RU96105992A - MICROPOROUS CRYSTALLINE SILICON POLYMPHOSPHATE, METHOD FOR ITS OBTAINING, USING R U W AS A CATALYST AND SORBENT - Google Patents
MICROPOROUS CRYSTALLINE SILICON POLYMPHOSPHATE, METHOD FOR ITS OBTAINING, USING R U W AS A CATALYST AND SORBENTInfo
- Publication number
- RU96105992A RU96105992A RU96105992/25A RU96105992A RU96105992A RU 96105992 A RU96105992 A RU 96105992A RU 96105992/25 A RU96105992/25 A RU 96105992/25A RU 96105992 A RU96105992 A RU 96105992A RU 96105992 A RU96105992 A RU 96105992A
- Authority
- RU
- Russia
- Prior art keywords
- source
- silica
- alumino
- sio
- weight
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims 5
- 239000003054 catalyst Substances 0.000 title claims 2
- 239000002594 sorbent Substances 0.000 title claims 2
- 229910021419 crystalline silicon Inorganic materials 0.000 title 1
- 229910019142 PO4 Inorganic materials 0.000 claims 4
- 239000000203 mixture Substances 0.000 claims 4
- 229910004298 SiO 2 Inorganic materials 0.000 claims 3
- 239000000463 material Substances 0.000 claims 3
- 239000010452 phosphate Substances 0.000 claims 3
- 238000001354 calcination Methods 0.000 claims 2
- 239000007791 liquid phase Substances 0.000 claims 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 1
- 238000002441 X-ray diffraction Methods 0.000 claims 1
- 230000002378 acidificating effect Effects 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 229910002026 crystalline silica Inorganic materials 0.000 claims 1
- 230000018044 dehydration Effects 0.000 claims 1
- 238000006297 dehydration reaction Methods 0.000 claims 1
- 238000003795 desorption Methods 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 238000001914 filtration Methods 0.000 claims 1
- 229910052734 helium Inorganic materials 0.000 claims 1
- 239000001307 helium Substances 0.000 claims 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims 1
- 239000004615 ingredient Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 150000002739 metals Chemical class 0.000 claims 1
- 238000002156 mixing Methods 0.000 claims 1
- 235000021317 phosphate Nutrition 0.000 claims 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 239000011574 phosphorus Substances 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- 235000012239 silicon dioxide Nutrition 0.000 claims 1
- 238000003786 synthesis reaction Methods 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
Claims (1)
Hx SixAlyPZ O2,
где x имеет значение между 0,005 и 0,1 и y и z имеют значения между 0,4 и 0,6, отличающийся тем, что продукт после обжига на воздухе при 550oC в течение 4 ч дает характерную рентгеновскую дифрактограмму, которая показана в таблице. vs = 90-100 m = 20-70 w = 5-19
2. Кремнеалюмофосфат по п.1, отличающийся тем, что он имеет кислотные свойства, которые иллюстрируются тем фактом, что > 0,1 ммоля NH3/г материала, сорбированного при комнатной температуре, десорбируется опять при температурах > 300oC при локальном максимуме десорбции, который находится выше 350oC, когда его нагревают в текучем гелии со скоростью 10oC/мин.1. Microporous crystalline silica aluminophosphate, the theoretical composition of which is anhydrous after synthesis and calcination, is
H x Si x Al y P Z O 2 ,
where x has a value between 0.005 and 0.1 and y and z have values between 0.4 and 0.6, characterized in that the product after calcination in air at 550 o C for 4 h gives a characteristic x-ray diffraction pattern, which is shown in the table. vs = 90-100 m = 20-70 w = 5-19
2. Silica-alumino-phosphate according to claim 1, characterized in that it has acidic properties, which are illustrated by the fact that> 0.1 mmol NH 3 / g of material adsorbed at room temperature is desorbed again at temperatures> 300 o C at a local maximum desorption, which is above 350 o C, when it is heated in flowing helium at a rate of 10 o C / min.
5. Способ получения кремнеалюмофосфатов со структурой AE1 из смеси реакционноспособных источников SiO2, Al2O3 и P2O5 и органического шаблонного материала, в котором смесь получают путем соединения по крайней мере одной доли источника Al и источника P в отсутствии источника Si и последующего смешивания образованной смеси с другими ингредиентами, после которого осуществлют сушку и обжиг, отличающийся тем, что источник алюминия смешивают с водой перед добавлением источника фосфора и тем, что после добавления источника кремния перед добавлением шаблонного материала из полученного геля удаляют значительную часть жидкой фазы.4. Silica-alumino-phosphate according to claim 1, characterized in that it has an AEl structure with channels of diameter
5. A method of producing silica-alumino phosphates with an AE1 structure from a mixture of reactive sources of SiO 2 , Al 2 O 3 and P 2 O 5 and an organic templating material, in which the mixture is obtained by combining at least one fraction of Al source and P source in the absence of a Si source subsequent mixing of the formed mixture with other ingredients, after which they will be dried and roasted, characterized in that the source of aluminum is mixed with water before adding the source of phosphorus and the fact that after adding a source of silicon before adding Ablon material obtained from gel removed a significant portion of the liquid phase.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NO932915 | 1993-08-17 | ||
| NO19932915A NO300012B1 (en) | 1993-08-17 | 1993-08-17 | Microporost crystalline silica aluminophosphate, process for the preparation thereof, and use thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU96105992A true RU96105992A (en) | 1998-06-10 |
| RU2116249C1 RU2116249C1 (en) | 1998-07-27 |
Family
ID=19896336
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU96105992A RU2116249C1 (en) | 1993-08-17 | 1994-07-22 | Microporous crystalline silicoalumphosphate, method of preparation thereof, catalyst, and sorbent |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US5609843A (en) |
| EP (1) | EP0714379B1 (en) |
| JP (1) | JP3371134B2 (en) |
| AU (1) | AU685491B2 (en) |
| CA (1) | CA2169766C (en) |
| DZ (1) | DZ1809A1 (en) |
| MY (1) | MY111120A (en) |
| NO (1) | NO300012B1 (en) |
| NZ (1) | NZ271459A (en) |
| RU (1) | RU2116249C1 (en) |
| WO (1) | WO1995005342A1 (en) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6040264A (en) * | 1996-04-04 | 2000-03-21 | Exxon Chemical Patents Inc. | Use of alkaline earth metal containing small pore non-zeolitic molecular sieve catalysts in oxygenate conversion |
| NO304108B1 (en) * | 1996-10-09 | 1998-10-26 | Polymers Holding As | A microporous silicoaluminophosphate composition, catalytic material comprising this composition and process for its preparation, and the use thereof to prepare olefins from methanol |
| US6162415A (en) * | 1997-10-14 | 2000-12-19 | Exxon Chemical Patents Inc. | Synthesis of SAPO-44 |
| US6051745A (en) * | 1999-03-04 | 2000-04-18 | Phillips Petroleum Company | Silicoaluminophosphate material, a method of making such improved material and the use thereof in the conversion of oxygenated hydrocarbons to olefins |
| DE60045157D1 (en) * | 1999-09-07 | 2010-12-09 | Lummus Technology Inc | INORGANIC OXIDES WITH MESOPOROSITY OR COMBINED MESO AND MICROPOROSITY AND METHOD FOR THEIR PREPARATION |
| US6812372B2 (en) | 2001-03-01 | 2004-11-02 | Exxonmobil Chemical Patents Inc. | Silicoaluminophosphate molecular sieve |
| US6953767B2 (en) | 2001-03-01 | 2005-10-11 | Exxonmobil Chemical Patents Inc. | Silicoaluminophosphate molecular sieve |
| US20050096214A1 (en) * | 2001-03-01 | 2005-05-05 | Janssen Marcel J. | Silicoaluminophosphate molecular sieve |
| US6685905B2 (en) * | 2001-12-21 | 2004-02-03 | Exxonmobil Chemical Patents Inc. | Silicoaluminophosphate molecular sieves |
| US6793901B2 (en) * | 2002-06-12 | 2004-09-21 | Exxonmobil Chemical Patents, Inc. | Synthesis of molecular sieves having the CHA framework type |
| CN100577564C (en) | 2003-12-23 | 2010-01-06 | 埃克森美孚化学专利公司 | Chabazite-type molecular sieves, their synthesis and their use in the conversion of oxygenates to olefins |
| EP1701913B1 (en) | 2003-12-23 | 2017-01-25 | ExxonMobil Chemical Patents Inc. | Chabazite-type molecular sieve and its synthesis method |
| US7166146B2 (en) * | 2003-12-24 | 2007-01-23 | Chevron U.S.A. Inc. | Mixed matrix membranes with small pore molecular sieves and methods for making and using the membranes |
| RU2254919C1 (en) * | 2004-02-05 | 2005-06-27 | ООО "Компания Катахим" | Hydrocarbon conversion catalyst and a method for preparation thereof |
| WO2005103204A2 (en) * | 2004-04-05 | 2005-11-03 | Exxonmobil Chemical Patents Inc. | Crystalline intergrowth material, its synthesis and its use in the conversion of oxygenates to olefins |
| US7090814B2 (en) * | 2004-11-10 | 2006-08-15 | Exxonmobil Chemical Patents Inc. | Method of synthesizing silicoaluminophosphate molecular sieves |
| US7754187B2 (en) | 2005-10-31 | 2010-07-13 | Exxonmobil Chemical Patents Inc. | Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins |
| WO2007053239A1 (en) | 2005-10-31 | 2007-05-10 | Exxonmobil Chemical Patents Inc. | Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins |
| WO2007130206A1 (en) | 2006-04-25 | 2007-11-15 | Exxonmobil Chemical Patents Inc. | Method of synthesizing aluminophosphate and silicoaluminophosphate molecular sieves |
| BRPI1011274B1 (en) | 2009-06-12 | 2019-04-24 | Albemarle Europe Sprl | CATALYSTALS OF FROG MOLECULAR FEATHERS AND THEIR PRODUCTION PROCESSES |
| KR102264058B1 (en) * | 2013-03-15 | 2021-06-11 | 존슨 맛쎄이 퍼블릭 리미티드 컴파니 | Catalyst for treating exhaust gas |
| JP6332913B2 (en) * | 2013-05-13 | 2018-05-30 | ポリプラスチックス株式会社 | Solid phosphoric acid catalyst and method for producing trioxane using the same |
| JP6513652B2 (en) * | 2013-10-31 | 2019-05-15 | ジョンソン、マッセイ、パブリック、リミテッド、カンパニーＪｏｈｎｓｏｎ Ｍａｔｔｈｅｙ Ｐｕｂｌｉｃ Ｌｉｍｉｔｅｄ Ｃｏｍｐａｎｙ | Synthesis of AEI zeolite |
| US9550178B2 (en) * | 2014-08-05 | 2017-01-24 | Sabic Global Technologies B.V. | Stable silicoaluminophosphate catalysts for conversion of alkyl halides to olefins |
| BR112017003715A2 (en) | 2014-08-22 | 2017-12-05 | Grace W R & Co | method for synthesizing silicoaluminophosphate-34 molecular sieves using amine monoisopropanol |
| JP2017036204A (en) * | 2015-08-13 | 2017-02-16 | 東ソー株式会社 | Method for producing AEI type zeolite |
| CN114014337B (en) | 2022-01-05 | 2022-03-15 | 中汽研（天津）汽车工程研究院有限公司 | AEI-CHA intergrowth molecular sieve and catalyst thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4310440A (en) * | 1980-07-07 | 1982-01-12 | Union Carbide Corporation | Crystalline metallophosphate compositions |
| US4440871A (en) * | 1982-07-26 | 1984-04-03 | Union Carbide Corporation | Crystalline silicoaluminophosphates |
| NO174341B1 (en) * | 1991-12-23 | 1994-04-21 | Polymers Holding As | Prepare foremost crystalline microporosis SiAl phosphates with controlled Si content, crystalline microporosis SiAl phosphates with improved stability against deactivation and use thereof in the preparation of olefins from methanol |
-
1993
- 1993-08-17 NO NO19932915A patent/NO300012B1/en not_active IP Right Cessation
-
1994
- 1994-07-22 RU RU96105992A patent/RU2116249C1/en not_active IP Right Cessation
- 1994-07-22 NZ NZ271459A patent/NZ271459A/en not_active IP Right Cessation
- 1994-07-22 US US08/591,657 patent/US5609843A/en not_active Expired - Lifetime
- 1994-07-22 AU AU75094/94A patent/AU685491B2/en not_active Ceased
- 1994-07-22 CA CA002169766A patent/CA2169766C/en not_active Expired - Fee Related
- 1994-07-22 WO PCT/NO1994/000130 patent/WO1995005342A1/en active IP Right Grant
- 1994-07-22 JP JP50687895A patent/JP3371134B2/en not_active Expired - Fee Related
- 1994-07-22 EP EP94925034A patent/EP0714379B1/en not_active Expired - Lifetime
- 1994-08-02 MY MYPI94002009A patent/MY111120A/en unknown
- 1994-08-16 DZ DZ940096A patent/DZ1809A1/en active
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