NO325283B1 - Fremstilling av metanol - Google Patents
Fremstilling av metanol Download PDFInfo
- Publication number
- NO325283B1 NO325283B1 NO19996105A NO996105A NO325283B1 NO 325283 B1 NO325283 B1 NO 325283B1 NO 19996105 A NO19996105 A NO 19996105A NO 996105 A NO996105 A NO 996105A NO 325283 B1 NO325283 B1 NO 325283B1
- Authority
- NO
- Norway
- Prior art keywords
- gas
- synthesis
- mixture
- methanol
- steam
- Prior art date
Links
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title claims abstract description 174
- 239000007789 gas Substances 0.000 claims abstract description 169
- 238000003786 synthesis reaction Methods 0.000 claims abstract description 114
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 113
- 239000003054 catalyst Substances 0.000 claims abstract description 50
- 239000000203 mixture Substances 0.000 claims abstract description 39
- 238000000034 method Methods 0.000 claims abstract description 29
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 28
- 238000002407 reforming Methods 0.000 claims abstract description 28
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 27
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 25
- 239000001257 hydrogen Substances 0.000 claims abstract description 21
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 230000006835 compression Effects 0.000 claims abstract description 13
- 238000007906 compression Methods 0.000 claims abstract description 13
- 238000001816 cooling Methods 0.000 claims abstract description 9
- 229910002090 carbon oxide Inorganic materials 0.000 claims abstract description 7
- 238000000926 separation method Methods 0.000 claims abstract description 7
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000004519 manufacturing process Methods 0.000 claims abstract description 6
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims abstract 2
- 239000007858 starting material Substances 0.000 claims description 48
- 238000000629 steam reforming Methods 0.000 claims description 14
- 239000000567 combustion gas Substances 0.000 claims description 8
- 238000004891 communication Methods 0.000 claims description 7
- 238000012546 transfer Methods 0.000 claims description 4
- 238000002485 combustion reaction Methods 0.000 abstract description 15
- 238000001193 catalytic steam reforming Methods 0.000 abstract 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 28
- 239000000047 product Substances 0.000 description 18
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 12
- 238000011084 recovery Methods 0.000 description 11
- 239000000376 reactant Substances 0.000 description 10
- 239000010410 layer Substances 0.000 description 9
- 229910052799 carbon Inorganic materials 0.000 description 8
- 239000002826 coolant Substances 0.000 description 8
- 239000000446 fuel Substances 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- 150000002431 hydrogen Chemical class 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
- 238000004821 distillation Methods 0.000 description 6
- 229910052759 nickel Inorganic materials 0.000 description 6
- 239000003345 natural gas Substances 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 238000006057 reforming reaction Methods 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- XFWJKVMFIVXPKK-UHFFFAOYSA-N calcium;oxido(oxo)alumane Chemical compound [Ca+2].[O-][Al]=O.[O-][Al]=O XFWJKVMFIVXPKK-UHFFFAOYSA-N 0.000 description 3
- 239000004568 cement Substances 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000003507 refrigerant Substances 0.000 description 3
- 239000002356 single layer Substances 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 239000000498 cooling water Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 150000003464 sulfur compounds Chemical class 0.000 description 2
- 239000013589 supplement Substances 0.000 description 2
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- YZCKVEUIGOORGS-IGMARMGPSA-N Protium Chemical compound [1H] YZCKVEUIGOORGS-IGMARMGPSA-N 0.000 description 1
- 241001233279 Scalopus Species 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- -1 atom hydrocarbon Chemical class 0.000 description 1
- 235000013844 butane Nutrition 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- KYYSIVCCYWZZLR-UHFFFAOYSA-N cobalt(2+);dioxido(dioxo)molybdenum Chemical compound [Co+2].[O-][Mo]([O-])(=O)=O KYYSIVCCYWZZLR-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000112 cooling gas Substances 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000008236 heating water Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical class CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 230000000153 supplemental effect Effects 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D7/00—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
- F28D7/10—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being arranged one within the other, e.g. concentrically
- F28D7/12—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being arranged one within the other, e.g. concentrically the surrounding tube being closed at one end, e.g. return type
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/382—Multi-step processes
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- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
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- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/384—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
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- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/1516—Multisteps
- C07C29/1518—Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
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- C—CHEMISTRY; METALLURGY
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/0495—Composition of the impurity the impurity being water
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/06—Integration with other chemical processes
- C01B2203/061—Methanol production
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- C—CHEMISTRY; METALLURGY
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- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
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- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
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- C01B2203/0822—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel the fuel containing hydrogen
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- C01B2203/0827—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel at least part of the fuel being a recycle stream
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
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- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0833—Heating by indirect heat exchange with hot fluids, other than combustion gases, product gases or non-combustive exothermic reaction product gases
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
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- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
- C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1052—Nickel or cobalt catalysts
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- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
- C01B2203/1241—Natural gas or methane
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
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- C01B2203/1258—Pre-treatment of the feed
- C01B2203/1264—Catalytic pre-treatment of the feed
- C01B2203/127—Catalytic desulfurisation
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- C01B2203/14—Details of the flowsheet
- C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
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- C01B2203/148—Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB9712209.7A GB9712209D0 (en) | 1997-06-13 | 1997-06-13 | Methanol |
| PCT/GB1998/001670 WO1998056744A1 (fr) | 1997-06-13 | 1998-06-08 | Clef electronique pour ordinateur |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO996105L NO996105L (no) | 1999-12-10 |
| NO996105D0 NO996105D0 (no) | 1999-12-10 |
| NO325283B1 true NO325283B1 (no) | 2008-03-17 |
Family
ID=10814024
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO19996105A NO325283B1 (no) | 1997-06-13 | 1999-12-10 | Fremstilling av metanol |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US6255357B1 (fr) |
| EP (1) | EP0988267B1 (fr) |
| JP (1) | JP4004550B2 (fr) |
| AT (1) | ATE252071T1 (fr) |
| AU (1) | AU728230B2 (fr) |
| CA (1) | CA2289643C (fr) |
| DE (1) | DE69818996T2 (fr) |
| DK (1) | DK0988267T3 (fr) |
| GB (1) | GB9712209D0 (fr) |
| NO (1) | NO325283B1 (fr) |
| WO (1) | WO1998056744A1 (fr) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2365019A (en) * | 2000-06-06 | 2002-02-13 | Ici Plc | Primary steam reforming plant |
| JP4959074B2 (ja) * | 2001-07-19 | 2012-06-20 | 三菱重工業株式会社 | メタノールの製造方法 |
| JP4781612B2 (ja) * | 2003-04-18 | 2011-09-28 | 三菱重工業株式会社 | メタノールの製造方法 |
| JP4496950B2 (ja) * | 2004-01-09 | 2010-07-07 | 株式会社日立製作所 | 改質炉システム |
| AU2006339054B2 (en) * | 2005-09-23 | 2012-07-12 | Heatric | Multiple reactor chemical production system |
| DK1928592T3 (da) * | 2005-09-23 | 2014-09-29 | Heatric | Kemisk produktionssystem med flere reaktorer |
| AU2012227278B2 (en) * | 2005-09-23 | 2014-06-05 | Heatric | Multiple reactor chemical production system |
| US20080260631A1 (en) | 2007-04-18 | 2008-10-23 | H2Gen Innovations, Inc. | Hydrogen production process |
| US9083020B2 (en) * | 2009-09-04 | 2015-07-14 | Lg Fuel Cell Systems Inc. | Reducing gas generators and methods for generating reducing gas |
| KR101777597B1 (ko) | 2010-12-22 | 2017-09-27 | 대우조선해양 주식회사 | 해상용 메탄올 생산 시스템 |
| CN102322353B (zh) * | 2011-05-30 | 2014-01-01 | 重庆大学 | 一种提高燃气轮机循环热效率的方法 |
| CN102220903B (zh) * | 2011-05-30 | 2014-01-01 | 重庆大学 | 基于甲烷燃烧-重整的提高燃气轮机循环热力性能的方法 |
| CN102213142B (zh) * | 2011-05-30 | 2014-01-01 | 重庆大学 | 基于甲烷重整提高燃气轮机再热循环热效率的方法 |
| CN104321272B (zh) * | 2012-03-30 | 2018-01-30 | 孟山都技术公司 | 用于将醇重整成包括氢的气体的混合物的醇重整器 |
| US9174903B2 (en) | 2013-03-15 | 2015-11-03 | Gas Technologies Llc | Reactive scrubbing for upgrading product value, simplifying process operation and product handling |
| US20140275634A1 (en) | 2013-03-15 | 2014-09-18 | Gas Technologies Llc | Ether Blends Via Reactive Distillation |
| US9255051B2 (en) * | 2013-03-15 | 2016-02-09 | Gas Technologies Llc | Efficiency, flexibility, and product value of a direct alkanes to oxygenates process |
| US9587189B2 (en) | 2013-10-01 | 2017-03-07 | Gas Technologies L.L.C. | Diesel fuel composition |
| KR101790102B1 (ko) | 2014-08-04 | 2017-10-25 | 한국화학연구원 | 이산화탄소의 배출을 저감시킬 수 있는 고효율 메탄올 생산 방법 |
| JP6663211B2 (ja) * | 2015-12-04 | 2020-03-11 | 三菱重工エンジニアリング株式会社 | メタノール製造システム及び製造方法 |
| EP3181218A1 (fr) * | 2015-12-15 | 2017-06-21 | L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Systeme collecteur de produit gazeux pour un epurateur a la vapeur |
| CN105756782A (zh) * | 2016-04-15 | 2016-07-13 | 浙江大学 | 一种太阳能化学回热燃气轮机系统及其方法 |
| RU2616977C1 (ru) * | 2016-05-26 | 2017-04-19 | Андрей Владиславович Курочкин | Установка синтеза метанола |
| RU2619101C1 (ru) * | 2016-05-26 | 2017-05-12 | Андрей Владиславович Курочкин | Установка получения метанола из углеводородного сырья |
| EP3532430B1 (fr) * | 2016-10-25 | 2020-07-01 | Technip France | Tube de catalyseur pour reformage à la vapeur |
| EP3714971B1 (fr) | 2019-03-28 | 2022-02-02 | Sener, Ingeniería y Sistemas, S.A. | Système et procédé de production de méthanol à partir d'un gaz de synthèse riche en hydrogène et co2/co |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4239693A (en) * | 1979-06-22 | 1980-12-16 | Foster Wheeler Energy Corporation | Process for production of methanol |
| GB8803766D0 (en) * | 1988-02-18 | 1988-03-16 | Ici Plc | Methanol |
| GB9000389D0 (en) * | 1990-01-08 | 1990-03-07 | Ici Plc | Steam reforming |
| US5177114A (en) * | 1990-04-11 | 1993-01-05 | Starchem Inc. | Process for recovering natural gas in the form of a normally liquid carbon containing compound |
| US5472986A (en) * | 1994-11-08 | 1995-12-05 | Starchem, Inc. | Methanol production process using a high nitrogen content synthesis gas with a hydrogen recycle |
-
1997
- 1997-06-13 GB GBGB9712209.7A patent/GB9712209D0/en active Pending
-
1998
- 1998-06-08 CA CA002289643A patent/CA2289643C/fr not_active Expired - Fee Related
- 1998-06-08 EP EP98928431A patent/EP0988267B1/fr not_active Expired - Lifetime
- 1998-06-08 DE DE69818996T patent/DE69818996T2/de not_active Expired - Lifetime
- 1998-06-08 WO PCT/GB1998/001670 patent/WO1998056744A1/fr active IP Right Grant
- 1998-06-08 JP JP50188599A patent/JP4004550B2/ja not_active Expired - Fee Related
- 1998-06-08 AT AT98928431T patent/ATE252071T1/de not_active IP Right Cessation
- 1998-06-08 AU AU80263/98A patent/AU728230B2/en not_active Ceased
- 1998-06-08 DK DK98928431T patent/DK0988267T3/da active
-
1999
- 1999-12-10 NO NO19996105A patent/NO325283B1/no not_active IP Right Cessation
- 1999-12-13 US US09/459,843 patent/US6255357B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DK0988267T3 (da) | 2004-01-19 |
| JP2002504111A (ja) | 2002-02-05 |
| ATE252071T1 (de) | 2003-11-15 |
| GB9712209D0 (en) | 1997-08-13 |
| CA2289643C (fr) | 2007-08-28 |
| EP0988267B1 (fr) | 2003-10-15 |
| CA2289643A1 (fr) | 1998-12-17 |
| AU8026398A (en) | 1998-12-30 |
| NO996105L (no) | 1999-12-10 |
| EP0988267A1 (fr) | 2000-03-29 |
| WO1998056744A1 (fr) | 1998-12-17 |
| US6255357B1 (en) | 2001-07-03 |
| DE69818996T2 (de) | 2004-09-02 |
| NO996105D0 (no) | 1999-12-10 |
| DE69818996D1 (de) | 2003-11-20 |
| JP4004550B2 (ja) | 2007-11-07 |
| AU728230B2 (en) | 2001-01-04 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM1K | Lapsed by not paying the annual fees |