varann och skaldelama faller ay. Nasta steg är en kombination av en hard perforerad vals under en gummioverdragen (1.e) som pressar ur vatskan. De sista valsama ar placerade pa ett hart underlag med hal. Dessa valsar (1.f) har en viss vinlcelskillnad sit att grodan rullar i sidled fram och Ater mot ett hart av overskottsvarme fran processen uppvarmt plant underlag. Delta far till foljd att fibrerna rengors fran kortare kolhydrater och proteiner vilka via halen far onskad granulatstorlek. The rolling is designed so that you first put on a reel in the form of a conveyor belt (1.a) scratches and tritisk the frog so that the free ones are exposed and separated, this Ors with the help of a rotating scratch (1.b) both scratches out of the seeds and throws the fibers to another conveyor belt that are rooted at a higher speed sit that the material in the roll becomes thinner. FrOna ends up in the collector (1.c). Furthermore, the frog is inserted between two threaded rollers (1.d) which spread the fibers evenly against the substrate, so that a coarse separation between the fibers takes place from each other and the shell parts fall ay. The next step is a combination of a hard perforated roller under a rubber coating (1.e) which is pressed out of the liquid. The last rollers are placed on a hard surface with a halo. These rollers (1.f) have a certain angle cell difference sit that the frog rolls sideways forward and Ater against a hart of excess heat from the process heated flat surface. Delta causes the fibers to be cleansed of shorter carbohydrates and proteins which via the tail get the desired granulate size.

De frilagda fibrema är torra och uppsamlas pa onskvart salt. The exposed fibers are dry and collected on black salt.

Resterande material bestar tillsanunans med frona och baljoma av protein, stdrkelse, maltodextriner, cellulosa, lignin och socker, foretradesvis glukos vilket samlas in med hjalp karet (1.c) och fors vidare i ekoreaktorprocessen med hj alp av en slcruv i botten av (1.c). The remaining material consists in combination with the seeds and pods of protein, starch, maltodextrins, cellulose, lignin and sugar, preferably glucose which is collected with the help of the vessel (1.c) and passed on in the ecoreactor process using a sludge screw at the bottom of (1c). .c).

Dar blandas det granulerade materialet med den transferlosning som bestar av vatten och / eller filtrerad drank tillsammans med glukos vilket far en specifik vikt av Riretradesvis 1,15kg/liter. Derma glukos bildas efter hydrolys och protein-avskummning, men fore tillforande av jast senare i processen och separeras genom att den tyngre starkelsen med en specifik vikt av 1.25kg/liter sjunker till botten och det lattare proteinet 1,05kg/liter fiyter upp till ytan. Delta sker i en vertikal hog och uppifran smalt utformad tank (6.a) dar starkelseproteinfraktionen blandas (6.b) med den hydrolyserade glukoslosningen sá att den skiktar sig medan den sakta flyter genom kdrlet i rumstemperatur. Nar starkelsen sjunkit till botten 3 537 606 skruvas den ut ur karlet med en skruv (6.c). Proteinet som flutit upp skummas av fran ytan for torkning genom att den forst skruvas med en trapetsskruv upp over en silduk (6.d) och sedan mot en filtertryckpress dar silduken och skruven far formen av en kona vilken beskrivs i (6.e) Det torkade proteinet tas ur processen for lagring via (6.f). Transferlosningen fortsatter sedan till fermentering via jasttillsats (3.b). There, the granulated material is mixed with the transfer solution consisting of water and / or filtered beverage together with glucose, which has a specific gravity of Riretradesvis 1.15 kg / liter. This glucose is formed after hydrolysis and protein foaming, but before the addition of yeast later in the process and separated by the heavier starch with a specific weight of 1.25 kg / liter sinking to the bottom and the lighter protein 1.05 kg / liter floating to the surface . Delta takes place in a vertical hog and a narrowly formed tank from above (6.a) where the starch protein fraction is mixed (6.b) with the hydrolysed glucose solution so that it stratifies as it slowly flows through the vessel at room temperature. When the starch has dropped to the bottom 3 537 606, unscrew it from the vessel with a screw (6.c). The floating protein is foamed from the surface for drying by first screwing it with a trapezoidal screw up over a screen cloth (6.d) and then against a filter pressure press where the screen cloth and the screw take the form of a cone which is described in (6.e). the dried protein is taken out of the process for storage via (6.f). The transfer solution then proceeds to fermentation via yeast additive (3.b).

Den utvunna starkelsen som awn kan innehalla socker och maltodextriner blandas med vatten och/eller filtrerad drank. Dessa hettas upp av en varmevaxlare som har formen av en trapetsskruv (2.a) vilken omringar (omsluter) ett rtir med god ledningsformaga foretradesvis av koppar eller aluminium (2.b). Skruven är innesluten i ett stone ror med dalig ledningsformaga foretradesvis av rostfritt stal eller plast som isoleras (2.c). Av varmen borjar cellvaggama att brista i den tillfZirda starkelsen som gelatiniseras, detta skapar en trogflytande vdtska som transporteras fram av en ovan beskriven skruv. Vatskan \Tams upp av den heta vatska som behover kylas (2.d). Skruven är av trapetsform vilken drivs av en vinkelvaxel. (2.e). Skruven har en utformning sa att den samtidigt genom mekanisk paverkan (slcrapning) hailer det inre och yttre rOret fritt fran proteinansamlingar och andra fasta partiklar. Skruvens tredje funktion är att fcira vatskan inifra'n det heta inre roret till det kalla yttre och omvant fOr att uppna maximal varmevaxling. Detta sker genom att skruven har en utformning med styrskenor som pa ovansidan av trapetsskruven är vinklade sa att vatskan fors ut fran det inre roret i mitten och pa undersidan är vinklade sá att vatskan fors till det inre roret. Altemativt är styrskenoma utformade sa att vatskan fors in mot det heta roret pa ovansidan och ut pa undersidan. \Tame tillfors ocksa pa samma satt fran den heta dranken som skall kylas och fran overskottsvarmen fran varmepumpen. Detta beskrivs senare i ansolcan. The starch obtained as awn may contain sugar and maltodextrins mixed with water and / or filtered beverage. These are heated by a heat exchanger in the form of a trapezoidal screw (2.a) which surrounds (encloses) a ring with good conductivity, preferably of copper or aluminum (2.b). The screw is enclosed in a stone rudder with a thin conductor shape, preferably made of stainless steel or plastic that is insulated (2.c). Due to the heat, the cell cradles begin to rupture in the supplied starch which is gelatinized, this creates a viscous liquid which is transported forward by a screw described above. The liquid \ Tams up the hot liquid that needs to be cooled (2.d). The screw is of a trapezoidal shape which is driven by an angular shaft. (2.e). The screw has a design so that it simultaneously by mechanical action (scraping) hails the inner and outer tube free from protein accumulations and other solid particles. The third function of the screw is to move the liquid from the hot inner tube to the cold outer and vice versa to achieve maximum heat exchange. This is done by the screw having a design with guide rails which are angled on the top of the trapezoidal screw so that the liquid is carried out from the inner tube in the middle and on the underside are angled so that the liquid is carried to the inner tube. Alternatively, the guide rails are designed so that the liquid is carried towards the hot pipe on the upper side and out on the lower side. Tame is also supplied in the same way from the hot beverage to be cooled and from the excess heat from the heat pump. This is described later in the ansolcan.

Det yttre och inre roret tillsammans med skruven är bojbara och kan darmed passas in i en ekoreaktor sA att den tar minimalt med utrymme. The outer and inner rudder together with the screw are bendable and can thus be fitted into an echo reactor so that it takes up minimal space.

Efter uppvarmning kan hydrolysen inledas genom att ett enzym sprayas Over den trogflytande vdtskan som nu är med hjdlp av en "brevldde-teknik" utbredd Over en rorlig uppvdrmd yta foretradesvis i form av en trumma eller tva mot varandra rullande trummor enligt (3.1). sa att en stor yta skapas (3.1.a). Genom att det uppvarmda underlaget ror sig och passerar igenom en "brevlada" distribueras ravaran jamt fordelad vilket är att foredra da mangden enzym (3.1.b) altemativt som sprayas pa den andra trumman cla kan optimeras. Denna hydrolys varar i ca.2 timmar medan vatskan efter sprayning eller parullning (3.1.c) sakta fors framat under omroming med hjalp av en skruv liknande den i (2) i karlet (3.1.d). Denna skruvvarmevaxlare 4 537 606 kan leverera varme och halla vatskan i jamn temperatur. Tillskottsvarmen kommer fran varmepumpen (5) fran pannan (2.0 fran dranken och bryter upp stdrkelsen till maltodextriner, samtidigt bryts gelatiniseringen och vatskan blir ater ldttflytande. After heating, the hydrolysis can be initiated by spraying an enzyme over the viscous liquid which is now spread by means of a "lettering technique" over a movable heated surface preferably in the form of a drum or two rolling drums according to (3.1). said that a large surface is created (3.1.a). As the heated substrate moves and passes through a "letter tray", the raw material is evenly distributed, which is preferable as the amount of enzyme (3.1.b) alternatively sprayed on the second drum cla can be optimized. This hydrolysis lasts for about 2 hours while the liquid after spraying or parrolling (3.1.c) is slowly rushed forward with stirring using a screw similar to that in (2) in the vessel (3.1.d). This screw heat exchanger 4,537,606 can supply heat and keep the liquid at an even temperature. The additional heat comes from the heat pump (5) from the boiler (2.0 from the beverage and breaks up the starch into maltodextrins, at the same time the gelatinization is broken and the liquid becomes liquid again.

Efter hydrolysen fors vatskan vidare under det aft temperaturen hojs ytterligare av energi fran varmepumpen (5) och / eller pannan (2.1) som nu i nasta "brev-lada" breds ut pa ett rorligt uppvannt underlag foretradesvis i form av en trumma. After the hydrolysis, the liquid is passed on while the temperature is further raised by energy from the heat pump (5) and / or the boiler (2.1) which is now spread in the next "letter box" on a well-heated surface, preferably in the form of a drum.

Det resterande protein som granulatet innehaller frigors da och bildar ett skum som flyter upp ur valskan ddr det mekaniskt skummas ay. Skumningen sker med hjalp av ett lutande stal med hal dar (2.g) är placerat mellan vatskan och det uppflytande proteinetskummet och separerar pa sa sätt dessa frail varann. The remaining protein that the granulate contains is then released and forms a foam that floats out of the roller where it is mechanically foamed. The foaming takes place with the aid of an inclined steel with halves (2.g) placed between the liquid and the liquid protein foam and thus separating these frail from each other.

Dena protein firs ut fran processen med hjalp av ett transportband (2.h) med medbringare och en skruv som via ett ror (2) i for proteinet ut fran processen till fortdtning och fOrddling. This protein is released from the process by means of a conveyor belt (2.h) with a carrier and a screw which, via a tube (2), carries the protein out of the process for compaction and processing.

Sedan sanks temperaturen till foretradesvis mellan 50 och 70°C genom aft destillatom (2.j) forvarms och efter avkylning sker ytterligare en hydrolys genom aft ravaran, nu renad frail protein och i formen av maltodextrin och socker utbreds via" brev-lade" teknik enligt (3.1.a) pa ett rorligt underlag foretradesvis i form av en trumma eller tva mot varandra rullande trununor for aft astadkomma en stor yta. Denna yta sprayas (2.k) med ett ytterligare enzym eller pafores med hjdlp av en trumma (3.1.c) och under omrorning via vridna plastskenor (2.1) som vdtskan passerar och omvandlar vaskan till glukosvattenlosning. Then the temperature is lowered to preferably between 50 and 70 ° C through the aft distiller (2.j) preheated and after cooling a further hydrolysis takes place through the aft raw material, now purified frail protein and in the form of maltodextrin and sugar is spread via "letter-laid" technique according to (3.1.a) on a movable surface, preferably in the form of a drum or two truncated rollers to achieve a large surface area. This surface is sprayed (2.k) with an additional enzyme or pafores using a drum (3.1.c) and while stirring via twisted plastic rails (2.1) as the liquid passes and converts the wash into glucose aqueous solution.

Glukos-vattenblandningen avkyls genom varmevaxling till jasbar temperatur med hjalp av skruven 2.a. som varmer upp den ursprungliga ohydrolycerade ravaran. The glucose-water mixture is cooled by heat exchange to a manageable temperature using the screw 2.a. which heats the original unhydrolyzed raw material.

Den jasbara transfervatskan anvand sedan som den katalysator for separering av stdrkelse och protein som finns beskrivet tidigare. Jast tillfiirs sedan vid (3.b) med hjdlp av en eller tva trummor enligt (3.1) for fermentering. Den jasbara vatskan fors in i ett *tom dar den pumpas in underifran och tillbringar en tid av foretradesvis 48 timmar i en spiral som forhindrar spontana vandringar i vatskan och samtidigt sugs upp av undertrycket i destillatom. Altemativ fors vatskan framat av en trapetsskruv (3.c) och den blandas samtidigt kontinuerligt enligt samma metod som i (2). Det inre roret (3.d) är i detta fall vattenfyllt och utrustat med backventiler for avgang av koldioxid via *rot. (3.e). 537 606 Vatskan borjar i samband med jasningen bilda alkohol som är latare an vatten och stravar dad& att ldgga sig overst. Jastornet beskrivs i (3). The fermentable transfer liquid then used as the catalyst for separation of starch and protein described earlier. The yeast is then added at (3.b) using one or two drums according to (3.1) for fermentation. The fermentable liquid is forced into a void where it is pumped in from below and spends a time of preferably 48 hours in a spiral which prevents spontaneous migrations in the liquid and at the same time is sucked up by the negative pressure in the distiller. Alternatively, the liquid is pushed forward by a trapezoidal screw (3.c) and it is mixed continuously at the same time according to the same method as in (2). In this case, the inner rudder (3.d) is filled with water and equipped with non-return valves for carbon dioxide discharge via * root. (3.e). 537 606 In connection with fermentation, the liquid begins to form alcohol, which is lighter than water and punishes the father & to lie down on top. The tower is described in (3).

Ndr vatskan nar toppen av tornet har den en alkoholhalt av fOretradesvis 11-13% vid (3.0 och skall nu destilleras fOr aft ná drivmedelstyrka (4). When the liquid reaches the top of the tower, it has an alcohol content of preferably 11-13% at (3.0 and must now be distilled to reach fuel strength (4).

Detta sker genom aft vatskan hettas upp till en temperatur av strax under etanolens kokpunkt 78° C. Forvarmning sker via varmevaxlare genom den avkylning som behovs i hydrolysprocessen (4.a) och fran dranken (4.b). Darefter sprids vdtskan ut igen over lutande element i en trappa. (4.c) som dr fyllda med 77°C varm vatska och utsatts for ett undertryck sa aft aven kokpunkten sanks. Detta resulterar ocksa i att angtrycket Over ytan minskar vilket minskar energiatgangen for att vatskan skall overga i gasform av undertrycket som skapas i en pump Fig.4.e som suger in den gas som nu bildas och som bestar av ren alkohol, undertrycket Or ocksa att vatskan i jastomet sugs upp (4.d) och (3.e). This is done by heating the liquid to a temperature just below the boiling point of ethanol 78 ° C. Preheating takes place via heat exchangers through the cooling required in the hydrolysis process (4.a) and from the beverage (4.b). Then the liquid is spread out again over inclined elements in a staircase. (4.c) which were filled with 77 ° C hot liquid and subjected to a negative pressure, so that the boiling point also dropped. This also results in the pressure above the surface decreasing, which reduces the energy input for the liquid to surrender in gaseous form from the negative pressure created in a pump Fig.4.e which sucks in the gas which is now formed and which consists of pure alcohol, the negative pressure Or also that the liquid in the jastome is sucked up (4.d) and (3.e).

Pumpen är av kolvform och utformad sá att en ventil (4.0 star Oppen vid insugning ndr kolven rOr sig sa att volymen i cylindern Okar och den alkoholhaltiga delen av vatskan over& i gasform. Den ventilen stangs sedan nar kolven vander och volymen i cylindem minskar och gasen sammanpressas da mot en annan ventil (4.g) som Oppnas och utanfiir vilken finns ett munstycke (4.h) var igenom gasen pressas. Vid sammanpressningen okar temperaturen pa den sammanpressade gasen av den minskande cylindervolymen (4.i). Den varmen firs bort fran pumpen sá att avkylning av cylindem kan ske via en varmevaxlare av (4.j) pa bilden och den bortforda vdrmen tillfors processen. Efter munstycket faller temperaturen och gasen kondenseras Ater till vdtska. Samtidigt arbetar en annan kolv i motsatt riktning sa att undertrycket och overtrycket halls konstant. The pump is piston-shaped and designed so that a valve (4.0 star Open during suction when the piston is moving so that the volume in the cylinder increases and the alcoholic part of the liquid over & in gaseous form. That valve is then closed when the piston flows and the volume in the cylinder decreases and the gas then compressed against another valve (4.g) which is opened and outside which there is a nozzle (4.h) through which the gas is pressed.During the compression the temperature of the compressed gas increases by the decreasing cylinder volume (4.i). away from the pump so that cooling of the cylinder can take place via a heat exchanger of (4.j) in the picture and the removed heat is supplied to the process.After the nozzle the temperature drops and the gas condenses again to liquid.At the same time another piston works in the opposite direction so that the negative pressure and the overpressure is kept constant.

Denna vatska som pressats genom munstycket bestar av ren alkohol och insamlas for detta andamal i ldmpligt kdrl. (7). This liquid which is forced through the nozzle consists of pure alcohol and is collected for this purpose in an airtight container. (7).

Den tillskottsenergi som processen behover tillsatts vid protein avskiljningen ddr processens hOgsta temperatur uppnas. Detta Or vid behov genom pyrolys av de insamlade och pelleterade fibrerna, men i forsta hand fran den bortforda overskottsvarmen fran destillationspumpen. 6 537 606 Pyroiysgasen tillfiirs en konventionell forbranningsmotor som via en generator producerar den elektricitet som processen behover. Kylvattnet fran motorn tillfors ekoreaktor-processen som pa detta satt blir sjalvforsorjande. overskottsvarmen frail destillationsvarmepumpen ateranvands tillsammans med dranken som skall avkylas. The additional energy that the process needs to be added at the protein separation when the highest temperature of the process is reached. This Or if necessary by pyrolysis of the collected and pelleted fibers, but primarily from the excess heat removed from the distillation pump. 6 537 606 The pyrolysis gas is supplied to a conventional internal combustion engine which, via a generator, produces the electricity needed by the process. The cooling water from the engine is supplied to the eco-reactor process, which in this way becomes self-sufficient. the excess heat from the distillation heat pump was reused with the beverage to be cooled.

Ekoreaktom drivs fOretradesvis av tva el-motorer som drivs av ovan namnda generator. 7 The echo reactor is preferably driven by two electric motors driven by the above-mentioned generator. 7

Claims (1)

537 606 Patentkrav 1. Forfarande, fozir framstallning av socker, etanol och protein ur ravara i form av ensilerade baljvaxter, rika pa bestandsdelarna jasbara kolhydrater, proteiner och dartill fibrer och vatten, innefattande separation av desamma samt hydrolys av kolhydrater till socker samt eventuellt forjasning av sockret till etanol och destillation till lag vattenhalt av denna kannetecknat av kombinationen av stegen: 1. 1 ravaran i form av en bal rullas upp pa ett transportband och repas, d.v.s. troskas och fron avskiljs, 1. 2 avskilda fibrer och skaldelar sprids jamnt over ett underlag och skaldelar avskiljs, 1. 3 fibrer pressas hart, sa aft skaldelar och aterstaende vatska avskiljs, 1. 4 ravaran, fran vilken fibrer avskiljts enligt stegen 1.1-1.3 bestaende av fron och baljor av protein, starkelse, maltodextriner, cellulosa, lignin, och socker, fors vidare for separering av protein och hydrolyserbar substans, 1. 5 den hydrolyserbara substansen hyrolyseras 1. 6 den hydrolyserbara substansen forjases i en forjasningsprocess och537 606 Claims 1. Process, basic production of sugar, ethanol and protein from raw material in the form of ensiled legumes, rich in the constituents of fermentable carbohydrates, proteins and in addition fibers and water, including separation thereof and hydrolysis of carbohydrates into sugar and possible fermentation of the sugar to ethanol and distillation to low water content thereof can be characterized by the combination of the steps: 1. 1 the raw material in the form of a bale is rolled up on a conveyor belt and scratched, ie. trout and seeds are separated, 1. 2 separated fibers and shell parts are spread evenly over a substrate and shell parts are separated, 1. 3 fibers are pressed hard, so that shell parts and remaining liquid are separated, 1. 4 raw material, from which fibers are separated according to steps 1.1-1.3 consisting of seeds and pods of protein, starch, maltodextrins, cellulose, lignin, and sugar, is further processed to separate protein and hydrolyzable substance, 1. the hydrolyzable substance is hydrolyzed 1. 6 the hydrolyzable substance is fermented in a fermentation process and 1. 7 den forjasta substansen destilleras i en destillationsprocess till etanol med lag vattenhalt 2 Anordning for genomforande av forfarande enligt krav 1, stegen 1.1-1.3 kannetecknas av ett forsta transportband (1.a) fir rullning av en bal av ravara, vidare en parallellt med balen inrattad roterande vals (1.b) forsedd med ett antal utstaende piggar for utskiljande av frOn och vidare transport av fibrer och aterstaende ravara till ett andra transportband, med hogre hastighet An det forsta transportbandet, och tva tvarstallda gangade valsar (1.d) for spridning av fibrerna Over underlaget och avskiljning av free, vidare tvarstallda valsar (1.e) och (1.0 for utpressning av aterstaende vatska 8 537 606The fermented substance is distilled in a distillation process to ethanol with a low water content. Device for carrying out the process according to claim 1, steps 1.1-1.3 can be characterized by a first conveyor belt (1.a) for rolling a bale of ravara, further a parallel with the bale rotating roller (1.b) provided with a number of protruding spikes for separating from and further transport of fibers and remaining raw material to a second conveyor belt, at a higher speed than the first conveyor belt, and two transverse threaded rollers (1.d ) for spreading the fibers Above the substrate and separating free, further transverse rollers (1.e) and (1.0 for squeezing out the remaining liquid 8 537 606
SE1100706A 2011-09-26 2011-09-26 Method and apparatus for producing sugar, protein and ethanol from ensiled legumes SE537606C2 (en)

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