RU2015129019A - Способ получения гидрированного воска - Google Patents
Способ получения гидрированного воска Download PDFInfo
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- RU2015129019A RU2015129019A RU2015129019A RU2015129019A RU2015129019A RU 2015129019 A RU2015129019 A RU 2015129019A RU 2015129019 A RU2015129019 A RU 2015129019A RU 2015129019 A RU2015129019 A RU 2015129019A RU 2015129019 A RU2015129019 A RU 2015129019A
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- RU
- Russia
- Prior art keywords
- stage
- hydrotreating
- hydrocracking
- temperature
- hydrocracking catalyst
- Prior art date
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- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims 2
- 239000001257 hydrogen Substances 0.000 title claims 2
- 229910052739 hydrogen Inorganic materials 0.000 title claims 2
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000000034 method Methods 0.000 claims 15
- 238000004517 catalytic hydrocracking Methods 0.000 claims 11
- 239000003054 catalyst Substances 0.000 claims 10
- 229930195733 hydrocarbon Natural products 0.000 claims 10
- 150000002430 hydrocarbons Chemical class 0.000 claims 10
- 239000004215 Carbon black (E152) Substances 0.000 claims 5
- 238000009835 boiling Methods 0.000 claims 5
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims 5
- 229910021536 Zeolite Inorganic materials 0.000 claims 4
- 239000010457 zeolite Substances 0.000 claims 4
- 229910052751 metal Inorganic materials 0.000 claims 2
- 239000002184 metal Substances 0.000 claims 2
- 150000002739 metals Chemical class 0.000 claims 2
- 230000000737 periodic effect Effects 0.000 claims 2
- 229910000323 aluminium silicate Inorganic materials 0.000 claims 1
- 230000003197 catalytic effect Effects 0.000 claims 1
- 239000007789 gas Substances 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M101/00—Lubricating compositions characterised by the base-material being a mineral or fatty oil
- C10M101/02—Petroleum fractions
- C10M101/025—Petroleum fractions waxes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/12—Silica and alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/882—Molybdenum and cobalt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/888—Tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/076—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/16—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J29/166—Y-type faujasite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/20—Sulfiding
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
- C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
- C10G47/12—Inorganic carriers
- C10G47/16—Crystalline alumino-silicate carriers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
- C10G65/12—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including cracking steps and other hydrotreatment steps
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G73/00—Recovery or refining of mineral waxes, e.g. montan wax
- C10G73/42—Refining of petroleum waxes
- C10G73/44—Refining of petroleum waxes in the presence of hydrogen or hydrogen-generating compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/30—Physical properties of feedstocks or products
- C10G2300/301—Boiling range
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Claims (19)
1. Способ получения гидрированного воска, который включает в себя стадии:
(a) получения углеводородного сырья, которое содержит больше чем 4 мас. % углеводородов, выкипающих от 550 до 800°С;
(b) гидроочистки углеводородного сырья с использованием катализатора гидроочистки в присутствии водородсодержащего газа в условиях гидроочистки, чтобы получить продукт гидроочистки;
(c) гидрокрекинг, по меньшей мере, части продукта гидроочистки, полученного на стадии (b), под действием катализатора гидрокрекинга в присутствии водородсодержащего газа в условиях гидрокрекинга, чтобы получить продукт гидрокрекинга, причем катализатор гидрокрекинга содержит цеолитный компонент, который присутствует в количестве, по меньшей мере, 14 мас.%, в расчете на общую массу катализатора гидрокрекинга, и объемное отношение катализатора гидроочистки, используемого на стадии (b), и катализатора гидрокрекинга составляет больше, чем 1; и
(d) извлечения гидрированного воска из продукта гидрокрекинга, полученного на стадии (c).
2. Способ по п. 1, в котором углеводородное сырье, полученное на стадии (а), содержит больше чем 8 мас.% углеводородов, выкипающих при температуре от 550 до 800°С.
3. Способ по п. 1 или 2, в котором углеводородное сырье, полученное на стадии (а), содержит между 8 и 30 мас.% углеводородов, выкипающих при температуре от 560 до 800°С.
4. Способ по п. 1 или 2, в котором в углеводородном сырье, полученном на стадии (а), отношение фракции углеводородов, выкипающих при температуре от 370 до 543°С, к фракции углеводородов, выкипающих при температуре от 550 до 800°С, составляет меньше чем 25.
5. Способ по п. 1 или 2, в котором цеолитный компонент в катализаторе гидрокрекинга присутствует в количестве от 18 до 30% в расчете на общую массу катализатора гидрокрекинга.
6. Способ по п. 5, в котором цеолитный компонент содержит цеолит Y.
7. Способ по п. 6, в котором цеолит имеет отношение Si/Al от 8 до 50.
8. Способ по п. 1 или 2, в котором катализатор гидрокрекинга дополнительно содержит аморфный алюмосиликат в количестве, меньшем чем 50% в расчете на общую массу катализатора гидрокрекинга.
9. Способ по п. 1 или 2, в котором условия гидроочистки на стадии (b) включают температуру от 250 до 480°С, давление от 30 до 250 бар и часовую массовую скорость подачи сырья от 0,2 до 10 ч-1.
10. Способ по п. 1 или 2, в котором условия гидрокрекинга на стадии (с) включают температуру от 350 до 460°С, давление от 80 до 240 бар и часовую массовую скорость подачи сырья от 0,4 до 7 ч-1.
11. Способ по п. 1 или 2, в котором весь продукт гидроочистки, полученный на стадии (b), подвергают гидрокрекингу на стадии (с).
12. Способ по п. 1 или 2, в котором, по меньшей мере, часть продукта гидрокрекинга, полученного на стадии (с), рециркулируют на стадию (b).
13. Способ по п. 1 или 2, в котором катализатор гидроочистки, используемый на стадии (b), содержит один или несколько металлов из групп VB, VIB и/или VIII периодической системы элементов, на твердом носителе.
14. Способ по п. 1 или 2, в котором катализатор гидрокрекинга, используемый на стадии (с), содержит один или несколько металлов из групп VIB и/или VIII периодической системы элементов.
15. Способ по п. 1 или 2, в котором гидрированный воск, извлеченный на стадии (d), обрабатывают на стадии каталитической депарафинизации и стадии гидроочистки.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP12197603.9 | 2012-12-17 | ||
| EP12197603 | 2012-12-17 | ||
| PCT/EP2013/076837 WO2014095813A1 (en) | 2012-12-17 | 2013-12-17 | Process for preparing a hydrowax |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2015129019A true RU2015129019A (ru) | 2017-01-23 |
| RU2674703C2 RU2674703C2 (ru) | 2018-12-12 |
Family
ID=47427246
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2015129019A RU2674703C2 (ru) | 2012-12-17 | 2013-12-17 | Способ получения гидрированного воска |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US10590361B2 (ru) |
| EP (1) | EP2931848A1 (ru) |
| RU (1) | RU2674703C2 (ru) |
| WO (1) | WO2014095813A1 (ru) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL2150557T3 (pl) | 2007-05-03 | 2016-12-30 | Produkt zawierający monomer i polimery tytanyli i sposoby ich wytwarzania | |
| US9828557B2 (en) | 2010-09-22 | 2017-11-28 | Auterra, Inc. | Reaction system, methods and products therefrom |
| TW201629193A (zh) * | 2014-12-17 | 2016-08-16 | 奧特拉有限公司 | 烴產物 |
| US10246647B2 (en) | 2015-03-26 | 2019-04-02 | Auterra, Inc. | Adsorbents and methods of use |
| EP3400188A4 (en) * | 2016-01-06 | 2019-08-07 | Oren Technologies, LLC | CONVEYOR WITH INTEGRATED DUST COLLECTOR SYSTEM |
| EP3411459A1 (en) | 2016-02-05 | 2018-12-12 | SABIC Global Technologies B.V. | Process and installation for the conversion of crude oil to petrochemicals having an improved product yield |
| US10450516B2 (en) | 2016-03-08 | 2019-10-22 | Auterra, Inc. | Catalytic caustic desulfonylation |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4435275A (en) * | 1982-05-05 | 1984-03-06 | Mobil Oil Corporation | Hydrocracking process for aromatics production |
| AU587032B2 (en) * | 1985-06-21 | 1989-08-03 | Mobil Oil Corporation | Hydrocracking process usung zeolite beta |
| GB8629476D0 (en) * | 1986-12-10 | 1987-01-21 | Shell Int Research | Manufacture of lubricating base oils |
| GB8722839D0 (en) * | 1987-09-29 | 1987-11-04 | Shell Int Research | Hydrocracking of hydrocarbon feedstock |
| US5139647A (en) | 1989-08-14 | 1992-08-18 | Chevron Research And Technology Company | Process for preparing low pour middle distillates and lube oil using a catalyst containing a silicoaluminophosphate molecular sieve |
| US5282958A (en) | 1990-07-20 | 1994-02-01 | Chevron Research And Technology Company | Use of modified 5-7 a pore molecular sieves for isomerization of hydrocarbons |
| JP2942629B2 (ja) | 1990-07-20 | 1999-08-30 | シェブロン リサーチ アンド テクノロジー カンパニー | 特殊気孔形態を有する触媒を用いたワックスの異性化 |
| EP0697455B1 (en) | 1994-07-22 | 2001-09-19 | Shell Internationale Research Maatschappij B.V. | Process for producing a hydrowax |
| FR2778345B1 (fr) * | 1998-05-06 | 2000-11-24 | Inst Francais Du Petrole | Catalyseur a base de zeolithe y contenant du bore et/ou du silicium, utilisable en hydrocraquage |
| RU2235115C2 (ru) | 1998-11-16 | 2004-08-27 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Способ каталитической депарафинизации и каталитическая композиция для его осуществления |
| US7794585B2 (en) * | 2007-10-15 | 2010-09-14 | Uop Llc | Hydrocarbon conversion process |
| US8066867B2 (en) * | 2008-11-10 | 2011-11-29 | Uop Llc | Combination of mild hydrotreating and hydrocracking for making low sulfur diesel and high octane naphtha |
-
2013
- 2013-12-17 WO PCT/EP2013/076837 patent/WO2014095813A1/en active Application Filing
- 2013-12-17 US US14/652,224 patent/US10590361B2/en active Active
- 2013-12-17 RU RU2015129019A patent/RU2674703C2/ru active
- 2013-12-17 EP EP13820752.7A patent/EP2931848A1/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| US20150322364A1 (en) | 2015-11-12 |
| WO2014095813A1 (en) | 2014-06-26 |
| RU2674703C2 (ru) | 2018-12-12 |
| EP2931848A1 (en) | 2015-10-21 |
| US10590361B2 (en) | 2020-03-17 |
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