RU97110281A - FIRE-RESISTANT COVER FROM MILAMINE-FORMALDEHYDE RESIN FIBER - Google Patents
FIRE-RESISTANT COVER FROM MILAMINE-FORMALDEHYDE RESIN FIBERInfo
- Publication number
- RU97110281A RU97110281A RU97110281/25A RU97110281A RU97110281A RU 97110281 A RU97110281 A RU 97110281A RU 97110281/25 A RU97110281/25 A RU 97110281/25A RU 97110281 A RU97110281 A RU 97110281A RU 97110281 A RU97110281 A RU 97110281A
- Authority
- RU
- Russia
- Prior art keywords
- fire
- resistant
- fibers
- melamine resin
- carbon atoms
- Prior art date
Links
- 230000009970 fire resistant effect Effects 0.000 title claims 16
- 239000000835 fiber Substances 0.000 title claims 13
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Substances O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 title claims 7
- 239000011347 resin Substances 0.000 title 1
- 229920005989 resin Polymers 0.000 title 1
- 229920000877 Melamine resin Polymers 0.000 claims 14
- 239000004640 Melamine resin Substances 0.000 claims 10
- 125000004432 carbon atom Chemical group C* 0.000 claims 6
- 238000004519 manufacturing process Methods 0.000 claims 4
- 239000000203 mixture Substances 0.000 claims 4
- 239000004760 aramid Substances 0.000 claims 3
- 229920006231 aramid fiber Polymers 0.000 claims 3
- 150000007974 melamines Chemical class 0.000 claims 3
- 150000002989 phenols Chemical class 0.000 claims 3
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims 2
- 125000000217 alkyl group Chemical group 0.000 claims 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 2
- 229910052782 aluminium Inorganic materials 0.000 claims 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims 2
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 claims 1
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 claims 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims 1
- QUWAJPZDCZDTJS-UHFFFAOYSA-N 2-(2-hydroxyphenyl)sulfonylphenol Chemical class OC1=CC=CC=C1S(=O)(=O)C1=CC=CC=C1O QUWAJPZDCZDTJS-UHFFFAOYSA-N 0.000 claims 1
- 229920000297 Rayon Polymers 0.000 claims 1
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 1
- 125000004103 aminoalkyl group Chemical group 0.000 claims 1
- 238000000576 coating method Methods 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 238000009833 condensation Methods 0.000 claims 1
- 230000005494 condensation Effects 0.000 claims 1
- 239000011152 fibreglass Substances 0.000 claims 1
- 239000000945 filler Substances 0.000 claims 1
- 239000003063 flame retardant Substances 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims 1
- 238000006068 polycondensation reaction Methods 0.000 claims 1
- 210000002268 wool Anatomy 0.000 claims 1
Claims (12)
(A) от 90% до 100% мол. смеси, состоящей в основном из
(а) от 30 до 100% мол. меламина и
(б) от 0 до 10% мол. замещенного меламина общей формулы I
в которой X1, X2 и X3 выбраны из группы, состоящей из -NH2, NR1R2, и X1, X2 и X3 одновременно не обозначают -NH2, и R1 и R2 выбраны из группы, содержащей: гидроксиалкил с 2-20 атомами углерода, гидроксиалкил-(окса-алкил)n с 2-4 атомами углерода в алкильной части и с 2-4 атомами углерода в окса-алкильной части, причем n = от 1 до 5, а также аминоалкил с 2-12 атомами углерода или смеси меламинов формулы I, и
(B) от 0 до 10 мол.% в расчете на (A) и (B) незамещенного фенола или фенолов, замещенных остатками из группы: алкил с 1-9 атомами углерода и гидроксил, алканов с 1-4 атомами углерода, замещенных двумя или тремя фенольными группами, ди-(гидроксифенил)-сульфонов или смесей этих фенолов с формальдегидом или соединениями, выделяющими формальдегид, при этом мольное соотношение меламинов к формальдегиду находится в диапазоне от 1:1,15 до 1:4,5.2. The use of fibers of melamine resin for the manufacture of fire-resistant covers, characterized in that the fibers of melamine resin are obtained by condensation of a mixture containing as components
(A) from 90% to 100 mol%. mixture consisting mainly of
(a) from 30 to 100 mol%. melamine and
(b) from 0 to 10 mol%. substituted melamine of general formula I
wherein X 1 , X 2 and X 3 are selected from the group consisting of —NH 2 , NR 1 R 2 , and X 1 , X 2 and X 3 do not simultaneously represent —NH 2 , and R 1 and R 2 are selected from the group containing: hydroxyalkyl with 2-20 carbon atoms, hydroxyalkyl- (oxa-alkyl) n with 2-4 carbon atoms in the alkyl part and with 2-4 carbon atoms in the oxa-alkyl part, and n = from 1 to 5, and also aminoalkyl with 2-12 carbon atoms or a mixture of melamines of the formula I, and
(B) from 0 to 10 mol.% Based on (A) and (B) unsubstituted phenol or phenols, substituted by residues from the group: alkyl with 1-9 carbon atoms and hydroxyl, alkanes with 1-4 carbon atoms, substituted by two or three phenolic groups, di- (hydroxyphenyl) -sulfones or mixtures of these phenols with formaldehyde or compounds that release formaldehyde, while the molar ratio of melamines to formaldehyde is in the range from 1: 1.15 to 1: 4.5.
(а) от 5 до 95 вес.% волокон меламиновой смолы,
(б) от 95 до 5 вес.% огнестойких волокон, выбранной их группы, содержащей стекловолокна, огнестойкую шерсть, огнестойкую вискозу и арамидные волокна, и
(в) от 0 до 25 вес.% наполнителей,
при условии, что если в качестве компонента (б) используются исключительно арамидные волокна, количество компонента (в) не равно 0.4. Fire resistant covers containing
(a) from 5 to 95 wt.% fibers of melamine resin,
(b) from 95 to 5% by weight of flame retardant fibers selected from a group comprising fiberglass, flame resistant wool, fire resistant viscose and aramid fibers, and
(c) from 0 to 25% by weight of fillers,
provided that if only aramid fibers are used as component (b), the amount of component (c) is not equal to 0.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEP4440491.3 | 1994-11-12 |
Publications (1)
Publication Number | Publication Date |
---|---|
RU97110281A true RU97110281A (en) | 1999-05-20 |
Family
ID=
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2319239C2 (en) * | 2002-03-28 | 2008-03-10 | Милликен Энд Компани | Fire-resistant insert for fiber-optic cable conduit |
RU2350636C2 (en) * | 2003-12-19 | 2009-03-27 | Ами Агролинц Меламин Интернейшнл, Гмбх | Fire-retardant mixture for lignocellulose composites |
RU2554581C2 (en) * | 2010-09-16 | 2015-06-27 | Сянь Джей энд Ар Файер Файтинг Эквипмент Ко., Лтд. | Fire-extinguishing composition forming fire-extinguishing agent at high temperature decomposition |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2319239C2 (en) * | 2002-03-28 | 2008-03-10 | Милликен Энд Компани | Fire-resistant insert for fiber-optic cable conduit |
RU2350636C2 (en) * | 2003-12-19 | 2009-03-27 | Ами Агролинц Меламин Интернейшнл, Гмбх | Fire-retardant mixture for lignocellulose composites |
RU2554581C2 (en) * | 2010-09-16 | 2015-06-27 | Сянь Джей энд Ар Файер Файтинг Эквипмент Ко., Лтд. | Fire-extinguishing composition forming fire-extinguishing agent at high temperature decomposition |
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