NO124026B - - Google Patents

Download PDF

Info

Publication number: NO124026B
Authority: NO; Norway
Prior art keywords: lithium; aluminum; complex; compounds; separated
Prior art date: 1970-09-29

Application number

NO3686/70A

Other languages

English (en)

Norwegian (no)

Inventor

F Folkestad

K Loeiten

G Mejdell

A Torvund

Original Assignee

Norsk Hydro As

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1970-09-29

Filing date

1970-09-29

Publication date

1972-02-21

1970-09-29 Application filed by Norsk Hydro As filed Critical Norsk Hydro As

1970-09-29 Priority to NO3686/70A priority Critical patent/NO124026B/no

1971-09-24 Priority to US00183683A priority patent/US3855392A/en

1971-09-28 Priority to FR7134848A priority patent/FR2108640A5/fr

1971-09-28 Priority to DE19712148464 priority patent/DE2148464C3/de

1971-09-28 Priority to JP7571771A priority patent/JPS5422436B1/ja

1971-09-28 Priority to GB4521171A priority patent/GB1354944A/en

1971-09-28 Priority to ES395503A priority patent/ES395503A1/es

1971-09-28 Priority to NL717113299A priority patent/NL153154B/nl

1972-02-21 Publication of NO124026B publication Critical patent/NO124026B/no

Links

238000001556 precipitation Methods 0.000 claims description 14
238000000034 method Methods 0.000 claims description 13
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 11
229910052744 lithium Inorganic materials 0.000 claims description 11
-1 aluminum tartaric acid Chemical class 0.000 claims description 10
GGIGFRDJXUTIDU-UHFFFAOYSA-H aluminum;oxalate Chemical class [Al+3].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O GGIGFRDJXUTIDU-UHFFFAOYSA-H 0.000 claims description 8
229910003002 lithium salt Inorganic materials 0.000 claims description 7
159000000002 lithium salts Chemical class 0.000 claims description 7
230000001376 precipitating effect Effects 0.000 claims description 7
ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims description 6
239000001099 ammonium carbonate Substances 0.000 claims description 6
235000012501 ammonium carbonate Nutrition 0.000 claims description 6
238000006243 chemical reaction Methods 0.000 claims description 5
239000003795 chemical substances by application Substances 0.000 claims description 5
150000001875 compounds Chemical class 0.000 claims description 5
230000007613 environmental effect Effects 0.000 claims description 5
150000002642 lithium compounds Chemical class 0.000 claims description 5
239000004254 Ammonium phosphate Substances 0.000 claims description 3
229910000148 ammonium phosphate Inorganic materials 0.000 claims description 3
235000019289 ammonium phosphates Nutrition 0.000 claims description 3
MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 3
150000002500 ions Chemical class 0.000 claims description 3
235000005985 organic acids Nutrition 0.000 claims description 3
238000003756 stirring Methods 0.000 claims description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
MVWFUDDHSYOBOS-UHFFFAOYSA-J C(C(=O)[O-])(=O)[O-].[Al+3].[Li+].C(C(=O)[O-])(=O)[O-] Chemical compound C(C(=O)[O-])(=O)[O-].[Al+3].[Li+].C(C(=O)[O-])(=O)[O-] MVWFUDDHSYOBOS-UHFFFAOYSA-J 0.000 claims description 2
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 2
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
229910052770 Uranium Inorganic materials 0.000 claims description 2
229910052804 chromium Inorganic materials 0.000 claims description 2
239000011651 chromium Substances 0.000 claims description 2
238000001640 fractional crystallisation Methods 0.000 claims description 2
XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 claims description 2
229910052808 lithium carbonate Inorganic materials 0.000 claims description 2
238000002156 mixing Methods 0.000 claims description 2
229910052750 molybdenum Inorganic materials 0.000 claims description 2
239000011733 molybdenum Substances 0.000 claims description 2
229910052758 niobium Inorganic materials 0.000 claims description 2
239000010955 niobium Substances 0.000 claims description 2
GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 2
150000007524 organic acids Chemical class 0.000 claims description 2
239000002244 precipitate Substances 0.000 claims description 2
239000012429 reaction media Substances 0.000 claims description 2
229910052715 tantalum Inorganic materials 0.000 claims description 2
GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 2
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 2
229910052721 tungsten Inorganic materials 0.000 claims description 2
239000010937 tungsten Substances 0.000 claims description 2
DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 claims description 2
229910052720 vanadium Inorganic materials 0.000 claims description 2
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims description 2
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Substances OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims 4
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims 3
VBZUAQQWTKKNFN-UHFFFAOYSA-N 2-hydroxypropane-1,2,3-tricarboxylic acid;lithium Chemical compound [Li].OC(=O)CC(O)(C(O)=O)CC(O)=O VBZUAQQWTKKNFN-UHFFFAOYSA-N 0.000 claims 1
FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims 1
FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims 1
230000015572 biosynthetic process Effects 0.000 claims 1
235000015165 citric acid Nutrition 0.000 claims 1
235000006408 oxalic acid Nutrition 0.000 claims 1
238000005185 salting out Methods 0.000 claims 1
239000007858 starting material Substances 0.000 claims 1
235000002906 tartaric acid Nutrition 0.000 claims 1
239000011975 tartaric acid Substances 0.000 claims 1
238000000926 separation method Methods 0.000 description 21
239000000243 solution Substances 0.000 description 7
150000003839 salts Chemical class 0.000 description 5
230000000694 effects Effects 0.000 description 4
239000002253 acid Substances 0.000 description 3
239000013078 crystal Substances 0.000 description 3
YNQRWVCLAIUHHI-UHFFFAOYSA-L dilithium;oxalate Chemical compound [Li+].[Li+].[O-]C(=O)C([O-])=O YNQRWVCLAIUHHI-UHFFFAOYSA-L 0.000 description 3
230000000155 isotopic effect Effects 0.000 description 3
239000000126 substance Substances 0.000 description 3
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
150000004649 carbonic acid derivatives Chemical class 0.000 description 2
238000005868 electrolysis reaction Methods 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
229910002651 NO3 Inorganic materials 0.000 description 1
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
ZCLVNIZJEKLGFA-UHFFFAOYSA-H bis(4,5-dioxo-1,3,2-dioxalumolan-2-yl) oxalate Chemical compound [Al+3].[Al+3].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O ZCLVNIZJEKLGFA-UHFFFAOYSA-H 0.000 description 1
239000001569 carbon dioxide Substances 0.000 description 1
229910002092 carbon dioxide Inorganic materials 0.000 description 1
238000003776 cleavage reaction Methods 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000008025 crystallization Effects 0.000 description 1
230000007423 decrease Effects 0.000 description 1
238000009792 diffusion process Methods 0.000 description 1
238000006073 displacement reaction Methods 0.000 description 1
230000029142 excretion Effects 0.000 description 1
238000000605 extraction Methods 0.000 description 1
239000000706 filtrate Substances 0.000 description 1
210000003918 fraction a Anatomy 0.000 description 1
238000005194 fractionation Methods 0.000 description 1
GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
238000011081 inoculation Methods 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
238000005372 isotope separation Methods 0.000 description 1
239000007788 liquid Substances 0.000 description 1
229910001760 lithium mineral Inorganic materials 0.000 description 1
GBPZIFLFRULNBM-UHFFFAOYSA-N lithium;oxalic acid Chemical compound [Li].OC(=O)C(O)=O GBPZIFLFRULNBM-UHFFFAOYSA-N 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
239000011707 mineral Substances 0.000 description 1
239000000203 mixture Substances 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
235000021395 porridge Nutrition 0.000 description 1
230000007017 scission Effects 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F5/00—Compounds of magnesium
- C01F5/26—Magnesium halides
- C01F5/30—Chlorides

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Life Sciences & Earth Sciences (AREA)
Geology (AREA)
Inorganic Chemistry (AREA)
Extraction Or Liquid Replacement (AREA)
Inorganic Compounds Of Heavy Metals (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

NO3686/70A 1970-09-29 1970-09-29 NO124026B (nl)

Priority Applications (8)

Application Number	Priority Date	Filing Date	Title
NO3686/70A NO124026B (nl)	1970-09-29	1970-09-29
US00183683A US3855392A (en)	1970-09-29	1971-09-24	Method of removing boric acid and boric acid salts from aqueous magnesium chloride solutions
FR7134848A FR2108640A5 (nl)	1970-09-29	1971-09-28
DE19712148464 DE2148464C3 (de)	1970-09-29	1971-09-28	Verfahren zum Reinigen von wässrigen Magnesiumchlorid-Lösungen von Borsäure und deren Salzen
JP7571771A JPS5422436B1 (nl)	1970-09-29	1971-09-28
GB4521171A GB1354944A (en)	1970-09-29	1971-09-28	Purification of aqueous magnesium chloride
ES395503A ES395503A1 (es)	1970-09-29	1971-09-28	Un metodo de separar sales de acido borico y sales del mis-mo de una solucion acuosa de cloruro de magnesio.
NL717113299A NL153154B (nl)	1970-09-29	1971-09-28	Werkwijze voor het verwijderen van boorzuur en boraten uit magnesiumchloride-oplossingen.

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
NO3686/70A NO124026B (nl)	1970-09-29	1970-09-29

Publications (1)

Publication Number	Publication Date
NO124026B true NO124026B (nl)	1972-02-21

Family

ID=19879783

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO3686/70A NO124026B (nl)	1970-09-29	1970-09-29

Country Status (7)

Country	Link
US (1)	US3855392A (nl)
JP (1)	JPS5422436B1 (nl)
ES (1)	ES395503A1 (nl)
FR (1)	FR2108640A5 (nl)
GB (1)	GB1354944A (nl)
NL (1)	NL153154B (nl)
NO (1)	NO124026B (nl)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB1514927A (en) *	1974-10-23	1978-06-21	United States Borax Chem	Process for the production of boric acid
US4201758A (en) *	1979-03-22	1980-05-06	Nalco Chemical Co.	Boron removal from ethylene glycol-magnesium chloride solutions
US4208392A (en) *	1979-03-23	1980-06-17	Nalco Chemical Co.	Two-step process for removing boron compounds from aqueous solutions of magnesium chloride
US5219550A (en) *	1989-03-31	1993-06-15	Cyprus Foote Mineral Company	Production of low boron lithium carbonate from lithium-containing brine
US4980136A (en) *	1989-07-14	1990-12-25	Cyprus Foote Mineral Company	Production of lithium metal grade lithium chloride from lithium-containing brine
US5785868A (en) *	1995-09-11	1998-07-28	Board Of Regents, Univ. Of Texas System	Method for selective separation of products at hydrothermal conditions
AR001916A1 (es) *	1996-02-20	1997-12-10	Minera Salar De Atacama S A So	Proceso para extraer boro desde salmueras naturales o industriales empleando extración por solventes
AR001917A1 (es) *	1996-03-28	1997-12-10	Minera Salar De Atacama S A So	Producción de carbonato de litio de alta pureza desde salmueras naturales o industriales
CA3214958A1 (en)	2018-12-21	2020-06-25	Mangrove Water Technologies Ltd.	Li recovery processes and onsite chemical production for li recovery processes
CN110422853B (zh) *	2019-08-26	2021-09-21	东北大学	一种利用高镁低硼溶液制备高纯硼酸的方法
FR3150198A1 (fr) *	2023-06-22	2024-12-27	Caremag	Procede d’extraction selective du bore par un solvant organique a partir de solutions issues de l’attaque acide d’aimants permanents comprenant des terres rares
FR3150199A1 (fr)	2023-06-22	2024-12-27	Caremag	Procede de recuperation d’un sel de bore a partir d’un solvant organique comprenant de l’acide borique
WO2024261418A1 (fr) *	2023-06-22	2024-12-26	Caremag	Procede d'extraction selective du bore par un solvant organique a partir de solutions issues de l'attaque acide d'aimants permanents comprenant des terres rares

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR1092284A (fr) *	1953-06-18	1955-04-20	Centre Nat Rech Scient	Procédé d'extraction et de purification d'acides forts en milieux aqueux. application particulière à l'acide perrhénique
US2969275A (en) *	1958-11-14	1961-01-24	American Potash & Chem Corp	Recovery of boron values
GB910541A (en) *	1959-08-18	1962-11-14	American Potash & Chem Corp	Improvements relating to the recovery of boron values from alkaline liquors
US3433604A (en) *	1965-09-22	1969-03-18	Dow Chemical Co	Calcium chloride and boric acid extraction from magnesium chloride brines using diols and catechols
US3424563A (en) *	1966-02-03	1969-01-28	Dow Chemical Co	Selective extraction of boron from aqueous solutions
US3493349A (en) *	1966-09-28	1970-02-03	Dow Chemical Co	Extraction of boron from brines having a ph of less than about 1.7 using beta-aliphatic diols

1970
- 1970-09-29 NO NO3686/70A patent/NO124026B/no unknown
1971
- 1971-09-24 US US00183683A patent/US3855392A/en not_active Expired - Lifetime
- 1971-09-28 JP JP7571771A patent/JPS5422436B1/ja active Pending
- 1971-09-28 ES ES395503A patent/ES395503A1/es not_active Expired
- 1971-09-28 NL NL717113299A patent/NL153154B/nl not_active IP Right Cessation
- 1971-09-28 GB GB4521171A patent/GB1354944A/en not_active Expired
- 1971-09-28 FR FR7134848A patent/FR2108640A5/fr not_active Expired

Also Published As

Publication number	Publication date
NL153154B (nl)	1977-05-16
NL7113299A (nl)	1972-04-04
JPS5422436B1 (nl)	1979-08-07
DE2148464B2 (de)	1976-03-04
DE2148464A1 (de)	1972-03-30
GB1354944A (en)	1974-06-05
FR2108640A5 (nl)	1972-05-19
ES395503A1 (es)	1973-12-16
US3855392A (en)	1974-12-17

Publication	Publication Date	Title
NO124026B (nl)	1972-02-21
DE1939608A1 (de)	1970-03-05	Gefaelltes Calciumcarbonat
Lindsay et al.	1959	Solubility criteria for the existence of variscite in soils
Small	1919	a Method for the Preparation of Soluble Starch.
DE3425582A1 (de)	1985-02-21	Verfahren zur verbesserung der ausbeute an soda bei dem solvay-prozess
US4839149A (en)	1989-06-13	Ammonium plutonate uranate, its preparation process and its use for producing the mixed oxide (U,Pu)O2
DE3723535A1 (de)	1989-01-26	Verfahren zur herstellung von cyanwasserstoff
US4110402A (en)	1978-08-29	Recovery of strontium from brine that contains strontium and calcium
US3085852A (en)	1963-04-16	Separation of lithium isotopes
US3694150A (en)	1972-09-26	Preparation of monoammonium aluminum tetrafluoride
Milburn et al.	1960	THE REDUCTION OF OXALATE BY CHROMIUM (II) 1, 2
Chowdhury et al.	1969	Thermal and neutron irradiation effects on the rate of racemization of d-K3Cr (C2O4) 3.2 H2O in the solid state
EP0081185A1 (de)	1983-06-15	Verfahren und Anlage zur Herstellung von Isomerose
GB1211417A (en)	1970-11-04	Process for the production of pure lactulose
DE2704073A1 (de)	1977-08-18	Verfahren zur entfernung von sulfationen aus extrahierter phosphorsaeure
Sabetta et al.	1935	Reduction of nitroguanidine. II. Preparation and properties of Nitrosoguanidine1
DE2703480C2 (nl)	1988-03-10
Wells et al.	1893	On the ammonium-lead halides
Deursch et al.	1977	The effect of fluoride ion concentration on apatite formation and on its crystal habit
DE1592477C (de)	1971-07-08	Verfahren zur Herstellung von Ammonium uranylcarbonat
DE158309C (nl)
Jacques	1938	THE ACCUMULATION OF ELECTROLYTES: XII. ACCUMULATION OF HALIDE AND NITRATE BY VALONIA IN HYPERTONIC SOLUTIONS
Marsh	1951	335. Separation of yttrium and erbium with the aid of ethylene-diaminetetra-acetic acid (“enta acid”)
SU975569A1 (ru)	1982-11-23	Способ получени водного раствора нитрита кальци
Tanford et al.	1949	The Reaction Between Calcium Hydroxide and Uranyl Nitrate Solutions