RU2006108543A - Способ десульфуризации углеводородной нефти - Google Patents
Способ десульфуризации углеводородной нефти Download PDFInfo
- Publication number
- RU2006108543A RU2006108543A RU2006108543/04A RU2006108543A RU2006108543A RU 2006108543 A RU2006108543 A RU 2006108543A RU 2006108543/04 A RU2006108543/04 A RU 2006108543/04A RU 2006108543 A RU2006108543 A RU 2006108543A RU 2006108543 A RU2006108543 A RU 2006108543A
- Authority
- RU
- Russia
- Prior art keywords
- sulfur
- hydrocarbon oil
- stream
- adsorbent
- oxidized
- Prior art date
Links
- 239000004215 Carbon black (E152) Substances 0.000 title claims 7
- 229930195733 hydrocarbon Natural products 0.000 title claims 7
- 150000002430 hydrocarbons Chemical class 0.000 title claims 7
- 238000000034 method Methods 0.000 title claims 2
- 230000003009 desulfurizing effect Effects 0.000 title 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 8
- 239000003921 oil Substances 0.000 claims 8
- 229910052717 sulfur Inorganic materials 0.000 claims 8
- 239000011593 sulfur Substances 0.000 claims 8
- 150000001875 compounds Chemical class 0.000 claims 7
- 239000003463 adsorbent Substances 0.000 claims 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims 3
- 239000010457 zeolite Substances 0.000 claims 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
- 239000007800 oxidant agent Substances 0.000 claims 2
- 230000003647 oxidation Effects 0.000 claims 2
- 238000007254 oxidation reaction Methods 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 229910021536 Zeolite Inorganic materials 0.000 claims 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 1
- 239000007864 aqueous solution Substances 0.000 claims 1
- 238000009835 boiling Methods 0.000 claims 1
- 239000003054 catalyst Substances 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 238000006477 desulfuration reaction Methods 0.000 claims 1
- 230000023556 desulfurization Effects 0.000 claims 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 238000004064 recycling Methods 0.000 claims 1
- 230000008929 regeneration Effects 0.000 claims 1
- 238000011069 regeneration method Methods 0.000 claims 1
- 235000012239 silicon dioxide Nutrition 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 239000000243 solution Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
- C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G53/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes
- C10G53/02—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only
- C10G53/14—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only including at least one oxidation step
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
- C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
- C10G67/12—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only including oxidation as the refining step in the absence of hydrogen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
- C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
- C10G67/14—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only including at least two different refining steps in the absence of hydrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Claims (1)
1. Способ десульфуризации углеводородной нефти, отличающийся тем, что содержит следующие стадии:
a) введение углеводородной нефти (1), кипящей в диапазоне от приблизительно 149 до приблизительно 538°С, в контакт с катализатором гидродесульфуризации в зоне реакции гидродесульфуризации (3) в условиях проведения гидродесульфуризации, которые включают давление в диапазоне от приблизительно 800 кПа до приблизительно 12,5 МПа, максимальную температуру в диапазоне от приблизительно 204 до приблизительно 400°С и соотношение количеств водорода и исходного сырья в диапазоне от приблизительно 33,7 нм3/м3 до приблизительно 1685 нм3/м3, с получением сероводорода и получающегося в результате первого потока углеводородной нефти, характеризующегося пониженной концентрацией серы;
b) введение первого потока углеводородной нефти, характеризующегося пониженной концентрацией серы, в контакт с водным раствором окислителя (10), содержащим уксусную кислоту и перекись водорода, в зоне окисления (8) с получением второго потока углеводородной нефти, содержащего соединения, окисленные по сере;
c) разложение, по меньшей мере, части раствора любого остаточного окислителя в продукте окисления серы;
d) введение потока продукта, выходящего со стадии (с), содержащего соединения, окисленные по сере, в контакт с селективным адсорбентом (18, 30), выбираемым из группы, состоящей из диоксида кремния, оксида алюминия, силикалита, ZSM-5, цеолита-L, цеолитов, относящихся к типам Х и Y, деалюминированного цеолита, относящегося к типу Y, цеолита-бета, цеолита-омега и SAPO-34 и характеризующимся большей селективностью по отношению к соединениям, окисленным по сере, в сопоставлении с не содержащей серу углеводородной нефтью, с получением адсорбента (18, 30), содержащего, по меньшей мере, часть соединений, окисленных по сере, и третьего потока углеводородной нефти, характеризующегося пониженной концентрацией соединений, окисленных по сере, (23);
e) выделение адсорбента (18, 30), содержащего, по меньшей мере, часть соединений, окисленных по сере, образованного на стадии (d), с получением адсорбента (18, 30), обогащенного соединениями, окисленными по сере;
f) регенерацию, по меньшей мере, части адсорбента (18, 30) со стадии (е) и отправление на рецикл на стадию (d) с получением, по меньшей мере, части селективного адсорбента;
g) извлечение третьего потока углеводородной нефти (23).
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/644,121 US20050040078A1 (en) | 2003-08-20 | 2003-08-20 | Process for the desulfurization of hydrocarbonacecus oil |
| US10/644,121 | 2003-08-20 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2006108543A true RU2006108543A (ru) | 2006-08-10 |
| RU2335528C2 RU2335528C2 (ru) | 2008-10-10 |
Family
ID=34194009
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2006108543/04A RU2335528C2 (ru) | 2003-08-20 | 2004-08-18 | Способ десульфуризации углеводородной нефти |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20050040078A1 (ru) |
| CN (1) | CN100432190C (ru) |
| CA (1) | CA2535349A1 (ru) |
| RU (1) | RU2335528C2 (ru) |
| WO (1) | WO2005019386A1 (ru) |
Families Citing this family (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102004031969A1 (de) * | 2004-07-01 | 2006-02-16 | Wacker Polymer Systems Gmbh & Co. Kg | Weich-modifizierte Polyvinylacetalharze |
| CA2531262A1 (en) * | 2005-12-21 | 2007-06-21 | Imperial Oil Resources Limited | Very low sulfur heavy crude oil and process for the production thereof |
| US9315733B2 (en) * | 2006-10-20 | 2016-04-19 | Saudi Arabian Oil Company | Asphalt production from solvent deasphalting bottoms |
| US7842181B2 (en) * | 2006-12-06 | 2010-11-30 | Saudi Arabian Oil Company | Composition and process for the removal of sulfur from middle distillate fuels |
| US20090145808A1 (en) * | 2007-11-30 | 2009-06-11 | Saudi Arabian Oil Company | Catalyst to attain low sulfur diesel |
| US8142646B2 (en) | 2007-11-30 | 2012-03-27 | Saudi Arabian Oil Company | Process to produce low sulfur catalytically cracked gasoline without saturation of olefinic compounds |
| WO2009099395A1 (en) * | 2008-02-06 | 2009-08-13 | Agency For Science, Technology And Research | Regeneration of solid adsorbent |
| WO2009105749A2 (en) | 2008-02-21 | 2009-08-27 | Saudi Arabian Oil Company | Catalyst to attain low sulfur gasoline |
| US9132421B2 (en) | 2009-11-09 | 2015-09-15 | Shell Oil Company | Composition useful in the hydroprocessing of a hydrocarbon feedstock |
| US9296960B2 (en) | 2010-03-15 | 2016-03-29 | Saudi Arabian Oil Company | Targeted desulfurization process and apparatus integrating oxidative desulfurization and hydrodesulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds |
| US20110220550A1 (en) * | 2010-03-15 | 2011-09-15 | Abdennour Bourane | Mild hydrodesulfurization integrating targeted oxidative desulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds |
| US8658027B2 (en) * | 2010-03-29 | 2014-02-25 | Saudi Arabian Oil Company | Integrated hydrotreating and oxidative desulfurization process |
| CN102294222A (zh) * | 2010-06-24 | 2011-12-28 | 中国石油化工股份有限公司 | 一种烃油脱硫吸附剂及其制备方法和应用 |
| CN102294224A (zh) * | 2010-06-24 | 2011-12-28 | 中国石油化工股份有限公司 | 一种烃油脱硫吸附剂及其制备方法和应用 |
| CN102294225A (zh) * | 2010-06-24 | 2011-12-28 | 中国石油化工股份有限公司 | 一种烃油脱硫吸附剂及其制备方法和应用 |
| CN102294223A (zh) * | 2010-06-24 | 2011-12-28 | 中国石油化工股份有限公司 | 一种烃油脱硫吸附剂及其制备方法和应用 |
| US9005432B2 (en) | 2010-06-29 | 2015-04-14 | Saudi Arabian Oil Company | Removal of sulfur compounds from petroleum stream |
| CN102343250A (zh) * | 2010-07-29 | 2012-02-08 | 中国石油化工股份有限公司 | 一种烃油脱硫吸附剂及其制备方法和应用 |
| CA2820269A1 (en) * | 2010-12-10 | 2012-06-14 | Shell Internationale Research Maatschappij B.V. | Hydrocracking of a heavy hydrocarbon feedstock using a copper molybdenum sulfided catalyst |
| CN103313956A (zh) * | 2010-12-15 | 2013-09-18 | 沙特阿拉伯石油公司 | 使用气态氧化剂的烃原料流的脱硫 |
| US20120160742A1 (en) * | 2010-12-22 | 2012-06-28 | Uop Llc | High Purity Heavy Normal Paraffins Utilizing Integrated Systems |
| US8535518B2 (en) | 2011-01-19 | 2013-09-17 | Saudi Arabian Oil Company | Petroleum upgrading and desulfurizing process |
| JP5841229B2 (ja) * | 2011-03-23 | 2016-01-13 | アディティア ビルラ サイエンス アンド テクノロジー カンパニー リミテッド | 石油系油分の脱硫方法 |
| RU2585633C2 (ru) * | 2011-07-28 | 2016-05-27 | Чайна Петролеум Энд Кемикал Корпорейшн | Адсорбирующее вещество для десульфуризации углеводородного масла, его получение и применение |
| US20130056214A1 (en) * | 2011-09-07 | 2013-03-07 | E. I. Du Pont De Nemours And Company | Reducing sulfide in production fluids during oil recovery |
| US8573300B2 (en) * | 2011-09-07 | 2013-11-05 | E I Du Pont De Nemours And Company | Reducing sulfide in oil reservoir production fluids |
| US9873797B2 (en) | 2011-10-24 | 2018-01-23 | Aditya Birla Nuvo Limited | Process for the production of carbon black |
| US8906227B2 (en) | 2012-02-02 | 2014-12-09 | Suadi Arabian Oil Company | Mild hydrodesulfurization integrating gas phase catalytic oxidation to produce fuels having an ultra-low level of organosulfur compounds |
| CN104334650B (zh) | 2012-03-30 | 2017-04-26 | 埃迪亚贝拉科技有限公司 | 用于获得含硫量减少的炭黑粉末的方法 |
| US8920635B2 (en) | 2013-01-14 | 2014-12-30 | Saudi Arabian Oil Company | Targeted desulfurization process and apparatus integrating gas phase oxidative desulfurization and hydrodesulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds |
| US10384197B2 (en) * | 2016-07-26 | 2019-08-20 | Saudi Arabian Oil Company | Additives for gas phase oxidative desulfurization catalysts |
| CN108236965A (zh) * | 2016-12-27 | 2018-07-03 | 中国石油天然气股份有限公司 | 一种改性的加氢脱硫催化剂及其制备方法 |
| WO2018152512A1 (en) * | 2017-02-20 | 2018-08-23 | Saudi Arabian Oil Company | Desulfurization and sulfone removal using a coker |
| US10752847B2 (en) | 2017-03-08 | 2020-08-25 | Saudi Arabian Oil Company | Integrated hydrothermal process to upgrade heavy oil |
| US10703999B2 (en) | 2017-03-14 | 2020-07-07 | Saudi Arabian Oil Company | Integrated supercritical water and steam cracking process |
| US10526552B1 (en) | 2018-10-12 | 2020-01-07 | Saudi Arabian Oil Company | Upgrading of heavy oil for steam cracking process |
| JP2021038932A (ja) * | 2019-08-30 | 2021-03-11 | Ｅｎｅｏｓ株式会社 | 潤滑油の判別方法及び潤滑油組成物 |
| RU2743291C1 (ru) * | 2020-07-24 | 2021-02-16 | Федеральное государственное бюджетное учреждение высшего образования «Тамбовский государственный технический университет» (ФГБОУ ВО «ТГТУ») | Способ адсорбционной десульфуризации нефти и нефтепродуктов: бензина, дизельного топлива с использованием композиционного адсорбента на основе минералов природного происхождения |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US2769760A (en) * | 1953-09-11 | 1956-11-06 | Pure Oil Co | Production of sweet naphthas from hydrocarbon mixtures by hydrofining the hydrocarbon mixture followed by contacting the hydrocarbon product with a composition containing cobalt and molybdenum |
| NL135711C (ru) * | 1968-05-24 | |||
| US4719007A (en) * | 1986-10-30 | 1988-01-12 | Uop Inc. | Process for hydrotreating a hydrocarbonaceous charge stock |
| US5064525A (en) * | 1991-02-19 | 1991-11-12 | Uop | Combined hydrogenolysis plus oxidation process for sweetening a sour hydrocarbon fraction |
| US5454933A (en) * | 1991-12-16 | 1995-10-03 | Exxon Research And Engineering Company | Deep desulfurization of distillate fuels |
| US5885439A (en) * | 1997-11-04 | 1999-03-23 | Uop Llc | Catalytic reforming process with multiple zones |
| FR2776297B1 (fr) * | 1998-03-23 | 2000-05-05 | Inst Francais Du Petrole | Procede de conversion de fractions lourdes petrolieres comprenant une etape d'hydrotraitement en lit fixe, une etape de conversion en lit bouillonnant et une etape de craquage catalytique |
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| US6171478B1 (en) * | 1998-07-15 | 2001-01-09 | Uop Llc | Process for the desulfurization of a hydrocarbonaceous oil |
| GB9925971D0 (en) * | 1999-11-03 | 1999-12-29 | Exxon Chemical Patents Inc | Reduced particulate froming distillate fuels |
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-
2003
- 2003-08-20 US US10/644,121 patent/US20050040078A1/en not_active Abandoned
-
2004
- 2004-08-18 CN CNB2004800270611A patent/CN100432190C/zh not_active Expired - Fee Related
- 2004-08-18 CA CA002535349A patent/CA2535349A1/en not_active Abandoned
- 2004-08-18 RU RU2006108543/04A patent/RU2335528C2/ru not_active IP Right Cessation
- 2004-08-18 WO PCT/US2004/027045 patent/WO2005019386A1/en active Application Filing
Also Published As
| Publication number | Publication date |
|---|---|
| RU2335528C2 (ru) | 2008-10-10 |
| CN100432190C (zh) | 2008-11-12 |
| CN1852966A (zh) | 2006-10-25 |
| WO2005019386A1 (en) | 2005-03-03 |
| CA2535349A1 (en) | 2005-03-03 |
| US20050040078A1 (en) | 2005-02-24 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | The patent is invalid due to non-payment of fees |
Effective date: 20140819 |