MXPA04001348A - NUEVOS COMPUESTOS DE FOSFITOS Y SUS COMPLEJOS METaLICOS. - Google Patents
NUEVOS COMPUESTOS DE FOSFITOS Y SUS COMPLEJOS METaLICOS.Info
- Publication number
- MXPA04001348A MXPA04001348A MXPA04001348A MXPA04001348A MXPA04001348A MX PA04001348 A MXPA04001348 A MX PA04001348A MX PA04001348 A MXPA04001348 A MX PA04001348A MX PA04001348 A MXPA04001348 A MX PA04001348A MX PA04001348 A MXPA04001348 A MX PA04001348A
- Authority
- MX
- Mexico
- Prior art keywords
- metal complexes
- phosphite compounds
- novel phosphite
- novel
- phosphites
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
- C07F9/6574—Esters of oxyacids of phosphorus
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0073—Rhodium compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
- C07F9/6574—Esters of oxyacids of phosphorus
- C07F9/65746—Esters of oxyacids of phosphorus the molecule containing more than one cyclic phosphorus atom
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
- B01J23/464—Rhodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/821—Ruthenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/824—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/828—Platinum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/845—Cobalt
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Se describe un fosfito segun la formula I o II y sus complejos metalicos, la elaboracion y la utilizacion de los fosfitos como ligandos en reacciones cataliticas, especialmente en procedimientos para la hidroformilacion de olefinas.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10140083A DE10140083A1 (de) | 2001-08-16 | 2001-08-16 | Neue Phosphitverbindungen und deren Metallkomplexe |
PCT/EP2002/008798 WO2003016320A1 (de) | 2001-08-16 | 2002-08-07 | Neue phosphitverbindungen und deren metallkomplexe |
Publications (1)
Publication Number | Publication Date |
---|---|
MXPA04001348A true MXPA04001348A (es) | 2004-05-05 |
Family
ID=7695542
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MXPA04001348A MXPA04001348A (es) | 2001-08-16 | 2002-08-07 | NUEVOS COMPUESTOS DE FOSFITOS Y SUS COMPLEJOS METaLICOS. |
Country Status (10)
Country | Link |
---|---|
US (1) | US7009068B2 (es) |
EP (1) | EP1417212B1 (es) |
JP (1) | JP4272986B2 (es) |
KR (1) | KR100869042B1 (es) |
CN (1) | CN1310928C (es) |
AT (1) | ATE388157T1 (es) |
DE (2) | DE10140083A1 (es) |
ES (1) | ES2301680T3 (es) |
MX (1) | MXPA04001348A (es) |
WO (1) | WO2003016320A1 (es) |
Families Citing this family (51)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10058383A1 (de) * | 2000-11-24 | 2002-05-29 | Oxeno Olefinchemie Gmbh | Neue Phosphininverbindungen und deren Metallkomplexe |
ATE377584T1 (de) * | 2001-09-26 | 2007-11-15 | Oxeno Olefinchemie Gmbh | Phthalsäurealkylestergemische mit kontrollierter viskosität |
DE10149348A1 (de) | 2001-10-06 | 2003-04-10 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von 1-Olefin mit Palladiumcarbenverbindungen |
DE60304034T2 (de) | 2002-03-11 | 2006-10-12 | Union Carbide Chemicals & Plastics Technology Corp., Danbury | Bisphosphit-ligande für carbonylierungsverfahren |
DE10220801A1 (de) * | 2002-05-10 | 2003-11-20 | Oxeno Olefinchemie Gmbh | Verfahren zur Rhodium-katalysierten Hydroformylierung von Olefinen unter Reduzierung der Rhodiumverluste |
DE10223593A1 (de) * | 2002-05-27 | 2003-12-11 | Degussa | Hydroxydiphosphine und deren Verwendung in der Katalyse |
DE10225565A1 (de) | 2002-06-10 | 2003-12-18 | Oxeno Olefinchemie Gmbh | Katalysator und Verfahren zur Hydrierung von aromatischen Verbindungen |
PL206922B1 (pl) | 2002-08-31 | 2010-10-29 | Oxeno Olefinchemie Gmbh | Sposób katalitycznego hydroformylowania związków nienasyconych olefinowo |
KR20050059116A (ko) | 2002-08-31 | 2005-06-17 | 옥세노 올레핀케미 게엠베하 | 사이클릭 카복실산 에스테르의 존재하에서의 올레핀계 불포화 화합물, 특히 올레핀의 하이드로포밀화 방법 |
ATE388956T1 (de) | 2002-10-15 | 2008-03-15 | Union Carbide Chem Plastic | Bischelatligand und seine verwendung in carbonylierungs-verfahren |
FR2847898A1 (fr) | 2002-12-02 | 2004-06-04 | Rhodia Polyamide Intermediates | Procede de fabrication de composes nitriles a partir de composes a insaturation ethylenique |
DE10257499A1 (de) | 2002-12-10 | 2004-07-01 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von 1-Olefinen durch katalytische Spaltung von 1-Alkoxyalkanen |
DE10329042A1 (de) | 2003-06-27 | 2005-01-13 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von 1-Octen aus Crack-C4 |
DE10359628A1 (de) * | 2003-12-18 | 2005-07-21 | Oxeno Olefinchemie Gmbh | Katalysator und Verfahren zur Herstellung von 1-Olefinen aus 2-Hydroxyalkanen |
DE10360772A1 (de) * | 2003-12-23 | 2005-07-28 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von Organoacylphosphiten |
DE10360771A1 (de) * | 2003-12-23 | 2005-07-28 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von dreiwertigen Organophosphor-Verbindungen |
DE102004033410A1 (de) * | 2004-02-14 | 2005-09-01 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von Olefinen mit 8 bis 12 Kohlenstoffatomen |
DE102004013514A1 (de) * | 2004-03-19 | 2005-10-06 | Oxeno Olefinchemie Gmbh | Verfahren zur Hydroformylierung von Olefinen in Anwesenheit von neuen phosphororganischen Verbindungen |
DE102004021128A1 (de) * | 2004-04-29 | 2005-11-24 | Oxeno Olefinchemie Gmbh | Vorrichtung und Verfahren für die kontinuierliche Umsetzung einer Flüssigkeit mit einem Gas an einem festen Katalysator |
DE102005036039A1 (de) | 2004-08-28 | 2006-03-02 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von 2,7-Octadienylderivaten |
DE102004063673A1 (de) * | 2004-12-31 | 2006-07-13 | Oxeno Olefinchemie Gmbh | Verfahren zur kontinuierlichen katalytischen Hydrierung von hydrierbaren Verbindungen an festen, im Festbett angeordneten Katalysatoren mit einem wasserstoffhaltigen Gas |
JP4964760B2 (ja) * | 2005-02-25 | 2012-07-04 | 株式会社クラレ | ビスホスファイト、並びに該ビスホスファイトおよび第8〜10族金属化合物を用いたアルデヒド化合物の製造方法 |
DE102005014055A1 (de) * | 2005-03-23 | 2006-09-28 | Degussa Ag | Unsymmetrisch substituierte Phospholankatalysatoren |
DE102005035816A1 (de) * | 2005-07-30 | 2007-02-01 | Oxeno Olefinchemie Gmbh | Verfahren zur Hydrierung von Oxo-Aldehyden mit hohen Estergehalten |
DE102005042464A1 (de) * | 2005-09-07 | 2007-03-08 | Oxeno Olefinchemie Gmbh | Carbonylierungsverfahren unter Zusatz von sterisch gehinderten sekundären Aminen |
DE102006034442A1 (de) * | 2006-07-26 | 2008-01-31 | Oxeno Olefinchemie Gmbh | Katalysatorvorstufe für einen Rh-Komplexkatalysator |
DE102006058682A1 (de) * | 2006-12-13 | 2008-06-19 | Evonik Oxeno Gmbh | Bisphosphitliganden für die übergangsmetallkatalysierte Hydroformylierung |
DE102007006442A1 (de) | 2007-02-05 | 2008-08-07 | Evonik Oxeno Gmbh | Gemisch von Diestern von Dianhydrohexitolderivaten mit Carbonsäuren der Summenformel C8H17COOH, Verfahren zur Herstellung dieser Diester und Verwendung dieser Gemische |
DE102007023514A1 (de) | 2007-05-18 | 2008-11-20 | Evonik Oxeno Gmbh | Stabile Katalysatorvorstufe von Rh-Komplexkatalysatoren |
DE102008002188A1 (de) * | 2008-06-03 | 2009-12-10 | Evonik Oxeno Gmbh | Verfahren zur Abtrennung von 1-Buten aus C4-haltigen Kohlenwasserstoffströmen durch Hydroformylierung |
DE102009001225A1 (de) | 2009-02-27 | 2010-09-02 | Evonik Oxeno Gmbh | Verfahren zur Anreicherung eines Homogenkatalysators aus einem Prozessstrom |
DE102009028975A1 (de) | 2009-08-28 | 2011-03-03 | Evonik Oxeno Gmbh | Esterderivate der 2,5-Furandicarbonsäure und ihre Verwendung als Weichmacher |
DE102009029050A1 (de) | 2009-08-31 | 2011-03-03 | Evonik Oxeno Gmbh | Organophosphorverbindungen basierend auf Tetraphenol(TP)-substituierten Strukturen |
GB0915946D0 (en) | 2009-09-11 | 2009-10-28 | Univ St Andrews | Metal-catalysed carbonylation of unsaturated compounds |
EP2624953B1 (en) * | 2010-10-05 | 2018-10-24 | Dow Technology Investments LLC | Hydroformylation process |
KR101890961B1 (ko) | 2010-11-12 | 2018-08-22 | 바스프 에스이 | 물 첨가에 의한 히드로포르밀화 방법에서의 오손의 완화 |
WO2012122407A2 (en) * | 2011-03-08 | 2012-09-13 | The Regents Of The University Of California | Chiral calixarenes |
SA112330271B1 (ar) | 2011-04-18 | 2015-02-09 | داو تكنولوجى انفستمنتس ال ال سى | تخفيف التلوث في عمليات هيدروفورملة عن طريق إضافة الماء |
DE102011085883A1 (de) | 2011-11-08 | 2013-05-08 | Evonik Oxeno Gmbh | Neue Organophosphorverbindungen auf Basis von Anthracentriol |
MY172419A (en) | 2012-06-04 | 2019-11-25 | Dow Technology Investments Llc | Hydroformylation process |
EP2900373B1 (en) | 2012-09-25 | 2019-04-17 | Dow Technology Investments LLC | Process for stabilizing a phosphite ligand against degradation |
JP6174711B2 (ja) | 2012-12-06 | 2017-08-02 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | ヒドロホルミル化方法 |
DE102014206520B4 (de) | 2013-05-03 | 2017-09-14 | Evonik Degussa Gmbh | Neue vierzähnige Phosphor-Liganden mit Hostanox O3 Leitstruktur |
CN106103399B (zh) | 2013-12-19 | 2019-07-09 | 陶氏技术投资有限责任公司 | 氢甲酰化方法 |
CN104725170B (zh) | 2013-12-19 | 2019-08-23 | 陶氏技术投资有限责任公司 | 加氢甲酰化方法 |
JP6560248B2 (ja) | 2014-03-31 | 2019-08-14 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | ヒドロホルミル化プロセス |
EP3029057B1 (de) | 2014-12-04 | 2019-02-20 | Evonik Degussa GmbH | Bisphosphite die einen unsymmetrischen biaryl-zentral-baustein aufweisen |
KR102000754B1 (ko) * | 2017-11-03 | 2019-07-17 | 한국과학기술원 | 두 고리 구조를 갖는 포스포라미다이트 유도체, 이의 제조방법 및 그 용도 |
PL3990176T3 (pl) | 2019-06-27 | 2025-01-27 | Dow Technology Investments Llc | Proces przygotowania roztworu z procesu hydroformylowania do odzysku metali szlachetnych |
WO2021126421A1 (en) | 2019-12-19 | 2021-06-24 | Dow Technology Investments Llc | Processes for preparing isoprene and mono-olefins comprising at least six carbon atoms |
WO2024228768A1 (en) | 2023-05-04 | 2024-11-07 | Dow Technology Investments Llc | Hydroformylation process |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4668651A (en) * | 1985-09-05 | 1987-05-26 | Union Carbide Corporation | Transition metal complex catalyzed processes |
US4748261A (en) * | 1985-09-05 | 1988-05-31 | Union Carbide Corporation | Bis-phosphite compounds |
US4885401A (en) * | 1985-09-05 | 1989-12-05 | Union Carbide Corporation | Bis-phosphite compounds |
DE4026406A1 (de) | 1990-08-21 | 1992-02-27 | Basf Ag | Rhodiumhydroformylierungskatalysatoren mit bis-phosphit-liganden |
US5312996A (en) * | 1992-06-29 | 1994-05-17 | Union Carbide Chemicals & Plastics Technology Corporation | Hydroformylation process for producing 1,6-hexanedials |
DE10053272A1 (de) | 2000-10-27 | 2002-05-08 | Oxeno Olefinchemie Gmbh | Neue Bisphosphitverbindungen und deren Metallkomplexe |
-
2001
- 2001-08-16 DE DE10140083A patent/DE10140083A1/de not_active Withdrawn
-
2002
- 2002-08-07 AT AT02769970T patent/ATE388157T1/de not_active IP Right Cessation
- 2002-08-07 WO PCT/EP2002/008798 patent/WO2003016320A1/de active IP Right Grant
- 2002-08-07 JP JP2003521242A patent/JP4272986B2/ja not_active Expired - Fee Related
- 2002-08-07 MX MXPA04001348A patent/MXPA04001348A/es active IP Right Grant
- 2002-08-07 KR KR1020047002197A patent/KR100869042B1/ko not_active Expired - Fee Related
- 2002-08-07 EP EP02769970A patent/EP1417212B1/de not_active Expired - Lifetime
- 2002-08-07 ES ES02769970T patent/ES2301680T3/es not_active Expired - Lifetime
- 2002-08-07 DE DE50211846T patent/DE50211846D1/de not_active Expired - Lifetime
- 2002-08-07 US US10/485,817 patent/US7009068B2/en not_active Expired - Fee Related
- 2002-08-07 CN CNB028160525A patent/CN1310928C/zh not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
WO2003016320A1 (de) | 2003-02-27 |
US7009068B2 (en) | 2006-03-07 |
JP2005500384A (ja) | 2005-01-06 |
CN1310928C (zh) | 2007-04-18 |
EP1417212B1 (de) | 2008-03-05 |
EP1417212A1 (de) | 2004-05-12 |
JP4272986B2 (ja) | 2009-06-03 |
CN1543469A (zh) | 2004-11-03 |
DE50211846D1 (de) | 2008-04-17 |
ES2301680T3 (es) | 2008-07-01 |
ATE388157T1 (de) | 2008-03-15 |
KR20040030086A (ko) | 2004-04-08 |
DE10140083A1 (de) | 2003-02-27 |
US20040236134A1 (en) | 2004-11-25 |
KR100869042B1 (ko) | 2008-11-17 |
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