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RU2008143260A - CATALYST OF REDUCING CARBON MONOXIDE, METHOD FOR PREPARING THE CATALYST AND METHOD FOR PRODUCING HYDROCARBON - Google Patents

CATALYST OF REDUCING CARBON MONOXIDE, METHOD FOR PREPARING THE CATALYST AND METHOD FOR PRODUCING HYDROCARBON Download PDF

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RU2008143260A
RU2008143260A RU2008143260/04A RU2008143260A RU2008143260A RU 2008143260 A RU2008143260 A RU 2008143260A RU 2008143260/04 A RU2008143260/04 A RU 2008143260/04A RU 2008143260 A RU2008143260 A RU 2008143260A RU 2008143260 A RU2008143260 A RU 2008143260A
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catalyst
metal oxide
carbon monoxide
aqueous solution
producing hydrocarbons
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RU2008143260/04A
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RU2436832C2 (en
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Хироюки СЕКИ (JP)
Хироюки СЕКИ
Хирофуми КОННО (JP)
Хирофуми КОННО
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Ниппон Ойл Корпорейшн (Jp)
Ниппон Ойл Корпорейшн
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Priority claimed from JP2006099880A external-priority patent/JP2007270049A/en
Priority claimed from JP2006099879A external-priority patent/JP4907212B2/en
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8913—Cobalt and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/333—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the platinum-group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
    • B01J35/397—Egg shell like

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)

Abstract

1. Способ получения углеводородов в результате восстановления монооксида углерода с использованием катализатора, включающего в себя носитель, содержащий оксид металла, и цирконий в виде оксида, селективно нанесенный вблизи внешней поверхности оксида металла, и один или несколько типов металла, выбранных из кобальта и рутения, нанесенных на носитель. ! 2. Способ получения углеводородов по п.1 с использованием катализатора, содержащего носитель, полученный в результате нанесения и затем отжига циркония на оксиде металла, который был предварительно обработан водным раствором с рН 7 или ниже, и один или несколько типов металла, выбранных из кобальта и рутения, нанесенных на носитель. ! 3. Способ получения углеводородов по п.1 с использованием катализатора, содержащего носитель, в котором оксид металла является сферическим и 75 мас.% или больше от общего количества оксида циркония наносят на 1/5 или меньшую часть радиальной области, распространяющейся от внешней поверхности катализатора к его центру. ! 4. Способ получения углеводородов по п.2 с использованием катализатора, содержащего носитель, в котором оксид металла является сферическим и 75 мас.% или больше от общего количества оксида циркония наносят на 1/5 или меньшую часть радиальной области, распространяющейся от внешней поверхности катализатора к его центру. ! 5. Способ получения углеводородов по любому из пп.1-4, в котором температура реакции составляет от 200 до 300°С. ! 6. Способ приготовления катализатора восстановления монооксида углерода, включающий в себя создание носителя в результате предварительной обработки оксида металла водным раствором с рН 7 или ниже, � 1. A process for producing hydrocarbons by reduction of carbon monoxide using a catalyst including a support containing a metal oxide, and zirconium oxide selectively deposited near the outer surface of the metal oxide, and one or more types of metal selected from cobalt and ruthenium, applied to the media. ! 2. The method of producing hydrocarbons according to claim 1 using a catalyst containing a support obtained by depositing and then annealing zirconium on a metal oxide that has been pre-treated with an aqueous solution having a pH of 7 or lower, and one or more types of metal selected from cobalt and ruthenium deposited on the carrier. ! 3. The method for producing hydrocarbons according to claim 1 using a catalyst containing a support in which the metal oxide is spherical and 75 wt.% or more of the total amount of zirconium oxide is supported on 1/5 or less of a radial region extending from the outer surface of the catalyst to its center. ! 4. The method for producing hydrocarbons according to claim 2 using a catalyst containing a support in which the metal oxide is spherical and 75 wt.% or more of the total amount of zirconium oxide is supported on 1/5 or less of a radial region extending from the outer surface of the catalyst to its center. ! 5. A method for producing hydrocarbons according to any one of claims 1-4, in which the reaction temperature is from 200 to 300°C. ! 6. A method of preparing a carbon monoxide reduction catalyst, which includes creating a support by pre-treating a metal oxide with an aqueous solution with a pH of 7 or lower,�

Claims (11)

1. Способ получения углеводородов в результате восстановления монооксида углерода с использованием катализатора, включающего в себя носитель, содержащий оксид металла, и цирконий в виде оксида, селективно нанесенный вблизи внешней поверхности оксида металла, и один или несколько типов металла, выбранных из кобальта и рутения, нанесенных на носитель.1. A method of producing hydrocarbons by reducing carbon monoxide using a catalyst comprising a carrier containing metal oxide and zirconium oxide, selectively deposited near the outer surface of the metal oxide, and one or more types of metal selected from cobalt and ruthenium, applied to the carrier. 2. Способ получения углеводородов по п.1 с использованием катализатора, содержащего носитель, полученный в результате нанесения и затем отжига циркония на оксиде металла, который был предварительно обработан водным раствором с рН 7 или ниже, и один или несколько типов металла, выбранных из кобальта и рутения, нанесенных на носитель.2. The method of producing hydrocarbons according to claim 1 using a catalyst containing a carrier obtained by applying and then annealing zirconium on a metal oxide that has been pretreated with an aqueous solution with a pH of 7 or lower, and one or more types of metal selected from cobalt and ruthenium deposited on a carrier. 3. Способ получения углеводородов по п.1 с использованием катализатора, содержащего носитель, в котором оксид металла является сферическим и 75 мас.% или больше от общего количества оксида циркония наносят на 1/5 или меньшую часть радиальной области, распространяющейся от внешней поверхности катализатора к его центру.3. The method of producing hydrocarbons according to claim 1 using a catalyst containing a carrier, in which the metal oxide is spherical and 75 wt.% Or more of the total amount of zirconium oxide is applied to 1/5 or less of the radial region extending from the outer surface of the catalyst to its center. 4. Способ получения углеводородов по п.2 с использованием катализатора, содержащего носитель, в котором оксид металла является сферическим и 75 мас.% или больше от общего количества оксида циркония наносят на 1/5 или меньшую часть радиальной области, распространяющейся от внешней поверхности катализатора к его центру.4. The method of producing hydrocarbons according to claim 2 using a catalyst containing a carrier, in which the metal oxide is spherical and 75 wt.% Or more of the total amount of zirconium oxide is applied to 1/5 or less of the radial region extending from the outer surface of the catalyst to its center. 5. Способ получения углеводородов по любому из пп.1-4, в котором температура реакции составляет от 200 до 300°С.5. The method of producing hydrocarbons according to any one of claims 1 to 4, in which the reaction temperature is from 200 to 300 ° C. 6. Способ приготовления катализатора восстановления монооксида углерода, включающий в себя создание носителя в результате предварительной обработки оксида металла водным раствором с рН 7 или ниже, и нанесение и отжиг циркония на оксиде металла, и нанесения одного или нескольких типов металлов, выбранных из кобальта и рутения, на носителе.6. A method of preparing a catalyst for the reduction of carbon monoxide, which includes the creation of a carrier by pretreating the metal oxide with an aqueous solution of pH 7 or lower, and applying and annealing zirconium on the metal oxide, and applying one or more types of metals selected from cobalt and ruthenium on the media. 7. Способ приготовления катализатора восстановления монооксида углерода по п.6, в котором водный раствор с рН 7 или ниже выбран из группы, состоящей из водного раствора азотной кислоты, водного раствора уксусной кислоты, водного раствора серной кислоты, водного раствора соляной кислоты, ионно-обменной воды и дистиллированной воды.7. A method of preparing a carbon monoxide reduction catalyst according to claim 6, wherein the aqueous solution with a pH of 7 or lower is selected from the group consisting of an aqueous solution of nitric acid, an aqueous solution of acetic acid, an aqueous solution of sulfuric acid, an aqueous solution of hydrochloric acid, ion exchange water and distilled water. 8. Способ приготовления катализатора восстановления монооксида углерода по п.6, в котором оксид металла является оксидом алюминия или диоксидом кремния.8. The method of preparing the catalyst for the reduction of carbon monoxide according to claim 6, in which the metal oxide is alumina or silicon dioxide. 9. Способ приготовления катализатора восстановления монооксида углерода по п.6, в котором общее количество металла, выбранного из кобальта и рутения, изменяется от 3 до 50 мас.% в расчете на катализатор.9. The method of preparation of the catalyst for the reduction of carbon monoxide according to claim 6, in which the total amount of metal selected from cobalt and ruthenium varies from 3 to 50 wt.% Based on the catalyst. 10. Способ приготовления катализатора восстановления монооксида углерода по п.6, в котором оксид металла является сферическим и 75 мас.% или больше от общего количества оксида циркония наносят на 1/5 или меньшую часть радиальной области, распространяющейся от внешней поверхности катализатора к его центру.10. The method of preparing the catalyst for the reduction of carbon monoxide according to claim 6, in which the metal oxide is spherical and 75 wt.% Or more of the total amount of zirconium oxide is applied to 1/5 or less of the radial region extending from the outer surface of the catalyst to its center . 11. Катализатор восстановления монооксида углерода приготовленный при помощи способа в соответствии с любым из пп.6-10. 11. The carbon monoxide reduction catalyst prepared using the method in accordance with any of claims 6-10.
RU2008143260/04A 2006-03-31 2007-02-27 Catalyst for reducing carbon monoxide, method of preparing catalyst and method of producing hydrocarbon RU2436832C2 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2006-099880 2006-03-31
JP2006099880A JP2007270049A (en) 2006-03-31 2006-03-31 Process for producing hydrocarbons by reduction of carbon monoxide
JP2006-099879 2006-03-31
JP2006099879A JP4907212B2 (en) 2006-03-31 2006-03-31 Carbon monoxide reduction catalyst and preparation method thereof

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RU2008143260A true RU2008143260A (en) 2010-05-10
RU2436832C2 RU2436832C2 (en) 2011-12-20

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MY (1) MY149135A (en)
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WO (1) WO2007113965A1 (en)

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RU2586069C1 (en) * 2015-06-15 2016-06-10 федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Южно-Российский государственный политехнический университет (НПИ) имени М.И. Платова" Catalyst for synthesis of hydrocarbons from co and h2 and preparation method thereof

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NL8003313A (en) * 1980-06-06 1982-01-04 Shell Int Research METHOD FOR PREPARING MIDDLE DISTILLATES.
GB8918845D0 (en) * 1989-08-18 1989-09-27 Shell Int Research Process for the preparation of a catalyst suitable for the preparation of hydrocarbons from carbon monoxide and hydrogen,and said catalyst
GB8925979D0 (en) * 1989-11-16 1990-01-04 Shell Int Research Process for the preparation of extrudates,extrudates,and use of the extrudates
IT1292422B1 (en) * 1997-06-26 1999-02-08 Agip Petroli BUBBLE REACTOR WITH DRAFT TUBE AND PROCEDURE FOR THE REGENERATION OF THE CATALYST CONTAINED
CA2395682A1 (en) * 2000-01-04 2001-07-12 Alla Jurievna Krylova Hydrocarbon synthesis catalyst enhancement with hydrogen and ammonia
RU2271250C2 (en) * 2000-07-24 2006-03-10 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Crusted metallic catalyst, method for preparation thereof, and a hydrocarbon production process
AU2002363534A1 (en) * 2001-11-08 2003-05-19 Conoco Inc. Modified zirconia support for catalyst for fischer-tropsch process
RU2256502C1 (en) * 2004-03-01 2005-07-20 Институт органической химии им. Н.Д. Зелинского РАН Catalyst for synthesis of hydrocarbons from co and h2

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RU2436832C2 (en) 2011-12-20
WO2007113965A1 (en) 2007-10-11
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MY149135A (en) 2013-07-15
AU2007232013A1 (en) 2007-10-11

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