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MXPA06013718A - Process for adding furyl-2-methylidene uv light absorbers to poly(ethylene terephthalate). - Google Patents

Process for adding furyl-2-methylidene uv light absorbers to poly(ethylene terephthalate).

Info

Publication number
MXPA06013718A
MXPA06013718A MXPA06013718A MXPA06013718A MXPA06013718A MX PA06013718 A MXPA06013718 A MX PA06013718A MX PA06013718 A MXPA06013718 A MX PA06013718A MX PA06013718 A MXPA06013718 A MX PA06013718A MX PA06013718 A MXPA06013718 A MX PA06013718A
Authority
MX
Mexico
Prior art keywords
polyester
reactants
esterified
absorbing compound
methylidene
Prior art date
Application number
MXPA06013718A
Other languages
Spanish (es)
Inventor
Earl Edmondson Howell Jr
Max Allen Weaver
Jason Clay Pearson
Perry Michael Murdaugh
Original Assignee
Eastman Chem Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastman Chem Co filed Critical Eastman Chem Co
Publication of MXPA06013718A publication Critical patent/MXPA06013718A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/91—Polymers modified by chemical after-treatment
    • C08G63/914—Polymers modified by chemical after-treatment derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/916—Dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/46—Polyesters chemically modified by esterification
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/685—Polyesters containing atoms other than carbon, hydrogen and oxygen containing nitrogen
    • C08G63/6854—Polyesters containing atoms other than carbon, hydrogen and oxygen containing nitrogen derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/6856—Dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/15—Heterocyclic compounds having oxygen in the ring
    • C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
    • C08K5/1535—Five-membered rings
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

A method for incorporating a UV light absorbing compound into a polyester prepared using direct esterification of reactants selected from a dicarboxylic acid and a diol, the method comprising reacting the reactants in an esterifying reactor under conditions sufficient to form an esterified product including at least one of an ester, an oligomer, or mixture having an ester and a mixture of low molecular weight polyester; polymerizing the esterified product in a polycondensation reactor to form a polyester; and adding the UV absorbing compound to the esterified products when at least 50% of the carboxy groups initially present in the reactants have been esterified to obtain a yield of UV absorbing compound incorporated into the polyester of greater than 40%. Articles utilizing the UV protected polyester are additionally disclosed.
MXPA06013718A 2004-05-27 2005-05-17 Process for adding furyl-2-methylidene uv light absorbers to poly(ethylene terephthalate). MXPA06013718A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/855,747 US20050277759A1 (en) 2004-05-27 2004-05-27 Process for adding furyl-2-methylidene UV light absorbers to poly(ethylene terephthalate)
PCT/US2005/017314 WO2005118671A1 (en) 2004-05-27 2005-05-17 Process for adding furyl-2-methylidene uv light absorbers to poly(ethylene terephthalate)

Publications (1)

Publication Number Publication Date
MXPA06013718A true MXPA06013718A (en) 2007-05-23

Family

ID=34970264

Family Applications (1)

Application Number Title Priority Date Filing Date
MXPA06013718A MXPA06013718A (en) 2004-05-27 2005-05-17 Process for adding furyl-2-methylidene uv light absorbers to poly(ethylene terephthalate).

Country Status (6)

Country Link
US (1) US20050277759A1 (en)
EP (1) EP1756194A1 (en)
AR (1) AR048978A1 (en)
CA (1) CA2565853A1 (en)
MX (1) MXPA06013718A (en)
WO (1) WO2005118671A1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9267007B2 (en) * 2005-09-16 2016-02-23 Grupo Petrotemex, S.A. De C.V. Method for addition of additives into a polymer melt
AU2019304450A1 (en) 2018-07-17 2021-03-11 Evonik Operations Gmbh Method for preparing C-H acidic (meth)acrylates
ES2844252T3 (en) * 2018-07-17 2021-07-21 Evonik Operations Gmbh CH-acid methacrylic esters for the preparation of aqueous polymer dispersions

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Also Published As

Publication number Publication date
CA2565853A1 (en) 2005-12-15
US20050277759A1 (en) 2005-12-15
EP1756194A1 (en) 2007-02-28
WO2005118671A1 (en) 2005-12-15
AR048978A1 (en) 2006-06-14

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