RU2244987C2 - Water-activated current supply anode - Google Patents
Water-activated current supply anode Download PDFInfo
- Publication number
- RU2244987C2 RU2244987C2 RU2003105559/09A RU2003105559A RU2244987C2 RU 2244987 C2 RU2244987 C2 RU 2244987C2 RU 2003105559/09 A RU2003105559/09 A RU 2003105559/09A RU 2003105559 A RU2003105559 A RU 2003105559A RU 2244987 C2 RU2244987 C2 RU 2244987C2
- Authority
- RU
- Russia
- Prior art keywords
- gallium
- water
- magnesium
- thallium
- content
- Prior art date
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 6
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 13
- 239000000956 alloy Substances 0.000 claims abstract description 13
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052733 gallium Inorganic materials 0.000 claims abstract description 11
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052716 thallium Inorganic materials 0.000 claims abstract description 10
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000011777 magnesium Substances 0.000 claims abstract description 9
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 8
- 229910000861 Mg alloy Inorganic materials 0.000 claims description 5
- 229910001007 Tl alloy Inorganic materials 0.000 claims description 2
- 229910000807 Ga alloy Inorganic materials 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 4
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 6
- 229910052753 mercury Inorganic materials 0.000 description 6
- 229910052793 cadmium Inorganic materials 0.000 description 3
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 239000013535 sea water Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000010405 anode material Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- Y02E60/12—
Landscapes
- Battery Electrode And Active Subsutance (AREA)
Abstract
Description
Изобретение относится к химическим источникам тока и может быть использовано при изготовлении резервных элементов, активируемых морской водой.The invention relates to chemical current sources and can be used in the manufacture of backup elements activated by sea water.
Известны химические источники тока одноразового действия, активируемые морской водой. В качестве анодного материала используются сплавы на базе магния с различными добавками, в том числе и с ртутью (см. Патент США №3.288.649).Known chemical sources of single-acting current activated by sea water. Magnesium-based alloys with various additives, including mercury, are used as the anode material (see US Pat. No. 3,288,649).
Однако ртутьсодержащие магниевые сплавы обладают существенными недостатками, заключающимися в необходимости использовать плакировку при прокатке тонких листов и последующем ее удалении и снятии интерметаллида алюминия с магнием, неизбежно образуемого при прокатке. Кроме того, технология использования ртути (при приготовлении сплава и удалении интерметаллида) представляет экологическую опасность.However, mercury-containing magnesium alloys have significant drawbacks in the need to use cladding when rolling thin sheets and then removing and removing the intermetallic aluminum with magnesium, which is inevitably formed during rolling. In addition, the use of mercury (in the preparation of the alloy and the removal of intermetallic) is an environmental hazard.
В качестве прототипа взят патент Англии №1251223 от 09.08.1968 "Электрические аккумуляторы и сплавы для них".As a prototype taken the patent of England No. 1251223 from 08/09/1968 "Electric batteries and alloys for them."
Известный сплав на базе магния состоит из:Known magnesium based alloy consists of:
таллия от 1 до 15% вес.thallium from 1 to 15% weight.
алюминия от 0 до 10% вес.aluminum from 0 to 10% weight.
ртути от 0 до 5% вес.mercury from 0 to 5% weight.
свинца от 0 до 5% вес.lead from 0 to 5% weight.
цинка от 0 до 3% вес.zinc from 0 to 3% weight.
марганца от 0 до 1% вес.manganese from 0 to 1% weight.
кальция от 0 до 1% вес.calcium from 0 to 1% weight.
кадмия от 0 до 1% вес.cadmium from 0 to 1% weight.
магния, по меньшей мере, 80% вес.magnesium, at least 80% by weight.
Недостатками известного сплава являются:The disadvantages of the known alloy are:
- анод на основе указанного сплава требует обработки специальным раствором, чтобы получить однородную структуру, что существенным образом усложняет технологический процесс изготовления водоактивируемых источников тока;- the anode based on the specified alloy requires processing with a special solution to obtain a homogeneous structure, which significantly complicates the manufacturing process of water-activated current sources;
- высокое содержание таллия (до 15%) приводит к удорожанию сплава;- high thallium content (up to 15%) leads to an increase in the cost of the alloy;
- наличие значительного количества свинца, кадмия, ртути и других металлов ухудшает экологию выплавки сплава;- the presence of a significant amount of lead, cadmium, mercury and other metals affects the ecology of alloy smelting;
- затруднена утилизация отработанных продуктов;- difficult disposal of waste products;
- усложнена технология получения сплава и высока себестоимость конечного продукта.- complicated technology for producing the alloy and high cost of the final product.
Задача, на решение которой направлено предлагаемое изобретение, является получение анодного сплава, исключающего при его изготовлении использование экологически вредных металлов (ртуть, кадмий, свинец и др.) и создание, таким образом, упрощенной и более экологически безопасной технологии.The problem to which the invention is directed is to obtain an anodic alloy, which excludes the use of environmentally harmful metals (mercury, cadmium, lead, etc.) during its manufacture and thus creates a simplified and more environmentally friendly technology.
Поставленная задача решается тем, что в сплав магния и таллия дополнительно введен галлий, при этом отношение суммарного содержания таллия и галлия к содержанию магния составляет 0,08-0,1.The problem is solved by the fact that gallium is additionally introduced into the magnesium and thallium alloy, while the ratio of the total content of thallium and gallium to the magnesium content is 0.08-0.1.
Пример 1Example 1
Сплав магния с таллием и галлием, в котором содержание таллия составляет 7%, галлия 2%.An alloy of magnesium with thallium and gallium, in which the thallium content is 7%, gallium 2%.
Пример 2Example 2
Сплав магния с таллием и галлием, в котором содержание таллия составляет 7%, галлия 0,5%.An alloy of magnesium with thallium and gallium, in which the thallium content is 7%, gallium 0.5%.
Разработана технология предлагаемого сплава. Анод, изготовленный из заявляемых ингредиентов с указанным их соотношением в составе водоактивируемого источника тока, позволил повысить его разрядные характеристики.The technology of the proposed alloy is developed. The anode made from the claimed ingredients with their indicated ratio in the composition of the water-activated current source, allowed to increase its discharge characteristics.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| RU2003105559/09A RU2244987C2 (en) | 2003-02-28 | 2003-02-28 | Water-activated current supply anode |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| RU2003105559/09A RU2244987C2 (en) | 2003-02-28 | 2003-02-28 | Water-activated current supply anode |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2003105559A RU2003105559A (en) | 2004-12-10 |
| RU2244987C2 true RU2244987C2 (en) | 2005-01-20 |
Family
ID=34978441
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2003105559/09A RU2244987C2 (en) | 2003-02-28 | 2003-02-28 | Water-activated current supply anode |
Country Status (1)
| Country | Link |
|---|---|
| RU (1) | RU2244987C2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2316080C1 (en) * | 2006-07-03 | 2008-01-27 | ОАО "Аккумуляторная компания "Ригель" | Water-activated current supply |
| RU2326469C1 (en) * | 2007-03-07 | 2008-06-10 | Федеральное государственное унитарное предприятие "Государственный научно-исследовательский и проектный институт редкометаллической промышленности "Гиредмет" | Method of alloy preparation on basis of magnesium for anodes of water activated chemical sources of current |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1251223A (en) * | 1968-08-09 | 1971-10-27 | ||
| US4613386A (en) * | 1984-01-26 | 1986-09-23 | The Dow Chemical Company | Method of making corrosion resistant magnesium and aluminum oxyalloys |
| EP0200327A2 (en) * | 1985-04-02 | 1986-11-05 | The Standard Oil Company | Improved double layer capacitors |
| RU2046457C1 (en) * | 1992-07-15 | 1995-10-20 | Акционерное общество "Балтэлектро" | Water-activated chemical source of electric energy |
| US6265109B1 (en) * | 1998-06-02 | 2001-07-24 | Matsushita Electric Industrial Co., Ltd. | Magnesium alloy battery |
-
2003
- 2003-02-28 RU RU2003105559/09A patent/RU2244987C2/en not_active IP Right Cessation
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1251223A (en) * | 1968-08-09 | 1971-10-27 | ||
| US4613386A (en) * | 1984-01-26 | 1986-09-23 | The Dow Chemical Company | Method of making corrosion resistant magnesium and aluminum oxyalloys |
| EP0200327A2 (en) * | 1985-04-02 | 1986-11-05 | The Standard Oil Company | Improved double layer capacitors |
| RU2046457C1 (en) * | 1992-07-15 | 1995-10-20 | Акционерное общество "Балтэлектро" | Water-activated chemical source of electric energy |
| US6265109B1 (en) * | 1998-06-02 | 2001-07-24 | Matsushita Electric Industrial Co., Ltd. | Magnesium alloy battery |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2316080C1 (en) * | 2006-07-03 | 2008-01-27 | ОАО "Аккумуляторная компания "Ригель" | Water-activated current supply |
| RU2326469C1 (en) * | 2007-03-07 | 2008-06-10 | Федеральное государственное унитарное предприятие "Государственный научно-исследовательский и проектный институт редкометаллической промышленности "Гиредмет" | Method of alloy preparation on basis of magnesium for anodes of water activated chemical sources of current |
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|---|---|---|---|
| MM4A | The patent is invalid due to non-payment of fees |
Effective date: 20130301 |