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RU2019143951A - Двухкомпонентные клеевые композиции, не содержащие растворителей - Google Patents

Двухкомпонентные клеевые композиции, не содержащие растворителей Download PDF

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Publication number
RU2019143951A
RU2019143951A RU2019143951A RU2019143951A RU2019143951A RU 2019143951 A RU2019143951 A RU 2019143951A RU 2019143951 A RU2019143951 A RU 2019143951A RU 2019143951 A RU2019143951 A RU 2019143951A RU 2019143951 A RU2019143951 A RU 2019143951A
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RU
Russia
Prior art keywords
component
adhesive composition
isocyanate
phosphoric acid
free adhesive
Prior art date
Application number
RU2019143951A
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English (en)
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RU2019143951A3 (ru
Inventor
Вэньвэнь ЛИ
Иньчжун ГО
Май ЧЭНЬ
Original Assignee
Дау Глоубл Текнолоджиз Ллк
Ром Энд Хаас Компани
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Application filed by Дау Глоубл Текнолоджиз Ллк, Ром Энд Хаас Компани filed Critical Дау Глоубл Текнолоджиз Ллк
Publication of RU2019143951A publication Critical patent/RU2019143951A/ru
Publication of RU2019143951A3 publication Critical patent/RU2019143951A3/ru

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    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C08G18/7671—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
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  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
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Claims (10)

1. Двухкомпонентная клеевая композиция, не содержащая растворителей, содержащая изоцианатный компонент, содержащий форполимер с концевыми изоцианатными группами; и изоцианат-активный компонент, содержащий полиуретановую смолу с концевыми гидроксильными группами; полиэфирполиол; усилитель адгезии на основе сложного эфира фосфорной кислоты; и необязательно, биополиол.
2. Двухкомпонентная клеевая композиция, не содержащая растворителей, по п. 1, отличающаяся тем, что полиуретановая смола с концевыми гидроксильными группами в изоцианат-активном компоненте представляет собой продукт реакции полиизоцианата и полиольного компонента.
3. Двухкомпонентная клеевая композиция, не содержащая растворителей, по п. 2, отличающаяся тем, что полиизоцианат представляет собой 4,4'-метилендифенилдиизоцианат.
4. Двухкомпонентная клеевая композиция, не содержащая растворителей, по п. 1, отличающаяся тем, что сложный эфир фосфорной кислоты получен из трифункционального пропиленгликоля, полифосфорной кислоты и полиизоцианата, причем содержание фосфорной кислоты в этом сложном эфире фосфорной кислоты составляет менее 3% мас. в расчете на массу сложного эфира фосфорной кислоты.
5. Двухкомпонентная клеевая композиция, не содержащая растворителей, по п. 1, отличающаяся тем, что усилитель адгезии на основе сложного эфира фосфорной кислоты составляет от 0,5 до 15% от общей массы изоцианат-активного компонента.
6. Двухкомпонентная клеевая композиция, не содержащая растворителей, по п. 1, отличающаяся тем, что биополиол составляет от 0 до 50% от общей массы изоцианат-активного компонента.
7. Двухкомпонентная клеевая композиция, не содержащая растворителей, по п. 1, отличающаяся тем, что биополиол представляет собой касторовое масло.
8. Двухкомпонентная клеевая композиция, не содержащая растворителей, по п. 1, отличающаяся тем, что мольное отношение групп NCO, присутствующих в изоцианатном компоненте, к группам OH, присутствующим в изоцианат-активном компоненте, составляет от 0,8 до 1,6.
9. Слоистая структура, содержащая двухкомпонентную клеевую композицию, не содержащую растворителей, по любому предшествующему или последующему пункту.
10. Способ получения слоистой структуры, включающий формирование клеевой композиции путем смешивания изоцианатного клеевого компонента, содержащего форполимер с концевыми изоцианатными группами, и изоцианат-активного клеевого компонента, содержащего полиуретановую смолу с концевыми гидроксильными группами, простой полиэфирполиол, усилитель адгезии на основе сложного эфира фосфорной кислоты и, необязательно, биополиол; нанесение клеевой композиции на поверхность первого субстрата; и приведение поверхности второго субстрата в контакт с клеевой композицией на поверхности первого субстрата, что приводит к формированию слоистой структуры.
RU2019143951A 2017-05-30 2018-04-04 Двухкомпонентные клеевые композиции, не содержащие растворителей RU2019143951A (ru)

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TWI853000B (zh) * 2019-03-05 2024-08-21 美商陶氏全球科技有限責任公司 ２組分無溶劑的粘合劑組合物、層壓體及形成２組分無溶劑的粘合劑組合物的方法
TWI846820B (zh) * 2019-03-05 2024-07-01 美商陶氏全球科技有限責任公司 雙組分無溶劑黏著劑組合物
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