PL123998B1 - Process for manufacturing herbicidal phosphorus compounds,in which phosphorus atom is linked with nitrogen atom via carbon atom - Google Patents
Process for manufacturing herbicidal phosphorus compounds,in which phosphorus atom is linked with nitrogen atom via carbon atom Download PDFInfo
- Publication number
- PL123998B1 PL123998B1 PL1979214793A PL21479379A PL123998B1 PL 123998 B1 PL123998 B1 PL 123998B1 PL 1979214793 A PL1979214793 A PL 1979214793A PL 21479379 A PL21479379 A PL 21479379A PL 123998 B1 PL123998 B1 PL 123998B1
- Authority
- PL
- Poland
- Prior art keywords
- atom
- phosphorus
- compounds
- different
- nitrogen atom
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 18
- 229910052698 phosphorus Inorganic materials 0.000 title claims description 14
- 229910052799 carbon Inorganic materials 0.000 title claims description 13
- 229910052757 nitrogen Inorganic materials 0.000 title claims description 13
- 125000004433 nitrogen atom Chemical group N* 0.000 title claims description 13
- 125000004437 phosphorous atom Chemical group 0.000 title claims description 13
- 125000004432 carbon atom Chemical group C* 0.000 title claims description 12
- 230000002363 herbicidal effect Effects 0.000 title claims description 8
- 150000003018 phosphorus compounds Chemical class 0.000 title claims description 6
- 238000004519 manufacturing process Methods 0.000 title description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 claims description 13
- 239000000047 product Substances 0.000 claims description 11
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 10
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 claims description 10
- 150000003335 secondary amines Chemical class 0.000 claims description 10
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 9
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Natural products NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims description 9
- -1 phosphonomethyl Chemical group 0.000 claims description 9
- 150000003141 primary amines Chemical class 0.000 claims description 7
- 239000004471 Glycine Substances 0.000 claims description 6
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 claims description 6
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 claims description 6
- 108010077895 Sarcosine Proteins 0.000 claims description 5
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 claims description 5
- NBZBKCUXIYYUSX-UHFFFAOYSA-N iminodiacetic acid Chemical compound OC(=O)CNCC(O)=O NBZBKCUXIYYUSX-UHFFFAOYSA-N 0.000 claims description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 5
- 150000003839 salts Chemical class 0.000 claims description 5
- 150000001299 aldehydes Chemical class 0.000 claims description 4
- 235000019270 ammonium chloride Nutrition 0.000 claims description 4
- 239000012467 final product Substances 0.000 claims description 4
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 3
- 239000003960 organic solvent Substances 0.000 claims description 3
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 claims description 3
- 125000003630 glycyl group Chemical group [H]N([H])C([H])([H])C(*)=O 0.000 claims description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 description 13
- 239000000203 mixture Substances 0.000 description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 239000006227 byproduct Substances 0.000 description 5
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical class OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 description 5
- 238000010992 reflux Methods 0.000 description 5
- 238000009835 boiling Methods 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 4
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 150000003863 ammonium salts Chemical class 0.000 description 3
- 239000008098 formaldehyde solution Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- MOFCYHDQWIZKMY-UHFFFAOYSA-N chloromethylphosphonic acid Chemical compound OP(O)(=O)CCl MOFCYHDQWIZKMY-UHFFFAOYSA-N 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 238000002955 isolation Methods 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- SGVDYFNFBJGOHB-UHFFFAOYSA-N 2-[methyl(phosphonomethyl)amino]acetic acid Chemical compound OC(=O)CN(C)CP(O)(O)=O SGVDYFNFBJGOHB-UHFFFAOYSA-N 0.000 description 1
- HAAZMOAXEMIBAJ-UHFFFAOYSA-N 4-chloro-2-methylquinazoline Chemical compound C1=CC=CC2=NC(C)=NC(Cl)=C21 HAAZMOAXEMIBAJ-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- YNGIKVRSMOSWQG-UHFFFAOYSA-N C(#N)C1N(N(N(CC1)C)C#N)C#N Chemical compound C(#N)C1N(N(N(CC1)C)C#N)C#N YNGIKVRSMOSWQG-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000001414 amino alcohols Chemical class 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 244000038559 crop plants Species 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000011964 heteropoly acid Substances 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 229940043230 sarcosine Drugs 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000006188 syrup Substances 0.000 description 1
- 235000020357 syrup Nutrition 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- RUQUOAVFUOAURH-UHFFFAOYSA-N triazine-4,5,6-tricarbonitrile Chemical class N#CC1=NN=NC(C#N)=C1C#N RUQUOAVFUOAURH-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
- C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Molecular Biology (AREA)
- Agronomy & Crop Science (AREA)
- Biochemistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Luminescent Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| HU78NI213A HU177486B (en) | 1978-04-11 | 1978-04-11 | Process for preparing phosphonic acid derivatives |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL214793A1 PL214793A1 (es) | 1980-01-02 |
| PL123998B1 true PL123998B1 (en) | 1982-12-31 |
Family
ID=11000006
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL1979214793A PL123998B1 (en) | 1978-04-11 | 1979-04-10 | Process for manufacturing herbicidal phosphorus compounds,in which phosphorus atom is linked with nitrogen atom via carbon atom |
Country Status (30)
| Country | Link |
|---|---|
| JP (1) | JPS554362A (es) |
| AR (1) | AR227625A1 (es) |
| AT (1) | AT373602B (es) |
| BE (1) | BE875501A (es) |
| BG (1) | BG34334A3 (es) |
| BR (1) | BR7900568A (es) |
| CA (1) | CA1135279A (es) |
| CH (1) | CH642666A5 (es) |
| CS (1) | CS239903B2 (es) |
| DD (1) | DD142888A5 (es) |
| DE (1) | DE2914294C2 (es) |
| DK (1) | DK149473C (es) |
| EG (1) | EG13622A (es) |
| ES (1) | ES471960A1 (es) |
| FR (1) | FR2422675B1 (es) |
| GB (1) | GB2021589B (es) |
| GR (1) | GR67713B (es) |
| HU (1) | HU177486B (es) |
| IL (1) | IL57008A0 (es) |
| IN (1) | IN149779B (es) |
| IT (1) | IT1118553B (es) |
| LU (1) | LU81126A1 (es) |
| NL (1) | NL7902854A (es) |
| NO (1) | NO160373C (es) |
| PL (1) | PL123998B1 (es) |
| PT (1) | PT69461A (es) |
| RO (1) | RO78631A (es) |
| SU (1) | SU776561A3 (es) |
| TR (1) | TR20811A (es) |
| YU (1) | YU41154B (es) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IL72142A0 (en) * | 1983-08-17 | 1984-10-31 | Stauffer Chemical Co | Preparation of phosphonomethylated amino acids |
| GB2154588B (en) * | 1984-02-20 | 1987-10-07 | Sunlead Chemical Industry Co L | A process for preparation of n-phosphonomethyl glycine |
| JPS6134834U (ja) * | 1985-07-24 | 1986-03-03 | 三菱農機株式会社 | 施肥装置付乗用水田作業機における肥料タンク等の取付装置 |
| HU205944B (en) * | 1988-02-08 | 1992-07-28 | Nitrokemia Ipartelepek | Process for producing n-phosphono-methyl-imino-diacetic acid |
| GB8825589D0 (en) * | 1988-11-02 | 1988-12-07 | Albright & Wilson | Purification |
| HU203360B (en) * | 1988-11-25 | 1991-07-29 | Monsanto Co | Process for producing n-acylamino methylphosphonates |
| JP2525977B2 (ja) * | 1991-10-17 | 1996-08-21 | 昭和電工株式会社 | Ｎ−アシルアミノメチルホスホン酸の製造法 |
| US5495042A (en) * | 1993-11-04 | 1996-02-27 | Cytogen Corporation | Non-alkaline purification of aminophosphonic acids |
| TR200402620T4 (tr) * | 2001-01-12 | 2004-11-22 | Basf Aktiengesellschaft | N-fosfonometiliminodiasetik asidin imali için yöntem |
| CN100400543C (zh) * | 2006-09-08 | 2008-07-09 | 四川贝尔实业有限责任公司 | 亚氨基二乙腈水解制备双甘膦的方法 |
-
1978
- 1978-04-11 HU HU78NI213A patent/HU177486B/hu not_active IP Right Cessation
- 1978-07-21 ES ES471960A patent/ES471960A1/es not_active Expired
- 1978-08-03 SU SU782643651A patent/SU776561A3/ru active
-
1979
- 1979-01-30 BR BR7900568A patent/BR7900568A/pt unknown
- 1979-03-30 CH CH296679A patent/CH642666A5/de not_active IP Right Cessation
- 1979-04-03 GR GR58770A patent/GR67713B/el unknown
- 1979-04-03 GB GB7911510A patent/GB2021589B/en not_active Expired
- 1979-04-03 IN IN332/CAL/79A patent/IN149779B/en unknown
- 1979-04-03 FR FR7908315A patent/FR2422675B1/fr not_active Expired
- 1979-04-05 IL IL57008A patent/IL57008A0/xx unknown
- 1979-04-06 LU LU81126A patent/LU81126A1/xx unknown
- 1979-04-06 CS CS792378A patent/CS239903B2/cs unknown
- 1979-04-07 EG EG208/79A patent/EG13622A/xx active
- 1979-04-09 AT AT0263179A patent/AT373602B/de not_active IP Right Cessation
- 1979-04-09 DE DE2914294A patent/DE2914294C2/de not_active Expired
- 1979-04-09 RO RO7997178A patent/RO78631A/ro unknown
- 1979-04-10 TR TR20811A patent/TR20811A/xx unknown
- 1979-04-10 YU YU850/79A patent/YU41154B/xx unknown
- 1979-04-10 DK DK148679A patent/DK149473C/da not_active IP Right Cessation
- 1979-04-10 PL PL1979214793A patent/PL123998B1/pl unknown
- 1979-04-10 BG BG043195A patent/BG34334A3/xx unknown
- 1979-04-10 PT PT69461A patent/PT69461A/pt unknown
- 1979-04-10 NO NO791217A patent/NO160373C/no unknown
- 1979-04-11 JP JP4409879A patent/JPS554362A/ja active Pending
- 1979-04-11 AR AR276155A patent/AR227625A1/es active
- 1979-04-11 BE BE0/194546A patent/BE875501A/xx not_active IP Right Cessation
- 1979-04-11 NL NL7902854A patent/NL7902854A/xx not_active Application Discontinuation
- 1979-04-11 CA CA000325294A patent/CA1135279A/en not_active Expired
- 1979-04-11 DD DD79212157A patent/DD142888A5/de not_active IP Right Cessation
- 1979-04-11 IT IT67767/79A patent/IT1118553B/it active
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