SE447396B - Elektrod, i synnerhet for elektrolys av vattenlosningar, forfarande for framstellning av elektroden samt anvendning av densamma - Google Patents
Elektrod, i synnerhet for elektrolys av vattenlosningar, forfarande for framstellning av elektroden samt anvendning av densammaInfo
- Publication number
- SE447396B SE447396B SE7801874A SE7801874A SE447396B SE 447396 B SE447396 B SE 447396B SE 7801874 A SE7801874 A SE 7801874A SE 7801874 A SE7801874 A SE 7801874A SE 447396 B SE447396 B SE 447396B
- Authority
- SE
- Sweden
- Prior art keywords
- chromium
- electrode
- alloy
- weight
- nickel
- Prior art date
Links
- 238000005868 electrolysis reaction Methods 0.000 title claims description 24
- 238000000034 method Methods 0.000 title claims description 17
- 238000004519 manufacturing process Methods 0.000 title claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 60
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 58
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 53
- 239000011651 chromium Substances 0.000 claims description 49
- 229910045601 alloy Inorganic materials 0.000 claims description 46
- 239000000956 alloy Substances 0.000 claims description 46
- 229910052804 chromium Inorganic materials 0.000 claims description 41
- 239000000758 substrate Substances 0.000 claims description 40
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 32
- 229910052759 nickel Inorganic materials 0.000 claims description 28
- 238000005530 etching Methods 0.000 claims description 25
- 239000007864 aqueous solution Substances 0.000 claims description 24
- 229910052742 iron Inorganic materials 0.000 claims description 22
- 229910052751 metal Inorganic materials 0.000 claims description 21
- 239000002184 metal Substances 0.000 claims description 21
- 239000010410 layer Substances 0.000 claims description 17
- 239000011148 porous material Substances 0.000 claims description 17
- 229910052750 molybdenum Inorganic materials 0.000 claims description 12
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 11
- 238000005488 sandblasting Methods 0.000 claims description 10
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 9
- 239000011733 molybdenum Substances 0.000 claims description 9
- 239000002344 surface layer Substances 0.000 claims description 9
- 229910001514 alkali metal chloride Inorganic materials 0.000 claims description 7
- 239000000243 solution Substances 0.000 claims description 7
- 238000005275 alloying Methods 0.000 claims description 2
- 239000007858 starting material Substances 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 description 32
- 229910052739 hydrogen Inorganic materials 0.000 description 32
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 31
- 229910001220 stainless steel Inorganic materials 0.000 description 16
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 14
- 239000010935 stainless steel Substances 0.000 description 13
- 239000000203 mixture Substances 0.000 description 11
- 229910052748 manganese Inorganic materials 0.000 description 9
- 238000011282 treatment Methods 0.000 description 8
- 239000011780 sodium chloride Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 230000010287 polarization Effects 0.000 description 6
- ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical class Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- 229920002313 fluoropolymer Polymers 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 229910000990 Ni alloy Inorganic materials 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- UQSQSQZYBQSBJZ-UHFFFAOYSA-N fluorosulfonic acid Chemical compound OS(F)(=O)=O UQSQSQZYBQSBJZ-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 3
- -1 platinum group metals Chemical group 0.000 description 3
- 229910001925 ruthenium oxide Inorganic materials 0.000 description 3
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 239000010963 304 stainless steel Substances 0.000 description 2
- 229910000589 SAE 304 stainless steel Inorganic materials 0.000 description 2
- 239000010425 asbestos Substances 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 239000010406 cathode material Substances 0.000 description 2
- 238000003486 chemical etching Methods 0.000 description 2
- 239000000788 chromium alloy Substances 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 229910000856 hastalloy Inorganic materials 0.000 description 2
- 239000003014 ion exchange membrane Substances 0.000 description 2
- 229910000623 nickel–chromium alloy Inorganic materials 0.000 description 2
- 229910052895 riebeckite Inorganic materials 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 241000234282 Allium Species 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 101100347993 Caenorhabditis elegans nas-1 gene Proteins 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 101100298295 Drosophila melanogaster flfl gene Proteins 0.000 description 1
- 229910001030 Iron–nickel alloy Inorganic materials 0.000 description 1
- 229910001260 Pt alloy Chemical group 0.000 description 1
- WAIPAZQMEIHHTJ-UHFFFAOYSA-N [Cr].[Co] Chemical compound [Cr].[Co] WAIPAZQMEIHHTJ-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910000963 austenitic stainless steel Inorganic materials 0.000 description 1
- RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 description 1
- 229910001863 barium hydroxide Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- BIJOYKCOMBZXAE-UHFFFAOYSA-N chromium iron nickel Chemical compound [Cr].[Fe].[Ni] BIJOYKCOMBZXAE-UHFFFAOYSA-N 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 229910001026 inconel Inorganic materials 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000000048 melt cooling Methods 0.000 description 1
- 229910001120 nichrome Inorganic materials 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- ing And Chemical Polishing (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1612277A JPS53102279A (en) | 1977-02-18 | 1977-02-18 | Electrode body |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| SE7801874L SE7801874L (sv) | 1978-08-19 |
| SE447396B true SE447396B (sv) | 1986-11-10 |
Family
ID=11907698
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SE7801874A SE447396B (sv) | 1977-02-18 | 1978-02-17 | Elektrod, i synnerhet for elektrolys av vattenlosningar, forfarande for framstellning av elektroden samt anvendning av densamma |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US4255247A (fr) |
| JP (1) | JPS53102279A (fr) |
| CA (1) | CA1142132A (fr) |
| DE (1) | DE2807054A1 (fr) |
| FR (1) | FR2381113A1 (fr) |
| GB (1) | GB1580019A (fr) |
| IT (1) | IT1095417B (fr) |
| SE (1) | SE447396B (fr) |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4248679A (en) * | 1979-01-24 | 1981-02-03 | Ppg Industries, Inc. | Electrolysis of alkali metal chloride in a cell having a nickel-molybdenum cathode |
| JPS55104491A (en) * | 1979-02-06 | 1980-08-09 | Asahi Glass Co Ltd | Preparation of electrode |
| JPS55115984A (en) * | 1979-03-01 | 1980-09-06 | Osaka Soda Co Ltd | Activated iron cathode |
| FR2459298A1 (fr) * | 1979-06-18 | 1981-01-09 | Inst Francais Du Petrole | Electrode activee a base de nickel et son utilisation notamment pour l'electrolyse de l'eau |
| US4221643A (en) * | 1979-08-02 | 1980-09-09 | Olin Corporation | Process for the preparation of low hydrogen overvoltage cathodes |
| US4414064A (en) * | 1979-12-17 | 1983-11-08 | Occidental Chemical Corporation | Method for preparing low voltage hydrogen cathodes |
| US4354915A (en) * | 1979-12-17 | 1982-10-19 | Hooker Chemicals & Plastics Corp. | Low overvoltage hydrogen cathodes |
| JPS56124447A (en) * | 1980-03-05 | 1981-09-30 | Hitachi Ltd | Manufacture of catalyst |
| US4470893A (en) * | 1981-06-01 | 1984-09-11 | Asahi Glass Company Ltd. | Method for water electrolysis |
| US4440638A (en) * | 1982-02-16 | 1984-04-03 | U.T. Board Of Regents | Surface field-effect device for manipulation of charged species |
| US4487818A (en) * | 1982-07-19 | 1984-12-11 | Energy Conversion Devices, Inc. | Fuel cell anode based on a disordered catalytic material |
| JPS6286187A (ja) * | 1985-10-09 | 1987-04-20 | Asahi Chem Ind Co Ltd | 水素発生用の電極 |
| US4744878A (en) * | 1986-11-18 | 1988-05-17 | Kerr-Mcgee Chemical Corporation | Anode material for electrolytic manganese dioxide cell |
| US4916098A (en) * | 1988-11-21 | 1990-04-10 | Sherbrooke University | Process and apparatus for manufacturing an electrocatalytic electrode |
| US5167788A (en) * | 1989-06-30 | 1992-12-01 | Eltech Systems Corporation | Metal substrate of improved surface morphology |
| US5314601A (en) * | 1989-06-30 | 1994-05-24 | Eltech Systems Corporation | Electrodes of improved service life |
| US6306544B1 (en) * | 1999-02-25 | 2001-10-23 | Wilson Greatbatch Ltd. | Cobalt-based alloys as positive electrode current collectors in nonaqueous electrochemical cells |
| CA2370899A1 (fr) * | 1999-05-06 | 2000-11-16 | Sandia Corporation | Cellule a combustible et membrane |
| US6890677B2 (en) | 1999-05-06 | 2005-05-10 | Sandia Corporation | Fuel cell and membrane |
| US20050112432A1 (en) * | 2002-08-27 | 2005-05-26 | Jonah Erlebacher | Method of plating metal leafs and metal membranes |
| US6805972B2 (en) * | 2002-08-27 | 2004-10-19 | Johns Hopkins University | Method of forming nanoporous membranes |
| US7562807B2 (en) * | 2004-05-05 | 2009-07-21 | Electric Power Research Institute | Weld filler for welding dissimilar alloy steels and method of using same |
| US7371988B2 (en) | 2004-10-22 | 2008-05-13 | Electric Power Research Institute, Inc. | Methods for extending the life of alloy steel welded joints by elimination and reduction of the HAZ |
| FR2940857B1 (fr) * | 2009-01-07 | 2011-02-11 | Commissariat Energie Atomique | Procede de fabrication d'un electrolyseur haute temperature ou d'une pile a combustible haute temperature comprenant un empilement de cellules elementaires |
| US20110159312A1 (en) | 2009-12-24 | 2011-06-30 | Panasonic Corporation | Aluminum foil for aluminum electrolytic capacitor electrode and method for manufacturing the same |
| FI2823079T3 (fi) | 2012-02-23 | 2023-05-04 | Treadstone Tech Inc | Korrosiota kestävä ja sähköä johtava metallin pinta |
| KR102442799B1 (ko) * | 2016-01-13 | 2022-09-14 | 엘지이노텍 주식회사 | 열전 소자 |
| JP7202082B2 (ja) | 2017-06-23 | 2023-01-11 | 三井・ケマーズ フロロプロダクツ株式会社 | 熱溶融性フッ素樹脂成形品 |
| WO2018237297A1 (fr) | 2017-06-23 | 2018-12-27 | Dupont-Mitsui Fluorochemicals Co. Ltd | Article moulé en une résine fluorée pouvant être mis en œuvre à l'état fondu |
| CN107587158B (zh) * | 2017-08-11 | 2019-08-16 | 天津工业大学 | 一种纳米多孔高熵合金电极及其制备方法和应用 |
| GB201809002D0 (en) * | 2018-06-01 | 2018-07-18 | Allied Gold Ltd | Treatment of articles of silver alloy |
| JP7249114B2 (ja) * | 2018-08-23 | 2023-03-30 | 三井・ケマーズ フロロプロダクツ株式会社 | 熱溶融性フッ素樹脂射出成形品 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH161836A (de) * | 1932-07-13 | 1933-05-31 | Oerlikon Maschf | Verfahren zur Herstellung von Elektroden mit fein gerauhter Oberfläche für elektrolytische Apparate, insbesondere für solche zur Zerlegung des Wassers. |
| GB634097A (en) | 1946-10-02 | 1950-03-15 | Peter William Reynolds | Improvements in and relating to copper catalysts |
| DE1244891B (de) * | 1961-05-06 | 1967-07-20 | Asea Ab | Verfahren zur Herstellung einer gesinterten poroesen Elektrode fuer Brennstoffelemente |
| BE627225A (fr) * | 1962-01-19 | |||
| GB1113421A (en) * | 1964-07-20 | 1968-05-15 | Imp Metal Ind Kynoch Ltd | Electrodes and methods of making same |
| DE1496108A1 (de) * | 1964-11-18 | 1969-01-09 | Hoechst Ag | Verfahren zur Herstellung von Sauerstoff-Loesungselektroden |
| DE1282004B (de) * | 1965-07-10 | 1968-11-07 | Basf Ag | Verwendung von Elektroden aus Legierungen von Wolfram und/oder Molybdaen mit Metallen der Eisengruppe |
| DE1288572B (de) * | 1965-12-30 | 1969-02-06 | Basf Ag | Kathodische Reduktion von nitrosen Gasen und/oder Salpetersaeure mit titan- und/oder wolframhaltigen Elektroden |
| US3380934A (en) * | 1966-10-20 | 1968-04-30 | Exxon Research Engineering Co | Noble metal catalysts and their production |
| DE1928929C3 (de) * | 1969-06-07 | 1979-04-12 | Siemens Ag, 1000 Berlin Und 8000 Muenchen | Raney-Mischkatalysator |
| US3637437A (en) * | 1970-06-03 | 1972-01-25 | Catalytic Technology Corp | Raney metal sheet material |
| AR205039A1 (es) * | 1974-07-17 | 1976-03-31 | Hooker Chemicals Plastics Corp | Catodo electrolitico que tiene una superficie microporosa y un procedimiento para prepararlo |
| HU170253B (fr) * | 1974-10-07 | 1977-05-28 | ||
| US4024044A (en) * | 1975-09-15 | 1977-05-17 | Diamond Shamrock Corporation | Electrolysis cathodes bearing a melt-sprayed and leached nickel or cobalt coating |
-
1977
- 1977-02-18 JP JP1612277A patent/JPS53102279A/ja active Granted
-
1978
- 1978-02-15 FR FR7804282A patent/FR2381113A1/fr active Granted
- 1978-02-16 IT IT20305/78A patent/IT1095417B/it active
- 1978-02-17 GB GB6420/78A patent/GB1580019A/en not_active Expired
- 1978-02-17 SE SE7801874A patent/SE447396B/sv not_active IP Right Cessation
- 1978-02-17 CA CA000297217A patent/CA1142132A/fr not_active Expired
- 1978-02-18 DE DE19782807054 patent/DE2807054A1/de active Granted
- 1978-02-21 US US05/879,751 patent/US4255247A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE2807054A1 (de) | 1978-08-24 |
| IT1095417B (it) | 1985-08-10 |
| JPS53102279A (en) | 1978-09-06 |
| GB1580019A (en) | 1980-11-26 |
| JPS5419229B2 (fr) | 1979-07-13 |
| DE2807054C2 (fr) | 1988-01-14 |
| SE7801874L (sv) | 1978-08-19 |
| FR2381113B1 (fr) | 1983-07-08 |
| FR2381113A1 (fr) | 1978-09-15 |
| IT7820305A0 (it) | 1978-02-16 |
| US4255247A (en) | 1981-03-10 |
| CA1142132A (fr) | 1983-03-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| NUG | Patent has lapsed |
Ref document number: 7801874-4 Effective date: 19900215 Format of ref document f/p: F |