SE444245B - Uppladdningsbar katod for en sekunder elektrokemisk energilagringscell samt forfarande for bildning av densamma - Google Patents

Uppladdningsbar katod for en sekunder elektrokemisk energilagringscell samt forfarande for bildning av densamma

Info

Publication number: SE444245B
Authority: SE; Sweden
Prior art keywords: cathode; hard metal; metal compound; refractory hard; metal
Prior art date: 1978-09-22

Application number

SE7907838A

Other languages

English (en)

Swedish (sv)

Other versions

SE7907838L (sv

Inventor

J Coetzer

M M Thackeray

Original Assignee

South African Inventions

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-09-22

Filing date

1979-09-21

Publication date

1986-03-24

1978-09-22 Priority claimed from ZA785392A external-priority patent/ZA785392B/xx

1979-09-21 Application filed by South African Inventions filed Critical South African Inventions

1980-03-23 Publication of SE7907838L publication Critical patent/SE7907838L/xx

1986-03-24 Publication of SE444245B publication Critical patent/SE444245B/sv

Links

238000000034 method Methods 0.000 title claims description 8
210000000352 storage cell Anatomy 0.000 title claims description 5
238000012983 electrochemical energy storage Methods 0.000 title claims description 3
210000004027 cell Anatomy 0.000 claims description 114
229910052751 metal Inorganic materials 0.000 claims description 77
239000002184 metal Substances 0.000 claims description 77
239000003792 electrolyte Substances 0.000 claims description 67
150000002736 metal compounds Chemical class 0.000 claims description 59
150000001875 compounds Chemical class 0.000 claims description 56
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 35
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 34
239000011651 chromium Substances 0.000 claims description 34
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 27
150000002739 metals Chemical class 0.000 claims description 27
229910052755 nonmetal Inorganic materials 0.000 claims description 27
229910052804 chromium Inorganic materials 0.000 claims description 26
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 23
229910052742 iron Inorganic materials 0.000 claims description 19
230000026030 halogenation Effects 0.000 claims description 18
238000005658 halogenation reaction Methods 0.000 claims description 18
229910052759 nickel Inorganic materials 0.000 claims description 18
229910017052 cobalt Inorganic materials 0.000 claims description 17
239000010941 cobalt Substances 0.000 claims description 17
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 17
-1 halide ions Chemical class 0.000 claims description 16
150000002843 nonmetals Chemical class 0.000 claims description 13
229910052799 carbon Inorganic materials 0.000 claims description 12
239000011572 manganese Substances 0.000 claims description 10
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 10
238000005868 electrolysis reaction Methods 0.000 claims description 9
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
229910052748 manganese Inorganic materials 0.000 claims description 8
229910052710 silicon Inorganic materials 0.000 claims description 8
239000010703 silicon Substances 0.000 claims description 8
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 7
150000004767 nitrides Chemical class 0.000 claims description 7
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 6
239000007789 gas Substances 0.000 claims description 6
229910052736 halogen Inorganic materials 0.000 claims description 6
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 5
229910052796 boron Inorganic materials 0.000 claims description 5
239000006182 cathode active material Substances 0.000 claims description 5
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 4
230000003213 activating effect Effects 0.000 claims description 4
229910052757 nitrogen Inorganic materials 0.000 claims description 4
229910052698 phosphorus Inorganic materials 0.000 claims description 4
239000011574 phosphorus Substances 0.000 claims description 4
238000007599 discharging Methods 0.000 claims description 3
CXOWYMLTGOFURZ-UHFFFAOYSA-N azanylidynechromium Chemical compound [Cr]#N CXOWYMLTGOFURZ-UHFFFAOYSA-N 0.000 claims description 2
ZDVYABSQRRRIOJ-UHFFFAOYSA-N boron;iron Chemical compound [Fe]#B ZDVYABSQRRRIOJ-UHFFFAOYSA-N 0.000 claims description 2
229910021357 chromium silicide Inorganic materials 0.000 claims description 2
RUFLMLWJRZAWLJ-UHFFFAOYSA-N nickel silicide Chemical compound [Ni]=[Si]=[Ni] RUFLMLWJRZAWLJ-UHFFFAOYSA-N 0.000 claims description 2
229910021334 nickel silicide Inorganic materials 0.000 claims description 2
239000007787 solid Substances 0.000 claims 3
238000002474 experimental method Methods 0.000 description 53
230000000694 effects Effects 0.000 description 24
150000001247 metal acetylides Chemical class 0.000 description 22
229910052784 alkaline earth metal Inorganic materials 0.000 description 14
229910052782 aluminium Inorganic materials 0.000 description 14
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 12
239000000126 substance Substances 0.000 description 12
238000001994 activation Methods 0.000 description 11
150000001340 alkali metals Chemical class 0.000 description 11
230000015572 biosynthetic process Effects 0.000 description 11
230000004913 activation Effects 0.000 description 10
229910002804 graphite Inorganic materials 0.000 description 10
239000010439 graphite Substances 0.000 description 10
239000000203 mixture Substances 0.000 description 10
150000001342 alkaline earth metals Chemical class 0.000 description 9
239000011162 core material Substances 0.000 description 9
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 8
229910052783 alkali metal Inorganic materials 0.000 description 8
229910045601 alloy Inorganic materials 0.000 description 8
239000000956 alloy Substances 0.000 description 8
KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 8
238000007789 sealing Methods 0.000 description 8
229910021332 silicide Inorganic materials 0.000 description 8
238000003860 storage Methods 0.000 description 8
125000004429 atom Chemical group 0.000 description 7
230000008901 benefit Effects 0.000 description 7
238000002844 melting Methods 0.000 description 7
230000001681 protective effect Effects 0.000 description 7
238000012360 testing method Methods 0.000 description 7
229910052723 transition metal Inorganic materials 0.000 description 7
150000003624 transition metals Chemical class 0.000 description 7
229910001508 alkali metal halide Inorganic materials 0.000 description 6
239000011521 glass Substances 0.000 description 6
230000008018 melting Effects 0.000 description 6
150000003839 salts Chemical class 0.000 description 6
239000002344 surface layer Substances 0.000 description 6
229910000838 Al alloy Inorganic materials 0.000 description 5
239000003513 alkali Substances 0.000 description 5
229910001615 alkaline earth metal halide Inorganic materials 0.000 description 5
239000011575 calcium Substances 0.000 description 5
229910052960 marcasite Inorganic materials 0.000 description 5
NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 5
229910052683 pyrite Inorganic materials 0.000 description 5
239000007784 solid electrolyte Substances 0.000 description 5
239000000758 substrate Substances 0.000 description 5
229910003470 tongbaite Inorganic materials 0.000 description 5
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
JFBZPFYRPYOZCQ-UHFFFAOYSA-N [Li].[Al] Chemical compound [Li].[Al] JFBZPFYRPYOZCQ-UHFFFAOYSA-N 0.000 description 4
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
238000004458 analytical method Methods 0.000 description 4
238000006243 chemical reaction Methods 0.000 description 4
239000002131 composite material Substances 0.000 description 4
230000006835 compression Effects 0.000 description 4
238000007906 compression Methods 0.000 description 4
238000010276 construction Methods 0.000 description 4
150000002367 halogens Chemical class 0.000 description 4
PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 description 4
239000011777 magnesium Substances 0.000 description 4
239000000463 material Substances 0.000 description 4
239000001103 potassium chloride Substances 0.000 description 4
235000011164 potassium chloride Nutrition 0.000 description 4
229910052719 titanium Inorganic materials 0.000 description 4
239000010936 titanium Substances 0.000 description 4
229910052720 vanadium Inorganic materials 0.000 description 4
229910010238 LiAlCl 4 Inorganic materials 0.000 description 3
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
230000001413 cellular effect Effects 0.000 description 3
230000007797 corrosion Effects 0.000 description 3
238000005260 corrosion Methods 0.000 description 3
239000013078 crystal Substances 0.000 description 3
238000004146 energy storage Methods 0.000 description 3
239000000446 fuel Substances 0.000 description 3
238000011065 in-situ storage Methods 0.000 description 3
231100000572 poisoning Toxicity 0.000 description 3
230000000607 poisoning effect Effects 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
230000036647 reaction Effects 0.000 description 3
229910052717 sulfur Inorganic materials 0.000 description 3
239000011593 sulfur Substances 0.000 description 3
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 3
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 3
INZDTEICWPZYJM-UHFFFAOYSA-N 1-(chloromethyl)-4-[4-(chloromethyl)phenyl]benzene Chemical compound C1=CC(CCl)=CC=C1C1=CC=C(CCl)C=C1 INZDTEICWPZYJM-UHFFFAOYSA-N 0.000 description 2
229910016467 AlCl 4 Inorganic materials 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
239000000010 aprotic solvent Substances 0.000 description 2
229910052786 argon Inorganic materials 0.000 description 2
229910052791 calcium Inorganic materials 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
230000015556 catabolic process Effects 0.000 description 2
229910001567 cementite Inorganic materials 0.000 description 2
GVEHJMMRQRRJPM-UHFFFAOYSA-N chromium(2+);methanidylidynechromium Chemical compound [Cr+2].[Cr]#[C-].[Cr]#[C-] GVEHJMMRQRRJPM-UHFFFAOYSA-N 0.000 description 2
239000010949 copper Substances 0.000 description 2
238000006731 degradation reaction Methods 0.000 description 2
150000002222 fluorine compounds Chemical class 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
229930195733 hydrocarbon Natural products 0.000 description 2
150000002430 hydrocarbons Chemical class 0.000 description 2
150000004694 iodide salts Chemical class 0.000 description 2
230000000670 limiting effect Effects 0.000 description 2
AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 description 2
229910001537 lithium tetrachloroaluminate Inorganic materials 0.000 description 2
HCQWRNRRURULEY-UHFFFAOYSA-L lithium;potassium;dichloride Chemical compound [Li+].[Cl-].[Cl-].[K+] HCQWRNRRURULEY-UHFFFAOYSA-L 0.000 description 2
239000002808 molecular sieve Substances 0.000 description 2
230000003647 oxidation Effects 0.000 description 2
238000007254 oxidation reaction Methods 0.000 description 2
229920001343 polytetrafluoroethylene Polymers 0.000 description 2
239000004810 polytetrafluoroethylene Substances 0.000 description 2
239000000843 powder Substances 0.000 description 2
230000008569 process Effects 0.000 description 2
239000011833 salt mixture Substances 0.000 description 2
238000000926 separation method Methods 0.000 description 2
FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 description 2
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 2
239000010935 stainless steel Substances 0.000 description 2
229910001220 stainless steel Inorganic materials 0.000 description 2
239000007858 starting material Substances 0.000 description 2
MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 description 2
229910052721 tungsten Inorganic materials 0.000 description 2
239000010937 tungsten Substances 0.000 description 2
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
229910019878 Cr3Si Inorganic materials 0.000 description 1
101100298295 Drosophila melanogaster flfl gene Proteins 0.000 description 1
MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical class [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
241001676573 Minium Species 0.000 description 1
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
238000002441 X-ray diffraction Methods 0.000 description 1
BCVDRWVZGWIKAM-UHFFFAOYSA-N [Cr+3].[Fe+2] Chemical compound [Cr+3].[Fe+2] BCVDRWVZGWIKAM-UHFFFAOYSA-N 0.000 description 1
CIHHRNQZUFCQRG-UHFFFAOYSA-L [Li+].[K+].[Br-].[Br-] Chemical compound [Li+].[K+].[Br-].[Br-] CIHHRNQZUFCQRG-UHFFFAOYSA-L 0.000 description 1
NRJQXKWCYLCOSW-UHFFFAOYSA-K [Li+].[Li+].[Li+].[F-].[Cl-].[Br-] Chemical compound [Li+].[Li+].[Li+].[F-].[Cl-].[Br-] NRJQXKWCYLCOSW-UHFFFAOYSA-K 0.000 description 1
CRYCBELFTGHLAD-UHFFFAOYSA-L [Li]F.[Li]Cl Chemical compound [Li]F.[Li]Cl CRYCBELFTGHLAD-UHFFFAOYSA-L 0.000 description 1
239000002253 acid Substances 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
239000013543 active substance Substances 0.000 description 1
239000000853 adhesive Substances 0.000 description 1
230000001070 adhesive effect Effects 0.000 description 1
230000002411 adverse Effects 0.000 description 1
150000008045 alkali metal halides Chemical class 0.000 description 1
229910001413 alkali metal ion Inorganic materials 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
239000002585 base Substances 0.000 description 1
150000003842 bromide salts Chemical class 0.000 description 1
239000001110 calcium chloride Substances 0.000 description 1
229910001628 calcium chloride Inorganic materials 0.000 description 1
WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 1
229910001634 calcium fluoride Inorganic materials 0.000 description 1
150000001722 carbon compounds Chemical class 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
JPNWDVUTVSTKMV-UHFFFAOYSA-N cobalt tungsten Chemical compound [Co].[W] JPNWDVUTVSTKMV-UHFFFAOYSA-N 0.000 description 1
238000000748 compression moulding Methods 0.000 description 1
230000001143 conditioned effect Effects 0.000 description 1
239000004020 conductor Substances 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
230000008878 coupling Effects 0.000 description 1
238000010168 coupling process Methods 0.000 description 1
238000005859 coupling reaction Methods 0.000 description 1
230000007547 defect Effects 0.000 description 1
238000013461 design Methods 0.000 description 1
238000009792 diffusion process Methods 0.000 description 1
238000010494 dissociation reaction Methods 0.000 description 1
230000005593 dissociations Effects 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
239000002019 doping agent Substances 0.000 description 1
239000007772 electrode material Substances 0.000 description 1
239000000374 eutectic mixture Substances 0.000 description 1
230000005496 eutectics Effects 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
230000002140 halogenating effect Effects 0.000 description 1
239000012535 impurity Substances 0.000 description 1
RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
CPFCQUVGQRHMCB-UHFFFAOYSA-N iron(2+);manganese(2+) Chemical compound [Mn+2].[Fe+2] CPFCQUVGQRHMCB-UHFFFAOYSA-N 0.000 description 1
239000010410 layer Substances 0.000 description 1
239000007788 liquid Substances 0.000 description 1
239000011244 liquid electrolyte Substances 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
LBEWFUFVQRYRPT-UHFFFAOYSA-L lithium rubidium(1+) difluoride Chemical compound [F-].[Rb+].[F-].[Li+] LBEWFUFVQRYRPT-UHFFFAOYSA-L 0.000 description 1
QNRUKMBLUVIEBO-UHFFFAOYSA-L lithium;magnesium;dichloride Chemical compound [Li+].[Mg+2].[Cl-].[Cl-] QNRUKMBLUVIEBO-UHFFFAOYSA-L 0.000 description 1
IEGSXYJGFBDOLI-UHFFFAOYSA-L lithium;potassium;diiodide Chemical compound [Li+].[K+].[I-].[I-] IEGSXYJGFBDOLI-UHFFFAOYSA-L 0.000 description 1
239000002932 luster Substances 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
229910001629 magnesium chloride Inorganic materials 0.000 description 1
239000011159 matrix material Substances 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
239000000155 melt Substances 0.000 description 1
150000005309 metal halides Chemical class 0.000 description 1
229910021404 metallic carbon Inorganic materials 0.000 description 1
JAGQSESDQXCFCH-UHFFFAOYSA-N methane;molybdenum Chemical compound C.[Mo].[Mo] JAGQSESDQXCFCH-UHFFFAOYSA-N 0.000 description 1
229910052750 molybdenum Inorganic materials 0.000 description 1
239000011733 molybdenum Substances 0.000 description 1
DDTIGTPWGISMKL-UHFFFAOYSA-N molybdenum nickel Chemical compound [Ni].[Mo] DDTIGTPWGISMKL-UHFFFAOYSA-N 0.000 description 1
239000002245 particle Substances 0.000 description 1
230000035515 penetration Effects 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
FFNMBRCFFADNAO-UHFFFAOYSA-N pirenzepine hydrochloride Chemical compound [H+].[H+].[Cl-].[Cl-].C1CN(C)CCN1CC(=O)N1C2=NC=CC=C2NC(=O)C2=CC=CC=C21 FFNMBRCFFADNAO-UHFFFAOYSA-N 0.000 description 1
239000004033 plastic Substances 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
238000000634 powder X-ray diffraction Methods 0.000 description 1
239000002243 precursor Substances 0.000 description 1
RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
239000011241 protective layer Substances 0.000 description 1
230000009467 reduction Effects 0.000 description 1
230000002829 reductive effect Effects 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
229910052706 scandium Inorganic materials 0.000 description 1
238000007790 scraping Methods 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
125000006850 spacer group Chemical group 0.000 description 1
239000010959 steel Substances 0.000 description 1
229910052715 tantalum Inorganic materials 0.000 description 1
GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
238000012546 transfer Methods 0.000 description 1
230000007704 transition Effects 0.000 description 1
150000003623 transition metal compounds Chemical class 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
239000010457 zeolite Substances 0.000 description 1

Classifications

- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/36—Accumulators not provided for in groups H01M10/05-H01M10/34
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/66—Selection of materials
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/66—Selection of materials
- H01M4/664—Ceramic materials
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries

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Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Electrochemistry (AREA)
General Chemical & Material Sciences (AREA)
Materials Engineering (AREA)
Ceramic Engineering (AREA)
Inorganic Chemistry (AREA)
Manufacturing & Machinery (AREA)
Secondary Cells (AREA)
Battery Electrode And Active Subsutance (AREA)

SE7907838A 1978-09-22 1979-09-21 Uppladdningsbar katod for en sekunder elektrokemisk energilagringscell samt forfarande for bildning av densamma SE444245B (sv)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
ZA785392A ZA785392B (en)	1978-09-22	1978-09-22	Cathode for an electrochemical cell,and an electrochemical cell
ZA791359		1979-03-21
ZA791739		1979-04-11

Publications (2)

Publication Number	Publication Date
SE7907838L SE7907838L (sv)	1980-03-23
SE444245B true SE444245B (sv)	1986-03-24

Family

ID=27420890

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SE7907838A SE444245B (sv)	1978-09-22	1979-09-21	Uppladdningsbar katod for en sekunder elektrokemisk energilagringscell samt forfarande for bildning av densamma

Country Status (8)

Country	Link
US (1)	US4288506A (it)
AU (1)	AU523792B2 (it)
BR (1)	BR7906061A (it)
CA (1)	CA1130821A (it)
DE (1)	DE2938252C2 (it)
GB (1)	GB2032167B (it)
IT (1)	IT1195740B (it)
SE (1)	SE444245B (it)

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ZA828603B (en) *	1981-12-10	1983-09-28	South African Inventions	Electrochemical cell
JPS59186253A (ja) *	1983-04-01	1984-10-23	インタ−ナショナル　ビジネス　マシ−ンズ　コ−ポレ−ション	電池の電極
GB8314235D0 (en) *	1983-05-23	1983-06-29	Ind Distributors Shannon Ltd	Electrochemical cell
GB8319749D0 (en) *	1983-07-22	1983-08-24	Ind Distributors Shannon Ltd	Electrochemical cell
AU566856B2 (en) *	1984-05-28	1987-10-29	Lilliwyte Societe Anonyme	Electrochemcial cell with fluoride in electrolyte
GB8423961D0 (en) *	1984-09-21	1984-10-31	Lilliwyte Sa	Electrochemical cells
US4650731A (en) *	1985-06-18	1987-03-17	The Dow Chemical Company	Electric current-producing cell and related composition
GB8523444D0 (en) *	1985-09-23	1985-10-30	Lilliwyte Sa	Electrochemical cell
GB8828829D0 (en) *	1988-12-09	1989-01-18	Lilliwyte Sa	Electrochemical cell
US5194343A (en) *	1990-10-09	1993-03-16	The United States Of America As Represented By The United States Department Of Energy	Method of electrode fabrication and an electrode for metal chloride battery
US5283135A (en) *	1991-10-10	1994-02-01	University Of Chicago	Electrochemical cell
US5536593A (en) *	1991-10-10	1996-07-16	Redey; Laszlo I.	Electrochemical cell
US5302473A (en) *	1992-07-20	1994-04-12	Westinghouse Electric Corp.	Current collector for electrochemical device
US6183896B1 (en) *	1993-05-11	2001-02-06	Agency Of Industrial Science And Technology	Solid oxide fuel cell and a carbon direct-oxidizing-type electrode for the fuel cell
US6468694B1 (en)	1997-03-27	2002-10-22	Millennium Cell, Inc.	High energy density boride batteries
AU750638B2 (en) *	1997-03-27	2002-07-25	Millennium Cell, Inc	High energy density boride batteries
US5948558A (en) *	1997-03-27	1999-09-07	National Patent Development Corporation	High energy density boride batteries
US6833217B2 (en) *	1997-12-31	2004-12-21	Duracell Inc.	Battery cathode
KR100276656B1 (ko)	1998-09-16	2001-04-02	박찬구	박막형 복합 재료 양극으로 구성된 고체형 이차 전지
WO2000051197A1 (en)	1999-02-26	2000-08-31	The Gillette Company	High performance alkaline battery
SG104277A1 (en) *	2001-09-24	2004-06-21	Inst Of Microelectronics	Circuit for measuring changes in capacitor gap using a switched capacitor technique
US7718319B2 (en)	2006-09-25	2010-05-18	Board Of Regents, The University Of Texas System	Cation-substituted spinel oxide and oxyfluoride cathodes for lithium ion batteries
WO2009154753A2 (en) *	2008-06-18	2009-12-23	Massachusetts Institute Of Technology	Catalytic materials, electrodes, and systems for water electrolysis and other electrochemical techniques
US8178231B2 (en) *	2009-09-24	2012-05-15	General Electric Company	Composition and energy storage device
US8343661B2 (en) *	2009-11-04	2013-01-01	General Electric Company	Cathode compositions comprising Zn and chalcogenide and energy storage cell comprising same
JP4846869B1 (ja) *	2010-09-07	2011-12-28	クロリンエンジニアズ株式会社	電解用陰極構造体およびそれを用いた電解槽
US8329336B2 (en)	2010-09-29	2012-12-11	General Electric Company	Composition and energy storage device
US8697279B2 (en)	2011-01-14	2014-04-15	General Electric Company	Composition and energy storage device
CN114715980B (zh) *	2022-04-01	2023-08-08	同济大学	一种活化过硫酸盐和o2协同降解全氟化合物的电化学方法

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DE1496176C3 (de) *	1964-06-12	1975-02-27	Licentia Patent-Verwaltungs-Gmbh, 6000 Frankfurt	Katalysatoren für Brennstoffelektroden von Brennstoffelementen mit saurem Elektrolyten
US3410730A (en) *	1966-01-03	1968-11-12	Standard Oil Co	Molybdenum-containing composite electrode
US3607402A (en) *	1969-10-29	1971-09-21	Standard Oil Co Ohio	Electrical energy storage device containing a silicon carbide electrode
US4041220A (en) *	1972-08-18	1977-08-09	Agence Nationale De Valorisation De La Recherche (Anvar)	Mixed conductors of graphite, processes for their preparation and their use, notably for the production of electrodes for electrochemical generators, and new electrochemical generators
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DE2659708A1 (de)	1976-12-31	1978-07-06	Hoechst Ag	Disazoverbindungen, verfahren zu ihrer herstellung und ihre verwendung als pigmente

1979
- 1979-09-05 US US06/072,762 patent/US4288506A/en not_active Expired - Lifetime
- 1979-09-11 AU AU50732/79A patent/AU523792B2/en not_active Ceased
- 1979-09-18 GB GB7932283A patent/GB2032167B/en not_active Expired
- 1979-09-18 CA CA335,814A patent/CA1130821A/en not_active Expired
- 1979-09-21 SE SE7907838A patent/SE444245B/sv not_active IP Right Cessation
- 1979-09-21 DE DE2938252A patent/DE2938252C2/de not_active Expired
- 1979-09-21 IT IT25928/79A patent/IT1195740B/it active
- 1979-09-21 BR BR7906061A patent/BR7906061A/pt not_active IP Right Cessation

Also Published As

Publication number	Publication date
GB2032167A (en)	1980-04-30
AU5073279A (en)	1980-03-27
DE2938252C2 (de)	1983-10-27
IT7925928A0 (it)	1979-09-21
IT1195740B (it)	1988-10-27
GB2032167B (en)	1983-02-09
AU523792B2 (en)	1982-08-12
SE7907838L (sv)	1980-03-23
DE2938252A1 (de)	1980-04-03
BR7906061A (pt)	1980-07-15
US4288506A (en)	1981-09-08
CA1130821A (en)	1982-08-31

Publication	Publication Date	Title
SE444245B (sv)	1986-03-24	Uppladdningsbar katod for en sekunder elektrokemisk energilagringscell samt forfarande for bildning av densamma
US7244530B2 (en)	2007-07-17	Rechargeable battery cell that is operated at normal temperatures
US10396404B2 (en)	2019-08-27	Electrochemical cell with bipolar faradaic membrane
AU2007338533B2 (en)	2012-05-03	Copper-based energy storage device and method
CA1058284A (en)	1979-07-10	Metallic sulfide additives for positive electrode material within a secondary electrochemical cell
US3751298A (en)	1973-08-07	Thermal, rechargeable electrochemical cell having lithium monoaluminide electrode and lithium tetrachloroaluminate electrolyte
Carlin et al.	1996	Electrochemistry of room-temperature chloroaluminate molten salts at graphitic and nongraphitic electrodes
SE453028B (sv)	1988-01-04	Elektrokemisk cell
US20020037452A1 (en)	2002-03-28	Novel compositions for use in batteries, capacitors, fuel cells and similar devices and for hydrogen production
JP2019526909A (ja)	2019-09-19	高温の反応性材料装置用シール
KR20070114323A (ko)	2007-11-30	용융염 조성물 및 이의 용도
Katagiri et al.	1991	Electrodeposition of Tungsten in ZnBr2‐NaBr and ZnCl2‐NaCl Melts
SE465143B (sv)	1991-07-29	Foerfarande foer framstaellning av utgaangsmaterial foer en elektrokemisk cell med smaelt elektrolyt samt utgaangsmaterial foer cellen
WO2016168727A1 (en)	2016-10-20	Sodium-aluminum battery with sodium ion conductive ceramic separator
US4064325A (en)	1977-12-20	Electric storage batteries
GB1592887A (en)	1981-07-08	Electrode for electrical energy storage device
CA1276907C (en)	1990-11-27	Refining of lithium-containing aluminum scrap
EP0159442A1 (en)	1985-10-30	Improved electrolyte for zinc-bromine batteries
US20110151289A1 (en)	2011-06-23	Energy storage device and associated method
US4145483A (en)	1979-03-20	Accumulators including halogen electrodes operating with fused halide based electrolytes
US20010046113A1 (en)	2001-11-29	Alloy Compositions for use as electrode materials and for hydrogen production
US4166156A (en)	1979-08-28	Secondary battery or cell with pyrolytic graphite coated graphite current collector
KR910001586B1 (ko)	1991-03-16	가역적 수소 저장을 위한 비정질 금속합금 조성물
WO2002000950A2 (en)	2002-01-03	Compositions for use as electrode materials and for hydrogen production
US20170324072A1 (en)	2017-11-09	Electrochemical Cell with Bipolar Faradaic Membrane

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