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RU2003124056A - COMPOSITIONS OF LIQUID FUEL FOR ELECTROCHEMICAL FUEL ELEMENTS AND A FUEL ELEMENT ON ITS BASIS - Google Patents

COMPOSITIONS OF LIQUID FUEL FOR ELECTROCHEMICAL FUEL ELEMENTS AND A FUEL ELEMENT ON ITS BASIS

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Publication number
RU2003124056A
RU2003124056A RU2003124056/09A RU2003124056A RU2003124056A RU 2003124056 A RU2003124056 A RU 2003124056A RU 2003124056/09 A RU2003124056/09 A RU 2003124056/09A RU 2003124056 A RU2003124056 A RU 2003124056A RU 2003124056 A RU2003124056 A RU 2003124056A
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RU
Russia
Prior art keywords
fuel
fuel composition
compound
hydrogen
containing inorganic
Prior art date
Application number
RU2003124056/09A
Other languages
Russian (ru)
Other versions
RU2265643C2 (en
Inventor
Геннадий ФИНКЕЛЬШТЕЙН
Юрий КАСТМАН
Борис ФИЛАНОВСКИЙ
Original Assignee
Мо Энерджи Лтд.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/752,551 external-priority patent/US6554877B2/en
Application filed by Мо Энерджи Лтд. filed Critical Мо Энерджи Лтд.
Publication of RU2003124056A publication Critical patent/RU2003124056A/en
Application granted granted Critical
Publication of RU2265643C2 publication Critical patent/RU2265643C2/en

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Claims (18)

1. Топливная композиция для применения в электрохимическом топливном элементе, содержащая:1. A fuel composition for use in an electrochemical fuel cell, comprising: (a) основное топливо, включающее по меньшей мере одно поверхностно-активное соединение;(a) a primary fuel comprising at least one surfactant; (b) вспомогательное топливо, включающее по меньшей мере одно водородсодержащее неорганическое соединение с высоким восстановительным потенциалом;(b) auxiliary fuel comprising at least one hydrogen-containing inorganic compound with a high reduction potential; (c) электролит с рН выше приблизительно 7; и(c) an electrolyte with a pH above about 7; and (d) по меньшей мере одно дополнительное соединение.(d) at least one additional compound. 2. Топливная композиция по п.1, в которой поверхностно-активным соединением является соединение с функциональной группой - ОН.2. The fuel composition according to claim 1, in which the surface-active compound is a compound with a functional group - OH. 3. Топливная композиция по п.1, в которой поверхностно-активное соединение включает по меньшей мере одно соединение из группы, состоящей из CH4O, С2Н6О, С3Н8О, С4Н10О, С3Н12О, С6Н14О, этиленгликоля и глицерина.3. The fuel composition according to claim 1, in which the surface-active compound comprises at least one compound from the group consisting of CH 4 O, C 2 H 6 O, C 3 H 8 O, C 4 H 10 O, C 3 H 12 O, C 6 H 14 O, ethylene glycol and glycerol. 4. Топливная композиция по п.1, в которой вспомогательное топливо включает по меньшей мере одно соединение из группы, состоящей из гидридов металлов, гидразина и производных гидразина.4. The fuel composition according to claim 1, in which the auxiliary fuel includes at least one compound from the group consisting of metal hydrides, hydrazine and hydrazine derivatives. 5. Топливная композиция по п.4, в которой вспомогательное топливо включает по меньшей мере одно соединение из группы, состоящей из LiAlH4, NaBH4, LiBH4, (СН3)2NHBH3, NaAlH4, В2Н6, NaCNBH3, СаН2, LiH, NaH, KH или бис(2-метоксиэтоксо)дигидридалюмината натрия.5. The fuel composition according to claim 4, in which the auxiliary fuel comprises at least one compound from the group consisting of LiAlH 4 , NaBH 4 , LiBH 4 , (CH 3 ) 2 NHBH 3 , NaAlH 4 , B 2 H 6 , NaCNBH 3 , CaH 2 , LiH, NaH, KH, or sodium bis (2-methoxyethoxy) dihydride aluminate. 6. Топливная композиция по п.1, в которой электролитом является водный раствор гидроксида щелочного металла.6. The fuel composition according to claim 1, in which the electrolyte is an aqueous solution of an alkali metal hydroxide. 7. Топливная композиция по п.6, в которой гидроксидом щелочного металла является КОН.7. The fuel composition according to claim 6, in which the alkali metal hydroxide is KOH. 8. Топливная композиция по п.7, в которой электролит имеет концентрацию КОН от приблизительно 3 М до приблизительно 12 М.8. The fuel composition according to claim 7, in which the electrolyte has a KOH concentration of from about 3 M to about 12 M. 9. Топливная композиция по п.8, в которой концентрация электролита равна 6 М.9. The fuel composition of claim 8, in which the electrolyte concentration is 6 M. 10. Топливная композиция по п.1, содержащая от 2 до 60% мас основного топлива и от 1% мас до насыщения вспомогательного топлива.10. The fuel composition according to claim 1, containing from 2 to 60% wt. Of the main fuel and from 1% wt to saturate the auxiliary fuel. 11. Топливная композиция для применения в электрохимическом топливном элементе, содержащая:11. A fuel composition for use in an electrochemical fuel cell, comprising: (a) основное топливо, включающее по меньшей мере одно поверхностно-активное соединение;(a) a primary fuel comprising at least one surfactant; (b) вспомогательное топливо, включающее по меньшей мере одно водородсодержащее неорганическое соединение с высоким восстановительным потенциалом; и(b) auxiliary fuel comprising at least one hydrogen-containing inorganic compound with a high reduction potential; and (c) водный раствор с концентрацией КОН 6 М.(c) an aqueous solution with a concentration of KOH 6 M. 12. Топливная композиция для применения в электрохимическом топливном элементе, содержащая:12. A fuel composition for use in an electrochemical fuel cell, comprising: (a) основное топливо, включающее по меньшей мере одно поверхностно-активное соединение;(a) a primary fuel comprising at least one surfactant; (b) вспомогательное топливо, включающее по меньшей мере одно водородсодержащее неорганическое соединение с высоким восстановительным потенциалом; и(b) auxiliary fuel comprising at least one hydrogen-containing inorganic compound with a high reduction potential; and (c) электролит с рН выше приблизительно 7;(c) an electrolyte with a pH above about 7; в которой топливная композиция содержит от 2 до 60% мас основного топлива и от 1 до 60% мас вспомогательного топлива.in which the fuel composition contains from 2 to 60% wt. of the main fuel and from 1 to 60% wt. of auxiliary fuel. 13. Топливный элемент для генерирования электрического тока, содержащий:13. A fuel cell for generating electric current, comprising: (a)анод;(a) an anode; (b) катод; и(b) a cathode; and (c) топливную композицию, включающую по меньшей мере одно поверхностно-активное соединение и по меньшей мере одно водородсодержащее неорганическое соединение с высоким восстановительным потенциалом.(c) a fuel composition comprising at least one surface-active compound and at least one hydrogen-containing inorganic compound with a high reduction potential. 14. Топливный элемент по п.13, в котором по меньшей мере одно из поверхностно-активных соединений является спиртом и по меньшей мере одно из водородсодержащих неорганических соединений выбрано из группы, состоящей из гидридов металлов, гидразина и производных гидразина.14. The fuel cell according to item 13, in which at least one of the surface-active compounds is alcohol and at least one of the hydrogen-containing inorganic compounds selected from the group consisting of metal hydrides, hydrazine and hydrazine derivatives. 15. Топливный элемент по п.13, в котором водородсодержащее неорганическое соединение выбирают из группы, состоящей из LiAlH4, NaBH4, LiBH4, (СН3)2NHBH3, NaAlH4, В2Н6, NaCNBH3, СаН2, LiH, NaH, KH или бис(2-метоксиэтоксо)дигидридалюмината натрия.15. The fuel cell according to item 13, wherein the hydrogen-containing inorganic compound is selected from the group consisting of LiAlH 4 , NaBH 4 , LiBH 4 , (CH 3 ) 2 NHBH 3 , NaAlH 4 , B 2 H 6 , NaCNBH 3 , CaH 2 , LiH, NaH, KH, or sodium bis (2-methoxyethoxy) dihydride aluminate. 16. Способ производства электричества, отличающийся тем, что включает следующие стадии:16. A method of producing electricity, characterized in that it includes the following stages: (a) обеспечения топливного элемента, который включает катод и анод;(a) providing a fuel cell that includes a cathode and an anode; (b) обеспечения топливной композиции, включающей по меньшей мере одно водородсодержащее неорганическое соединение с высоким восстановительным потенциалом и по меньшей мере одно поверхностно-активное вещество;(b) providing a fuel composition comprising at least one hydrogen-containing inorganic compound with a high reduction potential and at least one surfactant; (c) обеспечения цепи, соединяющей катод и анод; и(c) providing a circuit connecting the cathode and the anode; and (d) введение топливной композиции в контакт с анодом с целью окисления топливной композиции.(d) bringing the fuel composition into contact with the anode to oxidize the fuel composition. 17. Способ по п.16, отличающийся тем, что по меньшей мере одно из поверхностно-активных соединений является спиртом и по меньшей мере одно из водородсодержащих неорганических соединений выбирают из группы, состоящей из гидридов металлов, гидразина и производных гидразина.17. The method according to p. 16, characterized in that at least one of the surface-active compounds is alcohol and at least one of the hydrogen-containing inorganic compounds is selected from the group consisting of metal hydrides, hydrazine and hydrazine derivatives. 18. Способ по п.17, отличающийся тем, что водородсодержащее неорганическое соединение выбрано из группы, состоящей из LiAlH4, NaBH4, LiBH4, (СН3)2NHBH3, NaAlH4, В2Н6, NaCNBH3, СаН2, LiH, NaH, KH или бис(2-метоксиэтоксо)дигидридалюмината натрия.18. The method according to 17, characterized in that the hydrogen-containing inorganic compound is selected from the group consisting of LiAlH 4 , NaBH 4 , LiBH 4 , (CH 3 ) 2 NHBH 3 , NaAlH 4 , B 2 H 6 , NaCNBH 3 , CaH 2 , LiH, NaH, KH or sodium bis (2-methoxyethoxo) dihydridaluminate.
RU2003124056/09A 2001-01-03 2002-01-03 Liquid fuel composition for electrochemical fuel elements and fuel element on its base RU2265643C2 (en)

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US09/752,551 2001-01-03

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JP (1) JP3883509B2 (en)
KR (1) KR20030072587A (en)
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AU (1) AU2002241813B2 (en)
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CA (1) CA2433401A1 (en)
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