NL7907580A - Katalysator voor de hydrobehandeling van zware koolwaterstofolieen alsmede werkwijze ter bereiding van deze katalysator. - Google Patents

Katalysator voor de hydrobehandeling van zware koolwaterstofolieen alsmede werkwijze ter bereiding van deze katalysator. Download PDF

Info

Publication number: NL7907580A
Authority: NL; Netherlands
Prior art keywords: substrate; catalyst; vanadium; oil; heavy hydrocarbon
Prior art date: 1978-10-14

Application number

NL7907580A

Other languages

English (en)

Dutch (nl)

Original Assignee

Chiyoda Chem Eng Construct Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-10-14

Filing date

1979-10-12

Publication date

1980-04-16

1978-10-14 Priority claimed from JP12568978A external-priority patent/JPS5554036A/ja

1978-12-13 Priority claimed from JP15320078A external-priority patent/JPS5579043A/ja

1979-10-12 Application filed by Chiyoda Chem Eng Construct Co filed Critical Chiyoda Chem Eng Construct Co

1980-04-16 Publication of NL7907580A publication Critical patent/NL7907580A/nl

Links

239000003054 catalyst Substances 0.000 title claims description 198
239000003921 oil Substances 0.000 title claims description 169
229930195733 hydrocarbon Natural products 0.000 title claims description 88
150000002430 hydrocarbons Chemical class 0.000 title claims description 88
238000000034 method Methods 0.000 title claims description 88
239000004215 Carbon black (E152) Substances 0.000 title claims description 85
ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 title description 3
239000000758 substrate Substances 0.000 claims description 216
229910052720 vanadium Inorganic materials 0.000 claims description 115
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 113
239000011148 porous material Substances 0.000 claims description 58
230000003197 catalytic effect Effects 0.000 claims description 56
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 46
229910052739 hydrogen Inorganic materials 0.000 claims description 33
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 32
239000001257 hydrogen Substances 0.000 claims description 32
229910052624 sepiolite Inorganic materials 0.000 claims description 28
239000004113 Sepiolite Substances 0.000 claims description 27
235000019355 sepiolite Nutrition 0.000 claims description 25
229910052759 nickel Inorganic materials 0.000 claims description 23
229910052500 inorganic mineral Inorganic materials 0.000 claims description 21
239000011707 mineral Substances 0.000 claims description 21
229910052625 palygorskite Inorganic materials 0.000 claims description 21
KSECJOPEZIAKMU-UHFFFAOYSA-N [S--].[S--].[S--].[S--].[S--].[V+5].[V+5] Chemical compound [S--].[S--].[S--].[S--].[S--].[V+5].[V+5] KSECJOPEZIAKMU-UHFFFAOYSA-N 0.000 claims description 18
229910052750 molybdenum Inorganic materials 0.000 claims description 18
238000002360 preparation method Methods 0.000 claims description 17
230000008569 process Effects 0.000 claims description 17
239000002734 clay mineral Substances 0.000 claims description 16
239000011733 molybdenum Substances 0.000 claims description 16
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 15
229910017052 cobalt Inorganic materials 0.000 claims description 14
239000010941 cobalt Substances 0.000 claims description 14
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 14
229960000892 attapulgite Drugs 0.000 claims description 13
239000010949 copper Substances 0.000 claims description 12
229910052802 copper Inorganic materials 0.000 claims description 10
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 9
229910052796 boron Inorganic materials 0.000 claims description 9
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 8
239000000391 magnesium silicate Substances 0.000 claims description 8
229910052919 magnesium silicate Inorganic materials 0.000 claims description 8
235000019792 magnesium silicate Nutrition 0.000 claims description 8
239000010936 titanium Substances 0.000 claims description 7
229910052721 tungsten Inorganic materials 0.000 claims description 7
239000010937 tungsten Substances 0.000 claims description 7
239000007788 liquid Substances 0.000 claims description 6
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 6
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 5
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 5
229910052698 phosphorus Inorganic materials 0.000 claims description 5
239000011574 phosphorus Substances 0.000 claims description 5
229910052719 titanium Inorganic materials 0.000 claims description 5
HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 claims 2
241000876833 Emberizinae Species 0.000 claims 1
230000000694 effects Effects 0.000 description 47
238000006243 chemical reaction Methods 0.000 description 44
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 36
229910052717 sulfur Inorganic materials 0.000 description 36
239000011593 sulfur Substances 0.000 description 36
229910052751 metal Inorganic materials 0.000 description 35
239000002184 metal Substances 0.000 description 35
238000005336 cracking Methods 0.000 description 29
239000000203 mixture Substances 0.000 description 26
150000003682 vanadium compounds Chemical class 0.000 description 22
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 22
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 20
235000010755 mineral Nutrition 0.000 description 20
150000001875 compounds Chemical class 0.000 description 17
230000000704 physical effect Effects 0.000 description 15
239000000047 product Substances 0.000 description 15
229910052799 carbon Inorganic materials 0.000 description 14
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 13
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 12
230000035508 accumulation Effects 0.000 description 12
238000009825 accumulation Methods 0.000 description 12
238000006477 desulfuration reaction Methods 0.000 description 12
230000023556 desulfurization Effects 0.000 description 12
229910001385 heavy metal Inorganic materials 0.000 description 12
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 12
150000002739 metals Chemical class 0.000 description 12
238000002441 X-ray diffraction Methods 0.000 description 11
-1 for example Chemical class 0.000 description 11
239000000243 solution Substances 0.000 description 11
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 10
238000004898 kneading Methods 0.000 description 10
239000007858 starting material Substances 0.000 description 10
238000001354 calcination Methods 0.000 description 9
239000013078 crystal Substances 0.000 description 9
230000007423 decrease Effects 0.000 description 9
229910000037 hydrogen sulfide Inorganic materials 0.000 description 9
239000000843 powder Substances 0.000 description 9
238000012545 processing Methods 0.000 description 9
239000002253 acid Substances 0.000 description 8
238000000151 deposition Methods 0.000 description 8
230000005484 gravity Effects 0.000 description 8
230000002829 reductive effect Effects 0.000 description 8
239000012535 impurity Substances 0.000 description 7
239000000395 magnesium oxide Substances 0.000 description 7
230000009467 reduction Effects 0.000 description 7
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
239000007864 aqueous solution Substances 0.000 description 6
230000015572 biosynthetic process Effects 0.000 description 6
239000004927 clay Substances 0.000 description 6
230000008021 deposition Effects 0.000 description 6
FSBVERYRVPGNGG-UHFFFAOYSA-N dimagnesium dioxido-bis[[oxido(oxo)silyl]oxy]silane hydrate Chemical compound O.[Mg+2].[Mg+2].[O-][Si](=O)O[Si]([O-])([O-])O[Si]([O-])=O FSBVERYRVPGNGG-UHFFFAOYSA-N 0.000 description 6
238000009826 distribution Methods 0.000 description 6
238000004519 manufacturing process Methods 0.000 description 6
150000002736 metal compounds Chemical class 0.000 description 6
239000010734 process oil Substances 0.000 description 6
150000003839 salts Chemical class 0.000 description 6
239000000377 silicon dioxide Substances 0.000 description 6
239000000126 substance Substances 0.000 description 6
230000004913 activation Effects 0.000 description 5
238000004517 catalytic hydrocracking Methods 0.000 description 5
239000012153 distilled water Substances 0.000 description 5
238000001035 drying Methods 0.000 description 5
XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
239000000463 material Substances 0.000 description 5
229910052757 nitrogen Inorganic materials 0.000 description 5
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 4
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
230000018199 S phase Effects 0.000 description 4
XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 4
239000010426 asphalt Substances 0.000 description 4
238000000921 elemental analysis Methods 0.000 description 4
239000007789 gas Substances 0.000 description 4
238000002156 mixing Methods 0.000 description 4
239000002245 particle Substances 0.000 description 4
238000003756 stirring Methods 0.000 description 4
239000000725 suspension Substances 0.000 description 4
229910001935 vanadium oxide Inorganic materials 0.000 description 4
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 3
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 3
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 3
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
229910004298 SiO 2 Inorganic materials 0.000 description 3
WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 3
235000011114 ammonium hydroxide Nutrition 0.000 description 3
238000004458 analytical method Methods 0.000 description 3
125000004429 atom Chemical group 0.000 description 3
KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 3
229960002645 boric acid Drugs 0.000 description 3
235000010338 boric acid Nutrition 0.000 description 3
239000003245 coal Substances 0.000 description 3
229910052681 coesite Inorganic materials 0.000 description 3
229910052906 cristobalite Inorganic materials 0.000 description 3
239000010779 crude oil Substances 0.000 description 3
230000007812 deficiency Effects 0.000 description 3
238000011161 development Methods 0.000 description 3
230000018109 developmental process Effects 0.000 description 3
238000004821 distillation Methods 0.000 description 3
238000001914 filtration Methods 0.000 description 3
239000002198 insoluble material Substances 0.000 description 3
229910052742 iron Inorganic materials 0.000 description 3
239000011777 magnesium Substances 0.000 description 3
239000000693 micelle Substances 0.000 description 3
230000036961 partial effect Effects 0.000 description 3
238000011160 research Methods 0.000 description 3
235000012239 silicon dioxide Nutrition 0.000 description 3
239000002904 solvent Substances 0.000 description 3
229910052682 stishovite Inorganic materials 0.000 description 3
238000005486 sulfidation Methods 0.000 description 3
150000003464 sulfur compounds Chemical class 0.000 description 3
CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 3
229910052723 transition metal Inorganic materials 0.000 description 3
150000003624 transition metals Chemical class 0.000 description 3
229910052905 tridymite Inorganic materials 0.000 description 3
QPUYECUOLPXSFR-UHFFFAOYSA-N 1-methylnaphthalene Chemical compound C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 description 2
HNNQYHFROJDYHQ-UHFFFAOYSA-N 3-(4-ethylcyclohexyl)propanoic acid 3-(3-ethylcyclopentyl)propanoic acid Chemical compound CCC1CCC(CCC(O)=O)C1.CCC1CCC(CCC(O)=O)CC1 HNNQYHFROJDYHQ-UHFFFAOYSA-N 0.000 description 2
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 2
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
229910015667 MoO4 Inorganic materials 0.000 description 2
OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 2
230000002411 adverse Effects 0.000 description 2
238000007605 air drying Methods 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 2
239000011609 ammonium molybdate Substances 0.000 description 2
229940010552 ammonium molybdate Drugs 0.000 description 2
235000018660 ammonium molybdate Nutrition 0.000 description 2
MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
150000004982 aromatic amines Chemical class 0.000 description 2
229910052785 arsenic Inorganic materials 0.000 description 2
238000009835 boiling Methods 0.000 description 2
239000004327 boric acid Substances 0.000 description 2
239000007833 carbon precursor Substances 0.000 description 2
239000003575 carbonaceous material Substances 0.000 description 2
238000006555 catalytic reaction Methods 0.000 description 2
150000001805 chlorine compounds Chemical class 0.000 description 2
UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 2
229910001981 cobalt nitrate Inorganic materials 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
239000002131 composite material Substances 0.000 description 2
XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 2
NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
230000007547 defect Effects 0.000 description 2
239000010459 dolomite Substances 0.000 description 2
229910000514 dolomite Inorganic materials 0.000 description 2
239000000295 fuel oil Substances 0.000 description 2
239000008187 granular material Substances 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
238000005470 impregnation Methods 0.000 description 2
150000002605 large molecules Chemical class 0.000 description 2
229920002521 macromolecule Polymers 0.000 description 2
230000007246 mechanism Effects 0.000 description 2
229910017464 nitrogen compound Inorganic materials 0.000 description 2
150000002830 nitrogen compounds Chemical class 0.000 description 2
239000003208 petroleum Substances 0.000 description 2
235000011007 phosphoric acid Nutrition 0.000 description 2
IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 2
238000003825 pressing Methods 0.000 description 2
150000003856 quaternary ammonium compounds Chemical class 0.000 description 2
239000006104 solid solution Substances 0.000 description 2
150000003681 vanadium Chemical class 0.000 description 2
UUUGYDOQQLOJQA-UHFFFAOYSA-L vanadyl sulfate Chemical compound [V+2]=O.[O-]S([O-])(=O)=O UUUGYDOQQLOJQA-UHFFFAOYSA-L 0.000 description 2
229940041260 vanadyl sulfate Drugs 0.000 description 2
229910000352 vanadyl sulfate Inorganic materials 0.000 description 2
238000005406 washing Methods 0.000 description 2
WHRZCXAVMTUTDD-UHFFFAOYSA-N 1h-furo[2,3-d]pyrimidin-2-one Chemical compound N1C(=O)N=C2OC=CC2=C1 WHRZCXAVMTUTDD-UHFFFAOYSA-N 0.000 description 1
LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 description 1
PJRGDKFLFAYRBV-UHFFFAOYSA-N 2-phenylthiophene Chemical compound C1=CSC(C=2C=CC=CC=2)=C1 PJRGDKFLFAYRBV-UHFFFAOYSA-N 0.000 description 1
229910018404 Al2 O3 Inorganic materials 0.000 description 1
229910016467 AlCl 4 Inorganic materials 0.000 description 1
USFZMSVCRYTOJT-UHFFFAOYSA-N Ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 description 1
239000005695 Ammonium acetate Substances 0.000 description 1
229910021532 Calcite Inorganic materials 0.000 description 1
229910021580 Cobalt(II) chloride Inorganic materials 0.000 description 1
229910021503 Cobalt(II) hydroxide Inorganic materials 0.000 description 1
206010011878 Deafness Diseases 0.000 description 1
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
229910017344 Fe2 O3 Inorganic materials 0.000 description 1
CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
244000073231 Larrea tridentata Species 0.000 description 1
235000006173 Larrea tridentata Nutrition 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
UEZVMMHDMIWARA-UHFFFAOYSA-N Metaphosphoric acid Chemical compound OP(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-N 0.000 description 1
LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
229910004742 Na2 O Inorganic materials 0.000 description 1
241000282320 Panthera leo Species 0.000 description 1
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
240000004808 Saccharomyces cerevisiae Species 0.000 description 1
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
229910010298 TiOSO4 Inorganic materials 0.000 description 1
UDKXBPLHYDCWIG-UHFFFAOYSA-M [S-2].[S-2].[SH-].S.[V+5] Chemical compound [S-2].[S-2].[SH-].S.[V+5] UDKXBPLHYDCWIG-UHFFFAOYSA-M 0.000 description 1
LXASOGUHMSNFCR-UHFFFAOYSA-D [V+5].[V+5].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O Chemical compound [V+5].[V+5].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O LXASOGUHMSNFCR-UHFFFAOYSA-D 0.000 description 1
YNZSKFFENDBGOV-UHFFFAOYSA-N [V].N1C(C=C2N=C(C=C3NC(=C4)C=C3)C=C2)=CC=C1C=C1C=CC4=N1 Chemical compound [V].N1C(C=C2N=C(C=C3NC(=C4)C=C3)C=C2)=CC=C1C=C1C=CC4=N1 YNZSKFFENDBGOV-UHFFFAOYSA-N 0.000 description 1
229960000583 acetic acid Drugs 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
230000009471 action Effects 0.000 description 1
239000012190 activator Substances 0.000 description 1
125000002015 acyclic group Chemical class 0.000 description 1
239000003463 adsorbent Substances 0.000 description 1
230000001476 alcoholic effect Effects 0.000 description 1
125000002723 alicyclic group Chemical class 0.000 description 1
150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
239000012670 alkaline solution Substances 0.000 description 1
229910000147 aluminium phosphate Inorganic materials 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
229940043376 ammonium acetate Drugs 0.000 description 1
235000019257 ammonium acetate Nutrition 0.000 description 1
235000019270 ammonium chloride Nutrition 0.000 description 1
239000000908 ammonium hydroxide Substances 0.000 description 1
ZRIUUUJAJJNDSS-UHFFFAOYSA-N ammonium phosphates Chemical compound [NH4+].[NH4+].[NH4+].[O-]P([O-])([O-])=O ZRIUUUJAJJNDSS-UHFFFAOYSA-N 0.000 description 1
YVBOZGOAVJZITM-UHFFFAOYSA-P ammonium phosphomolybdate Chemical compound [NH4+].[NH4+].[NH4+].[NH4+].[O-]P([O-])=O.[O-][Mo]([O-])(=O)=O YVBOZGOAVJZITM-UHFFFAOYSA-P 0.000 description 1
229910052612 amphibole Inorganic materials 0.000 description 1
239000011260 aqueous acid Substances 0.000 description 1
150000001491 aromatic compounds Chemical class 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
UNTBPXHCXVWYOI-UHFFFAOYSA-O azanium;oxido(dioxo)vanadium Chemical compound [NH4+].[O-][V](=O)=O UNTBPXHCXVWYOI-UHFFFAOYSA-O 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
230000002308 calcification Effects 0.000 description 1
229910000019 calcium carbonate Inorganic materials 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
238000005119 centrifugation Methods 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
150000001868 cobalt Chemical class 0.000 description 1
229910021446 cobalt carbonate Inorganic materials 0.000 description 1
150000001869 cobalt compounds Chemical class 0.000 description 1
ZOTKGJBKKKVBJZ-UHFFFAOYSA-L cobalt(2+);carbonate Chemical compound [Co+2].[O-]C([O-])=O ZOTKGJBKKKVBJZ-UHFFFAOYSA-L 0.000 description 1
OBWXQDHWLMJOOD-UHFFFAOYSA-H cobalt(2+);dicarbonate;dihydroxide;hydrate Chemical compound O.[OH-].[OH-].[Co+2].[Co+2].[Co+2].[O-]C([O-])=O.[O-]C([O-])=O OBWXQDHWLMJOOD-UHFFFAOYSA-H 0.000 description 1
ASKVAEGIVYSGNY-UHFFFAOYSA-L cobalt(ii) hydroxide Chemical compound [OH-].[OH-].[Co+2] ASKVAEGIVYSGNY-UHFFFAOYSA-L 0.000 description 1
IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical class [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
230000001427 coherent effect Effects 0.000 description 1
238000000748 compression moulding Methods 0.000 description 1
239000000356 contaminant Substances 0.000 description 1
229910000365 copper sulfate Inorganic materials 0.000 description 1
ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 1
ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
OPQARKPSCNTWTJ-UHFFFAOYSA-L copper(ii) acetate Chemical compound [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 description 1
229960002126 creosote Drugs 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
238000007324 demetalation reaction Methods 0.000 description 1
230000003009 desulfurizing effect Effects 0.000 description 1
235000014113 dietary fatty acids Nutrition 0.000 description 1
DGVMNQYBHPSIJS-UHFFFAOYSA-N dimagnesium;2,2,6,6-tetraoxido-1,3,5,7-tetraoxa-2,4,6-trisilaspiro[3.3]heptane;hydrate Chemical compound O.[Mg+2].[Mg+2].O1[Si]([O-])([O-])O[Si]21O[Si]([O-])([O-])O2 DGVMNQYBHPSIJS-UHFFFAOYSA-N 0.000 description 1
XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 description 1
238000002845 discoloration Methods 0.000 description 1
150000002019 disulfides Chemical class 0.000 description 1
ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical compound CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 description 1
229940071106 ethylenediaminetetraacetate Drugs 0.000 description 1
239000000194 fatty acid Substances 0.000 description 1
229930195729 fatty acid Natural products 0.000 description 1
239000000835 fiber Substances 0.000 description 1
239000012065 filter cake Substances 0.000 description 1
239000010419 fine particle Substances 0.000 description 1
238000002309 gasification Methods 0.000 description 1
239000012362 glacial acetic acid Substances 0.000 description 1
229940093915 gynecological organic acid Drugs 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
125000005842 heteroatom Chemical group 0.000 description 1
238000003837 high-temperature calcination Methods 0.000 description 1
150000004677 hydrates Chemical class 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
238000005984 hydrogenation reaction Methods 0.000 description 1
238000007654 immersion Methods 0.000 description 1
230000006872 improvement Effects 0.000 description 1
230000002779 inactivation Effects 0.000 description 1
229910010272 inorganic material Inorganic materials 0.000 description 1
239000011147 inorganic material Substances 0.000 description 1
230000003993 interaction Effects 0.000 description 1
238000011835 investigation Methods 0.000 description 1
238000005342 ion exchange Methods 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
230000000670 limiting effect Effects 0.000 description 1
238000003754 machining Methods 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
229910052748 manganese Inorganic materials 0.000 description 1
238000005259 measurement Methods 0.000 description 1
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
229910052753 mercury Inorganic materials 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
239000005078 molybdenum compound Substances 0.000 description 1
150000002752 molybdenum compounds Chemical class 0.000 description 1
238000000465 moulding Methods 0.000 description 1
229910000480 nickel oxide Inorganic materials 0.000 description 1
BMGNSKKZFQMGDH-FDGPNNRMSA-L nickel(2+);(z)-4-oxopent-2-en-2-olate Chemical compound [Ni+2].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O BMGNSKKZFQMGDH-FDGPNNRMSA-L 0.000 description 1
229910000008 nickel(II) carbonate Inorganic materials 0.000 description 1
ZULUUIKRFGGGTL-UHFFFAOYSA-L nickel(ii) carbonate Chemical compound [Ni+2].[O-]C([O-])=O ZULUUIKRFGGGTL-UHFFFAOYSA-L 0.000 description 1
BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
235000005985 organic acids Nutrition 0.000 description 1
235000006408 oxalic acid Nutrition 0.000 description 1
VGTPKLINSHNZRD-UHFFFAOYSA-N oxoborinic acid Chemical compound OB=O VGTPKLINSHNZRD-UHFFFAOYSA-N 0.000 description 1
GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
KADRTWZQWGIUGO-UHFFFAOYSA-L oxotitanium(2+);sulfate Chemical compound [Ti+2]=O.[O-]S([O-])(=O)=O KADRTWZQWGIUGO-UHFFFAOYSA-L 0.000 description 1
230000035515 penetration Effects 0.000 description 1
MJKYCJBIICJHRD-UHFFFAOYSA-N pentane-2,4-dione;vanadium Chemical compound [V].CC(=O)CC(C)=O MJKYCJBIICJHRD-UHFFFAOYSA-N 0.000 description 1
239000003209 petroleum derivative Substances 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
UYDPQDSKEDUNKV-UHFFFAOYSA-N phosphanylidynetungsten Chemical compound [W]#P UYDPQDSKEDUNKV-UHFFFAOYSA-N 0.000 description 1
239000002574 poison Substances 0.000 description 1
231100000614 poison Toxicity 0.000 description 1
231100000572 poisoning Toxicity 0.000 description 1
230000000607 poisoning effect Effects 0.000 description 1
238000006068 polycondensation reaction Methods 0.000 description 1
125000003367 polycyclic group Chemical group 0.000 description 1
239000012254 powdered material Substances 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
238000011085 pressure filtration Methods 0.000 description 1
230000002035 prolonged effect Effects 0.000 description 1
230000001737 promoting effect Effects 0.000 description 1
229940005657 pyrophosphoric acid Drugs 0.000 description 1
238000007670 refining Methods 0.000 description 1
239000011347 resin Substances 0.000 description 1
229920005989 resin Polymers 0.000 description 1
230000004044 response Effects 0.000 description 1
230000005070 ripening Effects 0.000 description 1
238000004904 shortening Methods 0.000 description 1
238000007086 side reaction Methods 0.000 description 1
238000007873 sieving Methods 0.000 description 1
239000002002 slurry Substances 0.000 description 1
238000007613 slurry method Methods 0.000 description 1
239000007787 solid Substances 0.000 description 1
238000000638 solvent extraction Methods 0.000 description 1
238000001228 spectrum Methods 0.000 description 1
238000005507 spraying Methods 0.000 description 1
238000010561 standard procedure Methods 0.000 description 1
BUUPQKDIAURBJP-UHFFFAOYSA-N sulfinic acid Chemical compound OS=O BUUPQKDIAURBJP-UHFFFAOYSA-N 0.000 description 1
150000003460 sulfonic acids Chemical class 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
238000005987 sulfurization reaction Methods 0.000 description 1
229920002994 synthetic fiber Polymers 0.000 description 1
239000006188 syrup Substances 0.000 description 1
235000020357 syrup Nutrition 0.000 description 1
239000011275 tar sand Substances 0.000 description 1
238000012360 testing method Methods 0.000 description 1
238000004227 thermal cracking Methods 0.000 description 1
125000000101 thioether group Chemical group 0.000 description 1
229930192474 thiophene Natural products 0.000 description 1
JUWGUJSXVOBPHP-UHFFFAOYSA-B titanium(4+);tetraphosphate Chemical compound [Ti+4].[Ti+4].[Ti+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O JUWGUJSXVOBPHP-UHFFFAOYSA-B 0.000 description 1
125000005287 vanadyl group Chemical group 0.000 description 1
PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1
230000004580 weight loss Effects 0.000 description 1
238000005550 wet granulation Methods 0.000 description 1
238000009736 wetting Methods 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/20—Vanadium, niobium or tantalum
- B01J23/22—Vanadium
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
- B01J27/04—Sulfides
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/613—10-100 m2/g
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/635—0.5-1.0 ml/g
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/638—Pore volume more than 1.0 ml/g
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/647—2-50 nm
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

NL7907580A 1978-10-14 1979-10-12 Katalysator voor de hydrobehandeling van zware koolwaterstofolieen alsmede werkwijze ter bereiding van deze katalysator. NL7907580A (nl)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
JP12568978A JPS5554036A (en)	1978-10-14	1978-10-14	Preparing of catalyst for hydrogenation process
JP12568978		1978-10-14
JP15320078		1978-12-13
JP15320078A JPS5579043A (en)	1978-12-13	1978-12-13	Hydrogenation catalyst for heavy hydrocarbon oil

Publications (1)

Publication Number	Publication Date
NL7907580A true NL7907580A (nl)	1980-04-16

Family

ID=26462043

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NL7907580A NL7907580A (nl)	1978-10-14	1979-10-12	Katalysator voor de hydrobehandeling van zware koolwaterstofolieen alsmede werkwijze ter bereiding van deze katalysator.

Country Status (5)

Country	Link
US (1)	US4326991A (de)
CA (1)	CA1131199A (de)
DE (1)	DE2941010C2 (de)
GB (1)	GB2036582B (de)
NL (1)	NL7907580A (de)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS595011B2 (ja) *	1979-11-27	1984-02-02	千代田化工建設株式会社	重質炭化水素油の水素化処理用触媒ならびにその製法
JPS57123290A (en) *	1981-01-25	1982-07-31	Chiyoda Chem Eng & Constr Co Ltd	Method for converting heavy hydrocarbon oil into light fractions
JPS58219293A (ja) *	1982-06-15	1983-12-20	Chiyoda Chem Eng & Constr Co Ltd	重質油の水素化分解方法
US4450068A (en) *	1982-12-20	1984-05-22	Phillips Petroleum Company	Demetallization of hydrocarbon containing feed streams
US4519897A (en) *	1982-12-27	1985-05-28	Akzo Nv	Fluid cracking process using sepiolite-containing catalyst composition
US4539101A (en) *	1983-08-17	1985-09-03	Mobil Oil Corporation	Method and catalyst for removing contaminants from hydrocarbonaceous fluids using a copper-Group VIA metal-alumina catalyst
FR2588879B1 (fr) *	1985-10-18	1988-09-16	Elf France	Procede d'hydrotraitement des charges hydrocarbonees
US5296130A (en) *	1993-01-06	1994-03-22	Energy Mines And Resources Canada	Hydrocracking of heavy asphaltenic oil in presence of an additive to prevent coke formation
DE69708829T2 (de) *	1996-12-27	2002-04-04	Inst Francais Du Petrol	Wasserstoffbehandlung und Hydrocrackkatalysator enthaltend ein Mischsulfid mit Schwefel, zumindest ein Element der Gruppe 5B und zumindest ein Element der Gruppe 6B
FR2780303B1 (fr)	1998-06-25	2000-07-28	Inst Francais Du Petrole	Procede de sulfuration de catalyseurs en milieu reducteur et utilisation du catalyseur sulfure dans des reactions de raffinage ou d'hydroconversion
US6562752B2 (en) *	1998-06-25	2003-05-13	Institut Francais Du Petrole	Metallic sulphide catalysts, processes for synthesising said catalysts and use thereof
FR2780308B1 (fr)	1998-06-25	2000-08-11	Inst Francais Du Petrole	Catalyseur comprenant une argile et un element du groupe vb, et son utilisation en hydrocraquage de charges petrolieres hydrocarbonees
CN106268797B (zh) *	2016-07-15	2018-10-19	常州大学	一种凹土基贵金属重整生成油液相加氢脱烯烃催化剂及其制备方法和应用
CN106268792B (zh) *	2016-07-15	2018-10-19	常州大学	一种凹土基重整生成油液相加氢脱烯烃催化剂及其制备方法和应用

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* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR1307290A (fr) *	1961-08-30	1962-10-26	Exxon Research Engineering Co	Perfectionnements aux catalyseurs d'hydroraffinage
FR1482144A (fr)	1966-04-12	1967-05-26	Exxon Research Engineering Co	Perfectionnement aux catalyseurs d'hydroraffinage
US3553106A (en) *	1968-06-28	1971-01-05	Gulf Research Development Co	Catalytic removal of vanadium and nickel from oils
US3558474A (en) *	1968-09-30	1971-01-26	Universal Oil Prod Co	Slurry process for hydrorefining petroleum crude oil
US3576737A (en) *	1969-03-25	1971-04-27	Chevron Res	Vanadium removal from hydrocarbons
US3696027A (en) *	1970-01-12	1972-10-03	Chevron Res	Multi-stage desulfurization
DE2103027C3 (de) *	1971-01-22	1978-09-28	Uop Inc., Des Plaines, Ill. (V.St.A.)	Verfahren zum Raffinieren eines heptanunlösliche Asphaltene enthaltenden Kohlenwasserstoffmaterials
US3798156A (en) *	1971-09-22	1974-03-19	Standard Oil Co	Hydroprocessing catalyst and process
US3723294A (en) *	1971-10-18	1973-03-27	Universal Oil Prod Co	Conversion of asphaltene-containing hydrocarbonaceous charge stocks
US3723297A (en) *	1971-10-18	1973-03-27	Universal Oil Prod Co	Conversion of asphaltene-containing charge stocks
DE2421978C3 (de) *	1974-05-07	1980-03-20	Deutsche Texaco Ag, 2000 Hamburg	Verfahren zur Entmetallisierung von hauptsächlich metallorganische Verbindungen und Schwefelverbindungen sowie Asphaltene als Verunreinigungen enthaltenden Erdölkohlenwasserstoffeinsatzmaterialien
US4152250A (en) *	1975-12-09	1979-05-01	Chiyoda Chemical Engineering & Construction	Demetallation of hydrocarbons with catalysts supported on sepiolite
US4066530A (en) *	1976-07-02	1978-01-03	Exxon Research & Engineering Co.	Hydroconversion of heavy hydrocarbons
JPS541306A (en) *	1977-06-07	1979-01-08	Chiyoda Chem Eng & Constr Co Ltd	Hydrogenation of heavy hydrocarbon oil

1979
- 1979-10-08 GB GB7934802A patent/GB2036582B/en not_active Expired
- 1979-10-10 DE DE2941010A patent/DE2941010C2/de not_active Expired
- 1979-10-12 NL NL7907580A patent/NL7907580A/nl not_active Application Discontinuation
- 1979-10-12 CA CA337,480A patent/CA1131199A/en not_active Expired
- 1979-10-15 US US06/084,764 patent/US4326991A/en not_active Expired - Lifetime

Also Published As

Publication number	Publication date
US4326991A (en)	1982-04-27
DE2941010A1 (de)	1980-06-04
GB2036582B (en)	1983-03-02
DE2941010C2 (de)	1986-11-20
CA1131199A (en)	1982-09-07
GB2036582A (en)	1980-07-02

Publication	Publication Date	Title
US4424142A (en)	1984-01-03	Catalyst for hydrotreatment of heavy hydrocarbon oils
DE60012887T2 (de)	2005-08-25	Herstellung eines wasserstoffbehandlungskatalysators
US10569254B2 (en)	2020-02-25	Catalyst support and catalysts prepared therefrom
DE69423106T2 (de)	2000-11-09	Wasserstoffbehandlungskatalysator und seine verwendung
RU2342995C2 (ru)	2009-01-10	Катализаторы гидроконверсии и способы их изготовления и применения
US4082695A (en)	1978-04-04	Catalyst for residua demetalation and desulfurization
US8021538B2 (en)	2011-09-20	Hydroconversion catalysts and methods of making and using same
KR100209814B1 (ko)	1999-07-15	수소화처리 촉매조성물, 그 제조방법 및 용도
NL7907580A (nl)	1980-04-16	Katalysator voor de hydrobehandeling van zware koolwaterstofolieen alsmede werkwijze ter bereiding van deze katalysator.
NL8006444A (nl)	1981-07-01	Katalysator voor het hydrobehandelen van zware koolwaterstofolien, werkwijzen ter bereiding daarvan, alsmede werkwijzen voor het hydrobehandelen van zware koolwaterstofolieen in aanwezigheid van een dergelijke katalysator.
US3931052A (en)	1976-01-06	Alumina-supported catalyst for residua demetalation and desulfurization
WO2007050636A2 (en)	2007-05-03	Hydroprocessing using bulk bimetallic catalysts
JP2002534586A (ja)	2002-10-15	バルク多金属触媒を用いるスラリー水素処理
WO1993005878A1 (en)	1993-04-01	Resid hydroprocessing catalyst
JP2004517710A (ja)	2004-06-17	可燃性バインダーを含む混合金属触媒
CA3029930C (en)	2023-12-12	Hydrotreatment catalysts and process for preparing said catalysts
RU2473387C1 (ru)	2013-01-27	Способ получения массивного катализатора гидропереработки тяжелых нефтяных фракций
EP0178100B1 (de)	1990-01-03	Trägermischungen eines Sulfides von dreiwertigem Chrom und Molybdän oder Wolfram enthaltende Hydrierkatalysatoren
CN101360560B (zh)	2014-08-13	利用体相双金属催化剂的加氢处理
US11674094B2 (en)	2023-06-13	Co-mixed catalyst produced from solutions containing heteropolyanions, method for the production thereof, and use of same in hydroconversion of heavy hydrocarbon feedstock
US4910181A (en)	1990-03-20	Hydrogen bronze catalyst for demetallizing petroleum resids
Batista	2016	Innovative preparations of heterogeneous catalysts for the production of (bio) fuels
US4781817A (en)	1988-11-01	Hydrogen bronze catalyst and improved resid upgrading processes using it
US4812227A (en)	1989-03-14	Hydrotreating with catalysts comprising mixtures of an amorphous sulfide or trivalent chromium and microcrystallites of molybdenum sulfide or tungsten sulfide
EP0183354B1 (de)	1989-04-12	Hydrobehandlungskatalysatoren die eine Mischung aus einem amorphen Sulfid von dreiwertigem Chrom und Mikrokristalliten von Molybdän- oder Wolframsulfid enthalten

Legal Events

Date	Code	Title
1980-05-12	A1A	A request for search or an international-type search has been filed
1982-01-04	BB	A search report has been drawn up
1985-01-01	A85	Still pending on 85-01-01
1985-11-01	BC	A request for examination has been filed
1990-06-01	BV	The patent application has lapsed