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MY131210A - Light-duty dishwashing detergent composition containing an allkyl ethoxy carboxylate surfactant and calcium or magnesium ions - Google Patents

Light-duty dishwashing detergent composition containing an allkyl ethoxy carboxylate surfactant and calcium or magnesium ions

Info

Publication number
MY131210A
MY131210A MYPI91002116A MYPI9102116A MY131210A MY 131210 A MY131210 A MY 131210A MY PI91002116 A MYPI91002116 A MY PI91002116A MY PI9102116 A MYPI9102116 A MY PI9102116A MY 131210 A MY131210 A MY 131210A
Authority
MY
Malaysia
Prior art keywords
calcium
magnesium ions
detergent composition
compositions
light
Prior art date
Application number
MYPI91002116A
Other languages
English (en)
Inventor
Thomas Anthony Cripe
Kofi Ofosu-Asante
Original Assignee
Procter & Gamble
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter & Gamble filed Critical Procter & Gamble
Publication of MY131210A publication Critical patent/MY131210A/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/04Carboxylic acids or salts thereof
    • C11D1/06Ether- or thioether carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00Compositions of detergents, not provided for by one single preceding group
    • C11D10/04Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00Compositions of detergents, not provided for by one single preceding group
    • C11D10/04Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C11D10/042Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/003Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/143Sulfonic acid esters
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146Sulfuric acid esters
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/28Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29Sulfates of polyoxyalkylene ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/52Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/521Carboxylic amides (R1-CO-NR2R3), where R1, R2 and R3 are alkyl or alkenyl groups
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/52Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/525Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/662Carbohydrates or derivatives
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/75Amino oxides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88Ampholytes; Electroneutral compounds
    • C11D1/90Betaines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)
MYPI91002116A 1990-11-16 1991-11-15 Light-duty dishwashing detergent composition containing an allkyl ethoxy carboxylate surfactant and calcium or magnesium ions MY131210A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US61453290A 1990-11-16 1990-11-16
US61453190A 1990-11-16 1990-11-16

Publications (1)

Publication Number Publication Date
MY131210A true MY131210A (en) 2007-07-31

Family

ID=27087270

Family Applications (1)

Application Number Title Priority Date Filing Date
MYPI91002116A MY131210A (en) 1990-11-16 1991-11-15 Light-duty dishwashing detergent composition containing an allkyl ethoxy carboxylate surfactant and calcium or magnesium ions

Country Status (22)

Country Link
EP (1) EP0557426B1 (es)
JP (1) JP3009464B2 (es)
CN (1) CN1062371A (es)
AR (1) AR244795A1 (es)
AT (1) ATE149561T1 (es)
AU (1) AU9063991A (es)
BR (1) BR9106983A (es)
CZ (1) CZ87393A3 (es)
DE (1) DE69125022T2 (es)
DK (1) DK0557426T3 (es)
ES (1) ES2101078T3 (es)
FI (1) FI932199L (es)
GR (1) GR3023502T3 (es)
HU (1) HUT64782A (es)
MA (1) MA22342A1 (es)
MX (1) MX9102078A (es)
MY (1) MY131210A (es)
NO (1) NO931738L (es)
PT (2) PT99527A (es)
SK (1) SK48093A3 (es)
TR (1) TR26532A (es)
WO (1) WO1992008777A1 (es)

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* Cited by examiner, † Cited by third party
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DE69229503T2 (de) * 1991-09-06 2000-01-27 Procter & Gamble Calcium und polyhydroxyfettsäureamid enthaltenden waschmittelzusammensetzungen
US5298195A (en) * 1992-03-09 1994-03-29 Amway Corporation Liquid dishwashing detergent
NL9201339A (nl) * 1992-07-24 1994-02-16 Chem Y Gmbh Vloeibare geconcentreerde oplossingen van alkylethercarbonzuurzouten in water.
CA2143328A1 (en) * 1992-09-01 1994-03-17 Kofi Ofosu-Asante Liquid or gel dishwashing detergent containing alkyl ethoxy carboxylate, divalent ions and alkylpolyethoxypolycarboxylate
US5545354A (en) * 1992-09-01 1996-08-13 The Procter & Gamble Company Liquid or gel dishwashing detergent containing a polyhydroxy fatty acid amide, calcium ions and an alkylpolyethoxypolycarboxylate
US5269974A (en) * 1992-09-01 1993-12-14 The Procter & Gamble Company Liquid or gel dishwashing detergent composition containing alkyl amphocarboxylic acid and magnesium or calcium ions
CA2143330C (en) * 1992-09-01 1999-02-23 Julie Anne Dyet Liquid or gel detergent compositions containing calcium and stabilizing agent thereof
CA2148099A1 (en) * 1992-11-30 1994-06-09 Yi-Chang Fu Detergent compositions with calcium ions and polyhydroxy fatty acid amide nonionic/selected anionic/soap surfactant mixture
US5415814A (en) * 1993-08-27 1995-05-16 The Procter & Gamble Company Concentrated liquid or gel light duty dishwashing detergent composition containing calcium xylene sulfonate
US5417893A (en) * 1993-08-27 1995-05-23 The Procter & Gamble Company Concentrated liquid or gel light duty dishwashing detergent compositions containing calcium ions and disulfonate surfactants
US5415801A (en) * 1993-08-27 1995-05-16 The Procter & Gamble Company Concentrated light duty liquid or gel dishwashing detergent compositions containing sugar
US5474710A (en) * 1993-08-27 1995-12-12 Ofosu-Asanta; Kofi Process for preparing concentrated surfactant mixtures containing magnesium
KR100351396B1 (ko) * 1993-09-14 2002-11-23 더 프록터 앤드 갬블 캄파니 프로테아제를 함유하는 경질 액상 또는 겔상의 식기세척 세제조성물
ATE318304T1 (de) 1993-10-08 2006-03-15 Novozymes As Amylasevarianten
WO1995023202A1 (en) 1994-02-23 1995-08-31 Ecolab Inc. Alkaline cleaners based on alcohol ethoxy carboxylates
CA2147674C (en) * 1994-05-16 1999-03-30 David Robert Zint Shaped semi-solid or solid dishwashing detergent
ZA955295B (en) * 1994-06-27 1996-02-13 Diversey Corp Non-silicated soft metal safe product
US7404967B2 (en) 1994-12-21 2008-07-29 Cosmederm, Inc. Topical product formulations containing strontium for reducing skin irritation
US5958436A (en) * 1995-12-21 1999-09-28 Cosmederm Technologies Formulations and methods for reducing skin irritation
CN1247559A (zh) * 1996-12-20 2000-03-15 普罗格特-甘布尔公司 含有链烷醇胺的餐具洗涤组合物
AR017745A1 (es) * 1999-02-08 2001-09-12 Procter & Gamble Composiciones detergentes para lavar vajilla, que contienen diaminas organicas y magnesio, para una mejor limpieza con aguas blandas.
JP4509292B2 (ja) * 2000-04-04 2010-07-21 ライオン株式会社 界面活性剤組成物
KR20100014954A (ko) 2007-03-09 2010-02-11 다니스코 유에스 인크. 호알칼리성 바실러스 종 α-아밀라아제 변이체, α-아밀라아제 변이체를 함유하는 조성물 및 사용 방법
US9040279B2 (en) 2008-06-06 2015-05-26 Danisco Us Inc. Saccharification enzyme composition and method of saccharification thereof
MX2010013114A (es) 2008-06-06 2011-04-05 Danisco Inc Alfa-amilasas variantes de bacillus subtilis y metodos de uso de las mismas.
EP2310521A2 (en) 2008-06-06 2011-04-20 Danisco US Inc. Production of glucose from starch using alpha-amylases from bacillus subtilis
EP2264138B2 (en) 2009-06-19 2023-03-08 The Procter & Gamble Company Liquid hand dishwashing detergent composition
ES2412684T3 (es) 2009-06-19 2013-07-12 The Procter & Gamble Company Composición detergente de lavado de vajillas a mano líquida
CA2778471A1 (en) 2009-10-23 2011-04-28 Danisco Us Inc. Methods for reducing blue saccharide
SE1250261A1 (sv) * 2011-10-31 2013-05-01 Billerudkorsnaes Gaevle Froevi Ab Bestrykningskomposition, ett förfarande för bestrykning av ett substrat, ettbestruket substrat, ett förpackningsmaterial och vätskeförpackning
US9096818B2 (en) * 2011-12-09 2015-08-04 Clariant International Ltd. Automatic dishwashing detergent compositions comprising ethercarboxylic acids or their salts and nonionic surfactants with a high cloud point
AU2012396242B2 (en) 2012-12-07 2015-08-13 Colgate-Palmolive Company Cleaning composition
BR112017010367B1 (pt) * 2014-11-18 2022-08-02 Basf Se Método para produção de petróleo
MX2017009300A (es) 2015-01-15 2017-12-04 Ecolab Usa Inc Espuma de limpieza de larga duracion.
CN109126622A (zh) * 2017-06-27 2019-01-04 华南师范大学 一种阴离子表面活性剂、洗涤剂和洗涤剂组合物
JP2020090606A (ja) * 2018-12-05 2020-06-11 株式会社コープクリーン 洗浄剤組成物

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FR2014084A1 (es) * 1968-07-31 1970-04-10 Hoechst Ag
US4098818A (en) * 1976-12-10 1978-07-04 The Procter & Gamble Company Process for making carboxyalkylated alkyl polyether surfactants with narrow polyethoxy chain distribution
DE2754210A1 (de) * 1976-12-10 1978-06-15 Procter & Gamble Oberflaechenaktives mittel auf basis von carboxyalkylierten alkylpolyethern
EP0107946B1 (en) * 1982-10-28 1987-03-11 THE PROCTER & GAMBLE COMPANY Liquid detergent compositions
DE3905938A1 (de) * 1989-02-25 1990-08-30 Huels Chemische Werke Ag Detergentienzusammensetzungen mit erhoehter viskositaet
ES2106729T3 (es) * 1989-05-22 1997-11-16 Procter & Gamble Composicion detergente para lavavajillas, liquida o en gel, de accion ligera, que contiene un tensioactivo de alquil-etoxi-carboxilato.

Also Published As

Publication number Publication date
FI932199A0 (fi) 1993-05-14
AU9063991A (en) 1992-06-11
WO1992008777A1 (en) 1992-05-29
MA22342A1 (fr) 1992-07-01
PT99530A (pt) 1992-09-30
CZ87393A3 (en) 1994-07-13
HU9301418D0 (en) 1993-09-28
EP0557426A1 (en) 1993-09-01
DK0557426T3 (da) 1997-09-01
HUT64782A (en) 1994-02-28
EP0557426B1 (en) 1997-03-05
BR9106983A (pt) 1993-08-24
FI932199L (fi) 1993-05-14
TR26532A (tr) 1995-03-15
SK48093A3 (en) 1994-01-12
CN1062371A (zh) 1992-07-01
ES2101078T3 (es) 1997-07-01
ATE149561T1 (de) 1997-03-15
PT99527A (pt) 1992-09-30
DE69125022T2 (de) 1997-09-25
NO931738L (no) 1993-07-15
JP3009464B2 (ja) 2000-02-14
MX9102078A (es) 1992-06-01
DE69125022D1 (de) 1997-04-10
AR244795A1 (es) 1993-11-30
JPH06502884A (ja) 1994-03-31
GR3023502T3 (en) 1997-08-29
NO931738D0 (no) 1993-05-13

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