NO119385B - - Google Patents
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- Publication number
- NO119385B NO119385B NO163131A NO16313166A NO119385B NO 119385 B NO119385 B NO 119385B NO 163131 A NO163131 A NO 163131A NO 16313166 A NO16313166 A NO 16313166A NO 119385 B NO119385 B NO 119385B
- Authority
- NO
- Norway
- Prior art keywords
- ensiling
- acetic acid
- silage
- salts
- complex salts
- Prior art date
Links
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 24
- 150000003839 salts Chemical class 0.000 claims description 19
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 claims description 6
- 238000007792 addition Methods 0.000 claims description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- 150000001242 acetic acid derivatives Chemical class 0.000 claims description 4
- 239000011575 calcium Substances 0.000 claims description 4
- 229910052791 calcium Inorganic materials 0.000 claims description 4
- 150000004675 formic acid derivatives Chemical class 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- 239000004312 hexamethylene tetramine Substances 0.000 claims description 3
- 235000010299 hexamethylene tetramine Nutrition 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 235000013311 vegetables Nutrition 0.000 claims description 3
- 229960004011 methenamine Drugs 0.000 claims 1
- 235000002639 sodium chloride Nutrition 0.000 description 18
- 239000004460 silage Substances 0.000 description 11
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 10
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 5
- 235000019253 formic acid Nutrition 0.000 description 5
- 239000000654 additive Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- 239000004280 Sodium formate Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000004459 forage Substances 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 description 2
- 235000019254 sodium formate Nutrition 0.000 description 2
- 235000010624 Medicago sativa Nutrition 0.000 description 1
- 240000004658 Medicago sativa Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- MJWPFSQVORELDX-UHFFFAOYSA-K aluminium formate Chemical compound [Al+3].[O-]C=O.[O-]C=O.[O-]C=O MJWPFSQVORELDX-UHFFFAOYSA-K 0.000 description 1
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 1
- 239000012496 blank sample Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 235000013379 molasses Nutrition 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 230000004936 stimulating effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
- C25C7/02—Electrodes; Connections thereof
- C25C7/025—Electrodes; Connections thereof used in cells for the electrolysis of melts
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
- C25C3/08—Cell construction, e.g. bottoms, walls, cathodes
- C25C3/10—External supporting frames or structures
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Fodder In General (AREA)
Description
Fremgangsmåte for emsilering av vegetabilske produkter. Procedure for emsilization of vegetable products.
For ensilering av vegetabilske produkter kan man bl. a. anvende sure flytende ensileringsmidler som AIV-syre og maursyre eller «strøbare» tilsetningsmidler av forskjellig sammensetning. For ensiling vegetable products, you can, among other things, a. use acidic liquid silage agents such as AIV acid and formic acid or "sprinkable" additives of different composition.
De flytende ensileringsmidler er ag-gressive og vanskelige å håndtere, hvorfor det er ønskelig om mulig å gå over til «strøbare» tilsetninger. The liquid silage agents are aggressive and difficult to handle, which is why it is desirable, if possible, to switch to "spreadable" additives.
Det er kjent at formiater og acetater It is known that formates and acetates
av natrium, kalsium og aluminium danner flere komplekssalter med maursyre og eddiksyre. Disse salter er stabile og krystalli-serer godt. Det er likeledes kjent at komplekssaltene mellom natriumformiat og of sodium, calcium and aluminum form several complex salts with formic acid and acetic acid. These salts are stable and crystallize well. It is likewise known that the complex salts between sodium formate and
maursyre, og likeledes mellom aluminium-formiat og maursyre har ensileringsvirk-ning. Slike produkter finnes også på mar-kedet. Formic acid, and likewise between aluminum formate and formic acid, has an ensiling effect. Such products are also available on the market.
Det har nå vist seg at også komplekssalter mellom de ovennevnte salter og eddiksyre har en utmerket ensileringsvirk-ning. It has now been shown that complex salts between the above-mentioned salts and acetic acid also have an excellent ensiling effect.
Det har likeledes vist seg at tilsetninger av formalin eller hexametylentetramin eller annen formalinavspaltende substans til de ovennevnte komplekssalter kan ha gunstig virkning ved nedlegning av van-skelig ensilerbart for. It has also been shown that additions of formalin or hexamethylenetetramine or other formalin-releasing substance to the above-mentioned complex salts can have a beneficial effect when laying down difficult-to-ensilage forage.
Hensikten med oppfinnelsen er å gjen-nomføre ensilering ved hjelp av et strøbart tilsetningsmiddel, basert på ett eller flere av komplekssaltene mellom eddiksyre og formiater eller acetater av natrium, kalsium eller aluminium. Ensileringen kan skje med eller uten tilsetning av formalin eller hexametylentetramin eller annen formalinavspaltende substans. The purpose of the invention is to carry out ensiling using a spreadable additive, based on one or more of the complex salts between acetic acid and formates or acetates of sodium, calcium or aluminium. The ensiling can take place with or without the addition of formalin or hexamethylenetetramine or another formalin-decomposing substance.
Selvfølgelig kan de ovennevnte tilset- Of course, the above can add-
ninger kombineres med andre fordelaktige tilsetninger som koksalt eller melasse. nings are combined with other beneficial additives such as table salt or molasses.
Anvendelsen av de nye ensileringssalter i henhold til oppfinnelsen har vist seg å innebære betydelige fordeler fremfor hit-til anvendte ensileringssalter. Således har disse ensileringssalter, bestående av ett eller flere av komplekssaltene mellom eddiksyre og formiater eller acetater av natrium, kalsium eller aluminium The use of the new silage salts according to the invention has been shown to entail significant advantages over silage salts used up to now. Thus, these have silage salts, consisting of one or more of the complex salts between acetic acid and formates or acetates of sodium, calcium or aluminum
1) mindre korroderende innvirkning på beholdere og diverse andre gjenstander, da komplekssaltene spaltes slik at der dan-nes fri syre. I denne henseende er de nye ensileringsmidler spesielt overlegne over-for komplekssalter med maursyre. 2) større evne til under ensileringen å fremme melkesyregjæringen, som litt etter litt hindrer ytterligere nedbrytning av en-sileringsgodset. 3) mere stimulerende virkning på hus-dyrene. Ensileringsfor med ensileringssalt ifølge oppfinnelsen har vist seg mere til-trekkende enn ensileringsfor med andre ensileringssalter. Dessuten har ensilerings-saltet vist seg å fremme husdyrenes for-døyelse, slik at der kan oppnås bedre ut-nyttelse av foret. 1) less corrosive effect on containers and various other objects, as the complex salts are split so that free acid is formed. In this respect, the new ensiling agents are particularly superior to complex salts with formic acid. 2) greater ability to promote lactic acid fermentation during ensiling, which little by little prevents further degradation of the ensiling material. 3) more stimulating effect on the domestic animals. Silage feed with silage salt according to the invention has proven more attractive than silage feed with other silage salts. Furthermore, the silage salt has been shown to promote the livestock's digestion, so that better utilization of the forage can be achieved.
Eksempel: Example:
Lucern med et tørrstoffinnhold av 18,7 % og et totalt kvelstoffinnhold av 0,56 % ble ensilert med en tilsetning av 1 % av et komplekssalt mellom natriumformiat og eddiksyre. Resultatet ble sam-menlignet med en blindprøve uten tilsetning av ensileringsmiddel. Som det frem-går av analyseverdiene, har den ferdige ensilasje et lavt innhold av ammoniakk-kvelstoff og inneholder dessuten ingen Lucerne with a dry matter content of 18.7% and a total nitrogen content of 0.56% was ensiled with the addition of 1% of a complex salt between sodium formate and acetic acid. The result was compared with a blank test without the addition of ensiling agent. As can be seen from the analysis values, the finished silage has a low content of ammonia-nitrogen and also contains no
smørsyre. Foret var vel bevart og hadde en butyric acid. The lining was well preserved and had a
frisk lukt, mens blindprøven var av min-dreverdig kvalitet. fresh smell, while the blank sample was of inferior quality.
Claims (2)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR18483A FR1445602A (en) | 1965-05-26 | 1965-05-26 | Lifting beam for electrolytic cells |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NO119385B true NO119385B (en) | 1970-05-11 |
Family
ID=8579927
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO163131A NO119385B (en) | 1965-05-26 | 1966-05-24 |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US3434955A (en) |
| AT (1) | AT274404B (en) |
| BE (1) | BE681650A (en) |
| CH (1) | CH461112A (en) |
| DE (1) | DE1533457B1 (en) |
| ES (1) | ES327151A1 (en) |
| FR (1) | FR1445602A (en) |
| GB (1) | GB1149967A (en) |
| IS (1) | IS759B6 (en) |
| LU (1) | LU51178A1 (en) |
| NL (1) | NL149553B (en) |
| NO (1) | NO119385B (en) |
| SE (1) | SE327828B (en) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3484856A (en) * | 1966-07-21 | 1969-12-16 | Kaiser Aluminium Chem Corp | Anode adjusting apparatus |
| FR2039543A5 (en) * | 1969-04-14 | 1971-01-15 | Duclaux Daniel | |
| US4269673A (en) * | 1980-01-28 | 1981-05-26 | Aluminum Company Of America | Anode mount |
| FR2606428B1 (en) * | 1986-11-10 | 1989-02-03 | Pechiney Aluminium | METHOD AND DEVICE FOR SEALING, UNDER PRESSURE, CATHODE RATES |
| DE60023530D1 (en) * | 2000-12-19 | 2005-12-01 | Reel Saint Cyr Au Mont D Or | Lifting device for the anode support in electrolysis furnaces for aluminum production |
| FR2927908B1 (en) | 2008-02-25 | 2010-02-26 | Ecl | CHECKING THE ISOLATION OF THE INTERVENTION UNITS USED IN AN ELECTROLYSIS ROOM FOR THE PRODUCTION OF ALUMINUM BY IGNEE ELECTROLYSIS. |
| US8888156B2 (en) * | 2010-09-08 | 2014-11-18 | E.C.L. | Handling tool, for secure handling of connectors of electrolysis cells intended for aluminium production |
| CA2919331C (en) * | 2013-08-09 | 2021-11-16 | Rio Tinto Alcan International Limited | Electrolytic device and anode assembly intended for the production of aluminium, electrolytic cell and apparatus comprising such a device |
| FR3016900B1 (en) * | 2014-01-27 | 2016-01-15 | Rio Tinto Alcan Int Ltd | ELECTROLYSIS DEVICE AND ANODE ASSEMBLY FOR THE PRODUCTION OF ALUMINUM, ELECTROLYSIS CELL AND INSTALLATION COMPRISING SUCH A DEVICE. |
| CN109849170B (en) * | 2019-01-16 | 2023-11-10 | 安徽佳乐建设机械有限公司 | Dual-purpose brick holding machine for inserting and holding and method thereof |
| CN115043462A (en) * | 2022-06-17 | 2022-09-13 | 合肥工业大学 | Small-size reaction tank clamping device |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1075321B (en) * | 1952-08-12 | 1960-02-11 | Aluminium Company of America Pittsburgh Pa (V St A) | Continuous electrodes for melt flow electrolysis |
| US3127338A (en) * | 1958-03-25 | 1964-03-31 | mantovanello etal | |
| DE1163558B (en) * | 1960-12-23 | 1964-02-20 | Aluminium Ind Ag | Electrolysis cell for the production of aluminum |
| BE638855A (en) * | 1962-10-19 |
-
1965
- 1965-05-26 FR FR18483A patent/FR1445602A/en not_active Expired
-
1966
- 1966-05-24 NO NO163131A patent/NO119385B/no unknown
- 1966-05-24 US US554280A patent/US3434955A/en not_active Expired - Lifetime
- 1966-05-24 GB GB23055/66A patent/GB1149967A/en not_active Expired
- 1966-05-25 NL NL666607244A patent/NL149553B/en not_active IP Right Cessation
- 1966-05-25 IS IS1563A patent/IS759B6/en unknown
- 1966-05-25 CH CH754066A patent/CH461112A/en unknown
- 1966-05-25 AT AT494766A patent/AT274404B/en active
- 1966-05-25 LU LU51178A patent/LU51178A1/xx unknown
- 1966-05-25 DE DE19661533457 patent/DE1533457B1/en active Pending
- 1966-05-25 ES ES0327151A patent/ES327151A1/en not_active Expired
- 1966-05-26 SE SE07224/66A patent/SE327828B/xx unknown
- 1966-05-26 BE BE681650D patent/BE681650A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BE681650A (en) | 1966-11-28 |
| GB1149967A (en) | 1969-04-23 |
| IS759B6 (en) | 1970-11-23 |
| NL149553B (en) | 1976-05-17 |
| IS1563A7 (en) | 1966-11-27 |
| SE327828B (en) | 1970-08-31 |
| NL6607244A (en) | 1966-11-28 |
| FR1445602A (en) | 1966-07-15 |
| CH461112A (en) | 1968-08-15 |
| ES327151A1 (en) | 1967-07-16 |
| AT274404B (en) | 1969-09-25 |
| US3434955A (en) | 1969-03-25 |
| DE1533457B1 (en) | 1971-10-07 |
| LU51178A1 (en) | 1966-11-25 |
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