NO20180369A1 - Cathode elements for a Hall-Héroult cell for aluminium production and a cell of this type having such elements installed - Google Patents
Cathode elements for a Hall-Héroult cell for aluminium production and a cell of this type having such elements installed Download PDFInfo
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- NO20180369A1 NO20180369A1 NO20180369A NO20180369A NO20180369A1 NO 20180369 A1 NO20180369 A1 NO 20180369A1 NO 20180369 A NO20180369 A NO 20180369A NO 20180369 A NO20180369 A NO 20180369A NO 20180369 A1 NO20180369 A1 NO 20180369A1
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- element according
- cathode
- collector
- cathode element
- collector plate
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- 239000004411 aluminium Substances 0.000 title claims description 6
- 229910052782 aluminium Inorganic materials 0.000 title claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims description 6
- 238000004519 manufacturing process Methods 0.000 title description 5
- 239000004020 conductor Substances 0.000 claims description 57
- 239000002245 particle Substances 0.000 claims description 20
- 239000000463 material Substances 0.000 claims description 18
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 16
- 229910052802 copper Inorganic materials 0.000 claims description 16
- 239000010949 copper Substances 0.000 claims description 16
- 230000000295 complement effect Effects 0.000 claims description 9
- 238000003780 insertion Methods 0.000 claims description 9
- 230000037431 insertion Effects 0.000 claims description 9
- 238000005868 electrolysis reaction Methods 0.000 claims description 5
- 229910045601 alloy Inorganic materials 0.000 claims description 4
- 239000000956 alloy Substances 0.000 claims description 4
- 230000001681 protective effect Effects 0.000 claims description 4
- 239000007769 metal material Substances 0.000 claims description 3
- AYFVYJQAPQTCCC-GBXIJSLDSA-N L-threonine Chemical compound C[C@@H](O)[C@H](N)C(O)=O AYFVYJQAPQTCCC-GBXIJSLDSA-N 0.000 claims 1
- 229910000831 Steel Inorganic materials 0.000 description 16
- 239000010959 steel Substances 0.000 description 16
- 238000009826 distribution Methods 0.000 description 10
- 238000009434 installation Methods 0.000 description 6
- 238000007789 sealing Methods 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 229910001018 Cast iron Inorganic materials 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000009413 insulation Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000003575 carbonaceous material Substances 0.000 description 3
- 230000009975 flexible effect Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000011144 upstream manufacturing Methods 0.000 description 3
- 238000003466 welding Methods 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000013011 mating Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 230000000284 resting effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
- C25C7/02—Electrodes; Connections thereof
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
- C25C3/08—Cell construction, e.g. bottoms, walls, cathodes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
- C25C3/16—Electric current supply devices, e.g. bus bars
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
- Cell Electrode Carriers And Collectors (AREA)
- Primary Cells (AREA)
Description
The present invention relates to cathode elements for a Hall-Héroult cell for aluminiu production and a cell of this type having such elements installed.
Commonly, cathode elements for aluminium production cells are made of pre-baked catho blocks or bodies of a calcined carbonaceous material, the bodies having preformed gro or slots in the bottom thereof that allow current leads such as collector bars to be entered i them and rodded to it. The space between the wall of the slots and the bars can commonly filled with melted cast-iron or a contacting paste or glue for the fixation of said collector bar Several cathode elements are installed in the cell and form together the cathode.
In accordance with the Applicants own W02009/099335A1 there is applied electric conductive particles as a fill-in material between the electrical current conductor and the carbonace body of calcinated carbonaceous material in an electrode. The use of electric conduct particles without a hardening matrix facilitates mobility of the conductive particles for electri current when the geometry changes over time e.g. due to thermal expansion. The electri resistance in a cathode element where such particles is applied has been observed to improved with reference to commonly used contact paste or melted cast-iron. In Fig. 9 of sai WO-document it is disclosed an end-view of a cathode block having recesses or slots in it lower part. There are arranged collector elements into the slots, where the remaining spac filled with electric conductive particles. The collector elements are fixed to a collector plate th collects the current and that further secures stability of the cathode element and giv additional contact area.
The present invention relates to cathode elements based upon collector plates w carbonaceous bodies where it is included several novel and inventive features in t construction thereof. Some main elements are related to;
-horizontal current outlets (HO)
-vertical current outlet(s) (VO)
-conductor elements and their extension in combination with use of electric insulati and protective sheet material
-fixation of conductor elements
-arrangement of the current outlets with regard to the collector plates of the catho elements.
According to a characteristic feature of claim 1, the collector plate can comprise at least on horizontal current outlet on at least one side and/or at least one vertical metallic current ou connected to the collector plate.
Advantageously the collector plate can be planar without protruding collector elements an carbonaceous body can be without matching slots, the rodding material simply forms a lay of electric conductive material, that may comprise electrical conductive particles (0 -100 wt%), arranged in a space between the collector plate and the carbonaceous body.
In an embodiment of the invention, the carbonaceous body is rodded to the collector pla a manner where the outer end part of the carbonaceous body is electrically insulated from collector plate, at a distance up to 450 mm from the end thereof and inwards.
In one other embodiment, the carbonaceous body is rodded to the collector plate in a ma where the outer end parts of the carbonaceous body are electrically insulated from the colle plate at different lengths on the two ends of the plate (asymmetric configuration).
In one embodiment, at least one thermocouple (TC) is inserted into a metallic compone inside of or below the collector plate to be able to monitor the temperature at that location.
In one other embodiment, the at least one horizontal current outlet is integrated with t collector plate.
In a further embodiment, it is integrated in a slot in said collector plate.
In another embodiment, the horizontal current outlet comprises one current conductor integrated with the collector plate by a press-fit (knock) fixation in a recess of the collector plat that is complementary with a corresponding part of the conductor.
In one embodiment, the part of the current conductor integrated to the collector plate h delta shaped part.
In a further embodiment, it comprises at least one horizontal current outlet on each end b integrated with the collector plate.
In one embodiment, the cross section of or the insertion length of the horizontal current o at one end is different to that of the other end (asymmetric).
In still another embodiment the current outlet comprises a copper conductor preferably cove by a protective sheet material.
In one embodiment, there is arranged at least one vertical current outlet at the opposite of the collector plate than the carbonaceous body.
There is one embodiment where the vertical outlet comprise a socket integrated with th collector plate wherein a rod-shaped current conductor is attached to the socket.
In one embodiment, the socket can be of metallic material and welded to the collector plat
In a further embodiment, has an internal recess where an upper part of the current condu has a shape complementary with said recess for fixation of said current conductor to th socket.
In one embodiment, the fixation is a press-fit (knock) fixation.
In one other embodiment, the socket has internal threads at its outermost end for receivin sleeve with complementary external threads, wherein the sleeve surrounds the curre conductor and where the end of the sleeve abuts an annular flange or ring at the curre for forcing the rod into the socket when tightened.
In still another embodiment, there is a threaded bolt at the top of the socket communicati with a threaded bore.
In one embodiment, the current conductor is made out of copper or an alloy thereof.
In one other embodiment, at least one metallic collector element is arranged at the upper of a metallic collector plate, where said collector element is embedded in a correspondi recess in the bottom part of the carbonaceous body, the recess being wider than the colle element and being filled with an electric conductive material comprising conductive particle
In another embodiment, there are one or more collector elements, preferably 3 to 7 be separated at a distance of typically 50 mm to 150 mm.
In still another embodiment, the at least one collector element(s) is of same length or short length than the carbonaceous body.
According to one characteristic feature of claim 23, an electrolysis cell of Hall-Héroult type ca comprise several cathode elements of the invention where the cell is built with several catho elements and in a configuration of only the same type of elements.
According to one other characteristic feature of claim 24, an electrolysis cell of Hall-Héroult type can comprise several cathode elements of the invention where the cell is built with sever cathode elements and in a configuration of different elements.
Advantageously, the collector plate can have one to five inserts of materials with higher elect conductivity, like copper.
Preferably, the collector plate can have horizontal outlets (HO) made from steel or copper some similar good conducting material reaching out of the cathode shell to allow a connect to the cathode flexibles.
Advantageously, each collector plate can have none, one or two HOs on each end according to a different aspect, the HOs can be of rectangular or round cross section.
Preferably, the HO can be inserted into a slot (groove) in the plate from top, which can b closed with a welded steel plate from top, or into open space from the side of the plat preferably when a round cross-section is applied.
Advantageously, the HOs can be attached to the plate by welding, mechanical press fittin thermal press fitting, knock-in cones, threads, or a combination of those to get a stron mechanical and electric feasible connection.
Preferably, the HO can be attached to a delta-shaped insert of good conducting material, copper, to allow a low-resistance for the current flow.
Advantageously, the HOs can be connected to the cathode flexes by welding or clamps.
Preferably, the HOs on both side of the collector plate can have different cross section a insertion depth into the plate to allow a specific electric resistance on each side.
Advantageously, the HOs can be long enough to reach out of the cathode shell, or they short enough to allow a vertical placement of the cathode assembly into the cathode lining
Preferably, there is a round or rectangular opening for each HO in the steel shell.
Advantageously this opening is sealed with a steel frame, a sealing rope and a plate, whic fixed to press on the sealing rope ensuring a tight sealing between shell and HO.
Preferably, one or more VOs can be attached to each cathode assembly from the bottom si to conduct electric current to busbars under the cathode shell.
Advantageously, each VO can be of steel or copper or another good electrical conduct material, and according to one other aspect the cross section can be round or rectangular
Preferably, in a situation where the material of the VO is not steel, then a protecting ste socket on the upper part below the plate can be applied to allow a fixation of the VO with g mechanical and electric contact and protection of the conductive material from aggressiv chemicals or the VO can be protected by a steel tube reaching down to or close to the bott of the steel shell.
Advantageously, the mounting of the VO allows pre-installation to the plate, e.g. by weldi or it can be mounted after the plate is installed into the lining.
Preferably, a sealing like at the HOs can be applied at the VOs.
Advantageously, the space around the VOs can be filled with loose refractory material powder after the bottom shell sealing is applied. This filling can be applied from the side bef the neighbouring cathode assembly is installed.
Preferably, if the length of the HOs is too long to allow a straight vertical placement of th cathode assembly, a swing in has to be applied. If VOs are present, some refractory brick close to the centre of the lining have to be placed after installation of the plate to allo horizontal shift of the assembly.
Advantageously, the difference in thermal expansion at operating temperatures between copper connectors (HOs or VOs) can ensure high pressure at the contact with low electric resistance.
Preferably, the cathode element with collector plate can typically have less height than design with traditional collector bars - when the same height for carbon is assumed - this ext space in height can be used for higher bottom insulation or higher cavity.
The present cathode design has shown to be very advantageous with regard to t magnetohydrodynamic stability of the cell it has been installed in, it has shown to have improved life cycle and space usage and in operation, and it also represents a low cath voltage drop with regard to a conventional cathode design.
These and further advantages will be achieved by the invention as defined in t accompanying claims.
The present invention will in the following be further described by figures and examples wh
Fig. 1 discloses in a first embodiment a divided cathode element, seen in perspective, whe a collector plate is divided in two sections,
Fig. 2 discloses an embodiment of a non-divided cathode element in a cross-section vie where horizontal conductors extend into a collector plate at different lengths and further s from one side, the element having a vertical current outlet,
Fig. 3 discloses a top-side view of the same cathode element as shown in Fig. 2,
Fig. 4 discloses an alternative embodiment of a cathode element without a vertical curre outlet, where horizontal conductors extend into the collector plate at different lengths,
Fig. 5 discloses in a top-side part view of a collector plate like in Fig 1, but the horizontal outl extends to a delta-shaped conductor inside the plate,
Fig. 6 discloses in an enlarged view a cross-section through the cathode element of Fig. seen from one end and discloses further details of one vertical current outlet,
Fig. 7 discloses in an enlarged view an alternative embodiment of the outlet as describe Fig. 6.
Fig. 1 discloses a divided cathode element 1 seen in perspective. In this embodiment t collector plate consists of two sections 20, 20’. In the disclosed embodiment, collector plate sections 20, 20’ can be identical or not and will be described accordingly.
The collector plate section 20’ is provided in this example with six collector elements, 30, 30’ 30” , 30’” , 30” ” , 30’” ” that are in electrical contact with the collector plate section 20’. Preferably, these parts are made out of a steel quality that can easily be welded, and prefer the parts are welded together. A cathode block can be rodded to the collector elements, similar manner as disclosed in W02009/099335A1. The present solution may involve electric conductive particles or a contacting paste. The number of collector elements at the collect plate may differ from six as shown, for instance one to seven or even none.
At each outer end of the collector plate sections 20; 20’, there is arranged two horizontal curre outlets 50, 51; 50’, 5T respectively. The horizontal current outlets can be made out of conductors of a good conducting material like copper or copper alloy and further being, at l at its outlet ends, covered by a sheet material 60, 61; 60’, 6T, preferably made out of a metal such as steel. The horizontal current outlets 50, 51; 50’, 5T with their corresponding conductors can be integrated in slots S, S’; S” , S’” made in the corresponding collector plat sections 20; 20’. This integration may be based upon press-fit tolerances or pre-heated plat sections to use thermal expansion for a tight fit. However, any appropriate fixation includi welding may be applied. The conducting material in the slots may be covered by a protecti steel plate on the upper and lower side.
Further, close to the edge of the short and long sides of the collector plate sections, there be arranged a flexible sealing rope or stopper plates (not shown) intended to facilitate rodding of the plate to a carbonaceous body by means of electrically conductive me particles. When rodding the cathode block to the cathode plate, the outer part of t carbonaceous material closer to the horizontal outlets can preferably be electrically insulat from the cathode plate, for instance 100mm and up to 450mm from the end of the cathod block and inwards to avoid high current densities at the upper surface of the cathode bl close to the ends. The electric insulation can be asymmetric on each of the ends and also di between the cathode elements in the cell.
In Fig. 2 it can be seen a second embodiment of a cathode element T in a cross-section vi seen from one side, where a carbonaceous body 4 is arranged onto a collector plate 2 w is not divided. In this embodiment the collector plate 2 has collector elements, where only o 3 is seen from the side. At each end of the collector plate 2 there is arranged horizontal curr outlets 5, 5’. The horizontal current outlets can be made out of a copper material and be covered by a sheet material 6, 6’, preferably made out of a metal such as steel. It is also briefl disclosed a vertical outlet 7, that will be further described with reference to Fig. 6 and 7.
The cross section of the horizontal outlets may be different at one end of the plate versus t other to compensate for different electric current path lengths of the conducting busbars to next cell, e.g. for side-by-side arranged cells in a row of plural cells. The outlets on th upstream side could have a larger cross-section - either by a greater width or height or bot to reduce the electric resistance on that side of the cell and thus equalize the curre distribution into the top of the cathode block surface. If the conductors of the horizontal out are of a better conducting material than the plate, they can be applied with different inse length on each side of the plate when appropriate.
Fig. 3 discloses a top-side view of the same cathode as shown in Fig.2, with the carbonaceo body 4 laying onto a collector plate 2 with one outlet on each side 5, 5’ covered by sh material 6, 6’. Further, it is indicated a bore B in the collector plate for insertion of a thermocouple TC.
The embodiment shown in Fig. 4 relates to the same embodiment as shown in Fig. 2, howev without a vertical outlet. It discloses a cathode element 1 in a cross-section view seen from one side, where a carbonaceous body 4 is arranged onto a collector plate 2 which is divided, see below. In this embodiment the plate 2 has collector elements, where only one seen from the side. At each end of the collector plate 2 there is arranged horizontal curr outlets 5, 5’. The conductors of the horizontal current outlets can be made out of a cop material and being covered by a sheet material 6, 6’, preferably made out of a metal such steel. The dividing line D in the drawing indicates that the extension of the cathode elem can be varied, i.e. also the intrusion length of the current conductors 5, 5’ in the plate 2 m vary depending upon the actual design.
The current conductors may in principle have a rectangular or round cross-section and as alternative be out of any suitable electrical current conducting material.
Fig.5 discloses partly one end of a collector plate 2 or similarly a collector plate section th may have one single horizontal current outlet 5 at its end which comprises a triangle or de shaped electric conductor 51 made of copper or similar good conducting material to ensur better distribution of the currents leaving the plate 2 and entering into the conductor 51 further to its outlet 5, and by that reducing the electric resistance. The conductor 51 can press-fit inserted into a recess of the plate 2, or attached to it by any appropriate means. one alternative, the conductor could be cast into the recess, by for instance of melt copper. case there is cast an extension beyond the recess outside the plate, it could be done applying an appropriate mould or the similar.
Fig.6 discloses further details of the vertical current outlet 7 as shown in Fig. 2 and represen an enlarged end-view of a cross-section through one end of the cathode of Fig. 2. carbonaceous body 4 is resting onto a collector plate 2 having collector elements 3, 3’, 3” , 3” ” . The carbonaceous body has recesses or slots 9, 9’, 9” , 9” ’, 9” ” complementary with said collector elements. The remaining space between the collector elements and the slots is fill with electric conductive material or particles. The collector elements are in this embodimen fixed to a metallic collector plate 2 that collects the current and secures stability.
The vertical outlet 7 comprises a socket 10 integrated with the collector plate 2 where a rod shaped current conductor 11 can be attached to the socket 10. The conductor 11 can be m of a material with good electric conductivity like copper. The socket 10 can be made of a metallic material like steel and welded or press-fit to the collector plate 2. The vertical outle can be placed in the centre of the plate or asymmetric towards one of the horizontal outlet improve the magnetic field situation or to change the current distribution between horizo and vertical outlets in a desired way.
Further, the socket 10 has an internal recess 17’ where an upper part 17 of the curre conductor 11 has a shape complementary with said recess 17’ for fixation of said curre conductor 11 to the socket 10. The upper part 17 of the current conductor 11 can be provid with threads mating corresponding threads in the upper part of the socket 10. The fixation c be optionally a press-fit (knock) fixation.
Further, in an embodiment or in addition, see Fig. 7, the socket 10’ may have internal threa 13’ at its outermost end for receiving a sleeve 12’ with complementary external threads 16 wherein the sleeve surrounds the current conductor 1T and where the end of the sleeve a an annular flange or ring 14’ at the current rod 1T for forcing the rod 11’ into the socket when tightened. The current conductor 1T is preferably made out of copper or an alloy ther The sleeve 12’ both serves for fixation and protection against reactions of conductor 11’ w liquids or volatiles from the process. Further, it is disclosed a bore B’ for insertion of a thermocouple TC’.
As an alternative to the internal thread 13’ a threaded bolt can be attached inside the t the socket (not shown) and the conductor 11 ’ is fitted with a corresponding threaded bor fix the conductor to the socket (similar to that shown in Fig. 6). A removable connection of th outlet might be needed to allow for a vertical outlet conductor to be attached after the cath is placed with a swing-in movement on top of the bottom lining in the cell during installation
Advantageously, the whole assembly with the carbonaceous body 4 and the collector plat are tilted somewhat during the filling procedure of the particles, to allow the particles to fill t recess in a smooth and complete manner. Additionally some vibration might be applied to t plate or plate sections for homogeneous filling with the particles.
The recesses or slots 9 can be made in a green condition of the carbonaceous body commonly used techniques or in a calcinated condition by commonly available proce equipment. The geometry of the slots has to fit the plates.
It should be understood that the electrical conducting solids or particles can be of a appropriate metal such as steel, iron, copper, aluminium etc., or alloys of same. Further, th shape of the solids can be spherical, oval or elliptic, flaked, or have any appropriate sha The size and particle distribution may vary. The maximum size will in general be restricted by the width of the space to be filled. A non-homogenous distribution of particle sizes may convenient to obtain a compact filling as possible, with little space between the particles.
Apart from having good electrical conducting properties, the applied material should have mechanical properties (crushing properties) and be able to sustain high temperatures. mentioned later, magnetic properties may be advantageous.
Further, the size of said solids can be from 0,1 millimetres and close to the minimum opening between the carbonaceous body and conductor plate. Commonly, the size may be up t millimetres.
Preferably there can be several thermocouples attached to or inserted into the cathode to monitor the temperature in the cathode. For instance, holes up to the center of the plate be drilled in the cathode plate at appropriate locations for reception of thermocouples. steel plate creates a protective housing for the thermocouples to survive the chemic aggressive environment during operation.
The insertion length of the horizontal outlets can preferably be limited in that it does not co the central part of the cathode plate. The length of the insertion can for example be desi to reflect the existence of vertical outlets in that plate, and the path length of the current thro the conductors to the next cell. On side-by-side arranged cells the length of the insertion c be made longer on the upstream side to balance the current pick-up in the cathode block t more balanced.
Each cathode element can be fitted with horizontal outlets only for instance for end-to-e arranged cells or when there is no space for busbars under the cell, or with several horizo outlets and one vertical outlet. To optimize the magnetic field, a configuration with one or t vertical outlets only and no horizontal outlet can be possible as well.
A combination of different plate configurations can be applied in one cell to create a favour magnetic field from the electric current distribution or enhance the thermal properties of t cell by reducing the number of outlets where a heat loss is undesired, e.g. on the short e of the cell which tend to be colder due to the nearby corners. Vertical outlets attached to o some plates can be beneficial to optimize the curr aenndt m floawgnetic field. This may as well reduce the costs of the installation when the current distribution and magnetohydrodyna stability of the cell is sufficient.
The claimed plate cathode has multiple advantages compared to a traditional desi comprising a carbonaceous body with embedded collector bars:
- The cathode voltage drop (CVD) is significantly lower due to the number of outlets material electric properties, better electric contact due to initial mobility of particles, total surface of contact resistance and shorter current paths from the existence of vertical outlets
- The current distribution into the top cathode block surface is more homogeneous d to the plate geometry, conductance of insertions, and existence of vertical outlets, th avoiding undesired, instability causing horizontal currents in the liquid aluminium p above the cathode block surface. The higher stability of the cell can be used to redu the cell voltage and energy consumption further or increase the amperage a production volume
Due to the above mentioned better current distribution, the erosion of the carbonace material is more homogeneous thus increasing the life time of the cell
- The vertical space usage of the arrangement is less than with conventional desig thus allowing for a lower cathode shell or - if the shell height is kept, to use the extr space for better bottom insulation, higher and longer-lasting cathode blocks, or mo height for liquid aluminium or bath
- The design has a better ratio of electric to thermal conductivity at the most critical locations of high current density and heat flow, thus improving the energy efficiency the cell (less heat loss and lower cathode voltage drop CVD)
- When retrofitted to an existing cell design, vertical outlets according to the claims may allow to raise the amperage and thus increase production per cell
- Lower voltage drop (CVD), as less as 150mV
Better current distribution into the cathode surface giving improved MHD stability and thus options to reduce the ACD or increase the amperage level by up to 15%
Less heat loss because of smaller cross-section and exposed surface of HO and VO avoiding cold cathodes with bottom freeze, specifically if the technology is used to reduce energy consumption
Lower rodding cost as there is no cast iron
- No risk of cracking of carbon block compared to cast-in collector bars (cast iron)
Flexible installation of VOs after placing of the cathode blocks in the lining
Better balancing of current flow to upstream/downstream/bottom side giving better MHD stability
- Less total height of the assembly giving space for more thermal bottom insulation or larger cavity. This could be up to 150mm
Longer life time of carbon cathode block at same assembly height like traditional design with collector bars, as the height of the usable carbon block can be up to 150mm higher
- Easier installation of thermocouples inside the plate due to less deep drilling than i collector bars, or direct access from bottom side
Claims (24)
1. A cathode element for an electrolysis cell of Hall-Héroult type for produci aluminium, comprising a carbonaceous body (4) of calcinated carbonace material connected with the upper side of a metallic collector plate (2), wherei space between the said carbonaceous body (4) and the collector plate (2) filled with an electric conductive material, preferably comprising conductiv particles,
c h a r a c t e r i s e d in t h a t
the collector plate (2) further comprises at least one horizontal current outlet (5, on at least one side and/or at least one vertical metallic current outlet (7) conne to the collector plate (2).
2. A cathode element according to claim 1,
c h a r a c t e r i s e d in t h a t
the carbonaceous body (4) is rodded to the collector plate (2) in a manner wher outer end part of the carbonaceous body (4) is electrically insulated from collector plate (2), at a distance up to 450mm from the end thereof and inwards.
3. A cathode element according to claim 1,
c h a r a c t e r i s e d in t h a t
the carbonaceous body (4) is rodded to the collector plate (2) in a manner wher outer end part of the carbonaceous body (4) is electrically insulated from collector plate (2) at different lengths on both ends of the plate (asymmetric).
4. A cathode element according to claim 1,
c h a r a c t e r i s e d in t h a t
at least one thermocouple (TC) is inserted into a metallic component inside o below the collector plate (2).
5. A cathode element according to claim 1,
c h a r a c t e r i s e d in t h a t
it comprises at least one horizontal current outlet (5; 50) integrated with the collec plate (2; 20).
6. A cathode element according to claim 5,
c h a r a c t e r i s e d in t h a t
the at least one horizontal current outlet (5; 50) is integrated in a slot (S) in t collector plate (2; 20).
7. A cathode element according to claim 5,
c h a r a c t e r i s e d in t h a t
the horizontal current outlet (5; 50) comprises one current conducto 5r0 p<)>art (5 ; that is integrated to the collector plate (2; 20) by a press-fit (knock) fixation in recess of the collector plate (2; 20) that is complementary with the correspondi part of the conductor (5, 50).
8. A cathode element according to any of claims 5-7,
c h a r a c t e r i s e d in t h a t
the part of the current conductor (5; 50) integrated to the collector plate (2; 20) h a delta shaped part (51).
9. A cathode element according to any of claims 5-8,
c h a r a c t e r i s e d in t h a t
it comprises at least one horizontal current outlet (5, 5') on each end being integ with the collector plate (2).
10. A cathode element according to of claim 9,
c h a r a c t e r i s e d in t h a t
the cross section of or the insertion length of the horizontal current outlet at on is different of that of the other end (asymmetric).
11. A cathode element according to any of claims 5-10,
c h a r a c t e r i s e d in t h a t
the current outlet (5; 50) comprises a copper conductor preferably covered b protective sheet (6; 60).
12. A cathode element according to claim 1,
c h a r a c t e r i s e d in t h a t
it comprises at least one vertical current outlet (7) arranged at the opposite sid the collector (2) plate than the said carbonaceous body (4).
13. A cathode element according to claim 12,
c h a r a c t e r i s e d in t h a t
the vertical outlet (7) comprises of a socket (10) integrated with the collector plat (2) wherein a rod-shaped current conductor (11) is attached to the socket (10).
14. A cathode element according to claim 13,
c h a r a c t e r i s e d in t h a t
the socket (10) is of a metallic material and further welded to the collector plate (
15. A cathode element according to claims 13-14 ,
c h a r a c t e r i s e d in t h a t
the socket (10) has an internal recess (17’) where an upper part (17) of the curr conductor (11) has a shape complementary with said recess (17’) for fixation of s current conductor (11) to the socket (10).
16. A cathode element according to claims 13-15,
c h a r a c t e r i s e d in t h a t
the fixation is a press-fit (knock) fixation.
17. A cathode element according to claims 13-16,
c h a r a c t e r i s e d in t h a t
the socket (10) has internal threads 13 at its outermost end for receiving a sle (12’) with complementary external threads (16’), wherein the sleeve surrounds current conductor (11) and where the end of the sleeve abuts an annular fla ring (14’) at the current rod (11) for forcing the rod (11) into the socket (10) wh tightened.
18. A cathode element according to claims 13-17,
c h a r a c t e r i s e d in t h a t
there is a threaded bolt (17) at the top of the socket communicating with a thre bore (17’).
19. A cathode element according to any of preceding claims 12-18,
c h a r a c t e r i s e d in t h a t
the current conductor (11) is made out of copper or an alloy thereof.
20. A cathode element according to claim 1,
c h a r a c t e r i s e d in t h a t
at least one metallic collector element (3) is arranged at the upper side of a me collector plate (2), where said collector element (3) is embedded in a correspon recess (9) in the bottom part of said carbonaceous body (4), the recess being w than the collector element and being filled with an electric conductive mat comprising conductive particles.
21. A cathode element according to claim 20,
c h a r a c t e r i s e d in t h a t
there is one or more collector elements (3), preferably 3 to 7 being separated distance of typically 50 mm to 150 mm.
22. A cathode element according to claim 20,
c h a r a c t e r i s e d in t h a t
the at least one collector element(s) (3) is of same length or shorter length tha carbonaceous body (4).
23. An electrolysis cell of Hall-Héroult type comprising several cathode elements defined in any preceding claims 1-22,
c h a r a c t e r i s e d in t h a t
a cell is built with several cathode elements and in a configuration of only the s elements.
24. An electrolysis cell of Hall-Héroult type comprising several cathode elements defined in any preceding claims 1-22,
c h a r a c t e r i s e d in t h a t
a cell is built with several cathode elements and in a configuration of diffe elements.
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NO20180369A NO20180369A1 (en) | 2018-03-14 | 2018-03-14 | Cathode elements for a Hall-Héroult cell for aluminium production and a cell of this type having such elements installed |
NZ765670A NZ765670A (en) | 2018-03-14 | 2019-03-04 | Cathode elements for a hall-héroult cell for aluminium production and a cell of this type having such elements installed |
PCT/EP2019/055300 WO2019174948A1 (en) | 2018-03-14 | 2019-03-04 | Cathode elements for a hall-héroult cell for aluminium production and a cell of this type having such elements installed |
CA3087116A CA3087116A1 (en) | 2018-03-14 | 2019-03-04 | Cathode elements for a hall-heroult cell for aluminium production and a cell of this type having such elements installed |
US16/959,263 US20200332427A1 (en) | 2018-03-14 | 2019-03-04 | Cathode elements for a hall-héroult cell for aluminium production and a cell of this type having such elements installed |
EA202092170A EA202092170A1 (en) | 2018-03-14 | 2019-03-04 | CATHODE ELEMENTS FOR A HOLLA-EROU CELL FOR PRODUCING ALUMINUM AND A CELL OF THIS TYPE HAVING SUCH INSTALLED ELEMENTS |
AU2019235250A AU2019235250B2 (en) | 2018-03-14 | 2019-03-04 | Cathode elements for a Hall-Heroult cell for aluminium production and a cell of this type having such elements installed |
BR112020015021-5A BR112020015021B1 (en) | 2018-03-14 | 2019-03-04 | CATHODE ELEMENT, AND, HALL-HÉROULT TYPE ELECTROLYSIS CELL |
EP19710349.2A EP3765656A1 (en) | 2018-03-14 | 2019-03-04 | Cathode elements for a hall-héroult cell for aluminium production and a cell of this type having such elements installed |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NO20180369A NO20180369A1 (en) | 2018-03-14 | 2018-03-14 | Cathode elements for a Hall-Héroult cell for aluminium production and a cell of this type having such elements installed |
Publications (1)
Publication Number | Publication Date |
---|---|
NO20180369A1 true NO20180369A1 (en) | 2019-09-16 |
Family
ID=65729322
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO20180369A NO20180369A1 (en) | 2018-03-14 | 2018-03-14 | Cathode elements for a Hall-Héroult cell for aluminium production and a cell of this type having such elements installed |
Country Status (8)
Country | Link |
---|---|
US (1) | US20200332427A1 (en) |
EP (1) | EP3765656A1 (en) |
AU (1) | AU2019235250B2 (en) |
CA (1) | CA3087116A1 (en) |
EA (1) | EA202092170A1 (en) |
NO (1) | NO20180369A1 (en) |
NZ (1) | NZ765670A (en) |
WO (1) | WO2019174948A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2021213672A1 (en) | 2020-04-24 | 2021-10-28 | Norsk Hydro Asa | Cathode assembly for a hall-heroult cell for aluminium production and method for making same |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP7556048B2 (en) * | 2020-04-30 | 2024-09-25 | ノルスク・ヒドロ・アーエスアー | Cathode block for aluminum electrolysis and method for manufacturing same |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1997048838A1 (en) * | 1996-06-18 | 1997-12-24 | Comalco Aluminium Limited | Cathode construction |
WO1998053120A1 (en) * | 1997-05-23 | 1998-11-26 | Moltech Invent S.A. | Aluminium production cell and cathode |
WO2008033034A1 (en) * | 2006-09-14 | 2008-03-20 | Norsk Hydro Asa | Electrolysis cell and method for operating the same |
WO2009099335A1 (en) * | 2008-02-06 | 2009-08-13 | Norsk Hydro Asa | Electrode and a method for making same |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3434957A (en) * | 1966-02-18 | 1969-03-25 | Arthur F Johnson | Aluminum reduction cell with aluminum and refractory layered bottom construction |
FR2560613B2 (en) * | 1983-05-16 | 1987-03-27 | Pechiney Aluminium | IMPROVEMENT ON CATHODE RATES WITH A METAL SOLE, FOR HALL-HEROULT ELECTROLYSIS TANKS |
FR2977898A1 (en) * | 2011-07-12 | 2013-01-18 | Rio Tinto Alcan Int Ltd | ALUMINERY COMPRISING CATHODIC EXIT TANKS THROUGH THE BOTTOM OF THE HOUSING AND TANK STABILIZATION MEANS |
NO20141572A1 (en) * | 2014-12-23 | 2016-06-24 | Norsk Hydro As | A modified electrolytic cell and a method for modifying the same |
RU2744131C2 (en) * | 2016-07-26 | 2021-03-02 | Токай КОБЕКС ГмбХ | Cathode unit for aluminum manufacture |
RU2723867C1 (en) * | 2016-07-26 | 2020-06-17 | Токай КОБЕКС ГмбХ | Cathode current collector/connector for hall-héroult electrolyzer |
-
2018
- 2018-03-14 NO NO20180369A patent/NO20180369A1/en unknown
-
2019
- 2019-03-04 WO PCT/EP2019/055300 patent/WO2019174948A1/en active Application Filing
- 2019-03-04 CA CA3087116A patent/CA3087116A1/en active Pending
- 2019-03-04 US US16/959,263 patent/US20200332427A1/en active Pending
- 2019-03-04 AU AU2019235250A patent/AU2019235250B2/en active Active
- 2019-03-04 NZ NZ765670A patent/NZ765670A/en unknown
- 2019-03-04 EA EA202092170A patent/EA202092170A1/en unknown
- 2019-03-04 EP EP19710349.2A patent/EP3765656A1/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1997048838A1 (en) * | 1996-06-18 | 1997-12-24 | Comalco Aluminium Limited | Cathode construction |
WO1998053120A1 (en) * | 1997-05-23 | 1998-11-26 | Moltech Invent S.A. | Aluminium production cell and cathode |
WO2008033034A1 (en) * | 2006-09-14 | 2008-03-20 | Norsk Hydro Asa | Electrolysis cell and method for operating the same |
WO2009099335A1 (en) * | 2008-02-06 | 2009-08-13 | Norsk Hydro Asa | Electrode and a method for making same |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2021213672A1 (en) | 2020-04-24 | 2021-10-28 | Norsk Hydro Asa | Cathode assembly for a hall-heroult cell for aluminium production and method for making same |
Also Published As
Publication number | Publication date |
---|---|
US20200332427A1 (en) | 2020-10-22 |
AU2019235250B2 (en) | 2023-11-23 |
BR112020015021A2 (en) | 2021-01-19 |
WO2019174948A1 (en) | 2019-09-19 |
CA3087116A1 (en) | 2019-09-19 |
EP3765656A1 (en) | 2021-01-20 |
EA202092170A1 (en) | 2021-01-19 |
AU2019235250A1 (en) | 2020-07-09 |
NZ765670A (en) | 2023-03-31 |
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