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PE20060779A1 - PROCESS FOR THE PREPARATION OF A FUEL ADDITIVE CONTAINING LIQUID OR LIQUID HYDROCARBONS IN DIRECT FIRE OR OPEN FLAME BURNERS - Google Patents

PROCESS FOR THE PREPARATION OF A FUEL ADDITIVE CONTAINING LIQUID OR LIQUID HYDROCARBONS IN DIRECT FIRE OR OPEN FLAME BURNERS

Info

Publication number
PE20060779A1
PE20060779A1 PE2005001146A PE2005001146A PE20060779A1 PE 20060779 A1 PE20060779 A1 PE 20060779A1 PE 2005001146 A PE2005001146 A PE 2005001146A PE 2005001146 A PE2005001146 A PE 2005001146A PE 20060779 A1 PE20060779 A1 PE 20060779A1
Authority
PE
Peru
Prior art keywords
fuel
solvent
combustion
additive
mixing
Prior art date
Application number
PE2005001146A
Other languages
Spanish (es)
Inventor
Dwight M Smith
Sam Wernli
Abdul R Chughtai
Original Assignee
Envirofuels Lp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Envirofuels Lp filed Critical Envirofuels Lp
Publication of PE20060779A1 publication Critical patent/PE20060779A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L9/00—Treating solid fuels to improve their combustion
    • C10L9/10—Treating solid fuels to improve their combustion by using additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/0004—Preparation of sols
    • B01J13/0008—Sols of inorganic materials in water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/0004—Preparation of sols
    • B01J13/0026—Preparation of sols containing a liquid organic phase
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/0086—Preparation of sols by physical processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1283—Inorganic compounds phosphorus, arsenicum, antimonium containing compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/02—Use of additives to fuels or fires for particular purposes for reducing smoke development
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/003—Additives for gaseous fuels
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1233—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof
    • C10L1/125—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/16—Hydrocarbons
    • C10L1/1616—Hydrocarbons fractions, e.g. lubricants, solvents, naphta, bitumen, tars, terpentine
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/16—Hydrocarbons
    • C10L1/1625—Hydrocarbons macromolecular compounds
    • C10L1/1633—Hydrocarbons macromolecular compounds homo- or copolymers obtained by reactions only involving carbon-to carbon unsaturated bonds
    • C10L1/1641—Hydrocarbons macromolecular compounds homo- or copolymers obtained by reactions only involving carbon-to carbon unsaturated bonds from compounds containing aliphatic monomers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/188—Carboxylic acids; metal salts thereof
    • C10L1/1881—Carboxylic acids; metal salts thereof carboxylic group attached to an aliphatic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/192—Macromolecular compounds
    • C10L1/198—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid
    • C10L1/1985—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid polyethers, e.g. di- polygylcols and derivatives; ethers - esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/234—Macromolecular compounds
    • C10L1/238—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C10L1/2383—Polyamines or polyimines, or derivatives thereof (poly)amines and imines; derivatives thereof (substituted by a macromolecular group containing 30C)

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)

Abstract

DONDE EL PROCESO COMPRENDE: a) MEZCLAR LAS SALES [Y]xH2PO4 Y [Y]x+HPO4, EN DONDE [Y] ES UN CATION DE ELEMENTOS DEL GRUPO IA, EN UN DISOLVENTE QUE POR LO MENOS PARCIALMENTE DISPERSA LAS SALES EN EL DISOLVENTE, PARA PREPARAR UNA SOLUCION MADRE CONTENIENDO FOSFORO; b) MEZCLAR LA SOLUCION MADRE CON UN FLUIDO DE DISPERSION, TAL QUE LA SOLUCION MADRE ESTA GENERALMENTE DISPERSA EN EL FLUIDO; Y, c) REMOVER UNA PORCION SUSTANCIAL DEL DISOLVENTE DE LA MEZCLA DE LA SOLUCION MADRE CON EL FLUIDO DE DISPERSION, PARA PREPARAR EL ADITIVO CAPAZ DE MEJORAR LA COMBUSTION CUANDO ES AGREGADO A UN QUEMADOR DE FUEGO DIRECTO O LLAMA ABIERTA EN PRESENCIA DE UN COMBUSTIBLE CONTENIENDO HIDROCARBURO Y PUESTO EN COMBUSTION, SIENDO LA MEJORIA DE COMBUSTION MEDIDA POR EL AUMENTO EN LA EFICIENCIA COMBUSTIBLE O DISMINUCION EN LA EMISION DE CONTAMINANTES EN EL GAS EXPULSADO RESULTANTE DE LA COMBUSTION DEL COMBUSTIBLE Y EL ADITIVO. EL ADITIVO COMPRENDE ADEMAS [NH4]2HPO4 Y NH4C2H3O2 DONDE C2H3O2 ES UN GRUPO ACETATO. EL pH DE LA SOLUCION ES ENTRE 6 Y 8, Y EL DISOLVENTE ES AGUA U ALCOHOLES. EL FOSFORO ESTA PRESENTE EN EL COMBUSTIBLE MEJORADO EN UNA CANTIDAD ENTRE 1 Y 150 ppm EN PESO. UNA COMPOSICION QUIMICA ADITIVA INCLUYENDO PRODUCTOS DE REACCION DEL MEZCLADO DE UNA FUENTE DE ACIDO FOSFORICO, UN HIDROXIDO DE METAL ALCALINO, HIDROXIDO DE AMONIO, ACIDO ACETICO Y AGUA, SE AGREGA AL COMBUSTIBLE PARA MEJORAR SU DESEMPENOWHERE THE PROCESS INCLUDES: a) MIXING THE SALTS [Y] xH2PO4 AND [Y] x + HPO4, WHERE [Y] IS A CATION OF ELEMENTS OF GROUP IA, IN A SOLVENT THAT AT LEAST PARTIALLY DISPERSES THE SALTS IN THE SOLVENT , TO PREPARE A STEM SOLUTION CONTAINING PHOSPHORUS; b) MIXING THE STEM SOLUTION WITH A DISPERSION FLUID, SUCH THAT THE STEM SOLUTION IS GENERALLY DISPERSED IN THE FLUID; AND, c) REMOVE A SUBSTANTIAL PORTION OF THE SOLVENT FROM THE MIXTURE OF THE STEM SOLUTION WITH THE DISPERSION FLUID, TO PREPARE THE ADDITIVE CAPABLE OF IMPROVING COMBUSTION WHEN IT IS ADDED TO A DIRECT FIRE BURNER OR AN OPEN FLAME IN THE PRESENCE OF A CONTINUABLE FUEL. HYDROCARBON AND COMBUSTION, BEING THE IMPROVEMENT OF COMBUSTION MEASURED BY THE INCREASE IN FUEL EFFICIENCY OR DECREASE IN THE EMISSION OF POLLUTANTS IN THE EXPULED GAS RESULTING FROM THE COMBUSTION OF THE FUEL AND THE ADDITIVE. THE ADDITIVE ALSO INCLUDES [NH4] 2HPO4 AND NH4C2H3O2 WHERE C2H3O2 IS AN ACETATE GROUP. THE pH OF THE SOLUTION IS BETWEEN 6 AND 8, AND THE SOLVENT IS WATER OR ALCOHOLS. PHOSPHORUS IS PRESENT IN THE ENHANCED FUEL IN AN AMOUNT BETWEEN 1 AND 150 ppm BY WEIGHT. AN ADDITIVE CHEMICAL COMPOSITION INCLUDING REACTION PRODUCTS FROM THE MIXING OF A SOURCE OF PHOSPHORIC ACID, AN ALKALINE METAL HYDROXIDE, AMMONIUM HYDROXIDE, ACETIC ACID AND WATER, IS ADDED TO THE FUEL TO IMPROVE ITS PERFORMANCE

PE2005001146A 2004-09-28 2005-09-28 PROCESS FOR THE PREPARATION OF A FUEL ADDITIVE CONTAINING LIQUID OR LIQUID HYDROCARBONS IN DIRECT FIRE OR OPEN FLAME BURNERS PE20060779A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US61369904P 2004-09-28 2004-09-28

Publications (1)

Publication Number Publication Date
PE20060779A1 true PE20060779A1 (en) 2006-09-02

Family

ID=35645607

Family Applications (1)

Application Number Title Priority Date Filing Date
PE2005001146A PE20060779A1 (en) 2004-09-28 2005-09-28 PROCESS FOR THE PREPARATION OF A FUEL ADDITIVE CONTAINING LIQUID OR LIQUID HYDROCARBONS IN DIRECT FIRE OR OPEN FLAME BURNERS

Country Status (18)

Country Link
US (1) US20060179709A1 (en)
EP (1) EP1807486A1 (en)
JP (1) JP2008514766A (en)
KR (1) KR20070072893A (en)
CN (1) CN101065465A (en)
AR (1) AR051303A1 (en)
AU (1) AU2005289403A1 (en)
BR (1) BRPI0516153A (en)
CA (1) CA2581563A1 (en)
CR (1) CR9049A (en)
EA (1) EA200700755A1 (en)
IL (1) IL182137A0 (en)
MX (1) MX2007003772A (en)
PE (1) PE20060779A1 (en)
SV (1) SV2006002239A (en)
UY (1) UY29142A1 (en)
WO (1) WO2006037094A1 (en)
ZA (1) ZA200703377B (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006116070A2 (en) * 2005-04-22 2006-11-02 Envirofuels, L.L.C. Additive for hydrocarbon fuel consisting of non-acidic inorganic compounds of boron and related processes
WO2007136548A2 (en) * 2006-05-15 2007-11-29 Envirofuels, Llc Additive for hydrocarbon fuel and related processes consisting of compounds of adenosine phosphates
WO2008057232A2 (en) * 2006-10-26 2008-05-15 Envirofuels, Llc Process to make phosphate salt containing products

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Also Published As

Publication number Publication date
BRPI0516153A (en) 2008-08-26
AU2005289403A1 (en) 2006-04-06
CA2581563A1 (en) 2006-04-06
SV2006002239A (en) 2006-06-23
CR9049A (en) 2007-05-30
EA200700755A1 (en) 2007-10-26
MX2007003772A (en) 2008-10-24
KR20070072893A (en) 2007-07-06
US20060179709A1 (en) 2006-08-17
WO2006037094A1 (en) 2006-04-06
UY29142A1 (en) 2006-11-30
AR051303A1 (en) 2007-01-03
IL182137A0 (en) 2007-07-24
EP1807486A1 (en) 2007-07-18
CN101065465A (en) 2007-10-31
ZA200703377B (en) 2008-09-25
JP2008514766A (en) 2008-05-08

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