RU2010145022A - METHOD OF WORK OF GAS-TURBINE INSTALLATION - Google Patents
METHOD OF WORK OF GAS-TURBINE INSTALLATION Download PDFInfo
- Publication number
- RU2010145022A RU2010145022A RU2010145022/06A RU2010145022A RU2010145022A RU 2010145022 A RU2010145022 A RU 2010145022A RU 2010145022/06 A RU2010145022/06 A RU 2010145022/06A RU 2010145022 A RU2010145022 A RU 2010145022A RU 2010145022 A RU2010145022 A RU 2010145022A
- Authority
- RU
- Russia
- Prior art keywords
- methane
- catalytic reactor
- gas
- pressure steam
- gas mixture
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract 14
- 238000009434 installation Methods 0.000 title claims abstract 5
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract 40
- 239000007789 gas Substances 0.000 claims abstract 18
- 238000002485 combustion reaction Methods 0.000 claims abstract 13
- 239000000203 mixture Substances 0.000 claims abstract 12
- 230000003197 catalytic effect Effects 0.000 claims abstract 11
- 239000003345 natural gas Substances 0.000 claims abstract 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract 6
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims abstract 6
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract 6
- 238000010438 heat treatment Methods 0.000 claims abstract 5
- 230000015572 biosynthetic process Effects 0.000 claims abstract 4
- 238000001704 evaporation Methods 0.000 claims abstract 4
- 230000008020 evaporation Effects 0.000 claims abstract 4
- 238000013021 overheating Methods 0.000 claims abstract 4
- 239000003054 catalyst Substances 0.000 claims abstract 3
- 238000006243 chemical reaction Methods 0.000 claims abstract 3
- 150000001875 compounds Chemical class 0.000 claims abstract 3
- 229910052741 iridium Inorganic materials 0.000 claims abstract 3
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims abstract 3
- 229910052742 iron Inorganic materials 0.000 claims abstract 3
- 229910052751 metal Inorganic materials 0.000 claims abstract 3
- 239000002184 metal Substances 0.000 claims abstract 3
- 150000002739 metals Chemical class 0.000 claims abstract 3
- 229910052759 nickel Inorganic materials 0.000 claims abstract 3
- 229910052763 palladium Inorganic materials 0.000 claims abstract 3
- 229910052697 platinum Inorganic materials 0.000 claims abstract 3
- 238000009833 condensation Methods 0.000 claims abstract 2
- 230000005494 condensation Effects 0.000 claims abstract 2
- 238000001816 cooling Methods 0.000 claims abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 2
- 239000001257 hydrogen Substances 0.000 claims 2
- 238000002156 mixing Methods 0.000 claims 1
- 150000003464 sulfur compounds Chemical class 0.000 claims 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
- F02C3/00—Gas-turbine plants characterised by the use of combustion products as the working fluid
- F02C3/34—Gas-turbine plants characterised by the use of combustion products as the working fluid with recycling of part of the working fluid, i.e. semi-closed cycles with combustion products in the closed part of the cycle
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
- F02C6/00—Plural gas-turbine plants; Combinations of gas-turbine plants with other apparatus; Adaptations of gas-turbine plants for special use
- F02C6/18—Plural gas-turbine plants; Combinations of gas-turbine plants with other apparatus; Adaptations of gas-turbine plants for special use using the waste heat of gas-turbine plants outside the plants themselves, e.g. gas-turbine power heat plants
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1052—Nickel or cobalt catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
- C01B2203/84—Energy production
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Organic Chemistry (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Engine Equipment That Uses Special Cycles (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
1. Способ работы газотурбинной установки, включающий подачу в камеру сгорания сжатых воздуха и метансодержащей парогазовой смеси, расширение продуктов их сгорания в газовой турбине, охлаждение продуктов сгорания путем испарения или перегрева водяного пара высокого давления, конденсацию водяного пара низкого давления, содержащегося в продуктах сгорания, испарение и перегрев конденсата с образованием водяного пара высокого давления, направляемого в газотурбинную установку, отличающийся тем, что природный газ последовательно смешивают с водяным паром высокого давления, нагревают в первом теплообменнике продуктами сгорания метансодержащей парогазовой смеси, пропускают через каталитический реактор с образованием метансодержащей парогазовой смеси, которую нагревают во втором теплообменнике, пропускают через второй каталитический реактор и подают в камеру сгорания. ! 2. Способ по п.1, отличающийся тем, что нагрев природного газа с водяным паром высокого давления, подаваемым в каталитический реактор, ведут до температуры в диапазоне 350°С-530°С. ! 3. Способ по п.1, отличающийся тем, что нагрев метансодержащей парогазовой смеси, подаваемой во второй каталитический реактор, ведут до температуры в диапазоне 620-680°С. ! 4. Способ по п.1, отличающийся тем, что давление водяного пара высокого давления выбирают в диапазоне ориентировочно от 2,0 до 9,0 МПа. !5. Способ по п.1, отличающийся тем, что реакцию смеси природного газа с водяным паром высокого давления в каталитическом реакторе ведут без подвода тепловой энергии на катализаторе, содержащем металлы из ряда: никель, железо, платина, палладий, иридий или их соединения, с обра 1. The method of operation of a gas turbine installation, comprising supplying compressed air and a methane-containing gas mixture to the combustion chamber, expanding their combustion products in a gas turbine, cooling the combustion products by evaporation or overheating of high pressure steam, condensation of low pressure steam contained in the combustion products, evaporation and overheating of the condensate with the formation of high-pressure water vapor sent to a gas turbine installation, characterized in that the natural gas is sequentially mixed with high-pressure steam, they are heated in the first heat exchanger with the products of combustion of a methane-containing gas mixture, passed through a catalytic reactor to form a methane-containing gas mixture, which is heated in a second heat exchanger, passed through a second catalytic reactor and fed into the combustion chamber. ! 2. The method according to claim 1, characterized in that the heating of natural gas with high-pressure steam supplied to the catalytic reactor is carried out to a temperature in the range of 350 ° C-530 ° C. ! 3. The method according to claim 1, characterized in that the heating of the methane-containing vapor-gas mixture supplied to the second catalytic reactor is carried out to a temperature in the range of 620-680 ° C. ! 4. The method according to claim 1, characterized in that the pressure of high pressure water vapor is selected in the range of approximately from 2.0 to 9.0 MPa. !5. The method according to claim 1, characterized in that the reaction of a mixture of natural gas with high pressure steam in a catalytic reactor is carried out without supplying thermal energy to a catalyst containing metals from the series: nickel, iron, platinum, palladium, iridium or their compounds, with
Claims (8)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| RU2010145022/06A RU2467187C2 (en) | 2010-11-03 | 2010-11-03 | Method of operating gas turbine unit |
| PCT/RU2011/000844 WO2012060739A1 (en) | 2010-11-03 | 2011-11-01 | Method for operating a gas turbine unit |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| RU2010145022/06A RU2467187C2 (en) | 2010-11-03 | 2010-11-03 | Method of operating gas turbine unit |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2010145022A true RU2010145022A (en) | 2012-05-10 |
| RU2467187C2 RU2467187C2 (en) | 2012-11-20 |
Family
ID=46024680
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2010145022/06A RU2467187C2 (en) | 2010-11-03 | 2010-11-03 | Method of operating gas turbine unit |
Country Status (2)
| Country | Link |
|---|---|
| RU (1) | RU2467187C2 (en) |
| WO (1) | WO2012060739A1 (en) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9377202B2 (en) | 2013-03-15 | 2016-06-28 | General Electric Company | System and method for fuel blending and control in gas turbines |
| US9382850B2 (en) | 2013-03-21 | 2016-07-05 | General Electric Company | System and method for controlled fuel blending in gas turbines |
| RU2561755C2 (en) | 2013-11-07 | 2015-09-10 | Открытое акционерное общество "Газпром" | Operating method and system of gas-turbine plant |
| RU2626291C2 (en) * | 2015-11-13 | 2017-07-25 | Федеральное государственное бюджетное учреждение "Национальный исследовательский центр "Курчатовский институт" | Energy conversion method |
| RU2648478C2 (en) * | 2015-11-18 | 2018-03-26 | федеральное государственное бюджетное образовательное учреждение высшего образования "Самарский государственный технический университет" | Maneuvered regenerative steam gas thermal power plant operating method and device for its implementation |
| RU2639397C1 (en) * | 2016-12-29 | 2017-12-21 | Общество с ограниченной ответственностью "Газпром трансгаз Самара" | Mode of gas turbine plant operation on methane-contained steam-gas mixture and its actualization device |
| RU2643878C1 (en) * | 2017-02-27 | 2018-02-06 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Саратовский государственный технический университет имени Гагарина Ю.А." (СГТУ имени Гагарина Ю.А.) | Method of operation of the compressed-air power station with an absorption lithium bromide refrigerating system (lbrs) |
| RU2647013C1 (en) * | 2017-02-27 | 2018-03-13 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Саратовский государственный технический университет имени Гагарина Ю.А." (СГТУ имени Гагарина Ю.А.) | Method of operation of the compressed-air power station |
| RU2665745C1 (en) * | 2017-07-25 | 2018-09-04 | Андрей Владиславович Курочкин | Gas turbine installation |
| RU2689483C2 (en) * | 2017-10-30 | 2019-05-28 | федеральное государственное автономное образовательное учреждение высшего образования "Самарский национальный исследовательский университет имени академика С.П. Королёва" | Energy plant with high-temperature steam-gas condensate turbine |
| RU2672416C1 (en) * | 2018-03-12 | 2018-11-14 | Андрей Владиславович Курочкин | Hydrogen recovery plant (options) |
| RU2679241C1 (en) * | 2018-03-12 | 2019-02-06 | Андрей Владиславович Курочкин | Hydrogen recovery plant |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0062932B1 (en) * | 1981-04-03 | 1984-12-05 | BBC Aktiengesellschaft Brown, Boveri & Cie. | Combined steam and gas turbine power plant |
| DE3419560A1 (en) * | 1984-05-25 | 1985-11-28 | Brown, Boveri & Cie Ag, 6800 Mannheim | Method for the operation of a gas turbine plant and plant for the method |
| DE4003210A1 (en) * | 1990-02-01 | 1991-08-14 | Mannesmann Ag | METHOD AND APPARATUS FOR GENERATING MECHANICAL ENERGY |
| RU2097314C1 (en) * | 1996-02-01 | 1997-11-27 | Химический факультет МГУ им.М.В.Ломоносова | Method of catalytic conversion of natural gas |
| RU2117520C1 (en) * | 1998-03-20 | 1998-08-20 | Майер Виктор Викторович | Method of processing natural gas to produce methanol |
| GB0116894D0 (en) * | 2001-07-11 | 2001-09-05 | Accentus Plc | Catalytic reactor |
| RU2271333C2 (en) * | 2004-03-25 | 2006-03-10 | Институт Катализа Им. Г.К. Борескова Сибирского Отделения Российской Академии Наук | Hydrogen-containing gas generation process |
-
2010
- 2010-11-03 RU RU2010145022/06A patent/RU2467187C2/en not_active IP Right Cessation
-
2011
- 2011-11-01 WO PCT/RU2011/000844 patent/WO2012060739A1/en active Application Filing
Also Published As
| Publication number | Publication date |
|---|---|
| RU2467187C2 (en) | 2012-11-20 |
| WO2012060739A1 (en) | 2012-05-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | The patent is invalid due to non-payment of fees |
Effective date: 20131104 |